#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/76/1517616.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1517616
loop_
_publ_author_name
'Ping-Shing Cheng'
'Sam C.K. Hau'
'Thomas C.W. Mak'
_publ_section_title
;
 Layer-type organosilver(I) complexes assembled with nitrate and
 functionalized phenylethynide ligands
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              110
_journal_page_last               119
_journal_volume                  403
_journal_year                    2013
_chemical_formula_moiety         'C108 H84 Ag19 N7 O21'
_chemical_formula_sum            'C108 H84 Ag19 N7 O21'
_chemical_formula_weight         3865.35
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 129.5170(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   61.092(3)
_cell_length_b                   11.6850(5)
_cell_length_c                   40.4068(19)
_cell_measurement_temperature    296(2)
_cell_volume                     22251.9(18)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_molecular_graphics    DIAMOND
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'SMART CCD APEX II'
_diffrn_measurement_method       'ω and φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0890
_diffrn_reflns_av_sigmaI/netI    0.0502
_diffrn_reflns_limit_h_max       74
_diffrn_reflns_limit_h_min       -74
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       48
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_number            225677
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         0.86
_exptl_absorpt_coefficient_mu    3.327
_exptl_absorpt_correction_T_max  0.7320
_exptl_absorpt_correction_T_min  0.4351
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.308
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             14736
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.365
_refine_diff_density_min         -1.369
_refine_diff_density_rms         0.443
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1408
_refine_ls_number_reflns         20724
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      1.114
_refine_ls_R_factor_all          0.1011
_refine_ls_R_factor_gt           0.0338
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0375P)²+66.5622P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0698
_refine_ls_wR_factor_ref         0.1017
_reflns_number_gt                11875
_reflns_number_total             20724
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2013-403-110-119-6.cif
_cod_data_source_block           L6
_cod_original_cell_volume        22252.0(18)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               1517616
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.202157(12) 1.00521(5) 0.961526(19) 0.04500(16) Uani 1 1 d .
Ag2 Ag 0.195770(15) 1.28152(5) 0.98694(2) 0.05594(18) Uani 1 1 d .
Ag3 Ag 0.148861(13) 1.07297(6) 0.93810(2) 0.05190(18) Uani 1 1 d .
Ag4 Ag 0.166172(14) 0.62170(6) 0.95708(2) 0.0617(2) Uani 1 1 d .
Ag5 Ag 0.107237(12) 0.60258(5) 0.872577(18) 0.03953(15) Uani 1 1 d .
Ag6 Ag 0.110349(14) 0.85699(5) 0.89916(2) 0.04884(17) Uani 1 1 d .
Ag7 Ag 0.107449(12) 1.10231(5) 0.846275(18) 0.03756(14) Uani 1 1 d .
Ag8 Ag 0.049231(12) 1.10073(5) 0.814192(18) 0.03728(14) Uani 1 1 d .
Ag9 Ag 0.040187(16) 1.35378(5) 0.82961(2) 0.05555(19) Uani 1 1 d .
Ag10 Ag 0.251079(13) 1.00379(6) 0.95912(2) 0.05868(19) Uani 1 1 d .
Ag11 Ag 0.202150(12) 0.50919(5) 0.946576(19) 0.04681(16) Uani 1 1 d .
Ag12 Ag 0.151491(13) 0.57387(6) 0.86513(2) 0.05296(18) Uani 1 1 d .
Ag13 Ag 0.198663(15) 0.77840(5) 0.91065(2) 0.05894(19) Uani 1 1 d .
Ag14 Ag 0.168971(14) 1.11686(6) 0.88279(2) 0.0597(2) Uani 1 1 d .
Ag15 Ag 0.112960(14) 1.35743(5) 0.82990(2) 0.04913(17) Uani 1 1 d .
Ag16 Ag 0.043691(16) 0.85347(5) 0.75730(2) 0.05690(19) Uani 1 1 d .
Ag17 Ag 0.050524(12) 0.60209(5) 0.789171(18) 0.03867(14) Uani 1 1 d .
Ag18 Ag -0.004529(13) 0.59851(6) 0.70619(2) 0.05453(18) Uani 1 1 d .
Ag19 Ag 0.008407(13) 1.09846(6) 0.71972(2) 0.05344(18) Uani 1 1 d .
C1 C 0.19183(17) 1.0856(7) 0.9973(3) 0.047(2) Uani 1 1 d .
C2 C 0.19732(17) 1.1199(7) 1.0301(3) 0.049(2) Uani 1 1 d .
C3 C 0.2043(2) 1.1503(7) 1.0701(3) 0.053(2) Uani 1 1 d .
C4 C 0.2307(2) 1.1867(9) 1.1042(3) 0.079(3) Uani 1 1 d .
H4 H 0.2448 1.1929 1.1018 0.095 Uiso 1 1 calc R
C5 C 0.2367(3) 1.2148(10) 1.1426(3) 0.099(4) Uani 1 1 d .
H5 H 0.2546 1.2425 1.1654 0.119 Uiso 1 1 calc R
C6 C 0.2163(3) 1.2017(10) 1.1473(4) 0.088(4) Uani 1 1 d .
C7 C 0.1904(3) 1.1661(11) 1.1140(4) 0.100(4) Uani 1 1 d .
H7 H 0.1763 1.1599 1.1165 0.120 Uiso 1 1 calc R
C8 C 0.1845(2) 1.1383(10) 1.0757(3) 0.081(3) Uani 1 1 d .
H8 H 0.1666 1.1107 1.0530 0.097 Uiso 1 1 calc R
C9 C 0.2238(3) 1.2356(12) 1.1899(4) 0.146(6) Uani 1 1 d .
H9A H 0.2081 1.2193 1.1890 0.219 Uiso 1 1 calc R
H9B H 0.2280 1.3159 1.1947 0.219 Uiso 1 1 calc R
H9C H 0.2401 1.1929 1.2127 0.219 Uiso 1 1 calc R
C10 C 0.12349(15) 0.6803(6) 0.9316(3) 0.0377(18) Uani 1 1 d .
C11 C 0.13000(16) 0.7178(6) 0.9649(3) 0.0418(19) Uani 1 1 d .
C12 C 0.13548(18) 0.7502(7) 1.0040(3) 0.050(2) Uani 1 1 d .
C13 C 0.1534(3) 0.8375(10) 1.0296(4) 0.099(4) Uani 1 1 d .
H13 H 0.1631 0.8777 1.0225 0.118 Uiso 1 1 calc R
C14 C 0.1572(3) 0.8661(11) 1.0668(4) 0.116(5) Uani 1 1 d .
H14 H 0.1694 0.9258 1.0841 0.139 Uiso 1 1 calc R
C15 C 0.1436(3) 0.8087(13) 1.0778(4) 0.096(4) Uani 1 1 d .
C16 C 0.1251(3) 0.7295(13) 1.0514(4) 0.120(5) Uani 1 1 d .
H16 H 0.1141 0.6947 1.0569 0.144 Uiso 1 1 calc R
C17 C 0.1218(2) 0.6977(10) 1.0158(3) 0.091(4) Uani 1 1 d .
H17 H 0.1097 0.6373 0.9992 0.109 Uiso 1 1 calc R
C18 C 0.1485(4) 0.8472(14) 1.1189(4) 0.169(8) Uani 1 1 d .
H18A H 0.1399 0.7929 1.1254 0.253 Uiso 1 1 calc R
H18B H 0.1401 0.9211 1.1142 0.253 Uiso 1 1 calc R
H18C H 0.1685 0.8513 1.1425 0.253 Uiso 1 1 calc R
C19 C 0.10192(15) 1.0551(6) 0.8916(2) 0.0356(18) Uani 1 1 d .
C20 C 0.09806(15) 1.0456(6) 0.9174(3) 0.0384(18) Uani 1 1 d .
C21 C 0.09300(16) 1.0423(7) 0.9480(2) 0.046(2) Uani 1 1 d .
C22 C 0.1035(2) 1.1291(8) 0.9781(3) 0.060(2) Uani 1 1 d .
H22 H 0.1132 1.1908 0.9782 0.072 Uiso 1 1 calc R
C23 C 0.0994(2) 1.1222(9) 1.0082(3) 0.075(3) Uani 1 1 d .
H23 H 0.1067 1.1795 1.0288 0.090 Uiso 1 1 calc R
C24 C 0.0848(2) 1.0338(11) 1.0084(3) 0.078(3) Uani 1 1 d .
C25 C 0.0749(2) 0.9494(10) 0.9787(4) 0.081(3) Uani 1 1 d .
H25 H 0.0650 0.8886 0.9786 0.097 Uiso 1 1 calc R
C26 C 0.0790(2) 0.9513(8) 0.9488(3) 0.065(3) Uani 1 1 d .
H26 H 0.0724 0.8914 0.9293 0.079 Uiso 1 1 calc R
C27 C 0.0806(3) 1.0285(13) 1.0416(4) 0.129(5) Uani 1 1 d .
H27A H 0.0624 1.0597 1.0297 0.194 Uiso 1 1 calc R
H27B H 0.0952 1.0723 1.0664 0.194 Uiso 1 1 calc R
H27C H 0.0817 0.9504 1.0498 0.194 Uiso 1 1 calc R
C28 C 0.03081(16) 1.1719(6) 0.8400(2) 0.0387(18) Uani 1 1 d .
C29 C 0.02379(15) 1.2159(6) 0.8593(2) 0.0393(18) Uani 1 1 d .
C30 C 0.01512(17) 1.2571(7) 0.8826(3) 0.0426(19) Uani 1 1 d .
C31 C 0.0230(2) 1.1996(9) 0.9184(3) 0.072(3) Uani 1 1 d .
H31 H 0.0345 1.1352 0.9279 0.086 Uiso 1 1 calc R
C32 C 0.0138(3) 1.2368(12) 0.9402(4) 0.097(4) Uani 1 1 d .
H32 H 0.0192 1.1960 0.9641 0.116 Uiso 1 1 calc R
C33 C -0.0028(3) 1.3301(12) 0.9279(4) 0.091(4) Uani 1 1 d .
C34 C -0.0104(2) 1.3902(9) 0.8926(4) 0.077(3) Uani 1 1 d .
H34 H -0.0216 1.4555 0.8838 0.092 Uiso 1 1 calc R
C35 C -0.00152(19) 1.3537(7) 0.8700(3) 0.060(2) Uani 1 1 d .
H35 H -0.0068 1.3948 0.8461 0.072 Uiso 1 1 calc R
C36 C -0.0130(3) 1.3720(14) 0.9514(5) 0.166(7) Uani 1 1 d .
H36A H -0.0303 1.4143 0.9320 0.249 Uiso 1 1 calc R
H36B H 0.0012 1.4207 0.9747 0.249 Uiso 1 1 calc R
H36C H -0.0163 1.3078 0.9625 0.249 Uiso 1 1 calc R
C37 C 0.05025(15) 1.5493(6) 0.8393(3) 0.0395(19) Uani 1 1 d .
C38 C 0.05327(15) 1.5380(6) 0.8717(3) 0.0390(18) Uani 1 1 d .
C39 C 0.05780(16) 1.5316(7) 0.9117(2) 0.0411(19) Uani 1 1 d .
C40 C 0.0741(2) 1.4466(8) 0.9410(3) 0.066(3) Uani 1 1 d .
H40 H 0.0831 1.3936 0.9362 0.079 Uiso 1 1 calc R
C41 C 0.0770(3) 1.4403(10) 0.9782(3) 0.092(4) Uani 1 1 d .
H41 H 0.0882 1.3831 0.9982 0.110 Uiso 1 1 calc R
C42 C 0.0636(3) 1.5164(11) 0.9858(4) 0.086(3) Uani 1 1 d .
C43 C 0.0476(2) 1.6008(10) 0.9565(4) 0.083(3) Uani 1 1 d .
H43 H 0.0386 1.6539 0.9614 0.099 Uiso 1 1 calc R
C44 C 0.04451(19) 1.6086(8) 0.9196(3) 0.062(2) Uani 1 1 d .
H44 H 0.0333 1.6664 0.8998 0.075 Uiso 1 1 calc R
C45 C 0.0664(3) 1.5037(14) 1.0262(4) 0.155(7) Uani 1 1 d .
H45A H 0.0516 1.5469 1.0226 0.232 Uiso 1 1 calc R
H45B H 0.0845 1.5319 1.0506 0.232 Uiso 1 1 calc R
H45C H 0.0646 1.4245 1.0304 0.232 Uiso 1 1 calc R
C46 C 0.29829(15) 1.0205(6) 1.0013(3) 0.0411(19) Uani 1 1 d .
C47 C 0.30252(16) 1.0155(7) 0.9757(3) 0.045(2) Uani 1 1 d .
C48 C 0.3078(2) 1.0047(8) 0.9463(3) 0.061(2) Uani 1 1 d .
C49 C 0.3267(3) 1.0704(9) 0.9479(4) 0.090(4) Uani 1 1 d .
H49 H 0.3370 1.1252 0.9694 0.108 Uiso 1 1 calc R
C50 C 0.3309(3) 1.0583(12) 0.9183(5) 0.118(5) Uani 1 1 d .
H50 H 0.3441 1.1045 0.9204 0.142 Uiso 1 1 calc R
C51 C 0.3163(4) 0.9810(12) 0.8868(5) 0.113(5) Uani 1 1 d .
C52 C 0.2969(4) 0.9119(14) 0.8845(5) 0.150(7) Uani 1 1 d .
H52 H 0.2863 0.8585 0.8625 0.180 Uiso 1 1 calc R
C53 C 0.2934(3) 0.9226(11) 0.9147(4) 0.113(5) Uani 1 1 d .
H53 H 0.2811 0.8733 0.9139 0.136 Uiso 1 1 calc R
C54 C 0.3200(4) 0.9697(14) 0.8526(5) 0.194(9) Uani 1 1 d .
H54A H 0.3233 1.0440 0.8464 0.291 Uiso 1 1 calc R
H54B H 0.3031 0.9374 0.8270 0.291 Uiso 1 1 calc R
H54C H 0.3358 0.9209 0.8632 0.291 Uiso 1 1 calc R
C55 C 0.19492(17) 0.5869(7) 0.8925(3) 0.046(2) Uani 1 1 d .
C56 C 0.20516(17) 0.6103(7) 0.8760(3) 0.048(2) Uani 1 1 d .
C57 C 0.2181(2) 0.6257(7) 0.8567(3) 0.056(2) Uani 1 1 d .
C58 C 0.2463(2) 0.6006(9) 0.8792(3) 0.079(3) Uani 1 1 d .
H58 H 0.2576 0.5788 0.9078 0.095 Uiso 1 1 calc R
C59 C 0.2580(3) 0.6079(12) 0.8590(4) 0.105(4) Uani 1 1 d .
H59 H 0.2771 0.5904 0.8746 0.126 Uiso 1 1 calc R
C60 C 0.2427(4) 0.6395(12) 0.8177(5) 0.106(4) Uani 1 1 d .
C61 C 0.2151(3) 0.6673(12) 0.7953(4) 0.109(5) Uani 1 1 d .
H61 H 0.2045 0.6920 0.7671 0.131 Uiso 1 1 calc R
C62 C 0.2022(2) 0.6596(10) 0.8140(3) 0.091(4) Uani 1 1 d .
H62 H 0.1831 0.6771 0.7980 0.109 Uiso 1 1 calc R
C63 C 0.2555(4) 0.6432(15) 0.7955(5) 0.178(8) Uani 1 1 d .
H63A H 0.2538 0.7192 0.7850 0.267 Uiso 1 1 calc R
H63B H 0.2457 0.5903 0.7719 0.267 Uiso 1 1 calc R
H63C H 0.2752 0.6225 0.8155 0.267 Uiso 1 1 calc R
C64 C 0.20378(15) 0.9774(6) 0.9108(3) 0.0404(19) Uani 1 1 d .
C65 C 0.20255(15) 0.9748(7) 0.8791(3) 0.046(2) Uani 1 1 d .
C66 C 0.20036(19) 0.9773(7) 0.8415(3) 0.050(2) Uani 1 1 d .
C67 C 0.2222(3) 1.0171(11) 0.8443(4) 0.112(5) Uani 1 1 d .
H67 H 0.2384 1.0437 0.8706 0.135 Uiso 1 1 calc R
C68 C 0.2210(3) 1.0193(13) 0.8090(4) 0.123(5) Uani 1 1 d .
H68 H 0.2367 1.0455 0.8122 0.148 Uiso 1 1 calc R
C69 C 0.1980(3) 0.9848(10) 0.7704(4) 0.080(3) Uani 1 1 d .
C70 C 0.1764(2) 0.9441(11) 0.7679(3) 0.091(4) Uani 1 1 d .
H70 H 0.1603 0.9175 0.7416 0.109 Uiso 1 1 calc R
C71 C 0.1772(2) 0.9400(10) 0.8028(3) 0.081(3) Uani 1 1 d .
H71 H 0.1617 0.9114 0.7996 0.097 Uiso 1 1 calc R
C72 C 0.1962(3) 0.9880(13) 0.7313(4) 0.138(6) Uani 1 1 d .
H72A H 0.1904 1.0629 0.7187 0.165 Uiso 1 1 calc R
H72B H 0.1826 0.9325 0.7107 0.165 Uiso 1 1 calc R
H72C H 0.2144 0.9705 0.7395 0.165 Uiso 1 1 calc R
C73 C 0.10427(14) 0.5561(6) 0.8189(2) 0.0362(18) Uani 1 1 d .
C74 C 0.10439(15) 0.5441(6) 0.7890(2) 0.0393(19) Uani 1 1 d .
C75 C 0.10400(16) 0.5381(7) 0.7524(2) 0.0431(19) Uani 1 1 d .
C76 C 0.11643(19) 0.6231(8) 0.7458(3) 0.060(2) Uani 1 1 d .
H76 H 0.1243 0.6866 0.7638 0.072 Uiso 1 1 calc R
C77 C 0.1172(2) 0.6142(9) 0.7122(3) 0.073(3) Uani 1 1 d .
H77 H 0.1256 0.6722 0.7079 0.088 Uiso 1 1 calc R
C78 C 0.1058(2) 0.5214(9) 0.6853(3) 0.072(3) Uani 1 1 d .
C79 C 0.0927(2) 0.4397(9) 0.6914(3) 0.076(3) Uani 1 1 d .
H79 H 0.0839 0.3784 0.6724 0.091 Uiso 1 1 calc R
C80 C 0.0921(2) 0.4458(8) 0.7251(3) 0.067(3) Uani 1 1 d .
H80 H 0.0837 0.3875 0.7292 0.081 Uiso 1 1 calc R
C81 C 0.1076(3) 0.5128(11) 0.6496(4) 0.115(5) Uani 1 1 d .
H81A H 0.1057 0.5877 0.6382 0.138 Uiso 1 1 calc R
H81B H 0.0927 0.4642 0.6272 0.138 Uiso 1 1 calc R
H81C H 0.1257 0.4812 0.6608 0.138 Uiso 1 1 calc R
C82 C 0.12719(15) 1.1817(6) 0.8243(2) 0.0379(18) Uani 1 1 d .
C83 C 0.13880(16) 1.2198(6) 0.8109(2) 0.0382(18) Uani 1 1 d .
C84 C 0.15096(17) 1.2544(6) 0.7917(2) 0.0409(19) Uani 1 1 d .
C85 C 0.1410(2) 1.2147(8) 0.7523(3) 0.068(3) Uani 1 1 d .
H85 H 0.1257 1.1642 0.7371 0.082 Uiso 1 1 calc R
C86 C 0.1534(3) 1.2488(11) 0.7355(4) 0.090(4) Uani 1 1 d .
H86 H 0.1465 1.2193 0.7091 0.108 Uiso 1 1 calc R
C87 C 0.1752(3) 1.3237(11) 0.7554(4) 0.089(4) Uani 1 1 d .
C88 C 0.1858(3) 1.3613(10) 0.7953(4) 0.096(4) Uani 1 1 d .
H88 H 0.2015 1.4096 0.8106 0.115 Uiso 1 1 calc R
C89 C 0.1735(2) 1.3284(8) 0.8130(3) 0.075(3) Uani 1 1 d .
H89 H 0.1806 1.3568 0.8397 0.090 Uiso 1 1 calc R
C90 C 0.1890(3) 1.3621(13) 0.7364(5) 0.150(7) Uani 1 1 d .
H90A H 0.2025 1.4217 0.7539 0.225 Uiso 1 1 calc R
H90B H 0.1747 1.3904 0.7079 0.225 Uiso 1 1 calc R
H90C H 0.1986 1.2984 0.7356 0.225 Uiso 1 1 calc R
C91 C 0.03640(16) 0.6713(6) 0.7298(3) 0.0415(19) Uani 1 1 d .
C92 C 0.03295(15) 0.7145(6) 0.6995(2) 0.0401(19) Uani 1 1 d .
C93 C 0.02909(17) 0.7552(7) 0.6624(3) 0.046(2) Uani 1 1 d .
C94 C 0.0420(2) 0.6985(9) 0.6487(3) 0.072(3) Uani 1 1 d .
H94 H 0.0533 0.6348 0.6637 0.086 Uiso 1 1 calc R
C95 C 0.0380(3) 0.7365(12) 0.6128(4) 0.097(4) Uani 1 1 d .
H95 H 0.0470 0.6982 0.6042 0.117 Uiso 1 1 calc R
C96 C 0.0214(3) 0.8274(12) 0.5898(4) 0.097(4) Uani 1 1 d .
C97 C 0.0092(3) 0.8849(10) 0.6038(3) 0.089(4) Uani 1 1 d .
H97 H -0.0016 0.9497 0.5891 0.107 Uiso 1 1 calc R
C98 C 0.01254(19) 0.8493(8) 0.6393(3) 0.062(3) Uani 1 1 d .
H98 H 0.0036 0.8889 0.6477 0.075 Uiso 1 1 calc R
C99 C 0.0173(4) 0.8712(14) 0.5504(4) 0.170(8) Uani 1 1 d .
H99A H -0.0026 0.8765 0.5265 0.255 Uiso 1 1 calc R
H99B H 0.0260 0.8191 0.5435 0.255 Uiso 1 1 calc R
H99C H 0.0258 0.9453 0.5564 0.255 Uiso 1 1 calc R
C100 C 0.05376(15) 1.0483(6) 0.7685(2) 0.0387(19) Uani 1 1 d .
C101 C 0.06025(15) 1.0390(6) 0.7456(2) 0.0395(19) Uani 1 1 d .
C102 C 0.06852(15) 1.0365(6) 0.7194(2) 0.0360(18) Uani 1 1 d .
C103 C 0.05827(19) 1.1184(7) 0.6879(3) 0.055(2) Uani 1 1 d .
H103 H 0.0466 1.1765 0.6846 0.067 Uiso 1 1 calc R
C104 C 0.0652(2) 1.1148(9) 0.6614(3) 0.065(3) Uani 1 1 d .
H104 H 0.0581 1.1705 0.6403 0.078 Uiso 1 1 calc R
C105 C 0.0823(2) 1.0306(10) 0.6655(3) 0.068(3) Uani 1 1 d .
C106 C 0.0928(2) 0.9489(9) 0.6969(3) 0.070(3) Uani 1 1 d .
H106 H 0.1047 0.8919 0.7003 0.084 Uiso 1 1 calc R
C107 C 0.08586(18) 0.9505(7) 0.7235(3) 0.053(2) Uani 1 1 d .
H107 H 0.0928 0.8939 0.7442 0.064 Uiso 1 1 calc R
C108 C 0.0903(3) 1.0278(12) 0.6367(4) 0.123(5) Uani 1 1 d .
H10A H 0.0763 1.0685 0.6106 0.184 Uiso 1 1 calc R
H10B H 0.0912 0.9499 0.6301 0.184 Uiso 1 1 calc R
H10C H 0.1085 1.0634 0.6512 0.184 Uiso 1 1 calc R
N1 N 0.22801(17) 0.7854(6) 1.0151(2) 0.060(2) Uani 1 1 d .
O1 O 0.24173(16) 0.8645(7) 1.0164(2) 0.116(3) Uani 1 1 d .
O2 O 0.20225(14) 0.7810(5) 0.9820(2) 0.076(2) Uani 1 1 d .
O3 O 0.23799(16) 0.7173(5) 1.0442(2) 0.091(2) Uani 1 1 d .
N2 N 0.0399(2) 0.8373(6) 0.8291(3) 0.057(2) Uani 1 1 d .
O4 O 0.06131(14) 0.8285(5) 0.83135(18) 0.0634(17) Uani 1 1 d .
O5 O 0.01722(15) 0.8563(7) 0.7940(3) 0.101(3) Uani 1 1 d .
O6 O 0.0424(2) 0.8249(7) 0.8610(3) 0.120(3) Uani 1 1 d .
N3 N 0.04395(18) 1.3385(5) 0.7578(3) 0.0483(18) Uani 1 1 d .
O7 O 0.06325(12) 1.3276(5) 0.7982(2) 0.0564(15) Uani 1 1 d .
O8 O 0.01986(15) 1.3563(7) 0.7448(2) 0.096(3) Uani 1 1 d .
O9 O 0.05009(18) 1.3298(7) 0.7350(3) 0.102(3) Uani 1 1 d .
N4 N 0.13243(15) 0.8378(5) 0.8475(2) 0.0462(17) Uani 1 1 d .
O10 O 0.14138(13) 0.8111(6) 0.8287(2) 0.0689(18) Uani 1 1 d .
O11 O 0.14811(13) 0.8308(5) 0.8874(2) 0.0608(16) Uani 1 1 d .
O12 O 0.10756(13) 0.8684(5) 0.8282(2) 0.0722(19) Uani 1 1 d .
N5 N 0.22944(17) 0.2893(6) 0.9457(3) 0.057(2) Uani 1 1 d .
O13 O 0.24323(15) 0.3691(7) 0.9700(3) 0.104(3) Uani 1 1 d .
O14 O 0.20368(13) 0.2848(5) 0.92902(19) 0.0601(16) Uani 1 1 d .
O15 O 0.23895(17) 0.2204(5) 0.9351(3) 0.095(3) Uani 1 1 d .
N6 N 0.12951(16) 0.3384(5) 0.9205(2) 0.0474(17) Uani 1 1 d .
O16 O 0.14648(13) 0.3323(5) 0.91267(18) 0.0617(16) Uani 1 1 d .
O17 O 0.10515(13) 0.3715(6) 0.8918(2) 0.078(2) Uani 1 1 d .
O18 O 0.13715(14) 0.3081(6) 0.9557(2) 0.076(2) Uani 1 1 d .
N7 N 0.1374(4) 0.7549(10) 0.6411(6) 0.236(14) Uani 1 1 d D
O19 O 0.1321(4) 0.752(2) 0.6092(6) 0.40(2) Uani 1 1 d D
O20 O 0.1169(6) 0.7886(19) 0.6383(11) 0.56(3) Uani 1 1 d D
O21 O 0.1593(4) 0.7295(17) 0.6752(6) 0.283(11) Uani 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C64 158.8(3) . .
C1 Ag1 O1 102.6(3) . .
C64 Ag1 O1 97.9(3) . .
C1 Ag1 Ag14 104.8(2) . .
C64 Ag1 Ag14 54.51(19) . .
O1 Ag1 Ag14 152.3(2) . .
C1 Ag1 Ag3 48.4(2) . .
C64 Ag1 Ag3 117.48(19) . .
O1 Ag1 Ag3 135.0(2) . .
Ag14 Ag1 Ag3 69.15(2) . .
C1 Ag1 Ag10 138.0(2) . .
C64 Ag1 Ag10 47.56(19) . .
O1 Ag1 Ag10 67.8(2) . .
Ag14 Ag1 Ag10 88.97(3) . .
Ag3 Ag1 Ag10 157.15(3) . .
C1 Ag1 Ag13 148.6(2) . .
C64 Ag1 Ag13 45.6(2) . .
O1 Ag1 Ag13 71.0(2) . .
Ag14 Ag1 Ag13 87.29(3) . .
Ag3 Ag1 Ag13 114.19(3) . .
Ag10 Ag1 Ag13 69.50(2) . .
C46 Ag2 C1 159.9(3) 7_577 .
C46 Ag2 C2 131.6(3) 7_577 .
C1 Ag2 C2 28.4(2) . .
C46 Ag2 Ag11 41.0(2) 7_577 1_565
C1 Ag2 Ag11 158.8(2) . 1_565
C2 Ag2 Ag11 170.5(2) . 1_565
C46 Ag2 Ag3 144.63(18) 7_577 .
C1 Ag2 Ag3 40.8(2) . .
C2 Ag2 Ag3 59.9(2) . .
Ag11 Ag2 Ag3 129.59(3) 1_565 .
C1 Ag3 C19 161.7(3) . .
C1 Ag3 C20 135.1(3) . .
C19 Ag3 C20 26.6(2) . .
C1 Ag3 Ag1 47.6(2) . .
C19 Ag3 Ag1 146.90(19) . .
C20 Ag3 Ag1 157.05(15) . .
C1 Ag3 Ag7 150.5(2) . .
C19 Ag3 Ag7 47.3(2) . .
C20 Ag3 Ag7 73.60(17) . .
Ag1 Ag3 Ag7 109.87(3) . .
C1 Ag3 Ag6 127.7(2) . .
C19 Ag3 Ag6 48.87(18) . .
C20 Ag3 Ag6 52.40(16) . .
Ag1 Ag3 Ag6 106.13(3) . .
Ag7 Ag3 Ag6 71.58(2) . .
C1 Ag3 Ag14 91.5(2) . .
C19 Ag3 Ag14 106.7(2) . .
C20 Ag3 Ag14 133.27(18) . .
Ag1 Ag3 Ag14 54.18(2) . .
Ag7 Ag3 Ag14 59.74(2) . .
Ag6 Ag3 Ag14 106.23(3) . .
C1 Ag3 Ag2 45.8(2) . .
C19 Ag3 Ag2 137.62(18) . .
C20 Ag3 Ag2 132.15(16) . .
Ag1 Ag3 Ag2 68.52(2) . .
Ag7 Ag3 Ag2 113.52(3) . .
Ag6 Ag3 Ag2 173.40(3) . .
Ag14 Ag3 Ag2 74.09(2) . .
C10 Ag4 C46 145.0(3) . 7_567
C10 Ag4 O2 115.1(2) . .
C46 Ag4 O2 93.4(2) 7_567 .
C10 Ag4 C47 122.2(3) . 7_567
C46 Ag4 C47 27.4(2) 7_567 7_567
O2 Ag4 C47 99.1(2) . 7_567
C10 Ag4 C11 26.9(2) . .
C46 Ag4 C11 131.4(3) 7_567 .
O2 Ag4 C11 102.7(2) . .
C47 Ag4 C11 104.2(2) 7_567 .
C10 Ag4 Ag11 151.0(2) . .
C46 Ag4 Ag11 48.0(2) 7_567 .
O2 Ag4 Ag11 80.70(16) . .
C47 Ag4 Ag11 75.39(18) 7_567 .
C11 Ag4 Ag11 176.63(17) . .
C10 Ag4 Ag5 44.7(2) . .
C46 Ag4 Ag5 130.26(19) 7_567 .
O2 Ag4 Ag5 127.73(15) . .
C47 Ag4 Ag5 133.04(18) 7_567 .
C11 Ag4 Ag5 71.49(18) . .
Ag11 Ag4 Ag5 106.25(3) . .
C10 Ag4 Ag12 97.7(2) . .
C46 Ag4 Ag12 98.7(2) 7_567 .
O2 Ag4 Ag12 96.65(16) . .
C47 Ag4 Ag12 124.03(19) 7_567 .
C11 Ag4 Ag12 123.88(18) . .
Ag11 Ag4 Ag12 54.87(2) . .
Ag5 Ag4 Ag12 55.37(2) . .
C10 Ag5 C73 158.7(3) . .
C10 Ag5 Ag17 131.56(19) . .
C73 Ag5 Ag17 63.50(19) . .
C10 Ag5 Ag12 111.3(2) . .
C73 Ag5 Ag12 49.51(19) . .
Ag17 Ag5 Ag12 112.17(3) . .
C10 Ag5 Ag4 47.47(19) . .
C73 Ag5 Ag4 116.13(19) . .
Ag17 Ag5 Ag4 175.57(3) . .
Ag12 Ag5 Ag4 66.90(2) . .
C10 Ag5 Ag6 47.37(19) . .
C73 Ag5 Ag6 122.68(19) . .
Ag17 Ag5 Ag6 99.60(2) . .
Ag12 Ag5 Ag6 106.65(2) . .
Ag4 Ag5 Ag6 76.81(2) . .
C10 Ag6 C19 158.0(3) . .
C10 Ag6 O4 104.3(2) . .
C19 Ag6 O4 88.7(2) . .
C10 Ag6 C20 131.6(3) . .
C19 Ag6 C20 27.8(2) . .
O4 Ag6 C20 93.6(2) . .
C10 Ag6 C11 27.2(2) . .
C19 Ag6 C11 130.8(3) . .
O4 Ag6 C11 118.8(2) . .
C20 Ag6 C11 105.4(3) . .
C10 Ag6 Ag3 124.28(19) . .
C19 Ag6 Ag3 45.47(18) . .
O4 Ag6 Ag3 131.39(15) . .
C20 Ag6 Ag3 55.00(17) . .
C11 Ag6 Ag3 105.98(17) . .
C10 Ag6 Ag5 42.6(2) . .
C19 Ag6 Ag5 158.85(18) . .
O4 Ag6 Ag5 74.11(15) . .
C20 Ag6 Ag5 160.89(17) . .
C11 Ag6 Ag5 69.65(18) . .
Ag3 Ag6 Ag5 143.79(3) . .
C82 Ag7 C19 156.6(3) . .
C82 Ag7 Ag3 108.94(19) . .
C19 Ag7 Ag3 49.8(2) . .
C82 Ag7 Ag8 132.70(19) . .
C19 Ag7 Ag8 64.20(19) . .
Ag3 Ag7 Ag8 113.26(3) . .
C82 Ag7 Ag14 47.23(19) . .
C19 Ag7 Ag14 114.8(2) . .
Ag3 Ag7 Ag14 65.29(2) . .
Ag8 Ag7 Ag14 176.60(3) . .
C82 Ag7 Ag15 47.46(19) . .
C19 Ag7 Ag15 121.75(19) . .
Ag3 Ag7 Ag15 105.16(2) . .
Ag8 Ag7 Ag15 100.25(2) . .
Ag14 Ag7 Ag15 77.46(2) . .
C100 Ag8 C28 160.0(3) . .
C100 Ag8 Ag19 112.5(2) . 2_556
C28 Ag8 Ag19 50.5(2) . 2_556
C100 Ag8 Ag7 65.8(2) . .
C28 Ag8 Ag7 131.0(2) . .
Ag19 Ag8 Ag7 178.34(3) 2_556 .
C100 Ag8 Ag19 48.9(2) . .
C28 Ag8 Ag19 111.22(19) . .
Ag19 Ag8 Ag19 66.97(3) 2_556 .
Ag7 Ag8 Ag19 111.38(3) . .
C100 Ag8 Ag9 125.5(2) . .
C28 Ag8 Ag9 47.3(2) . .
Ag19 Ag8 Ag9 77.58(2) 2_556 .
Ag7 Ag8 Ag9 103.01(2) . .
Ag19 Ag8 Ag9 98.90(2) . .
C28 Ag9 C37 160.2(3) . .
C28 Ag9 O7 105.7(2) . .
C37 Ag9 O7 91.8(2) . .
C28 Ag9 C38 132.0(3) . .
C37 Ag9 C38 28.3(2) . .
O7 Ag9 C38 114.5(2) . .
C28 Ag9 C29 28.4(2) . .
C37 Ag9 C29 132.6(3) . .
O7 Ag9 C29 133.7(2) . .
C38 Ag9 C29 105.7(3) . .
C28 Ag9 Ag8 42.6(2) . .
C37 Ag9 Ag8 153.33(19) . .
O7 Ag9 Ag8 63.04(14) . .
C38 Ag9 Ag8 155.69(17) . .
C29 Ag9 Ag8 70.83(18) . .
C28 Ag9 Ag18 134.68(19) . 2_566
C37 Ag9 Ag18 42.17(18) . 2_566
O7 Ag9 Ag18 108.50(15) . 2_566
C38 Ag9 Ag18 53.13(17) . 2_566
C29 Ag9 Ag18 113.73(17) . 2_566
Ag8 Ag9 Ag18 150.94(3) . 2_566
C46 Ag10 C64 173.2(3) . .
C46 Ag10 C65 146.3(3) . .
C64 Ag10 C65 27.3(2) . .
C46 Ag10 Ag11 46.1(2) . 7_567
C64 Ag10 Ag11 139.4(2) . 7_567
C65 Ag10 Ag11 164.57(18) . 7_567
C46 Ag10 Ag1 142.1(2) . .
C64 Ag10 Ag1 44.5(2) . .
C65 Ag10 Ag1 71.61(19) . .
Ag11 Ag10 Ag1 96.97(3) 7_567 .
C55 Ag11 C46 161.1(3) . 7_567
C55 Ag11 Ag4 106.4(2) . .
C46 Ag11 Ag4 55.27(19) 7_567 .
C55 Ag11 Ag12 48.4(2) . .
C46 Ag11 Ag12 119.70(19) 7_567 .
Ag4 Ag11 Ag12 70.72(2) . .
C55 Ag11 Ag10 137.4(2) . 7_567
C46 Ag11 Ag10 48.55(19) 7_567 7_567
Ag4 Ag11 Ag10 92.08(3) . 7_567
Ag12 Ag11 Ag10 161.97(3) . 7_567
C55 Ag11 Ag2 147.5(2) . 1_545
C46 Ag11 Ag2 45.7(2) 7_567 1_545
Ag4 Ag11 Ag2 87.27(3) . 1_545
Ag12 Ag11 Ag2 114.06(3) . 1_545
Ag10 Ag11 Ag2 69.02(2) 7_567 1_545
C55 Ag12 C73 163.3(3) . .
C55 Ag12 C74 134.9(3) . .
C73 Ag12 C74 28.4(2) . .
C55 Ag12 Ag11 48.5(2) . .
C73 Ag12 Ag11 145.2(2) . .
C74 Ag12 Ag11 156.74(17) . .
C55 Ag12 Ag5 149.8(2) . .
C73 Ag12 Ag5 46.4(2) . .
C74 Ag12 Ag5 74.62(18) . .
Ag11 Ag12 Ag5 108.02(3) . .
C55 Ag12 Ag15 128.6(2) . 1_545
C73 Ag12 Ag15 49.03(18) . 1_545
C74 Ag12 Ag15 52.99(17) . 1_545
Ag11 Ag12 Ag15 105.29(3) . 1_545
Ag5 Ag12 Ag15 70.17(2) . 1_545
C55 Ag12 Ag13 45.1(2) . .
C73 Ag12 Ag13 138.26(18) . .
C74 Ag12 Ag13 133.49(17) . .
Ag11 Ag12 Ag13 67.69(2) . .
Ag5 Ag12 Ag13 113.62(3) . .
Ag15 Ag12 Ag13 172.60(3) 1_545 .
C55 Ag12 Ag4 92.7(2) . .
C73 Ag12 Ag4 103.9(2) . .
C74 Ag12 Ag4 132.30(19) . .
Ag11 Ag12 Ag4 54.41(2) . .
Ag5 Ag12 Ag4 57.73(2) . .
Ag15 Ag12 Ag4 103.84(3) 1_545 .
Ag13 Ag12 Ag4 74.27(2) . .
C55 Ag13 C64 160.6(3) . .
C55 Ag13 C56 27.7(2) . .
C64 Ag13 C56 133.5(3) . .
C55 Ag13 C65 133.6(3) . .
C64 Ag13 C65 27.1(2) . .
C56 Ag13 C65 107.4(3) . .
C55 Ag13 Ag12 40.7(2) . .
C64 Ag13 Ag12 142.72(17) . .
C56 Ag13 Ag12 61.52(19) . .
C65 Ag13 Ag12 131.73(17) . .
C55 Ag13 Ag1 158.8(2) . .
C64 Ag13 Ag1 40.6(2) . .
C56 Ag13 Ag1 169.47(19) . .
C65 Ag13 Ag1 67.64(19) . .
Ag12 Ag13 Ag1 128.86(3) . .
C82 Ag14 C64 145.9(3) . .
C82 Ag14 C83 28.6(2) . .
C64 Ag14 C83 131.4(3) . .
C82 Ag14 Ag1 151.7(2) . .
C64 Ag14 Ag1 48.6(2) . .
C83 Ag14 Ag1 179.7(2) . .
C82 Ag14 Ag7 44.0(2) . .
C64 Ag14 Ag7 131.44(19) . .
C83 Ag14 Ag7 72.49(18) . .
Ag1 Ag14 Ag7 107.75(3) . .
C82 Ag14 Ag3 96.1(2) . .
C64 Ag14 Ag3 100.7(2) . .
C83 Ag14 Ag3 123.50(18) . .
Ag1 Ag14 Ag3 56.67(2) . .
Ag7 Ag14 Ag3 54.98(2) . .
C82 Ag15 C73 156.2(3) . 1_565
C82 Ag15 O7 104.0(2) . .
C73 Ag15 O7 89.2(2) 1_565 .
C82 Ag15 C74 128.8(3) . 1_565
C73 Ag15 C74 28.2(2) 1_565 1_565
O7 Ag15 C74 96.1(2) . 1_565
C82 Ag15 O16 89.4(2) . 1_565
C73 Ag15 O16 104.6(2) 1_565 1_565
O7 Ag15 O16 110.8(2) . 1_565
C74 Ag15 O16 126.3(2) 1_565 1_565
C82 Ag15 C83 26.9(2) . .
C73 Ag15 C83 129.6(3) 1_565 .
O7 Ag15 C83 121.5(2) . .
C74 Ag15 C83 103.8(2) 1_565 .
O16 Ag15 C83 100.1(2) 1_565 .
C82 Ag15 Ag12 123.20(19) . 1_565
C73 Ag15 Ag12 45.67(17) 1_565 1_565
O7 Ag15 Ag12 132.65(14) . 1_565
C74 Ag15 Ag12 52.62(16) 1_565 1_565
O16 Ag15 Ag12 75.88(14) 1_565 1_565
C83 Ag15 Ag12 101.90(16) . 1_565
C82 Ag15 Ag7 42.7(2) . .
C73 Ag15 Ag7 159.86(19) 1_565 .
O7 Ag15 Ag7 73.16(14) . .
C74 Ag15 Ag7 159.79(17) 1_565 .
O16 Ag15 Ag7 73.85(14) 1_565 .
C83 Ag15 Ag7 69.55(17) . .
Ag12 Ag15 Ag7 146.28(3) 1_565 .
C91 Ag16 C100 160.3(3) . .
C91 Ag16 O4 106.0(2) . .
C100 Ag16 O4 91.3(2) . .
C91 Ag16 C101 132.0(3) . .
C100 Ag16 C101 28.4(2) . .
O4 Ag16 C101 113.9(2) . .
C91 Ag16 C92 28.2(2) . .
C100 Ag16 C92 132.8(3) . .
O4 Ag16 C92 133.7(2) . .
C101 Ag16 C92 105.7(3) . .
C91 Ag16 Ag17 42.8(2) . .
C100 Ag16 Ag17 152.84(19) . .
O4 Ag16 Ag17 63.20(14) . .
C101 Ag16 Ag17 155.04(16) . .
C92 Ag16 Ag17 70.71(18) . .
C91 Ag16 Ag19 134.87(19) . .
C100 Ag16 Ag19 42.11(18) . .
O4 Ag16 Ag19 108.18(16) . .
C101 Ag16 Ag19 53.29(16) . .
C92 Ag16 Ag19 114.52(17) . .
Ag17 Ag16 Ag19 151.36(3) . .
C91 Ag17 C37 160.3(3) . 1_545
C91 Ag17 Ag18 49.7(2) . .
C37 Ag17 Ag18 113.3(2) 1_545 .
C91 Ag17 Ag5 129.3(2) . .
C37 Ag17 Ag5 67.9(2) 1_545 .
Ag18 Ag17 Ag5 178.34(3) . .
C91 Ag17 Ag18 111.1(2) . 2_556
C37 Ag17 Ag18 49.21(19) 1_545 2_556
Ag18 Ag17 Ag18 67.39(3) . 2_556
Ag5 Ag17 Ag18 114.10(3) . 2_556
C91 Ag17 Ag16 47.6(2) . .
C37 Ag17 Ag16 125.8(2) 1_545 .
Ag18 Ag17 Ag16 77.41(2) . .
Ag5 Ag17 Ag16 102.90(2) . .
Ag18 Ag17 Ag16 99.06(2) 2_556 .
C91 Ag18 C37 159.7(3) . 2_546
C91 Ag18 C38 135.2(3) . 2_546
C37 Ag18 C38 26.1(2) 2_546 2_546
C91 Ag18 Ag17 47.4(2) . .
C37 Ag18 Ag17 152.9(2) 2_546 .
C38 Ag18 Ag17 165.30(16) 2_546 .
C91 Ag18 Ag17 146.8(2) . 2_556
C37 Ag18 Ag17 46.2(2) 2_546 2_556
C38 Ag18 Ag17 71.84(17) 2_546 2_556
Ag17 Ag18 Ag17 112.59(3) . 2_556
C91 Ag18 Ag18 99.8(2) . 2_556
C37 Ag18 Ag18 98.9(2) 2_546 2_556
C38 Ag18 Ag18 124.78(17) 2_546 2_556
Ag17 Ag18 Ag18 57.32(2) . 2_556
Ag17 Ag18 Ag18 55.29(2) 2_556 2_556
C91 Ag18 Ag9 140.5(2) . 2_546
C37 Ag18 Ag9 44.62(19) 2_546 2_546
C38 Ag18 Ag9 48.50(16) 2_546 2_546
Ag17 Ag18 Ag9 118.63(3) . 2_546
Ag17 Ag18 Ag9 69.53(2) 2_556 2_546
Ag18 Ag18 Ag9 94.90(2) 2_556 2_546
C28 Ag19 C100 159.6(3) 2_556 .
C28 Ag19 Ag8 47.6(2) 2_556 2_556
C100 Ag19 Ag8 152.7(2) . 2_556
C28 Ag19 Ag8 147.34(19) 2_556 .
C100 Ag19 Ag8 45.9(2) . .
Ag8 Ag19 Ag8 113.02(3) 2_556 .
C28 Ag19 Ag19 100.4(2) 2_556 2_556
C100 Ag19 Ag19 98.5(2) . 2_556
Ag8 Ag19 Ag19 57.90(2) 2_556 2_556
Ag8 Ag19 Ag19 55.12(2) . 2_556
C28 Ag19 Ag16 140.22(19) 2_556 .
C100 Ag19 Ag16 44.49(19) . .
Ag8 Ag19 Ag16 118.19(3) 2_556 .
Ag8 Ag19 Ag16 69.30(2) . .
Ag19 Ag19 Ag16 94.67(2) 2_556 .
C2 C1 Ag1 153.5(7) . .
C2 C1 Ag3 122.1(7) . .
Ag1 C1 Ag3 83.9(3) . .
C2 C1 Ag2 83.4(6) . .
Ag1 C1 Ag2 101.5(3) . .
Ag3 C1 Ag2 93.4(3) . .
C1 C2 C3 175.0(9) . .
C1 C2 Ag2 68.3(5) . .
C3 C2 Ag2 116.6(6) . .
C4 C3 C8 117.8(9) . .
C4 C3 C2 122.0(9) . .
C8 C3 C2 120.2(9) . .
C3 C4 C5 120.4(10) . .
C3 C4 H4 119.8 . .
C5 C4 H4 119.8 . .
C6 C5 C4 120.4(11) . .
C6 C5 H5 119.8 . .
C4 C5 H5 119.8 . .
C7 C6 C5 119.5(10) . .
C7 C6 C9 122.0(12) . .
C5 C6 C9 118.4(12) . .
C6 C7 C8 119.7(11) . .
C6 C7 H7 120.2 . .
C8 C7 H7 120.2 . .
C3 C8 C7 122.1(10) . .
C3 C8 H8 118.9 . .
C7 C8 H8 118.9 . .
C6 C9 H9A 109.5 . .
C6 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C6 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C11 C10 Ag5 171.5(7) . .
C11 C10 Ag4 97.9(6) . .
Ag5 C10 Ag4 87.8(3) . .
C11 C10 Ag6 93.2(5) . .
Ag5 C10 Ag6 90.0(3) . .
Ag4 C10 Ag6 115.0(3) . .
C10 C11 C12 172.5(9) . .
C10 C11 Ag6 59.6(5) . .
C12 C11 Ag6 125.2(5) . .
C10 C11 Ag4 55.2(5) . .
C12 C11 Ag4 127.4(5) . .
Ag6 C11 Ag4 91.1(3) . .
C17 C12 C13 117.0(9) . .
C17 C12 C11 120.3(8) . .
C13 C12 C11 122.6(9) . .
C12 C13 C14 119.5(11) . .
C12 C13 H13 120.3 . .
C14 C13 H13 120.3 . .
C15 C14 C13 121.2(12) . .
C15 C14 H14 119.4 . .
C13 C14 H14 119.4 . .
C16 C15 C14 118.3(12) . .
C16 C15 C18 123.4(15) . .
C14 C15 C18 118.0(15) . .
C15 C16 C17 121.1(13) . .
C15 C16 H16 119.4 . .
C17 C16 H16 119.4 . .
C12 C17 C16 122.6(12) . .
C12 C17 H17 118.7 . .
C16 C17 H17 118.7 . .
C15 C18 H18A 109.5 . .
C15 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C15 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 Ag7 170.2(6) . .
C20 C19 Ag3 97.8(6) . .
Ag7 C19 Ag3 82.9(3) . .
C20 C19 Ag6 86.9(5) . .
Ag7 C19 Ag6 102.9(3) . .
Ag3 C19 Ag6 85.7(2) . .
C19 C20 C21 176.2(8) . .
C19 C20 Ag6 65.3(5) . .
C21 C20 Ag6 118.5(5) . .
C19 C20 Ag3 55.6(5) . .
C21 C20 Ag3 124.8(5) . .
Ag6 C20 Ag3 72.60(19) . .
C26 C21 C22 119.4(8) . .
C26 C21 C20 120.8(8) . .
C22 C21 C20 119.7(8) . .
C21 C22 C23 118.9(9) . .
C21 C22 H22 120.6 . .
C23 C22 H22 120.6 . .
C24 C23 C22 121.8(10) . .
C24 C23 H23 119.1 . .
C22 C23 H23 119.1 . .
C25 C24 C23 118.2(10) . .
C25 C24 C27 121.1(12) . .
C23 C24 C27 120.6(12) . .
C24 C25 C26 122.1(10) . .
C24 C25 H25 119.0 . .
C26 C25 H25 119.0 . .
C21 C26 C25 119.6(10) . .
C21 C26 H26 120.2 . .
C25 C26 H26 120.2 . .
C24 C27 H27A 109.5 . .
C24 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C24 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C29 C28 Ag8 171.6(7) . .
C29 C28 Ag19 106.4(6) . 2_556
Ag8 C28 Ag19 81.9(3) . 2_556
C29 C28 Ag9 87.5(5) . .
Ag8 C28 Ag9 90.1(3) . .
Ag19 C28 Ag9 112.3(3) 2_556 .
C28 C29 C30 174.8(8) . .
C28 C29 Ag9 64.1(5) . .
C30 C29 Ag9 121.1(5) . .
C31 C30 C35 118.2(8) . .
C31 C30 C29 120.1(8) . .
C35 C30 C29 121.7(8) . .
C30 C31 C32 120.3(10) . .
C30 C31 H31 119.8 . .
C32 C31 H31 119.8 . .
C33 C32 C31 122.3(11) . .
C33 C32 H32 118.8 . .
C31 C32 H32 118.8 . .
C32 C33 C34 118.1(10) . .
C32 C33 C36 123.1(13) . .
C34 C33 C36 118.8(13) . .
C33 C34 C35 120.5(10) . .
C33 C34 H34 119.8 . .
C35 C34 H34 119.8 . .
C30 C35 C34 120.6(9) . .
C30 C35 H35 119.7 . .
C34 C35 H35 119.7 . .
C33 C36 H36A 109.5 . .
C33 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C33 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C38 C37 Ag17 167.3(7) . 1_565
C38 C37 Ag18 99.7(6) . 2_566
Ag17 C37 Ag18 84.6(3) 1_565 2_566
C38 C37 Ag9 85.2(5) . .
Ag17 C37 Ag9 106.6(3) 1_565 .
Ag18 C37 Ag9 93.2(3) 2_566 .
C37 C38 C39 176.3(8) . .
C37 C38 Ag9 66.5(5) . .
C39 C38 Ag9 117.1(5) . .
C37 C38 Ag18 54.2(5) . 2_566
C39 C38 Ag18 126.4(5) . 2_566
Ag9 C38 Ag18 78.4(2) . 2_566
C40 C39 C44 118.9(8) . .
C40 C39 C38 121.1(8) . .
C44 C39 C38 119.9(7) . .
C39 C40 C41 119.5(10) . .
C39 C40 H40 120.3 . .
C41 C40 H40 120.3 . .
C42 C41 C40 121.5(10) . .
C42 C41 H41 119.3 . .
C40 C41 H41 119.3 . .
C43 C42 C41 118.5(10) . .
C43 C42 C45 121.6(12) . .
C41 C42 C45 119.9(12) . .
C42 C43 C44 121.0(10) . .
C42 C43 H43 119.5 . .
C44 C43 H43 119.5 . .
C39 C44 C43 120.7(9) . .
C39 C44 H44 119.7 . .
C43 C44 H44 119.7 . .
C42 C45 H45A 109.5 . .
C42 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C42 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
C47 C46 Ag11 165.1(6) . 7_567
C47 C46 Ag10 102.5(6) . .
Ag11 C46 Ag10 85.4(3) 7_567 .
C47 C46 Ag2 97.4(6) . 7_577
Ag11 C46 Ag2 93.3(3) 7_567 7_577
Ag10 C46 Ag2 101.5(3) . 7_577
C47 C46 Ag4 88.6(5) . 7_567
Ag11 C46 Ag4 76.7(2) 7_567 7_567
Ag10 C46 Ag4 129.2(3) . 7_567
Ag2 C46 Ag4 126.3(3) 7_577 7_567
C46 C47 C48 177.5(9) . .
C46 C47 Ag4 64.0(5) . 7_567
C48 C47 Ag4 113.8(5) . 7_567
C49 C48 C53 117.4(10) . .
C49 C48 C47 123.4(9) . .
C53 C48 C47 119.1(10) . .
C48 C49 C50 121.6(12) . .
C48 C49 H49 119.2 . .
C50 C49 H49 119.2 . .
C51 C50 C49 120.9(14) . .
C51 C50 H50 119.6 . .
C49 C50 H50 119.6 . .
C50 C51 C52 119.0(13) . .
C50 C51 C54 121.4(16) . .
C52 C51 C54 119.6(15) . .
C53 C52 C51 119.7(14) . .
C53 C52 H52 120.2 . .
C51 C52 H52 120.2 . .
C52 C53 C48 121.4(14) . .
C52 C53 H53 119.3 . .
C48 C53 H53 119.3 . .
C51 C54 H54A 109.5 . .
C51 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C51 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 Ag12 130.0(7) . .
C56 C55 Ag11 145.4(7) . .
Ag12 C55 Ag11 83.1(3) . .
C56 C55 Ag13 88.5(6) . .
Ag12 C55 Ag13 94.2(3) . .
Ag11 C55 Ag13 100.0(3) . .
C55 C56 C57 174.0(9) . .
C55 C56 Ag13 63.8(5) . .
C57 C56 Ag13 121.8(6) . .
C58 C57 C62 118.0(9) . .
C58 C57 C56 120.5(8) . .
C62 C57 C56 121.4(9) . .
C57 C58 C59 119.7(10) . .
C57 C58 H58 120.1 . .
C59 C58 H58 120.1 . .
C60 C59 C58 122.5(12) . .
C60 C59 H59 118.8 . .
C58 C59 H59 118.8 . .
C59 C60 C61 118.8(12) . .
C59 C60 C63 121.9(15) . .
C61 C60 C63 119.3(14) . .
C60 C61 C62 121.0(11) . .
C60 C61 H61 119.5 . .
C62 C61 H61 119.5 . .
C57 C62 C61 120.0(11) . .
C57 C62 H62 120.0 . .
C61 C62 H62 120.0 . .
C60 C63 H63A 109.5 . .
C60 C63 H63B 109.5 . .
H63A C63 H63B 109.5 . .
C60 C63 H63C 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
C65 C64 Ag1 171.2(7) . .
C65 C64 Ag10 95.7(6) . .
Ag1 C64 Ag10 88.0(3) . .
C65 C64 Ag14 94.5(5) . .
Ag1 C64 Ag14 76.9(3) . .
Ag10 C64 Ag14 126.7(3) . .
C65 C64 Ag13 93.1(6) . .
Ag1 C64 Ag13 93.8(3) . .
Ag10 C64 Ag13 103.5(3) . .
Ag14 C64 Ag13 128.0(3) . .
C64 C65 C66 177.1(9) . .
C64 C65 Ag10 56.9(5) . .
C66 C65 Ag10 124.1(5) . .
C64 C65 Ag13 59.9(5) . .
C66 C65 Ag13 122.5(5) . .
Ag10 C65 Ag13 84.3(2) . .
C67 C66 C71 117.5(9) . .
C67 C66 C65 119.7(9) . .
C71 C66 C65 122.8(8) . .
C66 C67 C68 121.4(11) . .
C66 C67 H67 119.3 . .
C68 C67 H67 119.3 . .
C69 C68 C67 121.5(11) . .
C69 C68 H68 119.2 . .
C67 C68 H68 119.2 . .
C68 C69 C70 116.7(10) . .
C68 C69 C72 122.3(12) . .
C70 C69 C72 121.0(12) . .
C69 C70 C71 122.8(11) . .
C69 C70 H70 118.6 . .
C71 C70 H70 118.6 . .
C66 C71 C70 120.1(10) . .
C66 C71 H71 120.0 . .
C70 C71 H71 120.0 . .
C69 C72 H72A 109.5 . .
C69 C72 H72B 109.5 . .
H72A C72 H72B 109.5 . .
C69 C72 H72C 109.5 . .
H72A C72 H72C 109.5 . .
H72B C72 H72C 109.5 . .
C74 C73 Ag5 170.8(6) . .
C74 C73 Ag12 91.2(5) . .
Ag5 C73 Ag12 84.1(3) . .
C74 C73 Ag15 86.1(5) . 1_545
Ag5 C73 Ag15 101.3(3) . 1_545
Ag12 C73 Ag15 85.3(2) . 1_545
C73 C74 C75 176.0(8) . .
C73 C74 Ag12 60.4(4) . .
C75 C74 Ag12 120.1(5) . .
C73 C74 Ag15 65.7(5) . 1_545
C75 C74 Ag15 118.2(5) . 1_545
Ag12 C74 Ag15 74.4(2) . 1_545
C80 C75 C76 119.0(8) . .
C80 C75 C74 120.7(8) . .
C76 C75 C74 120.3(7) . .
C75 C76 C77 120.1(9) . .
C75 C76 H76 120.0 . .
C77 C76 H76 120.0 . .
C78 C77 C76 121.0(9) . .
C78 C77 H77 119.5 . .
C76 C77 H77 119.5 . .
C79 C78 C77 118.2(9) . .
C79 C78 C81 122.1(10) . .
C77 C78 C81 119.7(10) . .
C78 C79 C80 121.6(9) . .
C78 C79 H79 119.2 . .
C80 C79 H79 119.2 . .
C75 C80 C79 120.0(9) . .
C75 C80 H80 120.0 . .
C79 C80 H80 120.0 . .
C78 C81 H81A 109.5 . .
C78 C81 H81B 109.5 . .
H81A C81 H81B 109.5 . .
C78 C81 H81C 109.5 . .
H81A C81 H81C 109.5 . .
H81B C81 H81C 109.5 . .
C83 C82 Ag7 175.4(6) . .
C83 C82 Ag14 89.9(5) . .
Ag7 C82 Ag14 88.8(3) . .
C83 C82 Ag15 94.7(5) . .
Ag7 C82 Ag15 89.8(3) . .
Ag14 C82 Ag15 116.6(3) . .
C82 C83 C84 173.6(8) . .
C82 C83 Ag14 61.5(5) . .
C84 C83 Ag14 120.3(5) . .
C82 C83 Ag15 58.5(5) . .
C84 C83 Ag15 126.0(5) . .
Ag14 C83 Ag15 95.0(3) . .
C89 C84 C85 118.0(8) . .
C89 C84 C83 119.8(7) . .
C85 C84 C83 122.1(8) . .
C86 C85 C84 120.2(10) . .
C86 C85 H85 119.9 . .
C84 C85 H85 119.9 . .
C87 C86 C85 122.9(11) . .
C87 C86 H86 118.5 . .
C85 C86 H86 118.5 . .
C86 C87 C88 117.2(10) . .
C86 C87 C90 122.8(12) . .
C88 C87 C90 119.8(12) . .
C87 C88 C89 120.9(10) . .
C87 C88 H88 119.5 . .
C89 C88 H88 119.5 . .
C84 C89 C88 120.6(9) . .
C84 C89 H89 119.7 . .
C88 C89 H89 119.7 . .
C87 C90 H90A 109.5 . .
C87 C90 H90B 109.5 . .
H90A C90 H90B 109.5 . .
C87 C90 H90C 109.5 . .
H90A C90 H90C 109.5 . .
H90B C90 H90C 109.5 . .
C92 C91 Ag17 169.4(7) . .
C92 C91 Ag18 107.7(6) . .
Ag17 C91 Ag18 82.8(3) . .
C92 C91 Ag16 87.6(5) . .
Ag17 C91 Ag16 89.5(3) . .
Ag18 C91 Ag16 112.5(3) . .
C91 C92 C93 174.6(9) . .
C91 C92 Ag16 64.2(5) . .
C93 C92 Ag16 121.0(5) . .
C98 C93 C94 118.0(8) . .
C98 C93 C92 122.1(8) . .
C94 C93 C92 119.9(8) . .
C93 C94 C95 120.0(11) . .
C93 C94 H94 120.0 . .
C95 C94 H94 120.0 . .
C96 C95 C94 121.9(12) . .
C96 C95 H95 119.0 . .
C94 C95 H95 119.0 . .
C95 C96 C97 118.1(11) . .
C95 C96 C99 122.3(14) . .
C97 C96 C99 119.6(14) . .
C96 C97 C98 121.6(11) . .
C96 C97 H97 119.2 . .
C98 C97 H97 119.2 . .
C97 C98 C93 120.4(10) . .
C97 C98 H98 119.8 . .
C93 C98 H98 119.8 . .
C96 C99 H99A 109.5 . .
C96 C99 H99B 109.5 . .
H99A C99 H99B 109.5 . .
C96 C99 H99C 109.5 . .
H99A C99 H99C 109.5 . .
H99B C99 H99C 109.5 . .
C101 C100 Ag8 165.7(6) . .
C101 C100 Ag19 100.0(6) . .
Ag8 C100 Ag19 85.2(3) . .
C101 C100 Ag16 86.5(5) . .
Ag8 C100 Ag16 106.7(3) . .
Ag19 C100 Ag16 93.4(3) . .
C100 C101 C102 175.9(8) . .
C100 C101 Ag16 65.1(5) . .
C102 C101 Ag16 119.0(5) . .
C103 C102 C107 118.4(8) . .
C103 C102 C101 119.9(7) . .
C107 C102 C101 121.6(7) . .
C104 C103 C102 120.6(8) . .
C104 C103 H103 119.7 . .
C102 C103 H103 119.7 . .
C105 C104 C103 121.0(9) . .
C105 C104 H104 119.5 . .
C103 C104 H104 119.5 . .
C104 C105 C106 118.9(9) . .
C104 C105 C108 121.0(11) . .
C106 C105 C108 120.1(10) . .
C105 C106 C107 120.9(9) . .
C105 C106 H106 119.6 . .
C107 C106 H106 119.6 . .
C106 C107 C102 120.2(8) . .
C106 C107 H107 119.9 . .
C102 C107 H107 119.9 . .
C105 C108 H10A 109.5 . .
C105 C108 H10B 109.5 . .
H10A C108 H10B 109.5 . .
C105 C108 H10C 109.5 . .
H10A C108 H10C 109.5 . .
H10B C108 H10C 109.5 . .
O3 N1 O1 123.0(9) . .
O3 N1 O2 121.4(8) . .
O1 N1 O2 115.6(8) . .
N1 O1 Ag1 101.7(6) . .
N1 O2 Ag4 129.0(5) . .
O6 N2 O5 122.9(11) . .
O6 N2 O4 119.8(10) . .
O5 N2 O4 117.4(9) . .
N2 O4 Ag16 105.8(5) . .
N2 O4 Ag6 122.6(5) . .
Ag16 O4 Ag6 127.7(3) . .
O9 N3 O8 124.3(9) . .
O9 N3 O7 119.3(9) . .
O8 N3 O7 116.4(8) . .
N3 O7 Ag9 106.5(5) . .
N3 O7 Ag15 118.8(5) . .
Ag9 O7 Ag15 130.0(3) . .
O10 N4 O12 122.3(8) . .
O10 N4 O11 120.4(7) . .
O12 N4 O11 117.2(8) . .
O15 N5 O13 123.3(8) . .
O15 N5 O14 119.8(8) . .
O13 N5 O14 116.7(7) . .
O18 N6 O17 121.6(8) . .
O18 N6 O16 120.2(8) . .
O17 N6 O16 118.2(8) . .
N6 O16 Ag15 102.5(5) . 1_545
O19 N7 O21 128(2) . .
O19 N7 O20 112(2) . .
O21 N7 O20 121(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.128(9) .
Ag1 C64 2.139(9) .
Ag1 O1 2.578(8) .
Ag1 Ag14 2.7793(9) .
Ag1 Ag3 2.8639(9) .
Ag1 Ag10 3.0517(9) .
Ag1 Ag13 3.2769(9) .
Ag2 C46 2.343(8) 7_577
Ag2 C1 2.367(8) .
Ag2 C2 2.531(8) .
Ag2 Ag11 3.2708(9) 1_565
Ag2 Ag3 3.2936(9) .
Ag3 C1 2.155(8) .
Ag3 C19 2.223(7) .
Ag3 C20 2.670(7) .
Ag3 Ag7 2.8876(9) .
Ag3 Ag6 3.1096(9) .
Ag3 Ag14 3.2030(10) .
Ag4 C10 2.216(7) .
Ag4 C46 2.378(7) 7_567
Ag4 O2 2.552(6) .
Ag4 C47 2.645(8) 7_567
Ag4 C11 2.672(8) .
Ag4 Ag11 2.8156(9) .
Ag4 Ag5 3.0045(9) .
Ag4 Ag12 3.2683(10) .
Ag5 C10 2.116(8) .
Ag5 C73 2.129(8) .
Ag5 Ag17 2.9159(8) .
Ag5 Ag12 2.9237(9) .
Ag5 Ag6 3.1253(8) .
Ag6 C10 2.299(7) .
Ag6 C19 2.349(7) .
Ag6 O4 2.479(6) .
Ag6 C20 2.582(7) .
Ag6 C11 2.663(8) .
Ag7 C82 2.115(8) .
Ag7 C19 2.137(8) .
Ag7 Ag8 2.9092(8) .
Ag7 Ag14 3.0454(9) .
Ag7 Ag15 3.1180(8) .
Ag8 C100 2.124(8) .
Ag8 C28 2.129(8) .
Ag8 Ag19 2.8525(8) 2_556
Ag8 Ag19 2.9455(9) .
Ag8 Ag9 3.1424(8) .
Ag9 C28 2.308(7) .
Ag9 C37 2.334(8) .
Ag9 O7 2.441(6) .
Ag9 C38 2.536(7) .
Ag9 C29 2.563(8) .
Ag9 Ag18 3.3173(9) 2_566
Ag10 C46 2.237(7) .
Ag10 C64 2.253(7) .
Ag10 C65 2.676(8) .
Ag10 Ag11 2.9752(9) 7_567
Ag11 C55 2.136(9) .
Ag11 C46 2.151(8) 7_567
Ag11 Ag12 2.8317(8) .
Ag11 Ag10 2.9753(9) 7_567
Ag11 Ag2 3.2710(9) 1_545
Ag12 C55 2.133(8) .
Ag12 C73 2.235(7) .
Ag12 C74 2.570(7) .
Ag12 Ag15 3.1144(9) 1_545
Ag12 Ag13 3.2640(9) .
Ag13 C55 2.319(8) .
Ag13 C64 2.345(8) .
Ag13 C56 2.585(9) .
Ag13 C65 2.709(8) .
Ag14 C82 2.236(7) .
Ag14 C64 2.323(7) .
Ag14 C83 2.544(7) .
Ag15 C82 2.297(7) .
Ag15 C73 2.360(7) 1_565
Ag15 O7 2.457(6) .
Ag15 C74 2.582(8) 1_565
Ag15 O16 2.598(6) 1_565
Ag15 C83 2.686(8) .
Ag15 Ag12 3.1144(9) 1_565
Ag16 C91 2.309(8) .
Ag16 C100 2.326(7) .
Ag16 O4 2.469(6) .
Ag16 C101 2.560(8) .
Ag16 C92 2.563(8) .
Ag16 Ag17 3.1268(9) .
Ag16 Ag19 3.3138(9) .
Ag17 C91 2.126(8) .
Ag17 C37 2.126(8) 1_545
Ag17 Ag18 2.8643(8) .
Ag17 Ag18 2.9328(9) 2_556
Ag18 C91 2.203(7) .
Ag18 C37 2.231(7) 2_546
Ag18 C38 2.710(8) 2_546
Ag18 Ag17 2.9329(9) 2_556
Ag18 Ag18 3.2165(14) 2_556
Ag18 Ag9 3.3173(10) 2_546
Ag19 C28 2.222(7) 2_556
Ag19 C100 2.226(7) .
Ag19 Ag8 2.8525(8) 2_556
Ag19 Ag19 3.1999(14) 2_556
C1 C2 1.211(11) .
C2 C3 1.428(12) .
C3 C4 1.364(12) .
C3 C8 1.370(12) .
C4 C5 1.387(12) .
C4 H4 0.9300 .
C5 C6 1.384(15) .
C5 H5 0.9300 .
C6 C7 1.335(15) .
C6 C9 1.524(14) .
C7 C8 1.388(14) .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 C11 1.219(10) .
C11 C12 1.442(11) .
C12 C17 1.343(13) .
C12 C13 1.367(13) .
C13 C14 1.407(15) .
C13 H13 0.9300 .
C14 C15 1.346(17) .
C14 H14 0.9300 .
C15 C16 1.318(17) .
C15 C18 1.556(15) .
C16 C17 1.369(14) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 C20 1.208(10) .
C20 C21 1.454(11) .
C21 C26 1.378(11) .
C21 C22 1.389(11) .
C22 C23 1.396(12) .
C22 H22 0.9300 .
C23 C24 1.364(14) .
C23 H23 0.9300 .
C24 C25 1.360(15) .
C24 C27 1.521(13) .
C25 C26 1.384(12) .
C25 H25 0.9300 .
C26 H26 0.9300 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 C29 1.219(10) .
C28 Ag19 2.222(7) 2_556
C29 C30 1.427(10) .
C30 C31 1.373(11) .
C30 C35 1.381(11) .
C31 C32 1.380(13) .
C31 H31 0.9300 .
C32 C33 1.349(15) .
C32 H32 0.9300 .
C33 C34 1.380(15) .
C33 C36 1.509(14) .
C34 C35 1.394(12) .
C34 H34 0.9300 .
C35 H35 0.9300 .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
C37 C38 1.208(10) .
C37 Ag17 2.126(8) 1_565
C37 Ag18 2.231(7) 2_566
C38 C39 1.458(11) .
C38 Ag18 2.710(7) 2_566
C39 C40 1.371(11) .
C39 C44 1.378(11) .
C40 C41 1.400(13) .
C40 H40 0.9300 .
C41 C42 1.366(15) .
C41 H41 0.9300 .
C42 C43 1.364(15) .
C42 C45 1.537(13) .
C43 C44 1.384(13) .
C43 H43 0.9300 .
C44 H44 0.9300 .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C46 C47 1.217(10) .
C46 Ag11 2.150(8) 7_567
C46 Ag2 2.343(8) 7_577
C46 Ag4 2.378(7) 7_567
C47 C48 1.421(12) .
C47 Ag4 2.645(8) 7_567
C48 C49 1.353(13) .
C48 C53 1.377(14) .
C49 C50 1.382(14) .
C49 H49 0.9300 .
C50 C51 1.337(18) .
C50 H50 0.9300 .
C51 C52 1.385(19) .
C51 C54 1.540(16) .
C52 C53 1.374(17) .
C52 H52 0.9300 .
C53 H53 0.9300 .
C54 H54A 0.9600 .
C54 H54B 0.9600 .
C54 H54C 0.9600 .
C55 C56 1.202(11) .
C56 C57 1.432(12) .
C57 C58 1.378(12) .
C57 C62 1.392(12) .
C58 C59 1.383(14) .
C58 H58 0.9300 .
C59 C60 1.346(16) .
C59 H59 0.9300 .
C60 C61 1.350(17) .
C60 C63 1.523(15) .
C61 C62 1.397(15) .
C61 H61 0.9300 .
C62 H62 0.9300 .
C63 H63A 0.9600 .
C63 H63B 0.9600 .
C63 H63C 0.9600 .
C64 C65 1.235(10) .
C65 C66 1.439(11) .
C66 C67 1.348(12) .
C66 C71 1.350(12) .
C67 C68 1.382(14) .
C67 H67 0.9300 .
C68 C69 1.336(15) .
C68 H68 0.9300 .
C69 C70 1.342(14) .
C69 C72 1.514(13) .
C70 C71 1.379(13) .
C70 H70 0.9300 .
C71 H71 0.9300 .
C72 H72A 0.9600 .
C72 H72B 0.9600 .
C72 H72C 0.9600 .
C73 C74 1.223(10) .
C73 Ag15 2.360(7) 1_545
C74 C75 1.462(11) .
C74 Ag15 2.582(7) 1_545
C75 C80 1.375(11) .
C75 C76 1.376(11) .
C76 C77 1.394(12) .
C76 H76 0.9300 .
C77 C78 1.371(13) .
C77 H77 0.9300 .
C78 C79 1.365(13) .
C78 C81 1.522(12) .
C79 C80 1.386(12) .
C79 H79 0.9300 .
C80 H80 0.9300 .
C81 H81A 0.9600 .
C81 H81B 0.9600 .
C81 H81C 0.9600 .
C82 C83 1.217(10) .
C83 C84 1.432(10) .
C84 C89 1.370(11) .
C84 C85 1.373(11) .
C85 C86 1.359(13) .
C85 H85 0.9300 .
C86 C87 1.350(15) .
C86 H86 0.9300 .
C87 C88 1.372(14) .
C87 C90 1.527(14) .
C88 C89 1.381(12) .
C88 H88 0.9300 .
C89 H89 0.9300 .
C90 H90A 0.9600 .
C90 H90B 0.9600 .
C90 H90C 0.9600 .
C91 C92 1.211(10) .
C92 C93 1.441(11) .
C93 C98 1.379(11) .
C93 C94 1.384(12) .
C94 C95 1.386(14) .
C94 H94 0.9300 .
C95 C96 1.348(16) .
C95 H95 0.9300 .
C96 C97 1.368(16) .
C96 C99 1.533(15) .
C97 C98 1.377(13) .
C97 H97 0.9300 .
C98 H98 0.9300 .
C99 H99A 0.9600 .
C99 H99B 0.9600 .
C99 H99C 0.9600 .
C100 C101 1.221(10) .
C101 C102 1.435(11) .
C102 C103 1.382(11) .
C102 C107 1.391(10) .
C103 C104 1.382(11) .
C103 H103 0.9300 .
C104 C105 1.367(13) .
C104 H104 0.9300 .
C105 C106 1.378(13) .
C105 C108 1.525(13) .
C106 C107 1.385(12) .
C106 H106 0.9300 .
C107 H107 0.9300 .
C108 H10A 0.9600 .
C108 H10B 0.9600 .
C108 H10C 0.9600 .
N1 O3 1.213(9) .
N1 O1 1.227(9) .
N1 O2 1.262(9) .
N2 O6 1.209(9) .
N2 O5 1.218(9) .
N2 O4 1.255(9) .
N3 O9 1.200(9) .
N3 O8 1.225(9) .
N3 O7 1.275(9) .
N4 O10 1.227(8) .
N4 O12 1.240(8) .
N4 O11 1.249(8) .
N5 O15 1.219(8) .
N5 O13 1.221(9) .
N5 O14 1.259(8) .
N6 O18 1.230(8) .
N6 O17 1.231(8) .
N6 O16 1.265(8) .
O16 Ag15 2.598(6) 1_545
N7 O19 1.115(16) .
N7 O21 1.197(15) .
N7 O20 1.243(16) .
