#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/55/7015562.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7015562
loop_
_publ_author_name
'Singh, Nem'
'Elias, Anil J.'
_publ_section_title
;
 Palladacycles of novel bisoxazoline chelating ligands based on the
 dimeric cyclobutadiene linked cobalt sandwich compound
 [(η5-Cp)Co(η4-C4Ph3)]2.
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4882
_journal_page_last               4891
_journal_paper_doi               10.1039/c0dt01737j
_journal_volume                  40
_journal_year                    2011
_chemical_absolute_configuration syn
_chemical_formula_moiety         'C68 H60 Co2 N2 O4 Pd'
_chemical_formula_sum            'C68 H60 Co2 N2 O4 Pd'
_chemical_formula_weight         1193.44
_chemical_name_systematic
;
?
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.2720(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   14.1031(8)
_cell_length_b                   12.7228(7)
_cell_length_c                   16.6008(10)
_cell_measurement_reflns_used    4829
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.80
_cell_measurement_theta_min      1.86
_cell_volume                     2811.8(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0386
_diffrn_reflns_av_sigmaI/netI    0.0514
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            28326
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.30
_exptl_absorpt_coefficient_mu    0.951
_exptl_absorpt_correction_T_max  0.895
_exptl_absorpt_correction_T_min  0.864
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.410
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1228
_exptl_crystal_size_max          0.252
_exptl_crystal_size_mid          0.128
_exptl_crystal_size_min          0.114
_refine_diff_density_max         0.798
_refine_diff_density_min         -0.521
_refine_diff_density_rms         0.077
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.024(12)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     699
_refine_ls_number_reflns         10456
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0405
_refine_ls_R_factor_gt           0.0382
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0418P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0823
_refine_ls_wR_factor_ref         0.0833
_reflns_number_gt                9987
_reflns_number_total             10456
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt01737j.txt
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_Hall     P2yb
_cod_original_sg_symbol_H-M      P21
_cod_database_code               7015562
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.590592(18) 0.920245(19) 0.251598(16) 0.01815(7) Uani 1 1 d . . .
Co1 Co 0.69884(3) 0.83490(4) 0.08511(3) 0.01913(12) Uani 1 1 d . . .
Co2 Co 0.93217(4) 0.96841(5) 0.32893(3) 0.02668(13) Uani 1 1 d . . .
O2 O 0.7476(2) 1.2065(2) 0.28560(18) 0.0326(7) Uani 1 1 d . . .
O1 O 0.5136(2) 0.6322(2) 0.13681(18) 0.0322(7) Uani 1 1 d . . .
O3 O 0.56797(19) 0.9398(2) 0.36944(16) 0.0258(7) Uani 1 1 d . . .
O4 O 0.6639(2) 0.8038(2) 0.42961(19) 0.0380(7) Uani 1 1 d . . .
N2 N 0.6441(2) 1.0683(2) 0.25997(19) 0.0214(7) Uani 1 1 d . . .
N1 N 0.5423(2) 0.7675(2) 0.2273(2) 0.0237(7) Uani 1 1 d . . .
C1 C 0.5606(3) 0.8050(3) 0.0960(2) 0.0218(8) Uani 1 1 d . . .
C2 C 0.5932(2) 0.9059(3) 0.1338(2) 0.0198(8) Uani 1 1 d . . .
C3 C 0.6071(3) 0.9680(3) 0.0680(2) 0.0245(8) Uani 1 1 d . . .
H3 H 0.6305 1.0410 0.0740 0.029 Uiso 1 1 calc R . .
C4 C 0.5815(2) 0.9073(3) -0.0083(2) 0.0257(9) Uani 1 1 d . . .
H4 H 0.5837 0.9323 -0.0635 0.031 Uiso 1 1 calc R . .
C5 C 0.5525(3) 0.8052(3) 0.0084(2) 0.0248(9) Uani 1 1 d . . .
H5 H 0.5290 0.7477 -0.0326 0.030 Uiso 1 1 calc R . .
C6 C 0.8464(3) 0.8343(3) 0.1529(2) 0.0218(8) Uani 1 1 d . . .
C7 C 0.8286(3) 0.8311(3) 0.0612(2) 0.0218(8) Uani 1 1 d . . .
C8 C 0.7836(3) 0.7272(3) 0.0556(2) 0.0205(8) Uani 1 1 d . . .
C9 C 0.8009(3) 0.7294(3) 0.1475(2) 0.0221(8) Uani 1 1 d . . .
C10 C 0.5382(3) 0.7320(3) 0.1536(2) 0.0219(8) Uani 1 1 d . . .
C11 C 0.5096(4) 0.5880(3) 0.2173(3) 0.0382(11) Uani 1 1 d . . .
H11A H 0.5675 0.5437 0.2438 0.046 Uiso 1 1 calc R . .
H11B H 0.4490 0.5467 0.2078 0.046 Uiso 1 1 calc R . .
C12 C 0.5097(3) 0.6843(3) 0.2736(3) 0.0308(10) Uani 1 1 d . . .
H12 H 0.5597 0.6748 0.3303 0.037 Uiso 1 1 calc R . .
C13 C 0.4067(3) 0.7118(4) 0.2820(3) 0.0402(11) Uani 1 1 d . . .
H13 H 0.4131 0.7815 0.3084 0.048 Uiso 1 1 calc R . .
C14 C 0.3233(3) 0.7187(4) 0.1959(3) 0.0469(12) Uani 1 1 d . . .
H14A H 0.3147 0.6514 0.1683 0.070 Uiso 1 1 calc R . .
H14B H 0.3409 0.7699 0.1608 0.070 Uiso 1 1 calc R . .
H14C H 0.2617 0.7391 0.2044 0.070 Uiso 1 1 calc R . .
C15 C 0.3821(5) 0.6352(5) 0.3422(4) 0.0718(18) Uani 1 1 d . . .
H15A H 0.3193 0.6543 0.3488 0.108 Uiso 1 1 calc R . .
H15B H 0.4342 0.6372 0.3967 0.108 Uiso 1 1 calc R . .
H15C H 0.3772 0.5654 0.3191 0.108 Uiso 1 1 calc R . .
C16 C 0.8195(3) 1.0495(3) 0.3563(2) 0.0260(9) Uani 1 1 d . . .
C17 C 0.9151(3) 1.0969(4) 0.3973(3) 0.0368(11) Uani 1 1 d . . .
H17 H 0.9342 1.1694 0.3897 0.044 Uiso 1 1 calc R . .
C18 C 0.9750(3) 1.0226(4) 0.4527(3) 0.0394(12) Uani 1 1 d . . .
H18 H 1.0445 1.0339 0.4896 0.047 Uiso 1 1 calc R . .
C19 C 0.9207(3) 0.9283(5) 0.4468(2) 0.0374(10) Uani 1 1 d . . .
H19 H 0.9455 0.8635 0.4787 0.045 Uiso 1 1 calc R . .
C20 C 0.8239(3) 0.9443(3) 0.3870(2) 0.0305(11) Uani 1 1 d . . .
H20 H 0.7695 0.8925 0.3699 0.037 Uiso 1 1 calc R . .
C21 C 0.9190(3) 0.8953(3) 0.2187(2) 0.0240(9) Uani 1 1 d . . .
C22 C 0.9598(3) 1.0027(3) 0.2225(2) 0.0255(9) Uani 1 1 d . . .
C23 C 1.0504(3) 0.9691(4) 0.2908(2) 0.0271(9) Uani 1 1 d . . .
C24 C 1.0116(3) 0.8634(4) 0.2880(2) 0.0271(10) Uani 1 1 d . . .
C25 C 0.7337(3) 1.1038(3) 0.2980(2) 0.0258(9) Uani 1 1 d . . .
C26 C 0.6562(3) 1.2435(3) 0.2212(3) 0.0335(10) Uani 1 1 d . . .
H26A H 0.6650 1.2487 0.1657 0.040 Uiso 1 1 calc R . .
H26B H 0.6362 1.3115 0.2365 0.040 Uiso 1 1 calc R . .
C27 C 0.5789(3) 1.1586(3) 0.2211(3) 0.0260(9) Uani 1 1 d . . .
H27 H 0.5384 1.1416 0.1622 0.031 Uiso 1 1 calc R . .
C28 C 0.5092(3) 1.1867(3) 0.2727(3) 0.0266(9) Uani 1 1 d . . .
H28 H 0.4687 1.1243 0.2733 0.032 Uiso 1 1 calc R . .
C29 C 0.4374(3) 1.2735(4) 0.2278(3) 0.0385(11) Uani 1 1 d . . .
H29A H 0.3884 1.2839 0.2558 0.058 Uiso 1 1 calc R . .
H29B H 0.4040 1.2539 0.1694 0.058 Uiso 1 1 calc R . .
H29C H 0.4742 1.3374 0.2298 0.058 Uiso 1 1 calc R . .
C30 C 0.5677(3) 1.2138(4) 0.3652(3) 0.0348(10) Uani 1 1 d . . .
H30A H 0.6105 1.2730 0.3669 0.052 Uiso 1 1 calc R . .
H30B H 0.6079 1.1546 0.3922 0.052 Uiso 1 1 calc R . .
H30C H 0.5216 1.2308 0.3947 0.052 Uiso 1 1 calc R . .
C31 C 0.7940(3) 0.6508(3) 0.2110(2) 0.0252(9) Uani 1 1 d . . .
C32 C 0.7774(3) 0.6805(4) 0.2853(2) 0.0303(10) Uani 1 1 d . . .
H32 H 0.7663 0.7510 0.2941 0.036 Uiso 1 1 calc R . .
C33 C 0.7771(3) 0.6077(4) 0.3464(3) 0.0392(11) Uani 1 1 d . . .
H33 H 0.7657 0.6289 0.3960 0.047 Uiso 1 1 calc R . .
C34 C 0.7938(3) 0.5025(4) 0.3337(3) 0.0412(12) Uani 1 1 d . . .
H34 H 0.7931 0.4528 0.3746 0.049 Uiso 1 1 calc R . .
C35 C 0.8112(3) 0.4720(3) 0.2605(3) 0.0374(10) Uani 1 1 d . . .
H35 H 0.8233 0.4017 0.2522 0.045 Uiso 1 1 calc R . .
C36 C 0.8109(3) 0.5449(3) 0.1998(3) 0.0304(9) Uani 1 1 d . . .
H36 H 0.8222 0.5232 0.1503 0.037 Uiso 1 1 calc R . .
C37 C 0.7502(3) 0.6487(3) -0.0121(2) 0.0214(8) Uani 1 1 d . . .
C38 C 0.6809(3) 0.5697(3) -0.0118(3) 0.0263(9) Uani 1 1 d . . .
H38 H 0.6547 0.5664 0.0328 0.032 Uiso 1 1 calc R . .
C39 C 0.6511(3) 0.4968(3) -0.0767(3) 0.0297(9) Uani 1 1 d . . .
H39 H 0.6067 0.4435 -0.0749 0.036 Uiso 1 1 calc R . .
C40 C 0.6869(3) 0.5028(3) -0.1443(3) 0.0324(10) Uani 1 1 d . . .
H40 H 0.6653 0.4546 -0.1887 0.039 Uiso 1 1 calc R . .
C41 C 0.7550(3) 0.5804(3) -0.1464(3) 0.0341(10) Uani 1 1 d . . .
H41 H 0.7790 0.5842 -0.1922 0.041 Uiso 1 1 calc R . .
C42 C 0.7871(3) 0.6520(3) -0.0803(2) 0.0264(9) Uani 1 1 d . . .
H42 H 0.8338 0.7030 -0.0814 0.032 Uiso 1 1 calc R . .
C43 C 0.8641(3) 0.8966(3) 0.0036(2) 0.0251(9) Uani 1 1 d . . .
C44 C 0.8033(3) 0.9204(4) -0.0796(2) 0.0379(10) Uani 1 1 d . . .
H44 H 0.7384 0.8934 -0.1000 0.045 Uiso 1 1 calc R . .
C45 C 0.8371(5) 0.9825(4) -0.1316(3) 0.0532(14) Uani 1 1 d . . .
H45 H 0.7960 0.9960 -0.1872 0.064 Uiso 1 1 calc R . .
C46 C 0.9316(6) 1.0247(4) -0.1018(4) 0.070(2) Uani 1 1 d . . .
H46 H 0.9533 1.0691 -0.1367 0.084 Uiso 1 1 calc R . .
C47 C 0.9944(5) 1.0025(5) -0.0212(4) 0.074(2) Uani 1 1 d . . .
H47 H 1.0587 1.0310 -0.0015 0.088 Uiso 1 1 calc R . .
C48 C 0.9607(3) 0.9361(4) 0.0317(3) 0.0454(13) Uani 1 1 d . . .
H48 H 1.0037 0.9189 0.0858 0.055 Uiso 1 1 calc R . .
C49 C 0.9280(3) 1.0995(3) 0.1729(2) 0.0266(9) Uani 1 1 d . . .
C50 C 0.8317(3) 1.1073(3) 0.1138(3) 0.0329(10) Uani 1 1 d . . .
H50 H 0.7872 1.0516 0.1078 0.039 Uiso 1 1 calc R . .
C51 C 0.8007(4) 1.1947(4) 0.0644(3) 0.0395(11) Uani 1 1 d . . .
H51 H 0.7360 1.1977 0.0253 0.047 Uiso 1 1 calc R . .
C52 C 0.8653(4) 1.2785(4) 0.0725(3) 0.0453(12) Uani 1 1 d . . .
H52 H 0.8444 1.3387 0.0397 0.054 Uiso 1 1 calc R . .
C53 C 0.9606(4) 1.2716(4) 0.1297(4) 0.0555(14) Uani 1 1 d . . .
H53 H 1.0047 1.3275 0.1349 0.067 Uiso 1 1 calc R . .
C54 C 0.9929(4) 1.1833(4) 0.1799(3) 0.0457(12) Uani 1 1 d . . .
H54 H 1.0581 1.1803 0.2183 0.055 Uiso 1 1 calc R . .
C55 C 1.1522(3) 1.0129(4) 0.3353(2) 0.0327(10) Uani 1 1 d . . .
C56 C 1.1673(3) 1.1086(4) 0.3769(3) 0.0462(13) Uani 1 1 d . . .
H56 H 1.1125 1.1489 0.3774 0.055 Uiso 1 1 calc R . .
C57 C 1.2651(4) 1.1450(5) 0.4186(3) 0.0592(16) Uani 1 1 d . . .
H57 H 1.2756 1.2082 0.4483 0.071 Uiso 1 1 calc R . .
C58 C 1.3452(4) 1.0861(5) 0.4148(3) 0.0577(16) Uani 1 1 d . . .
H58 H 1.4102 1.1104 0.4417 0.069 Uiso 1 1 calc R . .
C59 C 1.3311(3) 0.9917(5) 0.3720(3) 0.0467(13) Uani 1 1 d . . .
H59 H 1.3859 0.9529 0.3693 0.056 Uiso 1 1 calc R . .
C60 C 1.2351(3) 0.9555(4) 0.3333(3) 0.0371(11) Uani 1 1 d . . .
H60 H 1.2254 0.8911 0.3051 0.045 Uiso 1 1 calc R . .
C61 C 1.0568(3) 0.7654(4) 0.3289(2) 0.0299(10) Uani 1 1 d . . .
C62 C 1.1258(3) 0.7685(4) 0.4132(3) 0.0414(12) Uani 1 1 d . . .
H62 H 1.1402 0.8314 0.4433 0.050 Uiso 1 1 calc R . .
C63 C 1.1712(3) 0.6759(5) 0.4495(3) 0.0500(15) Uani 1 1 d . . .
H63 H 1.2172 0.6772 0.5046 0.060 Uiso 1 1 calc R . .
C64 C 1.1507(4) 0.5829(5) 0.4072(3) 0.0500(14) Uani 1 1 d . . .
H64 H 1.1816 0.5215 0.4335 0.060 Uiso 1 1 calc R . .
C65 C 1.0839(3) 0.5799(4) 0.3251(3) 0.0445(12) Uani 1 1 d . . .
H65 H 1.0693 0.5164 0.2958 0.053 Uiso 1 1 calc R . .
C66 C 1.0389(3) 0.6711(4) 0.2866(3) 0.0353(10) Uani 1 1 d . . .
H66 H 0.9953 0.6688 0.2307 0.042 Uiso 1 1 calc R . .
C67 C 0.6080(3) 0.8800(3) 0.4295(2) 0.0231(8) Uani 1 1 d . . .
C68 C 0.5869(4) 0.9031(4) 0.5124(3) 0.0449(12) Uani 1 1 d . . .
H68A H 0.5982 0.9764 0.5260 0.067 Uiso 1 1 calc R . .
H68B H 0.6309 0.8617 0.5577 0.067 Uiso 1 1 calc R . .
H68C H 0.5184 0.8859 0.5053 0.067 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Pd1 N2 91.47(14) . . ?
C2 Pd1 N1 80.33(15) . . ?
N2 Pd1 N1 171.55(13) . . ?
C2 Pd1 O3 172.58(12) . . ?
N2 Pd1 O3 89.63(11) . . ?
N1 Pd1 O3 98.77(11) . . ?
C8 Co1 C9 43.24(15) . . ?
C8 Co1 C7 42.94(15) . . ?
C9 Co1 C7 62.27(16) . . ?
C8 Co1 C6 62.59(15) . . ?
C9 Co1 C6 43.09(16) . . ?
C7 Co1 C6 42.70(14) . . ?
C8 Co1 C1 124.13(15) . . ?
C9 Co1 C1 111.95(15) . . ?
C7 Co1 C1 166.56(15) . . ?
C6 Co1 C1 141.88(15) . . ?
C8 Co1 C5 106.33(15) . . ?
C9 Co1 C5 126.85(16) . . ?
C7 Co1 C5 131.73(15) . . ?
C6 Co1 C5 168.44(16) . . ?
C1 Co1 C5 40.34(15) . . ?
C8 Co1 C4 121.30(15) . . ?
C9 Co1 C4 161.90(16) . . ?
C7 Co1 C4 114.81(15) . . ?
C6 Co1 C4 147.43(16) . . ?
C1 Co1 C4 66.52(15) . . ?
C5 Co1 C4 39.96(16) . . ?
C8 Co1 C3 157.17(15) . . ?
C9 Co1 C3 157.62(15) . . ?
C7 Co1 C3 123.96(16) . . ?
C6 Co1 C3 123.91(16) . . ?
C1 Co1 C3 66.37(15) . . ?
C5 Co1 C3 67.55(16) . . ?
C4 Co1 C3 39.99(15) . . ?
C8 Co1 C2 161.16(16) . . ?
C9 Co1 C2 124.62(15) . . ?
C7 Co1 C2 153.18(15) . . ?
C6 Co1 C2 121.06(14) . . ?
C1 Co1 C2 40.26(15) . . ?
C5 Co1 C2 68.21(14) . . ?
C4 Co1 C2 66.88(14) . . ?
C3 Co1 C2 39.19(15) . . ?
C23 Co2 C22 43.53(15) . . ?
C23 Co2 C24 42.75(17) . . ?
C22 Co2 C24 63.04(17) . . ?
C23 Co2 C21 62.78(15) . . ?
C22 Co2 C21 43.49(16) . . ?
C24 Co2 C21 43.46(15) . . ?
C23 Co2 C17 116.16(17) . . ?
C22 Co2 C17 114.36(19) . . ?
C24 Co2 C17 154.42(16) . . ?
C21 Co2 C17 152.01(18) . . ?
C23 Co2 C18 108.55(17) . . ?
C22 Co2 C18 137.49(19) . . ?
C24 Co2 C18 123.34(17) . . ?
C21 Co2 C18 166.78(17) . . ?
C17 Co2 C18 39.62(19) . . ?
C23 Co2 C16 149.58(18) . . ?
C22 Co2 C16 118.59(17) . . ?
C24 Co2 C16 164.80(16) . . ?
C21 Co2 C16 125.84(15) . . ?
C17 Co2 C16 40.61(15) . . ?
C18 Co2 C16 66.89(16) . . ?
C23 Co2 C19 129.84(16) . . ?
C22 Co2 C19 173.38(15) . . ?
C24 Co2 C19 112.47(19) . . ?
C21 Co2 C19 137.0(2) . . ?
C17 Co2 C19 67.3(2) . . ?
C18 Co2 C19 39.8(2) . . ?
C16 Co2 C19 67.12(18) . . ?
C23 Co2 C20 168.14(17) . . ?
C22 Co2 C20 146.84(15) . . ?
C24 Co2 C20 129.64(17) . . ?
C21 Co2 C20 119.54(16) . . ?
C17 Co2 C20 67.82(17) . . ?
C18 Co2 C20 66.77(17) . . ?
C16 Co2 C20 40.22(16) . . ?
C19 Co2 C20 39.71(14) . . ?
C25 O2 C26 106.7(3) . . ?
C10 O1 C11 105.2(3) . . ?
C67 O3 Pd1 120.7(2) . . ?
C25 N2 C27 108.0(3) . . ?
C25 N2 Pd1 130.0(3) . . ?
C27 N2 Pd1 122.0(2) . . ?
C10 N1 C12 108.7(3) . . ?
C10 N1 Pd1 115.2(3) . . ?
C12 N1 Pd1 136.1(3) . . ?
C5 C1 C2 110.5(3) . . ?
C5 C1 C10 136.1(4) . . ?
C2 C1 C10 113.3(3) . . ?
C5 C1 Co1 70.5(2) . . ?
C2 C1 Co1 72.3(2) . . ?
C10 C1 Co1 126.9(3) . . ?
C3 C2 C1 105.6(3) . . ?
C3 C2 Pd1 140.0(3) . . ?
C1 C2 Pd1 114.0(3) . . ?
C3 C2 Co1 69.5(2) . . ?
C1 C2 Co1 67.4(2) . . ?
Pd1 C2 Co1 131.47(18) . . ?
C2 C3 C4 109.0(4) . . ?
C2 C3 Co1 71.4(2) . . ?
C4 C3 Co1 69.2(2) . . ?
C2 C3 H3 125.5 . . ?
C4 C3 H3 125.5 . . ?
Co1 C3 H3 125.5 . . ?
C5 C4 C3 109.2(3) . . ?
C5 C4 Co1 70.0(2) . . ?
C3 C4 Co1 70.8(2) . . ?
C5 C4 H4 125.4 . . ?
C3 C4 H4 125.4 . . ?
Co1 C4 H4 125.4 . . ?
C4 C5 C1 105.7(3) . . ?
C4 C5 Co1 70.1(2) . . ?
C1 C5 Co1 69.1(2) . . ?
C4 C5 H5 127.1 . . ?
C1 C5 H5 127.1 . . ?
Co1 C5 H5 127.1 . . ?
C21 C6 C7 129.5(3) . . ?
C21 C6 C9 135.8(3) . . ?
C7 C6 C9 89.4(3) . . ?
C21 C6 Co1 139.6(3) . . ?
C7 C6 Co1 68.07(19) . . ?
C9 C6 Co1 67.64(19) . . ?
C8 C7 C6 90.7(3) . . ?
C8 C7 C43 134.8(3) . . ?
C6 C7 C43 133.1(3) . . ?
C8 C7 Co1 68.02(19) . . ?
C6 C7 Co1 69.2(2) . . ?
C43 C7 Co1 130.2(3) . . ?
C7 C8 C37 133.9(3) . . ?
C7 C8 C9 89.8(3) . . ?
C37 C8 C9 135.7(3) . . ?
C7 C8 Co1 69.0(2) . . ?
C37 C8 Co1 126.5(2) . . ?
C9 C8 Co1 68.6(2) . . ?
C8 C9 C6 90.0(3) . . ?
C8 C9 C31 134.6(4) . . ?
C6 C9 C31 134.4(3) . . ?
C8 C9 Co1 68.1(2) . . ?
C6 C9 Co1 69.3(2) . . ?
C31 C9 Co1 128.3(3) . . ?
N1 C10 O1 117.6(4) . . ?
N1 C10 C1 117.0(3) . . ?
O1 C10 C1 125.4(3) . . ?
O1 C11 C12 104.7(3) . . ?
O1 C11 H11A 110.8 . . ?
C12 C11 H11A 110.8 . . ?
O1 C11 H11B 110.8 . . ?
C12 C11 H11B 110.8 . . ?
H11A C11 H11B 108.9 . . ?
N1 C12 C11 101.2(3) . . ?
N1 C12 C13 110.5(3) . . ?
C11 C12 C13 115.0(4) . . ?
N1 C12 H12 109.9 . . ?
C11 C12 H12 109.9 . . ?
C13 C12 H12 109.9 . . ?
C15 C13 C14 112.4(4) . . ?
C15 C13 C12 109.9(4) . . ?
C14 C13 C12 112.7(4) . . ?
C15 C13 H13 107.2 . . ?
C14 C13 H13 107.2 . . ?
C12 C13 H13 107.2 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C20 C16 C17 107.7(4) . . ?
C20 C16 C25 127.9(3) . . ?
C17 C16 C25 124.4(4) . . ?
C20 C16 Co2 70.4(2) . . ?
C17 C16 Co2 69.1(2) . . ?
C25 C16 Co2 128.6(3) . . ?
C18 C17 C16 107.4(4) . . ?
C18 C17 Co2 70.6(3) . . ?
C16 C17 Co2 70.3(2) . . ?
C18 C17 H17 126.3 . . ?
C16 C17 H17 126.3 . . ?
Co2 C17 H17 126.3 . . ?
C17 C18 C19 109.5(4) . . ?
C17 C18 Co2 69.8(2) . . ?
C19 C18 Co2 70.9(2) . . ?
C17 C18 H18 125.2 . . ?
C19 C18 H18 125.2 . . ?
Co2 C18 H18 125.2 . . ?
C18 C19 C20 107.7(4) . . ?
C18 C19 Co2 69.3(2) . . ?
C20 C19 Co2 70.2(2) . . ?
C18 C19 H19 126.2 . . ?
C20 C19 H19 126.2 . . ?
Co2 C19 H19 126.2 . . ?
C19 C20 C16 107.7(4) . . ?
C19 C20 Co2 70.1(2) . . ?
C16 C20 Co2 69.4(2) . . ?
C19 C20 H20 126.1 . . ?
C16 C20 H20 126.1 . . ?
Co2 C20 H20 126.1 . . ?
C6 C21 C22 134.1(4) . . ?
C6 C21 C24 131.2(4) . . ?
C22 C21 C24 89.3(3) . . ?
C6 C21 Co2 139.9(3) . . ?
C22 C21 Co2 67.3(2) . . ?
C24 C21 Co2 68.1(2) . . ?
C23 C22 C49 134.9(4) . . ?
C23 C22 C21 89.5(3) . . ?
C49 C22 C21 135.3(3) . . ?
C23 C22 Co2 67.9(2) . . ?
C49 C22 Co2 124.9(3) . . ?
C21 C22 Co2 69.2(2) . . ?
C24 C23 C22 91.2(3) . . ?
C24 C23 C55 131.1(4) . . ?
C22 C23 C55 136.6(4) . . ?
C24 C23 Co2 69.8(2) . . ?
C22 C23 Co2 68.6(2) . . ?
C55 C23 Co2 128.5(3) . . ?
C23 C24 C61 132.4(3) . . ?
C23 C24 C21 89.9(3) . . ?
C61 C24 C21 136.9(4) . . ?
C23 C24 Co2 67.5(2) . . ?
C61 C24 Co2 128.3(3) . . ?
C21 C24 Co2 68.4(2) . . ?
N2 C25 O2 115.6(4) . . ?
N2 C25 C16 128.7(4) . . ?
O2 C25 C16 115.6(3) . . ?
O2 C26 C27 103.3(3) . . ?
O2 C26 H26A 111.1 . . ?
C27 C26 H26A 111.1 . . ?
O2 C26 H26B 111.1 . . ?
C27 C26 H26B 111.1 . . ?
H26A C26 H26B 109.1 . . ?
N2 C27 C26 101.9(3) . . ?
N2 C27 C28 110.8(3) . . ?
C26 C27 C28 114.8(3) . . ?
N2 C27 H27 109.7 . . ?
C26 C27 H27 109.7 . . ?
C28 C27 H27 109.7 . . ?
C29 C28 C30 112.5(4) . . ?
C29 C28 C27 109.8(3) . . ?
C30 C28 C27 112.3(3) . . ?
C29 C28 H28 107.3 . . ?
C30 C28 H28 107.3 . . ?
C27 C28 H28 107.3 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 C36 118.1(4) . . ?
C32 C31 C9 121.4(4) . . ?
C36 C31 C9 120.4(4) . . ?
C33 C32 C31 121.1(4) . . ?
C33 C32 H32 119.4 . . ?
C31 C32 H32 119.4 . . ?
C32 C33 C34 119.8(4) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 H33 120.1 . . ?
C35 C34 C33 119.7(4) . . ?
C35 C34 H34 120.1 . . ?
C33 C34 H34 120.1 . . ?
C36 C35 C34 120.2(4) . . ?
C36 C35 H35 119.9 . . ?
C34 C35 H35 119.9 . . ?
C35 C36 C31 121.2(4) . . ?
C35 C36 H36 119.4 . . ?
C31 C36 H36 119.4 . . ?
C42 C37 C38 118.1(3) . . ?
C42 C37 C8 119.5(3) . . ?
C38 C37 C8 122.4(3) . . ?
C39 C38 C37 120.8(4) . . ?
C39 C38 H38 119.6 . . ?
C37 C38 H38 119.6 . . ?
C40 C39 C38 120.0(4) . . ?
C40 C39 H39 120.0 . . ?
C38 C39 H39 120.0 . . ?
C39 C40 C41 120.4(4) . . ?
C39 C40 H40 119.8 . . ?
C41 C40 H40 119.8 . . ?
C42 C41 C40 119.8(4) . . ?
C42 C41 H41 120.1 . . ?
C40 C41 H41 120.1 . . ?
C41 C42 C37 120.9(4) . . ?
C41 C42 H42 119.6 . . ?
C37 C42 H42 119.6 . . ?
C48 C43 C44 118.0(4) . . ?
C48 C43 C7 119.7(4) . . ?
C44 C43 C7 122.3(4) . . ?
C45 C44 C43 121.4(5) . . ?
C45 C44 H44 119.3 . . ?
C43 C44 H44 119.3 . . ?
C44 C45 C46 120.0(5) . . ?
C44 C45 H45 120.0 . . ?
C46 C45 H45 120.0 . . ?
C47 C46 C45 120.7(5) . . ?
C47 C46 H46 119.6 . . ?
C45 C46 H46 119.6 . . ?
C46 C47 C48 119.4(5) . . ?
C46 C47 H47 120.3 . . ?
C48 C47 H47 120.3 . . ?
C43 C48 C47 120.4(5) . . ?
C43 C48 H48 119.8 . . ?
C47 C48 H48 119.8 . . ?
C54 C49 C50 117.9(4) . . ?
C54 C49 C22 121.9(4) . . ?
C50 C49 C22 120.2(4) . . ?
C51 C50 C49 121.8(4) . . ?
C51 C50 H50 119.1 . . ?
C49 C50 H50 119.1 . . ?
C50 C51 C52 120.1(4) . . ?
C50 C51 H51 120.0 . . ?
C52 C51 H51 120.0 . . ?
C53 C52 C51 118.9(5) . . ?
C53 C52 H52 120.5 . . ?
C51 C52 H52 120.5 . . ?
C52 C53 C54 121.5(5) . . ?
C52 C53 H53 119.2 . . ?
C54 C53 H53 119.2 . . ?
C53 C54 C49 119.8(5) . . ?
C53 C54 H54 120.1 . . ?
C49 C54 H54 120.1 . . ?
C56 C55 C60 118.9(4) . . ?
C56 C55 C23 122.9(4) . . ?
C60 C55 C23 118.2(4) . . ?
C55 C56 C57 120.2(5) . . ?
C55 C56 H56 119.9 . . ?
C57 C56 H56 119.9 . . ?
C58 C57 C56 119.1(5) . . ?
C58 C57 H57 120.4 . . ?
C56 C57 H57 120.4 . . ?
C57 C58 C59 121.2(5) . . ?
C57 C58 H58 119.4 . . ?
C59 C58 H58 119.4 . . ?
C60 C59 C58 119.2(5) . . ?
C60 C59 H59 120.4 . . ?
C58 C59 H59 120.4 . . ?
C59 C60 C55 121.3(5) . . ?
C59 C60 H60 119.3 . . ?
C55 C60 H60 119.3 . . ?
C66 C61 C62 118.7(4) . . ?
C66 C61 C24 122.0(4) . . ?
C62 C61 C24 119.1(4) . . ?
C63 C62 C61 118.4(5) . . ?
C63 C62 H62 120.8 . . ?
C61 C62 H62 120.8 . . ?
C64 C63 C62 121.9(4) . . ?
C64 C63 H63 119.0 . . ?
C62 C63 H63 119.0 . . ?
C63 C64 C65 119.7(5) . . ?
C63 C64 H64 120.1 . . ?
C65 C64 H64 120.1 . . ?
C66 C65 C64 119.7(5) . . ?
C66 C65 H65 120.1 . . ?
C64 C65 H65 120.1 . . ?
C61 C66 C65 121.5(4) . . ?
C61 C66 H66 119.2 . . ?
C65 C66 H66 119.2 . . ?
O3 C67 O4 127.0(4) . . ?
O3 C67 C68 115.8(4) . . ?
O4 C67 C68 117.3(4) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 C2 1.977(3) . ?
Pd1 N2 2.017(3) . ?
Pd1 N1 2.054(3) . ?
Pd1 O3 2.098(2) . ?
Co1 C8 1.983(4) . ?
Co1 C9 1.991(4) . ?
Co1 C7 1.997(3) . ?
Co1 C6 2.013(4) . ?
Co1 C1 2.052(4) . ?
Co1 C5 2.071(3) . ?
Co1 C4 2.072(4) . ?
Co1 C3 2.093(4) . ?
Co1 C2 2.117(3) . ?
Co2 C23 1.970(4) . ?
Co2 C22 1.979(4) . ?
Co2 C24 2.000(4) . ?
Co2 C21 2.005(4) . ?
Co2 C17 2.050(4) . ?
Co2 C18 2.060(4) . ?
Co2 C16 2.066(4) . ?
Co2 C19 2.079(4) . ?
Co2 C20 2.080(4) . ?
O2 C25 1.347(5) . ?
O2 C26 1.455(5) . ?
O1 C10 1.322(5) . ?
O1 C11 1.469(5) . ?
O3 C67 1.233(4) . ?
O4 C67 1.249(5) . ?
N2 C25 1.293(5) . ?
N2 C27 1.481(5) . ?
N1 C10 1.288(5) . ?
N1 C12 1.468(5) . ?
C1 C5 1.422(5) . ?
C1 C2 1.436(5) . ?
C1 C10 1.440(5) . ?
C2 C3 1.412(5) . ?
C3 C4 1.424(5) . ?
C3 H3 0.9800 . ?
C4 C5 1.416(6) . ?
C4 H4 0.9800 . ?
C5 H5 0.9800 . ?
C6 C21 1.451(5) . ?
C6 C7 1.460(5) . ?
C6 C9 1.471(5) . ?
C7 C8 1.457(5) . ?
C7 C43 1.475(5) . ?
C8 C37 1.459(5) . ?
C8 C9 1.464(5) . ?
C9 C31 1.479(5) . ?
C11 C12 1.540(6) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.544(6) . ?
C12 H12 0.9800 . ?
C13 C15 1.516(7) . ?
C13 C14 1.525(7) . ?
C13 H13 0.9800 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 C20 1.425(6) . ?
C16 C17 1.428(5) . ?
C16 C25 1.451(6) . ?
C17 C18 1.393(7) . ?
C17 H17 0.9800 . ?
C18 C19 1.409(7) . ?
C18 H18 0.9800 . ?
C19 C20 1.413(5) . ?
C19 H19 0.9800 . ?
C20 H20 0.9800 . ?
C21 C22 1.476(6) . ?
C21 C24 1.483(5) . ?
C22 C23 1.464(5) . ?
C22 C49 1.467(6) . ?
C23 C24 1.447(6) . ?
C23 C55 1.488(5) . ?
C24 C61 1.462(6) . ?
C26 C27 1.535(5) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.544(5) . ?
C27 H27 0.9800 . ?
C28 C29 1.518(6) . ?
C28 C30 1.523(6) . ?
C28 H28 0.9800 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 C32 1.382(6) . ?
C31 C36 1.391(6) . ?
C32 C33 1.375(6) . ?
C32 H32 0.9300 . ?
C33 C34 1.387(7) . ?
C33 H33 0.9300 . ?
C34 C35 1.372(6) . ?
C34 H34 0.9300 . ?
C35 C36 1.368(6) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 C42 1.395(5) . ?
C37 C38 1.403(5) . ?
C38 C39 1.379(6) . ?
C38 H38 0.9300 . ?
C39 C40 1.375(6) . ?
C39 H39 0.9300 . ?
C40 C41 1.385(6) . ?
C40 H40 0.9300 . ?
C41 C42 1.382(5) . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C43 C48 1.381(6) . ?
C43 C44 1.397(5) . ?
C44 C45 1.367(6) . ?
C44 H44 0.9300 . ?
C45 C46 1.369(8) . ?
C45 H45 0.9300 . ?
C46 C47 1.368(9) . ?
C46 H46 0.9300 . ?
C47 C48 1.409(8) . ?
C47 H47 0.9300 . ?
C48 H48 0.9300 . ?
C49 C54 1.386(6) . ?
C49 C50 1.392(6) . ?
C50 C51 1.364(6) . ?
C50 H50 0.9300 . ?
C51 C52 1.380(7) . ?
C51 H51 0.9300 . ?
C52 C53 1.369(7) . ?
C52 H52 0.9300 . ?
C53 C54 1.383(7) . ?
C53 H53 0.9300 . ?
C54 H54 0.9300 . ?
C55 C56 1.381(7) . ?
C55 C60 1.389(6) . ?
C56 C57 1.401(6) . ?
C56 H56 0.9300 . ?
C57 C58 1.375(8) . ?
C57 H57 0.9300 . ?
C58 C59 1.376(8) . ?
C58 H58 0.9300 . ?
C59 C60 1.372(6) . ?
C59 H59 0.9300 . ?
C60 H60 0.9300 . ?
C61 C66 1.370(6) . ?
C61 C62 1.417(6) . ?
C62 C63 1.382(7) . ?
C62 H62 0.9300 . ?
C63 C64 1.357(8) . ?
C63 H63 0.9300 . ?
C64 C65 1.378(7) . ?
C64 H64 0.9300 . ?
C65 C66 1.375(6) . ?
C65 H65 0.9300 . ?
C66 H66 0.9300 . ?
C67 C68 1.529(5) . ?
C68 H68A 0.9600 . ?
C68 H68B 0.9600 . ?
C68 H68C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Pd1 O3 C67 -122.6(3) . . . . ?
N1 Pd1 O3 C67 56.4(3) . . . . ?
C2 Pd1 N2 C25 -102.4(3) . . . . ?
O3 Pd1 N2 C25 84.9(3) . . . . ?
C2 Pd1 N2 C27 79.0(3) . . . . ?
O3 Pd1 N2 C27 -93.7(3) . . . . ?
C2 Pd1 N1 C10 1.8(3) . . . . ?
O3 Pd1 N1 C10 174.3(3) . . . . ?
C2 Pd1 N1 C12 -178.1(4) . . . . ?
O3 Pd1 N1 C12 -5.6(4) . . . . ?
C8 Co1 C1 C5 -74.1(3) . . . . ?
C9 Co1 C1 C5 -121.6(2) . . . . ?
C7 Co1 C1 C5 -59.8(7) . . . . ?
C6 Co1 C1 C5 -162.0(3) . . . . ?
C4 Co1 C1 C5 38.8(2) . . . . ?
C3 Co1 C1 C5 82.6(2) . . . . ?
C2 Co1 C1 C5 120.2(3) . . . . ?
C8 Co1 C1 C2 165.7(2) . . . . ?
C9 Co1 C1 C2 118.2(2) . . . . ?
C7 Co1 C1 C2 180.0(6) . . . . ?
C6 Co1 C1 C2 77.8(3) . . . . ?
C5 Co1 C1 C2 -120.2(3) . . . . ?
C4 Co1 C1 C2 -81.4(2) . . . . ?
C3 Co1 C1 C2 -37.6(2) . . . . ?
C8 Co1 C1 C10 59.5(4) . . . . ?
C9 Co1 C1 C10 12.0(4) . . . . ?
C7 Co1 C1 C10 73.8(8) . . . . ?
C6 Co1 C1 C10 -28.4(5) . . . . ?
C5 Co1 C1 C10 133.6(4) . . . . ?
C4 Co1 C1 C10 172.4(4) . . . . ?
C3 Co1 C1 C10 -143.8(4) . . . . ?
C2 Co1 C1 C10 -106.2(4) . . . . ?
C5 C1 C2 C3 -1.2(4) . . . . ?
C10 C1 C2 C3 -177.4(3) . . . . ?
Co1 C1 C2 C3 59.3(2) . . . . ?
C5 C1 C2 Pd1 172.7(2) . . . . ?
C10 C1 C2 Pd1 -3.6(4) . . . . ?
Co1 C1 C2 Pd1 -126.9(2) . . . . ?
C5 C1 C2 Co1 -60.5(2) . . . . ?
C10 C1 C2 Co1 123.3(3) . . . . ?
N2 Pd1 C2 C3 -10.2(4) . . . . ?
N1 Pd1 C2 C3 171.8(4) . . . . ?
N2 Pd1 C2 C1 179.1(3) . . . . ?
N1 Pd1 C2 C1 1.1(2) . . . . ?
N2 Pd1 C2 Co1 98.7(3) . . . . ?
N1 Pd1 C2 Co1 -79.3(3) . . . . ?
C8 Co1 C2 C3 -157.2(4) . . . . ?
C9 Co1 C2 C3 158.6(2) . . . . ?
C7 Co1 C2 C3 62.2(4) . . . . ?
C6 Co1 C2 C3 107.0(2) . . . . ?
C1 Co1 C2 C3 -117.8(3) . . . . ?
C5 Co1 C2 C3 -80.8(2) . . . . ?
C4 Co1 C2 C3 -37.4(2) . . . . ?
C8 Co1 C2 C1 -39.4(5) . . . . ?
C9 Co1 C2 C1 -83.5(2) . . . . ?
C7 Co1 C2 C1 -180.0(3) . . . . ?
C6 Co1 C2 C1 -135.2(2) . . . . ?
C5 Co1 C2 C1 37.0(2) . . . . ?
C4 Co1 C2 C1 80.4(2) . . . . ?
C3 Co1 C2 C1 117.8(3) . . . . ?
C8 Co1 C2 Pd1 63.3(6) . . . . ?
C9 Co1 C2 Pd1 19.2(3) . . . . ?
C7 Co1 C2 Pd1 -77.3(4) . . . . ?
C6 Co1 C2 Pd1 -32.5(3) . . . . ?
C1 Co1 C2 Pd1 102.7(3) . . . . ?
C5 Co1 C2 Pd1 139.8(3) . . . . ?
C4 Co1 C2 Pd1 -176.8(3) . . . . ?
C3 Co1 C2 Pd1 -139.5(4) . . . . ?
C1 C2 C3 C4 1.2(4) . . . . ?
Pd1 C2 C3 C4 -170.0(3) . . . . ?
Co1 C2 C3 C4 59.2(2) . . . . ?
C1 C2 C3 Co1 -58.0(2) . . . . ?
Pd1 C2 C3 Co1 130.8(4) . . . . ?
C8 Co1 C3 C2 161.2(4) . . . . ?
C9 Co1 C3 C2 -51.9(5) . . . . ?
C7 Co1 C3 C2 -151.2(2) . . . . ?
C6 Co1 C3 C2 -99.2(2) . . . . ?
C1 Co1 C3 C2 38.6(2) . . . . ?
C5 Co1 C3 C2 82.6(2) . . . . ?
C4 Co1 C3 C2 119.7(3) . . . . ?
C8 Co1 C3 C4 41.5(5) . . . . ?
C9 Co1 C3 C4 -171.6(4) . . . . ?
C7 Co1 C3 C4 89.1(3) . . . . ?
C6 Co1 C3 C4 141.1(2) . . . . ?
C1 Co1 C3 C4 -81.1(2) . . . . ?
C5 Co1 C3 C4 -37.1(2) . . . . ?
C2 Co1 C3 C4 -119.7(3) . . . . ?
C2 C3 C4 C5 -0.9(4) . . . . ?
Co1 C3 C4 C5 59.6(2) . . . . ?
C2 C3 C4 Co1 -60.5(2) . . . . ?
C8 Co1 C4 C5 77.7(3) . . . . ?
C9 Co1 C4 C5 49.8(5) . . . . ?
C7 Co1 C4 C5 126.2(2) . . . . ?
C6 Co1 C4 C5 164.9(3) . . . . ?
C1 Co1 C4 C5 -39.2(2) . . . . ?
C3 Co1 C4 C5 -119.8(3) . . . . ?
C2 Co1 C4 C5 -83.2(2) . . . . ?
C8 Co1 C4 C3 -162.5(2) . . . . ?
C9 Co1 C4 C3 169.7(4) . . . . ?
C7 Co1 C4 C3 -114.0(2) . . . . ?
C6 Co1 C4 C3 -75.3(3) . . . . ?
C1 Co1 C4 C3 80.7(2) . . . . ?
C5 Co1 C4 C3 119.8(3) . . . . ?
C2 Co1 C4 C3 36.7(2) . . . . ?
C3 C4 C5 C1 0.2(4) . . . . ?
Co1 C4 C5 C1 60.3(2) . . . . ?
C3 C4 C5 Co1 -60.1(2) . . . . ?
C2 C1 C5 C4 0.6(4) . . . . ?
C10 C1 C5 C4 175.6(4) . . . . ?
Co1 C1 C5 C4 -60.9(2) . . . . ?
C2 C1 C5 Co1 61.5(2) . . . . ?
C10 C1 C5 Co1 -123.5(4) . . . . ?
C8 Co1 C5 C4 -119.6(2) . . . . ?
C9 Co1 C5 C4 -162.7(2) . . . . ?
C7 Co1 C5 C4 -79.1(3) . . . . ?
C6 Co1 C5 C4 -135.5(7) . . . . ?
C1 Co1 C5 C4 116.5(3) . . . . ?
C3 Co1 C5 C4 37.1(2) . . . . ?
C2 Co1 C5 C4 79.5(2) . . . . ?
C8 Co1 C5 C1 123.9(2) . . . . ?
C9 Co1 C5 C1 80.7(3) . . . . ?
C7 Co1 C5 C1 164.4(2) . . . . ?
C6 Co1 C5 C1 108.0(7) . . . . ?
C4 Co1 C5 C1 -116.5(3) . . . . ?
C3 Co1 C5 C1 -79.4(2) . . . . ?
C2 Co1 C5 C1 -37.0(2) . . . . ?
C8 Co1 C6 C21 174.9(5) . . . . ?
C9 Co1 C6 C21 -135.4(5) . . . . ?
C7 Co1 C6 C21 125.7(5) . . . . ?
C1 Co1 C6 C21 -73.8(5) . . . . ?
C5 Co1 C6 C21 -167.8(6) . . . . ?
C4 Co1 C6 C21 68.9(5) . . . . ?
C3 Co1 C6 C21 20.4(5) . . . . ?
C2 Co1 C6 C21 -26.3(5) . . . . ?
C8 Co1 C6 C7 49.2(2) . . . . ?
C9 Co1 C6 C7 98.9(3) . . . . ?
C1 Co1 C6 C7 160.4(2) . . . . ?
C5 Co1 C6 C7 66.4(8) . . . . ?
C4 Co1 C6 C7 -56.8(4) . . . . ?
C3 Co1 C6 C7 -105.3(2) . . . . ?
C2 Co1 C6 C7 -152.1(2) . . . . ?
C8 Co1 C6 C9 -49.7(2) . . . . ?
C7 Co1 C6 C9 -98.9(3) . . . . ?
C1 Co1 C6 C9 61.6(3) . . . . ?
C5 Co1 C6 C9 -32.4(8) . . . . ?
C4 Co1 C6 C9 -155.7(3) . . . . ?
C3 Co1 C6 C9 155.8(2) . . . . ?
C2 Co1 C6 C9 109.1(2) . . . . ?
C21 C6 C7 C8 156.9(4) . . . . ?
C9 C6 C7 C8 -0.1(3) . . . . ?
Co1 C6 C7 C8 -66.09(19) . . . . ?
C21 C6 C7 C43 -10.8(7) . . . . ?
C9 C6 C7 C43 -167.8(4) . . . . ?
Co1 C6 C7 C43 126.2(4) . . . . ?
C21 C6 C7 Co1 -137.0(4) . . . . ?
C9 C6 C7 Co1 66.04(19) . . . . ?
C9 Co1 C7 C8 50.0(2) . . . . ?
C6 Co1 C7 C8 99.7(3) . . . . ?
C1 Co1 C7 C8 -17.5(7) . . . . ?
C5 Co1 C7 C8 -66.1(3) . . . . ?
C4 Co1 C7 C8 -110.1(2) . . . . ?
C3 Co1 C7 C8 -155.1(2) . . . . ?
C2 Co1 C7 C8 162.5(3) . . . . ?
C8 Co1 C7 C6 -99.7(3) . . . . ?
C9 Co1 C7 C6 -49.7(2) . . . . ?
C1 Co1 C7 C6 -117.2(6) . . . . ?
C5 Co1 C7 C6 -165.7(2) . . . . ?
C4 Co1 C7 C6 150.2(2) . . . . ?
C3 Co1 C7 C6 105.2(2) . . . . ?
C2 Co1 C7 C6 62.8(4) . . . . ?
C8 Co1 C7 C43 130.9(4) . . . . ?
C9 Co1 C7 C43 -179.2(4) . . . . ?
C6 Co1 C7 C43 -129.5(4) . . . . ?
C1 Co1 C7 C43 113.4(7) . . . . ?
C5 Co1 C7 C43 64.8(4) . . . . ?
C4 Co1 C7 C43 20.8(4) . . . . ?
C3 Co1 C7 C43 -24.3(4) . . . . ?
C2 Co1 C7 C43 -66.7(5) . . . . ?
C6 C7 C8 C37 -171.7(4) . . . . ?
C43 C7 C8 C37 -4.4(7) . . . . ?
Co1 C7 C8 C37 121.1(4) . . . . ?
C6 C7 C8 C9 0.1(3) . . . . ?
C43 C7 C8 C9 167.4(4) . . . . ?
Co1 C7 C8 C9 -67.14(19) . . . . ?
C6 C7 C8 Co1 67.2(2) . . . . ?
C43 C7 C8 Co1 -125.4(4) . . . . ?
C9 Co1 C8 C7 -98.4(3) . . . . ?
C6 Co1 C8 C7 -48.9(2) . . . . ?
C1 Co1 C8 C7 175.2(2) . . . . ?
C5 Co1 C8 C7 134.7(2) . . . . ?
C4 Co1 C8 C7 93.9(2) . . . . ?
C3 Co1 C8 C7 64.0(5) . . . . ?
C2 Co1 C8 C7 -155.1(4) . . . . ?
C9 Co1 C8 C37 131.8(4) . . . . ?
C7 Co1 C8 C37 -129.9(4) . . . . ?
C6 Co1 C8 C37 -178.7(4) . . . . ?
C1 Co1 C8 C37 45.3(4) . . . . ?
C5 Co1 C8 C37 4.8(4) . . . . ?
C4 Co1 C8 C37 -36.0(4) . . . . ?
C3 Co1 C8 C37 -65.9(6) . . . . ?
C2 Co1 C8 C37 75.0(6) . . . . ?
C7 Co1 C8 C9 98.4(3) . . . . ?
C6 Co1 C8 C9 49.5(2) . . . . ?
C1 Co1 C8 C9 -86.5(2) . . . . ?
C5 Co1 C8 C9 -126.9(2) . . . . ?
C4 Co1 C8 C9 -167.8(2) . . . . ?
C3 Co1 C8 C9 162.3(4) . . . . ?
C2 Co1 C8 C9 -56.8(5) . . . . ?
C7 C8 C9 C6 -0.1(3) . . . . ?
C37 C8 C9 C6 171.5(4) . . . . ?
Co1 C8 C9 C6 -67.6(2) . . . . ?
C7 C8 C9 C31 -169.6(4) . . . . ?
C37 C8 C9 C31 1.9(7) . . . . ?
Co1 C8 C9 C31 122.9(4) . . . . ?
C7 C8 C9 Co1 67.5(2) . . . . ?
C37 C8 C9 Co1 -121.0(4) . . . . ?
C21 C6 C9 C8 -154.3(4) . . . . ?
C7 C6 C9 C8 0.1(3) . . . . ?
Co1 C6 C9 C8 66.49(19) . . . . ?
C21 C6 C9 C31 15.3(7) . . . . ?
C7 C6 C9 C31 169.7(4) . . . . ?
Co1 C6 C9 C31 -123.9(4) . . . . ?
C21 C6 C9 Co1 139.2(4) . . . . ?
C7 C6 C9 Co1 -66.44(19) . . . . ?
C7 Co1 C9 C8 -49.6(2) . . . . ?
C6 Co1 C9 C8 -98.8(3) . . . . ?
C1 Co1 C9 C8 117.0(2) . . . . ?
C5 Co1 C9 C8 73.5(3) . . . . ?
C4 Co1 C9 C8 35.7(6) . . . . ?
C3 Co1 C9 C8 -162.0(4) . . . . ?
C2 Co1 C9 C8 160.8(2) . . . . ?
C8 Co1 C9 C6 98.8(3) . . . . ?
C7 Co1 C9 C6 49.2(2) . . . . ?
C1 Co1 C9 C6 -144.2(2) . . . . ?
C5 Co1 C9 C6 172.3(2) . . . . ?
C4 Co1 C9 C6 134.4(5) . . . . ?
C3 Co1 C9 C6 -63.2(5) . . . . ?
C2 Co1 C9 C6 -100.4(2) . . . . ?
C8 Co1 C9 C31 -130.3(4) . . . . ?
C7 Co1 C9 C31 -179.9(4) . . . . ?
C6 Co1 C9 C31 130.9(4) . . . . ?
C1 Co1 C9 C31 -13.3(4) . . . . ?
C5 Co1 C9 C31 -56.8(4) . . . . ?
C4 Co1 C9 C31 -94.7(6) . . . . ?
C3 Co1 C9 C31 67.7(6) . . . . ?
C2 Co1 C9 C31 30.5(4) . . . . ?
C12 N1 C10 O1 -4.1(5) . . . . ?
Pd1 N1 C10 O1 175.9(2) . . . . ?
C12 N1 C10 C1 175.6(3) . . . . ?
Pd1 N1 C10 C1 -4.4(4) . . . . ?
C11 O1 C10 N1 -6.7(5) . . . . ?
C11 O1 C10 C1 173.7(4) . . . . ?
C5 C1 C10 N1 -169.7(4) . . . . ?
C2 C1 C10 N1 5.2(5) . . . . ?
Co1 C1 C10 N1 90.0(4) . . . . ?
C5 C1 C10 O1 10.0(7) . . . . ?
C2 C1 C10 O1 -175.1(3) . . . . ?
Co1 C1 C10 O1 -90.3(4) . . . . ?
C10 O1 C11 C12 13.8(4) . . . . ?
C10 N1 C12 C11 12.2(4) . . . . ?
Pd1 N1 C12 C11 -167.9(3) . . . . ?
C10 N1 C12 C13 -110.1(4) . . . . ?
Pd1 N1 C12 C13 69.8(5) . . . . ?
O1 C11 C12 N1 -15.4(4) . . . . ?
O1 C11 C12 C13 103.7(4) . . . . ?
N1 C12 C13 C15 -170.5(4) . . . . ?
C11 C12 C13 C15 75.7(5) . . . . ?
N1 C12 C13 C14 63.3(5) . . . . ?
C11 C12 C13 C14 -50.6(5) . . . . ?
C23 Co2 C16 C20 -168.3(3) . . . . ?
C22 Co2 C16 C20 146.3(2) . . . . ?
C24 Co2 C16 C20 54.2(7) . . . . ?
C21 Co2 C16 C20 95.0(3) . . . . ?
C17 Co2 C16 C20 -118.8(4) . . . . ?
C18 Co2 C16 C20 -80.8(3) . . . . ?
C19 Co2 C16 C20 -37.4(2) . . . . ?
C23 Co2 C16 C17 -49.6(4) . . . . ?
C22 Co2 C16 C17 -94.9(3) . . . . ?
C24 Co2 C16 C17 173.0(6) . . . . ?
C21 Co2 C16 C17 -146.2(3) . . . . ?
C18 Co2 C16 C17 37.9(3) . . . . ?
C19 Co2 C16 C17 81.3(3) . . . . ?
C20 Co2 C16 C17 118.8(4) . . . . ?
C23 Co2 C16 C25 68.3(5) . . . . ?
C22 Co2 C16 C25 23.0(4) . . . . ?
C24 Co2 C16 C25 -69.1(8) . . . . ?
C21 Co2 C16 C25 -28.3(4) . . . . ?
C17 Co2 C16 C25 117.9(5) . . . . ?
C18 Co2 C16 C25 155.8(4) . . . . ?
C19 Co2 C16 C25 -160.8(4) . . . . ?
C20 Co2 C16 C25 -123.3(5) . . . . ?
C20 C16 C17 C18 -1.1(4) . . . . ?
C25 C16 C17 C18 175.6(3) . . . . ?
Co2 C16 C17 C18 -61.2(3) . . . . ?
C20 C16 C17 Co2 60.1(3) . . . . ?
C25 C16 C17 Co2 -123.2(4) . . . . ?
C23 Co2 C17 C18 -87.8(3) . . . . ?
C22 Co2 C17 C18 -136.2(3) . . . . ?
C24 Co2 C17 C18 -58.2(5) . . . . ?
C21 Co2 C17 C18 -168.5(3) . . . . ?
C16 Co2 C17 C18 117.6(4) . . . . ?
C19 Co2 C17 C18 36.8(3) . . . . ?
C20 Co2 C17 C18 79.9(3) . . . . ?
C23 Co2 C17 C16 154.6(2) . . . . ?
C22 Co2 C17 C16 106.2(3) . . . . ?
C24 Co2 C17 C16 -175.7(4) . . . . ?
C21 Co2 C17 C16 73.9(4) . . . . ?
C18 Co2 C17 C16 -117.6(4) . . . . ?
C19 Co2 C17 C16 -80.8(3) . . . . ?
C20 Co2 C17 C16 -37.7(2) . . . . ?
C16 C17 C18 C19 1.1(5) . . . . ?
Co2 C17 C18 C19 -59.9(3) . . . . ?
C16 C17 C18 Co2 61.0(3) . . . . ?
C23 Co2 C18 C17 108.9(3) . . . . ?
C22 Co2 C18 C17 68.9(3) . . . . ?
C24 Co2 C18 C17 154.0(3) . . . . ?
C21 Co2 C18 C17 155.9(7) . . . . ?
C16 Co2 C18 C17 -38.8(3) . . . . ?
C19 Co2 C18 C17 -120.3(4) . . . . ?
C20 Co2 C18 C17 -82.8(3) . . . . ?
C23 Co2 C18 C19 -130.8(3) . . . . ?
C22 Co2 C18 C19 -170.8(3) . . . . ?
C24 Co2 C18 C19 -85.7(3) . . . . ?
C21 Co2 C18 C19 -83.7(8) . . . . ?
C17 Co2 C18 C19 120.3(4) . . . . ?
C16 Co2 C18 C19 81.5(3) . . . . ?
C20 Co2 C18 C19 37.6(2) . . . . ?
C17 C18 C19 C20 -0.7(5) . . . . ?
Co2 C18 C19 C20 -60.0(3) . . . . ?
C17 C18 C19 Co2 59.3(3) . . . . ?
C23 Co2 C19 C18 69.2(4) . . . . ?
C24 Co2 C19 C18 115.6(3) . . . . ?
C21 Co2 C19 C18 160.5(3) . . . . ?
C17 Co2 C19 C18 -36.6(3) . . . . ?
C16 Co2 C19 C18 -80.8(3) . . . . ?
C20 Co2 C19 C18 -118.7(4) . . . . ?
C23 Co2 C19 C20 -172.0(3) . . . . ?
C24 Co2 C19 C20 -125.6(3) . . . . ?
C21 Co2 C19 C20 -80.7(4) . . . . ?
C17 Co2 C19 C20 82.1(3) . . . . ?
C18 Co2 C19 C20 118.7(4) . . . . ?
C16 Co2 C19 C20 37.9(3) . . . . ?
C18 C19 C20 C16 0.0(4) . . . . ?
Co2 C19 C20 C16 -59.4(3) . . . . ?
C18 C19 C20 Co2 59.4(3) . . . . ?
C17 C16 C20 C19 0.7(4) . . . . ?
C25 C16 C20 C19 -175.9(4) . . . . ?
Co2 C16 C20 C19 59.9(3) . . . . ?
C17 C16 C20 Co2 -59.2(3) . . . . ?
C25 C16 C20 Co2 124.2(4) . . . . ?
C23 Co2 C20 C19 31.3(9) . . . . ?
C22 Co2 C20 C19 178.3(4) . . . . ?
C24 Co2 C20 C19 77.3(3) . . . . ?
C21 Co2 C20 C19 129.4(3) . . . . ?
C17 Co2 C20 C19 -80.7(3) . . . . ?
C18 Co2 C20 C19 -37.6(3) . . . . ?
C16 Co2 C20 C19 -118.8(4) . . . . ?
C23 Co2 C20 C16 150.1(8) . . . . ?
C22 Co2 C20 C16 -62.9(4) . . . . ?
C24 Co2 C20 C16 -164.0(2) . . . . ?
C21 Co2 C20 C16 -111.8(2) . . . . ?
C17 Co2 C20 C16 38.0(2) . . . . ?
C18 Co2 C20 C16 81.1(3) . . . . ?
C19 Co2 C20 C16 118.8(4) . . . . ?
C7 C6 C21 C22 37.1(7) . . . . ?
C9 C6 C21 C22 -177.0(4) . . . . ?
Co1 C6 C21 C22 -65.6(6) . . . . ?
C7 C6 C21 C24 -108.7(5) . . . . ?
C9 C6 C21 C24 37.2(7) . . . . ?
Co1 C6 C21 C24 148.6(4) . . . . ?
C7 C6 C21 Co2 145.6(4) . . . . ?
C9 C6 C21 Co2 -68.6(7) . . . . ?
Co1 C6 C21 Co2 42.8(7) . . . . ?
C23 Co2 C21 C6 177.6(5) . . . . ?
C22 Co2 C21 C6 -132.4(5) . . . . ?
C24 Co2 C21 C6 128.7(5) . . . . ?
C17 Co2 C21 C6 -87.3(6) . . . . ?
C18 Co2 C21 C6 126.3(8) . . . . ?
C16 Co2 C21 C6 -36.8(5) . . . . ?
C19 Co2 C21 C6 57.3(5) . . . . ?
C20 Co2 C21 C6 10.8(5) . . . . ?
C23 Co2 C21 C22 -50.0(2) . . . . ?
C24 Co2 C21 C22 -98.9(3) . . . . ?
C17 Co2 C21 C22 45.1(4) . . . . ?
C18 Co2 C21 C22 -101.3(8) . . . . ?
C16 Co2 C21 C22 95.5(2) . . . . ?
C19 Co2 C21 C22 -170.4(2) . . . . ?
C20 Co2 C21 C22 143.2(2) . . . . ?
C23 Co2 C21 C24 48.9(2) . . . . ?
C22 Co2 C21 C24 98.9(3) . . . . ?
C17 Co2 C21 C24 144.0(3) . . . . ?
C18 Co2 C21 C24 -2.4(9) . . . . ?
C16 Co2 C21 C24 -165.6(2) . . . . ?
C19 Co2 C21 C24 -71.5(3) . . . . ?
C20 Co2 C21 C24 -117.9(2) . . . . ?
C6 C21 C22 C23 -155.0(4) . . . . ?
C24 C21 C22 C23 0.0(3) . . . . ?
Co2 C21 C22 C23 66.4(2) . . . . ?
C6 C21 C22 C49 19.5(7) . . . . ?
C24 C21 C22 C49 174.5(4) . . . . ?
Co2 C21 C22 C49 -119.1(4) . . . . ?
C6 C21 C22 Co2 138.5(4) . . . . ?
C24 C21 C22 Co2 -66.4(2) . . . . ?
C24 Co2 C22 C23 -48.6(2) . . . . ?
C21 Co2 C22 C23 -98.3(3) . . . . ?
C17 Co2 C22 C23 103.1(3) . . . . ?
C18 Co2 C22 C23 62.3(4) . . . . ?
C16 Co2 C22 C23 148.5(2) . . . . ?
C20 Co2 C22 C23 -170.6(3) . . . . ?
C23 Co2 C22 C49 -130.2(4) . . . . ?
C24 Co2 C22 C49 -178.9(4) . . . . ?
C21 Co2 C22 C49 131.4(4) . . . . ?
C17 Co2 C22 C49 -27.2(4) . . . . ?
C18 Co2 C22 C49 -67.9(4) . . . . ?
C16 Co2 C22 C49 18.2(4) . . . . ?
C20 Co2 C22 C49 59.1(5) . . . . ?
C23 Co2 C22 C21 98.3(3) . . . . ?
C24 Co2 C22 C21 49.7(2) . . . . ?
C17 Co2 C22 C21 -158.6(2) . . . . ?
C18 Co2 C22 C21 160.6(2) . . . . ?
C16 Co2 C22 C21 -113.2(2) . . . . ?
C20 Co2 C22 C21 -72.3(4) . . . . ?
C49 C22 C23 C24 -174.5(4) . . . . ?
C21 C22 C23 C24 0.0(3) . . . . ?
Co2 C22 C23 C24 67.7(2) . . . . ?
C49 C22 C23 C55 -6.1(8) . . . . ?
C21 C22 C23 C55 168.4(4) . . . . ?
Co2 C22 C23 C55 -124.0(5) . . . . ?
C49 C22 C23 Co2 117.8(4) . . . . ?
C21 C22 C23 Co2 -67.7(2) . . . . ?
C22 Co2 C23 C24 -99.7(3) . . . . ?
C21 Co2 C23 C24 -49.8(2) . . . . ?
C17 Co2 C23 C24 161.6(2) . . . . ?
C18 Co2 C23 C24 119.4(3) . . . . ?
C16 Co2 C23 C24 -164.9(3) . . . . ?
C19 Co2 C23 C24 80.3(3) . . . . ?
C20 Co2 C23 C24 54.6(9) . . . . ?
C24 Co2 C23 C22 99.7(3) . . . . ?
C21 Co2 C23 C22 50.0(2) . . . . ?
C17 Co2 C23 C22 -98.6(3) . . . . ?
C18 Co2 C23 C22 -140.9(3) . . . . ?
C16 Co2 C23 C22 -65.1(4) . . . . ?
C19 Co2 C23 C22 180.0(3) . . . . ?
C20 Co2 C23 C22 154.4(8) . . . . ?
C22 Co2 C23 C55 133.3(5) . . . . ?
C24 Co2 C23 C55 -127.0(5) . . . . ?
C21 Co2 C23 C55 -176.7(5) . . . . ?
C17 Co2 C23 C55 34.7(5) . . . . ?
C18 Co2 C23 C55 -7.6(5) . . . . ?
C16 Co2 C23 C55 68.2(5) . . . . ?
C19 Co2 C23 C55 -46.7(5) . . . . ?
C20 Co2 C23 C55 -72.3(10) . . . . ?
C22 C23 C24 C61 171.4(4) . . . . ?
C55 C23 C24 C61 2.0(7) . . . . ?
Co2 C23 C24 C61 -122.0(4) . . . . ?
C22 C23 C24 C21 0.0(3) . . . . ?
C55 C23 C24 C21 -169.4(4) . . . . ?
Co2 C23 C24 C21 66.6(2) . . . . ?
C22 C23 C24 Co2 -66.6(2) . . . . ?
C55 C23 C24 Co2 124.0(4) . . . . ?
C6 C21 C24 C23 156.2(4) . . . . ?
C22 C21 C24 C23 0.0(3) . . . . ?
Co2 C21 C24 C23 -65.7(2) . . . . ?
C6 C21 C24 C61 -14.5(7) . . . . ?
C22 C21 C24 C61 -170.7(5) . . . . ?
Co2 C21 C24 C61 123.6(5) . . . . ?
C6 C21 C24 Co2 -138.1(4) . . . . ?
C22 C21 C24 Co2 65.7(2) . . . . ?
C22 Co2 C24 C23 49.6(2) . . . . ?
C21 Co2 C24 C23 99.3(3) . . . . ?
C17 Co2 C24 C23 -40.9(5) . . . . ?
C18 Co2 C24 C23 -81.3(3) . . . . ?
C16 Co2 C24 C23 149.7(6) . . . . ?
C19 Co2 C24 C23 -125.0(2) . . . . ?
C20 Co2 C24 C23 -167.4(2) . . . . ?
C23 Co2 C24 C61 127.1(4) . . . . ?
C22 Co2 C24 C61 176.7(4) . . . . ?
C21 Co2 C24 C61 -133.5(5) . . . . ?
C17 Co2 C24 C61 86.2(6) . . . . ?
C18 Co2 C24 C61 45.8(4) . . . . ?
C16 Co2 C24 C61 -83.2(7) . . . . ?
C19 Co2 C24 C61 2.1(4) . . . . ?
C20 Co2 C24 C61 -40.3(4) . . . . ?
C23 Co2 C24 C21 -99.3(3) . . . . ?
C22 Co2 C24 C21 -49.7(2) . . . . ?
C17 Co2 C24 C21 -140.2(4) . . . . ?
C18 Co2 C24 C21 179.3(2) . . . . ?
C16 Co2 C24 C21 50.4(7) . . . . ?
C19 Co2 C24 C21 135.6(2) . . . . ?
C20 Co2 C24 C21 93.2(3) . . . . ?
C27 N2 C25 O2 -6.8(4) . . . . ?
Pd1 N2 C25 O2 174.5(2) . . . . ?
C27 N2 C25 C16 169.1(4) . . . . ?
Pd1 N2 C25 C16 -9.6(6) . . . . ?
C26 O2 C25 N2 -7.6(4) . . . . ?
C26 O2 C25 C16 175.9(3) . . . . ?
C20 C16 C25 N2 -1.9(6) . . . . ?
C17 C16 C25 N2 -177.9(4) . . . . ?
Co2 C16 C25 N2 92.5(5) . . . . ?
C20 C16 C25 O2 174.1(3) . . . . ?
C17 C16 C25 O2 -2.0(5) . . . . ?
Co2 C16 C25 O2 -91.5(4) . . . . ?
C25 O2 C26 C27 17.7(4) . . . . ?
C25 N2 C27 C26 17.1(4) . . . . ?
Pd1 N2 C27 C26 -164.0(2) . . . . ?
C25 N2 C27 C28 -105.4(4) . . . . ?
Pd1 N2 C27 C28 73.4(4) . . . . ?
O2 C26 C27 N2 -20.6(4) . . . . ?
O2 C26 C27 C28 99.2(4) . . . . ?
N2 C27 C28 C29 -175.4(3) . . . . ?
C26 C27 C28 C29 69.8(4) . . . . ?
N2 C27 C28 C30 58.6(4) . . . . ?
C26 C27 C28 C30 -56.1(5) . . . . ?
C8 C9 C31 C32 -155.0(4) . . . . ?
C6 C9 C31 C32 39.7(6) . . . . ?
Co1 C9 C31 C32 -58.5(5) . . . . ?
C8 C9 C31 C36 29.4(6) . . . . ?
C6 C9 C31 C36 -135.9(4) . . . . ?
Co1 C9 C31 C36 125.9(4) . . . . ?
C36 C31 C32 C33 -0.4(6) . . . . ?
C9 C31 C32 C33 -176.0(4) . . . . ?
C31 C32 C33 C34 0.1(7) . . . . ?
C32 C33 C34 C35 0.5(7) . . . . ?
C33 C34 C35 C36 -0.9(6) . . . . ?
C34 C35 C36 C31 0.6(6) . . . . ?
C32 C31 C36 C35 0.0(6) . . . . ?
C9 C31 C36 C35 175.7(4) . . . . ?
C7 C8 C37 C42 20.3(6) . . . . ?
C9 C8 C37 C42 -147.9(4) . . . . ?
Co1 C8 C37 C42 115.8(4) . . . . ?
C7 C8 C37 C38 -159.1(4) . . . . ?
C9 C8 C37 C38 32.7(6) . . . . ?
Co1 C8 C37 C38 -63.6(5) . . . . ?
C42 C37 C38 C39 0.7(5) . . . . ?
C8 C37 C38 C39 -180.0(3) . . . . ?
C37 C38 C39 C40 -2.0(6) . . . . ?
C38 C39 C40 C41 1.7(6) . . . . ?
C39 C40 C41 C42 0.0(6) . . . . ?
C40 C41 C42 C37 -1.4(6) . . . . ?
C38 C37 C42 C41 1.0(6) . . . . ?
C8 C37 C42 C41 -178.4(4) . . . . ?
C8 C7 C43 C48 -126.2(5) . . . . ?
C6 C7 C43 C48 36.3(6) . . . . ?
Co1 C7 C43 C48 135.2(4) . . . . ?
C8 C7 C43 C44 53.6(6) . . . . ?
C6 C7 C43 C44 -143.8(4) . . . . ?
Co1 C7 C43 C44 -44.9(5) . . . . ?
C48 C43 C44 C45 -1.1(6) . . . . ?
C7 C43 C44 C45 179.0(4) . . . . ?
C43 C44 C45 C46 -1.5(7) . . . . ?
C44 C45 C46 C47 2.4(8) . . . . ?
C45 C46 C47 C48 -0.6(9) . . . . ?
C44 C43 C48 C47 2.9(7) . . . . ?
C7 C43 C48 C47 -177.2(4) . . . . ?
C46 C47 C48 C43 -2.1(8) . . . . ?
C23 C22 C49 C54 6.5(7) . . . . ?
C21 C22 C49 C54 -165.7(4) . . . . ?
Co2 C22 C49 C54 99.2(4) . . . . ?
C23 C22 C49 C50 -176.5(4) . . . . ?
C21 C22 C49 C50 11.3(7) . . . . ?
Co2 C22 C49 C50 -83.8(4) . . . . ?
C54 C49 C50 C51 -0.6(6) . . . . ?
C22 C49 C50 C51 -177.7(4) . . . . ?
C49 C50 C51 C52 -0.3(7) . . . . ?
C50 C51 C52 C53 1.0(7) . . . . ?
C51 C52 C53 C54 -0.8(8) . . . . ?
C52 C53 C54 C49 -0.1(8) . . . . ?
C50 C49 C54 C53 0.7(7) . . . . ?
C22 C49 C54 C53 177.8(4) . . . . ?
C24 C23 C55 C56 -138.3(5) . . . . ?
C22 C23 C55 C56 57.2(7) . . . . ?
Co2 C23 C55 C56 -42.2(6) . . . . ?
C24 C23 C55 C60 42.8(6) . . . . ?
C22 C23 C55 C60 -121.7(5) . . . . ?
Co2 C23 C55 C60 138.9(4) . . . . ?
C60 C55 C56 C57 -1.9(7) . . . . ?
C23 C55 C56 C57 179.2(4) . . . . ?
C55 C56 C57 C58 2.2(8) . . . . ?
C56 C57 C58 C59 -0.9(8) . . . . ?
C57 C58 C59 C60 -0.8(8) . . . . ?
C58 C59 C60 C55 1.1(7) . . . . ?
C56 C55 C60 C59 0.2(7) . . . . ?
C23 C55 C60 C59 179.2(4) . . . . ?
C23 C24 C61 C66 -139.5(4) . . . . ?
C21 C24 C61 C66 27.8(7) . . . . ?
Co2 C24 C61 C66 127.0(4) . . . . ?
C23 C24 C61 C62 36.8(6) . . . . ?
C21 C24 C61 C62 -155.8(4) . . . . ?
Co2 C24 C61 C62 -56.7(5) . . . . ?
C66 C61 C62 C63 -0.7(6) . . . . ?
C24 C61 C62 C63 -177.2(4) . . . . ?
C61 C62 C63 C64 -0.7(7) . . . . ?
C62 C63 C64 C65 1.0(7) . . . . ?
C63 C64 C65 C66 0.3(7) . . . . ?
C62 C61 C66 C65 2.0(6) . . . . ?
C24 C61 C66 C65 178.3(4) . . . . ?
C64 C65 C66 C61 -1.7(7) . . . . ?
Pd1 O3 C67 O4 -0.2(5) . . . . ?
Pd1 O3 C67 C68 179.3(3) . . . . ?
