#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/67/1516790.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1516790
loop_
_publ_author_name
'Veliks, Janis'
'Tseng, Jui-Chang'
'Arias, Karla I.'
'Weisshar, Florian'
'Linden, Anthony'
'Siegel, Jay S.'
_publ_section_title
;
 Linear bilateral extended
 2,2′:6′,2′′-terpyridine ligands, their
 coordination complexes and heterometallic supramolecular networks
;
_journal_issue                   11
_journal_name_full               'Chem. Sci.'
_journal_page_first              4317
_journal_paper_doi               10.1039/C4SC01025F
_journal_volume                  5
_journal_year                    2014
_chemical_formula_moiety
'2(C58 H34 Ag Fe N10 O4 3+), 6(F6 P -), 13(C2 H3 N)'
_chemical_formula_sum            'C142 H107 Ag2 F36 Fe2 N33 O8 P6'
_chemical_formula_weight         3600.82
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             25-Apr-2012
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.590(1)
_cell_angle_beta                 108.832(1)
_cell_angle_gamma                107.228(1)
_cell_formula_units_Z            2
_cell_length_a                   17.3266(2)
_cell_length_b                   21.9786(3)
_cell_length_c                   23.2172(2)
_cell_measurement_reflns_used    39813
_cell_measurement_temperature    160(1)
_cell_measurement_theta_max      27.2714
_cell_measurement_theta_min      2.0233
_cell_volume                     7649.13(18)
_computing_cell_refinement
'CrysAlisPro, Version 1.171.35.21 (Agilent Technologies, 2012)'
_computing_data_collection
'CrysAlisPro, Version 1.171.35.21 (Agilent Technologies, 2012)'
_computing_data_reduction
'CrysAlisPro, Version 1.171.35.21 (Agilent Technologies, 2012)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL97 and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      160(1)
_diffrn_detector                 'Atlas CCD camera on \k goniostat'
_diffrn_detector_area_resol_mean 10.3801
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.904
_diffrn_measurement_device_type
'Oxford Diffraction SuperNova, dual radiation diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_av_sigmaI/netI    0.0360
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            86017
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         27.33
_diffrn_reflns_theta_min         2.03
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.611
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.81071
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
CrysAlisPro, Version 1.171.35.21 (Agilent Technologies, 2012)
;
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.563
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3628
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.10
_platon_squeeze_details          '  see _refine_special_details'
_refine_diff_density_max         5.423
_refine_diff_density_min         -1.514
_refine_diff_density_rms         0.144
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1858
_refine_ls_number_reflns         31245
_refine_ls_number_restraints     7163
_refine_ls_restrained_S_all      1.117
_refine_ls_R_factor_all          0.0904
_refine_ls_R_factor_gt           0.0749
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1380P)²+8.9667P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2149
_refine_ls_wR_factor_ref         0.2252
_reflns_number_gt                23483
_reflns_number_total             31245
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c4sc01025f2.cif
_cod_data_source_block           L32FeAg
_cod_depositor_comments
'Adding full bibliography for 1516783--1516791.cif.'
_cod_original_cell_volume        7649.13(15)
_cod_database_code               1516790
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.07168(2) 0.876551(15) 0.171788(16) 0.02880(11) Uani 1 1 d . . .
Ag2 Ag 2.09824(2) 0.387449(15) 0.662515(17) 0.03052(11) Uani 1 1 d . . .
Fe1 Fe 0.67591(4) 0.26649(3) 0.07026(3) 0.01876(13) Uani 1 1 d . . .
Fe2 Fe 1.70133(4) 0.77885(3) 0.56034(2) 0.01727(13) Uani 1 1 d . . .
O1 O 1.9006(2) 0.63146(14) 0.61512(13) 0.0290(7) Uani 1 1 d . . .
O2 O 1.43735(19) 0.83684(15) 0.40972(13) 0.0257(6) Uani 1 1 d . . .
O3 O 0.8761(2) 0.12100(15) 0.13270(14) 0.0302(7) Uani 1 1 d . . .
O4 O 0.4328(2) 0.33552(15) -0.08708(13) 0.0272(6) Uani 1 1 d . . .
O5 O 0.8864(2) 0.52090(14) 0.11901(15) 0.0329(7) Uani 1 1 d . . .
O6 O 0.4082(2) 0.07935(14) 0.08826(14) 0.0307(7) Uani 1 1 d . . .
O7 O 1.4484(2) 0.59088(14) 0.59061(14) 0.0316(7) Uani 1 1 d . . .
O8 O 1.8984(2) 1.03244(14) 0.59993(15) 0.0290(7) Uani 1 1 d . . .
N1 N 1.7912(2) 0.74890(16) 0.61156(16) 0.0228(7) Uani 1 1 d . . .
N2 N 1.7148(2) 0.82288(15) 0.64161(15) 0.0200(7) Uani 1 1 d . . .
N3 N 1.6106(2) 0.81811(16) 0.53513(15) 0.0200(7) Uani 1 1 d . . .
N4 N 2.0403(3) 0.4655(2) 0.6656(2) 0.0358(9) Uani 1 1 d . . .
N5 N 1.1919(2) 0.88446(18) 0.26521(17) 0.0271(8) Uani 1 1 d . . .
N6 N 0.7610(2) 0.23471(15) 0.12385(15) 0.0207(7) Uani 1 1 d . . .
N7 N 0.6850(2) 0.30996(15) 0.15070(16) 0.0211(7) Uani 1 1 d . . .
N8 N 0.5896(2) 0.30890(16) 0.04262(15) 0.0221(7) Uani 1 1 d . . .
N9 N 1.0309(3) -0.03558(18) 0.18317(18) 0.0286(8) Uani 1 1 d . . .
N10 N 0.2055(2) 0.39232(18) -0.23952(17) 0.0262(8) Uani 1 1 d . . .
N11 N 0.7653(2) 0.34154(17) 0.06330(16) 0.0247(7) Uani 1 1 d . . .
N12 N 0.6724(2) 0.22641(16) -0.00928(16) 0.0213(7) Uani 1 1 d . . .
N13 N 0.5797(2) 0.18090(16) 0.04880(15) 0.0220(7) Uani 1 1 d . . .
N14 N 1.0100(3) 0.76471(18) 0.13771(18) 0.0337(9) Uani 1 1 d . . .
N15 N 0.1630(3) -0.08944(19) 0.11276(18) 0.0326(9) Uani 1 1 d . . .
N16 N 1.6080(2) 0.69192(16) 0.54245(16) 0.0231(7) Uani 1 1 d . . .
N17 N 1.6910(2) 0.73797(15) 0.47848(15) 0.0200(7) Uani 1 1 d . . .
N18 N 1.7861(2) 0.85460(15) 0.55043(15) 0.0195(7) Uani 1 1 d . . .
N19 N 1.1975(3) 0.42545(18) 0.61309(19) 0.0337(9) Uani 1 1 d . . .
N20 N 2.0340(3) 1.27512(18) 0.62512(18) 0.0320(9) Uani 1 1 d . . .
C1 C 1.8200(3) 0.70411(19) 0.58862(19) 0.0243(9) Uani 1 1 d . . .
H1 H 1.8051 0.6886 0.5443 0.029 Uiso 1 1 calc R . .
C2 C 1.8718(3) 0.6810(2) 0.6310(2) 0.0264(9) Uani 1 1 d . . .
C3 C 1.9457(3) 0.6231(2) 0.6725(2) 0.0315(10) Uani 1 1 d . . .
C4 C 1.9457(3) 0.6642(2) 0.7223(2) 0.0322(10) Uani 1 1 d . . .
H4 H 1.9721 0.6669 0.7659 0.039 Uiso 1 1 calc R . .
C5 C 1.8978(3) 0.7030(2) 0.6963(2) 0.0267(9) Uani 1 1 d . . .
C6 C 1.8687(3) 0.7509(2) 0.7196(2) 0.0276(9) Uani 1 1 d . . .
H6 H 1.8850 0.7683 0.7639 0.033 Uiso 1 1 calc R . .
C7 C 1.8157(3) 0.77190(19) 0.67598(18) 0.0220(8) Uani 1 1 d . . .
C8 C 1.7747(3) 0.81810(19) 0.69370(19) 0.0225(8) Uani 1 1 d . . .
C9 C 1.7904(3) 0.8533(2) 0.7542(2) 0.0298(10) Uani 1 1 d . . .
H9 H 1.8321 0.8498 0.7907 0.036 Uiso 1 1 calc R . .
C10 C 1.7436(3) 0.8939(2) 0.7604(2) 0.0344(11) Uani 1 1 d . . .
H10 H 1.7526 0.9178 0.8015 0.041 Uiso 1 1 calc R . .
C11 C 1.6842(3) 0.8999(2) 0.70747(19) 0.0289(9) Uani 1 1 d . . .
H11 H 1.6534 0.9286 0.7119 0.035 Uiso 1 1 calc R . .
C12 C 1.6700(3) 0.86292(19) 0.64719(18) 0.0211(8) Uani 1 1 d . . .
C13 C 1.6093(3) 0.86096(18) 0.58561(18) 0.0204(8) Uani 1 1 d . . .
C14 C 1.5554(3) 0.8968(2) 0.57786(19) 0.0235(8) Uani 1 1 d . . .
H14 H 1.5576 0.9270 0.6133 0.028 Uiso 1 1 calc R . .
C15 C 1.4976(3) 0.8873(2) 0.5162(2) 0.0239(8) Uani 1 1 d . . .
C16 C 1.4319(3) 0.9122(2) 0.4866(2) 0.0274(9) Uani 1 1 d . . .
H16 H 1.4154 0.9445 0.5069 0.033 Uiso 1 1 calc R . .
C17 C 1.3982(3) 0.8803(2) 0.4236(2) 0.0243(8) Uani 1 1 d . . .
C18 C 1.4990(3) 0.8422(2) 0.46726(19) 0.0234(8) Uani 1 1 d . . .
C19 C 1.5550(3) 0.8084(2) 0.47616(19) 0.0236(8) Uani 1 1 d . . .
H19 H 1.5542 0.7786 0.4410 0.028 Uiso 1 1 calc R . .
C20 C 1.9782(3) 0.5690(2) 0.6691(2) 0.0310(10) Uani 1 1 d . . .
C21 C 1.9756(4) 0.5338(2) 0.6139(2) 0.0376(11) Uani 1 1 d . . .
H21 H 1.9521 0.5443 0.5755 0.045 Uiso 1 1 calc R . .
C22 C 2.0071(4) 0.4832(3) 0.6134(2) 0.0445(13) Uani 1 1 d . . .
H22 H 2.0050 0.4597 0.5743 0.053 Uiso 1 1 calc R . .
C23 C 2.0425(4) 0.4995(3) 0.7195(2) 0.0426(13) Uani 1 1 d . . .
H23 H 2.0649 0.4873 0.7570 0.051 Uiso 1 1 calc R . .
C24 C 2.0137(4) 0.5516(2) 0.7237(2) 0.0391(12) Uani 1 1 d . . .
H24 H 2.0182 0.5754 0.7635 0.047 Uiso 1 1 calc R . .
C25 C 1.3279(3) 0.8818(2) 0.36884(19) 0.0231(8) Uani 1 1 d . . .
C26 C 1.2966(3) 0.8366(2) 0.3098(2) 0.0344(11) Uani 1 1 d . . .
H26 H 1.3216 0.8042 0.3036 0.041 Uiso 1 1 calc R . .
C27 C 1.2288(3) 0.8389(2) 0.2602(2) 0.0322(10) Uani 1 1 d . . .
H27 H 1.2069 0.8066 0.2202 0.039 Uiso 1 1 calc R . .
C28 C 1.2236(3) 0.9276(2) 0.3218(2) 0.0302(10) Uani 1 1 d . . .
H28 H 1.1990 0.9606 0.3262 0.036 Uiso 1 1 calc R . .
C29 C 1.2894(3) 0.9287(2) 0.3748(2) 0.0282(9) Uani 1 1 d . . .
H29 H 1.3082 0.9605 0.4145 0.034 Uiso 1 1 calc R . .
C30 C 0.7923(3) 0.1906(2) 0.1032(2) 0.0268(9) Uani 1 1 d . . .
H30 H 0.7800 0.1755 0.0592 0.032 Uiso 1 1 calc R . .
C31 C 0.8429(3) 0.1675(2) 0.1466(2) 0.0262(9) Uani 1 1 d . . .
C32 C 0.9198(3) 0.1127(2) 0.1911(2) 0.0267(9) Uani 1 1 d . . .
C33 C 0.9164(3) 0.1531(2) 0.2397(2) 0.0293(9) Uani 1 1 d . . .
H33 H 0.9424 0.1567 0.2835 0.035 Uiso 1 1 calc R . .
C34 C 0.8654(3) 0.1902(2) 0.2119(2) 0.0259(9) Uani 1 1 d . . .
C35 C 0.8347(3) 0.23721(19) 0.23314(19) 0.0252(9) Uani 1 1 d . . .
H35 H 0.8497 0.2551 0.2772 0.030 Uiso 1 1 calc R . .
C36 C 0.7815(3) 0.25718(19) 0.18816(19) 0.0233(8) Uani 1 1 d . . .
C37 C 0.7411(3) 0.30358(19) 0.20319(19) 0.0243(9) Uani 1 1 d . . .
C38 C 0.7539(3) 0.3384(2) 0.2638(2) 0.0357(11) Uani 1 1 d . . .
H38 H 0.7935 0.3344 0.3010 0.043 Uiso 1 1 calc R . .
C39 C 0.7070(4) 0.3790(3) 0.2679(2) 0.0421(13) Uani 1 1 d . . .
H39 H 0.7141 0.4031 0.3085 0.050 Uiso 1 1 calc R . .
C40 C 0.6493(3) 0.3850(2) 0.2132(2) 0.0337(11) Uani 1 1 d . . .
H40 H 0.6167 0.4125 0.2161 0.040 Uiso 1 1 calc R . .
C41 C 0.6405(3) 0.3500(2) 0.15469(19) 0.0249(9) Uani 1 1 d . . .
C42 C 0.5856(3) 0.35048(19) 0.09155(19) 0.0230(8) Uani 1 1 d . . .
C43 C 0.5345(3) 0.3887(2) 0.08175(19) 0.0260(9) Uani 1 1 d . . .
H43 H 0.5339 0.4179 0.1166 0.031 Uiso 1 1 calc R . .
C44 C 0.4842(3) 0.3832(2) 0.01941(19) 0.0237(8) Uani 1 1 d . . .
C45 C 0.4248(3) 0.4114(2) -0.0128(2) 0.0271(9) Uani 1 1 d . . .
H45 H 0.4087 0.4448 0.0063 0.033 Uiso 1 1 calc R . .
C46 C 0.3961(3) 0.3819(2) -0.0750(2) 0.0247(9) Uani 1 1 d . . .
C47 C 0.4870(3) 0.3376(2) -0.02868(18) 0.0247(9) Uani 1 1 d . . .
C48 C 0.5403(3) 0.3017(2) -0.01770(19) 0.0260(9) Uani 1 1 d . . .
H48 H 0.5421 0.2727 -0.0520 0.031 Uiso 1 1 calc R . .
C49 C 0.9610(3) 0.0636(2) 0.1884(2) 0.0275(9) Uani 1 1 d . . .
C50 C 0.9746(4) 0.0391(2) 0.1352(2) 0.0379(11) Uani 1 1 d . . .
H50 H 0.9600 0.0556 0.0995 0.045 Uiso 1 1 calc R . .
C51 C 1.0097(3) -0.0098(3) 0.1346(2) 0.0377(11) Uani 1 1 d . . .
H51 H 1.0192 -0.0259 0.0979 0.045 Uiso 1 1 calc R . .
C52 C 1.0194(3) -0.0104(2) 0.2346(2) 0.0304(10) Uani 1 1 d . . .
H52 H 1.0354 -0.0275 0.2698 0.037 Uiso 1 1 calc R . .
C53 C 0.9860(3) 0.0388(2) 0.2402(2) 0.0308(10) Uani 1 1 d . . .
H53 H 0.9800 0.0554 0.2783 0.037 Uiso 1 1 calc R . .
C54 C 0.3304(3) 0.38536(19) -0.13177(19) 0.0216(8) Uani 1 1 d . . .
C55 C 0.2897(3) 0.3335(2) -0.1873(2) 0.0284(9) Uani 1 1 d . . .
H55 H 0.3041 0.2949 -0.1898 0.034 Uiso 1 1 calc R . .
C56 C 0.2276(3) 0.3388(2) -0.2392(2) 0.0269(9) Uani 1 1 d . . .
H56 H 0.1988 0.3024 -0.2769 0.032 Uiso 1 1 calc R . .
C57 C 0.2470(3) 0.4424(2) -0.1847(2) 0.0288(9) Uani 1 1 d . . .
H57 H 0.2324 0.4809 -0.1836 0.035 Uiso 1 1 calc R . .
C58 C 0.3086(3) 0.4415(2) -0.1308(2) 0.0294(9) Uani 1 1 d . . .
H58 H 0.3359 0.4783 -0.0935 0.035 Uiso 1 1 calc R . .
C59 C 0.8046(3) 0.40448(19) 0.1038(2) 0.0261(9) Uani 1 1 d . . .
H59 H 0.7993 0.4133 0.1436 0.031 Uiso 1 1 calc R . .
C60 C 0.8517(3) 0.4546(2) 0.0869(2) 0.0321(10) Uani 1 1 d . . .
C61 C 0.9213(3) 0.5536(2) 0.0820(2) 0.0369(11) Uani 1 1 d . . .
C62 C 0.9116(4) 0.5088(2) 0.0293(3) 0.0411(12) Uani 1 1 d . . .
H62 H 0.9323 0.5190 -0.0025 0.049 Uiso 1 1 calc R . .
C63 C 0.8651(3) 0.4445(2) 0.0305(2) 0.0312(10) Uani 1 1 d . . .
C64 C 0.8283(3) 0.3799(2) -0.0093(2) 0.0326(10) Uani 1 1 d . . .
H64 H 0.8377 0.3699 -0.0474 0.039 Uiso 1 1 calc R . .
C65 C 0.7772(3) 0.3301(2) 0.0079(2) 0.0248(9) Uani 1 1 d . . .
C66 C 0.7258(3) 0.2613(2) -0.0328(2) 0.0249(9) Uani 1 1 d . . .
C67 C 0.7270(3) 0.2320(2) -0.0905(2) 0.0320(10) Uani 1 1 d . . .
H67 H 0.7659 0.2563 -0.1069 0.038 Uiso 1 1 calc R . .
C68 C 0.6710(3) 0.1674(2) -0.1232(2) 0.0376(11) Uani 1 1 d . . .
H68 H 0.6711 0.1465 -0.1624 0.045 Uiso 1 1 calc R . .
C69 C 0.6139(3) 0.1326(2) -0.0989(2) 0.0335(10) Uani 1 1 d . . .
H69 H 0.5746 0.0880 -0.1214 0.040 Uiso 1 1 calc R . .
C70 C 0.6152(3) 0.1637(2) -0.0417(2) 0.0246(8) Uani 1 1 d . . .
C71 C 0.5586(3) 0.1369(2) -0.00880(19) 0.0231(8) Uani 1 1 d . . .
C72 C 0.4896(3) 0.0765(2) -0.0346(2) 0.0248(9) Uani 1 1 d . . .
H72 H 0.4768 0.0478 -0.0747 0.030 Uiso 1 1 calc R . .
C73 C 0.4383(3) 0.0589(2) 0.0008(2) 0.0256(9) Uani 1 1 d . . .
C74 C 0.3620(3) 0.0043(2) -0.0073(2) 0.0284(9) Uani 1 1 d . . .
H74 H 0.3287 -0.0341 -0.0430 0.034 Uiso 1 1 calc R . .
C75 C 0.3468(3) 0.0186(2) 0.0466(2) 0.0264(9) Uani 1 1 d . . .
C76 C 0.4632(3) 0.1037(2) 0.0591(2) 0.0270(9) Uani 1 1 d . . .
C77 C 0.5313(3) 0.1640(2) 0.08299(19) 0.0265(9) Uani 1 1 d . . .
H77 H 0.5442 0.1933 0.1228 0.032 Uiso 1 1 calc R . .
C78 C 0.9542(3) 0.6260(2) 0.1036(2) 0.0358(11) Uani 1 1 d . . .
C79 C 0.9335(4) 0.6603(2) 0.1492(2) 0.0450(13) Uani 1 1 d . . .
H79 H 0.8998 0.6369 0.1693 0.054 Uiso 1 1 calc R . .
C80 C 0.9633(4) 0.7289(2) 0.1643(2) 0.0433(13) Uani 1 1 d . . .
H80 H 0.9496 0.7519 0.1956 0.052 Uiso 1 1 calc R . .
C81 C 1.0286(3) 0.7314(2) 0.0934(3) 0.0397(12) Uani 1 1 d . . .
H81 H 1.0616 0.7561 0.0736 0.048 Uiso 1 1 calc R . .
C82 C 1.0018(4) 0.6627(2) 0.0752(3) 0.0440(13) Uani 1 1 d . . .
H82 H 1.0161 0.6411 0.0434 0.053 Uiso 1 1 calc R . .
C83 C 0.2833(3) -0.0173(2) 0.0690(2) 0.0259(9) Uani 1 1 d . . .
C84 C 0.3033(3) -0.0060(2) 0.1336(2) 0.0327(10) Uani 1 1 d . . .
H84 H 0.3575 0.0267 0.1642 0.039 Uiso 1 1 calc R . .
C85 C 0.2404(3) -0.0446(2) 0.1517(2) 0.0335(10) Uani 1 1 d . . .
H85 H 0.2549 -0.0379 0.1960 0.040 Uiso 1 1 calc R . .
C86 C 0.1444(3) -0.0989(2) 0.0503(2) 0.0311(10) Uani 1 1 d . . .
H86 H 0.0890 -0.1311 0.0209 0.037 Uiso 1 1 calc R . .
C87 C 0.2015(3) -0.0643(2) 0.0267(2) 0.0314(10) Uani 1 1 d . . .
H87 H 0.1853 -0.0725 -0.0178 0.038 Uiso 1 1 calc R . .
C88 C 1.5677(3) 0.6747(2) 0.58107(19) 0.0252(9) Uani 1 1 d . . .
H88 H 1.5871 0.7030 0.6227 0.030 Uiso 1 1 calc R . .
C89 C 1.4976(3) 0.6149(2) 0.5589(2) 0.0264(9) Uani 1 1 d . . .
C90 C 1.3822(3) 0.5324(2) 0.5483(2) 0.0338(10) Uani 1 1 d . . .
C91 C 1.3905(3) 0.5184(2) 0.4924(2) 0.0351(11) Uani 1 1 d . . .
H91 H 1.3536 0.4807 0.4565 0.042 Uiso 1 1 calc R . .
C92 C 1.4658(3) 0.5716(2) 0.4982(2) 0.0319(10) Uani 1 1 d . . .
C93 C 1.5103(3) 0.5896(2) 0.4590(2) 0.0337(10) Uani 1 1 d . . .
H93 H 1.4925 0.5615 0.4174 0.040 Uiso 1 1 calc R . .
C94 C 1.5807(3) 0.6496(2) 0.48297(19) 0.0255(9) Uani 1 1 d . . .
C95 C 1.6321(3) 0.67619(19) 0.44739(19) 0.0241(8) Uani 1 1 d . . .
C96 C 1.6223(3) 0.6444(2) 0.3870(2) 0.0372(11) Uani 1 1 d . . .
H96 H 1.5808 0.6003 0.3647 0.045 Uiso 1 1 calc R . .
C97 C 1.6756(4) 0.6796(3) 0.3602(2) 0.0421(12) Uani 1 1 d . . .
H97 H 1.6712 0.6588 0.3193 0.051 Uiso 1 1 calc R . .
C98 C 1.7355(3) 0.7450(2) 0.3924(2) 0.0330(10) Uani 1 1 d . . .
H98 H 1.7711 0.7692 0.3738 0.040 Uiso 1 1 calc R . .
C99 C 1.7410(3) 0.7732(2) 0.4522(2) 0.0232(8) Uani 1 1 d . . .
C100 C 1.7934(3) 0.84222(19) 0.49241(19) 0.0221(8) Uani 1 1 d . . .
C101 C 1.8394(3) 0.8910(2) 0.4722(2) 0.0257(9) Uani 1 1 d . . .
H101 H 1.8458 0.8804 0.4330 0.031 Uiso 1 1 calc R . .
C102 C 1.8759(3) 0.9560(2) 0.5112(2) 0.0272(9) Uani 1 1 d . . .
C103 C 1.9176(3) 1.0205(2) 0.5067(2) 0.0304(10) Uani 1 1 d . . .
H103 H 1.9341 1.0307 0.4731 0.037 Uiso 1 1 calc R . .
C104 C 1.9289(3) 1.0642(2) 0.5601(2) 0.0315(10) Uani 1 1 d . . .
C105 C 1.8667(3) 0.96687(19) 0.5691(2) 0.0250(9) Uani 1 1 d . . .
C106 C 1.8234(3) 0.9167(2) 0.58861(19) 0.0238(8) Uani 1 1 d . . .
H106 H 1.8200 0.9262 0.6290 0.029 Uiso 1 1 calc R . .
C107 C 1.3198(3) 0.4962(2) 0.5718(2) 0.0327(10) Uani 1 1 d . . .
C108 C 1.3397(3) 0.5040(2) 0.6356(2) 0.0329(10) Uani 1 1 d . . .
H108 H 1.3954 0.5345 0.6664 0.039 Uiso 1 1 calc R . .
C109 C 1.2769(3) 0.4664(2) 0.6542(2) 0.0342(10) Uani 1 1 d . . .
H109 H 1.2917 0.4704 0.6981 0.041 Uiso 1 1 calc R . .
C110 C 1.1781(3) 0.4182(2) 0.5512(2) 0.0379(11) Uani 1 1 d . . .
H110 H 1.1214 0.3883 0.5215 0.046 Uiso 1 1 calc R . .
C111 C 1.2367(3) 0.4521(2) 0.5290(2) 0.0382(11) Uani 1 1 d . . .
H111 H 1.2207 0.4456 0.4846 0.046 Uiso 1 1 calc R . .
C112 C 1.9647(3) 1.1372(2) 0.5835(2) 0.0310(10) Uani 1 1 d . . .
C113 C 1.9619(3) 1.1702(2) 0.6372(2) 0.0398(12) Uani 1 1 d . . .
H113 H 1.9362 1.1462 0.6611 0.048 Uiso 1 1 calc R . .
C114 C 1.9969(4) 1.2390(2) 0.6568(2) 0.0405(12) Uani 1 1 d . . .
H114 H 1.9944 1.2616 0.6945 0.049 Uiso 1 1 calc R . .
C115 C 2.0361(3) 1.2427(2) 0.5724(2) 0.0323(10) Uani 1 1 d . . .
H115 H 2.0621 1.2680 0.5494 0.039 Uiso 1 1 calc R . .
C116 C 2.0026(3) 1.1744(2) 0.5494(2) 0.0319(10) Uani 1 1 d . . .
H116 H 2.0051 1.1530 0.5114 0.038 Uiso 1 1 calc R . .
P1 P 0.50043(8) 0.00953(6) 0.70571(6) 0.0399(3) Uani 1 1 d D . .
F1 F 0.49147(18) 0.01626(13) 0.63674(10) 0.0496(8) Uani 1 1 d D . .
F2 F 0.39988(14) -0.00277(16) 0.68769(14) 0.0683(11) Uani 1 1 d D . .
F3 F 0.51036(19) 0.00232(14) 0.77447(10) 0.0566(9) Uani 1 1 d D . .
F4 F 0.60156(14) 0.02071(14) 0.72342(14) 0.0584(9) Uani 1 1 d D . .
F5 F 0.52645(19) 0.08708(10) 0.73136(13) 0.0644(10) Uani 1 1 d D . .
F6 F 0.4756(2) -0.06856(10) 0.68011(13) 0.0635(10) Uani 1 1 d D . .
P2 P 0.88672(9) 0.29198(7) 0.43336(6) 0.0496(4) Uani 1 1 d D . .
F7 F 0.8206(5) 0.3252(5) 0.4433(3) 0.125(3) Uani 0.76(2) 1 d PDU A 1
F8 F 0.9634(4) 0.3457(3) 0.4956(3) 0.0852(18) Uani 0.76(2) 1 d PDU A 1
F9 F 0.9532(5) 0.2583(5) 0.4237(3) 0.105(3) Uani 0.76(2) 1 d PDU A 1
F10 F 0.8105(6) 0.2392(7) 0.3700(6) 0.088(3) Uani 0.76(2) 1 d PDU A 1
F11 F 0.9110(6) 0.3381(4) 0.3913(4) 0.080(2) Uani 0.76(2) 1 d PDU A 1
F12 F 0.8623(6) 0.2443(4) 0.4746(4) 0.116(3) Uani 0.76(2) 1 d PDU A 1
F7A F 0.8485(16) 0.3492(9) 0.4387(11) 0.125(5) Uani 0.24(2) 1 d PDU A 2
F8A F 0.9741(10) 0.3381(11) 0.4933(9) 0.086(4) Uani 0.24(2) 1 d PDU A 2
F9A F 0.9249(16) 0.2349(9) 0.4280(11) 0.111(4) Uani 0.24(2) 1 d PDU A 2
F10A F 0.7973(18) 0.2447(17) 0.375(2) 0.076(4) Uani 0.24(2) 1 d PDU A 2
F11A F 0.9287(17) 0.3212(14) 0.3877(12) 0.067(4) Uani 0.24(2) 1 d PDU A 2
F12A F 0.8442(17) 0.2626(14) 0.4788(12) 0.127(5) Uani 0.24(2) 1 d PDU A 2
P3 P 0.17066(10) 0.12023(7) 0.71720(7) 0.0534(4) Uani 1 1 d D . .
F13 F 0.1988(8) 0.0851(4) 0.6662(4) 0.082(2) Uani 0.369(12) 1 d PDU B 1
F14 F 0.0706(3) 0.0749(3) 0.6752(5) 0.081(3) Uani 0.369(12) 1 d PDU B 1
F15 F 0.1435(9) 0.1557(4) 0.7686(4) 0.090(2) Uani 0.369(12) 1 d PDU B 1
F16 F 0.2713(3) 0.1655(3) 0.7593(5) 0.088(3) Uani 0.369(12) 1 d PDU B 1
F13A F 0.2364(5) 0.1063(3) 0.6871(3) 0.0781(17) Uani 0.631(12) 1 d PDU B 2
F14A F 0.0902(4) 0.06461(18) 0.6576(2) 0.090(2) Uani 0.631(12) 1 d PDU B 2
F15A F 0.1037(5) 0.1336(3) 0.7462(4) 0.0812(17) Uani 0.631(12) 1 d PDU B 2
F16A F 0.2508(4) 0.17533(18) 0.7765(2) 0.087(2) Uani 0.631(12) 1 d PDU B 2
F17 F 0.1623(2) 0.17454(14) 0.68090(15) 0.0768(12) Uani 1 1 d D B .
F18 F 0.1791(2) 0.06554(15) 0.75314(16) 0.0930(14) Uani 1 1 d D B .
P4 P 0.45246(14) 0.24961(9) 0.23221(10) 0.0770(6) Uani 1 1 d D . .
F19 F 0.4579(4) 0.2539(3) 0.16548(18) 0.120(2) Uani 0.726(4) 1 d PDU C 1
F20 F 0.3531(2) 0.2444(3) 0.2039(3) 0.125(2) Uani 0.726(4) 1 d PDU C 1
F21 F 0.4462(4) 0.2453(2) 0.29780(17) 0.113(2) Uani 0.726(4) 1 d PDU C 1
F22 F 0.5513(2) 0.2548(2) 0.2592(3) 0.110(2) Uani 0.726(4) 1 d PDU C 1
F23 F 0.4198(3) 0.17086(13) 0.2080(3) 0.112(2) Uani 0.726(4) 1 d PDU C 1
F24 F 0.4849(3) 0.32840(13) 0.2554(3) 0.109(2) Uani 0.726(4) 1 d PDU C 1
F19A F 0.4408(8) 0.3049(5) 0.1982(5) 0.115(3) Uani 0.274(4) 1 d PDU C 2
F20A F 0.3869(7) 0.2600(6) 0.2639(6) 0.115(3) Uani 0.274(4) 1 d PDU C 2
F21A F 0.4646(8) 0.1941(5) 0.2666(5) 0.117(3) Uani 0.274(4) 1 d PDU C 2
F22A F 0.5188(7) 0.2392(6) 0.2013(6) 0.107(3) Uani 0.274(4) 1 d PDU C 2
F23A F 0.3725(6) 0.1941(5) 0.1729(4) 0.122(3) Uani 0.274(4) 1 d PDU C 2
F24A F 0.5329(5) 0.3049(5) 0.2920(4) 0.118(3) Uani 0.274(4) 1 d PDU C 2
P5 P 0.47830(10) 0.51533(7) 0.20379(8) 0.0571(4) Uani 1 1 d D . .
F25 F 0.57794(17) 0.5208(2) 0.22645(18) 0.1031(17) Uani 1 1 d D . .
F26 F 0.4775(2) 0.51951(16) 0.13612(12) 0.0745(11) Uani 1 1 d D . .
F27 F 0.37951(16) 0.5094(2) 0.18179(17) 0.1106(19) Uani 1 1 d D . .
F28 F 0.4802(2) 0.51108(17) 0.27219(12) 0.0855(13) Uani 1 1 d D . .
F29 F 0.5115(3) 0.59391(11) 0.22835(17) 0.121(2) Uani 1 1 d D . .
F30 F 0.4470(3) 0.43667(11) 0.18031(17) 0.1019(17) Uani 1 1 d D . .
P6 P 0.00786(11) 0.30764(12) 0.09495(8) 0.0817(7) Uani 1 1 d D . .
F31 F 0.0619(2) 0.2822(2) 0.05926(17) 0.146(3) Uani 1 1 d D . .
F32 F 0.0157(3) 0.36760(17) 0.06480(17) 0.1142(19) Uani 1 1 d D . .
F33 F -0.04627(19) 0.33228(17) 0.13076(13) 0.0713(11) Uani 1 1 d D . .
F34 F 0.0009(2) 0.24759(17) 0.12568(17) 0.0968(15) Uani 1 1 d D . .
F35 F -0.08109(19) 0.26262(18) 0.03573(13) 0.1014(17) Uani 1 1 d D . .
F36 F 0.09684(17) 0.3526(2) 0.15422(14) 0.123(2) Uani 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 284 0.0033 0.0016
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
H H 214 0.0000 0.0000
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Ag Ag 4 -0.8971 1.1015
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
F F 72 0.0171 0.0103
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Fe Fe 4 0.3463 0.8444
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
N N 66 0.0061 0.0033
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
O O 16 0.0106 0.0060
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
P P 12 0.1023 0.0942
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N9 Ag1 N14 139.22(15) 1_565 .
N9 Ag1 N5 112.84(13) 1_565 .
N14 Ag1 N5 96.43(14) . .
N9 Ag1 N15 98.62(13) 1_565 1_665
N14 Ag1 N15 106.78(14) . 1_665
N5 Ag1 N15 94.93(13) . 1_665
N4 Ag2 N20 131.18(15) . 1_545
N4 Ag2 N10 116.60(14) . 1_756
N20 Ag2 N10 96.64(13) 1_545 1_756
N4 Ag2 N19 101.85(15) . 1_655
N20 Ag2 N19 108.64(14) 1_545 1_655
N10 Ag2 N19 97.12(14) 1_756 1_655
N12 Fe1 N7 177.10(15) . .
N12 Fe1 N13 81.36(14) . .
N7 Fe1 N13 101.46(14) . .
N12 Fe1 N11 80.89(14) . .
N7 Fe1 N11 96.33(14) . .
N13 Fe1 N11 161.85(14) . .
N12 Fe1 N6 98.18(14) . .
N7 Fe1 N6 81.20(14) . .
N13 Fe1 N6 90.69(13) . .
N11 Fe1 N6 95.54(14) . .
N12 Fe1 N8 99.71(14) . .
N7 Fe1 N8 81.02(14) . .
N13 Fe1 N8 90.35(14) . .
N11 Fe1 N8 88.93(14) . .
N6 Fe1 N8 162.03(14) . .
N2 Fe2 N17 177.57(15) . .
N2 Fe2 N18 95.91(14) . .
N17 Fe2 N18 81.67(14) . .
N2 Fe2 N16 101.33(14) . .
N17 Fe2 N16 81.07(14) . .
N18 Fe2 N16 162.45(14) . .
N2 Fe2 N3 81.03(13) . .
N17 Fe2 N3 98.72(13) . .
N18 Fe2 N3 89.74(13) . .
N16 Fe2 N3 89.73(14) . .
N2 Fe2 N1 81.58(14) . .
N17 Fe2 N1 98.80(14) . .
N18 Fe2 N1 95.38(14) . .
N16 Fe2 N1 90.39(14) . .
N3 Fe2 N1 162.29(14) . .
C2 O1 C3 105.0(3) . .
C18 O2 C17 105.3(3) . .
C31 O3 C32 105.1(3) . .
C47 O4 C46 104.8(3) . .
C60 O5 C61 106.0(3) . .
C76 O6 C75 106.1(3) . .
C89 O7 C90 105.6(3) . .
C105 O8 C104 104.7(3) . .
C1 N1 C7 119.7(3) . .
C1 N1 Fe2 125.8(3) . .
C7 N1 Fe2 113.9(3) . .
C12 N2 C8 121.2(3) . .
C12 N2 Fe2 119.3(3) . .
C8 N2 Fe2 119.2(3) . .
C19 N3 C13 119.3(3) . .
C19 N3 Fe2 126.6(3) . .
C13 N3 Fe2 114.0(3) . .
C23 N4 C22 116.9(4) . .
C23 N4 Ag2 122.2(3) . .
C22 N4 Ag2 120.8(3) . .
C28 N5 C27 116.1(4) . .
C28 N5 Ag1 126.6(3) . .
C27 N5 Ag1 117.2(3) . .
C30 N6 C36 119.4(3) . .
C30 N6 Fe1 126.3(3) . .
C36 N6 Fe1 114.0(3) . .
C41 N7 C37 121.6(3) . .
C41 N7 Fe1 119.4(3) . .
C37 N7 Fe1 118.9(3) . .
C48 N8 C42 120.3(3) . .
C48 N8 Fe1 125.6(3) . .
C42 N8 Fe1 114.1(3) . .
C52 N9 C51 116.8(4) . .
C52 N9 Ag1 123.1(3) . 1_545
C51 N9 Ag1 119.8(3) . 1_545
C56 N10 C57 116.1(3) . .
C56 N10 Ag2 115.9(3) . 1_354
C57 N10 Ag2 128.0(3) . 1_354
C59 N11 C65 118.8(4) . .
C59 N11 Fe1 125.6(3) . .
C65 N11 Fe1 114.9(3) . .
C66 N12 C70 121.5(4) . .
C66 N12 Fe1 119.2(3) . .
C70 N12 Fe1 119.3(3) . .
C77 N13 C71 119.0(3) . .
C77 N13 Fe1 126.1(3) . .
C71 N13 Fe1 114.8(3) . .
C80 N14 C81 117.2(4) . .
C80 N14 Ag1 123.0(3) . .
C81 N14 Ag1 119.4(3) . .
C85 N15 C86 116.3(4) . .
C85 N15 Ag1 110.1(3) . 1_445
C86 N15 Ag1 132.5(3) . 1_445
C88 N16 C94 120.1(4) . .
C88 N16 Fe2 125.5(3) . .
C94 N16 Fe2 114.2(3) . .
C95 N17 C99 122.1(3) . .
C95 N17 Fe2 119.0(3) . .
C99 N17 Fe2 118.8(3) . .
C106 N18 C100 119.0(3) . .
C106 N18 Fe2 126.0(3) . .
C100 N18 Fe2 114.0(3) . .
C109 N19 C110 118.4(4) . .
C109 N19 Ag2 113.2(3) . 1_455
C110 N19 Ag2 127.5(3) . 1_455
C115 N20 C114 117.7(4) . .
C115 N20 Ag2 120.8(3) . 1_565
C114 N20 Ag2 121.4(3) . 1_565
N1 C1 C2 118.3(4) . .
N1 C1 H1 120.8 . .
C2 C1 H1 120.8 . .
O1 C2 C1 125.7(4) . .
O1 C2 C5 110.7(3) . .
C1 C2 C5 123.5(4) . .
C4 C3 O1 112.4(4) . .
C4 C3 C20 130.9(4) . .
O1 C3 C20 116.5(4) . .
C3 C4 C5 106.0(4) . .
C3 C4 H4 127.0 . .
C5 C4 H4 127.0 . .
C2 C5 C6 117.4(4) . .
C2 C5 C4 105.9(4) . .
C6 C5 C4 136.5(4) . .
C7 C6 C5 117.6(4) . .
C7 C6 H6 121.2 . .
C5 C6 H6 121.2 . .
N1 C7 C6 123.4(4) . .
N1 C7 C8 113.4(3) . .
C6 C7 C8 123.1(4) . .
N2 C8 C9 120.8(4) . .
N2 C8 C7 111.6(3) . .
C9 C8 C7 127.6(4) . .
C8 C9 C10 118.3(4) . .
C8 C9 H9 120.9 . .
C10 C9 H9 120.9 . .
C11 C10 C9 120.9(4) . .
C11 C10 H10 119.5 . .
C9 C10 H10 119.5 . .
C10 C11 C12 118.7(4) . .
C10 C11 H11 120.7 . .
C12 C11 H11 120.7 . .
N2 C12 C11 120.0(4) . .
N2 C12 C13 112.5(3) . .
C11 C12 C13 127.5(4) . .
C14 C13 N3 123.1(4) . .
C14 C13 C12 124.3(4) . .
N3 C13 C12 112.6(3) . .
C13 C14 C15 117.8(4) . .
C13 C14 H14 121.1 . .
C15 C14 H14 121.1 . .
C18 C15 C14 117.1(4) . .
C18 C15 C16 106.0(4) . .
C14 C15 C16 136.9(4) . .
C17 C16 C15 105.8(4) . .
C17 C16 H16 127.1 . .
C15 C16 H16 127.1 . .
C16 C17 O2 112.4(4) . .
C16 C17 C25 132.7(4) . .
O2 C17 C25 114.9(3) . .
C19 C18 O2 125.6(4) . .
C19 C18 C15 123.9(4) . .
O2 C18 C15 110.5(3) . .
N3 C19 C18 118.7(4) . .
N3 C19 H19 120.7 . .
C18 C19 H19 120.7 . .
C21 C20 C24 117.2(4) . .
C21 C20 C3 122.7(4) . .
C24 C20 C3 120.0(4) . .
C20 C21 C22 120.3(4) . .
C20 C21 H21 119.9 . .
C22 C21 H21 119.9 . .
N4 C22 C21 122.9(5) . .
N4 C22 H22 118.6 . .
C21 C22 H22 118.6 . .
N4 C23 C24 123.4(4) . .
N4 C23 H23 118.3 . .
C24 C23 H23 118.3 . .
C23 C24 C20 119.3(5) . .
C23 C24 H24 120.4 . .
C20 C24 H24 120.4 . .
C26 C25 C29 117.7(4) . .
C26 C25 C17 121.4(4) . .
C29 C25 C17 120.9(4) . .
C27 C26 C25 119.3(4) . .
C27 C26 H26 120.4 . .
C25 C26 H26 120.4 . .
N5 C27 C26 123.5(4) . .
N5 C27 H27 118.3 . .
C26 C27 H27 118.3 . .
N5 C28 C29 125.1(4) . .
N5 C28 H28 117.5 . .
C29 C28 H28 117.5 . .
C28 C29 C25 118.3(4) . .
C28 C29 H29 120.9 . .
C25 C29 H29 120.9 . .
N6 C30 C31 119.1(4) . .
N6 C30 H30 120.4 . .
C31 C30 H30 120.4 . .
O3 C31 C30 126.0(4) . .
O3 C31 C34 111.6(3) . .
C30 C31 C34 122.4(4) . .
C33 C32 O3 112.0(3) . .
C33 C32 C49 132.5(4) . .
O3 C32 C49 115.5(4) . .
C32 C33 C34 106.4(4) . .
C32 C33 H33 126.8 . .
C34 C33 H33 126.8 . .
C35 C34 C31 118.0(4) . .
C35 C34 C33 137.1(4) . .
C31 C34 C33 104.8(4) . .
C36 C35 C34 117.8(4) . .
C36 C35 H35 121.1 . .
C34 C35 H35 121.1 . .
C35 C36 N6 123.1(4) . .
C35 C36 C37 123.9(4) . .
N6 C36 C37 113.0(3) . .
N7 C37 C38 120.6(4) . .
N7 C37 C36 112.6(3) . .
C38 C37 C36 126.8(4) . .
C39 C38 C37 117.8(4) . .
C39 C38 H38 121.1 . .
C37 C38 H38 121.1 . .
C38 C39 C40 120.8(4) . .
C38 C39 H39 119.6 . .
C40 C39 H39 119.6 . .
C41 C40 C39 118.6(4) . .
C41 C40 H40 120.7 . .
C39 C40 H40 120.7 . .
N7 C41 C40 120.6(4) . .
N7 C41 C42 111.9(3) . .
C40 C41 C42 127.5(4) . .
N8 C42 C43 122.7(4) . .
N8 C42 C41 113.2(3) . .
C43 C42 C41 124.1(4) . .
C42 C43 C44 118.0(4) . .
C42 C43 H43 121.0 . .
C44 C43 H43 121.0 . .
C43 C44 C47 117.1(4) . .
C43 C44 C45 137.7(4) . .
C47 C44 C45 105.2(4) . .
C46 C45 C44 106.7(4) . .
C46 C45 H45 126.6 . .
C44 C45 H45 126.6 . .
C45 C46 O4 112.2(3) . .
C45 C46 C54 133.3(4) . .
O4 C46 C54 114.4(3) . .
O4 C47 C48 125.2(4) . .
O4 C47 C44 111.1(3) . .
C48 C47 C44 123.6(4) . .
N8 C48 C47 118.2(4) . .
N8 C48 H48 120.9 . .
C47 C48 H48 120.9 . .
C50 C49 C53 117.9(4) . .
C50 C49 C32 122.1(4) . .
C53 C49 C32 120.0(4) . .
C51 C50 C49 119.2(4) . .
C51 C50 H50 120.4 . .
C49 C50 H50 120.4 . .
N9 C51 C50 123.3(4) . .
N9 C51 H51 118.3 . .
C50 C51 H51 118.3 . .
N9 C52 C53 124.3(4) . .
N9 C52 H52 117.9 . .
C53 C52 H52 117.9 . .
C52 C53 C49 118.5(4) . .
C52 C53 H53 120.8 . .
C49 C53 H53 120.8 . .
C55 C54 C58 118.6(4) . .
C55 C54 C46 120.9(4) . .
C58 C54 C46 120.5(4) . .
C56 C55 C54 118.7(4) . .
C56 C55 H55 120.7 . .
C54 C55 H55 120.7 . .
N10 C56 C55 123.8(4) . .
N10 C56 H56 118.1 . .
C55 C56 H56 118.1 . .
N10 C57 C58 124.4(4) . .
N10 C57 H57 117.8 . .
C58 C57 H57 117.8 . .
C57 C58 C54 118.4(4) . .
C57 C58 H58 120.8 . .
C54 C58 H58 120.8 . .
N11 C59 C60 119.4(4) . .
N11 C59 H59 120.3 . .
C60 C59 H59 120.3 . .
C59 C60 O5 126.0(4) . .
C59 C60 C63 123.2(4) . .
O5 C60 C63 110.7(4) . .
C62 C61 O5 110.3(4) . .
C62 C61 C78 133.6(5) . .
O5 C61 C78 115.9(4) . .
C61 C62 C63 107.6(4) . .
C61 C62 H62 126.2 . .
C63 C62 H62 126.2 . .
C64 C63 C60 117.3(4) . .
C64 C63 C62 137.3(5) . .
C60 C63 C62 105.2(4) . .
C63 C64 C65 118.1(4) . .
C63 C64 H64 120.9 . .
C65 C64 H64 120.9 . .
N11 C65 C64 123.1(4) . .
N11 C65 C66 112.6(4) . .
C64 C65 C66 124.2(4) . .
N12 C66 C67 120.4(4) . .
N12 C66 C65 112.2(4) . .
C67 C66 C65 127.4(4) . .
C68 C67 C66 118.8(4) . .
C68 C67 H67 120.6 . .
C66 C67 H67 120.6 . .
C67 C68 C69 120.0(4) . .
C67 C68 H68 120.0 . .
C69 C68 H68 120.0 . .
C70 C69 C68 119.1(4) . .
C70 C69 H69 120.4 . .
C68 C69 H69 120.4 . .
N12 C70 C69 120.2(4) . .
N12 C70 C71 112.0(3) . .
C69 C70 C71 127.8(4) . .
C72 C71 N13 123.9(4) . .
C72 C71 C70 123.5(4) . .
N13 C71 C70 112.5(3) . .
C71 C72 C73 117.3(4) . .
C71 C72 H72 121.3 . .
C73 C72 H72 121.3 . .
C76 C73 C72 116.8(4) . .
C76 C73 C74 106.6(4) . .
C72 C73 C74 136.5(4) . .
C75 C74 C73 106.1(4) . .
C75 C74 H74 127.0 . .
C73 C74 H74 127.0 . .
C74 C75 O6 111.0(4) . .
C74 C75 C83 133.4(4) . .
O6 C75 C83 115.5(3) . .
C77 C76 O6 125.3(4) . .
C77 C76 C73 124.6(4) . .
O6 C76 C73 110.2(4) . .
N13 C77 C76 118.4(4) . .
N13 C77 H77 120.8 . .
C76 C77 H77 120.8 . .
C82 C78 C79 118.0(4) . .
C82 C78 C61 119.7(5) . .
C79 C78 C61 122.2(4) . .
C80 C79 C78 118.4(5) . .
C80 C79 H79 120.8 . .
C78 C79 H79 120.8 . .
N14 C80 C79 124.0(5) . .
N14 C80 H80 118.0 . .
C79 C80 H80 118.0 . .
N14 C81 C82 123.0(4) . .
N14 C81 H81 118.5 . .
C82 C81 H81 118.5 . .
C78 C82 C81 119.4(5) . .
C78 C82 H82 120.3 . .
C81 C82 H82 120.3 . .
C84 C83 C87 118.4(4) . .
C84 C83 C75 120.4(4) . .
C87 C83 C75 121.2(4) . .
C83 C84 C85 117.2(4) . .
C83 C84 H84 121.4 . .
C85 C84 H84 121.4 . .
N15 C85 C84 125.5(4) . .
N15 C85 H85 117.2 . .
C84 C85 H85 117.2 . .
N15 C86 C87 123.4(4) . .
N15 C86 H86 118.3 . .
C87 C86 H86 118.3 . .
C86 C87 C83 119.2(4) . .
C86 C87 H87 120.4 . .
C83 C87 H87 120.4 . .
N16 C88 C89 118.4(4) . .
N16 C88 H88 120.8 . .
C89 C88 H88 120.8 . .
O7 C89 C88 126.1(4) . .
O7 C89 C92 110.5(4) . .
C88 C89 C92 123.4(4) . .
C91 C90 O7 111.9(4) . .
C91 C90 C107 131.9(4) . .
O7 C90 C107 116.2(4) . .
C90 C91 C92 105.8(4) . .
C90 C91 H91 127.1 . .
C92 C91 H91 127.1 . .
C89 C92 C93 117.5(4) . .
C89 C92 C91 106.1(4) . .
C93 C92 C91 136.3(4) . .
C94 C93 C92 117.4(4) . .
C94 C93 H93 121.3 . .
C92 C93 H93 121.3 . .
N16 C94 C93 123.1(4) . .
N16 C94 C95 112.8(4) . .
C93 C94 C95 124.0(4) . .
N17 C95 C96 120.8(4) . .
N17 C95 C94 112.7(3) . .
C96 C95 C94 126.5(4) . .
C95 C96 C97 117.5(4) . .
C95 C96 H96 121.2 . .
C97 C96 H96 121.2 . .
C96 C97 C98 121.2(4) . .
C96 C97 H97 119.4 . .
C98 C97 H97 119.4 . .
C99 C98 C97 117.7(4) . .
C99 C98 H98 121.1 . .
C97 C98 H98 121.1 . .
N17 C99 C98 120.6(4) . .
N17 C99 C100 112.1(3) . .
C98 C99 C100 127.3(4) . .
C101 C100 N18 123.4(4) . .
C101 C100 C99 123.3(4) . .
N18 C100 C99 113.2(3) . .
C100 C101 C102 117.5(4) . .
C100 C101 H101 121.2 . .
C102 C101 H101 121.2 . .
C101 C102 C105 117.6(4) . .
C101 C102 C103 136.6(4) . .
C105 C102 C103 105.6(4) . .
C104 C103 C102 105.8(4) . .
C104 C103 H103 127.1 . .
C102 C103 H103 127.1 . .
C103 C104 O8 112.2(4) . .
C103 C104 C112 133.4(4) . .
O8 C104 C112 114.4(4) . .
O8 C105 C106 125.0(4) . .
O8 C105 C102 111.6(4) . .
C106 C105 C102 123.1(4) . .
N18 C106 C105 119.3(4) . .
N18 C106 H106 120.3 . .
C105 C106 H106 120.3 . .
C108 C107 C111 118.1(4) . .
C108 C107 C90 122.4(4) . .
C111 C107 C90 119.5(4) . .
C107 C108 C109 118.8(4) . .
C107 C108 H108 120.6 . .
C109 C108 H108 120.6 . .
N19 C109 C108 122.6(4) . .
N19 C109 H109 118.7 . .
C108 C109 H109 118.7 . .
N19 C110 C111 122.6(5) . .
N19 C110 H110 118.7 . .
C111 C110 H110 118.7 . .
C110 C111 C107 119.4(5) . .
C110 C111 H111 120.3 . .
C107 C111 H111 120.3 . .
C113 C112 C116 118.4(4) . .
C113 C112 C104 122.3(4) . .
C116 C112 C104 119.3(4) . .
C112 C113 C114 119.5(4) . .
C112 C113 H113 120.2 . .
C114 C113 H113 120.2 . .
N20 C114 C113 122.7(5) . .
N20 C114 H114 118.7 . .
C113 C114 H114 118.7 . .
N20 C115 C116 123.3(4) . .
N20 C115 H115 118.3 . .
C116 C115 H115 118.3 . .
C115 C116 C112 118.3(4) . .
C115 C116 H116 120.8 . .
C112 C116 H116 120.8 . .
F5 P1 F2 90.88(14) . .
F5 P1 F3 90.24(14) . .
F2 P1 F3 90.24(14) . .
F5 P1 F1 90.23(14) . .
F2 P1 F1 90.43(14) . .
F3 P1 F1 179.17(16) . .
F5 P1 F6 179.18(16) . .
F2 P1 F6 89.94(14) . .
F3 P1 F6 89.74(14) . .
F1 P1 F6 89.79(13) . .
F5 P1 F4 90.03(14) . .
F2 P1 F4 179.08(17) . .
F3 P1 F4 89.81(14) . .
F1 P1 F4 89.50(13) . .
F6 P1 F4 89.14(14) . .
F11 P2 F7 90.56(18) . .
F11 P2 F8 90.70(19) . .
F7 P2 F8 89.95(18) . .
F11A P2 F9A 90.1(2) . .
F8A P2 F9A 90.1(2) . .
F11A P2 F12A 179.7(3) . .
F8A P2 F12A 90.1(2) . .
F9A P2 F12A 90.0(2) . .
F11A P2 F10A 92(3) . .
F8A P2 F10A 177(3) . .
F9A P2 F10A 90.1(2) . .
F12A P2 F10A 87(3) . .
F11 P2 F10 87.9(9) . .
F7 P2 F10 90.08(18) . .
F8 P2 F10 178.6(9) . .
F11A P2 F7A 90.0(2) . .
F8A P2 F7A 89.9(2) . .
F9A P2 F7A 179.9(3) . .
F12A P2 F7A 89.9(2) . .
F10A P2 F7A 89.9(2) . .
F11 P2 F12 178.8(2) . .
F7 P2 F12 90.36(19) . .
F8 P2 F12 90.10(19) . .
F10 P2 F12 91.3(9) . .
F11 P2 F9 89.75(18) . .
F7 P2 F9 179.7(2) . .
F8 P2 F9 89.98(18) . .
F10 P2 F9 90.00(19) . .
F12 P2 F9 89.33(18) . .
F15 P3 F17 90.17(16) . .
F15 P3 F14 90.42(19) . .
F17 P3 F14 90.21(16) . .
F15 P3 F16 89.76(19) . .
F17 P3 F16 89.96(16) . .
F14 P3 F16 179.8(3) . .
F16A P3 F15A 90.51(18) . .
F14A P3 F15A 89.57(18) . .
F15 P3 F18 90.22(16) . .
F17 P3 F18 179.60(16) . .
F14 P3 F18 89.70(16) . .
F16 P3 F18 90.13(16) . .
F16A P3 F13A 90.37(18) . .
F14A P3 F13A 89.55(17) . .
F15A P3 F13A 179.1(2) . .
F15 P3 F13 179.5(3) . .
F17 P3 F13 89.91(16) . .
F14 P3 F13 90.13(19) . .
F16 P3 F13 89.69(19) . .
F18 P3 F13 89.70(16) . .
F21 P4 F22 90.64(19) . .
F19A P4 F23A 90.3(2) . .
F19A P4 F20A 90.3(2) . .
F23A P4 F20A 90.2(2) . .
F21 P4 F23 90.27(18) . .
F22 P4 F23 90.09(18) . .
F21 P4 F24 90.49(18) . .
F22 P4 F24 90.11(18) . .
F23 P4 F24 179.2(2) . .
F19A P4 F22A 90.2(2) . .
F23A P4 F22A 90.2(2) . .
F20A P4 F22A 179.3(3) . .
F19A P4 F24A 90.2(2) . .
F23A P4 F24A 179.5(3) . .
F20A P4 F24A 89.9(2) . .
F22A P4 F24A 89.7(2) . .
F19A P4 F21A 179.8(3) . .
F23A P4 F21A 89.9(2) . .
F20A P4 F21A 89.8(2) . .
F22A P4 F21A 89.7(2) . .
F24A P4 F21A 89.6(2) . .
F21 P4 F20 90.31(18) . .
F22 P4 F20 179.0(2) . .
F23 P4 F20 89.81(18) . .
F24 P4 F20 89.97(18) . .
F21 P4 F19 179.5(2) . .
F22 P4 F19 89.85(18) . .
F23 P4 F19 89.68(18) . .
F24 P4 F19 89.55(18) . .
F20 P4 F19 89.19(19) . .
F27 P5 F29 90.81(16) . .
F27 P5 F26 90.86(16) . .
F29 P5 F26 90.36(16) . .
F27 P5 F30 90.35(17) . .
F29 P5 F30 178.7(2) . .
F26 P5 F30 90.20(15) . .
F27 P5 F25 179.4(2) . .
F29 P5 F25 89.53(17) . .
F26 P5 F25 89.62(16) . .
F30 P5 F25 89.31(16) . .
F27 P5 F28 89.85(16) . .
F29 P5 F28 89.71(16) . .
F26 P5 F28 179.28(18) . .
F30 P5 F28 89.71(16) . .
F25 P5 F28 89.67(16) . .
F32 P6 F33 90.45(16) . .
F32 P6 F35 90.25(16) . .
F33 P6 F35 90.06(15) . .
F32 P6 F36 89.78(17) . .
F33 P6 F36 89.94(16) . .
F35 P6 F36 180.0(3) . .
F32 P6 F31 90.17(16) . .
F33 P6 F31 179.4(2) . .
F35 P6 F31 89.84(17) . .
F36 P6 F31 90.17(16) . .
F32 P6 F34 179.5(2) . .
F33 P6 F34 89.77(15) . .
F35 P6 F34 90.24(17) . .
F36 P6 F34 89.72(16) . .
F31 P6 F34 89.62(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N9 2.249(3) 1_565
Ag1 N14 2.250(4) .
Ag1 N5 2.411(3) .
Ag1 N15 2.446(4) 1_665
Ag2 N4 2.231(4) .
Ag2 N20 2.263(4) 1_545
Ag2 N10 2.390(3) 1_756
Ag2 N19 2.391(4) 1_655
Fe1 N12 1.882(3) .
Fe1 N7 1.885(3) .
Fe1 N13 1.965(3) .
Fe1 N11 1.970(4) .
Fe1 N6 1.981(3) .
Fe1 N8 1.981(3) .
Fe2 N2 1.878(3) .
Fe2 N17 1.889(3) .
Fe2 N18 1.970(3) .
Fe2 N16 1.978(4) .
Fe2 N3 1.984(3) .
Fe2 N1 1.986(3) .
O1 C2 1.369(5) .
O1 C3 1.383(5) .
O2 C18 1.375(5) .
O2 C17 1.377(5) .
O3 C31 1.355(5) .
O3 C32 1.395(5) .
O4 C47 1.362(5) .
O4 C46 1.388(5) .
O5 C60 1.368(5) .
O5 C61 1.380(6) .
O6 C76 1.374(5) .
O6 C75 1.384(5) .
O7 C89 1.348(5) .
O7 C90 1.382(5) .
O8 C105 1.351(5) .
O8 C104 1.391(5) .
N1 C1 1.338(5) .
N1 C7 1.372(5) .
N2 C12 1.350(5) .
N2 C8 1.360(5) .
N3 C19 1.333(5) .
N3 C13 1.387(5) .
N4 C23 1.330(7) .
N4 C22 1.339(6) .
N5 C28 1.318(6) .
N5 C27 1.348(5) .
N6 C30 1.337(5) .
N6 C36 1.381(5) .
N7 C41 1.341(5) .
N7 C37 1.350(5) .
N8 C48 1.338(5) .
N8 C42 1.369(5) .
N9 C52 1.331(6) .
N9 C51 1.341(6) .
N9 Ag1 2.249(3) 1_545
N10 C56 1.340(5) .
N10 C57 1.350(6) .
N10 Ag2 2.390(3) 1_354
N11 C59 1.363(5) .
N11 C65 1.361(5) .
N12 C66 1.337(6) .
N12 C70 1.345(5) .
N13 C77 1.348(6) .
N13 C71 1.379(5) .
N14 C80 1.326(6) .
N14 C81 1.342(6) .
N15 C85 1.314(6) .
N15 C86 1.345(6) .
N15 Ag1 2.446(4) 1_445
N16 C88 1.340(5) .
N16 C94 1.374(5) .
N17 C95 1.336(5) .
N17 C99 1.350(5) .
N18 C106 1.331(5) .
N18 C100 1.383(5) .
N19 C109 1.321(6) .
N19 C110 1.335(6) .
N19 Ag2 2.391(4) 1_455
N20 C115 1.326(6) .
N20 C114 1.335(6) .
N20 Ag2 2.263(4) 1_565
C1 C2 1.378(6) .
C1 H1 0.9500 .
C2 C5 1.387(6) .
C3 C4 1.344(6) .
C3 C20 1.458(6) .
C4 C5 1.432(6) .
C4 H4 0.9500 .
C5 C6 1.398(6) .
C6 C7 1.373(6) .
C6 H6 0.9500 .
C7 C8 1.477(5) .
C8 C9 1.383(6) .
C9 C10 1.393(6) .
C9 H9 0.9500 .
C10 C11 1.379(6) .
C10 H10 0.9500 .
C11 C12 1.400(5) .
C11 H11 0.9500 .
C12 C13 1.461(5) .
C13 C14 1.378(5) .
C14 C15 1.395(6) .
C14 H14 0.9500 .
C15 C18 1.391(6) .
C15 C16 1.434(6) .
C16 C17 1.355(6) .
C16 H16 0.9500 .
C17 C25 1.462(6) .
C18 C19 1.373(6) .
C19 H19 0.9500 .
C20 C21 1.363(7) .
C20 C24 1.389(6) .
C21 C22 1.376(6) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 C24 1.378(6) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C26 1.381(6) .
C25 C29 1.396(6) .
C26 C27 1.375(6) .
C26 H26 0.9500 .
C27 H27 0.9500 .
C28 C29 1.372(6) .
C28 H28 0.9500 .
C29 H29 0.9500 .
C30 C31 1.381(6) .
C30 H30 0.9500 .
C31 C34 1.398(6) .
C32 C33 1.343(6) .
C32 C49 1.463(6) .
C33 C34 1.446(5) .
C33 H33 0.9500 .
C34 C35 1.386(6) .
C35 C36 1.380(6) .
C35 H35 0.9500 .
C36 C37 1.454(6) .
C37 C38 1.398(6) .
C38 C39 1.385(6) .
C38 H38 0.9500 .
C39 C40 1.393(6) .
C39 H39 0.9500 .
C40 C41 1.382(6) .
C40 H40 0.9500 .
C41 C42 1.471(5) .
C42 C43 1.383(5) .
C43 C44 1.391(6) .
C43 H43 0.9500 .
C44 C47 1.394(6) .
C44 C45 1.429(6) .
C45 C46 1.337(6) .
C45 H45 0.9500 .
C46 C54 1.468(5) .
C47 C48 1.373(6) .
C48 H48 0.9500 .
C49 C50 1.385(6) .
C49 C53 1.396(6) .
C50 C51 1.381(6) .
C50 H50 0.9500 .
C51 H51 0.9500 .
C52 C53 1.376(6) .
C52 H52 0.9500 .
C53 H53 0.9500 .
C54 C55 1.380(6) .
C54 C58 1.393(5) .
C55 C56 1.381(6) .
C55 H55 0.9500 .
C56 H56 0.9500 .
C57 C58 1.366(6) .
C57 H57 0.9500 .
C58 H58 0.9500 .
C59 C60 1.361(6) .
C59 H59 0.9500 .
C60 C63 1.395(7) .
C61 C62 1.364(7) .
C61 C78 1.457(6) .
C62 C63 1.415(6) .
C62 H62 0.9500 .
C63 C64 1.388(6) .
C64 C65 1.394(6) .
C64 H64 0.9500 .
C65 C66 1.468(6) .
C66 C67 1.397(6) .
C67 C68 1.371(6) .
C67 H67 0.9500 .
C68 C69 1.392(7) .
C68 H68 0.9500 .
C69 C70 1.379(6) .
C69 H69 0.9500 .
C70 C71 1.477(6) .
C71 C72 1.372(6) .
C72 C73 1.412(6) .
C72 H72 0.9500 .
C73 C76 1.382(6) .
C73 C74 1.430(6) .
C74 C75 1.367(6) .
C74 H74 0.9500 .
C75 C83 1.448(6) .
C76 C77 1.365(6) .
C77 H77 0.9500 .
C78 C82 1.377(7) .
C78 C79 1.398(7) .
C79 C80 1.383(7) .
C79 H79 0.9500 .
C80 H80 0.9500 .
C81 C82 1.386(7) .
C81 H81 0.9500 .
C82 H82 0.9500 .
C83 C84 1.384(6) .
C83 C87 1.391(6) .
C84 C85 1.398(6) .
C84 H84 0.9500 .
C85 H85 0.9500 .
C86 C87 1.378(6) .
C86 H86 0.9500 .
C87 H87 0.9500 .
C88 C89 1.375(6) .
C88 H88 0.9500 .
C89 C92 1.392(6) .
C90 C91 1.346(6) .
C90 C107 1.456(7) .
C91 C92 1.421(7) .
C91 H91 0.9500 .
C92 C93 1.405(7) .
C93 C94 1.378(6) .
C93 H93 0.9500 .
C94 C95 1.465(6) .
C95 C96 1.391(6) .
C96 C97 1.395(7) .
C96 H96 0.9500 .
C97 C98 1.399(7) .
C97 H97 0.9500 .
C98 C99 1.383(6) .
C98 H98 0.9500 .
C99 C100 1.470(6) .
C100 C101 1.382(6) .
C101 C102 1.387(6) .
C101 H101 0.9500 .
C102 C105 1.395(6) .
C102 C103 1.427(6) .
C103 C104 1.355(6) .
C103 H103 0.9500 .
C104 C112 1.467(6) .
C105 C106 1.370(6) .
C106 H106 0.9500 .
C107 C108 1.374(7) .
C107 C111 1.389(7) .
C108 C109 1.395(7) .
C108 H108 0.9500 .
C109 H109 0.9500 .
C110 C111 1.368(7) .
C110 H110 0.9500 .
C111 H111 0.9500 .
C112 C113 1.356(7) .
C112 C116 1.400(6) .
C113 C114 1.383(7) .
C113 H113 0.9500 .
C114 H114 0.9500 .
C115 C116 1.377(6) .
C115 H115 0.9500 .
C116 H116 0.9500 .
P1 F5 1.580(2) .
P1 F2 1.580(2) .
P1 F3 1.590(2) .
P1 F1 1.594(2) .
P1 F6 1.594(2) .
P1 F4 1.596(2) .
P2 F11 1.582(3) .
P2 F7 1.583(3) .
P2 F8 1.584(3) .
P2 F11A 1.587(3) .
P2 F8A 1.587(3) .
P2 F9A 1.588(3) .
P2 F12A 1.588(3) .
P2 F10A 1.589(3) .
P2 F10 1.589(3) .
P2 F7A 1.590(3) .
P2 F12 1.590(3) .
P2 F9 1.595(3) .
P3 F16A 1.582(2) .
P3 F15 1.587(3) .
P3 F17 1.586(2) .
P3 F14A 1.592(2) .
P3 F14 1.584(3) .
P3 F16 1.591(3) .
P3 F15A 1.589(2) .
P3 F18 1.588(2) .
P3 F13A 1.590(2) .
P3 F13 1.591(3) .
P4 F21 1.578(3) .
P4 F19A 1.583(3) .
P4 F22 1.584(3) .
P4 F23A 1.585(3) .
P4 F20A 1.588(3) .
P4 F23 1.588(3) .
P4 F24 1.588(3) .
P4 F22A 1.589(3) .
P4 F24A 1.592(3) .
P4 F21A 1.593(3) .
P4 F20 1.593(3) .
P4 F19 1.599(3) .
P5 F27 1.578(2) .
P5 F29 1.584(2) .
P5 F26 1.585(2) .
P5 F30 1.588(2) .
P5 F25 1.594(2) .
P5 F28 1.596(2) .
P6 F32 1.584(2) .
P6 F33 1.587(2) .
P6 F35 1.587(2) .
P6 F36 1.588(2) .
P6 F31 1.591(2) .
P6 F34 1.594(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N2 Fe2 N1 C1 173.3(4) .
N17 Fe2 N1 C1 -9.1(4) .
N18 Fe2 N1 C1 -91.5(4) .
N16 Fe2 N1 C1 71.9(4) .
N3 Fe2 N1 C1 162.2(4) .
N2 Fe2 N1 C7 1.3(3) .
N17 Fe2 N1 C7 178.9(3) .
N18 Fe2 N1 C7 96.5(3) .
N16 Fe2 N1 C7 -100.1(3) .
N3 Fe2 N1 C7 -9.8(6) .
N18 Fe2 N2 C12 82.3(3) .
N16 Fe2 N2 C12 -94.4(3) .
N3 Fe2 N2 C12 -6.5(3) .
N1 Fe2 N2 C12 176.9(3) .
N18 Fe2 N2 C8 -92.3(3) .
N16 Fe2 N2 C8 91.0(3) .
N3 Fe2 N2 C8 178.9(3) .
N1 Fe2 N2 C8 2.3(3) .
N2 Fe2 N3 C19 -175.5(4) .
N17 Fe2 N3 C19 7.0(4) .
N18 Fe2 N3 C19 88.5(4) .
N16 Fe2 N3 C19 -73.9(4) .
N1 Fe2 N3 C19 -164.4(4) .
N2 Fe2 N3 C13 6.4(3) .
N17 Fe2 N3 C13 -171.2(3) .
N18 Fe2 N3 C13 -89.7(3) .
N16 Fe2 N3 C13 107.9(3) .
N1 Fe2 N3 C13 17.4(6) .
N20 Ag2 N4 C23 107.1(4) 1_545
N10 Ag2 N4 C23 -20.5(5) 1_756
N19 Ag2 N4 C23 -124.8(4) 1_655
N20 Ag2 N4 C22 -77.5(5) 1_545
N10 Ag2 N4 C22 154.9(4) 1_756
N19 Ag2 N4 C22 50.6(4) 1_655
N9 Ag1 N5 C28 11.2(4) 1_565
N14 Ag1 N5 C28 -139.7(4) .
N15 Ag1 N5 C28 112.8(4) 1_665
N9 Ag1 N5 C27 -171.2(3) 1_565
N14 Ag1 N5 C27 37.8(3) .
N15 Ag1 N5 C27 -69.7(3) 1_665
N12 Fe1 N6 C30 -7.8(4) .
N7 Fe1 N6 C30 175.1(4) .
N13 Fe1 N6 C30 73.6(4) .
N11 Fe1 N6 C30 -89.4(4) .
N8 Fe1 N6 C30 166.8(4) .
N12 Fe1 N6 C36 178.4(3) .
N7 Fe1 N6 C36 1.3(3) .
N13 Fe1 N6 C36 -100.2(3) .
N11 Fe1 N6 C36 96.8(3) .
N8 Fe1 N6 C36 -6.9(6) .
N13 Fe1 N7 C41 -93.2(3) .
N11 Fe1 N7 C41 83.2(3) .
N6 Fe1 N7 C41 177.8(3) .
N8 Fe1 N7 C41 -4.7(3) .
N13 Fe1 N7 C37 91.4(3) .
N11 Fe1 N7 C37 -92.2(3) .
N6 Fe1 N7 C37 2.4(3) .
N8 Fe1 N7 C37 179.9(3) .
N12 Fe1 N8 C48 5.7(4) .
N7 Fe1 N8 C48 -177.2(4) .
N13 Fe1 N8 C48 -75.6(4) .
N11 Fe1 N8 C48 86.2(4) .
N6 Fe1 N8 C48 -169.0(4) .
N12 Fe1 N8 C42 -171.7(3) .
N7 Fe1 N8 C42 5.5(3) .
N13 Fe1 N8 C42 107.0(3) .
N11 Fe1 N8 C42 -91.1(3) .
N6 Fe1 N8 C42 13.7(6) .
N12 Fe1 N11 C59 172.6(3) .
N7 Fe1 N11 C59 -8.3(3) .
N13 Fe1 N11 C59 160.4(4) .
N6 Fe1 N11 C59 -90.0(3) .
N8 Fe1 N11 C59 72.6(3) .
N12 Fe1 N11 C65 2.7(3) .
N7 Fe1 N11 C65 -178.2(3) .
N13 Fe1 N11 C65 -9.5(6) .
N6 Fe1 N11 C65 100.1(3) .
N8 Fe1 N11 C65 -97.3(3) .
N13 Fe1 N12 C66 176.9(3) .
N11 Fe1 N12 C66 0.7(3) .
N6 Fe1 N12 C66 -93.6(3) .
N8 Fe1 N12 C66 88.1(3) .
N13 Fe1 N12 C70 -2.0(3) .
N11 Fe1 N12 C70 -178.2(3) .
N6 Fe1 N12 C70 87.4(3) .
N8 Fe1 N12 C70 -90.9(3) .
N12 Fe1 N13 C77 -175.7(4) .
N7 Fe1 N13 C77 5.0(4) .
N11 Fe1 N13 C77 -163.6(4) .
N6 Fe1 N13 C77 86.1(3) .
N8 Fe1 N13 C77 -76.0(3) .
N12 Fe1 N13 C71 0.3(3) .
N7 Fe1 N13 C71 -179.0(3) .
N11 Fe1 N13 C71 12.5(6) .
N6 Fe1 N13 C71 -97.8(3) .
N8 Fe1 N13 C71 100.1(3) .
N9 Ag1 N14 C80 -61.1(5) 1_565
N5 Ag1 N14 C80 75.7(4) .
N15 Ag1 N14 C80 172.8(4) 1_665
N9 Ag1 N14 C81 126.8(4) 1_565
N5 Ag1 N14 C81 -96.4(4) .
N15 Ag1 N14 C81 0.7(4) 1_665
N2 Fe2 N16 C88 1.4(4) .
N17 Fe2 N16 C88 -178.3(4) .
N18 Fe2 N16 C88 -167.7(4) .
N3 Fe2 N16 C88 -79.4(3) .
N1 Fe2 N16 C88 82.9(3) .
N2 Fe2 N16 C94 176.6(3) .
N17 Fe2 N16 C94 -3.0(3) .
N18 Fe2 N16 C94 7.5(6) .
N3 Fe2 N16 C94 95.8(3) .
N1 Fe2 N16 C94 -101.9(3) .
N18 Fe2 N17 C95 -176.1(3) .
N16 Fe2 N17 C95 0.7(3) .
N3 Fe2 N17 C95 -87.7(3) .
N1 Fe2 N17 C95 89.7(3) .
N18 Fe2 N17 C99 1.1(3) .
N16 Fe2 N17 C99 177.9(3) .
N3 Fe2 N17 C99 89.6(3) .
N1 Fe2 N17 C99 -93.1(3) .
N2 Fe2 N18 C106 -9.6(3) .
N17 Fe2 N18 C106 170.2(3) .
N16 Fe2 N18 C106 159.6(4) .
N3 Fe2 N18 C106 71.3(3) .
N1 Fe2 N18 C106 -91.7(3) .
N2 Fe2 N18 C100 -177.8(3) .
N17 Fe2 N18 C100 2.0(3) .
N16 Fe2 N18 C100 -8.6(6) .
N3 Fe2 N18 C100 -96.9(3) .
N1 Fe2 N18 C100 100.1(3) .
C7 N1 C1 C2 1.9(6) .
Fe2 N1 C1 C2 -169.7(3) .
C3 O1 C2 C1 -176.8(4) .
C3 O1 C2 C5 -0.2(5) .
N1 C1 C2 O1 174.3(4) .
N1 C1 C2 C5 -1.8(7) .
C2 O1 C3 C4 0.4(5) .
C2 O1 C3 C20 175.5(4) .
O1 C3 C4 C5 -0.5(6) .
C20 C3 C4 C5 -174.6(5) .
O1 C2 C5 C6 -176.3(4) .
C1 C2 C5 C6 0.4(7) .
O1 C2 C5 C4 -0.1(5) .
C1 C2 C5 C4 176.6(4) .
C3 C4 C5 C2 0.3(5) .
C3 C4 C5 C6 175.4(5) .
C2 C5 C6 C7 0.9(6) .
C4 C5 C6 C7 -173.8(5) .
C1 N1 C7 C6 -0.6(6) .
Fe2 N1 C7 C6 171.9(3) .
C1 N1 C7 C8 -176.8(4) .
Fe2 N1 C7 C8 -4.2(4) .
C5 C6 C7 N1 -0.8(7) .
C5 C6 C7 C8 174.9(4) .
C12 N2 C8 C9 1.3(6) .
Fe2 N2 C8 C9 175.8(3) .
C12 N2 C8 C7 -179.6(3) .
Fe2 N2 C8 C7 -5.0(4) .
N1 C7 C8 N2 5.9(5) .
C6 C7 C8 N2 -170.3(4) .
N1 C7 C8 C9 -175.1(4) .
C6 C7 C8 C9 8.8(7) .
N2 C8 C9 C10 -0.3(7) .
C7 C8 C9 C10 -179.3(4) .
C8 C9 C10 C11 -1.2(7) .
C9 C10 C11 C12 1.6(7) .
C8 N2 C12 C11 -0.8(6) .
Fe2 N2 C12 C11 -175.3(3) .
C8 N2 C12 C13 179.8(3) .
Fe2 N2 C12 C13 5.2(4) .
C10 C11 C12 N2 -0.7(7) .
C10 C11 C12 C13 178.7(4) .
C19 N3 C13 C14 -2.9(6) .
Fe2 N3 C13 C14 175.4(3) .
C19 N3 C13 C12 176.3(4) .
Fe2 N3 C13 C12 -5.3(4) .
N2 C12 C13 C14 179.6(4) .
C11 C12 C13 C14 0.2(7) .
N2 C12 C13 N3 0.4(5) .
C11 C12 C13 N3 -179.0(4) .
N3 C13 C14 C15 2.3(6) .
C12 C13 C14 C15 -176.9(4) .
C13 C14 C15 C18 0.0(6) .
C13 C14 C15 C16 179.5(5) .
C18 C15 C16 C17 1.0(5) .
C14 C15 C16 C17 -178.5(5) .
C15 C16 C17 O2 -0.5(5) .
C15 C16 C17 C25 177.6(4) .
C18 O2 C17 C16 -0.1(5) .
C18 O2 C17 C25 -178.6(3) .
C17 O2 C18 C19 -178.9(4) .
C17 O2 C18 C15 0.8(4) .
C14 C15 C18 C19 -1.8(6) .
C16 C15 C18 C19 178.6(4) .
C14 C15 C18 O2 178.5(4) .
C16 C15 C18 O2 -1.1(5) .
C13 N3 C19 C18 1.1(6) .
Fe2 N3 C19 C18 -177.0(3) .
O2 C18 C19 N3 -179.1(4) .
C15 C18 C19 N3 1.2(7) .
C4 C3 C20 C21 -177.4(5) .
O1 C3 C20 C21 8.6(7) .
C4 C3 C20 C24 2.5(8) .
O1 C3 C20 C24 -171.5(5) .
C24 C20 C21 C22 0.3(8) .
C3 C20 C21 C22 -179.8(5) .
C23 N4 C22 C21 -0.3(8) .
Ag2 N4 C22 C21 -175.9(4) .
C20 C21 C22 N4 0.6(9) .
C22 N4 C23 C24 -1.0(8) .
Ag2 N4 C23 C24 174.5(4) .
N4 C23 C24 C20 1.9(9) .
C21 C20 C24 C23 -1.5(8) .
C3 C20 C24 C23 178.7(5) .
C16 C17 C25 C26 -170.0(5) .
O2 C17 C25 C26 8.1(6) .
C16 C17 C25 C29 9.1(7) .
O2 C17 C25 C29 -172.8(4) .
C29 C25 C26 C27 -0.9(7) .
C17 C25 C26 C27 178.3(4) .
C28 N5 C27 C26 -0.9(7) .
Ag1 N5 C27 C26 -178.7(4) .
C25 C26 C27 N5 1.8(8) .
C27 N5 C28 C29 -0.8(7) .
Ag1 N5 C28 C29 176.7(3) .
N5 C28 C29 C25 1.7(7) .
C26 C25 C29 C28 -0.7(6) .
C17 C25 C29 C28 -179.8(4) .
C36 N6 C30 C31 1.4(6) .
Fe1 N6 C30 C31 -172.1(3) .
C32 O3 C31 C30 -178.4(4) .
C32 O3 C31 C34 1.2(5) .
N6 C30 C31 O3 177.2(4) .
N6 C30 C31 C34 -2.4(7) .
C31 O3 C32 C33 -1.5(5) .
C31 O3 C32 C49 179.3(4) .
O3 C32 C33 C34 1.2(5) .
C49 C32 C33 C34 -179.8(5) .
O3 C31 C34 C35 -179.0(4) .
C30 C31 C34 C35 0.6(7) .
O3 C31 C34 C33 -0.5(5) .
C30 C31 C34 C33 179.1(4) .
C32 C33 C34 C35 177.6(5) .
C32 C33 C34 C31 -0.4(5) .
C31 C34 C35 C36 1.9(6) .
C33 C34 C35 C36 -175.9(5) .
C34 C35 C36 N6 -2.9(6) .
C34 C35 C36 C37 176.9(4) .
C30 N6 C36 C35 1.2(6) .
Fe1 N6 C36 C35 175.5(3) .
C30 N6 C36 C37 -178.6(4) .
Fe1 N6 C36 C37 -4.4(4) .
C41 N7 C37 C38 0.6(6) .
Fe1 N7 C37 C38 175.9(4) .
C41 N7 C37 C36 179.3(4) .
Fe1 N7 C37 C36 -5.4(5) .
C35 C36 C37 N7 -173.7(4) .
N6 C36 C37 N7 6.2(5) .
C35 C36 C37 C38 4.9(7) .
N6 C36 C37 C38 -175.2(4) .
N7 C37 C38 C39 0.4(7) .
C36 C37 C38 C39 -178.1(5) .
C37 C38 C39 C40 -0.4(8) .
C38 C39 C40 C41 -0.6(8) .
C37 N7 C41 C40 -1.6(6) .
Fe1 N7 C41 C40 -176.9(3) .
C37 N7 C41 C42 178.3(4) .
Fe1 N7 C41 C42 3.0(5) .
C39 C40 C41 N7 1.6(7) .
C39 C40 C41 C42 -178.3(5) .
C48 N8 C42 C43 -2.8(6) .
Fe1 N8 C42 C43 174.7(3) .
C48 N8 C42 C41 177.1(4) .
Fe1 N8 C42 C41 -5.4(4) .
N7 C41 C42 N8 1.8(5) .
C40 C41 C42 N8 -178.4(4) .
N7 C41 C42 C43 -178.3(4) .
C40 C41 C42 C43 1.5(7) .
N8 C42 C43 C44 1.3(7) .
C41 C42 C43 C44 -178.6(4) .
C42 C43 C44 C47 2.1(6) .
C42 C43 C44 C45 -179.4(5) .
C43 C44 C45 C46 -177.8(5) .
C47 C44 C45 C46 0.8(5) .
C44 C45 C46 O4 -0.4(5) .
C44 C45 C46 C54 175.0(4) .
C47 O4 C46 C45 -0.2(5) .
C47 O4 C46 C54 -176.5(4) .
C46 O4 C47 C48 -177.0(4) .
C46 O4 C47 C44 0.8(5) .
C43 C44 C47 O4 178.0(4) .
C45 C44 C47 O4 -1.0(5) .
C43 C44 C47 C48 -4.3(7) .
C45 C44 C47 C48 176.8(4) .
C42 N8 C48 C47 0.7(6) .
Fe1 N8 C48 C47 -176.5(3) .
O4 C47 C48 N8 -179.6(4) .
C44 C47 C48 N8 2.9(7) .
C33 C32 C49 C50 -163.8(5) .
O3 C32 C49 C50 15.2(7) .
C33 C32 C49 C53 17.8(8) .
O3 C32 C49 C53 -163.3(4) .
C53 C49 C50 C51 1.8(7) .
C32 C49 C50 C51 -176.7(5) .
C52 N9 C51 C50 -2.1(8) .
Ag1 N9 C51 C50 172.4(4) 1_545
C49 C50 C51 N9 0.6(8) .
C51 N9 C52 C53 1.3(7) .
Ag1 N9 C52 C53 -173.0(4) 1_545
N9 C52 C53 C49 1.0(7) .
C50 C49 C53 C52 -2.5(7) .
C32 C49 C53 C52 176.0(4) .
C45 C46 C54 C55 -155.7(5) .
O4 C46 C54 C55 19.6(6) .
C45 C46 C54 C58 24.9(7) .
O4 C46 C54 C58 -159.8(4) .
C58 C54 C55 C56 -1.3(6) .
C46 C54 C55 C56 179.2(4) .
C57 N10 C56 C55 -1.0(6) .
Ag2 N10 C56 C55 178.6(4) 1_354
C54 C55 C56 N10 1.6(7) .
C56 N10 C57 C58 0.2(7) .
Ag2 N10 C57 C58 -179.2(3) 1_354
N10 C57 C58 C54 -0.1(7) .
C55 C54 C58 C57 0.7(6) .
C46 C54 C58 C57 -179.9(4) .
C65 N11 C59 C60 2.7(6) .
Fe1 N11 C59 C60 -166.9(3) .
N11 C59 C60 O5 172.3(4) .
N11 C59 C60 C63 -2.8(7) .
C61 O5 C60 C59 -174.7(5) .
C61 O5 C60 C63 0.9(5) .
C60 O5 C61 C62 -2.1(6) .
C60 O5 C61 C78 173.8(4) .
O5 C61 C62 C63 2.6(6) .
C78 C61 C62 C63 -172.3(6) .
C59 C60 C63 C64 -0.1(7) .
O5 C60 C63 C64 -175.9(4) .
C59 C60 C63 C62 176.4(5) .
O5 C60 C63 C62 0.7(5) .
C61 C62 C63 C64 173.5(6) .
C61 C62 C63 C60 -1.9(6) .
C60 C63 C64 C65 3.0(7) .
C62 C63 C64 C65 -172.1(6) .
C59 N11 C65 C64 0.3(6) .
Fe1 N11 C65 C64 170.9(3) .
C59 N11 C65 C66 -175.8(4) .
Fe1 N11 C65 C66 -5.2(4) .
C63 C64 C65 N11 -3.1(7) .
C63 C64 C65 C66 172.5(4) .
C70 N12 C66 C67 -3.6(6) .
Fe1 N12 C66 C67 177.5(3) .
C70 N12 C66 C65 175.3(4) .
Fe1 N12 C66 C65 -3.7(5) .
N11 C65 C66 N12 5.6(5) .
C64 C65 C66 N12 -170.4(4) .
N11 C65 C66 C67 -175.6(4) .
C64 C65 C66 C67 8.3(7) .
N12 C66 C67 C68 1.6(7) .
C65 C66 C67 C68 -177.1(4) .
C66 C67 C68 C69 0.4(8) .
C67 C68 C69 C70 -0.5(8) .
C66 N12 C70 C69 3.5(6) .
Fe1 N12 C70 C69 -177.6(3) .
C66 N12 C70 C71 -175.8(4) .
Fe1 N12 C70 C71 3.2(5) .
C68 C69 C70 N12 -1.4(7) .
C68 C69 C70 C71 177.7(5) .
C77 N13 C71 C72 1.2(6) .
Fe1 N13 C71 C72 -175.2(3) .
C77 N13 C71 C70 177.5(4) .
Fe1 N13 C71 C70 1.2(4) .
N12 C70 C71 C72 173.7(4) .
C69 C70 C71 C72 -5.5(7) .
N12 C70 C71 N13 -2.7(5) .
C69 C70 C71 N13 178.1(4) .
N13 C71 C72 C73 -0.7(6) .
C70 C71 C72 C73 -176.7(4) .
C71 C72 C73 C76 -1.0(6) .
C71 C72 C73 C74 178.1(5) .
C76 C73 C74 C75 -1.3(5) .
C72 C73 C74 C75 179.5(5) .
C73 C74 C75 O6 0.6(5) .
C73 C74 C75 C83 -176.4(5) .
C76 O6 C75 C74 0.3(5) .
C76 O6 C75 C83 177.9(4) .
C75 O6 C76 C77 177.3(4) .
C75 O6 C76 C73 -1.2(5) .
C72 C73 C76 C77 2.4(7) .
C74 C73 C76 C77 -176.9(4) .
C72 C73 C76 O6 -179.1(4) .
C74 C73 C76 O6 1.6(5) .
C71 N13 C77 C76 0.1(6) .
Fe1 N13 C77 C76 176.0(3) .
O6 C76 C77 N13 179.7(4) .
C73 C76 C77 N13 -2.0(7) .
C62 C61 C78 C82 -15.0(9) .
O5 C61 C78 C82 170.3(5) .
C62 C61 C78 C79 160.0(6) .
O5 C61 C78 C79 -14.7(8) .
C82 C78 C79 C80 -1.3(8) .
C61 C78 C79 C80 -176.3(5) .
C81 N14 C80 C79 0.2(9) .
Ag1 N14 C80 C79 -172.1(5) .
C78 C79 C80 N14 0.6(9) .
C80 N14 C81 C82 -0.3(8) .
Ag1 N14 C81 C82 172.3(4) .
C79 C78 C82 C81 1.2(8) .
C61 C78 C82 C81 176.3(5) .
N14 C81 C82 C78 -0.4(9) .
C74 C75 C83 C84 152.3(5) .
O6 C75 C83 C84 -24.6(6) .
C74 C75 C83 C87 -27.1(8) .
O6 C75 C83 C87 156.0(4) .
C87 C83 C84 C85 2.1(6) .
C75 C83 C84 C85 -177.2(4) .
C86 N15 C85 C84 1.0(7) .
Ag1 N15 C85 C84 -168.3(4) 1_445
C83 C84 C85 N15 -2.0(7) .
C85 N15 C86 C87 -0.2(7) .
Ag1 N15 C86 C87 166.1(3) 1_445
N15 C86 C87 C83 0.5(7) .
C84 C83 C87 C86 -1.5(7) .
C75 C83 C87 C86 177.9(4) .
C94 N16 C88 C89 -1.8(6) .
Fe2 N16 C88 C89 173.2(3) .
C90 O7 C89 C88 175.6(4) .
C90 O7 C89 C92 -2.1(5) .
N16 C88 C89 O7 -178.0(4) .
N16 C88 C89 C92 -0.6(7) .
C89 O7 C90 C91 2.0(5) .
C89 O7 C90 C107 179.5(4) .
O7 C90 C91 C92 -1.1(6) .
C107 C90 C91 C92 -178.1(5) .
O7 C89 C92 C93 -179.9(4) .
C88 C89 C92 C93 2.3(7) .
O7 C89 C92 C91 1.5(5) .
C88 C89 C92 C91 -176.3(4) .
C90 C91 C92 C89 -0.3(6) .
C90 C91 C92 C93 -178.4(6) .
C89 C92 C93 C94 -1.6(7) .
C91 C92 C93 C94 176.4(5) .
C88 N16 C94 C93 2.5(6) .
Fe2 N16 C94 C93 -173.1(4) .
C88 N16 C94 C95 -179.8(4) .
Fe2 N16 C94 C95 4.7(4) .
C92 C93 C94 N16 -0.7(7) .
C92 C93 C94 C95 -178.2(4) .
C99 N17 C95 C96 2.6(6) .
Fe2 N17 C95 C96 179.8(3) .
C99 N17 C95 C94 -175.5(4) .
Fe2 N17 C95 C94 1.7(5) .
N16 C94 C95 N17 -4.1(5) .
C93 C94 C95 N17 173.6(4) .
N16 C94 C95 C96 177.9(4) .
C93 C94 C95 C96 -4.4(7) .
N17 C95 C96 C97 -0.5(7) .
C94 C95 C96 C97 177.4(5) .
C95 C96 C97 C98 -1.3(8) .
C96 C97 C98 C99 1.0(8) .
C95 N17 C99 C98 -2.9(6) .
Fe2 N17 C99 C98 179.9(3) .
C95 N17 C99 C100 173.4(4) .
Fe2 N17 C99 C100 -3.8(4) .
C97 C98 C99 N17 1.0(7) .
C97 C98 C99 C100 -174.7(4) .
C106 N18 C100 C101 1.6(6) .
Fe2 N18 C100 C101 170.7(3) .
C106 N18 C100 C99 -173.5(3) .
Fe2 N18 C100 C99 -4.4(4) .
N17 C99 C100 C101 -169.9(4) .
C98 C99 C100 C101 6.2(7) .
N17 C99 C100 N18 5.2(5) .
C98 C99 C100 N18 -178.8(4) .
N18 C100 C101 C102 -3.5(6) .
C99 C100 C101 C102 171.1(4) .
C100 C101 C102 C105 2.7(6) .
C100 C101 C102 C103 -170.9(5) .
C101 C102 C103 C104 173.2(5) .
C105 C102 C103 C104 -0.9(5) .
C102 C103 C104 O8 0.9(5) .
C102 C103 C104 C112 -177.7(5) .
C105 O8 C104 C103 -0.5(5) .
C105 O8 C104 C112 178.4(4) .
C104 O8 C105 C106 -174.5(4) .
C104 O8 C105 C102 -0.1(5) .
C101 C102 C105 O8 -174.8(4) .
C103 C102 C105 O8 0.6(5) .
C101 C102 C105 C106 -0.3(6) .
C103 C102 C105 C106 175.1(4) .
C100 N18 C106 C105 1.0(6) .
Fe2 N18 C106 C105 -166.6(3) .
O8 C105 C106 N18 172.1(4) .
C102 C105 C106 N18 -1.7(6) .
C91 C90 C107 C108 154.3(5) .
O7 C90 C107 C108 -22.6(7) .
C91 C90 C107 C111 -25.8(8) .
O7 C90 C107 C111 157.3(4) .
C111 C107 C108 C109 1.5(7) .
C90 C107 C108 C109 -178.6(4) .
C110 N19 C109 C108 2.4(7) .
Ag2 N19 C109 C108 -167.7(4) 1_455
C107 C108 C109 N19 -2.8(7) .
C109 N19 C110 C111 -0.9(7) .
Ag2 N19 C110 C111 167.6(4) 1_455
N19 C110 C111 C107 -0.2(8) .
C108 C107 C111 C110 -0.1(7) .
C90 C107 C111 C110 -180.0(5) .
C103 C104 C112 C113 174.0(6) .
O8 C104 C112 C113 -4.6(7) .
C103 C104 C112 C116 -5.6(8) .
O8 C104 C112 C116 175.8(4) .
C116 C112 C113 C114 -0.5(8) .
C104 C112 C113 C114 179.9(5) .
C115 N20 C114 C113 0.6(8) .
Ag2 N20 C114 C113 -175.9(4) 1_565
C112 C113 C114 N20 -0.1(9) .
C114 N20 C115 C116 -0.3(7) .
Ag2 N20 C115 C116 176.2(4) 1_565
N20 C115 C116 C112 -0.3(7) .
C113 C112 C116 C115 0.7(7) .
C104 C112 C116 C115 -179.7(4) .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.003 0.004 0.007 2413 557 ' '
