#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/70/1517022.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1517022
loop_
_publ_author_name
'Mazzanti, Virginia'
'Jiang, Huixin'
'Gotfredsen, Henrik'
'Morsing, Thorbjørn J'
'Parker, Christian R.'
'Nielsen, Mogens Brøndsted'
_publ_section_title
;
 The Gilded Edge in Acetylenic Scaffolding: Pd-Catalyzed Cross-Coupling
 Reactions of Phosphine-Gold(I) Oligoynyl Complexes.
;
_journal_issue                   14
_journal_name_full               'Organic letters'
_journal_page_first              3736
_journal_paper_doi               10.1021/ol5015587
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C32 H36 Au P Si, 2(C3 H3)'
_chemical_formula_sum            'C38 H42 Au P Si'
_chemical_formula_weight         754.78
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             2014-05-28
_audit_creation_method
;
Olex2 1.2
(compiled 2014.03.20 svn.r2918 for OlexSys, GUI svn.r4816)
;
_cell_angle_alpha                90
_cell_angle_beta                 113.278(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   25.9774(15)
_cell_length_b                   25.2649(15)
_cell_length_c                   11.2161(6)
_cell_measurement_reflns_used    9766
_cell_measurement_temperature    122(2)
_cell_measurement_theta_max      29.28
_cell_measurement_theta_min      2.55
_cell_volume                     6762.1(7)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine (Bourhis et al., 2013)'
_diffrn_ambient_temperature      122(2)
_diffrn_measured_fraction_theta_full 0.9994
_diffrn_measured_fraction_theta_max 0.9994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0838
_diffrn_reflns_av_unetI/netI     0.0392
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            115500
_diffrn_reflns_theta_full        26.3714
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.35
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.458
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.5618
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0994 before and 0.0685 after correction.
The Ratio of minimum to maximum transmission is 0.7529.
The λ/2 correction factor is 0.0000.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.4827
_exptl_crystal_description       Prism
_exptl_crystal_F_000             3024.0
_exptl_crystal_size_max          0.262
_exptl_crystal_size_mid          0.173
_exptl_crystal_size_min          0.098
_refine_diff_density_max         1.6385
_refine_diff_density_min         -1.1245
_refine_diff_density_rms         0.1622
_refine_ls_d_res_high            0.8000
_refine_ls_d_res_low             8.6740
_refine_ls_goodness_of_fit_ref   1.0753
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_constraints    72
_refine_ls_number_parameters     376
_refine_ls_number_reflns         6907
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.0751
_refine_ls_R_factor_all          0.0362
_refine_ls_R_factor_gt           0.0249
_refine_ls_shift/su_max          0.0002
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0361P)²+12.2719P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0594
_refine_ls_wR_factor_ref         0.0663
_reflns_Friedel_coverage         0.0
_reflns_limit_h_max              29
_reflns_limit_h_min              -32
_reflns_limit_k_max              31
_reflns_limit_k_min              0
_reflns_limit_l_max              14
_reflns_limit_l_min              0
_reflns_number_gt                5824
_reflns_number_total             6907
_reflns_threshold_expression     I>=2u(I)
_cod_data_source_file            ol5015587_si_002.cif
_cod_data_source_block           mo_D8V512_0m-1
_cod_depositor_comments
'Adding full bibliography for 1517022--1517023.cif.'
_cod_database_code               1517022
#BEGIN Tags that were not found in dictionaries:
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C35-C34 = C36-C35 = C36-C34_$1
 1.395 with sigma of 0.005
3.a Ternary CH refined with riding coordinates:
 C25(H25), C28(H28), C31(H31)
3.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C34(H34), C35(H35),
  C36(H36), C37(H37), C38(H38), C39(H39)
3.c Idealised Me refined as rotating group:
 C26(H26a,H26b,H26c), C27(H27a,H27b,H27c), C29(H29a,H29b,H29c), C30(H30a,H30b,
 H30c), C32(H32a,H32b,H32c), C33(H33a,H33b,H33c)
;
#END Tags that were not found in dictionaries
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y,-z+1/2
3 -x,-y,-z
4 x,-y,z-1/2
5 x+1/2,y+1/2,z
6 -x+1/2,y+1/2,-z+1/2
7 -x+1/2,-y+1/2,-z
8 x+1/2,-y+1/2,z-1/2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Au1 Au 0.111936(2) 0.139877(2) 0.635838(2) 0.01633(5) Uani 1.000000 1 . . .
P1 P 0.166425(3) 0.109889(3) 0.837603(3) 0.01524(16) Uani 1.000000 1 . . .
Si1 Si 0.103524(3) 0.375384(3) 0.587574(3) 0.01845(19) Uani 1.000000 1 . . .
C1 C 0.150682(3) 0.143603(3) 0.962489(3) 0.0181(5) Uani 1.000000 1 . . .
C2 C 0.095474(3) 0.160231(3) 0.931946(3) 0.0257(5) Uani 1.000000 1 . . .
H2 H 0.068525(3) 0.155497(3) 0.848338(3) 0.0309(6) Uiso 1.000000 1 R . .
C3 C 0.080843(3) 0.183718(3) 1.025853(3) 0.0315(5) Uani 1.000000 1 . . .
H3 H 0.044167(3) 0.194789(3) 1.005113(3) 0.0378(7) Uiso 1.000000 1 R . .
C4 C 0.120749(3) 0.190677(3) 1.150242(3) 0.0294(6) Uani 1.000000 1 . . .
H4 H 0.110721(3) 0.205819(3) 1.213565(3) 0.0353(7) Uiso 1.000000 1 R . .
C5 C 0.175373(3) 0.175238(3) 1.180725(3) 0.0278(6) Uani 1.000000 1 . . .
H5 H 0.202179(3) 0.180390(3) 1.264319(3) 0.0333(7) Uiso 1.000000 1 R . .
C6 C 0.190567(3) 0.152013(3) 1.087119(3) 0.0228(5) Uani 1.000000 1 . . .
H6 H 0.227588(3) 0.142062(3) 1.108007(3) 0.0274(6) Uiso 1.000000 1 R . .
C7 C 0.240536(3) 0.121745(3) 0.877897(3) 0.0167(5) Uani 1.000000 1 . . .
C8 C 0.277807(3) 0.081411(3) 0.886128(3) 0.0283(5) Uani 1.000000 1 . . .
H8 H 0.265977(3) 0.046393(3) 0.879746(3) 0.0340(7) Uiso 1.000000 1 R . .
C9 C 0.332273(3) 0.092536(3) 0.903677(3) 0.0353(6) Uani 1.000000 1 . . .
H9 H 0.356596(3) 0.064949(3) 0.907625(3) 0.0424(7) Uiso 1.000000 1 R . .
C10 C 0.351224(3) 0.144258(3) 0.915501(3) 0.0295(6) Uani 1.000000 1 . . .
H10 H 0.387990(3) 0.151524(3) 0.927053(3) 0.0355(7) Uiso 1.000000 1 R . .
C11 C 0.314996(3) 0.184745(3) 0.909948(3) 0.0319(6) Uani 1.000000 1 . . .
H11 H 0.327543(3) 0.219582(3) 0.919305(3) 0.0382(7) Uiso 1.000000 1 R . .
C12 C 0.259591(3) 0.174001(3) 0.890401(3) 0.0278(6) Uani 1.000000 1 . . .
H12 H 0.235256(3) 0.201677(3) 0.885672(3) 0.0334(7) Uiso 1.000000 1 R . .
C13 C 0.161637(3) 0.039567(3) 0.863402(3) 0.0166(5) Uani 1.000000 1 . . .
C14 C 0.135009(3) 0.006761(3) 0.757780(3) 0.0200(5) Uani 1.000000 1 . . .
H14 H 0.117921(3) 0.021214(3) 0.675106(3) 0.0240(6) Uiso 1.000000 1 R . .
C15 C 0.133732(3) -0.047664(3) 0.774873(3) 0.0243(5) Uani 1.000000 1 . . .
H15 H 0.116056(3) -0.069462(3) 0.703468(3) 0.0292(6) Uiso 1.000000 1 R . .
C16 C 0.158616(3) -0.069550(3) 0.897541(3) 0.0247(5) Uani 1.000000 1 . . .
H16 H 0.157936(3) -0.105982(3) 0.908684(3) 0.0297(6) Uiso 1.000000 1 R . .
C17 C 0.184505(3) -0.036931(3) 1.003479(3) 0.0247(5) Uani 1.000000 1 . . .
H17 H 0.201080(3) -0.051488(3) 1.086151(3) 0.0296(7) Uiso 1.000000 1 R . .
C18 C 0.185882(3) 0.017331(3) 0.987104(3) 0.0223(5) Uani 1.000000 1 . . .
H18 H 0.203054(3) 0.039042(3) 1.058933(3) 0.0267(6) Uiso 1.000000 1 R . .
C19 C 0.064716(3) 0.171112(3) 0.463088(3) 0.0158(5) Uani 1.000000 1 . . .
C20 C 0.035484(3) 0.192269(3) 0.364177(3) 0.0152(5) Uani 1.000000 1 . . .
C21 C 0.0 0.220585(3) 0.25 0.0144(6) Uani 1.000000 2 S T P
C22 C 0.0 0.275116(3) 0.25 0.0159(6) Uani 1.000000 2 S T P
C23 C 0.035703(3) 0.305021(3) 0.359263(3) 0.0187(5) Uani 1.000000 1 . . .
C24 C 0.064910(3) 0.332491(3) 0.448425(3) 0.0224(5) Uani 1.000000 1 . . .
C25 C 0.121281(3) 0.334252(3) 0.738561(3) 0.0216(5) Uani 1.000000 1 . . .
H25 H 0.141568(3) 0.356871(3) 0.813481(3) 0.0259(6) Uiso 1.000000 1 R . .
C26 C 0.068502(3) 0.313693(3) 0.753035(3) 0.0360(6) Uani 1.000000 1 . . .
H26a H 0.047021(3) 0.292619(3) 0.678750(3) 0.0540(9) Uiso 1.000000 1 GR . .
H26b H 0.079127(3) 0.292480(3) 0.830078(3) 0.0540(9) Uiso 1.000000 1 GR . .
H26c H 0.046320(3) 0.343110(3) 0.759337(3) 0.0540(9) Uiso 1.000000 1 GR . .
C27 C 0.158963(3) 0.287324(3) 0.742398(3) 0.0292(6) Uani 1.000000 1 . . .
H27a H 0.169723(3) 0.269451(3) 0.824225(3) 0.0438(9) Uiso 1.000000 1 GR . .
H27b H 0.138991(3) 0.263237(3) 0.673357(3) 0.0438(9) Uiso 1.000000 1 GR . .
H27c H 0.191861(3) 0.299786(3) 0.732023(3) 0.0438(9) Uiso 1.000000 1 GR . .
C28 C 0.168656(3) 0.399242(3) 0.571746(3) 0.0251(5) Uani 1.000000 1 . . .
H28 H 0.192473(3) 0.368221(3) 0.579990(3) 0.0301(7) Uiso 1.000000 1 R . .
C29 C 0.156795(3) 0.424192(3) 0.437934(3) 0.0434(6) Uani 1.000000 1 . . .
H29a H 0.132458(3) 0.454149(3) 0.425218(3) 0.0650(10) Uiso 1.000000 1 GR . .
H29b H 0.191420(3) 0.435449(3) 0.434186(3) 0.0650(10) Uiso 1.000000 1 GR . .
H29c H 0.139124(3) 0.398505(3) 0.371117(3) 0.0650(10) Uiso 1.000000 1 GR . .
C30 C 0.202236(3) 0.437926(3) 0.679797(3) 0.0311(6) Uani 1.000000 1 . . .
H30a H 0.237264(3) 0.445729(3) 0.673610(3) 0.0467(9) Uiso 1.000000 1 GR . .
H30b H 0.181262(3) 0.470036(3) 0.670742(3) 0.0467(9) Uiso 1.000000 1 GR . .
H30c H 0.209214(3) 0.422240(3) 0.762715(3) 0.0467(9) Uiso 1.000000 1 GR . .
C31 C 0.056426(3) 0.433081(3) 0.581612(3) 0.0278(6) Uani 1.000000 1 . . .
H31 H 0.062925(3) 0.459634(3) 0.525386(3) 0.0334(7) Uiso 1.000000 1 R . .
C32 C -0.006205(3) 0.420201(3) 0.519941(3) 0.0386(6) Uani 1.000000 1 . . .
H32a H -0.014845(3) 0.394157(3) 0.571584(3) 0.0578(9) Uiso 1.000000 1 GR . .
H32b H -0.027445(3) 0.451768(3) 0.515596(3) 0.0578(9) Uiso 1.000000 1 GR . .
H32c H -0.015615(3) 0.406599(3) 0.433958(3) 0.0578(9) Uiso 1.000000 1 GR . .
C33 C 0.071503(3) 0.459869(3) 0.713936(3) 0.0377(6) Uani 1.000000 1 . . .
H33a H 0.050011(3) 0.491755(3) 0.703005(3) 0.0566(9) Uiso 1.000000 1 GR . .
H33b H 0.063206(3) 0.436289(3) 0.771094(3) 0.0566(9) Uiso 1.000000 1 GR . .
H33c H 0.110723(3) 0.468323(3) 0.750491(3) 0.0566(9) Uiso 1.000000 1 GR . .
C34 C -0.258930(3) 0.294218(3) 0.059090(3) 0.0668(7) Uani 1.000000 1 D . .
H34 H -0.264866(3) 0.324439(3) 0.099281(3) 0.0802(8) Uiso 1.000000 1 R . .
C35 C -0.205600(3) 0.281334(3) 0.072429(3) 0.0613(7) Uani 1.000000 1 D . .
H35 H -0.175576(3) 0.302673(3) 0.121917(3) 0.0736(8) Uiso 1.000000 1 R . .
C36 C -0.196575(3) 0.236982(3) 0.012769(3) 0.0627(7) Uani 1.000000 1 D . .
H36 H -0.160539(3) 0.228215(3) 0.021113(3) 0.0752(8) Uiso 1.000000 1 R . .
C37 C -0.006324(3) 0.054186(3) 0.503396(3) 0.0280(6) Uani 1.000000 1 . . .
H37 H -0.010651(3) 0.090653(3) 0.505960(3) 0.0336(7) Uiso 1.000000 1 R . .
C38 C -0.026051(3) 0.021222(3) 0.574551(3) 0.0279(6) Uani 1.000000 1 . . .
H38 H -0.043666(3) 0.035635(3) 0.624885(3) 0.0334(7) Uiso 1.000000 1 R . .
C39 C 0.019719(3) 0.032832(3) 0.428819(3) 0.0273(6) Uani 1.000000 1 . . .
H39 H 0.033006(3) 0.054843(3) 0.380832(3) 0.0328(7) Uiso 1.000000 1 R . .
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
_atom_type_scat_dispersion_source
H 0.00000 0.00000 0.49300 0.32291 0.14019 0.04081 10.51090 26.12570 3.14236
57.79970 0.0030380000826
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
C 0.00347 0.00161 2.31000 1.02000 1.58860 0.86500 20.84390 10.20750 0.56870
51.65120 0.215599998832
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Au -1.84507 8.87037 16.88190 18.59130 25.55820 5.86000 0.46110 8.62160 1.48260
36.39560 12.0657997131
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Si 0.08192 0.07060 6.29150 3.03530 1.98910 1.54100 2.43860 32.33370 0.67850
81.69370 1.14069998264
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
P 0.10434 0.09671 6.43450 4.17910 1.78000 1.49080 1.90670 27.15700 0.52600
68.16450 1.11489999294
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C19 Au1 P1 176.217(4) . .
C1 P1 Au1 111.690(4) . .
C7 P1 Au1 111.947(3) . .
C7 P1 C1 105.629(3) . .
C13 P1 Au1 115.512(3) . .
C13 P1 C1 106.599(4) . .
C13 P1 C7 104.733(4) . .
C25 Si1 C24 107.210(4) . .
C28 Si1 C24 108.671(3) . .
C28 Si1 C25 110.747(3) . .
C31 Si1 C24 107.259(3) . .
C31 Si1 C25 112.535(4) . .
C31 Si1 C28 110.242(4) . .
C2 C1 P1 118.177(3) . .
C6 C1 P1 122.793(5) . .
C6 C1 C2 119.000(5) . .
H2 C2 C1 119.865(2) . .
C3 C2 C1 120.270(3) . .
C3 C2 H2 119.865(3) . .
H3 C3 C2 119.999(3) . .
C4 C3 C2 120.002(6) . .
C4 C3 H3 119.999(4) . .
H4 C4 C3 119.913(4) . .
C5 C4 C3 120.174(5) . .
C5 C4 H4 119.913(2) . .
H5 C5 C4 119.858(2) . .
C6 C5 C4 120.284(3) . .
C6 C5 H5 119.858(3) . .
C5 C6 C1 120.241(6) . .
H6 C6 C1 119.879(4) . .
H6 C6 C5 119.879(3) . .
C8 C7 P1 122.620(5) . .
C12 C7 P1 118.579(5) . .
C12 C7 C8 118.583(6) . .
H8 C8 C7 119.628(4) . .
C9 C8 C7 120.745(6) . .
C9 C8 H8 119.628(4) . .
H9 C9 C8 119.588(4) . .
C10 C9 C8 120.824(6) . .
C10 C9 H9 119.588(4) . .
H10 C10 C9 120.429(4) . .
C11 C10 C9 119.141(6) . .
C11 C10 H10 120.429(4) . .
H11 C11 C10 119.736(4) . .
C12 C11 C10 120.529(6) . .
C12 C11 H11 119.736(4) . .
C11 C12 C7 120.161(6) . .
H12 C12 C7 119.919(4) . .
H12 C12 C11 119.919(4) . .
C14 C13 P1 119.494(3) . .
C18 C13 P1 121.402(4) . .
C18 C13 C14 119.067(6) . .
H14 C14 C13 119.850(3) . .
C15 C14 C13 120.299(3) . .
C15 C14 H14 119.8505(16) . .
H15 C15 C14 119.8291(16) . .
C16 C15 C14 120.342(4) . .
C16 C15 H15 119.829(3) . .
H16 C16 C15 120.202(3) . .
C17 C16 C15 119.596(6) . .
C17 C16 H16 120.202(3) . .
H17 C17 C16 119.831(3) . .
C18 C17 C16 120.339(4) . .
C18 C17 H17 119.8305(16) . .
C17 C18 C13 120.337(4) . .
H18 C18 C13 119.832(3) . .
H18 C18 C17 119.8315(16) . .
C20 C19 Au1 175.707(6) . .
C21 C20 C19 176.310(6) . .
C20 C21 C20 120.340(6) 2 .
C22 C21 C20 119.830(3) . .
C22 C21 C20 119.830(3) . 2
C23 C22 C21 121.986(3) . .
C23 C22 C21 121.986(3) 2 .
C23 C22 C23 116.029(6) 2 .
C24 C23 C22 176.897(6) . .
C23 C24 Si1 174.609(6) . .
H25 C25 Si1 107.881(2) . .
C26 C25 Si1 111.762(4) . .
C26 C25 H25 107.881(2) . .
C27 C25 Si1 112.358(4) . .
C27 C25 H25 107.881(2) . .
C27 C25 C26 108.902(5) . .
H26a C26 C25 109.5 . .
H26b C26 C25 109.5 . .
H26b C26 H26a 109.5 . .
H26c C26 C25 109.5 . .
H26c C26 H26a 109.5 . .
H26c C26 H26b 109.5 . .
H27a C27 C25 109.5 . .
H27b C27 C25 109.5 . .
H27b C27 H27a 109.5 . .
H27c C27 C25 109.5 . .
H27c C27 H27a 109.5 . .
H27c C27 H27b 109.5 . .
H28 C28 Si1 107.129(3) . .
C29 C28 Si1 112.575(4) . .
C29 C28 H28 107.129(3) . .
C30 C28 Si1 112.591(4) . .
C30 C28 H28 107.129(3) . .
C30 C28 C29 109.949(5) . .
H29a C29 C28 109.5 . .
H29b C29 C28 109.5 . .
H29b C29 H29a 109.5 . .
H29c C29 C28 109.5 . .
H29c C29 H29a 109.5 . .
H29c C29 H29b 109.5 . .
H30a C30 C28 109.5 . .
H30b C30 C28 109.5 . .
H30b C30 H30a 109.5 . .
H30c C30 C28 109.5 . .
H30c C30 H30a 109.5 . .
H30c C30 H30b 109.5 . .
H31 C31 Si1 106.107(2) . .
C32 C31 Si1 114.225(5) . .
C32 C31 H31 106.107(3) . .
C33 C31 Si1 113.098(3) . .
C33 C31 H31 106.107(3) . .
C33 C31 C32 110.508(5) . .
H32a C32 C31 109.5 . .
H32b C32 C31 109.5 . .
H32b C32 H32a 109.5 . .
H32c C32 C31 109.5 . .
H32c C32 H32a 109.5 . .
H32c C32 H32b 109.5 . .
H33a C33 C31 109.5 . .
H33b C33 C31 109.5 . .
H33b C33 H33a 109.5 . .
H33c C33 C31 109.5 . .
H33c C33 H33a 109.5 . .
H33c C33 H33b 109.5 . .
C35 C34 H34 119.698(3) . .
C36 C34 H34 119.698(4) 7_455 .
C36 C34 C35 120.605(6) 7_455 .
H35 C35 C34 119.993(3) . .
C36 C35 C34 120.014(5) . .
C36 C35 H35 119.993(4) . .
C35 C36 C34 119.380(6) . 7_455
H36 C36 C34 120.310(4) . 7_455
H36 C36 C35 120.310(4) . .
C38 C37 H37 120.091(4) . .
C39 C37 H37 120.091(4) . .
C39 C37 C38 119.817(6) . .
H38 C38 C37 119.832(4) . .
C39 C38 C37 120.336(5) 3_556 .
C39 C38 H38 119.832(3) 3_556 .
C38 C39 C37 119.847(5) 3_556 .
H39 C39 C37 120.077(4) . .
H39 C39 C38 120.077(3) . 3_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.27311(11) .
Au1 C19 2.00078(10) .
P1 C1 1.81867(10) .
P1 C7 1.82011(14) .
P1 C13 1.81225(14) .
Si1 C24 1.83822(9) .
Si1 C25 1.88233(10) .
Si1 C28 1.86949(13) .
Si1 C31 1.88721(12) .
C1 C2 1.40085(12) .
C1 C6 1.38851(8) .
C2 H2 0.9300 .
C2 C3 1.38649(9) .
C3 H3 0.9300 .
C3 C4 1.38162(8) .
C4 H4 0.9300 .
C4 C5 1.37807(12) .
C5 H5 0.9300 .
C5 C6 1.38921(9) .
C6 H6 0.9300 .
C7 C8 1.38338(11) .
C7 C12 1.39743(12) .
C8 H8 0.9300 .
C8 C9 1.37822(12) .
C9 H9 0.9300 .
C9 C10 1.38417(12) .
C10 H10 0.9300 .
C10 C11 1.37460(11) .
C11 H11 0.9300 .
C11 C12 1.39422(12) .
C12 H12 0.9300 .
C13 C14 1.38608(8) .
C13 C18 1.39522(8) .
C14 H14 0.9300 .
C14 C15 1.39054(12) .
C15 H15 0.9300 .
C15 C16 1.38334(8) .
C16 H16 0.9300 .
C16 C17 1.38265(8) .
C17 H17 0.9300 .
C17 C18 1.38551(12) .
C18 H18 0.9300 .
C19 C20 1.19469(7) .
C20 C21 1.43821(8) .
C21 C22 1.37770(12) .
C22 C23 1.42639(8) 2
C22 C23 1.42639(8) .
C23 C24 1.20735(8) .
C25 H25 0.9800 .
C25 C26 1.53359(12) .
C25 C27 1.52726(11) .
C26 H26a 0.9600 .
C26 H26b 0.9600 .
C26 H26c 0.9600 .
C27 H27a 0.9600 .
C27 H27b 0.9600 .
C27 H27c 0.9600 .
C28 H28 0.9800 .
C28 C29 1.54251(9) .
C28 C30 1.53275(9) .
C29 H29a 0.9600 .
C29 H29b 0.9600 .
C29 H29c 0.9600 .
C30 H30a 0.9600 .
C30 H30b 0.9600 .
C30 H30c 0.9600 .
C31 H31 0.9800 .
C31 C32 1.53036(12) .
C31 C33 1.53451(9) .
C32 H32a 0.9600 .
C32 H32b 0.9600 .
C32 H32c 0.9600 .
C33 H33a 0.9600 .
C33 H33b 0.9600 .
C33 H33c 0.9600 .
C34 H34 0.9300 .
C34 C35 1.37250(12) .
C34 C36 1.36771(10) 7_455
C35 H35 0.9300 .
C35 C36 1.37200(10) .
C36 H36 0.9300 .
C37 H37 0.9300 .
C37 C38 1.38433(10) .
C37 C39 1.37684(10) .
C38 H38 0.9300 .
C38 C39 1.37785(12) 3_556
C39 H39 0.9300 .
#BEGIN Loops that were not found in dictionaries:
loop_
_restr_distance_atom_site_label_1
_restr_distance_atom_site_label_2
_restr_distance_site_symmetry_2
_restr_distance_target
_restr_distance_target_weight_param
_restr_distance_diff
C35 C34 1 1.3950 0.0050 0.0225
C36 C34 7_455 1.3950 0.0050 0.0273
C36 C35 1 1.3950 0.0050 0.0230
#END Loops that were not found in dictionaries
