#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/27/1512782.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1512782
loop_
_publ_author_name
'Rosenani A. Haque'
'Mohammed Z. Ghdhayeb'
'Srinivasa Budagumpi'
'Abbas Washeel Salman'
'Mohamed B. Khadeer Ahamed'
'Amin Malik Shah Abdul Majid'
_publ_section_title
;
 Non-symmetrically substituted N-heterocyclic carbene-Ag(I) complexes of
 benzimidazol-2-ylidenes: Synthesis, crystal structures, anticancer
 activity and transmetallation studies
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              519
_journal_page_last               525
_journal_paper_doi               10.1016/j.ica.2012.09.013
_journal_volume                  394
_journal_year                    2013
_chemical_formula_sum            'C37.42 H34.27 Ag Br0 N5.32 O1.93'
_chemical_formula_weight         697.19
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                108.4830(10)
_cell_angle_beta                 91.926(2)
_cell_angle_gamma                100.9250(10)
_cell_formula_units_Z            2
_cell_length_a                   10.5279(2)
_cell_length_b                   10.7966(3)
_cell_length_c                   14.6437(2)
_cell_measurement_temperature    100(2)
_cell_volume                     1542.15(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0253
_diffrn_reflns_av_sigmaI/netI    0.0289
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            32999
_diffrn_reflns_theta_full        30.12
_diffrn_reflns_theta_max         30.12
_diffrn_reflns_theta_min         1.98
_exptl_absorpt_coefficient_mu    0.698
_exptl_absorpt_correction_T_max  0.9129
_exptl_absorpt_correction_T_min  0.7707
_exptl_crystal_density_diffrn    1.501
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             717
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.13
_refine_diff_density_max         3.420
_refine_diff_density_min         -1.033
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.318
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     725
_refine_ls_number_reflns         8981
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.318
_refine_ls_R_factor_all          0.1041
_refine_ls_R_factor_gt           0.0894
_refine_ls_shift/su_max          5.992
_refine_ls_shift/su_mean         0.121
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0670P)²+4.0311P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2096
_refine_ls_wR_factor_ref         0.2182
_reflns_number_gt                7356
_reflns_number_total             8981
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2013-394-519-525-1.cif
_cod_data_source_block           a
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1512782
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.04776(4) -0.14181(5) -0.32281(3) 0.04969(16) Uani 1 1 d . . .
N1X N 0.915(4) -0.458(4) -0.362(2) 0.026(7) Uani 0.249(12) 1 d P A 2
N2X N 1.111(7) -0.398(7) -0.370(4) 0.030(7) Uani 0.249(12) 1 d P A 2
N3X N 1.009(4) 0.172(3) -0.224(3) 0.042(7) Uani 0.249(12) 1 d P A 2
N4X N 1.185(6) 0.158(7) -0.267(3) 0.09(2) Uani 0.249(12) 1 d P A 2
C1X C 1.026(4) -0.311(3) -0.344(3) 0.032(7) Uani 0.249(12) 1 d P A 2
C2X C 1.066(5) -0.531(7) -0.385(3) 0.039(9) Uani 0.249(12) 1 d P A 2
C3X C 1.144(7) -0.625(5) -0.426(4) 0.077(19) Uani 0.249(12) 1 d P A 2
H3XA H 1.2340 -0.5980 -0.4292 0.093 Uiso 0.249(12) 1 calc PR A 2
C4X C 1.069(8) -0.778(7) -0.465(3) 0.08(3) Uani 0.249(12) 1 d P A 2
H4XA H 1.1119 -0.8472 -0.4979 0.096 Uiso 0.249(12) 1 calc PR A 2
C5X C 0.940(8) -0.806(7) -0.449(3) 0.052(17) Uani 0.249(12) 1 d P A 2
H5XA H 0.8973 -0.8963 -0.4595 0.063 Uiso 0.249(12) 1 calc PR A 2
C6X C 0.873(5) -0.706(4) -0.418(3) 0.031(8) Uani 0.249(12) 1 d P A 2
H6XA H 0.7821 -0.7198 -0.4128 0.037 Uiso 0.249(12) 1 calc PR A 2
C7X C 0.959(6) -0.579(5) -0.394(3) 0.040(15) Uani 0.249(12) 1 d P A 2
C15X C 1.243(5) -0.338(6) -0.380(4) 0.054(12) Uani 0.249(12) 1 d P A 2
H15A H 1.2811 -0.4090 -0.4241 0.065 Uiso 0.249(12) 1 calc PR A 2
H15B H 1.2388 -0.2712 -0.4125 0.065 Uiso 0.249(12) 1 calc PR A 2
C16X C 1.332(4) -0.275(4) -0.294(2) 0.039(8) Uani 0.249(12) 1 d P A 2
H16A H 1.3308 -0.3096 -0.2425 0.047 Uiso 0.249(12) 1 calc PR A 2
C17X C 1.413(2) -0.166(3) -0.2912(19) 0.068(9) Uani 0.249(12) 1 d P A 2
H17A H 1.4520 -0.1191 -0.2245 0.102 Uiso 0.249(12) 1 calc PR A 2
H17B H 1.3669 -0.1089 -0.3134 0.102 Uiso 0.249(12) 1 calc PR A 2
H17C H 1.4813 -0.1898 -0.3332 0.102 Uiso 0.249(12) 1 calc PR A 2
C18X C 1.074(9) 0.086(8) -0.264(4) 0.09(3) Uani 0.249(12) 1 d P A 2
C19X C 1.197(4) 0.312(4) -0.218(3) 0.039(9) Uani 0.249(12) 1 d P A 2
C20X C 1.297(3) 0.430(5) -0.184(2) 0.071(13) Uani 0.249(12) 1 d P A 2
H20A H 1.3652 0.4141 -0.1430 0.086 Uiso 0.249(12) 1 calc PR A 2
H20B H 1.3379 0.4458 -0.2403 0.086 Uiso 0.249(12) 1 calc PR A 2
C21X C 1.261(3) 0.536(3) -0.135(2) 0.058(9) Uani 0.249(12) 1 d P A 2
H21A H 1.3217 0.6188 -0.1180 0.070 Uiso 0.249(12) 1 calc PR A 2
C22X C 1.131(3) 0.538(3) -0.104(3) 0.076(12) Uani 0.249(12) 1 d P A 2
H22A H 1.1089 0.6181 -0.0641 0.091 Uiso 0.249(12) 1 calc PR A 2
C23X C 1.041(3) 0.419(3) -0.134(3) 0.063(10) Uani 0.249(12) 1 d P A 2
H23A H 0.9533 0.4166 -0.1195 0.075 Uiso 0.249(12) 1 calc PR A 2
C24X C 1.079(3) 0.298(5) -0.188(4) 0.043(8) Uani 0.249(12) 1 d P A 2
C32X C 1.310(7) 0.105(9) -0.309(5) 0.10(3) Uani 0.249(12) 1 d P A 2
H32A H 1.2869 0.0085 -0.3463 0.114 Uiso 0.249(12) 1 calc PR A 2
H32B H 1.3478 0.1538 -0.3526 0.114 Uiso 0.249(12) 1 calc PR A 2
C33X C 1.404(9) 0.133(12) -0.221(9) 0.19(6) Uani 0.249(12) 1 d P A 2
H33A H 1.3946 0.0902 -0.1739 0.224 Uiso 0.249(12) 1 calc PR A 2
C34X C 1.530(4) 0.257(5) -0.224(6) 0.18(3) Uani 0.249(12) 1 d P A 2
H34A H 1.6125 0.2359 -0.2061 0.276 Uiso 0.249(12) 1 calc PR A 2
H34B H 1.5207 0.3419 -0.1780 0.276 Uiso 0.249(12) 1 calc PR A 2
H34C H 1.5305 0.2627 -0.2893 0.276 Uiso 0.249(12) 1 calc PR A 2
C8X C 0.7842(10) -0.4187(12) -0.3430(8) 0.043(2) Uani 0.784(11) 1 d P A 2
H8XA H 0.7863 -0.3294 -0.3487 0.052 Uiso 0.784(11) 1 calc PR A 2
H8XB H 0.7144 -0.4843 -0.3905 0.052 Uiso 0.784(11) 1 calc PR A 2
C9X C 0.7598(12) -0.4168(14) -0.2436(9) 0.044(3) Uani 0.784(11) 1 d P A 2
C10X C 0.6732(8) -0.5237(8) -0.2300(5) 0.053(2) Uani 0.784(11) 1 d P A 2
H10A H 0.6326 -0.5981 -0.2843 0.064 Uiso 0.784(11) 1 calc PR A 2
C11X C 0.6462(9) -0.5212(11) -0.1368(6) 0.073(3) Uani 0.784(11) 1 d P A 2
H11A H 0.5863 -0.5943 -0.1293 0.087 Uiso 0.784(11) 1 calc PR A 2
C12X C 0.7010(17) -0.420(2) -0.0579(9) 0.103(7) Uani 0.784(11) 1 d P A 2
H12A H 0.6868 -0.4235 0.0051 0.124 Uiso 0.784(11) 1 calc PR A 2
C13X C 0.7808(16) -0.309(2) -0.0717(9) 0.145(10) Uani 0.784(11) 1 d P A 2
H13A H 0.8160 -0.2318 -0.0174 0.174 Uiso 0.784(11) 1 calc PR A 2
C14X C 0.8090(13) -0.3096(13) -0.1646(9) 0.093(5) Uani 0.784(11) 1 d P A 2
H14A H 0.8637 -0.2336 -0.1723 0.112 Uiso 0.784(11) 1 calc PR A 2
C25X C 0.8655(19) 0.112(2) -0.2241(13) 0.059(4) Uani 0.536(17) 1 d P A 2
H25A H 0.8430 0.0229 -0.2751 0.071 Uiso 0.536(17) 1 calc PR A 2
H25B H 0.8121 0.1693 -0.2405 0.071 Uiso 0.536(17) 1 calc PR A 2
C26X C 0.831(6) 0.095(5) -0.124(4) 0.055(10) Uani 0.536(17) 1 d P A 2
C29X C 0.749(3) 0.041(3) 0.0367(18) 0.082(6) Uani 0.536(17) 1 d P A 2
H29A H 0.7186 0.0267 0.0938 0.098 Uiso 0.536(17) 1 calc PR A 2
C27X C 0.8947(19) 0.161(2) -0.0432(11) 0.093(7) Uani 0.536(17) 1 d P A 2
H27A H 0.9716 0.2258 -0.0393 0.111 Uiso 0.536(17) 1 calc PR A 2
C28X C 0.852(2) 0.1384(19) 0.0404(12) 0.082(5) Uani 0.536(17) 1 d P A 2
H28A H 0.8963 0.1932 0.1015 0.098 Uiso 0.536(17) 1 calc PR A 2
C30X C 0.692(2) -0.035(3) -0.0504(14) 0.121(10) Uani 0.536(17) 1 d P A 2
H30A H 0.6234 -0.1091 -0.0552 0.145 Uiso 0.536(17) 1 calc PR A 2
C31X C 0.727(2) -0.011(2) -0.1370(15) 0.092(6) Uani 0.536(17) 1 d P A 2
H31A H 0.6836 -0.0634 -0.1988 0.110 Uiso 0.536(17) 1 calc PR A 2
N1 N 0.9229(17) -0.4335(18) -0.3573(10) 0.051(4) Uani 0.751(12) 1 d P A 1
N2 N 1.129(3) -0.422(3) -0.3834(15) 0.040(3) Uani 0.751(12) 1 d P A 1
N3 N 0.9838(14) 0.1289(13) -0.2371(10) 0.050(3) Uani 0.751(12) 1 d P A 1
N4 N 1.1898(13) 0.1551(12) -0.2723(9) 0.045(4) Uani 0.751(12) 1 d P A 1
C1 C 1.0302(16) -0.3563(11) -0.3570(9) 0.033(3) Uani 0.751(12) 1 d P A 1
C2 C 1.0802(19) -0.5561(18) -0.4067(10) 0.037(3) Uani 0.751(12) 1 d P A 1
C3 C 1.1316(12) -0.6685(13) -0.4402(9) 0.045(3) Uani 0.751(12) 1 d P A 1
H3A H 1.2199 -0.6623 -0.4532 0.053 Uiso 0.751(12) 1 calc PR A 1
C4 C 1.052(2) -0.788(2) -0.4539(13) 0.063(5) Uani 0.751(12) 1 d P A 1
H4A H 1.0860 -0.8664 -0.4756 0.076 Uiso 0.751(12) 1 calc PR A 1
C5 C 0.918(3) -0.799(3) -0.4366(16) 0.068(6) Uani 0.751(12) 1 d P A 1
H5A H 0.8654 -0.8862 -0.4497 0.082 Uiso 0.751(12) 1 calc PR A 1
C6 C 0.862(2) -0.691(2) -0.4021(13) 0.063(6) Uani 0.751(12) 1 d P A 1
H6A H 0.7738 -0.7016 -0.3891 0.075 Uiso 0.751(12) 1 calc PR A 1
C7 C 0.9422(19) -0.5605(18) -0.3862(15) 0.051(6) Uani 0.751(12) 1 d P A 1
C15 C 1.2638(13) -0.3597(16) -0.3894(12) 0.047(3) Uani 0.751(12) 1 d P A 1
H15C H 1.3063 -0.4286 -0.4309 0.057 Uiso 0.751(12) 1 calc PR A 1
H15D H 1.2630 -0.2910 -0.4209 0.057 Uiso 0.751(12) 1 calc PR A 1
C16 C 1.339(2) -0.299(2) -0.2972(15) 0.098(7) Uani 0.751(12) 1 d P A 1
H16B H 1.2967 -0.2484 -0.2465 0.118 Uiso 0.751(12) 1 calc PR A 1
C17 C 1.4517(11) -0.3033(18) -0.2750(8) 0.111(6) Uani 0.751(12) 1 d P A 1
H17D H 1.4743 -0.2578 -0.2054 0.167 Uiso 0.751(12) 1 calc PR A 1
H17E H 1.5110 -0.2588 -0.3107 0.167 Uiso 0.751(12) 1 calc PR A 1
H17F H 1.4593 -0.3967 -0.2914 0.167 Uiso 0.751(12) 1 calc PR A 1
C18 C 1.0768(12) 0.0626(16) -0.2786(11) 0.039(2) Uani 0.751(12) 1 d P A 1
C19 C 1.162(2) 0.2786(19) -0.2244(13) 0.061(5) Uani 0.751(12) 1 d P A 1
C20 C 1.2485(18) 0.4057(11) -0.2037(8) 0.073(4) Uani 0.751(12) 1 d P A 1
H20C H 1.3359 0.4177 -0.2193 0.088 Uiso 0.751(12) 1 calc PR A 1
C21 C 1.185(3) 0.5142(12) -0.1556(9) 0.101(7) Uani 0.751(12) 1 d P A 1
H21B H 1.2332 0.6033 -0.1383 0.121 Uiso 0.751(12) 1 calc PR A 1
C22 C 1.058(3) 0.495(2) -0.1339(9) 0.107(7) Uani 0.751(12) 1 d P A 1
H22B H 1.0243 0.5707 -0.1013 0.129 Uiso 0.751(12) 1 calc PR A 1
C23 C 0.981(2) 0.3737(17) -0.1567(8) 0.093(5) Uani 0.751(12) 1 d P A 1
H23B H 0.8935 0.3627 -0.1416 0.112 Uiso 0.751(12) 1 calc PR A 1
C24 C 1.0342(19) 0.2638(19) -0.2036(10) 0.059(4) Uani 0.751(12) 1 d P A 1
C32 C 1.3050(16) 0.125(2) -0.3120(10) 0.051(3) Uani 0.751(12) 1 d P A 1
H32C H 1.3377 0.1883 -0.3461 0.061 Uiso 0.751(12) 1 calc PR A 1
H32D H 1.2838 0.0340 -0.3606 0.061 Uiso 0.751(12) 1 calc PR A 1
C33 C 1.4092(16) 0.130(3) -0.2407(14) 0.086(6) Uani 0.751(12) 1 d P A 1
H33B H 1.4901 0.1162 -0.2644 0.103 Uiso 0.751(12) 1 calc PR A 1
C34 C 1.4023(13) 0.1504(15) -0.1493(8) 0.086(4) Uani 0.751(12) 1 d P A 1
H34D H 1.4903 0.1748 -0.1160 0.129 Uiso 0.751(12) 1 calc PR A 1
H34E H 1.3546 0.0690 -0.1397 0.129 Uiso 0.751(12) 1 calc PR A 1
H34F H 1.3568 0.2233 -0.1229 0.129 Uiso 0.751(12) 1 calc PR A 1
C8 C 0.814(3) -0.392(5) -0.328(3) 0.059(14) Uani 0.216(11) 1 d P A 1
H8XC H 0.7470 -0.4367 -0.3834 0.071 Uiso 0.216(11) 1 calc PR A 1
H8XD H 0.8316 -0.2958 -0.3203 0.071 Uiso 0.216(11) 1 calc PR A 1
C9 C 0.736(5) -0.404(7) -0.227(3) 0.048(12) Uani 0.216(11) 1 d P A 1
C10 C 0.620(3) -0.390(4) -0.217(3) 0.081(12) Uani 0.216(11) 1 d P A 1
H10B H 0.5667 -0.3810 -0.2667 0.097 Uiso 0.216(11) 1 calc PR A 1
C11 C 0.573(3) -0.390(4) -0.124(3) 0.073(10) Uani 0.216(11) 1 d P A 1
H11B H 0.4844 -0.3940 -0.1120 0.088 Uiso 0.216(11) 1 calc PR A 1
C12 C 0.660(4) -0.385(3) -0.061(4) 0.050(10) Uani 0.216(11) 1 d P A 1
H12B H 0.6298 -0.3839 -0.0002 0.060 Uiso 0.216(11) 1 calc PR A 1
C13 C 0.793(3) -0.379(2) -0.0635(19) 0.037(6) Uani 0.216(11) 1 d P A 1
H13B H 0.8497 -0.3808 -0.0123 0.045 Uiso 0.216(11) 1 calc PR A 1
C14 C 0.831(3) -0.371(4) -0.150(2) 0.043(7) Uani 0.216(11) 1 d P A 1
H14B H 0.9197 -0.3429 -0.1576 0.052 Uiso 0.216(11) 1 calc PR A 1
C25 C 0.843(2) 0.054(2) -0.2312(17) 0.055(5) Uani 0.464(17) 1 d P A 1
H25C H 0.7783 0.0925 -0.2576 0.066 Uiso 0.464(17) 1 calc PR A 1
H25D H 0.8304 -0.0417 -0.2706 0.066 Uiso 0.464(17) 1 calc PR A 1
C26 C 0.823(7) 0.066(6) -0.132(5) 0.052(10) Uani 0.464(17) 1 d P A 1
C29 C 0.788(3) 0.088(3) 0.0645(17) 0.079(7) Uani 0.464(17) 1 d P A 1
H29B H 0.7765 0.0979 0.1302 0.095 Uiso 0.464(17) 1 calc PR A 1
C27 C 0.9229(15) 0.0635(18) -0.0620(10) 0.060(4) Uani 0.464(17) 1 d P A 1
H27B H 1.0064 0.0553 -0.0827 0.072 Uiso 0.464(17) 1 calc PR A 1
C28 C 0.905(2) 0.072(3) 0.0315(12) 0.082(7) Uani 0.464(17) 1 d P A 1
H28B H 0.9740 0.0676 0.0731 0.098 Uiso 0.464(17) 1 calc PR A 1
C30 C 0.690(2) 0.091(3) 0.0057(16) 0.096(8) Uani 0.464(17) 1 d P A 1
H30B H 0.6073 0.0977 0.0277 0.116 Uiso 0.464(17) 1 calc PR A 1
C31 C 0.7135(17) 0.082(3) -0.0923(14) 0.081(6) Uani 0.464(17) 1 d P A 1
H31B H 0.6438 0.0888 -0.1322 0.097 Uiso 0.464(17) 1 calc PR A 1
O2 N 1.4407(6) 0.3896(6) -0.4821(5) 0.109(2) Uiso 1 1 d P B 1
C36 C 1.5549(7) 0.2286(7) -0.4444(5) 0.094(2) Uiso 1 1 d P B 1
C37 C 1.383(2) 0.218(2) -0.5446(15) 0.236(8) Uiso 1 1 d P B 1
O1 O 1.6410(9) 0.0492(9) -0.4079(7) 0.100(3) Uiso 0.776(13) 1 d P C 2
C35 C 1.5323(7) 0.0006(9) -0.4876(6) 0.056(2) Uiso 0.776(13) 1 d P . 2
O1W O 1.7061(13) -0.1154(14) -0.4123(10) 0.114(6) Uiso 0.64(3) 1 d P D 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C1X Ag1 C18 172.2(14) .
C1X Ag1 C1 4.3(17) .
C18 Ag1 C1 174.2(5) .
C1X Ag1 C18X 169(2) .
C18 Ag1 C18X 4(2) .
C1 Ag1 C18X 171.6(17) .
C7X N1X C8X 136(4) .
C7X N1X C1X 118(4) .
C8X N1X C1X 106(3) .
C7X N1X C2X 36(4) .
C8X N1X C2X 172(4) .
C1X N1X C2X 82(3) .
C1X N2X C2X 119(6) .
C1X N2X C15X 116(6) .
C2X N2X C15X 124(4) .
C18X N3X C24X 114(5) .
C18X N3X C25X 113(5) .
C24X N3X C25X 132(4) .
C18X N4X C19X 114(5) .
C18X N4X C32X 127(7) .
C19X N4X C32X 119(5) .
N2X C1X N1X 82(4) .
N2X C1X Ag1 131(5) .
N1X C1X Ag1 146(3) .
C7X C2X C3X 113(6) .
C7X C2X N2X 122(5) .
C3X C2X N2X 121(5) .
C7X C2X N1X 48(3) .
C3X C2X N1X 159(5) .
N2X C2X N1X 76(3) .
C2X C3X C4X 116(6) .
C2X C3X H3XA 121.8 .
C4X C3X H3XA 122.3 .
C5X C4X C3X 117(5) .
C5X C4X H4XA 121.6 .
C3X C4X H4XA 121.3 .
C6X C5X C4X 121(6) .
C6X C5X H5XA 119.7 .
C4X C5X H5XA 119.5 .
C5X C6X C7X 110(5) .
C5X C6X H6XA 124.9 .
C7X C6X H6XA 124.8 .
C2X C7X C6X 141(5) .
C2X C7X N1X 96(5) .
C6X C7X N1X 122(5) .
C16X C15X N2X 118(4) .
C16X C15X H15A 107.9 .
N2X C15X H15A 107.6 .
C16X C15X H15B 107.8 .
N2X C15X H15B 107.9 .
H15A C15X H15B 107.2 .
C17X C16X C15X 117(4) .
C17X C16X H16A 121.7 .
C15X C16X H16A 121.8 .
C16X C17X H17A 109.7 .
C16X C17X H17B 109.2 .
H17A C17X H17B 109.5 .
C16X C17X H17C 109.5 .
H17A C17X H17C 109.5 .
H17B C17X H17C 109.5 .
N3X C18X N4X 103(7) .
N3X C18X Ag1 139(6) .
N4X C18X Ag1 118(6) .
C24X C19X C20X 125(4) .
C24X C19X N4X 94(4) .
C20X C19X N4X 138(5) .
C21X C20X C19X 115(3) .
C21X C20X H20A 108.5 .
C19X C20X H20A 108.5 .
C21X C20X H20B 108.4 .
C19X C20X H20B 108.4 .
H20A C20X H20B 107.5 .
C20X C21X C22X 124(2) .
C20X C21X H21A 118.1 .
C22X C21X H21A 117.8 .
C23X C22X C21X 117(3) .
C23X C22X H22A 121.4 .
C21X C22X H22A 121.4 .
C22X C23X C24X 120(3) .
C22X C23X H23A 119.8 .
C24X C23X H23A 120.0 .
C19X C24X N3X 113(5) .
C19X C24X C23X 116(3) .
N3X C24X C23X 130(3) .
C33X C32X N4X 105(6) .
C33X C32X H32A 110.1 .
N4X C32X H32A 111.0 .
C33X C32X H32B 111.0 .
N4X C32X H32B 111.1 .
H32A C32X H32B 109.0 .
C32X C33X C34X 107(7) .
C32X C33X H33A 126.8 .
C34X C33X H33A 126.3 .
C33X C34X H34A 109.2 .
C33X C34X H34B 110.4 .
H34A C34X H34B 109.5 .
C33X C34X H34C 108.9 .
H34A C34X H34C 109.5 .
H34B C34X H34C 109.5 .
C9X C8X N1X 107.3(18) .
C9X C8X H8XA 110.2 .
N1X C8X H8XA 110.1 .
C9X C8X H8XB 110.3 .
N1X C8X H8XB 110.3 .
H8XA C8X H8XB 108.5 .
C14X C9X C10X 117.7(11) .
C14X C9X C8X 122.4(12) .
C10X C9X C8X 119.7(10) .
C11X C10X C9X 120.2(8) .
C11X C10X H10A 120.0 .
C9X C10X H10A 119.8 .
C12X C11X C10X 122.6(10) .
C12X C11X H11A 118.6 .
C10X C11X H11A 118.8 .
C11X C12X C13X 117.3(12) .
C11X C12X H12A 121.6 .
C13X C12X H12A 121.1 .
C12X C13X C14X 120.7(11) .
C12X C13X H13A 119.7 .
C14X C13X H13A 119.6 .
C9X C14X C13X 121.3(12) .
C9X C14X H14A 119.3 .
C13X C14X H14A 119.4 .
N3X C25X C26X 113(3) .
N3X C25X H25A 109.2 .
C26X C25X H25A 109.2 .
N3X C25X H25B 109.0 .
C26X C25X H25B 108.5 .
H25A C25X H25B 107.8 .
C27X C26X C31X 123(5) .
C27X C26X C25X 125(4) .
C31X C26X C25X 111(4) .
C30X C29X C28X 116.8(19) .
C30X C29X H29A 121.6 .
C28X C29X H29A 121.6 .
C26X C27X C28X 119(3) .
C26X C27X H27A 120.5 .
C28X C27X H27A 120.1 .
C29X C28X C27X 121.8(18) .
C29X C28X H28A 119.1 .
C27X C28X H28A 119.1 .
C29X C30X C31X 123.2(17) .
C29X C30X H30A 118.5 .
C31X C30X H30A 118.3 .
C26X C31X C30X 115(3) .
C26X C31X H31A 122.5 .
C30X C31X H31A 122.8 .
C1 N1 C8 124(2) .
C1 N1 C7 107.7(15) .
C8 N1 C7 128(3) .
C1 N2 C2 108(2) .
C1 N2 C15 126(2) .
C2 N2 C15 125.7(14) .
C18 N3 C24 109.7(13) .
C18 N3 C25 122.3(14) .
C24 N3 C25 128.0(17) .
C18 N4 C19 105.4(15) .
C18 N4 C32 125.0(15) .
C19 N4 C32 129.5(14) .
N1 C1 N2 113.4(18) .
N1 C1 Ag1 121.9(12) .
N2 C1 Ag1 124.7(17) .
N2 C2 C3 134.4(18) .
N2 C2 C7 102.2(14) .
C3 C2 C7 123.3(17) .
C4 C3 C2 117.6(16) .
C4 C3 H3A 121.2 .
C2 C3 H3A 121.2 .
C3 C4 C5 122(2) .
C3 C4 H4A 118.9 .
C5 C4 H4A 119.0 .
C6 C5 C4 123(2) .
C6 C5 H5A 118.7 .
C4 C5 H5A 118.6 .
C5 C6 C7 118(2) .
C5 C6 H6A 121.0 .
C7 C6 H6A 121.1 .
N1 C7 C6 135.5(18) .
N1 C7 C2 108.2(16) .
C6 C7 C2 116.3(17) .
C16 C15 N2 113.4(17) .
C16 C15 H15C 109.0 .
N2 C15 H15C 108.9 .
C16 C15 H15D 108.8 .
N2 C15 H15D 108.9 .
H15C C15 H15D 107.7 .
C17 C16 C15 128(2) .
C17 C16 H16B 115.9 .
C15 C16 H16B 115.8 .
C16 C17 H17D 109.2 .
C16 C17 H17E 109.5 .
H17D C17 H17E 109.5 .
C16 C17 H17F 109.7 .
H17D C17 H17F 109.5 .
H17E C17 H17F 109.5 .
N3 C18 N4 108.7(14) .
N3 C18 Ag1 122.0(8) .
N4 C18 Ag1 128.8(12) .
C24 C19 N4 110.5(14) .
C24 C19 C20 124(2) .
N4 C19 C20 125.8(18) .
C19 C20 C21 110.8(19) .
C19 C20 H20C 124.6 .
C21 C20 H20C 124.6 .
C22 C21 C20 123.7(14) .
C22 C21 H21B 118.1 .
C20 C21 H21B 118.1 .
C23 C22 C21 122.8(14) .
C23 C22 H22B 118.6 .
C21 C22 H22B 118.7 .
C22 C23 C24 117.4(17) .
C22 C23 H23B 121.3 .
C24 C23 H23B 121.3 .
N3 C24 C19 105.6(16) .
N3 C24 C23 132.7(19) .
C19 C24 C23 121.7(18) .
N4 C32 C33 114.5(13) .
N4 C32 H32C 108.7 .
C33 C32 H32C 108.5 .
N4 C32 H32D 108.6 .
C33 C32 H32D 108.8 .
H32C C32 H32D 107.6 .
C34 C33 C32 126.9(15) .
C34 C33 H33B 116.5 .
C32 C33 H33B 116.6 .
C33 C34 H34D 109.5 .
C33 C34 H34E 109.6 .
H34D C34 H34E 109.5 .
C33 C34 H34F 109.2 .
H34D C34 H34F 109.5 .
H34E C34 H34F 109.5 .
N1 C8 C9 128(4) .
N1 C8 H8XA 105.5 .
C9 C8 H8XA 105.4 .
N1 C8 H8XB 105.1 .
C9 C8 H8XB 105.3 .
H8XA C8 H8XB 106.0 .
C10 C9 C14 124(4) .
C10 C9 C8 123(4) .
C14 C9 C8 108(3) .
C9 C10 C11 116(4) .
C9 C10 H10B 122.0 .
C11 C10 H10B 122.0 .
C12 C11 C10 114(4) .
C12 C11 H11B 123.2 .
C10 C11 H11B 122.7 .
C11 C12 C13 132(5) .
C11 C12 H12B 114.0 .
C13 C12 H12B 114.3 .
C14 C13 C12 111(3) .
C14 C13 H13B 124.6 .
C12 C13 H13B 124.8 .
C13 C14 C9 119(3) .
C13 C14 H14B 120.8 .
C9 C14 H14B 120.7 .
C26 C25 N3 110(3) .
C26 C25 H25C 110.3 .
N3 C25 H25C 109.5 .
C26 C25 H25D 109.3 .
N3 C25 H25D 109.5 .
H25C C25 H25D 108.1 .
C31 C26 C25 125(5) .
C31 C26 C27 111(5) .
C25 C26 C27 124(5) .
C30 C29 C28 121(2) .
C30 C29 H29B 119.7 .
C28 C29 H29B 119.7 .
C28 C27 C26 125(3) .
C28 C27 H27B 117.9 .
C26 C27 H27B 117.5 .
C29 C28 C27 119(2) .
C29 C28 H28B 120.2 .
C27 C28 H28B 120.5 .
C29 C30 C31 118(2) .
C29 C30 H30B 120.9 .
C31 C30 H30B 120.9 .
C26 C31 C30 126(4) .
C26 C31 H31B 117.1 .
C30 C31 H31B 116.8 .
O2 C37 C36 74.9(9) .
C35 C35 O1 155.8(17) 2_854
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1X 1.73(3) .
Ag1 C18 2.051(16) .
Ag1 C1 2.178(11) .
Ag1 C18X 2.29(8) .
N1X C7X 1.42(5) .
N1X C8X 1.52(4) .
N1X C1X 1.71(6) .
N1X C2X 1.91(6) .
N2X C1X 1.39(5) .
N2X C2X 1.37(12) .
N2X C15X 1.46(8) .
N3X C18X 1.26(9) .
N3X C24X 1.35(4) .
N3X C25X 1.52(4) .
N4X C18X 1.29(10) .
N4X C19X 1.56(9) .
N4X C32X 1.60(9) .
C2X C7X 1.13(9) .
C2X C3X 1.41(8) .
C3X C4X 1.61(8) .
C3X H3XA 0.9500 .
C4X C5X 1.38(12) .
C4X H4XA 0.9500 .
C5X C6X 1.37(8) .
C5X H5XA 0.9500 .
C6X C7X 1.43(7) .
C6X H6XA 0.9500 .
C15X C16X 1.43(7) .
C15X H15A 0.9900 .
C15X H15B 0.9900 .
C16X C17X 1.30(5) .
C16X H16A 0.9500 .
C17X H17A 0.9800 .
C17X H17B 0.9800 .
C17X H17C 0.9800 .
C19X C24X 1.33(4) .
C19X C20X 1.43(4) .
C20X C21X 1.28(6) .
C20X H20A 0.9900 .
C20X H20B 0.9900 .
C21X C22X 1.46(4) .
C21X H21A 0.9500 .
C22X C23X 1.38(3) .
C22X H22A 0.9500 .
C23X C24X 1.43(7) .
C23X H23A 0.9500 .
C32X C33X 1.51(12) .
C32X H32A 0.9900 .
C32X H32B 0.9900 .
C33X C34X 1.71(10) .
C33X H33A 0.9500 .
C34X H34A 0.9800 .
C34X H34B 0.9800 .
C34X H34C 0.9800 .
C8X C9X 1.481(17) .
C8X H8XA 0.9900 .
C8X H8XB 0.9900 .
C9X C14X 1.353(16) .
C9X C10X 1.401(15) .
C10X C11X 1.396(10) .
C10X H10A 0.9500 .
C11X C12X 1.331(18) .
C11X H11A 0.9500 .
C12X C13X 1.41(2) .
C12X H12A 0.9500 .
C13X C14X 1.398(17) .
C13X H13A 0.9500 .
C14X H14A 0.9500 .
C25X C26X 1.58(6) .
C25X H25A 0.9900 .
C25X H25B 0.9900 .
C26X C27X 1.26(7) .
C26X C31X 1.38(6) .
C29X C30X 1.33(3) .
C29X C28X 1.35(3) .
C29X H29A 0.9500 .
C27X C28X 1.40(2) .
C27X H27A 0.9500 .
C28X H28A 0.9500 .
C30X C31X 1.42(2) .
C30X H30A 0.9500 .
C31X H31A 0.9500 .
N1 C1 1.27(2) .
N1 C8 1.34(5) .
N1 C7 1.36(2) .
N2 C1 1.366(17) .
N2 C2 1.37(4) .
N2 C15 1.47(3) .
N3 C18 1.37(2) .
N3 C24 1.371(18) .
N3 C25 1.57(2) .
N4 C18 1.381(15) .
N4 C19 1.39(3) .
N4 C32 1.41(2) .
C2 C3 1.377(17) .
C2 C7 1.49(3) .
C3 C4 1.35(3) .
C3 H3A 0.9500 .
C4 C5 1.43(4) .
C4 H4A 0.9500 .
C5 C6 1.37(3) .
C5 H5A 0.9500 .
C6 C7 1.44(3) .
C6 H6A 0.9500 .
C15 C16 1.43(3) .
C15 H15C 0.9900 .
C15 H15D 0.9900 .
C16 C17 1.23(3) .
C16 H16B 0.9500 .
C17 H17D 0.9800 .
C17 H17E 0.9800 .
C17 H17F 0.9800 .
C19 C24 1.38(2) .
C19 C20 1.433(16) .
C20 C21 1.46(2) .
C20 H20C 0.9500 .
C21 C22 1.37(3) .
C21 H21B 0.9500 .
C22 C23 1.34(3) .
C22 H22B 0.9500 .
C23 C24 1.40(2) .
C23 H23B 0.9500 .
C32 C33 1.47(2) .
C32 H32C 0.9900 .
C32 H32D 0.9900 .
C33 C34 1.29(2) .
C33 H33B 0.9500 .
C34 H34D 0.9800 .
C34 H34E 0.9800 .
C34 H34F 0.9800 .
C8 C9 1.74(6) .
C8 H8XA 0.9900 .
C8 H8XB 0.9900 .
C9 C10 1.27(6) .
C9 C14 1.38(6) .
C10 C11 1.47(5) .
C10 H10B 0.9500 .
C11 C12 1.26(6) .
C11 H11B 0.9500 .
C12 C13 1.39(5) .
C12 H12B 0.9500 .
C13 C14 1.37(4) .
C13 H13B 0.9500 .
C14 H14B 0.9500 .
C25 C26 1.44(7) .
C25 H25C 0.9900 .
C25 H25D 0.9900 .
C26 C31 1.33(7) .
C26 C27 1.45(7) .
C29 C30 1.33(4) .
C29 C28 1.36(4) .
C29 H29B 0.9500 .
C27 C28 1.36(2) .
C27 H27B 0.9500 .
C28 H28B 0.9500 .
C30 C31 1.44(2) .
C30 H30B 0.9500 .
C31 H31B 0.9500 .
O2 C37 1.76(2) .
C36 C37 2.26(2) .
O1 C35 1.497(11) .
C35 C35 0.756(14) 2_854
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C2X N2X C1X N1X -5(5)
C15X N2X C1X N1X 174(6)
C2X N2X C1X Ag1 -178(4)
C15X N2X C1X Ag1 2(8)
C7X N1X C1X N2X -2(5)
C8X N1X C1X N2X -179(4)
C2X N1X C1X N2X 3(3)
C7X N1X C1X Ag1 168(5)
C8X N1X C1X Ag1 -9(6)
C2X N1X C1X Ag1 173(5)
C18 Ag1 C1X N2X -100(11)
C1 Ag1 C1X N2X 33(22)
C18X Ag1 C1X N2X -110(13)
C18 Ag1 C1X N1X 93(12)
C1 Ag1 C1X N1X -134(28)
C18X Ag1 C1X N1X 84(15)
C1X N2X C2X C7X 14(9)
C15X N2X C2X C7X -165(6)
C1X N2X C2X C3X 171(5)
C15X N2X C2X C3X -9(9)
C1X N2X C2X N1X 5(5)
C15X N2X C2X N1X -175(7)
C8X N1X C2X C7X 22(19)
C1X N1X C2X C7X -172(5)
C7X N1X C2X C3X 24(13)
C8X N1X C2X C3X 46(27)
C1X N1X C2X C3X -148(13)
C7X N1X C2X N2X 169(6)
C8X N1X C2X N2X -169(19)
C1X N1X C2X N2X -3(3)
C7X C2X C3X C4X -6(7)
N2X C2X C3X C4X -165(5)
N1X C2X C3X C4X -26(15)
C2X C3X C4X C5X -5(7)
C3X C4X C5X C6X 12(8)
C4X C5X C6X C7X -8(8)
C3X C2X C7X C6X 15(11)
N2X C2X C7X C6X 173(6)
N1X C2X C7X C6X -174(10)
C3X C2X C7X N1X -171(5)
N2X C2X C7X N1X -13(7)
C5X C6X C7X C2X -9(10)
C5X C6X C7X N1X 179(5)
C8X N1X C7X C2X -175(4)
C1X N1X C7X C2X 9(6)
C8X N1X C7X C6X 0(8)
C1X N1X C7X C6X -176(4)
C2X N1X C7X C6X 176(8)
C1X N2X C15X C16X 82(7)
C2X N2X C15X C16X -99(7)
N2X C15X C16X C17X -142(4)
C24X N3X C18X N4X -9(7)
C25X N3X C18X N4X 172(4)
C24X N3X C18X Ag1 169(5)
C25X N3X C18X Ag1 -10(9)
C19X N4X C18X N3X 3(7)
C32X N4X C18X N3X 180(5)
C19X N4X C18X Ag1 -176(3)
C32X N4X C18X Ag1 1(9)
C1X Ag1 C18X N3X -66(17)
C18 Ag1 C18X N3X 134(40)
C1 Ag1 C18X N3X -84(18)
C1X Ag1 C18X N4X 112(13)
C18 Ag1 C18X N4X -48(32)
C1 Ag1 C18X N4X 94(15)
C18X N4X C19X C24X 4(6)
C32X N4X C19X C24X -174(5)
C18X N4X C19X C20X 164(6)
C32X N4X C19X C20X -13(8)
C24X C19X C20X C21X -14(7)
N4X C19X C20X C21X -170(5)
C19X C20X C21X C22X 8(6)
C20X C21X C22X C23X -4(7)
C21X C22X C23X C24X 5(7)
C20X C19X C24X N3X -173(4)
N4X C19X C24X N3X -9(5)
C20X C19X C24X C23X 15(8)
N4X C19X C24X C23X 179(4)
C18X N3X C24X C19X 13(7)
C25X N3X C24X C19X -169(4)
C18X N3X C24X C23X -176(5)
C25X N3X C24X C23X 2(8)
C22X C23X C24X C19X -10(7)
C22X C23X C24X N3X 179(5)
C18X N4X C32X C33X -108(8)
C19X N4X C32X C33X 69(7)
N4X C32X C33X C34X -111(7)
C7X N1X C8X C9X 85(5)
C1X N1X C8X C9X -99(2)
C2X N1X C8X C9X 66(19)
N1X C8X C9X C14X 84(2)
N1X C8X C9X C10X -102(2)
C14X C9X C10X C11X -4(2)
C8X C9X C10X C11X -178.0(11)
C9X C10X C11X C12X -0.7(19)
C10X C11X C12X C13X 5(3)
C11X C12X C13X C14X -5(3)
C10X C9X C14X C13X 4(3)
C8X C9X C14X C13X 177.8(17)
C12X C13X C14X C9X 1(3)
C18X N3X C25X C26X 101(5)
C24X N3X C25X C26X -78(6)
N3X C25X C26X C27X 23(6)
N3X C25X C26X C31X -151(4)
C31X C26X C27X C28X -8(7)
C25X C26X C27X C28X 179(3)
C30X C29X C28X C27X 1(4)
C26X C27X C28X C29X 5(5)
C28X C29X C30X C31X -5(5)
C27X C26X C31X C30X 4(7)
C25X C26X C31X C30X 178(3)
C29X C30X C31X C26X 3(5)
C8 N1 C1 N2 175(3)
C7 N1 C1 N2 -1(2)
C8 N1 C1 Ag1 -7(3)
C7 N1 C1 Ag1 176.8(12)
C2 N2 C1 N1 3(2)
C15 N2 C1 N1 -179.7(19)
C2 N2 C1 Ag1 -175.2(11)
C15 N2 C1 Ag1 3(3)
C1X Ag1 C1 N1 36(24)
C18 Ag1 C1 N1 116(5)
C18X Ag1 C1 N1 91(15)
C1X Ag1 C1 N2 -146(25)
C18 Ag1 C1 N2 -66(6)
C18X Ag1 C1 N2 -91(15)
C1 N2 C2 C3 177.8(16)
C15 N2 C2 C3 0(4)
C1 N2 C2 C7 -3(2)
C15 N2 C2 C7 180(2)
N2 C2 C3 C4 179(2)
C7 C2 C3 C4 -1(2)
C2 C3 C4 C5 1(2)
C3 C4 C5 C6 -2(3)
C4 C5 C6 C7 2(3)
C1 N1 C7 C6 -179(2)
C8 N1 C7 C6 5(4)
C1 N1 C7 C2 -1(2)
C8 N1 C7 C2 -177(3)
C5 C6 C7 N1 177(2)
C5 C6 C7 C2 -2(3)
N2 C2 C7 N1 2(2)
C3 C2 C7 N1 -178.2(15)
N2 C2 C7 C6 -178.9(18)
C3 C2 C7 C6 1(3)
C1 N2 C15 C16 78(3)
C2 N2 C15 C16 -104(2)
N2 C15 C16 C17 137(2)
C24 N3 C18 N4 0.1(16)
C25 N3 C18 N4 -179.6(15)
C24 N3 C18 Ag1 172.4(10)
C25 N3 C18 Ag1 -7(2)
C19 N4 C18 N3 0.8(16)
C32 N4 C18 N3 -176.4(13)
C19 N4 C18 Ag1 -170.8(11)
C32 N4 C18 Ag1 12(2)
C1X Ag1 C18 N3 -73(12)
C1 Ag1 C18 N3 -106(5)
C18X Ag1 C18 N3 -44(34)
C1X Ag1 C18 N4 97(11)
C1 Ag1 C18 N4 65(6)
C18X Ag1 C18 N4 127(35)
C18 N4 C19 C24 -1.4(17)
C32 N4 C19 C24 175.7(14)
C18 N4 C19 C20 -177.9(14)
C32 N4 C19 C20 -1(3)
C24 C19 C20 C21 1.9(19)
N4 C19 C20 C21 177.9(13)
C19 C20 C21 C22 0.0(17)
C20 C21 C22 C23 -1(2)
C21 C22 C23 C24 0.7(19)
C18 N3 C24 C19 -0.9(16)
C25 N3 C24 C19 178.7(16)
C18 N3 C24 C23 179.7(15)
C25 N3 C24 C23 -1(3)
N4 C19 C24 N3 1.4(17)
C20 C19 C24 N3 178.0(13)
N4 C19 C24 C23 -179.1(12)
C20 C19 C24 C23 -3(2)
C22 C23 C24 N3 -179.6(14)
C22 C23 C24 C19 1(2)
C18 N4 C32 C33 -104(2)
C19 N4 C32 C33 79(2)
N4 C32 C33 C34 5(4)
C1 N1 C8 C9 -112(4)
C7 N1 C8 C9 63(5)
N1 C8 C9 C10 -163(5)
N1 C8 C9 C14 43(7)
C14 C9 C10 C11 -24(9)
C8 C9 C10 C11 -174(4)
C9 C10 C11 C12 10(6)
C10 C11 C12 C13 0(6)
C11 C12 C13 C14 4(5)
C12 C13 C14 C9 -17(5)
C10 C9 C14 C13 29(8)
C8 C9 C14 C13 -177(3)
C18 N3 C25 C26 111(3)
C24 N3 C25 C26 -68(3)
N3 C25 C26 C31 142(5)
N3 C25 C26 C27 -37(5)
C31 C26 C27 C28 2(6)
C25 C26 C27 C28 -179(3)
C30 C29 C28 C27 2(4)
C26 C27 C28 C29 -2(4)
C28 C29 C30 C31 -3(4)
C25 C26 C31 C30 178(4)
C27 C26 C31 C30 -3(6)
C29 C30 C31 C26 3(5)
