#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/76/1517612.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1517612
loop_
_publ_author_name
'Ping-Shing Cheng'
'Sam C.K. Hau'
'Thomas C.W. Mak'
_publ_section_title
;
 Layer-type organosilver(I) complexes assembled with nitrate and
 functionalized phenylethynide ligands
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              110
_journal_page_last               119
_journal_volume                  403
_journal_year                    2013
_chemical_formula_moiety         'C9 H4 Ag2 N2 O3'
_chemical_formula_sum            'C9 H4 Ag2 N2 O3'
_chemical_formula_weight         403.88
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 106.0680(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   13.4303(8)
_cell_length_b                   23.1607(14)
_cell_length_c                   6.9961(4)
_cell_measurement_temperature    296(2)
_cell_volume                     2091.2(2)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_molecular_graphics    DIAMOND
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'SMART CCD APEX II'
_diffrn_measurement_method       'ω and φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0232
_diffrn_reflns_av_sigmaI/netI    0.0119
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            15684
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.81
_exptl_absorpt_coefficient_mu    3.735
_exptl_absorpt_correction_T_max  0.3166
_exptl_absorpt_correction_T_min  0.2568
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.566
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1520
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.40
_refine_diff_density_max         1.566
_refine_diff_density_min         -1.565
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     147
_refine_ls_number_reflns         1951
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0316
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0240P)²+17.0944P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0707
_refine_ls_wR_factor_ref         0.0731
_reflns_number_gt                1753
_reflns_number_total             1951
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2013-403-110-119-2.cif
_cod_data_source_block           L2
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               1517612
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.0000 0.5000 1.0000 0.04720(16) Uani 1 2 d S
Ag2 Ag 0.17582(3) 0.45702(2) 1.33494(6) 0.05656(15) Uani 1 1 d .
Ag3 Ag 0.0000 0.39099(3) 0.7500 0.0810(2) Uani 1 2 d S
C1 C 0.1339(3) 0.4560(2) 0.9829(7) 0.0423(10) Uani 1 1 d .
C2 C 0.2064(3) 0.4260(2) 0.9738(7) 0.0405(10) Uani 1 1 d .
C3 C 0.2939(3) 0.3910(2) 0.9659(7) 0.0414(10) Uani 1 1 d .
C4 C 0.3903(3) 0.4160(2) 0.9915(7) 0.0406(10) Uani 1 1 d .
H4 H 0.3985 0.4557 1.0099 0.049 Uiso 1 1 calc R
C5 C 0.4748(3) 0.3816(2) 0.9897(7) 0.0421(10) Uani 1 1 d .
C6 C 0.4643(4) 0.3229(2) 0.9621(10) 0.0614(15) Uani 1 1 d .
H6 H 0.5216 0.3000 0.9644 0.074 Uiso 1 1 calc R
C7 C 0.3684(5) 0.2984(2) 0.9312(13) 0.082(2) Uani 1 1 d .
H7 H 0.3604 0.2590 0.9079 0.098 Uiso 1 1 calc R
C8 C 0.2828(5) 0.3318(2) 0.9339(11) 0.0669(17) Uani 1 1 d .
H8 H 0.2182 0.3146 0.9145 0.080 Uiso 1 1 calc R
C9 C 0.5741(4) 0.4090(2) 1.0130(7) 0.0481(11) Uani 1 1 d .
N1 N 0.6500(3) 0.4319(2) 1.0291(8) 0.0632(12) Uani 1 1 d .
N2 N 0.1054(6) 0.3376(3) 0.4610(12) 0.101(2) Uani 1 1 d .
O1 O 0.1057(3) 0.38774(17) 0.5077(7) 0.0714(12) Uani 1 1 d .
O2 O 0.0652(8) 0.3036(3) 0.5562(16) 0.205(5) Uani 1 1 d .
O3 O 0.1480(9) 0.3245(4) 0.3349(15) 0.196(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C1 179.999(1) . 5_567
C1 Ag1 Ag2 51.81(13) . .
C1 Ag1 Ag2 128.19(13) 5_567 .
C1 Ag1 Ag2 128.19(13) . 5_567
C1 Ag1 Ag2 51.81(13) 5_567 5_567
Ag2 Ag1 Ag2 180.0 . 5_567
C1 Ag1 Ag2 51.31(13) . 6_565
C1 Ag1 Ag2 128.69(13) 5_567 6_565
Ag2 Ag1 Ag2 83.118(13) . 6_565
Ag2 Ag1 Ag2 96.881(13) 5_567 6_565
C1 Ag1 Ag2 128.69(13) . 2_557
C1 Ag1 Ag2 51.31(13) 5_567 2_557
Ag2 Ag1 Ag2 96.882(13) . 2_557
Ag2 Ag1 Ag2 83.119(13) 5_567 2_557
Ag2 Ag1 Ag2 180.000(16) 6_565 2_557
C1 Ag1 Ag3 55.50(13) . .
C1 Ag1 Ag3 124.50(13) 5_567 .
Ag2 Ag1 Ag3 92.751(11) . .
Ag2 Ag1 Ag3 87.250(11) 5_567 .
Ag2 Ag1 Ag3 86.048(10) 6_565 .
Ag2 Ag1 Ag3 93.952(11) 2_557 .
C1 Ag1 Ag3 124.50(13) . 5_567
C1 Ag1 Ag3 55.50(13) 5_567 5_567
Ag2 Ag1 Ag3 87.250(11) . 5_567
Ag2 Ag1 Ag3 92.749(11) 5_567 5_567
Ag2 Ag1 Ag3 93.952(10) 6_565 5_567
Ag2 Ag1 Ag3 86.048(10) 2_557 5_567
Ag3 Ag1 Ag3 180.0 . 5_567
N1 Ag2 O1 96.78(17) 2_657 1_556
N1 Ag2 C1 110.06(16) 2_657 .
O1 Ag2 C1 120.85(17) 1_556 .
N1 Ag2 C1 111.13(17) 2_657 6_566
O1 Ag2 C1 100.11(15) 1_556 6_566
C1 Ag2 C1 116.07(13) . 6_566
N1 Ag2 Ag1 151.88(12) 2_657 .
O1 Ag2 Ag1 106.67(12) 1_556 .
C1 Ag2 Ag1 44.12(11) . .
C1 Ag2 Ag1 80.25(11) 6_566 .
N1 Ag2 Ag1 135.57(13) 2_657 2_557
O1 Ag2 Ag1 64.50(10) 1_556 2_557
C1 Ag2 Ag1 114.10(11) . 2_557
C1 Ag2 Ag1 43.02(10) 6_566 2_557
Ag1 Ag2 Ag1 70.413(10) . 2_557
O1 Ag3 O1 176.54(19) . 2_556
O1 Ag3 C1 90.98(15) . 2_556
O1 Ag3 C1 91.06(15) 2_556 2_556
O1 Ag3 C1 91.06(15) . .
O1 Ag3 C1 90.98(15) 2_556 .
C1 Ag3 C1 107.8(2) 2_556 .
O1 Ag3 Ag1 120.09(10) . .
O1 Ag3 Ag1 63.15(10) 2_556 .
C1 Ag3 Ag1 76.57(11) 2_556 .
C1 Ag3 Ag1 42.58(10) . .
O1 Ag3 Ag1 63.15(10) . 2_556
O1 Ag3 Ag1 120.09(10) 2_556 2_556
C1 Ag3 Ag1 42.58(10) 2_556 2_556
C1 Ag3 Ag1 76.57(11) . 2_556
Ag1 Ag3 Ag1 69.424(17) . 2_556
C2 C1 Ag1 174.0(4) . .
C2 C1 Ag2 95.6(3) . .
Ag1 C1 Ag2 84.07(16) . .
C2 C1 Ag2 99.8(3) . 6_565
Ag1 C1 Ag2 85.66(16) . 6_565
Ag2 C1 Ag2 115.0(2) . 6_565
C2 C1 Ag3 93.6(3) . .
Ag1 C1 Ag3 81.92(15) . .
Ag2 C1 Ag3 126.21(19) . .
Ag2 C1 Ag3 115.28(19) 6_565 .
C1 C2 C3 178.9(5) . .
C4 C3 C8 119.2(4) . .
C4 C3 C2 120.2(4) . .
C8 C3 C2 120.6(4) . .
C3 C4 C5 119.8(4) . .
C3 C4 H4 120.1 . .
C5 C4 H4 120.1 . .
C6 C5 C4 121.0(5) . .
C6 C5 C9 120.4(4) . .
C4 C5 C9 118.5(4) . .
C7 C6 C5 119.1(5) . .
C7 C6 H6 120.4 . .
C5 C6 H6 120.4 . .
C6 C7 C8 121.0(5) . .
C6 C7 H7 119.5 . .
C8 C7 H7 119.5 . .
C7 C8 C3 119.9(5) . .
C7 C8 H8 120.1 . .
C3 C8 H8 120.1 . .
N1 C9 C5 178.0(6) . .
C9 N1 Ag2 158.8(5) . 2_657
O1 N2 O3 118.0(9) . .
O1 N2 O2 115.7(9) . .
O3 N2 O2 126.3(9) . .
N2 O1 Ag2 119.3(5) . 1_554
N2 O1 Ag3 104.7(5) . .
Ag2 O1 Ag3 135.32(18) 1_554 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.099(4) .
Ag1 C1 2.099(4) 5_567
Ag1 Ag2 2.9991(4) .
Ag1 Ag2 2.9992(4) 5_567
Ag1 Ag2 3.0676(4) 6_565
Ag1 Ag2 3.0676(4) 2_557
Ag1 Ag3 3.0714(7) .
Ag1 Ag3 3.0715(7) 5_567
Ag2 N1 2.341(5) 2_657
Ag2 O1 2.356(4) 1_556
Ag2 C1 2.370(5) .
Ag2 C1 2.401(5) 6_566
Ag2 Ag1 3.0676(4) 2_557
Ag3 O1 2.496(4) .
Ag3 O1 2.496(4) 2_556
Ag3 C1 2.557(5) 2_556
Ag3 C1 2.557(5) .
Ag3 Ag1 3.0714(7) 2_556
C1 C2 1.211(6) .
C1 Ag2 2.401(5) 6_565
C2 C3 1.441(6) .
C3 C4 1.384(6) .
C3 C8 1.392(7) .
C4 C5 1.390(6) .
C4 H4 0.9300 .
C5 C6 1.376(7) .
C5 C9 1.444(7) .
C6 C7 1.368(9) .
C6 H6 0.9300 .
C7 C8 1.389(8) .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 N1 1.127(7) .
N1 Ag2 2.341(5) 2_657
N2 O1 1.207(7) .
N2 O3 1.215(11) .
N2 O2 1.247(11) .
O1 Ag2 2.356(4) 1_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ag1 Ag2 N1 27.9(3) . 2_657
C1 Ag1 Ag2 N1 -152.1(3) 5_567 2_657
Ag2 Ag1 Ag2 N1 -68(5) 5_567 2_657
Ag2 Ag1 Ag2 N1 -17.2(3) 6_565 2_657
Ag2 Ag1 Ag2 N1 162.8(3) 2_557 2_657
Ag3 Ag1 Ag2 N1 68.5(3) . 2_657
Ag3 Ag1 Ag2 N1 -111.5(3) 5_567 2_657
C1 Ag1 Ag2 O1 -117.4(2) . 1_556
C1 Ag1 Ag2 O1 62.6(2) 5_567 1_556
Ag2 Ag1 Ag2 O1 147(5) 5_567 1_556
Ag2 Ag1 Ag2 O1 -162.48(11) 6_565 1_556
Ag2 Ag1 Ag2 O1 17.52(11) 2_557 1_556
Ag3 Ag1 Ag2 O1 -76.80(11) . 1_556
Ag3 Ag1 Ag2 O1 103.20(11) 5_567 1_556
C1 Ag1 Ag2 C1 180.000(1) 5_567 .
Ag2 Ag1 Ag2 C1 -95(5) 5_567 .
Ag2 Ag1 Ag2 C1 -45.08(17) 6_565 .
Ag2 Ag1 Ag2 C1 134.92(17) 2_557 .
Ag3 Ag1 Ag2 C1 40.60(17) . .
Ag3 Ag1 Ag2 C1 -139.40(17) 5_567 .
C1 Ag1 Ag2 C1 144.87(18) . 6_566
C1 Ag1 Ag2 C1 -35.13(18) 5_567 6_566
Ag2 Ag1 Ag2 C1 50(5) 5_567 6_566
Ag2 Ag1 Ag2 C1 99.79(11) 6_565 6_566
Ag2 Ag1 Ag2 C1 -80.21(11) 2_557 6_566
Ag3 Ag1 Ag2 C1 -174.53(11) . 6_566
Ag3 Ag1 Ag2 C1 5.47(11) 5_567 6_566
C1 Ag1 Ag2 Ag1 -171.69(17) . 2_557
C1 Ag1 Ag2 Ag1 8.31(17) 5_567 2_557
Ag2 Ag1 Ag2 Ag1 93(5) 5_567 2_557
Ag2 Ag1 Ag2 Ag1 143.226(15) 6_565 2_557
Ag2 Ag1 Ag2 Ag1 -36.774(15) 2_557 2_557
Ag3 Ag1 Ag2 Ag1 -131.093(9) . 2_557
Ag3 Ag1 Ag2 Ag1 48.908(9) 5_567 2_557
C1 Ag1 Ag3 O1 -53.2(2) . .
C1 Ag1 Ag3 O1 126.8(2) 5_567 .
Ag2 Ag1 Ag3 O1 -91.57(13) . .
Ag2 Ag1 Ag3 O1 88.43(13) 5_567 .
Ag2 Ag1 Ag3 O1 -8.67(13) 6_565 .
Ag2 Ag1 Ag3 O1 171.33(13) 2_557 .
Ag3 Ag1 Ag3 O1 39(5) 5_567 .
C1 Ag1 Ag3 O1 125.4(2) . 2_556
C1 Ag1 Ag3 O1 -54.6(2) 5_567 2_556
Ag2 Ag1 Ag3 O1 87.04(12) . 2_556
Ag2 Ag1 Ag3 O1 -92.97(12) 5_567 2_556
Ag2 Ag1 Ag3 O1 169.94(12) 6_565 2_556
Ag2 Ag1 Ag3 O1 -10.06(12) 2_557 2_556
Ag3 Ag1 Ag3 O1 -143(5) 5_567 2_556
C1 Ag1 Ag3 C1 -136.42(16) . 2_556
C1 Ag1 Ag3 C1 43.58(16) 5_567 2_556
Ag2 Ag1 Ag3 C1 -174.79(10) . 2_556
Ag2 Ag1 Ag3 C1 5.21(10) 5_567 2_556
Ag2 Ag1 Ag3 C1 -91.89(10) 6_565 2_556
Ag2 Ag1 Ag3 C1 88.11(10) 2_557 2_556
Ag3 Ag1 Ag3 C1 -44(4) 5_567 2_556
C1 Ag1 Ag3 C1 180.0 5_567 .
Ag2 Ag1 Ag3 C1 -38.37(16) . .
Ag2 Ag1 Ag3 C1 141.63(16) 5_567 .
Ag2 Ag1 Ag3 C1 44.54(16) 6_565 .
Ag2 Ag1 Ag3 C1 -135.46(16) 2_557 .
Ag3 Ag1 Ag3 C1 92(5) 5_567 .
C1 Ag1 Ag3 Ag1 -92.39(15) . 2_556
C1 Ag1 Ag3 Ag1 87.61(15) 5_567 2_556
Ag2 Ag1 Ag3 Ag1 -130.759(9) . 2_556
Ag2 Ag1 Ag3 Ag1 49.240(9) 5_567 2_556
Ag2 Ag1 Ag3 Ag1 -47.857(8) 6_565 2_556
Ag2 Ag1 Ag3 Ag1 132.143(8) 2_557 2_556
Ag3 Ag1 Ag3 Ag1 0(4) 5_567 2_556
C1 Ag1 C1 C2 71(9) 5_567 .
Ag2 Ag1 C1 C2 87(4) . .
Ag2 Ag1 C1 C2 -93(4) 5_567 .
Ag2 Ag1 C1 C2 -158(4) 6_565 .
Ag2 Ag1 C1 C2 22(4) 2_557 .
Ag3 Ag1 C1 C2 -41(4) . .
Ag3 Ag1 C1 C2 139(4) 5_567 .
C1 Ag1 C1 Ag2 -15(6) 5_567 .
Ag2 Ag1 C1 Ag2 179.998(2) 5_567 .
Ag2 Ag1 C1 Ag2 115.76(18) 6_565 .
Ag2 Ag1 C1 Ag2 -64.24(18) 2_557 .
Ag3 Ag1 C1 Ag2 -127.93(17) . .
Ag3 Ag1 C1 Ag2 52.07(17) 5_567 .
C1 Ag1 C1 Ag2 -131(6) 5_567 6_565
Ag2 Ag1 C1 Ag2 -115.76(18) . 6_565
Ag2 Ag1 C1 Ag2 64.24(18) 5_567 6_565
Ag2 Ag1 C1 Ag2 180.0 2_557 6_565
Ag3 Ag1 C1 Ag2 116.31(16) . 6_565
Ag3 Ag1 C1 Ag2 -63.69(16) 5_567 6_565
C1 Ag1 C1 Ag3 113(7) 5_567 .
Ag2 Ag1 C1 Ag3 127.93(17) . .
Ag2 Ag1 C1 Ag3 -52.07(17) 5_567 .
Ag2 Ag1 C1 Ag3 -116.31(17) 6_565 .
Ag2 Ag1 C1 Ag3 63.69(17) 2_557 .
Ag3 Ag1 C1 Ag3 180.0 5_567 .
N1 Ag2 C1 C2 19.5(4) 2_657 .
O1 Ag2 C1 C2 -91.8(3) 1_556 .
C1 Ag2 C1 C2 146.8(3) 6_566 .
Ag1 Ag2 C1 C2 -174.0(4) . .
Ag1 Ag2 C1 C2 -165.5(3) 2_557 .
N1 Ag2 C1 Ag1 -166.44(16) 2_657 .
O1 Ag2 C1 Ag1 82.18(19) 1_556 .
C1 Ag2 C1 Ag1 -39.1(2) 6_566 .
Ag1 Ag2 C1 Ag1 8.58(17) 2_557 .
N1 Ag2 C1 Ag2 -84.1(2) 2_657 6_565
O1 Ag2 C1 Ag2 164.57(16) 1_556 6_565
C1 Ag2 C1 Ag2 43.2(3) 6_566 6_565
Ag1 Ag2 C1 Ag2 82.39(19) . 6_565
Ag1 Ag2 C1 Ag2 90.97(17) 2_557 6_565
N1 Ag2 C1 Ag3 118.1(2) 2_657 .
O1 Ag2 C1 Ag3 6.7(3) 1_556 .
C1 Ag2 C1 Ag3 -114.60(13) 6_566 .
Ag1 Ag2 C1 Ag3 -75.5(2) . .
Ag1 Ag2 C1 Ag3 -66.9(2) 2_557 .
O1 Ag3 C1 C2 -47.8(3) . .
O1 Ag3 C1 C2 129.4(3) 2_556 .
C1 Ag3 C1 C2 -139.2(4) 2_556 .
Ag1 Ag3 C1 C2 176.1(4) . .
Ag1 Ag3 C1 C2 -109.8(3) 2_556 .
O1 Ag3 C1 Ag1 136.13(15) . .
O1 Ag3 C1 Ag1 -46.66(15) 2_556 .
C1 Ag3 C1 Ag1 44.76(8) 2_556 .
Ag1 Ag3 C1 Ag1 74.09(11) 2_556 .
O1 Ag3 C1 Ag2 -147.4(2) . .
O1 Ag3 C1 Ag2 29.8(2) 2_556 .
C1 Ag3 C1 Ag2 121.3(2) 2_556 .
Ag1 Ag3 C1 Ag2 76.5(2) . .
Ag1 Ag3 C1 Ag2 150.6(2) 2_556 .
O1 Ag3 C1 Ag2 54.84(19) . 6_565
O1 Ag3 C1 Ag2 -127.95(19) 2_556 6_565
C1 Ag3 C1 Ag2 -36.53(11) 2_556 6_565
Ag1 Ag3 C1 Ag2 -81.29(19) . 6_565
Ag1 Ag3 C1 Ag2 -7.19(14) 2_556 6_565
Ag1 C1 C2 C3 -133(27) . .
Ag2 C1 C2 C3 -47(29) . .
Ag2 C1 C2 C3 69(29) 6_565 .
Ag3 C1 C2 C3 -174(100) . .
C1 C2 C3 C4 -34(29) . .
C1 C2 C3 C8 145(29) . .
C8 C3 C4 C5 -1.5(8) . .
C2 C3 C4 C5 178.0(4) . .
C3 C4 C5 C6 0.2(8) . .
C3 C4 C5 C9 178.8(4) . .
C4 C5 C6 C7 1.6(9) . .
C9 C5 C6 C7 -177.0(6) . .
C5 C6 C7 C8 -2.2(11) . .
C6 C7 C8 C3 0.9(12) . .
C4 C3 C8 C7 1.0(9) . .
C2 C3 C8 C7 -178.5(6) . .
C6 C5 C9 N1 154(16) . .
C4 C5 C9 N1 -25(16) . .
C5 C9 N1 Ag2 144(15) . 2_657
O3 N2 O1 Ag2 4.9(11) . 1_554
O2 N2 O1 Ag2 -178.6(6) . 1_554
O3 N2 O1 Ag3 176.5(8) . .
O2 N2 O1 Ag3 -7.0(9) . .
O1 Ag3 O1 N2 8.9(5) 2_556 .
C1 Ag3 O1 N2 -117.2(5) 2_556 .
C1 Ag3 O1 N2 135.0(5) . .
Ag1 Ag3 O1 N2 167.8(4) . .
Ag1 Ag3 O1 N2 -150.6(5) 2_556 .
O1 Ag3 O1 Ag2 178.4(3) 2_556 1_554
C1 Ag3 O1 Ag2 52.3(3) 2_556 1_554
C1 Ag3 O1 Ag2 -55.5(3) . 1_554
Ag1 Ag3 O1 Ag2 -22.7(3) . 1_554
Ag1 Ag3 O1 Ag2 18.8(2) 2_556 1_554
