#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/58/1515836.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1515836
loop_
_publ_author_name
'Núñez Magro, A. Alberto'
'Robb, Lynzi-Marie'
'Pogorzelec, Peter J.'
'Slawin, Alexandra M. Z.'
'Eastham, Graham R.'
'Cole-Hamilton, David J.'
_publ_section_title
;
 Highly selective formation of unsaturated esters or cascade reactions to
 α,ω-diesters by the methoxycarbonylation of alkynes catalysed by
 palladium complexes of 1,2-bis(ditertbutylphosphinomethyl)benzene
;
_journal_issue                   6
_journal_name_full               'Chemical Science'
_journal_page_first              723
_journal_paper_doi               10.1039/c0sc00276c
_journal_volume                  1
_journal_year                    2010
_chemical_formula_moiety         'C24 H44 Cl2 P2 Pd'
_chemical_formula_sum            'C24 H44 Cl2 P2 Pd'
_chemical_formula_weight         571.83
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.766(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.1553(15)
_cell_length_b                   19.646(3)
_cell_length_c                   15.159(3)
_cell_measurement_reflns_used    7217
_cell_measurement_temperature    93(2)
_cell_measurement_theta_max      28.6648
_cell_measurement_theta_min      1.7196
_cell_volume                     2669.3(8)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2004)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2004)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2004)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      93(2)
_diffrn_measured_fraction_theta_full 0.891
_diffrn_measured_fraction_theta_max 0.886
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0241
_diffrn_reflns_av_sigmaI/netI    0.0305
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            14255
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.34
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    1.025
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8170
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.423
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1192
_exptl_crystal_size_max          0.1000
_exptl_crystal_size_mid          0.1000
_exptl_crystal_size_min          0.0700
_refine_diff_density_max         0.785
_refine_diff_density_min         -0.633
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     263
_refine_ls_number_reflns         4316
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0354
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0339P)²+2.5154P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0710
_refine_ls_wR_factor_ref         0.0738
_reflns_number_gt                3889
_reflns_number_total             4316
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0sc00276c.txt
_cod_data_source_block           PdBDTBPMBCl2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               1515836
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.70096(2) 0.234949(10) 0.016154(15) 0.01203(9) Uani 1 1 d .
Cl1 Cl 0.63122(8) 0.30121(3) -0.11595(5) 0.01838(16) Uani 1 1 d .
Cl2 Cl 0.61022(8) 0.14382(3) -0.08113(5) 0.01992(17) Uani 1 1 d .
P1 P 0.81697(8) 0.15605(3) 0.12015(5) 0.01256(17) Uani 1 1 d .
C1 C 0.8881(3) 0.18291(13) 0.23780(19) 0.0165(6) Uani 1 1 d .
H1A H 0.7998 0.1954 0.2627 0.020 Uiso 1 1 calc R
H1B H 0.9317 0.1419 0.2710 0.020 Uiso 1 1 calc R
C2 C 0.9999(3) 0.23920(13) 0.2637(2) 0.0151(6) Uani 1 1 d .
C3 C 0.9585(3) 0.30813(13) 0.25718(19) 0.0142(6) Uani 1 1 d .
C4 C 0.7976(3) 0.32879(13) 0.22527(19) 0.0162(6) Uani 1 1 d .
H4A H 0.7860 0.3743 0.2509 0.019 Uiso 1 1 calc R
H4B H 0.7365 0.2969 0.2531 0.019 Uiso 1 1 calc R
P4 P 0.71239(8) 0.33303(3) 0.10357(5) 0.01273(17) Uani 1 1 d .
C5 C 1.1465(3) 0.22210(14) 0.3037(2) 0.0190(7) Uani 1 1 d .
H5A H 1.1735 0.1754 0.3106 0.023 Uiso 1 1 calc R
C6 C 1.2537(3) 0.27107(14) 0.3337(2) 0.0202(7) Uani 1 1 d .
H6A H 1.3538 0.2582 0.3580 0.024 Uiso 1 1 calc R
C7 C 1.2131(3) 0.33929(15) 0.3278(2) 0.0195(7) Uani 1 1 d .
H7A H 1.2850 0.3737 0.3482 0.023 Uiso 1 1 calc R
C8 C 1.0667(3) 0.35655(14) 0.2919(2) 0.0181(6) Uani 1 1 d .
H8A H 1.0385 0.4031 0.2907 0.022 Uiso 1 1 calc R
C9 C 0.6967(3) 0.08018(14) 0.1422(2) 0.0176(6) Uani 1 1 d .
C10 C 0.5382(3) 0.10735(15) 0.1367(2) 0.0236(7) Uani 1 1 d .
H10A H 0.4729 0.0701 0.1476 0.035 Uiso 1 1 calc R
H10B H 0.5006 0.1265 0.0767 0.035 Uiso 1 1 calc R
H10C H 0.5396 0.1428 0.1823 0.035 Uiso 1 1 calc R
C11 C 0.6925(3) 0.02167(14) 0.0744(2) 0.0218(7) Uani 1 1 d .
H11A H 0.6297 -0.0152 0.0894 0.033 Uiso 1 1 calc R
H11B H 0.7939 0.0046 0.0770 0.033 Uiso 1 1 calc R
H11C H 0.6511 0.0383 0.0134 0.033 Uiso 1 1 calc R
C12 C 0.7497(3) 0.04876(14) 0.2367(2) 0.0225(7) Uani 1 1 d .
H12A H 0.6849 0.0104 0.2443 0.034 Uiso 1 1 calc R
H12B H 0.7452 0.0833 0.2827 0.034 Uiso 1 1 calc R
H12C H 0.8526 0.0326 0.2430 0.034 Uiso 1 1 calc R
C13 C 0.9901(3) 0.12817(14) 0.0790(2) 0.0175(6) Uani 1 1 d .
C14 C 0.9564(3) 0.09535(15) -0.0142(2) 0.0229(7) Uani 1 1 d .
H14A H 1.0500 0.0821 -0.0313 0.034 Uiso 1 1 calc R
H14B H 0.9033 0.1280 -0.0583 0.034 Uiso 1 1 calc R
H14C H 0.8941 0.0549 -0.0130 0.034 Uiso 1 1 calc R
C15 C 1.0832(3) 0.07740(15) 0.1452(2) 0.0229(7) Uani 1 1 d .
H15A H 1.1716 0.0638 0.1223 0.034 Uiso 1 1 calc R
H15B H 1.0228 0.0371 0.1509 0.034 Uiso 1 1 calc R
H15C H 1.1145 0.0990 0.2042 0.034 Uiso 1 1 calc R
C16 C 1.0820(3) 0.19232(15) 0.0704(2) 0.0222(7) Uani 1 1 d .
H16A H 1.1725 0.1796 0.0492 0.033 Uiso 1 1 calc R
H16B H 1.1096 0.2146 0.1292 0.033 Uiso 1 1 calc R
H16C H 1.0224 0.2237 0.0271 0.033 Uiso 1 1 calc R
C17 C 0.8062(3) 0.41022(14) 0.0617(2) 0.0198(7) Uani 1 1 d .
C18 C 0.9422(3) 0.38256(15) 0.0289(2) 0.0279(8) Uani 1 1 d .
H18A H 0.9948 0.4202 0.0066 0.042 Uiso 1 1 calc R
H18B H 0.9094 0.3498 -0.0199 0.042 Uiso 1 1 calc R
H18C H 1.0095 0.3600 0.0789 0.042 Uiso 1 1 calc R
C19 C 0.8588(4) 0.46323(15) 0.1355(2) 0.0294(8) Uani 1 1 d .
H19A H 0.9059 0.5014 0.1104 0.044 Uiso 1 1 calc R
H19B H 0.9311 0.4423 0.1847 0.044 Uiso 1 1 calc R
H19C H 0.7730 0.4799 0.1587 0.044 Uiso 1 1 calc R
C20 C 0.7039(3) 0.44907(14) -0.0150(2) 0.0241(7) Uani 1 1 d .
H20A H 0.7583 0.4878 -0.0333 0.036 Uiso 1 1 calc R
H20B H 0.6159 0.4656 0.0060 0.036 Uiso 1 1 calc R
H20C H 0.6723 0.4185 -0.0665 0.036 Uiso 1 1 calc R
C21 C 0.5117(3) 0.35221(14) 0.1106(2) 0.0172(6) Uani 1 1 d .
C22 C 0.4972(3) 0.41637(15) 0.1666(2) 0.0239(7) Uani 1 1 d .
H22A H 0.3919 0.4238 0.1683 0.036 Uiso 1 1 calc R
H22B H 0.5356 0.4558 0.1390 0.036 Uiso 1 1 calc R
H22C H 0.5546 0.4102 0.2281 0.036 Uiso 1 1 calc R
C23 C 0.4089(3) 0.35955(15) 0.0173(2) 0.0206(7) Uani 1 1 d .
H23A H 0.3071 0.3693 0.0245 0.031 Uiso 1 1 calc R
H23B H 0.4096 0.3171 -0.0165 0.031 Uiso 1 1 calc R
H23C H 0.4446 0.3969 -0.0156 0.031 Uiso 1 1 calc R
C24 C 0.4536(3) 0.29119(15) 0.1564(2) 0.0247(7) Uani 1 1 d .
H24A H 0.3500 0.2995 0.1613 0.037 Uiso 1 1 calc R
H24B H 0.5153 0.2849 0.2168 0.037 Uiso 1 1 calc R
H24C H 0.4584 0.2501 0.1205 0.037 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
P1 Pd1 P4 101.88(3)
P1 Pd1 Cl2 88.38(3)
P4 Pd1 Cl2 162.26(3)
P1 Pd1 Cl1 162.72(3)
P4 Pd1 Cl1 89.97(3)
Cl2 Pd1 Cl1 83.60(3)
C1 P1 C13 104.23(13)
C1 P1 C9 98.95(13)
C13 P1 C9 112.30(12)
C1 P1 Pd1 119.34(9)
C13 P1 Pd1 105.55(10)
C9 P1 Pd1 116.04(9)
C2 C1 P1 123.3(2)
C2 C1 H1A 106.5
P1 C1 H1A 106.5
C2 C1 H1B 106.5
P1 C1 H1B 106.5
H1A C1 H1B 106.5
C5 C2 C3 118.9(3)
C5 C2 C1 118.6(2)
C3 C2 C1 122.1(2)
C8 C3 C2 118.1(3)
C8 C3 C4 120.5(2)
C2 C3 C4 120.9(2)
C3 C4 P4 121.1(2)
C3 C4 H4A 107.0
P4 C4 H4A 107.0
C3 C4 H4B 107.0
P4 C4 H4B 107.0
H4A C4 H4B 106.8
C4 P4 C21 99.71(13)
C4 P4 C17 103.85(13)
C21 P4 C17 111.48(12)
C4 P4 Pd1 119.37(9)
C21 P4 Pd1 105.33(9)
C17 P4 Pd1 115.97(10)
C6 C5 C2 122.0(3)
C6 C5 H5A 119.0
C2 C5 H5A 119.0
C5 C6 C7 119.2(3)
C5 C6 H6A 120.4
C7 C6 H6A 120.4
C8 C7 C6 119.2(3)
C8 C7 H7A 120.4
C6 C7 H7A 120.4
C7 C8 C3 122.5(3)
C7 C8 H8A 118.7
C3 C8 H8A 118.7
C10 C9 C11 109.2(2)
C10 C9 C12 107.7(2)
C11 C9 C12 106.4(2)
C10 C9 P1 106.88(18)
C11 C9 P1 113.6(2)
C12 C9 P1 112.85(19)
C9 C10 H10A 109.5
C9 C10 H10B 109.5
H10A C10 H10B 109.5
C9 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
C9 C11 H11A 109.5
C9 C11 H11B 109.5
H11A C11 H11B 109.5
C9 C11 H11C 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
C9 C12 H12A 109.5
C9 C12 H12B 109.5
H12A C12 H12B 109.5
C9 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C14 C13 C16 106.1(2)
C14 C13 C15 108.0(2)
C16 C13 C15 110.3(2)
C14 C13 P1 113.6(2)
C16 C13 P1 107.45(19)
C15 C13 P1 111.2(2)
C13 C14 H14A 109.5
C13 C14 H14B 109.5
H14A C14 H14B 109.5
C13 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C13 C15 H15A 109.5
C13 C15 H15B 109.5
H15A C15 H15B 109.5
C13 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C13 C16 H16A 109.5
C13 C16 H16B 109.5
H16A C16 H16B 109.5
C13 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C18 C17 C19 108.9(2)
C18 C17 C20 109.9(3)
C19 C17 C20 105.5(2)
C18 C17 P4 106.03(18)
C19 C17 P4 113.1(2)
C20 C17 P4 113.47(19)
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C17 C19 H19A 109.5
C17 C19 H19B 109.5
H19A C19 H19B 109.5
C17 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C17 C20 H20A 109.5
C17 C20 H20B 109.5
H20A C20 H20B 109.5
C17 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C24 C21 C23 106.6(2)
C24 C21 C22 108.3(2)
C23 C21 C22 108.9(2)
C24 C21 P4 107.40(19)
C23 C21 P4 112.6(2)
C22 C21 P4 112.7(2)
C21 C22 H22A 109.5
C21 C22 H22B 109.5
H22A C22 H22B 109.5
C21 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C21 C23 H23A 109.5
C21 C23 H23B 109.5
H23A C23 H23B 109.5
C21 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C21 C24 H24A 109.5
C21 C24 H24B 109.5
H24A C24 H24B 109.5
C21 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pd1 P1 2.3094(8)
Pd1 P4 2.3288(8)
Pd1 Cl2 2.3602(7)
Pd1 Cl1 2.3645(8)
P1 C1 1.847(3)
P1 C13 1.898(3)
P1 C9 1.922(3)
C1 C2 1.503(4)
C1 H1A 0.9900
C1 H1B 0.9900
C2 C5 1.397(4)
C2 C3 1.404(4)
C3 C8 1.396(4)
C3 C4 1.509(4)
C4 P4 1.853(3)
C4 H4A 0.9900
C4 H4B 0.9900
P4 C21 1.900(3)
P4 C17 1.914(3)
C5 C6 1.383(4)
C5 H5A 0.9500
C6 C7 1.389(4)
C6 H6A 0.9500
C7 C8 1.382(4)
C7 H7A 0.9500
C8 H8A 0.9500
C9 C10 1.533(4)
C9 C11 1.537(4)
C9 C12 1.545(4)
C10 H10A 0.9800
C10 H10B 0.9800
C10 H10C 0.9800
C11 H11A 0.9800
C11 H11B 0.9800
C11 H11C 0.9800
C12 H12A 0.9800
C12 H12B 0.9800
C12 H12C 0.9800
C13 C14 1.527(4)
C13 C16 1.536(4)
C13 C15 1.542(4)
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
C16 H16A 0.9800
C16 H16B 0.9800
C16 H16C 0.9800
C17 C18 1.532(4)
C17 C19 1.533(4)
C17 C20 1.538(4)
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
C21 C24 1.534(4)
C21 C23 1.538(4)
C21 C22 1.540(4)
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 H23A 0.9800
C23 H23B 0.9800
C23 H23C 0.9800
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
P4 Pd1 P1 C1 -0.22(11)
Cl2 Pd1 P1 C1 -165.61(11)
Cl1 Pd1 P1 C1 132.18(12)
P4 Pd1 P1 C13 -116.91(9)
Cl2 Pd1 P1 C13 77.69(9)
Cl1 Pd1 P1 C13 15.48(14)
P4 Pd1 P1 C9 118.03(10)
Cl2 Pd1 P1 C9 -47.37(10)
Cl1 Pd1 P1 C9 -109.58(13)
C13 P1 C1 C2 59.8(3)
C9 P1 C1 C2 175.7(2)
Pd1 P1 C1 C2 -57.5(3)
P1 C1 C2 C5 -106.3(3)
P1 C1 C2 C3 80.2(3)
C5 C2 C3 C8 -0.4(4)
C1 C2 C3 C8 173.1(3)
C5 C2 C3 C4 -172.3(3)
C1 C2 C3 C4 1.2(4)
C8 C3 C4 P4 106.1(3)
C2 C3 C4 P4 -82.2(3)
C3 C4 P4 C21 174.5(2)
C3 C4 P4 C17 -70.4(2)
C3 C4 P4 Pd1 60.6(2)
P1 Pd1 P4 C4 -1.34(11)
Cl2 Pd1 P4 C4 122.87(13)
Cl1 Pd1 P4 C4 -168.67(10)
P1 Pd1 P4 C21 -112.14(10)
Cl2 Pd1 P4 C21 12.07(14)
Cl1 Pd1 P4 C21 80.53(10)
P1 Pd1 P4 C17 124.09(10)
Cl2 Pd1 P4 C17 -111.70(13)
Cl1 Pd1 P4 C17 -43.24(10)
C3 C2 C5 C6 -2.8(5)
C1 C2 C5 C6 -176.5(3)
C2 C5 C6 C7 3.1(5)
C5 C6 C7 C8 -0.2(5)
C6 C7 C8 C3 -3.0(5)
C2 C3 C8 C7 3.3(4)
C4 C3 C8 C7 175.2(3)
C1 P1 C9 C10 93.1(2)
C13 P1 C9 C10 -157.4(2)
Pd1 P1 C9 C10 -35.9(2)
C1 P1 C9 C11 -146.3(2)
C13 P1 C9 C11 -36.8(2)
Pd1 P1 C9 C11 84.7(2)
C1 P1 C9 C12 -25.1(2)
C13 P1 C9 C12 84.4(2)
Pd1 P1 C9 C12 -154.09(17)
C1 P1 C13 C14 172.9(2)
C9 P1 C13 C14 66.8(2)
Pd1 P1 C13 C14 -60.5(2)
C1 P1 C13 C16 -69.9(2)
C9 P1 C13 C16 -176.1(2)
Pd1 P1 C13 C16 56.6(2)
C1 P1 C13 C15 50.8(2)
C9 P1 C13 C15 -55.3(2)
Pd1 P1 C13 C15 177.35(17)
C4 P4 C17 C18 92.2(2)
C21 P4 C17 C18 -161.3(2)
Pd1 P4 C17 C18 -40.8(2)
C4 P4 C17 C19 -27.0(2)
C21 P4 C17 C19 79.5(2)
Pd1 P4 C17 C19 -159.98(18)
C4 P4 C17 C20 -147.0(2)
C21 P4 C17 C20 -40.5(2)
Pd1 P4 C17 C20 80.0(2)
C4 P4 C21 C24 -63.4(2)
C17 P4 C21 C24 -172.5(2)
Pd1 P4 C21 C24 60.9(2)
C4 P4 C21 C23 179.6(2)
C17 P4 C21 C23 70.4(2)
Pd1 P4 C21 C23 -56.2(2)
C4 P4 C21 C22 55.8(2)
C17 P4 C21 C22 -53.4(2)
Pd1 P4 C21 C22 -179.93(19)
