#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/80/1518020.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1518020
loop_
_publ_author_name
'Braunschweig, Holger'
'Celik, Mehmet Ali'
'Dewhurst, Rian D.'
'Heid, Magdalena'
'Hupp, Florian'
'Sen, Sakya S.'
_publ_section_title
;
 Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and
 dications in the coordination sphere of platinum
;
_journal_issue                   1
_journal_name_full               'Chem. Sci.'
_journal_page_first              425
_journal_paper_doi               10.1039/C4SC02948H
_journal_volume                  6
_journal_year                    2015
_chemical_formula_moiety         'C72 H132 Cl2 P4 Pb2 Pt2, 2(C24 H12 B Cl8)'
_chemical_formula_sum            'C120 H156 B2 Cl18 P4 Pb2 Pt2'
_chemical_formula_weight         3186.61
_chemical_name_common
;
?
;
_chemical_name_systematic
; 
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.785(2)
_cell_angle_beta                 90.439(2)
_cell_angle_gamma                90.796(2)
_cell_formula_units_Z            1
_cell_length_a                   10.5092(6)
_cell_length_b                   15.3892(10)
_cell_length_c                   20.0776(12)
_cell_measurement_temperature    100(2)
_cell_volume                     3054.9(3)
_computing_cell_refinement       'Saint+ ver. 7.68A (Bruker AXS)'
_computing_data_collection       'APEX2 ver. 2010.3 (Bruker AXS)'
_computing_data_reduction        'Saint+ ver. 7.68A (Bruker AXS)'
_computing_molecular_graphics    'XP ver. 5.1 (Bruker AXS, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker X8-APEX II'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'multi-layer mirror'
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_sigmaI/netI    0.0299
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            58065
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.08
_exptl_absorpt_coefficient_mu    5.523
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6086
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sadabs 2008/1 (Bruker 2008)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.732
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1572
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.068
_refine_diff_density_min         -0.798
_refine_diff_density_rms         0.098
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     677
_refine_ls_number_reflns         12492
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0275
_refine_ls_R_factor_gt           0.0209
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0171P)²+2.7796P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0435
_refine_ls_wR_factor_ref         0.0454
_reflns_number_gt                10951
_reflns_number_total             12492
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4sc02948h2.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2827 2014-09-09 07:05:25Z andrius 

 Adding full bibliography for 1518019--1518027.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1518020
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.529977(10) -0.032098(8) 0.297740(5) 0.00961(3) Uani 1 1 d . . .
Pb1 Pb 0.386607(10) -0.001168(8) 0.408536(5) 0.01175(3) Uani 0.9795(3) 1 d PU .
1
Pb2 Pb 0.5383(5) 0.0076(4) 0.3957(2) 0.0084(10) Uani 0.0205(3) 1 d PU . 2
Cl1 Cl 0.51466(7) 0.11681(5) 0.52895(4) 0.01732(16) Uani 1 1 d . . .
P1 P 0.49130(7) -0.19037(5) 0.24975(4) 0.01034(15) Uani 1 1 d . . .
P2 P 0.62106(7) 0.11477(5) 0.32848(4) 0.01076(15) Uani 1 1 d . . .
C11 C 0.5727(3) -0.2514(2) 0.30260(14) 0.0123(6) Uani 1 1 d . . .
H11A H 0.5221 -0.2373 0.3469 0.015 Uiso 1 1 calc R . .
C12 C 0.7064(3) -0.2106(2) 0.32752(15) 0.0151(6) Uani 1 1 d . . .
H12A H 0.7612 -0.2204 0.2858 0.018 Uiso 1 1 calc R . .
H12B H 0.7003 -0.1433 0.3524 0.018 Uiso 1 1 calc R . .
C13 C 0.7669(3) -0.2552(2) 0.37692(17) 0.0227(7) Uani 1 1 d . . .
H13A H 0.8556 -0.2320 0.3879 0.027 Uiso 1 1 calc R . .
H13B H 0.7196 -0.2370 0.4219 0.027 Uiso 1 1 calc R . .
C14 C 0.7667(3) -0.3593(2) 0.34480(18) 0.0241(8) Uani 1 1 d . . .
H14A H 0.8025 -0.3856 0.3794 0.029 Uiso 1 1 calc R . .
H14B H 0.8212 -0.3780 0.3024 0.029 Uiso 1 1 calc R . .
C15 C 0.6320(3) -0.3973(2) 0.32393(17) 0.0221(7) Uani 1 1 d . . .
H15A H 0.5788 -0.3817 0.3667 0.027 Uiso 1 1 calc R . .
H15B H 0.6341 -0.4654 0.3025 0.027 Uiso 1 1 calc R . .
C16 C 0.5732(3) -0.3571(2) 0.27126(16) 0.0164(7) Uani 1 1 d . . .
H16A H 0.4849 -0.3810 0.2596 0.020 Uiso 1 1 calc R . .
H16B H 0.6226 -0.3765 0.2270 0.020 Uiso 1 1 calc R . .
C21 C 0.5531(3) -0.2323(2) 0.15797(14) 0.0127(6) Uani 1 1 d . . .
H21A H 0.5093 -0.2928 0.1329 0.015 Uiso 1 1 calc R . .
C22 C 0.5185(3) -0.1673(2) 0.11746(15) 0.0177(7) Uani 1 1 d . . .
H22A H 0.4257 -0.1566 0.1204 0.021 Uiso 1 1 calc R . .
H22B H 0.5627 -0.1069 0.1397 0.021 Uiso 1 1 calc R . .
C23 C 0.5563(3) -0.2078(2) 0.03970(16) 0.0233(7) Uani 1 1 d . . .
H23A H 0.5069 -0.2655 0.0165 0.028 Uiso 1 1 calc R . .
H23B H 0.5354 -0.1635 0.0153 0.028 Uiso 1 1 calc R . .
C24 C 0.6972(3) -0.2279(2) 0.03277(17) 0.0255(8) Uani 1 1 d . . .
H24A H 0.7178 -0.2582 -0.0178 0.031 Uiso 1 1 calc R . .
H24B H 0.7467 -0.1692 0.0508 0.031 Uiso 1 1 calc R . .
C25 C 0.7344(3) -0.2901(2) 0.07381(16) 0.0210(7) Uani 1 1 d . . .
H25A H 0.8276 -0.2990 0.0709 0.025 Uiso 1 1 calc R . .
H25B H 0.6923 -0.3512 0.0521 0.025 Uiso 1 1 calc R . .
C26 C 0.6969(3) -0.2495(2) 0.15171(15) 0.0151(6) Uani 1 1 d . . .
H26A H 0.7441 -0.1907 0.1746 0.018 Uiso 1 1 calc R . .
H26B H 0.7201 -0.2929 0.1765 0.018 Uiso 1 1 calc R . .
C31 C 0.3283(3) -0.2421(2) 0.23916(15) 0.0152(6) Uani 1 1 d . . .
H31A H 0.3402 -0.3104 0.2231 0.018 Uiso 1 1 calc R . .
C32 C 0.2583(3) -0.2179(3) 0.30930(16) 0.0236(8) Uani 1 1 d . . .
H32A H 0.2407 -0.1509 0.3271 0.028 Uiso 1 1 calc R . .
H32B H 0.3130 -0.2318 0.3447 0.028 Uiso 1 1 calc R . .
C33 C 0.1331(3) -0.2724(3) 0.30058(18) 0.0295(9) Uani 1 1 d . . .
H33A H 0.1514 -0.3390 0.2874 0.035 Uiso 1 1 calc R . .
H33B H 0.0882 -0.2532 0.3463 0.035 Uiso 1 1 calc R . .
C34 C 0.0480(3) -0.2576(3) 0.24479(17) 0.0253(8) Uani 1 1 d . . .
H34A H 0.0203 -0.1926 0.2607 0.030 Uiso 1 1 calc R . .
H34B H -0.0288 -0.2978 0.2379 0.030 Uiso 1 1 calc R . .
C35 C 0.1176(3) -0.2794(3) 0.17494(17) 0.0261(8) Uani 1 1 d . . .
H35A H 0.0622 -0.2645 0.1403 0.031 Uiso 1 1 calc R . .
H35B H 0.1348 -0.3464 0.1560 0.031 Uiso 1 1 calc R . .
C36 C 0.2433(3) -0.2253(3) 0.18312(17) 0.0230(8) Uani 1 1 d . . .
H36A H 0.2878 -0.2445 0.1373 0.028 Uiso 1 1 calc R . .
H36B H 0.2259 -0.1585 0.1968 0.028 Uiso 1 1 calc R . .
C41 C 0.7144(3) 0.1165(2) 0.25123(14) 0.0123(6) Uani 1 1 d . . .
H41A H 0.7727 0.1718 0.2672 0.015 Uiso 1 1 calc R . .
C42 C 0.7973(3) 0.0300(2) 0.22526(15) 0.0165(7) Uani 1 1 d . . .
H42A H 0.8539 0.0280 0.2644 0.020 Uiso 1 1 calc R . .
H42B H 0.7418 -0.0260 0.2113 0.020 Uiso 1 1 calc R . .
C43 C 0.8780(3) 0.0300(2) 0.16210(16) 0.0221(7) Uani 1 1 d . . .
H43A H 0.9403 0.0821 0.1775 0.027 Uiso 1 1 calc R . .
H43B H 0.9260 -0.0281 0.1448 0.027 Uiso 1 1 calc R . .
C44 C 0.7955(3) 0.0391(2) 0.10202(16) 0.0223(7) Uani 1 1 d . . .
H44A H 0.8505 0.0429 0.0633 0.027 Uiso 1 1 calc R . .
H44B H 0.7396 -0.0164 0.0830 0.027 Uiso 1 1 calc R . .
C45 C 0.7146(3) 0.1245(2) 0.12796(16) 0.0216(7) Uani 1 1 d . . .
H45A H 0.6594 0.1276 0.0887 0.026 Uiso 1 1 calc R . .
H45B H 0.7707 0.1802 0.1429 0.026 Uiso 1 1 calc R . .
C46 C 0.6315(3) 0.1241(2) 0.19020(15) 0.0165(7) Uani 1 1 d . . .
H46A H 0.5705 0.0713 0.1745 0.020 Uiso 1 1 calc R . .
H46B H 0.5823 0.1817 0.2068 0.020 Uiso 1 1 calc R . .
C51 C 0.5163(3) 0.2159(2) 0.34886(15) 0.0120(6) Uani 1 1 d . . .
H51A H 0.4649 0.2084 0.3051 0.014 Uiso 1 1 calc R . .
C52 C 0.4222(3) 0.2224(2) 0.40769(17) 0.0178(7) Uani 1 1 d . . .
H52A H 0.4702 0.2253 0.4510 0.021 Uiso 1 1 calc R . .
H52B H 0.3683 0.1657 0.3936 0.021 Uiso 1 1 calc R . .
C53 C 0.3364(3) 0.3064(2) 0.42472(16) 0.0179(7) Uani 1 1 d . . .
H53A H 0.2806 0.3004 0.3834 0.021 Uiso 1 1 calc R . .
H53B H 0.2815 0.3088 0.4651 0.021 Uiso 1 1 calc R . .
C54 C 0.4144(3) 0.3949(2) 0.44296(15) 0.0168(7) Uani 1 1 d . . .
H54A H 0.4642 0.4041 0.4870 0.020 Uiso 1 1 calc R . .
H54B H 0.3571 0.4479 0.4513 0.020 Uiso 1 1 calc R . .
C55 C 0.5045(3) 0.3906(2) 0.38282(16) 0.0179(7) Uani 1 1 d . . .
H55A H 0.5570 0.4480 0.3961 0.021 Uiso 1 1 calc R . .
H55B H 0.4542 0.3865 0.3399 0.021 Uiso 1 1 calc R . .
C56 C 0.5914(3) 0.3074(2) 0.36633(15) 0.0134(6) Uani 1 1 d . . .
H56A H 0.6481 0.3150 0.4076 0.016 Uiso 1 1 calc R . .
H56B H 0.6456 0.3050 0.3256 0.016 Uiso 1 1 calc R . .
C61 C 0.7388(3) 0.1400(2) 0.40297(14) 0.0113(6) Uani 1 1 d . . .
H61A H 0.6949 0.1802 0.4462 0.014 Uiso 1 1 calc R . .
C62 C 0.8599(3) 0.1935(2) 0.39513(15) 0.0142(6) Uani 1 1 d . . .
H62A H 0.9060 0.1568 0.3522 0.017 Uiso 1 1 calc R . .
H62B H 0.8356 0.2525 0.3893 0.017 Uiso 1 1 calc R . .
C63 C 0.9475(3) 0.2134(2) 0.46009(16) 0.0193(7) Uani 1 1 d . . .
H63A H 1.0271 0.2435 0.4521 0.023 Uiso 1 1 calc R . .
H63B H 0.9053 0.2569 0.5018 0.023 Uiso 1 1 calc R . .
C64 C 0.9800(3) 0.1264(2) 0.47536(16) 0.0183(7) Uani 1 1 d . . .
H64A H 1.0316 0.1428 0.5195 0.022 Uiso 1 1 calc R . .
H64B H 1.0313 0.0860 0.4363 0.022 Uiso 1 1 calc R . .
C65 C 0.8602(3) 0.0748(2) 0.48324(15) 0.0179(7) Uani 1 1 d . . .
H65A H 0.8128 0.1130 0.5251 0.021 Uiso 1 1 calc R . .
H65B H 0.8838 0.0169 0.4911 0.021 Uiso 1 1 calc R . .
C66 C 0.7752(3) 0.0520(2) 0.41767(14) 0.0132(6) Uani 1 1 d . . .
H66A H 0.6970 0.0196 0.4246 0.016 Uiso 1 1 calc R A 2
H66B H 0.8203 0.0102 0.3764 0.016 Uiso 1 1 calc R A 2
Cl90 Cl 0.68393(7) 0.37156(6) 0.18662(4) 0.02415(18) Uani 1 1 d . . .
Cl91 Cl 0.37954(7) 0.54794(6) 0.05772(4) 0.02043(17) Uani 1 1 d . . .
Cl92 Cl 0.38487(7) 0.00962(5) 0.05956(4) 0.01728(16) Uani 1 1 d . . .
Cl93 Cl 0.15108(7) 0.06187(6) 0.30713(4) 0.02115(17) Uani 1 1 d . . .
Cl94 Cl -0.11117(8) 0.15665(6) -0.03673(4) 0.02674(19) Uani 1 1 d . . .
Cl95 Cl -0.14144(7) 0.52442(6) 0.09437(5) 0.02487(18) Uani 1 1 d . . .
Cl96 Cl -0.14729(7) 0.44867(5) 0.40834(4) 0.02025(17) Uani 1 1 d . . .
Cl97 Cl 0.30279(7) 0.62548(6) 0.42263(4) 0.02105(17) Uani 1 1 d . . .
B100 B 0.1779(3) 0.3334(2) 0.19304(17) 0.0120(7) Uani 1 1 d . . .
C101 C 0.3036(3) 0.3752(2) 0.16406(14) 0.0120(6) Uani 1 1 d . . .
C102 C 0.2943(3) 0.4343(2) 0.12502(14) 0.0137(6) Uani 1 1 d . . .
H10A H 0.2126 0.4490 0.1118 0.016 Uiso 1 1 calc R . .
C103 C 0.4018(3) 0.4722(2) 0.10500(15) 0.0150(6) Uani 1 1 d . . .
C104 C 0.5234(3) 0.4530(2) 0.12184(14) 0.0156(7) Uani 1 1 d . . .
H10B H 0.5966 0.4780 0.1070 0.019 Uiso 1 1 calc R . .
C105 C 0.5326(3) 0.3957(2) 0.16136(15) 0.0153(7) Uani 1 1 d . . .
C106 C 0.4270(3) 0.3573(2) 0.18228(15) 0.0153(6) Uani 1 1 d . . .
H10C H 0.4383 0.3181 0.2095 0.018 Uiso 1 1 calc R . .
C111 C 0.2093(2) 0.2301(2) 0.19347(14) 0.0112(6) Uani 1 1 d . . .
C112 C 0.2750(3) 0.1691(2) 0.13605(14) 0.0130(6) Uani 1 1 d . . .
H11B H 0.3013 0.1898 0.0987 0.016 Uiso 1 1 calc R . .
C113 C 0.3022(3) 0.0804(2) 0.13239(14) 0.0124(6) Uani 1 1 d . . .
C114 C 0.2669(3) 0.0459(2) 0.18441(15) 0.0151(6) Uani 1 1 d . . .
H11C H 0.2865 -0.0152 0.1819 0.018 Uiso 1 1 calc R . .
C115 C 0.2013(3) 0.1049(2) 0.24044(14) 0.0134(6) Uani 1 1 d . . .
C116 C 0.1722(2) 0.1941(2) 0.24596(14) 0.0123(6) Uani 1 1 d . . .
H11D H 0.1266 0.2316 0.2857 0.015 Uiso 1 1 calc R . .
C121 C 0.0588(3) 0.3305(2) 0.13890(14) 0.0125(6) Uani 1 1 d . . .
C122 C 0.0206(3) 0.2516(2) 0.08302(15) 0.0142(6) Uani 1 1 d . . .
H12C H 0.0547 0.1934 0.0795 0.017 Uiso 1 1 calc R . .
C123 C -0.0666(3) 0.2576(2) 0.03260(15) 0.0148(6) Uani 1 1 d . . .
C124 C -0.1174(3) 0.3398(2) 0.03360(16) 0.0177(7) Uani 1 1 d . . .
H12D H -0.1740 0.3431 -0.0026 0.021 Uiso 1 1 calc R . .
C125 C -0.0819(3) 0.4176(2) 0.09016(16) 0.0167(7) Uani 1 1 d . . .
C126 C 0.0012(3) 0.4130(2) 0.14233(15) 0.0144(6) Uani 1 1 d . . .
H12E H 0.0196 0.4673 0.1815 0.017 Uiso 1 1 calc R . .
C131 C 0.1447(3) 0.4050(2) 0.27241(14) 0.0120(6) Uani 1 1 d . . .
C132 C 0.0280(3) 0.3984(2) 0.30421(15) 0.0133(6) Uani 1 1 d . . .
H13C H -0.0321 0.3516 0.2798 0.016 Uiso 1 1 calc R . .
C133 C -0.0004(3) 0.4593(2) 0.37050(15) 0.0136(6) Uani 1 1 d . . .
C134 C 0.0812(3) 0.5298(2) 0.40876(15) 0.0149(6) Uani 1 1 d . . .
H13D H 0.0599 0.5712 0.4542 0.018 Uiso 1 1 calc R . .
C135 C 0.1951(3) 0.5368(2) 0.37734(15) 0.0139(6) Uani 1 1 d . . .
C136 C 0.2273(3) 0.4766(2) 0.31128(14) 0.0118(6) Uani 1 1 d . . .
H13E H 0.3072 0.4841 0.2919 0.014 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Pb2 Pt1 P2 76.28(16) . .
Pb2 Pt1 P1 111.59(17) . .
P2 Pt1 P1 163.99(3) . .
Pb2 Pt1 Pb1 38.31(15) . .
P2 Pt1 Pb1 97.241(18) . .
P1 Pt1 Pb1 97.140(18) . .
Pt1 Pb1 Cl1 102.010(16) . 2_656
Pt1 Pb1 Cl1 109.926(16) . .
Cl1 Pb1 Cl1 75.85(3) 2_656 .
Pt1 Pb2 C66 100.9(2) . .
Pt1 Pb2 P2 60.00(14) . .
C66 Pb2 P2 66.00(14) . .
Pt1 Pb2 Cl1 159.5(3) . .
C66 Pb2 Cl1 83.82(16) . .
P2 Pb2 Cl1 105.26(19) . .
Pt1 Pb2 Cl1 121.0(2) . 2_656
C66 Pb2 Cl1 106.16(18) . 2_656
P2 Pb2 Cl1 171.7(2) . 2_656
Cl1 Pb2 Cl1 75.82(12) . 2_656
Pb2 Cl1 Pb1 97.65(11) . 2_656
Pb1 Cl1 Pb1 104.14(3) 2_656 .
Pb2 Cl1 Pb2 104.18(12) . 2_656
Pb1 Cl1 Pb2 90.80(10) . 2_656
C11 P1 C31 102.11(13) . .
C11 P1 C21 109.09(13) . .
C31 P1 C21 103.06(13) . .
C11 P1 Pt1 110.70(9) . .
C31 P1 Pt1 122.62(11) . .
C21 P1 Pt1 108.49(10) . .
C41 P2 C51 105.19(13) . .
C41 P2 C61 105.24(12) . .
C51 P2 C61 106.83(13) . .
C41 P2 Pt1 106.22(10) . .
C51 P2 Pt1 119.15(9) . .
C61 P2 Pt1 113.08(10) . .
C41 P2 Pb2 143.42(15) . .
C51 P2 Pb2 108.51(14) . .
C61 P2 Pb2 78.24(14) . .
C16 C11 C12 111.9(2) . .
C16 C11 P1 116.7(2) . .
C12 C11 P1 112.1(2) . .
C16 C11 H11A 105.0 . .
C12 C11 H11A 105.0 . .
P1 C11 H11A 105.0 . .
C13 C12 C11 111.5(2) . .
C13 C12 H12A 109.3 . .
C11 C12 H12A 109.3 . .
C13 C12 H12B 109.3 . .
C11 C12 H12B 109.3 . .
H12A C12 H12B 108.0 . .
C14 C13 C12 112.0(3) . .
C14 C13 H13A 109.2 . .
C12 C13 H13A 109.2 . .
C14 C13 H13B 109.2 . .
C12 C13 H13B 109.2 . .
H13A C13 H13B 107.9 . .
C13 C14 C15 110.7(3) . .
C13 C14 H14A 109.5 . .
C15 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
C15 C14 H14B 109.5 . .
H14A C14 H14B 108.1 . .
C14 C15 C16 110.9(3) . .
C14 C15 H15A 109.5 . .
C16 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
C16 C15 H15B 109.5 . .
H15A C15 H15B 108.0 . .
C15 C16 C11 110.3(2) . .
C15 C16 H16A 109.6 . .
C11 C16 H16A 109.6 . .
C15 C16 H16B 109.6 . .
C11 C16 H16B 109.6 . .
H16A C16 H16B 108.1 . .
C22 C21 C26 108.7(2) . .
C22 C21 P1 111.6(2) . .
C26 C21 P1 115.48(19) . .
C22 C21 H21A 106.9 . .
C26 C21 H21A 106.9 . .
P1 C21 H21A 106.9 . .
C23 C22 C21 111.2(3) . .
C23 C22 H22A 109.4 . .
C21 C22 H22A 109.4 . .
C23 C22 H22B 109.4 . .
C21 C22 H22B 109.4 . .
H22A C22 H22B 108.0 . .
C24 C23 C22 111.2(3) . .
C24 C23 H23A 109.4 . .
C22 C23 H23A 109.4 . .
C24 C23 H23B 109.4 . .
C22 C23 H23B 109.4 . .
H23A C23 H23B 108.0 . .
C25 C24 C23 110.9(3) . .
C25 C24 H24A 109.5 . .
C23 C24 H24A 109.5 . .
C25 C24 H24B 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 108.1 . .
C24 C25 C26 111.8(3) . .
C24 C25 H25A 109.3 . .
C26 C25 H25A 109.3 . .
C24 C25 H25B 109.3 . .
C26 C25 H25B 109.3 . .
H25A C25 H25B 107.9 . .
C25 C26 C21 110.5(2) . .
C25 C26 H26A 109.5 . .
C21 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
C21 C26 H26B 109.5 . .
H26A C26 H26B 108.1 . .
C36 C31 C32 110.2(2) . .
C36 C31 P1 116.4(2) . .
C32 C31 P1 112.5(2) . .
C36 C31 H31A 105.6 . .
C32 C31 H31A 105.6 . .
P1 C31 H31A 105.6 . .
C31 C32 C33 111.2(3) . .
C31 C32 H32A 109.4 . .
C33 C32 H32A 109.4 . .
C31 C32 H32B 109.4 . .
C33 C32 H32B 109.4 . .
H32A C32 H32B 108.0 . .
C34 C33 C32 111.9(3) . .
C34 C33 H33A 109.2 . .
C32 C33 H33A 109.2 . .
C34 C33 H33B 109.2 . .
C32 C33 H33B 109.2 . .
H33A C33 H33B 107.9 . .
C33 C34 C35 110.7(3) . .
C33 C34 H34A 109.5 . .
C35 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
C35 C34 H34B 109.5 . .
H34A C34 H34B 108.1 . .
C34 C35 C36 112.2(3) . .
C34 C35 H35A 109.2 . .
C36 C35 H35A 109.2 . .
C34 C35 H35B 109.2 . .
C36 C35 H35B 109.2 . .
H35A C35 H35B 107.9 . .
C31 C36 C35 110.8(3) . .
C31 C36 H36A 109.5 . .
C35 C36 H36A 109.5 . .
C31 C36 H36B 109.5 . .
C35 C36 H36B 109.5 . .
H36A C36 H36B 108.1 . .
C46 C41 C42 110.3(2) . .
C46 C41 P2 113.22(19) . .
C42 C41 P2 109.8(2) . .
C46 C41 H41A 107.8 . .
C42 C41 H41A 107.8 . .
P2 C41 H41A 107.8 . .
C43 C42 C41 111.3(3) . .
C43 C42 H42A 109.4 . .
C41 C42 H42A 109.4 . .
C43 C42 H42B 109.4 . .
C41 C42 H42B 109.4 . .
H42A C42 H42B 108.0 . .
C44 C43 C42 111.4(2) . .
C44 C43 H43A 109.4 . .
C42 C43 H43A 109.4 . .
C44 C43 H43B 109.4 . .
C42 C43 H43B 109.4 . .
H43A C43 H43B 108.0 . .
C45 C44 C43 110.7(3) . .
C45 C44 H44A 109.5 . .
C43 C44 H44A 109.5 . .
C45 C44 H44B 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 108.1 . .
C44 C45 C46 111.6(3) . .
C44 C45 H45A 109.3 . .
C46 C45 H45A 109.3 . .
C44 C45 H45B 109.3 . .
C46 C45 H45B 109.3 . .
H45A C45 H45B 108.0 . .
C45 C46 C41 110.5(2) . .
C45 C46 H46A 109.6 . .
C41 C46 H46A 109.6 . .
C45 C46 H46B 109.6 . .
C41 C46 H46B 109.6 . .
H46A C46 H46B 108.1 . .
C52 C51 C56 109.6(2) . .
C52 C51 P2 113.6(2) . .
C56 C51 P2 112.54(19) . .
C52 C51 H51A 106.9 . .
C56 C51 H51A 106.9 . .
P2 C51 H51A 106.9 . .
C51 C52 C53 113.4(2) . .
C51 C52 H52A 108.9 . .
C53 C52 H52A 108.9 . .
C51 C52 H52B 108.9 . .
C53 C52 H52B 108.9 . .
H52A C52 H52B 107.7 . .
C54 C53 C52 111.0(2) . .
C54 C53 H53A 109.4 . .
C52 C53 H53A 109.4 . .
C54 C53 H53B 109.4 . .
C52 C53 H53B 109.4 . .
H53A C53 H53B 108.0 . .
C53 C54 C55 110.2(2) . .
C53 C54 H54A 109.6 . .
C55 C54 H54A 109.6 . .
C53 C54 H54B 109.6 . .
C55 C54 H54B 109.6 . .
H54A C54 H54B 108.1 . .
C54 C55 C56 111.3(2) . .
C54 C55 H55A 109.4 . .
C56 C55 H55A 109.4 . .
C54 C55 H55B 109.4 . .
C56 C55 H55B 109.4 . .
H55A C55 H55B 108.0 . .
C55 C56 C51 112.3(2) . .
C55 C56 H56A 109.1 . .
C51 C56 H56A 109.1 . .
C55 C56 H56B 109.1 . .
C51 C56 H56B 109.1 . .
H56A C56 H56B 107.9 . .
C66 C61 C62 110.1(2) . .
C66 C61 P2 111.50(19) . .
C62 C61 P2 115.22(19) . .
C66 C61 H61A 106.5 . .
C62 C61 H61A 106.5 . .
P2 C61 H61A 106.5 . .
C63 C62 C61 110.9(2) . .
C63 C62 H62A 109.5 . .
C61 C62 H62A 109.5 . .
C63 C62 H62B 109.5 . .
C61 C62 H62B 109.5 . .
H62A C62 H62B 108.0 . .
C64 C63 C62 112.1(3) . .
C64 C63 H63A 109.2 . .
C62 C63 H63A 109.2 . .
C64 C63 H63B 109.2 . .
C62 C63 H63B 109.2 . .
H63A C63 H63B 107.9 . .
C63 C64 C65 110.9(2) . .
C63 C64 H64A 109.5 . .
C65 C64 H64A 109.5 . .
C63 C64 H64B 109.5 . .
C65 C64 H64B 109.5 . .
H64A C64 H64B 108.0 . .
C64 C65 C66 111.1(2) . .
C64 C65 H65A 109.4 . .
C66 C65 H65A 109.4 . .
C64 C65 H65B 109.4 . .
C66 C65 H65B 109.4 . .
H65A C65 H65B 108.0 . .
C65 C66 C61 110.9(2) . .
C65 C66 Pb2 132.5(2) . .
C61 C66 Pb2 85.26(19) . .
C65 C66 H66A 109.5 . .
C61 C66 H66A 109.5 . .
C65 C66 H66B 109.5 . .
C61 C66 H66B 109.5 . .
Pb2 C66 H66B 105.9 . .
H66A C66 H66B 108.0 . .
C111 B100 C121 111.1(2) . .
C111 B100 C131 112.3(2) . .
C121 B100 C131 109.1(2) . .
C111 B100 C101 109.0(2) . .
C121 B100 C101 107.2(2) . .
C131 B100 C101 108.0(2) . .
C102 C101 C106 116.2(3) . .
C102 C101 B100 123.0(3) . .
C106 C101 B100 120.7(3) . .
C103 C102 C101 121.4(3) . .
C103 C102 H10A 119.3 . .
C101 C102 H10A 119.3 . .
C104 C103 C102 122.3(3) . .
C104 C103 Cl91 119.9(2) . .
C102 C103 Cl91 117.8(2) . .
C105 C104 C103 116.3(3) . .
C105 C104 H10B 121.8 . .
C103 C104 H10B 121.8 . .
C104 C105 C106 122.5(3) . .
C104 C105 Cl90 118.5(2) . .
C106 C105 Cl90 119.0(2) . .
C105 C106 C101 121.2(3) . .
C105 C106 H10C 119.4 . .
C101 C106 H10C 119.4 . .
C116 C111 C112 115.6(3) . .
C116 C111 B100 125.3(3) . .
C112 C111 B100 119.0(2) . .
C113 C112 C111 122.0(3) . .
C113 C112 H11B 119.0 . .
C111 C112 H11B 119.0 . .
C114 C113 C112 122.1(3) . .
C114 C113 Cl92 118.9(2) . .
C112 C113 Cl92 119.0(2) . .
C113 C114 C115 116.3(3) . .
C113 C114 H11C 121.9 . .
C115 C114 H11C 121.9 . .
C116 C115 C114 123.3(3) . .
C116 C115 Cl93 119.2(2) . .
C114 C115 Cl93 117.5(2) . .
C115 C116 C111 120.7(3) . .
C115 C116 H11D 119.7 . .
C111 C116 H11D 119.7 . .
C126 C121 C122 116.6(3) . .
C126 C121 B100 119.1(3) . .
C122 C121 B100 123.8(3) . .
C123 C122 C121 120.5(3) . .
C123 C122 H12C 119.7 . .
C121 C122 H12C 119.7 . .
C124 C123 C122 122.8(3) . .
C124 C123 Cl94 118.4(2) . .
C122 C123 Cl94 118.8(2) . .
C123 C124 C125 116.5(3) . .
C123 C124 H12D 121.7 . .
C125 C124 H12D 121.7 . .
C126 C125 C124 121.8(3) . .
C126 C125 Cl95 119.2(2) . .
C124 C125 Cl95 119.0(2) . .
C125 C126 C121 121.6(3) . .
C125 C126 H12E 119.2 . .
C121 C126 H12E 119.2 . .
C136 C131 C132 116.2(3) . .
C136 C131 B100 123.0(2) . .
C132 C131 B100 120.8(2) . .
C133 C132 C131 120.8(3) . .
C133 C132 H13C 119.6 . .
C131 C132 H13C 119.6 . .
C134 C133 C132 123.0(3) . .
C134 C133 Cl96 117.7(2) . .
C132 C133 Cl96 119.3(2) . .
C135 C134 C133 116.2(3) . .
C135 C134 H13D 121.9 . .
C133 C134 H13D 121.9 . .
C134 C135 C136 122.4(3) . .
C134 C135 Cl97 118.7(2) . .
C136 C135 Cl97 118.9(2) . .
C135 C136 C131 121.4(3) . .
C135 C136 H13E 119.3 . .
C131 C136 H13E 119.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 Pb2 1.853(5) .
Pt1 P2 2.3220(8) .
Pt1 P1 2.3246(8) .
Pt1 Pb1 2.60762(19) .
Pb1 Cl1 2.7135(8) 2_656
Pb1 Cl1 2.8041(7) .
Pb2 C66 2.567(5) .
Pb2 P2 2.605(5) .
Pb2 Cl1 2.649(5) .
Pb2 Cl1 2.865(5) 2_656
Cl1 Pb1 2.7135(8) 2_656
Cl1 Pb2 2.865(5) 2_656
P1 C11 1.850(3) .
P1 C31 1.859(3) .
P1 C21 1.860(3) .
P2 C41 1.849(3) .
P2 C51 1.851(3) .
P2 C61 1.867(3) .
C11 C16 1.532(4) .
C11 C12 1.540(4) .
C11 H11A 1.0000 .
C12 C13 1.523(4) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.511(5) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C15 1.524(4) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 C16 1.525(4) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C21 C22 1.534(4) .
C21 C26 1.537(4) .
C21 H21A 1.0000 .
C22 C23 1.530(4) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C24 1.515(5) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.511(4) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.532(4) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C31 C36 1.522(4) .
C31 C32 1.527(4) .
C31 H31A 1.0000 .
C32 C33 1.527(4) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 C34 1.507(4) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C34 C35 1.523(4) .
C34 H34A 0.9900 .
C34 H34B 0.9900 .
C35 C36 1.530(4) .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C41 C46 1.535(4) .
C41 C42 1.540(4) .
C41 H41A 1.0000 .
C42 C43 1.531(4) .
C42 H42A 0.9900 .
C42 H42B 0.9900 .
C43 C44 1.526(4) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C44 C45 1.516(5) .
C44 H44A 0.9900 .
C44 H44B 0.9900 .
C45 C46 1.531(4) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 H46A 0.9900 .
C46 H46B 0.9900 .
C51 C52 1.524(4) .
C51 C56 1.536(4) .
C51 H51A 1.0000 .
C52 C53 1.529(4) .
C52 H52A 0.9900 .
C52 H52B 0.9900 .
C53 C54 1.512(4) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 C55 1.524(4) .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 C56 1.528(4) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C56 H56A 0.9900 .
C56 H56B 0.9900 .
C61 C66 1.533(4) .
C61 C62 1.544(4) .
C61 H61A 1.0000 .
C62 C63 1.532(4) .
C62 H62A 0.9900 .
C62 H62B 0.9900 .
C63 C64 1.514(4) .
C63 H63A 0.9900 .
C63 H63B 0.9900 .
C64 C65 1.518(4) .
C64 H64A 0.9900 .
C64 H64B 0.9900 .
C65 C66 1.521(4) .
C65 H65A 0.9900 .
C65 H65B 0.9900 .
C66 H66A 0.9900 .
C66 H66B 0.9900 .
Cl90 C105 1.748(3) .
Cl91 C103 1.751(3) .
Cl92 C113 1.746(3) .
Cl93 C115 1.764(3) .
Cl94 C123 1.754(3) .
Cl95 C125 1.742(3) .
Cl96 C133 1.756(3) .
Cl97 C135 1.753(3) .
B100 C111 1.632(4) .
B100 C121 1.642(4) .
B100 C131 1.645(4) .
B100 C101 1.655(4) .
C101 C102 1.391(4) .
C101 C106 1.400(4) .
C102 C103 1.387(4) .
C102 H10A 0.9500 .
C103 C104 1.381(4) .
C104 C105 1.375(4) .
C104 H10B 0.9500 .
C105 C106 1.384(4) .
C106 H10C 0.9500 .
C111 C116 1.402(4) .
C111 C112 1.408(4) .
C112 C113 1.376(4) .
C112 H11B 0.9500 .
C113 C114 1.373(4) .
C114 C115 1.379(4) .
C114 H11C 0.9500 .
C115 C116 1.379(4) .
C116 H11D 0.9500 .
C121 C126 1.394(4) .
C121 C122 1.397(4) .
C122 C123 1.387(4) .
C122 H12C 0.9500 .
C123 C124 1.374(4) .
C124 C125 1.387(4) .
C124 H12D 0.9500 .
C125 C126 1.380(4) .
C126 H12E 0.9500 .
C131 C136 1.399(4) .
C131 C132 1.405(4) .
C132 C133 1.381(4) .
C132 H13C 0.9500 .
C133 C134 1.379(4) .
C134 C135 1.377(4) .
C134 H13D 0.9500 .
C135 C136 1.384(4) .
C136 H13E 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Pb2 Pt1 Pb1 Cl1 -59.3(3) . 2_656
P2 Pt1 Pb1 Cl1 -116.21(2) . 2_656
P1 Pt1 Pb1 Cl1 56.74(2) . 2_656
Pb2 Pt1 Pb1 Cl1 19.8(3) . .
P2 Pt1 Pb1 Cl1 -37.09(3) . .
P1 Pt1 Pb1 Cl1 135.86(2) . .
P2 Pt1 Pb2 C66 -53.91(15) . .
P1 Pt1 Pb2 C66 111.44(16) . .
Pb1 Pt1 Pb2 C66 -175.1(4) . .
P1 Pt1 Pb2 P2 165.36(4) . .
Pb1 Pt1 Pb2 P2 -121.2(2) . .
P2 Pt1 Pb2 Cl1 47.6(7) . .
P1 Pt1 Pb2 Cl1 -147.1(7) . .
Pb1 Pt1 Pb2 Cl1 -73.6(7) . .
P2 Pt1 Pb2 Cl1 -170.4(2) . 2_656
P1 Pt1 Pb2 Cl1 -5.0(3) . 2_656
Pb1 Pt1 Pb2 Cl1 68.4(2) . 2_656
Pt1 Pb2 Cl1 Pb1 -179.2(7) . 2_656
C66 Pb2 Cl1 Pb1 -74.62(13) . 2_656
P2 Pb2 Cl1 Pb1 -137.64(13) . 2_656
Cl1 Pb2 Cl1 Pb1 33.81(8) 2_656 2_656
Pt1 Pb2 Cl1 Pb1 77.0(7) . .
C66 Pb2 Cl1 Pb1 -178.5(3) . .
P2 Pb2 Cl1 Pb1 118.5(3) . .
Cl1 Pb2 Cl1 Pb1 -70.06(16) 2_656 .
Pt1 Pb2 Cl1 Pb2 147.0(8) . 2_656
C66 Pb2 Cl1 Pb2 -108.43(16) . 2_656
P2 Pb2 Cl1 Pb2 -171.4(2) . 2_656
Cl1 Pb2 Cl1 Pb2 0.0 2_656 2_656
Pt1 Pb1 Cl1 Pb2 -15.0(2) . .
Cl1 Pb1 Cl1 Pb2 82.9(2) 2_656 .
Pt1 Pb1 Cl1 Pb1 -97.87(2) . 2_656
Cl1 Pb1 Cl1 Pb1 0.0 2_656 2_656
Pt1 Pb1 Cl1 Pb2 -129.27(10) . 2_656
Cl1 Pb1 Cl1 Pb2 -31.40(10) 2_656 2_656
Pb2 Pt1 P1 C11 -35.73(19) . .
P2 Pt1 P1 C11 81.30(14) . .
Pb1 Pt1 P1 C11 -72.51(10) . .
Pb2 Pt1 P1 C31 84.81(19) . .
P2 Pt1 P1 C31 -158.16(13) . .
Pb1 Pt1 P1 C31 48.03(11) . .
Pb2 Pt1 P1 C21 -155.39(18) . .
P2 Pt1 P1 C21 -38.36(14) . .
Pb1 Pt1 P1 C21 167.83(9) . .
Pb2 Pt1 P2 C41 154.93(18) . .
P1 Pt1 P2 C41 33.42(14) . .
Pb1 Pt1 P2 C41 -172.77(9) . .
Pb2 Pt1 P2 C51 -86.72(19) . .
P1 Pt1 P2 C51 151.77(12) . .
Pb1 Pt1 P2 C51 -54.42(11) . .
Pb2 Pt1 P2 C61 40.01(18) . .
P1 Pt1 P2 C61 -81.50(14) . .
Pb1 Pt1 P2 C61 72.30(10) . .
P1 Pt1 P2 Pb2 -121.51(18) . .
Pb1 Pt1 P2 Pb2 32.30(16) . .
Pt1 Pb2 P2 C41 -43.0(3) . .
C66 Pb2 P2 C41 76.6(2) . .
Pt1 Pb2 P2 C51 113.15(14) . .
C66 Pb2 P2 C51 -127.17(13) . .
Pt1 Pb2 P2 C61 -142.84(16) . .
C66 Pb2 P2 C61 -23.15(12) . .
Cl1 Pb2 P2 C61 52.74(15) . .
C66 Pb2 P2 Pt1 119.68(18) . .
Cl1 Pb2 P2 Pt1 -164.4(2) . .
C31 P1 C11 C16 57.1(2) . .
C21 P1 C11 C16 -51.5(2) . .
Pt1 P1 C11 C16 -170.84(18) . .
C31 P1 C11 C12 -172.1(2) . .
C21 P1 C11 C12 79.4(2) . .
Pt1 P1 C11 C12 -39.9(2) . .
C16 C11 C12 C13 -52.4(3) . .
P1 C11 C12 C13 174.4(2) . .
C11 C12 C13 C14 53.1(3) . .
C12 C13 C14 C15 -56.2(4) . .
C13 C14 C15 C16 58.4(4) . .
C14 C15 C16 C11 -57.4(3) . .
C12 C11 C16 C15 54.5(3) . .
P1 C11 C16 C15 -174.5(2) . .
C11 P1 C21 C22 -164.2(2) . .
C31 P1 C21 C22 87.8(2) . .
Pt1 P1 C21 C22 -43.5(2) . .
C11 P1 C21 C26 -39.4(3) . .
C31 P1 C21 C26 -147.3(2) . .
Pt1 P1 C21 C26 81.3(2) . .
C26 C21 C22 C23 58.0(3) . .
P1 C21 C22 C23 -173.5(2) . .
C21 C22 C23 C24 -57.3(4) . .
C22 C23 C24 C25 55.1(4) . .
C23 C24 C25 C26 -55.5(4) . .
C24 C25 C26 C21 57.4(4) . .
C22 C21 C26 C25 -57.6(3) . .
P1 C21 C26 C25 176.1(2) . .
C11 P1 C31 C36 -165.5(2) . .
C21 P1 C31 C36 -52.3(3) . .
Pt1 P1 C31 C36 70.0(3) . .
C11 P1 C31 C32 66.0(3) . .
C21 P1 C31 C32 179.1(2) . .
Pt1 P1 C31 C32 -58.6(3) . .
C36 C31 C32 C33 56.6(4) . .
P1 C31 C32 C33 -171.7(2) . .
C31 C32 C33 C34 -56.4(4) . .
C32 C33 C34 C35 54.6(4) . .
C33 C34 C35 C36 -54.4(4) . .
C32 C31 C36 C35 -56.0(4) . .
P1 C31 C36 C35 174.3(2) . .
C34 C35 C36 C31 55.6(4) . .
C51 P2 C41 C46 -51.3(2) . .
C61 P2 C41 C46 -163.9(2) . .
Pt1 P2 C41 C46 75.9(2) . .
Pb2 P2 C41 C46 105.3(3) . .
C51 P2 C41 C42 -175.05(19) . .
C61 P2 C41 C42 72.3(2) . .
Pt1 P2 C41 C42 -47.8(2) . .
Pb2 P2 C41 C42 -18.4(3) . .
C46 C41 C42 C43 55.7(3) . .
P2 C41 C42 C43 -178.89(19) . .
C41 C42 C43 C44 -55.5(3) . .
C42 C43 C44 C45 55.6(4) . .
C43 C44 C45 C46 -56.7(3) . .
C44 C45 C46 C41 57.3(3) . .
C42 C41 C46 C45 -56.1(3) . .
P2 C41 C46 C45 -179.6(2) . .
C41 P2 C51 C52 175.0(2) . .
C61 P2 C51 C52 -73.5(2) . .
Pt1 P2 C51 C52 56.1(2) . .
Pb2 P2 C51 C52 9.5(2) . .
C41 P2 C51 C56 -59.7(2) . .
C61 P2 C51 C56 51.8(2) . .
Pt1 P2 C51 C56 -178.57(16) . .
Pb2 P2 C51 C56 134.7(2) . .
C56 C51 C52 C53 52.8(3) . .
P2 C51 C52 C53 179.6(2) . .
C51 C52 C53 C54 -55.7(3) . .
C52 C53 C54 C55 56.3(3) . .
C53 C54 C55 C56 -57.1(3) . .
C54 C55 C56 C51 56.1(3) . .
C52 C51 C56 C55 -52.8(3) . .
P2 C51 C56 C55 179.76(19) . .
C41 P2 C61 C66 -102.2(2) . .
C51 P2 C61 C66 146.28(19) . .
Pt1 P2 C61 C66 13.3(2) . .
Pb2 P2 C61 C66 40.3(2) . .
C41 P2 C61 C62 24.2(2) . .
C51 P2 C61 C62 -87.3(2) . .
Pt1 P2 C61 C62 139.72(19) . .
Pb2 P2 C61 C62 166.7(2) . .
C66 C61 C62 C63 -54.8(3) . .
P2 C61 C62 C63 178.0(2) . .
C61 C62 C63 C64 54.6(3) . .
C62 C63 C64 C65 -55.2(3) . .
C63 C64 C65 C66 56.6(3) . .
C64 C65 C66 C61 -57.9(3) . .
C64 C65 C66 Pb2 -161.2(3) . .
C62 C61 C66 C65 56.8(3) . .
P2 C61 C66 C65 -174.04(19) . .
C62 C61 C66 Pb2 -169.3(2) . .
P2 C61 C66 Pb2 -40.11(19) . .
Pt1 Pb2 C66 C65 -167.8(3) . .
P2 Pb2 C66 C65 142.2(3) . .
Cl1 Pb2 C66 C65 32.5(3) . .
Cl1 Pb2 C66 C65 -40.8(4) 2_656 .
Pt1 Pb2 C66 C61 78.1(2) . .
P2 Pb2 C66 C61 28.05(14) . .
Cl1 Pb2 C66 C61 -81.70(18) . .
Cl1 Pb2 C66 C61 -155.0(2) 2_656 .
C111 B100 C101 C102 147.1(3) . .
C121 B100 C101 C102 26.8(4) . .
C131 B100 C101 C102 -90.6(3) . .
C111 B100 C101 C106 -37.3(3) . .
C121 B100 C101 C106 -157.6(3) . .
C131 B100 C101 C106 84.9(3) . .
C106 C101 C102 C103 0.6(4) . .
B100 C101 C102 C103 176.3(3) . .
C101 C102 C103 C104 0.7(4) . .
C101 C102 C103 Cl91 -178.5(2) . .
C102 C103 C104 C105 -1.6(4) . .
Cl91 C103 C104 C105 177.6(2) . .
C103 C104 C105 C106 1.3(4) . .
C103 C104 C105 Cl90 -178.1(2) . .
C104 C105 C106 C101 -0.1(5) . .
Cl90 C105 C106 C101 179.3(2) . .
C102 C101 C106 C105 -0.9(4) . .
B100 C101 C106 C105 -176.7(3) . .
C121 B100 C111 C116 -101.4(3) . .
C131 B100 C111 C116 21.0(4) . .
C101 B100 C111 C116 140.7(3) . .
C121 B100 C111 C112 76.2(3) . .
C131 B100 C111 C112 -161.4(2) . .
C101 B100 C111 C112 -41.7(3) . .
C116 C111 C112 C113 -0.8(4) . .
B100 C111 C112 C113 -178.6(2) . .
C111 C112 C113 C114 0.1(4) . .
C111 C112 C113 Cl92 -179.6(2) . .
C112 C113 C114 C115 0.6(4) . .
Cl92 C113 C114 C115 -179.7(2) . .
C113 C114 C115 C116 -0.5(4) . .
C113 C114 C115 Cl93 178.5(2) . .
C114 C115 C116 C111 -0.2(4) . .
Cl93 C115 C116 C111 -179.2(2) . .
C112 C111 C116 C115 0.9(4) . .
B100 C111 C116 C115 178.5(2) . .
C111 B100 C121 C126 166.7(2) . .
C131 B100 C121 C126 42.5(3) . .
C101 B100 C121 C126 -74.3(3) . .
C111 B100 C121 C122 -21.6(4) . .
C131 B100 C121 C122 -145.8(3) . .
C101 B100 C121 C122 97.4(3) . .
C126 C121 C122 C123 2.5(4) . .
B100 C121 C122 C123 -169.4(3) . .
C121 C122 C123 C124 1.5(4) . .
C121 C122 C123 Cl94 179.8(2) . .
C122 C123 C124 C125 -3.0(4) . .
Cl94 C123 C124 C125 178.6(2) . .
C123 C124 C125 C126 0.6(4) . .
C123 C124 C125 Cl95 179.3(2) . .
C124 C125 C126 C121 3.4(4) . .
Cl95 C125 C126 C121 -175.3(2) . .
C122 C121 C126 C125 -4.8(4) . .
B100 C121 C126 C125 167.4(3) . .
C111 B100 C131 C136 108.4(3) . .
C121 B100 C131 C136 -128.1(3) . .
C101 B100 C131 C136 -11.9(4) . .
C111 B100 C131 C132 -73.3(3) . .
C121 B100 C131 C132 50.2(4) . .
C101 B100 C131 C132 166.4(3) . .
C136 C131 C132 C133 -0.8(4) . .
B100 C131 C132 C133 -179.2(3) . .
C131 C132 C133 C134 0.9(5) . .
C131 C132 C133 Cl96 180.0(2) . .
C132 C133 C134 C135 -0.3(5) . .
Cl96 C133 C134 C135 -179.4(2) . .
C133 C134 C135 C136 -0.3(5) . .
C133 C134 C135 Cl97 179.4(2) . .
C134 C135 C136 C131 0.3(5) . .
Cl97 C135 C136 C131 -179.4(2) . .
C132 C131 C136 C135 0.3(4) . .
B100 C131 C136 C135 178.6(3) . .
