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#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/28/1512850.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1512850
loop_
_publ_author_name
'Pallab Bhowmik'
'Shouvik Chattopadhyay'
'Michael G.B. Drew'
'Ashutosh Ghosh'
_publ_section_title
;
 A polynuclear helical and two dinuclear copper(II) complexes of a
 monocondensed N,N,O donor Schiff base with pseudohalides as co-ligand
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              24
_journal_page_last               32
_journal_paper_doi               10.1016/j.ica.2012.10.020
_journal_volume                  395
_journal_year                    2013
_chemical_formula_sum            'C14 H19 Cu N5 O2'
_chemical_formula_weight         352.88
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 103.855(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   16.8018(17)
_cell_length_b                   10.7634(12)
_cell_length_c                   17.9184(16)
_cell_measurement_reflns_used    18996
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.00
_cell_measurement_theta_min      2.50
_cell_volume                     3146.2(6)
_computing_cell_refinement       'Crysalis, Oxford Diffraction'
_computing_data_collection       'Crysalis, Oxford Diffraction'
_computing_data_reduction        'Crysalis, Oxford Diffraction'
_computing_molecular_graphics    PLATON(Spek,2004)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device       'Oxford Diffaction X-Calibur System'
_diffrn_measurement_method       '321 frames, counting time 10 s.'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1235
_diffrn_reflns_av_sigmaI/netI    0.2208
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            18996
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.00
_diffrn_reflns_theta_min         2.50
_exptl_absorpt_coefficient_mu    1.403
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.877
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'ABSPACK, Oxford Diffraction Ltd'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.490
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1464
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.627
_refine_diff_density_min         -0.835
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         8963
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.2275
_refine_ls_R_factor_gt           0.1009
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
_refine_ls_weighting_details 
  w=1/[σ²(Fo²)+(0.0209P)²+0.0000P] where P=(Fo²+2Fc²)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1301
_refine_ls_wR_factor_ref         0.1703
_reflns_number_gt                4045
_reflns_number_total             8963
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2013-395-24-32-3.cif
_cod_data_source_block           3
_cod_original_cell_volume        3146.1(6)
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               1512850
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.41885(5) 0.57917(7) 0.20710(5) 0.0194(2) Uani 1 1 d .
O11 O 0.4585(3) 0.6408(5) 0.3087(2) 0.0310(13) Uani 1 1 d .
C12 C 0.5265(4) 0.7047(6) 0.3346(3) 0.0164(15) Uani 1 1 d .
C13 C 0.5554(5) 0.7119(7) 0.4161(4) 0.030(2) Uani 1 1 d .
H13 H 0.5250 0.6754 0.4473 0.037 Uiso 1 1 calc R
C14 C 0.6267(5) 0.7710(8) 0.4488(4) 0.039(2) Uani 1 1 d .
H14 H 0.6448 0.7727 0.5021 0.047 Uiso 1 1 calc R
C15 C 0.6729(5) 0.8291(8) 0.4041(5) 0.049(3) Uani 1 1 d .
H15 H 0.7215 0.8698 0.4268 0.059 Uiso 1 1 calc R
C16 C 0.6450(5) 0.8247(7) 0.3254(4) 0.041(2) Uani 1 1 d .
H16 H 0.6754 0.8634 0.2949 0.050 Uiso 1 1 calc R
C17 C 0.5705(4) 0.7619(6) 0.2889(4) 0.0238(16) Uani 1 1 d .
C18 C 0.5454(4) 0.7676(6) 0.2034(4) 0.0210(16) Uani 1 1 d .
C181 C 0.5946(5) 0.8513(7) 0.1635(4) 0.036(2) Uani 1 1 d .
H18A H 0.5644 0.8657 0.1115 0.054 Uiso 1 1 calc R
H18B H 0.6458 0.8121 0.1632 0.054 Uiso 1 1 calc R
H18C H 0.6047 0.9290 0.1903 0.054 Uiso 1 1 calc R
N19 N 0.4829(3) 0.7035(5) 0.1653(3) 0.0202(13) Uani 1 1 d .
C20 C 0.4605(4) 0.7075(7) 0.0810(3) 0.0277(19) Uani 1 1 d .
H20A H 0.5050 0.6747 0.0611 0.033 Uiso 1 1 calc R
H20B H 0.4507 0.7927 0.0637 0.033 Uiso 1 1 calc R
C21 C 0.3840(4) 0.6310(6) 0.0514(4) 0.0221(16) Uani 1 1 d .
H21A H 0.3362 0.6786 0.0556 0.027 Uiso 1 1 calc R
H21B H 0.3788 0.6113 -0.0023 0.027 Uiso 1 1 calc R
N22 N 0.3881(3) 0.5151(5) 0.0962(3) 0.0185(13) Uani 1 1 d .
C23 C 0.4515(4) 0.4303(7) 0.0833(4) 0.0298(19) Uani 1 1 d .
H23A H 0.5032 0.4728 0.0936 0.045 Uiso 1 1 calc R
H23B H 0.4375 0.4025 0.0309 0.045 Uiso 1 1 calc R
H23C H 0.4553 0.3601 0.1170 0.045 Uiso 1 1 calc R
C24 C 0.3087(4) 0.4471(7) 0.0737(4) 0.033(2) Uani 1 1 d .
H24A H 0.2972 0.4271 0.0199 0.049 Uiso 1 1 calc R
H24B H 0.2655 0.4985 0.0834 0.049 Uiso 1 1 calc R
H24C H 0.3121 0.3720 0.1031 0.049 Uiso 1 1 calc R
N1 N 0.2930(4) 0.6629(6) 0.1937(3) 0.0318(16) Uani 1 1 d .
C2 C 0.2327(5) 0.7199(7) 0.1837(4) 0.0252(18) Uani 1 1 d .
N3 N 0.1620(3) 0.7772(6) 0.1665(3) 0.0282(15) Uani 1 1 d .
C4 C 0.1396(4) 0.8523(7) 0.2149(4) 0.0215(16) Uani 1 1 d .
N5 N 0.1096(3) 0.9167(6) 0.2517(3) 0.0247(14) Uani 1 1 d .
Cu2 Cu 0.57679(5) 0.23124(8) 0.29218(5) 0.0215(2) Uani 1 1 d .
O31 O 0.5358(3) 0.1707(5) 0.1908(2) 0.0293(13) Uani 1 1 d .
C32 C 0.4677(5) 0.1067(7) 0.1643(4) 0.0284(19) Uani 1 1 d .
C33 C 0.4413(5) 0.0907(7) 0.0841(4) 0.031(2) Uani 1 1 d .
H33 H 0.4721 0.1262 0.0529 0.038 Uiso 1 1 calc R
C34 C 0.3727(5) 0.0253(7) 0.0503(5) 0.039(2) Uani 1 1 d .
H34 H 0.3572 0.0177 -0.0029 0.047 Uiso 1 1 calc R
C35 C 0.3258(5) -0.0300(8) 0.0953(5) 0.048(3) Uani 1 1 d .
H35 H 0.2783 -0.0732 0.0725 0.057 Uiso 1 1 calc R
C36 C 0.3508(5) -0.0200(7) 0.1748(4) 0.036(2) Uani 1 1 d .
H36 H 0.3185 -0.0552 0.2047 0.043 Uiso 1 1 calc R
C37 C 0.4239(4) 0.0423(7) 0.2115(4) 0.0254(16) Uani 1 1 d .
C38 C 0.4483(4) 0.0441(7) 0.2970(4) 0.0263(18) Uani 1 1 d .
C381 C 0.4008(5) -0.0365(7) 0.3387(4) 0.039(2) Uani 1 1 d .
H38A H 0.4283 -0.0400 0.3922 0.058 Uiso 1 1 calc R
H38B H 0.3966 -0.1188 0.3174 0.058 Uiso 1 1 calc R
H38C H 0.3468 -0.0026 0.3333 0.058 Uiso 1 1 calc R
N39 N 0.5116(3) 0.1073(5) 0.3334(3) 0.0185(13) Uani 1 1 d .
C40 C 0.5342(4) 0.1035(6) 0.4184(4) 0.0237(17) Uani 1 1 d .
H40A H 0.5421 0.0180 0.4358 0.028 Uiso 1 1 calc R
H40B H 0.4906 0.1392 0.4385 0.028 Uiso 1 1 calc R
C41 C 0.6125(4) 0.1764(7) 0.4471(4) 0.030(2) Uani 1 1 d .
H41A H 0.6189 0.1962 0.5010 0.036 Uiso 1 1 calc R
H41B H 0.6589 0.1259 0.4424 0.036 Uiso 1 1 calc R
N42 N 0.6116(3) 0.2930(6) 0.4027(3) 0.0241(14) Uani 1 1 d .
C43 C 0.5493(4) 0.3801(7) 0.4171(4) 0.0300(19) Uani 1 1 d .
H43A H 0.5643 0.4071 0.4697 0.045 Uiso 1 1 calc R
H43B H 0.4970 0.3392 0.4073 0.045 Uiso 1 1 calc R
H43C H 0.5459 0.4507 0.3837 0.045 Uiso 1 1 calc R
C44 C 0.6926(4) 0.3530(8) 0.4248(4) 0.036(2) Uani 1 1 d .
H44A H 0.6919 0.4279 0.3956 0.055 Uiso 1 1 calc R
H44B H 0.7334 0.2975 0.4146 0.055 Uiso 1 1 calc R
H44C H 0.7051 0.3726 0.4786 0.055 Uiso 1 1 calc R
N6 N 0.7034(4) 0.1389(7) 0.3036(4) 0.043(2) Uani 1 1 d .
C7 C 0.7652(5) 0.0868(7) 0.3137(4) 0.0286(18) Uani 1 1 d .
N8 N 0.8373(4) 0.0330(6) 0.3334(3) 0.0312(16) Uani 1 1 d .
C9 C 0.8618(4) -0.0424(7) 0.2861(4) 0.0240(17) Uani 1 1 d .
N10 N 0.8903(4) -0.1080(6) 0.2493(3) 0.0314(16) Uani 1 1 d .
O1 O 0.6478(5) 0.1783(9) 0.0982(3) 0.079(2) Uani 1 1 d D
H1A H 0.6996(18) 0.162(10) 0.120(4) 0.095 Uiso 1 1 d D
H1B H 0.622(4) 0.177(9) 0.134(3) 0.095 Uiso 1 1 d D
O2 O 0.3349(5) 0.6620(9) 0.3872(4) 0.086(3) Uani 1 1 d D
H2A H 0.370(4) 0.630(9) 0.365(5) 0.103 Uiso 1 1 d D
H2B H 0.286(2) 0.635(9) 0.366(5) 0.103 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Cu1 N19 91.7(2) . .
O11 Cu1 N5 90.6(2) . 2_545
N19 Cu1 N5 158.9(2) . 2_545
O11 Cu1 N22 174.1(2) . .
N19 Cu1 N22 83.9(2) . .
N5 Cu1 N22 92.1(2) 2_545 .
O11 Cu1 N1 93.8(2) . .
N19 Cu1 N1 105.7(2) . .
N5 Cu1 N1 95.0(2) 2_545 .
N22 Cu1 N1 91.0(2) . .
C12 O11 Cu1 126.4(4) . .
O11 C12 C17 124.7(6) . .
O11 C12 C13 116.2(6) . .
C17 C12 C13 119.1(6) . .
C14 C13 C12 121.1(7) . .
C14 C13 H13 119.5 . .
C12 C13 H13 119.5 . .
C13 C14 C15 121.2(7) . .
C13 C14 H14 119.4 . .
C15 C14 H14 119.4 . .
C16 C15 C14 118.4(7) . .
C16 C15 H15 120.8 . .
C14 C15 H15 120.8 . .
C15 C16 C17 121.9(8) . .
C15 C16 H16 119.1 . .
C17 C16 H16 119.1 . .
C12 C17 C16 118.4(6) . .
C12 C17 C18 124.9(6) . .
C16 C17 C18 116.7(7) . .
N19 C18 C17 120.7(6) . .
N19 C18 C181 122.0(6) . .
C17 C18 C181 117.3(6) . .
C18 C181 H18A 109.5 . .
C18 C181 H18B 109.5 . .
H18A C181 H18B 109.5 . .
C18 C181 H18C 109.5 . .
H18A C181 H18C 109.5 . .
H18B C181 H18C 109.5 . .
C18 N19 C20 119.9(6) . .
C18 N19 Cu1 127.2(5) . .
C20 N19 Cu1 112.5(4) . .
N19 C20 C21 109.4(6) . .
N19 C20 H20A 109.8 . .
C21 C20 H20A 109.8 . .
N19 C20 H20B 109.8 . .
C21 C20 H20B 109.8 . .
H20A C20 H20B 108.2 . .
N22 C21 C20 110.2(5) . .
N22 C21 H21A 109.6 . .
C20 C21 H21A 109.6 . .
N22 C21 H21B 109.6 . .
C20 C21 H21B 109.6 . .
H21A C21 H21B 108.1 . .
C23 N22 C21 112.5(6) . .
C23 N22 C24 106.8(5) . .
C21 N22 C24 110.3(5) . .
C23 N22 Cu1 109.8(4) . .
C21 N22 Cu1 102.2(4) . .
C24 N22 Cu1 115.4(4) . .
N22 C23 H23A 109.5 . .
N22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
N22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N22 C24 H24A 109.5 . .
N22 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
N22 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C2 N1 Cu1 171.0(6) . .
N1 C2 N3 174.3(8) . .
C4 N3 C2 121.7(6) . .
N5 C4 N3 171.0(7) . .
C4 N5 Cu1 156.0(6) . 2
O31 Cu2 N39 91.1(2) . .
O31 Cu2 N10 90.6(2) . 2_655
N39 Cu2 N10 160.7(2) . 2_655
O31 Cu2 N42 175.3(2) . .
N39 Cu2 N42 85.0(2) . .
N10 Cu2 N42 92.2(2) 2_655 .
O31 Cu2 N6 93.0(2) . .
N39 Cu2 N6 104.9(2) . .
N10 Cu2 N6 94.2(3) 2_655 .
N42 Cu2 N6 90.6(2) . .
C32 O31 Cu2 127.4(5) . .
O31 C32 C33 117.6(8) . .
O31 C32 C37 124.4(6) . .
C33 C32 C37 117.6(7) . .
C34 C33 C32 122.9(8) . .
C34 C33 H33 118.6 . .
C32 C33 H33 118.6 . .
C33 C34 C35 120.0(8) . .
C33 C34 H34 120.0 . .
C35 C34 H34 120.0 . .
C34 C35 C36 119.2(8) . .
C34 C35 H35 120.4 . .
C36 C35 H35 120.4 . .
C35 C36 C37 121.9(8) . .
C35 C36 H36 119.0 . .
C37 C36 H36 119.0 . .
C36 C37 C32 117.9(7) . .
C36 C37 C38 118.7(7) . .
C32 C37 C38 123.3(6) . .
N39 C38 C37 121.0(7) . .
N39 C38 C381 121.7(7) . .
C37 C38 C381 117.2(6) . .
C38 C381 H38A 109.5 . .
C38 C381 H38B 109.5 . .
H38A C381 H38B 109.5 . .
C38 C381 H38C 109.5 . .
H38A C381 H38C 109.5 . .
H38B C381 H38C 109.5 . .
C38 N39 C40 118.6(6) . .
C38 N39 Cu2 128.8(5) . .
C40 N39 Cu2 112.0(4) . .
N39 C40 C41 108.8(5) . .
N39 C40 H40A 109.9 . .
C41 C40 H40A 109.9 . .
N39 C40 H40B 109.9 . .
C41 C40 H40B 109.9 . .
H40A C40 H40B 108.3 . .
N42 C41 C40 111.1(5) . .
N42 C41 H41A 109.4 . .
C40 C41 H41A 109.4 . .
N42 C41 H41B 109.4 . .
C40 C41 H41B 109.4 . .
H41A C41 H41B 108.0 . .
C43 N42 C44 108.9(6) . .
C43 N42 C41 111.1(6) . .
C44 N42 C41 109.7(5) . .
C43 N42 Cu2 109.1(4) . .
C44 N42 Cu2 115.9(4) . .
C41 N42 Cu2 102.0(4) . .
N42 C43 H43A 109.5 . .
N42 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
N42 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
N42 C44 H44A 109.5 . .
N42 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
N42 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C7 N6 Cu2 174.6(7) . .
N6 C7 N8 173.3(8) . .
C7 N8 C9 120.8(6) . .
N10 C9 N8 173.6(7) . .
C9 N10 Cu2 158.7(7) . 2_645
H1A O1 H1B 107(3) . .
H2A O2 H2B 110(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O11 1.902(4) .
Cu1 N19 1.973(6) .
Cu1 N5 2.000(6) 2_545
Cu1 N22 2.050(5) .
Cu1 N1 2.258(6) .
O11 C12 1.320(7) .
C12 C17 1.372(9) .
C12 C13 1.426(8) .
C13 C14 1.358(10) .
C13 H13 0.9300 .
C14 C15 1.391(11) .
C14 H14 0.9300 .
C15 C16 1.377(9) .
C15 H15 0.9300 .
C16 C17 1.435(9) .
C16 H16 0.9300 .
C17 C18 1.490(8) .
C18 N19 1.305(8) .
C18 C181 1.512(9) .
C181 H18A 0.9600 .
C181 H18B 0.9600 .
C181 H18C 0.9600 .
N19 C20 1.467(7) .
C20 C21 1.511(9) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 N22 1.476(8) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
N22 C23 1.462(8) .
N22 C24 1.491(8) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
N1 C2 1.161(9) .
C2 N3 1.308(9) .
N3 C4 1.306(8) .
C4 N5 1.152(8) .
N5 Cu1 2.000(6) 2
Cu2 O31 1.898(4) .
Cu2 N39 1.977(5) .
Cu2 N10 2.012(6) 2_655
Cu2 N42 2.038(5) .
Cu2 N6 2.312(7) .
O31 C32 1.323(8) .
C32 C33 1.409(9) .
C32 C37 1.427(10) .
C33 C34 1.363(10) .
C33 H33 0.9300 .
C34 C35 1.389(11) .
C34 H34 0.9300 .
C35 C36 1.388(10) .
C35 H35 0.9300 .
C36 C37 1.415(9) .
C36 H36 0.9300 .
C37 C38 1.489(9) .
C38 N39 1.298(8) .
C38 C381 1.496(10) .
C381 H38A 0.9600 .
C381 H38B 0.9600 .
C381 H38C 0.9600 .
N39 C40 1.479(7) .
C40 C41 1.513(9) .
C40 H40A 0.9700 .
C40 H40B 0.9700 .
C41 N42 1.484(8) .
C41 H41A 0.9700 .
C41 H41B 0.9700 .
N42 C43 1.474(9) .
N42 C44 1.471(8) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
N6 C7 1.156(9) .
C7 N8 1.313(9) .
N8 C9 1.310(9) .
C9 N10 1.146(9) .
N10 Cu2 2.012(6) 2_645
O1 H1A 0.88(2) .
O1 H1B 0.86(2) .
O2 H2A 0.85(2) .
O2 H2B 0.86(2) .
