#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/76/1517614.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1517614
loop_
_publ_author_name
'Ping-Shing Cheng'
'Sam C.K. Hau'
'Thomas C.W. Mak'
_publ_section_title
;
 Layer-type organosilver(I) complexes assembled with nitrate and
 functionalized phenylethynide ligands
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              110
_journal_page_last               119
_journal_volume                  403
_journal_year                    2013
_chemical_formula_moiety         'C20 H20 Ag4 N4 O12 S2'
_chemical_formula_sum            'C20 H20 Ag4 N4 O12 S2'
_chemical_formula_weight         1004.00
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                102.6630(10)
_cell_angle_beta                 90.4210(10)
_cell_angle_gamma                95.6150(10)
_cell_formula_units_Z            2
_cell_length_a                   7.7120(3)
_cell_length_b                   10.9193(5)
_cell_length_c                   17.7306(8)
_cell_measurement_temperature    296(2)
_cell_volume                     1449.14(11)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_molecular_graphics    DIAMOND
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'SMART CCD APEX II'
_diffrn_measurement_method       'ω and φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0403
_diffrn_reflns_av_sigmaI/netI    0.0190
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            57761
_diffrn_reflns_theta_full        28.11
_diffrn_reflns_theta_max         28.11
_diffrn_reflns_theta_min         1.18
_exptl_absorpt_coefficient_mu    2.873
_exptl_absorpt_correction_T_max  0.5973
_exptl_absorpt_correction_T_min  0.4795
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.301
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             968
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.780
_refine_diff_density_min         -1.233
_refine_diff_density_rms         0.269
_refine_ls_extinction_coef       0.0049(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.141
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     394
_refine_ls_number_reflns         7035
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.0428
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0457P)²+1.5833P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0804
_refine_ls_wR_factor_ref         0.0962
_reflns_number_gt                5889
_reflns_number_total             7035
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2013-403-110-119-4.cif
_cod_data_source_block           L4
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1517614
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.17764(3) 0.49681(2) 0.533048(13) 0.03792(8) Uani 1 1 d .
Ag2 Ag 0.55489(4) 0.49714(4) 0.584565(19) 0.05941(11) Uani 1 1 d .
Ag3 Ag 0.30002(6) 0.67723(3) 0.69994(2) 0.07434(13) Uani 1 1 d .
Ag4 Ag 0.8633(8) 0.7055(3) 0.6291(6) 0.0713(7) Uani 0.63(3) 1 d P
Ag4' Ag 0.8867(7) 0.7139(4) 0.6442(3) 0.0562(7) Uani 0.37(3) 1 d P
C1 C 0.2954(4) 0.4720(3) 0.63676(19) 0.0395(7) Uani 1 1 d .
C2 C 0.3306(4) 0.4441(3) 0.6971(2) 0.0411(7) Uani 1 1 d .
C3 C 0.3627(5) 0.3962(3) 0.7650(2) 0.0424(7) Uani 1 1 d .
C4 C 0.3307(6) 0.4662(4) 0.8384(2) 0.0536(9) Uani 1 1 d .
H4 H 0.2918 0.5455 0.8440 0.064 Uiso 1 1 calc R
C5 C 0.3566(6) 0.4178(5) 0.9030(2) 0.0611(11) Uani 1 1 d .
H5 H 0.3339 0.4632 0.9521 0.073 Uiso 1 1 calc R
C6 C 0.4167(6) 0.3013(4) 0.8929(2) 0.0602(11) Uani 1 1 d .
C7 C 0.4516(6) 0.2310(4) 0.8219(3) 0.0616(11) Uani 1 1 d .
H7 H 0.4928 0.1525 0.8173 0.074 Uiso 1 1 calc R
C8 C 0.4248(5) 0.2786(4) 0.7571(2) 0.0507(9) Uani 1 1 d .
H8 H 0.4481 0.2321 0.7083 0.061 Uiso 1 1 calc R
N1 N 0.4428(8) 0.2506(5) 0.9625(3) 0.0913(17) Uani 1 1 d .
O1 O 0.5118(10) 0.1536(5) 0.9538(3) 0.154(3) Uani 1 1 d .
O2 O 0.3987(7) 0.3086(5) 1.0246(2) 0.1176(18) Uani 1 1 d .
C9 C 0.8496(4) 0.4871(3) 0.58406(18) 0.0347(6) Uani 1 1 d .
C10 C 0.8505(4) 0.4607(3) 0.64721(18) 0.0359(6) Uani 1 1 d .
C11 C 0.8638(4) 0.4193(3) 0.71868(18) 0.0370(6) Uani 1 1 d .
C12 C 0.8307(6) 0.4983(3) 0.7888(2) 0.0494(9) Uani 1 1 d .
H12 H 0.7976 0.5783 0.7899 0.059 Uiso 1 1 calc R
C13 C 0.8470(6) 0.4582(4) 0.8572(2) 0.0547(10) Uani 1 1 d .
H13 H 0.8259 0.5106 0.9044 0.066 Uiso 1 1 calc R
C14 C 0.8949(5) 0.3396(4) 0.8538(2) 0.0494(9) Uani 1 1 d .
C15 C 0.9265(6) 0.2582(4) 0.7856(2) 0.0554(10) Uani 1 1 d .
H15 H 0.9575 0.1779 0.7852 0.066 Uiso 1 1 calc R
C16 C 0.9111(6) 0.2992(4) 0.7177(2) 0.0519(9) Uani 1 1 d .
H16 H 0.9325 0.2459 0.6709 0.062 Uiso 1 1 calc R
N2 N 0.9177(6) 0.2979(4) 0.9270(2) 0.0689(11) Uani 1 1 d .
O3 O 0.9849(7) 0.2003(4) 0.9248(2) 0.0974(13) Uani 1 1 d .
O4 O 0.8690(7) 0.3626(4) 0.98591(19) 0.1027(15) Uani 1 1 d .
N3 N 0.6275(4) 0.7804(3) 0.5027(2) 0.0512(8) Uani 1 1 d .
O5 O 0.7786(4) 0.8082(4) 0.5302(3) 0.0936(13) Uani 1 1 d .
O6 O 0.5234(4) 0.7065(3) 0.52984(18) 0.0571(7) Uani 1 1 d .
O7 O 0.5815(5) 0.8242(3) 0.4485(2) 0.0731(9) Uani 1 1 d .
N4 N 0.6138(5) 0.8756(4) 0.7296(2) 0.0634(9) Uani 1 1 d .
O8 O 0.6212(6) 0.7595(4) 0.7190(2) 0.0902(12) Uani 1 1 d .
O9 O 0.4738(6) 0.9159(4) 0.7466(2) 0.0936(12) Uani 1 1 d .
O10 O 0.7430(7) 0.9439(5) 0.7221(3) 0.130(2) Uani 1 1 d .
O11 O 1.1650(4) 0.7702(2) 0.60880(17) 0.0515(6) Uani 1 1 d .
S1 S 1.25466(11) 0.88948(8) 0.58825(5) 0.04107(18) Uani 1 1 d .
C17 C 1.1316(6) 1.0115(4) 0.6362(2) 0.0544(9) Uani 1 1 d .
H17A H 1.1539 1.0269 0.6910 0.082 Uiso 1 1 calc R
H17B H 1.0096 0.9863 0.6250 0.082 Uiso 1 1 calc R
H17C H 1.1647 1.0872 0.6184 0.082 Uiso 1 1 calc R
C18 C 1.1851(5) 0.8791(4) 0.4916(2) 0.0483(8) Uani 1 1 d .
H18A H 1.0603 0.8636 0.4874 0.072 Uiso 1 1 calc R
H18B H 1.2358 0.8113 0.4581 0.072 Uiso 1 1 calc R
H18C H 1.2214 0.9570 0.4768 0.072 Uiso 1 1 calc R
O12 O 0.0749(6) 0.7491(4) 0.7816(2) 0.0908(13) Uani 1 1 d .
S2 S 0.0833(2) 0.87935(11) 0.83129(6) 0.0690(3) Uani 1 1 d .
C19 C -0.1015(9) 0.8756(6) 0.8911(3) 0.0893(17) Uani 1 1 d .
H19A H -0.0931 0.8130 0.9210 0.134 Uiso 1 1 calc R
H19B H -0.2060 0.8551 0.8592 0.134 Uiso 1 1 calc R
H19C H -0.1049 0.9568 0.9251 0.134 Uiso 1 1 calc R
C20 C 0.2473(10) 0.8879(8) 0.9029(4) 0.120(3) Uani 1 1 d .
H20A H 0.3583 0.8811 0.8790 0.180 Uiso 1 1 calc R
H20B H 0.2227 0.8201 0.9290 0.180 Uiso 1 1 calc R
H20C H 0.2500 0.9671 0.9396 0.180 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C9 159.80(12) . 2_666
C1 Ag1 C9 95.39(11) . 1_455
C9 Ag1 C9 104.56(9) 2_666 1_455
C1 Ag1 Ag2 109.51(9) . 2_666
C9 Ag1 Ag2 50.38(8) 2_666 2_666
C9 Ag1 Ag2 154.78(7) 1_455 2_666
C1 Ag1 Ag1 139.04(9) . 2_566
C9 Ag1 Ag1 60.82(8) 2_666 2_566
C9 Ag1 Ag1 43.74(7) 1_455 2_566
Ag2 Ag1 Ag1 111.130(13) 2_666 2_566
C1 Ag1 Ag2 47.09(9) . .
C9 Ag1 Ag2 113.10(8) 2_666 .
C9 Ag1 Ag2 142.33(7) 1_455 .
Ag2 Ag1 Ag2 62.847(12) 2_666 .
Ag1 Ag1 Ag2 173.860(14) 2_566 .
C1 Ag1 Ag4 126.31(15) . 2_666
C9 Ag1 Ag4 46.61(12) 2_666 2_666
C9 Ag1 Ag4 102.00(11) 1_455 2_666
Ag2 Ag1 Ag4 60.14(6) 2_666 2_666
Ag1 Ag1 Ag4 72.35(12) 2_566 2_666
Ag2 Ag1 Ag4 104.31(11) . 2_666
C1 Ag1 Ag3 44.11(10) . .
C9 Ag1 Ag3 138.24(9) 2_666 .
C9 Ag1 Ag3 88.01(7) 1_455 .
Ag2 Ag1 Ag3 112.498(14) 2_666 .
Ag1 Ag1 Ag3 120.098(15) 2_566 .
Ag2 Ag1 Ag3 63.399(11) . .
Ag4 Ag1 Ag3 167.50(12) 2_666 .
C1 Ag2 C9 151.57(12) . .
C1 Ag2 C10 124.16(11) . .
C9 Ag2 C10 27.50(10) . .
C1 Ag2 Ag1 160.30(9) . 2_666
C9 Ag2 Ag1 45.92(8) . 2_666
C10 Ag2 Ag1 73.18(7) . 2_666
C1 Ag2 Ag1 44.32(9) . .
C9 Ag2 Ag1 162.71(8) . .
C10 Ag2 Ag1 166.93(7) . .
Ag1 Ag2 Ag1 117.152(12) 2_666 .
C1 Ag2 Ag4 131.40(13) . .
C9 Ag2 Ag4 48.61(9) . .
C10 Ag2 Ag4 56.79(13) . .
Ag1 Ag2 Ag4 64.11(12) 2_666 .
Ag1 Ag2 Ag4 133.74(9) . .
C1 Ag2 Ag2 101.09(9) . 2_666
C9 Ag2 Ag2 105.83(8) . 2_666
C10 Ag2 Ag2 132.46(7) . 2_666
Ag1 Ag2 Ag2 60.014(11) 2_666 2_666
Ag1 Ag2 Ag2 57.137(10) . 2_666
Ag4 Ag2 Ag2 105.12(17) . 2_666
C1 Ag2 Ag4' 129.38(11) . .
C9 Ag2 Ag4' 48.00(11) . .
C10 Ag2 Ag4' 54.01(12) . .
Ag1 Ag2 Ag4' 66.93(7) 2_666 .
Ag1 Ag2 Ag4' 135.92(9) . .
Ag4 Ag2 Ag4' 4.11(15) . .
Ag2 Ag2 Ag4' 109.23(9) 2_666 .
C1 Ag2 Ag3 43.14(9) . .
C9 Ag2 Ag3 132.77(8) . .
C10 Ag2 Ag3 116.04(7) . .
Ag1 Ag2 Ag3 142.644(16) 2_666 .
Ag1 Ag2 Ag3 61.369(10) . .
Ag4 Ag2 Ag3 89.94(7) . .
Ag2 Ag2 Ag3 106.496(17) 2_666 .
Ag4' Ag2 Ag3 88.90(7) . .
C1 Ag3 O12 121.67(12) . .
C1 Ag3 O11 102.93(11) . 1_455
O12 Ag3 O11 85.27(14) . 1_455
C1 Ag3 O8 105.32(12) . .
O12 Ag3 O8 125.88(14) . .
O11 Ag3 O8 110.28(12) 1_455 .
C1 Ag3 C2 28.11(11) . .
O12 Ag3 C2 110.50(13) . .
O11 Ag3 C2 130.02(11) 1_455 .
O8 Ag3 C2 98.13(12) . .
C1 Ag3 Ag1 40.65(8) . .
O12 Ag3 Ag1 115.98(10) . .
O11 Ag3 Ag1 62.30(7) 1_455 .
O8 Ag3 Ag1 117.06(9) . .
C2 Ag3 Ag1 68.32(8) . .
C1 Ag3 Ag2 42.13(8) . .
O12 Ag3 Ag2 163.63(9) . .
O11 Ag3 Ag2 100.01(7) 1_455 .
O8 Ag3 Ag2 66.98(9) . .
C2 Ag3 Ag2 54.42(8) . .
Ag1 Ag3 Ag2 55.232(10) . .
C9 Ag4 O5 111.7(4) . .
C9 Ag4 O11 101.68(13) . .
O5 Ag4 O11 89.20(16) . .
C9 Ag4 O8 109.93(17) . .
O5 Ag4 O8 98.2(2) . .
O11 Ag4 O8 141.8(4) . .
C9 Ag4 Ag2 47.28(15) . .
O5 Ag4 Ag2 91.6(3) . .
O11 Ag4 Ag2 146.3(2) . .
O8 Ag4 Ag2 71.29(15) . .
C9 Ag4 Ag1 41.58(17) . 2_666
O5 Ag4 Ag1 71.0(3) . 2_666
O11 Ag4 Ag1 93.06(18) . 2_666
O8 Ag4 Ag1 124.8(3) . 2_666
Ag2 Ag4 Ag1 55.75(15) . 2_666
O11 Ag4' C9 101.30(18) . .
O11 Ag4' O8 152.0(3) . .
C9 Ag4' O8 106.4(2) . .
O11 Ag4' Ag2 139.66(19) . .
C9 Ag4' Ag2 43.69(12) . .
O8 Ag4' Ag2 67.63(16) . .
C2 C1 Ag1 166.8(3) . .
C2 C1 Ag2 103.2(3) . .
Ag1 C1 Ag2 88.59(12) . .
C2 C1 Ag3 89.7(3) . .
Ag1 C1 Ag3 95.25(13) . .
Ag2 C1 Ag3 94.73(13) . .
C1 C2 C3 173.2(4) . .
C1 C2 Ag3 62.2(2) . .
C3 C2 Ag3 123.9(3) . .
C8 C3 C4 119.7(3) . .
C8 C3 C2 119.7(3) . .
C4 C3 C2 120.6(3) . .
C5 C4 C3 120.2(4) . .
C5 C4 H4 119.9 . .
C3 C4 H4 119.9 . .
C6 C5 C4 118.5(4) . .
C6 C5 H5 120.8 . .
C4 C5 H5 120.8 . .
C7 C6 C5 122.9(4) . .
C7 C6 N1 119.3(5) . .
C5 C6 N1 117.8(5) . .
C6 C7 C8 118.9(4) . .
C6 C7 H7 120.5 . .
C8 C7 H7 120.5 . .
C7 C8 C3 119.9(4) . .
C7 C8 H8 120.1 . .
C3 C8 H8 120.1 . .
O1 N1 O2 123.8(5) . .
O1 N1 C6 117.1(6) . .
O2 N1 C6 119.1(6) . .
C10 C9 Ag1 170.2(3) . 2_666
C10 C9 Ag2 92.2(2) . .
Ag1 C9 Ag2 83.70(11) 2_666 .
C10 C9 Ag4 96.6(3) . .
Ag1 C9 Ag4 91.8(3) 2_666 .
Ag2 C9 Ag4 84.11(18) . .
C10 C9 Ag4' 91.0(3) . .
Ag1 C9 Ag4' 97.69(17) 2_666 .
Ag2 C9 Ag4' 88.31(17) . .
Ag4 C9 Ag4' 6.9(2) . .
C10 C9 Ag1 108.9(2) . 1_655
Ag1 C9 Ag1 75.44(9) 2_666 1_655
Ag2 C9 Ag1 158.89(14) . 1_655
Ag4 C9 Ag1 93.23(13) . 1_655
Ag4' C9 Ag1 91.27(14) . 1_655
C9 C10 C11 173.8(3) . .
C9 C10 Ag2 60.26(19) . .
C11 C10 Ag2 124.1(2) . .
C12 C11 C16 119.5(3) . .
C12 C11 C10 120.7(3) . .
C16 C11 C10 119.8(3) . .
C13 C12 C11 120.1(4) . .
C13 C12 H12 119.9 . .
C11 C12 H12 119.9 . .
C14 C13 C12 118.6(3) . .
C14 C13 H13 120.7 . .
C12 C13 H13 120.7 . .
C13 C14 C15 123.0(3) . .
C13 C14 N2 118.7(4) . .
C15 C14 N2 118.3(4) . .
C14 C15 C16 118.1(4) . .
C14 C15 H15 120.9 . .
C16 C15 H15 120.9 . .
C15 C16 C11 120.7(3) . .
C15 C16 H16 119.6 . .
C11 C16 H16 119.6 . .
O4 N2 O3 123.5(4) . .
O4 N2 C14 118.1(4) . .
O3 N2 C14 118.4(4) . .
O7 N3 O5 119.8(4) . .
O7 N3 O6 120.3(4) . .
O5 N3 O6 119.9(4) . .
N3 O5 Ag4 117.4(3) . .
O10 N4 O9 122.4(5) . .
O10 N4 O8 119.7(5) . .
O9 N4 O8 117.9(5) . .
N4 O8 Ag4' 106.3(4) . .
N4 O8 Ag4 107.3(3) . .
Ag4' O8 Ag4 7.2(2) . .
N4 O8 Ag3 101.4(3) . .
Ag4' O8 Ag3 134.6(2) . .
Ag4 O8 Ag3 128.1(3) . .
S1 O11 Ag4' 133.67(19) . .
S1 O11 Ag3 119.78(15) . 1_655
Ag4' O11 Ag3 93.85(17) . 1_655
S1 O11 Ag4 132.13(17) . .
Ag4' O11 Ag4 7.1(2) . .
Ag3 O11 Ag4 99.3(2) 1_655 .
O11 S1 C18 104.33(18) . .
O11 S1 C17 103.98(18) . .
C18 S1 C17 99.6(2) . .
S1 C17 H17A 109.5 . .
S1 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
S1 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
S1 C18 H18A 109.5 . .
S1 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
S1 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
S2 O12 Ag3 123.2(2) . .
O12 S2 C20 106.1(4) . .
O12 S2 C19 104.5(3) . .
C20 S2 C19 98.2(3) . .
S2 C19 H19A 109.5 . .
S2 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
S2 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
S2 C20 H20A 109.5 . .
S2 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
S2 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.126(3) .
Ag1 C9 2.132(3) 2_666
Ag1 C9 2.693(3) 1_455
Ag1 Ag2 2.9504(4) 2_666
Ag1 Ag1 2.9852(5) 2_566
Ag1 Ag2 3.0424(4) .
Ag1 Ag4 3.211(9) 2_666
Ag1 Ag3 3.2507(5) .
Ag2 C1 2.229(3) .
Ag2 C9 2.286(3) .
Ag2 C10 2.631(3) .
Ag2 Ag1 2.9505(4) 2_666
Ag2 Ag4 3.096(7) .
Ag2 Ag2 3.1254(7) 2_666
Ag2 Ag4' 3.308(6) .
Ag2 Ag3 3.3115(5) .
Ag3 C1 2.272(4) .
Ag3 O12 2.352(4) .
Ag3 O11 2.372(3) 1_455
Ag3 O8 2.544(5) .
Ag3 C2 2.569(4) .
Ag4 C9 2.335(5) .
Ag4 O5 2.397(9) .
Ag4 O11 2.418(5) .
Ag4 O8 2.494(5) .
Ag4 Ag1 3.211(9) 2_666
Ag4' O11 2.305(5) .
Ag4' C9 2.460(6) .
Ag4' O8 2.480(6) .
C1 C2 1.211(5) .
C2 C3 1.442(5) .
C3 C8 1.393(5) .
C3 C4 1.395(5) .
C4 C5 1.383(6) .
C4 H4 0.9300 .
C5 C6 1.371(7) .
C5 H5 0.9300 .
C6 C7 1.367(7) .
C6 N1 1.480(5) .
C7 C8 1.383(5) .
C7 H7 0.9300 .
C8 H8 0.9300 .
N1 O1 1.212(8) .
N1 O2 1.213(7) .
C9 C10 1.216(5) .
C9 Ag1 2.132(3) 2_666
C9 Ag1 2.693(3) 1_655
C10 C11 1.442(4) .
C11 C12 1.391(5) .
C11 C16 1.392(5) .
C12 C13 1.385(5) .
C12 H12 0.9300 .
C13 C14 1.370(6) .
C13 H13 0.9300 .
C14 C15 1.374(6) .
C14 N2 1.480(5) .
C15 C16 1.381(5) .
C15 H15 0.9300 .
C16 H16 0.9300 .
N2 O4 1.211(5) .
N2 O3 1.223(6) .
N3 O7 1.228(5) .
N3 O5 1.243(5) .
N3 O6 1.255(4) .
N4 O10 1.211(6) .
N4 O9 1.220(5) .
N4 O8 1.248(5) .
O11 S1 1.530(3) .
O11 Ag3 2.372(3) 1_655
S1 C18 1.769(4) .
S1 C17 1.778(4) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
O12 S2 1.495(4) .
S2 C20 1.767(7) .
S2 C19 1.785(6) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
