#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/24/1512440.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1512440
loop_
_publ_author_name
'Yue Zhao'
'Ling-Ling Zhai'
'Gao-Chao Lv'
'Xin Zhou'
'Wei-Yin Sun'
_publ_section_title
;
 Silver(I) complexes with oxazoline-containing bidentate ligands:
 Syntheses, structures and properties
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              38
_journal_page_last               45
_journal_paper_doi               10.1016/j.ica.2012.06.035
_journal_volume                  392
_journal_year                    2012
_chemical_formula_moiety         'C28 H30 Ag2 N6 O4, 2(F6 P)'
_chemical_formula_sum            'C28 H30 Ag2 F12 N6 O4 P2'
_chemical_formula_weight         1020.26
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.655(2)
_cell_angle_beta                 92.791(2)
_cell_angle_gamma                107.9320(10)
_cell_formula_units_Z            2
_cell_length_a                   9.1724(10)
_cell_length_b                   14.1347(16)
_cell_length_c                   15.6201(18)
_cell_measurement_reflns_used    2681
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.61
_cell_measurement_theta_min      2.36
_cell_volume                     1846.4(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0518
_diffrn_reflns_av_sigmaI/netI    0.0746
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9424
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    1.251
_exptl_absorpt_correction_T_max  0.8062
_exptl_absorpt_correction_T_min  0.7792
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.835
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1008
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.005
_refine_diff_density_min         -0.682
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.933
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     489
_refine_ls_number_reflns         6399
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      0.933
_refine_ls_R_factor_all          0.0695
_refine_ls_R_factor_gt           0.0498
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0673P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1250
_refine_ls_wR_factor_ref         0.1353
_reflns_number_gt                4304
_reflns_number_total             6399
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2012-392-38-45-4.cif
_cod_data_source_block           4
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1512440
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.83869(6) 0.69289(3) 0.43446(3) 0.05573(18) Uani 1 1 d .
Ag2 Ag 1.08823(6) 0.78268(3) 1.09503(3) 0.05715(18) Uani 1 1 d .
C1 C 0.8265(6) 0.8471(4) 0.8541(3) 0.0409(13) Uani 1 1 d .
H1 H 0.7258 0.8021 0.8338 0.049 Uiso 1 1 calc R
C2 C 0.9352(7) 0.8141(4) 0.8939(4) 0.0434(13) Uani 1 1 d .
C3 C 1.0851(6) 0.8803(4) 0.9210(4) 0.0468(14) Uani 1 1 d .
H3 H 1.1577 0.8588 0.9472 0.056 Uiso 1 1 calc R
C4 C 1.1280(6) 0.9777(4) 0.9095(4) 0.0437(13) Uani 1 1 d .
H4 H 1.2300 1.0214 0.9271 0.052 Uiso 1 1 calc R
C5 C 1.0211(6) 1.0111(4) 0.8722(4) 0.0455(14) Uani 1 1 d .
H5 H 1.0509 1.0774 0.8650 0.055 Uiso 1 1 calc R
C6 C 0.8691(6) 0.9461(4) 0.8451(3) 0.0415(13) Uani 1 1 d .
C7 C 0.7513(7) 0.9806(4) 0.8068(4) 0.0468(14) Uani 1 1 d .
C8 C 0.6096(8) 1.0700(5) 0.7709(5) 0.073(2) Uani 1 1 d .
H8A H 0.6324 1.1036 0.7238 0.087 Uiso 1 1 calc R
H8B H 0.5508 1.1036 0.8105 0.087 Uiso 1 1 calc R
C9 C 0.5217(8) 0.9553(5) 0.7322(5) 0.082(2) Uani 1 1 d .
H9A H 0.4274 0.9351 0.7585 0.098 Uiso 1 1 calc R
H9B H 0.4957 0.9376 0.6679 0.098 Uiso 1 1 calc R
C10 C 0.8835(6) 0.7117(4) 0.9091(4) 0.0421(13) Uani 1 1 d .
C11 C 0.7321(7) 0.5463(4) 0.8811(5) 0.0610(17) Uani 1 1 d .
H11A H 0.7316 0.4825 0.8391 0.073 Uiso 1 1 calc R
H11B H 0.6291 0.5374 0.8975 0.073 Uiso 1 1 calc R
C12 C 0.8484(7) 0.5756(4) 0.9616(4) 0.0580(16) Uani 1 1 d .
H12A H 0.7986 0.5606 1.0123 0.070 Uiso 1 1 calc R
H12B H 0.9225 0.5391 0.9501 0.070 Uiso 1 1 calc R
C13 C 1.0267(8) 0.6022(5) 1.2192(4) 0.0611(17) Uani 1 1 d U
C14 C 0.9917(9) 0.5272(5) 1.2687(5) 0.078(2) Uani 1 1 d .
H14A H 0.8938 0.5221 1.2897 0.118 Uiso 1 1 calc R
H14B H 1.0710 0.5482 1.3187 0.118 Uiso 1 1 calc R
H14C H 0.9870 0.4609 1.2307 0.118 Uiso 1 1 calc R
C15 C 1.1035(6) 1.0084(4) 0.6655(3) 0.0413(13) Uani 1 1 d .
H15 H 1.1936 1.0099 0.6967 0.050 Uiso 1 1 calc R
C16 C 0.9927(6) 0.9138(4) 0.6203(3) 0.0408(13) Uani 1 1 d .
C17 C 0.8560(6) 0.9125(4) 0.5765(4) 0.0454(14) Uani 1 1 d .
H17 H 0.7800 0.8495 0.5480 0.054 Uiso 1 1 calc R
C18 C 0.8317(7) 1.0040(4) 0.5747(4) 0.0523(15) Uani 1 1 d .
H18 H 0.7408 1.0023 0.5443 0.063 Uiso 1 1 calc R
C19 C 0.9438(6) 1.0981(4) 0.6185(4) 0.0475(14) Uani 1 1 d .
H19 H 0.9279 1.1596 0.6173 0.057 Uiso 1 1 calc R
C20 C 1.0801(6) 1.1009(4) 0.6643(3) 0.0429(13) Uani 1 1 d .
C21 C 1.1978(7) 1.1999(4) 0.7113(4) 0.0473(14) Uani 1 1 d .
C22 C 1.3515(8) 1.3634(5) 0.7595(4) 0.0624(17) Uani 1 1 d .
H22A H 1.3154 1.4176 0.7931 0.075 Uiso 1 1 calc R
H22B H 1.4401 1.3946 0.7324 0.075 Uiso 1 1 calc R
C23 C 1.3922(9) 1.3033(5) 0.8188(5) 0.081(2) Uani 1 1 d .
H23A H 1.4969 1.3021 0.8151 0.097 Uiso 1 1 calc R
H23B H 1.3831 1.3335 0.8806 0.097 Uiso 1 1 calc R
C24 C 1.0173(6) 0.8175(4) 0.6228(4) 0.0439(13) Uani 1 1 d .
C25 C 1.1278(9) 0.7210(5) 0.6797(5) 0.071(2) Uani 1 1 d .
H25A H 1.1023 0.6970 0.7318 0.086 Uiso 1 1 calc R
H25B H 1.2312 0.7209 0.6695 0.086 Uiso 1 1 calc R
C26 C 1.0117(8) 0.6539(4) 0.5989(4) 0.0576(16) Uani 1 1 d .
H26A H 1.0605 0.6188 0.5534 0.069 Uiso 1 1 calc R
H26B H 0.9286 0.6024 0.6149 0.069 Uiso 1 1 calc R
C27 C 0.4305(9) 0.3705(7) 0.3567(6) 0.100(3) Uani 1 1 d .
H27A H 0.3860 0.3776 0.3027 0.150 Uiso 1 1 calc R
H27B H 0.3656 0.3802 0.4023 0.150 Uiso 1 1 calc R
H27C H 0.4387 0.3025 0.3457 0.150 Uiso 1 1 calc R
C28 C 0.5785(10) 0.4454(5) 0.3850(5) 0.0677(19) Uani 1 1 d .
F1 F 0.4315(7) 0.6533(6) 0.8419(4) 0.173(3) Uani 1 1 d .
F2 F 0.3853(10) 0.5892(5) 0.9470(6) 0.214(4) Uani 1 1 d .
F3 F 0.5665(5) 0.7327(4) 0.9723(3) 0.1151(17) Uani 1 1 d .
F4 F 0.3492(7) 0.7227(7) 1.0297(4) 0.203(4) Uani 1 1 d .
F5 F 0.4041(11) 0.7948(6) 0.9194(8) 0.260(5) Uani 1 1 d .
F6 F 0.2152(6) 0.6585(7) 0.8986(4) 0.196(4) Uani 1 1 d .
F7 F 0.3577(9) 0.6982(9) 0.3375(4) 0.245(5) Uani 1 1 d .
F8 F 0.2980(13) 0.6301(6) 0.4388(8) 0.274(6) Uani 1 1 d .
F9 F 0.5305(8) 0.7128(10) 0.4459(5) 0.261(5) Uani 1 1 d .
F10 F 0.4698(18) 0.8367(7) 0.4379(10) 0.413(11) Uani 1 1 d .
F11 F 0.2282(10) 0.7477(8) 0.4267(7) 0.255(5) Uani 1 1 d .
F12 F 0.4061(11) 0.7663(8) 0.5392(4) 0.222(4) Uani 1 1 d .
N1 N 0.9240(5) 0.6881(3) 0.9776(3) 0.0472(11) Uani 1 1 d .
N2 N 0.7524(5) 1.0733(3) 0.8201(3) 0.0508(12) Uani 1 1 d .
N3 N 0.9528(5) 0.7277(3) 0.5672(3) 0.0460(11) Uani 1 1 d .
N4 N 1.2273(5) 1.2849(3) 0.6911(3) 0.0474(11) Uani 1 1 d .
N5 N 1.0504(8) 0.6594(5) 1.1790(4) 0.0843(19) Uani 1 1 d .
N6 N 0.6980(9) 0.5040(5) 0.4049(5) 0.101(2) Uani 1 1 d .
O1 O 0.7834(5) 0.6340(3) 0.8426(3) 0.0586(11) Uani 1 1 d .
O2 O 0.6280(5) 0.9056(3) 0.7554(3) 0.0635(12) Uani 1 1 d .
O3 O 1.2803(5) 1.1993(3) 0.7843(3) 0.0654(12) Uani 1 1 d .
O4 O 1.1169(5) 0.8237(3) 0.6915(3) 0.0572(11) Uani 1 1 d .
P1 P 0.3894(2) 0.69171(15) 0.93522(13) 0.0663(5) Uani 1 1 d .
P2 P 0.3812(2) 0.73561(19) 0.43807(15) 0.0785(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N4 159.43(17) . 2_776
N3 Ag1 N6 100.3(2) . .
N4 Ag1 N6 100.2(2) 2_776 .
N2 Ag2 N1 153.96(17) 2_777 .
N2 Ag2 N5 106.7(2) 2_777 .
N1 Ag2 N5 99.0(2) . .
C6 C1 C2 119.9(5) . .
C6 C1 H1 120.0 . .
C2 C1 H1 120.0 . .
C3 C2 C1 119.4(5) . .
C3 C2 C10 121.9(5) . .
C1 C2 C10 118.7(5) . .
C4 C3 C2 120.5(5) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C3 C4 C5 120.4(5) . .
C3 C4 H4 119.8 . .
C5 C4 H4 119.8 . .
C4 C5 C6 120.2(5) . .
C4 C5 H5 119.9 . .
C6 C5 H5 119.9 . .
C1 C6 C5 119.6(5) . .
C1 C6 C7 119.0(5) . .
C5 C6 C7 121.4(5) . .
N2 C7 O2 117.1(5) . .
N2 C7 C6 126.8(5) . .
O2 C7 C6 116.0(5) . .
N2 C8 C9 104.1(5) . .
N2 C8 H8A 110.9 . .
C9 C8 H8A 110.9 . .
N2 C8 H8B 110.9 . .
C9 C8 H8B 110.9 . .
H8A C8 H8B 109.0 . .
O2 C9 C8 104.0(5) . .
O2 C9 H9A 110.9 . .
C8 C9 H9A 110.9 . .
O2 C9 H9B 110.9 . .
C8 C9 H9B 110.9 . .
H9A C9 H9B 109.0 . .
N1 C10 O1 116.9(5) . .
N1 C10 C2 126.7(5) . .
O1 C10 C2 116.4(5) . .
O1 C11 C12 104.1(5) . .
O1 C11 H11A 110.9 . .
C12 C11 H11A 110.9 . .
O1 C11 H11B 110.9 . .
C12 C11 H11B 110.9 . .
H11A C11 H11B 109.0 . .
N1 C12 C11 103.5(5) . .
N1 C12 H12A 111.1 . .
C11 C12 H12A 111.1 . .
N1 C12 H12B 111.1 . .
C11 C12 H12B 111.1 . .
H12A C12 H12B 109.0 . .
N5 C13 C14 178.1(8) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C20 120.3(5) . .
C16 C15 H15 119.9 . .
C20 C15 H15 119.9 . .
C15 C16 C17 119.3(5) . .
C15 C16 C24 119.9(5) . .
C17 C16 C24 120.7(5) . .
C18 C17 C16 120.9(5) . .
C18 C17 H17 119.6 . .
C16 C17 H17 119.6 . .
C17 C18 C19 119.6(5) . .
C17 C18 H18 120.2 . .
C19 C18 H18 120.2 . .
C18 C19 C20 120.4(5) . .
C18 C19 H19 119.8 . .
C20 C19 H19 119.8 . .
C15 C20 C19 119.5(5) . .
C15 C20 C21 119.9(5) . .
C19 C20 C21 120.6(5) . .
N4 C21 O3 117.8(5) . .
N4 C21 C20 127.1(5) . .
O3 C21 C20 115.1(5) . .
N4 C22 C23 104.1(5) . .
N4 C22 H22A 110.9 . .
C23 C22 H22A 110.9 . .
N4 C22 H22B 110.9 . .
C23 C22 H22B 110.9 . .
H22A C22 H22B 109.0 . .
O3 C23 C22 104.5(5) . .
O3 C23 H23A 110.9 . .
C22 C23 H23A 110.9 . .
O3 C23 H23B 110.9 . .
C22 C23 H23B 110.9 . .
H23A C23 H23B 108.9 . .
N3 C24 O4 116.9(5) . .
N3 C24 C16 127.0(5) . .
O4 C24 C16 116.1(5) . .
O4 C25 C26 104.5(5) . .
O4 C25 H25A 110.8 . .
C26 C25 H25A 110.8 . .
O4 C25 H25B 110.8 . .
C26 C25 H25B 110.8 . .
H25A C25 H25B 108.9 . .
N3 C26 C25 104.2(5) . .
N3 C26 H26A 110.9 . .
C25 C26 H26A 110.9 . .
N3 C26 H26B 110.9 . .
C25 C26 H26B 110.9 . .
H26A C26 H26B 108.9 . .
C28 C27 H27A 109.5 . .
C28 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C28 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
N6 C28 C27 177.6(9) . .
C10 N1 C12 107.6(5) . .
C10 N1 Ag2 129.9(4) . .
C12 N1 Ag2 122.3(4) . .
C7 N2 C8 107.6(5) . .
C7 N2 Ag2 131.1(4) . 2_777
C8 N2 Ag2 121.2(4) . 2_777
C24 N3 C26 107.1(5) . .
C24 N3 Ag1 127.4(4) . .
C26 N3 Ag1 123.1(4) . .
C21 N4 C22 107.3(5) . .
C21 N4 Ag1 127.6(4) . 2_776
C22 N4 Ag1 123.1(4) . 2_776
C13 N5 Ag2 176.9(6) . .
C28 N6 Ag1 141.5(7) . .
C10 O1 C11 104.7(4) . .
C7 O2 C9 106.8(4) . .
C21 O3 C23 106.1(4) . .
C24 O4 C25 107.1(4) . .
F2 P1 F5 175.5(5) . .
F2 P1 F4 89.6(5) . .
F5 P1 F4 94.0(6) . .
F2 P1 F1 86.1(4) . .
F5 P1 F1 90.3(6) . .
F4 P1 F1 175.6(5) . .
F2 P1 F6 96.4(5) . .
F5 P1 F6 86.4(5) . .
F4 P1 F6 88.9(3) . .
F1 P1 F6 92.2(3) . .
F2 P1 F3 87.4(4) . .
F5 P1 F3 89.9(4) . .
F4 P1 F3 90.7(3) . .
F1 P1 F3 88.4(3) . .
F6 P1 F3 176.2(4) . .
F10 P2 F8 176.8(8) . .
F10 P2 F11 96.9(8) . .
F8 P2 F11 86.3(6) . .
F10 P2 F9 87.8(8) . .
F8 P2 F9 89.0(7) . .
F11 P2 F9 174.8(7) . .
F10 P2 F7 91.9(7) . .
F8 P2 F7 88.3(6) . .
F11 P2 F7 84.6(5) . .
F9 P2 F7 93.0(5) . .
F10 P2 F12 91.1(7) . .
F8 P2 F12 88.5(6) . .
F11 P2 F12 97.4(5) . .
F9 P2 F12 84.6(5) . .
F7 P2 F12 176.2(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.143(5) .
Ag1 N4 2.151(5) 2_776
Ag1 N6 2.490(6) .
Ag2 N2 2.156(5) 2_777
Ag2 N1 2.161(5) .
Ag2 N5 2.389(6) .
C1 C6 1.379(7) .
C1 C2 1.403(7) .
C1 H1 0.9300 .
C2 C3 1.377(8) .
C2 C10 1.462(7) .
C3 C4 1.370(7) .
C3 H3 0.9300 .
C4 C5 1.376(7) .
C4 H4 0.9300 .
C5 C6 1.387(7) .
C5 H5 0.9300 .
C6 C7 1.474(7) .
C7 N2 1.270(6) .
C7 O2 1.338(6) .
C8 N2 1.468(7) .
C8 C9 1.515(9) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 O2 1.446(7) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 N1 1.270(7) .
C10 O1 1.355(6) .
C11 O1 1.471(7) .
C11 C12 1.492(8) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 N1 1.475(7) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 N5 1.120(8) .
C13 C14 1.433(9) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.392(7) .
C15 C20 1.393(7) .
C15 H15 0.9300 .
C16 C17 1.392(7) .
C16 C24 1.456(7) .
C17 C18 1.384(7) .
C17 H17 0.9300 .
C18 C19 1.387(8) .
C18 H18 0.9300 .
C19 C20 1.394(7) .
C19 H19 0.9300 .
C20 C21 1.461(7) .
C21 N4 1.271(7) .
C21 O3 1.340(6) .
C22 N4 1.474(7) .
C22 C23 1.510(9) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 O3 1.456(7) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 N3 1.282(6) .
C24 O4 1.343(6) .
C25 O4 1.452(7) .
C25 C26 1.505(9) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 N3 1.488(7) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 C28 1.407(10) .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 N6 1.124(9) .
F1 P1 1.533(5) .
F2 P1 1.496(6) .
F3 P1 1.571(5) .
F4 P1 1.527(5) .
F5 P1 1.506(7) .
F6 P1 1.554(5) .
F7 P2 1.507(7) .
F8 P2 1.454(8) .
F9 P2 1.506(7) .
F10 P2 1.410(8) .
F11 P2 1.473(6) .
F12 P2 1.514(7) .
N2 Ag2 2.156(5) 2_777
N4 Ag1 2.151(5) 2_776
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -2.1(8) . .
C6 C1 C2 C10 175.1(5) . .
C1 C2 C3 C4 0.3(8) . .
C10 C2 C3 C4 -176.9(5) . .
C2 C3 C4 C5 1.1(8) . .
C3 C4 C5 C6 -0.5(8) . .
C2 C1 C6 C5 2.7(8) . .
C2 C1 C6 C7 -177.3(5) . .
C4 C5 C6 C1 -1.4(8) . .
C4 C5 C6 C7 178.6(5) . .
C1 C6 C7 N2 154.5(6) . .
C5 C6 C7 N2 -25.4(9) . .
C1 C6 C7 O2 -22.8(8) . .
C5 C6 C7 O2 157.3(5) . .
N2 C8 C9 O2 -5.4(8) . .
C3 C2 C10 N1 37.9(8) . .
C1 C2 C10 N1 -139.3(6) . .
C3 C2 C10 O1 -141.4(5) . .
C1 C2 C10 O1 41.4(7) . .
O1 C11 C12 N1 17.2(6) . .
C20 C15 C16 C17 -2.2(8) . .
C20 C15 C16 C24 -179.3(5) . .
C15 C16 C17 C18 2.3(8) . .
C24 C16 C17 C18 179.4(5) . .
C16 C17 C18 C19 -1.1(9) . .
C17 C18 C19 C20 -0.2(9) . .
C16 C15 C20 C19 0.9(8) . .
C16 C15 C20 C21 -179.5(5) . .
C18 C19 C20 C15 0.3(8) . .
C18 C19 C20 C21 -179.4(5) . .
C15 C20 C21 N4 150.3(6) . .
C19 C20 C21 N4 -30.1(9) . .
C15 C20 C21 O3 -30.8(8) . .
C19 C20 C21 O3 148.8(5) . .
N4 C22 C23 O3 -4.8(7) . .
C15 C16 C24 N3 -158.8(5) . .
C17 C16 C24 N3 24.1(9) . .
C15 C16 C24 O4 22.1(7) . .
C17 C16 C24 O4 -155.0(5) . .
O4 C25 C26 N3 4.4(7) . .
O1 C10 N1 C12 1.8(7) . .
C2 C10 N1 C12 -177.5(5) . .
O1 C10 N1 Ag2 176.2(3) . .
C2 C10 N1 Ag2 -3.1(8) . .
C11 C12 N1 C10 -12.3(6) . .
C11 C12 N1 Ag2 172.8(4) . .
N2 Ag2 N1 C10 6.2(8) 2_777 .
N5 Ag2 N1 C10 175.9(5) . .
N2 Ag2 N1 C12 179.8(4) 2_777 .
N5 Ag2 N1 C12 -10.5(5) . .
O2 C7 N2 C8 -0.8(7) . .
C6 C7 N2 C8 -178.1(6) . .
O2 C7 N2 Ag2 174.2(4) . 2_777
C6 C7 N2 Ag2 -3.1(9) . 2_777
C9 C8 N2 C7 4.0(7) . .
C9 C8 N2 Ag2 -171.6(4) . 2_777
O4 C24 N3 C26 0.4(7) . .
C16 C24 N3 C26 -178.6(5) . .
O4 C24 N3 Ag1 -162.3(4) . .
C16 C24 N3 Ag1 18.6(8) . .
C25 C26 N3 C24 -3.1(6) . .
C25 C26 N3 Ag1 160.6(4) . .
N4 Ag1 N3 C24 19.3(8) 2_776 .
N6 Ag1 N3 C24 -165.0(5) . .
N4 Ag1 N3 C26 -140.9(5) 2_776 .
N6 Ag1 N3 C26 34.7(5) . .
O3 C21 N4 C22 -0.6(7) . .
C20 C21 N4 C22 178.2(5) . .
O3 C21 N4 Ag1 163.7(4) . 2_776
C20 C21 N4 Ag1 -17.4(9) . 2_776
C23 C22 N4 C21 3.4(7) . .
C23 C22 N4 Ag1 -161.8(5) . 2_776
C14 C13 N5 Ag2 60(30) . .
N2 Ag2 N5 C13 100(12) 2_777 .
N1 Ag2 N5 C13 -75(12) . .
C27 C28 N6 Ag1 107(22) . .
N3 Ag1 N6 C28 124.2(11) . .
N4 Ag1 N6 C28 -57.4(11) 2_776 .
N1 C10 O1 C11 9.7(6) . .
C2 C10 O1 C11 -170.9(5) . .
C12 C11 O1 C10 -16.4(6) . .
N2 C7 O2 C9 -2.9(8) . .
C6 C7 O2 C9 174.7(5) . .
C8 C9 O2 C7 5.1(7) . .
N4 C21 O3 C23 -2.6(8) . .
C20 C21 O3 C23 178.4(5) . .
C22 C23 O3 C21 4.5(7) . .
N3 C24 O4 C25 2.6(7) . .
C16 C24 O4 C25 -178.3(5) . .
C26 C25 O4 C24 -4.3(7) . .
