#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/1/52/06/1520666.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1520666
loop_
_publ_author_name
'Sasamori, Takahiro'
'Sugahara, Tomohiro'
'Agou, Tomohiro'
'Sugamata, Koh'
'Guo, Jing-Dong'
'Nagase, Shigeru'
'Tokitoh, Norihiro'
_publ_section_title
;
 Reaction of a diaryldigermyne with ethylene
;
_journal_issue                   10
_journal_name_full               'Chem. Sci.'
_journal_page_first              5526
_journal_paper_doi               10.1039/C5SC01266J
_journal_volume                  6
_journal_year                    2015
_chemical_formula_moiety         'C66 H146 Ge2 Si14, 2 (C7H8)'
_chemical_formula_sum            'C80 H162 Ge2 Si14'
_chemical_formula_weight         1662.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-03-17 deposited with the CCDC.
2015-06-24 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 103.2478(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.7486(2)
_cell_length_b                   20.8969(4)
_cell_length_c                   18.9393(3)
_cell_measurement_temperature    103(2)
_cell_measurement_theta_max      26.0
_cell_measurement_theta_min      1.91
_cell_volume                     4911.28(15)
_computing_cell_refinement       HKL2000
_computing_data_collection       CrystalClear
_computing_data_reduction        HKL2000
_computing_molecular_graphics
'Yadokari-XG 2011 (Wakita Nemoto et al., 2011)'
_computing_publication_material
'Yadokari-XG 2011 (Wakita,Nemoto et al., 2011)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      103(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku VariMax Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_source         'rotating-anode X-ray tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_av_sigmaI/netI    0.0328
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            44247
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    0.819
_exptl_absorpt_correction_T_max  0.9919
_exptl_absorpt_correction_T_min  0.9225
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 MULABS - Empirical Correction for Absorption Anisotropy.
 Blessing, R. H., Acta Cryst., A51, 33-38 (1995).
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.124
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1804
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.575
_refine_diff_density_min         -0.466
_refine_diff_density_rms         0.050
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     555
_refine_ls_number_reflns         9642
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0495
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0412P)²+3.3946P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0902
_refine_ls_wR_factor_ref         0.0977
_reflns_number_gt                8023
_reflns_number_total             9642
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5sc01266j2.cif
_cod_data_source_block           comp11
_cod_depositor_comments
'Adding full bibliography for 1520665--1520667.cif.'
_cod_original_cell_volume        4911.27(14)
_cod_original_sg_symbol_Hall     '-P 2yab '
_cod_original_sg_symbol_H-M      P21/a
_cod_database_code               1520666
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x-1/2, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.016792(18) 0.030797(12) 0.883863(12) 0.03085(8) Uani 1 1 d . . .
C1 C -0.0794(2) 0.10258(15) 0.86759(17) 0.0587(8) Uani 1 1 d . . .
H1 H -0.1001 0.1211 0.9106 0.070 Uiso 1 1 calc R . .
H2 H -0.0683 0.1347 0.8316 0.070 Uiso 1 1 calc R . .
C2 C -0.1342(2) 0.03906(15) 0.83762(15) 0.0503(7) Uani 1 1 d . . .
H3 H -0.1547 0.0341 0.7842 0.060 Uiso 1 1 calc R . .
H4 H -0.1865 0.0204 0.8632 0.060 Uiso 1 1 calc R . .
C3 C 0.0436(2) -0.00728(13) 0.98030(13) 0.0405(6) Uani 1 1 d . . .
H5 H 0.0498 -0.0543 0.9758 0.049 Uiso 1 1 calc R . .
H6 H 0.1132 0.0088 1.0094 0.049 Uiso 1 1 calc R . .
C4 C 0.12386(16) 0.01914(10) 0.82635(10) 0.0244(4) Uani 1 1 d . . .
C5 C 0.12010(15) -0.03570(9) 0.78270(10) 0.0235(4) Uani 1 1 d . . .
C6 C 0.19465(15) -0.04218(9) 0.73921(10) 0.0229(4) Uani 1 1 d . . .
H7 H 0.1902 -0.0789 0.7091 0.027 Uiso 1 1 calc R . .
C7 C 0.27553(15) 0.00293(9) 0.73802(10) 0.0214(4) Uani 1 1 d . A .
C8 C 0.27895(16) 0.05593(10) 0.78415(10) 0.0234(4) Uani 1 1 d . . .
H8 H 0.3331 0.0874 0.7851 0.028 Uiso 1 1 calc R . .
C9 C 0.20651(16) 0.06469(10) 0.82869(10) 0.0243(4) Uani 1 1 d . . .
C10 C 0.03740(17) -0.08851(10) 0.78268(12) 0.0282(4) Uani 1 1 d . . .
H9 H -0.0055 -0.0708 0.8162 0.034 Uiso 1 1 calc R . .
C11 C 0.35303(16) -0.00357(10) 0.68646(10) 0.0236(4) Uani 1 1 d . . .
C12 C 0.22040(17) 0.12141(11) 0.88089(11) 0.0311(5) Uani 1 1 d . . .
H10 H 0.1500 0.1223 0.8957 0.037 Uiso 1 1 calc R . .
Si1 Si -0.06743(5) -0.09508(3) 0.69423(4) 0.03531(15) Uani 1 1 d . . .
C13 C -0.0856(2) -0.01448(13) 0.65022(15) 0.0471(6) Uani 1 1 d . . .
H11 H -0.1526 -0.0140 0.6125 0.071 Uiso 1 1 calc R . .
H12 H -0.0245 -0.0054 0.6284 0.071 Uiso 1 1 calc R . .
H13 H -0.0892 0.0182 0.6867 0.071 Uiso 1 1 calc R . .
C14 C -0.1968(2) -0.12145(15) 0.71665(17) 0.0544(7) Uani 1 1 d . . .
H14 H -0.2133 -0.0933 0.7541 0.082 Uiso 1 1 calc R . .
H15 H -0.1892 -0.1656 0.7346 0.082 Uiso 1 1 calc R . .
H16 H -0.2553 -0.1192 0.6730 0.082 Uiso 1 1 calc R . .
C15 C -0.0353(2) -0.15343(13) 0.62669(15) 0.0489(7) Uani 1 1 d . . .
H17 H -0.0821 -0.1451 0.5788 0.073 Uiso 1 1 calc R . .
H18 H -0.0473 -0.1972 0.6418 0.073 Uiso 1 1 calc R . .
H19 H 0.0402 -0.1485 0.6242 0.073 Uiso 1 1 calc R . .
Si2 Si 0.09607(6) -0.16450(3) 0.83153(4) 0.03956(17) Uani 1 1 d . . .
C16 C -0.0021(3) -0.19518(19) 0.8832(2) 0.0954(15) Uani 1 1 d . . .
H20 H 0.0244 -0.2356 0.9070 0.143 Uiso 1 1 calc R . .
H21 H -0.0721 -0.2023 0.8498 0.143 Uiso 1 1 calc R . .
H22 H -0.0102 -0.1637 0.9200 0.143 Uiso 1 1 calc R . .
C17 C 0.1207(3) -0.23117(13) 0.77160(18) 0.0605(8) Uani 1 1 d . . .
H23 H 0.1581 -0.2145 0.7356 0.091 Uiso 1 1 calc R . .
H24 H 0.0517 -0.2500 0.7467 0.091 Uiso 1 1 calc R . .
H25 H 0.1654 -0.2640 0.8010 0.091 Uiso 1 1 calc R . .
C18 C 0.2260(2) -0.14525(14) 0.89667(15) 0.0551(7) Uani 1 1 d . . .
H26 H 0.2576 -0.1846 0.9206 0.083 Uiso 1 1 calc R . .
H27 H 0.2126 -0.1150 0.9332 0.083 Uiso 1 1 calc R . .
H28 H 0.2759 -0.1260 0.8704 0.083 Uiso 1 1 calc R . .
Si3 Si 0.42001(8) -0.08786(5) 0.69685(5) 0.0296(2) Uani 0.6306(12) 1 d P A 1
C19 C 0.3331(2) -0.15744(12) 0.6956(2) 0.0627(9) Uani 1 1 d . . .
H29 H 0.2941 -0.1534 0.7344 0.094 Uiso 0.6306(12) 1 calc PR A 1
H30 H 0.3772 -0.1964 0.7032 0.094 Uiso 0.6306(12) 1 calc PR A 1
H31 H 0.2814 -0.1599 0.6486 0.094 Uiso 0.6306(12) 1 calc PR A 1
H32 H 0.2774 -0.1519 0.7232 0.094 Uiso 0.3694(12) 1 calc PR A 2
H33 H 0.4039 -0.1602 0.7293 0.094 Uiso 0.3694(12) 1 calc PR A 2
H34 H 0.3193 -0.1968 0.6669 0.094 Uiso 0.3694(12) 1 calc PR A 2
C20 C 0.4800(3) -0.1106(2) 0.6184(2) 0.0440(10) Uani 0.6306(12) 1 d P A 1
H35 H 0.5304 -0.0773 0.6109 0.066 Uiso 0.6306(12) 1 calc PR A 1
H36 H 0.4223 -0.1150 0.5744 0.066 Uiso 0.6306(12) 1 calc PR A 1
H37 H 0.5183 -0.1514 0.6289 0.066 Uiso 0.6306(12) 1 calc PR A 1
C21 C 0.5316(2) -0.08737(15) 0.78273(15) 0.0547(8) Uani 1 1 d . . .
H38 H 0.5776 -0.0498 0.7826 0.082 Uiso 0.6306(12) 1 calc PR A 1
H39 H 0.5749 -0.1264 0.7847 0.082 Uiso 0.6306(12) 1 calc PR A 1
H40 H 0.4999 -0.0857 0.8252 0.082 Uiso 0.6306(12) 1 calc PR A 1
H41 H 0.5126 -0.1203 0.7451 0.082 Uiso 0.3694(12) 1 calc PR A 2
H42 H 0.4895 -0.0939 0.8194 0.082 Uiso 0.3694(12) 1 calc PR A 2
H43 H 0.6086 -0.0904 0.8057 0.082 Uiso 0.3694(12) 1 calc PR A 2
Si4 Si 0.46993(7) 0.05671(5) 0.70585(5) 0.0309(2) Uani 0.6306(12) 1 d P A 1
C22 C 0.53540(19) 0.06272(14) 0.80872(14) 0.0444(6) Uani 1 1 d . . .
H44 H 0.4812 0.0767 0.8347 0.067 Uiso 0.6306(12) 1 calc PR A 1
H45 H 0.5945 0.0938 0.8165 0.067 Uiso 0.6306(12) 1 calc PR A 1
H46 H 0.5636 0.0207 0.8269 0.067 Uiso 0.6306(12) 1 calc PR A 1
H47 H 0.6125 0.0600 0.8314 0.067 Uiso 0.3694(12) 1 calc PR A 2
H48 H 0.4936 0.0563 0.8456 0.067 Uiso 0.3694(12) 1 calc PR A 2
H49 H 0.5191 0.1050 0.7865 0.067 Uiso 0.3694(12) 1 calc PR A 2
C23 C 0.5888(2) 0.02998(17) 0.66903(18) 0.0648(9) Uani 1 1 d . . .
H50 H 0.6459 0.0623 0.6804 0.097 Uiso 0.6306(12) 1 calc PR A 1
H51 H 0.5660 0.0247 0.6163 0.097 Uiso 0.6306(12) 1 calc PR A 1
H52 H 0.6160 -0.0109 0.6913 0.097 Uiso 0.6306(12) 1 calc PR A 1
H53 H 0.5784 0.0009 0.6274 0.097 Uiso 0.3694(12) 1 calc PR A 2
H54 H 0.6650 0.0304 0.6943 0.097 Uiso 0.3694(12) 1 calc PR A 2
H55 H 0.5664 0.0733 0.6521 0.097 Uiso 0.3694(12) 1 calc PR A 2
C24 C 0.4127(3) 0.14165(14) 0.66708(17) 0.0764(11) Uani 1 1 d . . .
H56 H 0.3516 0.1534 0.6877 0.115 Uiso 0.6306(12) 1 calc PR A 1
H57 H 0.3891 0.1393 0.6141 0.115 Uiso 0.6306(12) 1 calc PR A 1
H58 H 0.4695 0.1740 0.6804 0.115 Uiso 0.6306(12) 1 calc PR A 1
H59 H 0.4881 0.1276 0.6779 0.115 Uiso 0.3694(12) 1 calc PR A 2
H60 H 0.3927 0.1537 0.7122 0.115 Uiso 0.3694(12) 1 calc PR A 2
H61 H 0.4040 0.1786 0.6344 0.115 Uiso 0.3694(12) 1 calc PR A 2
Si5 Si 0.26657(7) 0.00896(5) 0.59108(5) 0.0269(2) Uani 0.6306(12) 1 d P A 1
C25 C 0.1859(2) -0.06544(14) 0.55536(13) 0.0506(7) Uani 1 1 d . . .
H62 H 0.1402 -0.0774 0.5884 0.076 Uiso 0.6306(12) 1 calc PR A 1
H63 H 0.2353 -0.1007 0.5521 0.076 Uiso 0.6306(12) 1 calc PR A 1
H64 H 0.1405 -0.0566 0.5072 0.076 Uiso 0.6306(12) 1 calc PR A 1
H65 H 0.1307 -0.0578 0.5829 0.076 Uiso 0.3694(12) 1 calc PR A 2
H66 H 0.1675 -0.1040 0.5256 0.076 Uiso 0.3694(12) 1 calc PR A 2
H67 H 0.1893 -0.0287 0.5239 0.076 Uiso 0.3694(12) 1 calc PR A 2
C26 C 0.1712(2) 0.08038(12) 0.59221(13) 0.0406(6) Uani 1 1 d . . .
H68 H 0.1290 0.0729 0.6287 0.061 Uiso 0.6306(12) 1 calc PR A 1
H69 H 0.1223 0.0849 0.5443 0.061 Uiso 0.6306(12) 1 calc PR A 1
H70 H 0.2136 0.1196 0.6042 0.061 Uiso 0.6306(12) 1 calc PR A 1
H71 H 0.1416 0.0852 0.6353 0.061 Uiso 0.3694(12) 1 calc PR A 2
H72 H 0.1399 0.0424 0.5650 0.061 Uiso 0.3694(12) 1 calc PR A 2
H73 H 0.1535 0.1184 0.5614 0.061 Uiso 0.3694(12) 1 calc PR A 2
C27 C 0.3482(4) 0.0247(3) 0.5214(2) 0.0432(10) Uani 0.6306(12) 1 d P A 1
H74 H 0.3934 0.0626 0.5355 0.065 Uiso 0.6306(12) 1 calc PR A 1
H75 H 0.2994 0.0321 0.4740 0.065 Uiso 0.6306(12) 1 calc PR A 1
H76 H 0.3940 -0.0124 0.5184 0.065 Uiso 0.6306(12) 1 calc PR A 1
Si6 Si 0.32072(5) 0.10532(4) 0.97044(3) 0.04121(18) Uani 1 1 d . . .
C28 C 0.3466(2) 0.01788(14) 0.98204(14) 0.0463(6) Uani 1 1 d . . .
H77 H 0.3817 0.0025 0.9443 0.069 Uiso 1 1 calc R . .
H78 H 0.2781 -0.0047 0.9780 0.069 Uiso 1 1 calc R . .
H79 H 0.3936 0.0098 1.0299 0.069 Uiso 1 1 calc R . .
C29 C 0.4539(2) 0.14519(15) 0.98091(16) 0.0559(8) Uani 1 1 d . . .
H80 H 0.5001 0.1339 1.0281 0.084 Uiso 1 1 calc R . .
H81 H 0.4438 0.1917 0.9780 0.084 Uiso 1 1 calc R . .
H82 H 0.4879 0.1309 0.9422 0.084 Uiso 1 1 calc R . .
C30 C 0.2578(3) 0.13549(19) 1.04468(14) 0.0704(10) Uani 1 1 d . . .
H83 H 0.3078 0.1289 1.0918 0.106 Uiso 1 1 calc R . .
H84 H 0.1908 0.1121 1.0434 0.106 Uiso 1 1 calc R . .
H85 H 0.2420 0.1812 1.0375 0.106 Uiso 1 1 calc R . .
Si7 Si 0.22537(6) 0.20342(3) 0.83973(4) 0.04151(17) Uani 1 1 d . . .
C31 C 0.3599(2) 0.22715(13) 0.82317(19) 0.0592(8) Uani 1 1 d . . .
H86 H 0.3973 0.1890 0.8115 0.089 Uiso 1 1 calc R . .
H87 H 0.4033 0.2474 0.8668 0.089 Uiso 1 1 calc R . .
H88 H 0.3492 0.2574 0.7826 0.089 Uiso 1 1 calc R . .
C32 C 0.1907(3) 0.26377(14) 0.90396(18) 0.0626(9) Uani 1 1 d . . .
H89 H 0.1830 0.3061 0.8810 0.094 Uiso 1 1 calc R . .
H90 H 0.2483 0.2651 0.9482 0.094 Uiso 1 1 calc R . .
H91 H 0.1228 0.2517 0.9162 0.094 Uiso 1 1 calc R . .
C33 C 0.1218(2) 0.20642(13) 0.75282(15) 0.0532(7) Uani 1 1 d . . .
H92 H 0.0506 0.1980 0.7622 0.080 Uiso 1 1 calc R . .
H93 H 0.1381 0.1740 0.7196 0.080 Uiso 1 1 calc R . .
H94 H 0.1221 0.2489 0.7310 0.080 Uiso 1 1 calc R . .
C34 C -0.1687(4) 0.2389(2) 0.5182(3) 0.0548(17) Uani 0.592(8) 1 d P B 1
C35 C -0.2707(13) 0.2344(8) 0.5312(6) 0.058(3) Uani 0.592(8) 1 d P B 1
H95 H -0.3278 0.2589 0.5027 0.069 Uiso 0.592(8) 1 calc PR B 1
C36 C -0.2907(6) 0.1952(3) 0.5848(4) 0.0634(19) Uani 0.592(8) 1 d P B 1
H96 H -0.3615 0.1918 0.5927 0.076 Uiso 0.592(8) 1 calc PR B 1
C37 C -0.2072(5) 0.1607(3) 0.6271(3) 0.0642(19) Uani 0.592(8) 1 d P B 1
H97 H -0.2202 0.1339 0.6647 0.077 Uiso 0.592(8) 1 calc PR B 1
C38 C -0.1074(5) 0.1651(3) 0.6152(5) 0.0572(18) Uani 0.592(8) 1 d P B 1
H98 H -0.0499 0.1413 0.6443 0.069 Uiso 0.592(8) 1 calc PR B 1
C39 C -0.0885(8) 0.2046(7) 0.5598(10) 0.062(4) Uani 0.592(8) 1 d P B 1
H99 H -0.0179 0.2073 0.5514 0.074 Uiso 0.592(8) 1 calc PR B 1
C40 C -0.1471(7) 0.2830(4) 0.4608(4) 0.080(2) Uani 0.592(8) 1 d P B 1
H100 H -0.0705 0.2813 0.4602 0.120 Uiso 0.592(8) 1 calc PR B 1
H101 H -0.1664 0.3269 0.4712 0.120 Uiso 0.592(8) 1 calc PR B 1
H102 H -0.1904 0.2698 0.4133 0.120 Uiso 0.592(8) 1 calc PR B 1
Si8 Si 0.33062(14) -0.07758(8) 0.62491(9) 0.0309(4) Uani 0.3694(12) 1 d P A 2
C41 C 0.4391(7) -0.0911(4) 0.5737(4) 0.0456(18) Uani 0.3694(12) 1 d P A 2
H103 H 0.4222 -0.1296 0.5437 0.068 Uiso 0.3694(12) 1 calc PR A 2
H104 H 0.5086 -0.0967 0.6082 0.068 Uiso 0.3694(12) 1 calc PR A 2
H105 H 0.4429 -0.0541 0.5427 0.068 Uiso 0.3694(12) 1 calc PR A 2
Si9 Si 0.49919(13) -0.00016(8) 0.73761(9) 0.0288(4) Uani 0.3694(12) 1 d P A 2
Si10 Si 0.31912(14) 0.07130(8) 0.62022(9) 0.0295(4) Uani 0.3694(12) 1 d P A 2
C42 C 0.3633(6) 0.0638(4) 0.5320(4) 0.0397(16) Uani 0.3694(12) 1 d P A 2
H106 H 0.4418 0.0587 0.5421 0.060 Uiso 0.3694(12) 1 calc PR A 2
H107 H 0.3424 0.1024 0.5028 0.060 Uiso 0.3694(12) 1 calc PR A 2
H108 H 0.3287 0.0264 0.5052 0.060 Uiso 0.3694(12) 1 calc PR A 2
C43 C -0.2312(9) 0.2001(4) 0.5660(5) 0.058(3) Uani 0.408(8) 1 d P B 2
C44 C -0.1223(12) 0.1864(6) 0.5873(6) 0.057(4) Uani 0.408(8) 1 d P B 2
H109 H -0.0978 0.1598 0.6284 0.068 Uiso 0.408(8) 1 calc PR B 2
C45 C -0.0498(12) 0.2093(10) 0.5521(13) 0.055(4) Uani 0.408(8) 1 d P B 2
H110 H 0.0244 0.1990 0.5678 0.066 Uiso 0.408(8) 1 calc PR B 2
C46 C -0.0876(6) 0.2495(4) 0.4906(4) 0.050(2) Uani 0.408(8) 1 d P B 2
H111 H -0.0387 0.2673 0.4649 0.061 Uiso 0.408(8) 1 calc PR B 2
C47 C -0.1973(8) 0.2622(4) 0.4692(5) 0.057(2) Uani 0.408(8) 1 d P B 2
H112 H -0.2229 0.2891 0.4284 0.069 Uiso 0.408(8) 1 calc PR B 2
C48 C -0.269(2) 0.2375(12) 0.5046(7) 0.055(4) Uani 0.408(8) 1 d P B 2
H113 H -0.3435 0.2456 0.4878 0.065 Uiso 0.408(8) 1 calc PR B 2
C49 C -0.3068(13) 0.1705(7) 0.6065(8) 0.098(5) Uani 0.408(8) 1 d P B 2
H114 H -0.2657 0.1446 0.6465 0.148 Uiso 0.408(8) 1 calc PR B 2
H115 H -0.3585 0.1432 0.5736 0.148 Uiso 0.408(8) 1 calc PR B 2
H116 H -0.3455 0.2043 0.6259 0.148 Uiso 0.408(8) 1 calc PR B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C1 Ge1 C2 47.37(13) .
C1 Ge1 C4 120.85(10) .
C2 Ge1 C4 120.74(10) .
C1 Ge1 C3 115.99(11) .
C2 Ge1 C3 113.83(11) .
C4 Ge1 C3 118.57(9) .
C2 C1 Ge1 66.78(14) .
C2 C1 H1 117.0 .
Ge1 C1 H1 117.0 .
C2 C1 H2 117.0 .
Ge1 C1 H2 117.0 .
H1 C1 H2 114.1 .
C1 C2 Ge1 65.85(14) .
C1 C2 H3 117.1 .
Ge1 C2 H3 117.1 .
C1 C2 H4 117.1 .
Ge1 C2 H4 117.1 .
H3 C2 H4 114.2 .
C3 C3 Ge1 113.0(2) 3_557
C3 C3 H5 109.0 3_557
Ge1 C3 H5 109.0 .
C3 C3 H6 109.0 3_557
Ge1 C3 H6 109.0 .
H5 C3 H6 107.8 .
C5 C4 C9 119.45(18) .
C5 C4 Ge1 119.78(15) .
C9 C4 Ge1 120.76(15) .
C6 C5 C4 119.21(18) .
C6 C5 C10 119.49(18) .
C4 C5 C10 121.30(18) .
C5 C6 C7 123.09(18) .
C5 C6 H7 118.5 .
C7 C6 H7 118.5 .
C6 C7 C8 116.00(17) .
C6 C7 C11 122.02(17) .
C8 C7 C11 121.92(17) .
C9 C8 C7 123.20(19) .
C9 C8 H8 118.4 .
C7 C8 H8 118.4 .
C8 C9 C4 118.93(18) .
C8 C9 C12 119.82(18) .
C4 C9 C12 121.20(18) .
C5 C10 Si1 113.59(14) .
C5 C10 Si2 114.13(14) .
Si1 C10 Si2 119.26(12) .
C5 C10 H9 102.2 .
Si1 C10 H9 102.2 .
Si2 C10 H9 102.2 .
C7 C11 Si9 111.70(14) .
C7 C11 Si5 105.79(13) .
Si9 C11 Si5 140.06(12) .
C7 C11 Si8 115.28(14) .
Si9 C11 Si8 109.46(12) .
Si5 C11 Si8 64.00(9) .
C7 C11 Si4 113.68(14) .
Si9 C11 Si4 41.28(7) .
Si5 C11 Si4 110.23(11) .
Si8 C11 Si4 130.21(12) .
C7 C11 Si3 110.16(13) .
Si9 C11 Si3 67.99(9) .
Si5 C11 Si3 111.40(10) .
Si8 C11 Si3 48.17(8) .
Si4 C11 Si3 105.70(10) .
C7 C11 Si10 104.55(13) .
Si9 C11 Si10 109.80(12) .
Si5 C11 Si10 45.55(7) .
Si8 C11 Si10 105.67(11) .
Si4 C11 Si10 69.63(9) .
Si3 C11 Si10 143.28(12) .
C9 C12 Si7 116.53(15) .
C9 C12 Si6 113.19(15) .
Si7 C12 Si6 116.62(12) .
C9 C12 H10 102.5 .
Si7 C12 H10 102.5 .
Si6 C12 H10 102.5 .
C13 Si1 C14 109.87(13) .
C13 Si1 C15 107.76(13) .
C14 Si1 C15 107.65(13) .
C13 Si1 C10 108.61(11) .
C14 Si1 C10 107.44(12) .
C15 Si1 C10 115.45(11) .
Si1 C13 H11 109.5 .
Si1 C13 H12 109.5 .
H11 C13 H12 109.5 .
Si1 C13 H13 109.5 .
H11 C13 H13 109.5 .
H12 C13 H13 109.5 .
Si1 C14 H14 109.5 .
Si1 C14 H15 109.5 .
H14 C14 H15 109.5 .
Si1 C14 H16 109.5 .
H14 C14 H16 109.5 .
H15 C14 H16 109.5 .
Si1 C15 H17 109.5 .
Si1 C15 H18 109.5 .
H17 C15 H18 109.5 .
Si1 C15 H19 109.5 .
H17 C15 H19 109.5 .
H18 C15 H19 109.5 .
C18 Si2 C17 108.33(14) .
C18 Si2 C16 109.05(18) .
C17 Si2 C16 106.77(18) .
C18 Si2 C10 109.37(11) .
C17 Si2 C10 115.41(12) .
C16 Si2 C10 107.75(13) .
Si2 C16 H20 109.5 .
Si2 C16 H21 109.5 .
H20 C16 H21 109.5 .
Si2 C16 H22 109.5 .
H20 C16 H22 109.5 .
H21 C16 H22 109.5 .
Si2 C17 H23 109.5 .
Si2 C17 H24 109.5 .
H23 C17 H24 109.5 .
Si2 C17 H25 109.5 .
H23 C17 H25 109.5 .
H24 C17 H25 109.5 .
Si2 C18 H26 109.5 .
Si2 C18 H27 109.5 .
H26 C18 H27 109.5 .
Si2 C18 H28 109.5 .
H26 C18 H28 109.5 .
H27 C18 H28 109.5 .
C19 Si3 C20 98.28(18) .
C19 Si3 C21 110.39(16) .
C20 Si3 C21 108.51(17) .
C19 Si3 C11 117.94(11) .
C20 Si3 C11 113.38(17) .
C21 Si3 C11 107.86(11) .
Si3 C19 Si8 46.13(9) .
Si3 C19 H29 109.5 .
Si8 C19 H29 117.7 .
Si3 C19 H30 109.5 .
Si8 C19 H30 131.8 .
H29 C19 H30 109.5 .
Si3 C19 H31 109.5 .
Si8 C19 H31 64.0 .
H29 C19 H31 109.5 .
H30 C19 H31 109.5 .
Si3 C19 H32 114.3 .
Si8 C19 H32 109.5 .
H29 C19 H32 15.6 .
H30 C19 H32 118.7 .
H31 C19 H32 94.0 .
Si3 C19 H33 64.7 .
Si8 C19 H33 109.5 .
H29 C19 H33 93.9 .
H30 C19 H33 56.2 .
H31 C19 H33 156.2 .
H32 C19 H33 109.5 .
Si3 C19 H34 135.1 .
Si8 C19 H34 109.5 .
H29 C19 H34 115.4 .
H30 C19 H34 53.8 .
H31 C19 H34 56.9 .
H32 C19 H34 109.5 .
H33 C19 H34 109.5 .
Si3 C20 H35 109.5 .
Si3 C20 H36 109.5 .
H35 C20 H36 109.5 .
Si3 C20 H37 109.5 .
H35 C20 H37 109.5 .
H36 C20 H37 109.5 .
Si3 C21 Si9 66.49(10) .
Si3 C21 H38 109.5 .
Si9 C21 H38 48.7 .
Si3 C21 H39 109.5 .
Si9 C21 H39 145.8 .
H38 C21 H39 109.5 .
Si3 C21 H40 109.5 .
Si9 C21 H40 103.4 .
H38 C21 H40 109.5 .
H39 C21 H40 109.5 .
Si3 C21 H41 50.3 .
Si9 C21 H41 109.5 .
H38 C21 H41 127.5 .
H39 C21 H41 59.2 .
H40 C21 H41 122.8 .
Si3 C21 H42 100.4 .
Si9 C21 H42 109.5 .
H38 C21 H42 122.6 .
H39 C21 H42 104.7 .
H40 C21 H42 13.4 .
H41 C21 H42 109.5 .
Si3 C21 H43 148.9 .
Si9 C21 H43 109.5 .
H38 C21 H43 60.9 .
H39 C21 H43 55.4 .
H40 C21 H43 101.5 .
H41 C21 H43 109.5 .
H42 C21 H43 109.5 .
C23 Si4 C11 112.81(12) .
C23 Si4 C22 101.11(13) .
C11 Si4 C22 111.77(11) .
C23 Si4 C24 112.53(16) .
C11 Si4 C24 108.12(13) .
C22 Si4 C24 110.43(13) .
Si9 C22 Si4 41.38(8) .
Si9 C22 H44 119.1 .
Si4 C22 H44 109.5 .
Si9 C22 H45 129.1 .
Si4 C22 H45 109.5 .
H44 C22 H45 109.5 .
Si9 C22 H46 68.4 .
Si4 C22 H46 109.5 .
H44 C22 H46 109.5 .
H45 C22 H46 109.5 .
Si9 C22 H47 109.5 .
Si4 C22 H47 126.4 .
H44 C22 H47 123.3 .
H45 C22 H47 46.6 .
H46 C22 H47 62.9 .
Si9 C22 H48 109.5 .
Si4 C22 H48 121.9 .
H44 C22 H48 28.6 .
H45 C22 H48 120.6 .
H46 C22 H48 80.9 .
H47 C22 H48 109.5 .
Si9 C22 H49 109.5 .
Si4 C22 H49 68.2 .
H44 C22 H49 80.9 .
H45 C22 H49 63.1 .
H46 C22 H49 169.2 .
H47 C22 H49 109.5 .
H48 C22 H49 109.5 .
Si4 C23 Si9 40.10(8) .
Si4 C23 H50 109.5 .
Si9 C23 H50 125.1 .
Si4 C23 H51 109.5 .
Si9 C23 H51 122.8 .
H50 C23 H51 109.5 .
Si4 C23 H52 109.5 .
Si9 C23 H52 69.4 .
H50 C23 H52 109.5 .
H51 C23 H52 109.5 .
Si4 C23 H53 120.5 .
Si9 C23 H53 109.5 .
H50 C23 H53 124.0 .
H51 C23 H53 32.5 .
H52 C23 H53 77.1 .
Si4 C23 H54 127.3 .
Si9 C23 H54 109.5 .
H50 C23 H54 44.2 .
H51 C23 H54 121.8 .
H52 C23 H54 65.4 .
H53 C23 H54 109.5 .
Si4 C23 H55 69.5 .
Si9 C23 H55 109.5 .
H50 C23 H55 65.3 .
H51 C23 H55 77.0 .
H52 C23 H55 173.1 .
H53 C23 H55 109.5 .
H54 C23 H55 109.5 .
Si10 C24 Si4 68.57(11) .
Si10 C24 H56 84.9 .
Si4 C24 H56 109.5 .
Si10 C24 H57 59.3 .
Si4 C24 H57 109.5 .
H56 C24 H57 109.5 .
Si10 C24 H58 164.8 .
Si4 C24 H58 109.5 .
H56 C24 H58 109.5 .
H57 C24 H58 109.5 .
Si10 C24 H59 109.5 .
Si4 C24 H59 53.0 .
H56 C24 H59 145.4 .
H57 C24 H59 104.9 .
H58 C24 H59 61.5 .
Si10 C24 H60 109.5 .
Si4 C24 H60 93.1 .
H56 C24 H60 36.7 .
H57 C24 H60 145.6 .
H58 C24 H60 85.6 .
H59 C24 H60 109.5 .
Si10 C24 H61 109.5 .
Si4 C24 H61 156.0 .
H56 C24 H61 93.9 .
H57 C24 H61 55.2 .
H58 C24 H61 65.8 .
H59 C24 H61 109.5 .
H60 C24 H61 109.5 .
C27 Si5 C25 103.51(18) .
C27 Si5 C11 113.27(16) .
C25 Si5 C11 111.91(11) .
C27 Si5 C26 108.84(18) .
C25 Si5 C26 110.22(13) .
C11 Si5 C26 108.96(10) .
Si5 C25 Si8 62.11(9) .
Si5 C25 H62 109.5 .
Si8 C25 H62 98.0 .
Si5 C25 H63 109.5 .
Si8 C25 H63 56.2 .
H62 C25 H63 109.5 .
Si5 C25 H64 109.5 .
Si8 C25 H64 152.4 .
H62 C25 H64 109.5 .
H63 C25 H64 109.5 .
Si5 C25 H65 94.2 .
Si8 C25 H65 109.5 .
H62 C25 H65 25.5 .
H63 C25 H65 134.9 .
H64 C25 H65 97.0 .
Si5 C25 H66 156.2 .
Si8 C25 H66 109.5 .
H62 C25 H66 93.4 .
H63 C25 H66 54.5 .
H64 C25 H66 66.9 .
H65 C25 H66 109.5 .
Si5 C25 H67 58.6 .
Si8 C25 H67 109.5 .
H62 C25 H67 134.8 .
H63 C25 H67 115.6 .
H64 C25 H67 52.0 .
H65 C25 H67 109.5 .
H66 C25 H67 109.5 .
Si10 C26 Si5 47.08(8) .
Si10 C26 H68 118.0 .
Si5 C26 H68 109.5 .
Si10 C26 H69 131.7 .
Si5 C26 H69 109.5 .
H68 C26 H69 109.5 .
Si10 C26 H70 63.0 .
Si5 C26 H70 109.5 .
H68 C26 H70 109.5 .
H69 C26 H70 109.5 .
Si10 C26 H71 109.5 .
Si5 C26 H71 116.9 .
H68 C26 H71 18.4 .
H69 C26 H71 118.5 .
H70 C26 H71 91.1 .
Si10 C26 H72 109.5 .
Si5 C26 H72 63.2 .
H68 C26 H72 91.0 .
H69 C26 H72 59.8 .
H70 C26 H72 159.4 .
H71 C26 H72 109.5 .
Si10 C26 H73 109.5 .
Si5 C26 H73 132.8 .
H68 C26 H73 117.5 .
H69 C26 H73 50.2 .
H70 C26 H73 60.0 .
H71 C26 H73 109.5 .
H72 C26 H73 109.5 .
Si5 C27 H74 109.5 .
Si5 C27 H75 109.5 .
H74 C27 H75 109.5 .
Si5 C27 H76 109.5 .
H74 C27 H76 109.5 .
H75 C27 H76 109.5 .
C29 Si6 C28 107.12(13) .
C29 Si6 C30 107.80(15) .
C28 Si6 C30 109.60(15) .
C29 Si6 C12 115.20(13) .
C28 Si6 C12 110.06(11) .
C30 Si6 C12 106.98(11) .
Si6 C28 H77 109.5 .
Si6 C28 H78 109.5 .
H77 C28 H78 109.5 .
Si6 C28 H79 109.5 .
H77 C28 H79 109.5 .
H78 C28 H79 109.5 .
Si6 C29 H80 109.5 .
Si6 C29 H81 109.5 .
H80 C29 H81 109.5 .
Si6 C29 H82 109.5 .
H80 C29 H82 109.5 .
H81 C29 H82 109.5 .
Si6 C30 H83 109.5 .
Si6 C30 H84 109.5 .
H83 C30 H84 109.5 .
Si6 C30 H85 109.5 .
H83 C30 H85 109.5 .
H84 C30 H85 109.5 .
C33 Si7 C32 109.07(14) .
C33 Si7 C31 109.47(15) .
C32 Si7 C31 106.89(14) .
C33 Si7 C12 108.15(11) .
C32 Si7 C12 107.90(13) .
C31 Si7 C12 115.23(12) .
Si7 C31 H86 109.5 .
Si7 C31 H87 109.5 .
H86 C31 H87 109.5 .
Si7 C31 H88 109.5 .
H86 C31 H88 109.5 .
H87 C31 H88 109.5 .
Si7 C32 H89 109.5 .
Si7 C32 H90 109.5 .
H89 C32 H90 109.5 .
Si7 C32 H91 109.5 .
H89 C32 H91 109.5 .
H90 C32 H91 109.5 .
Si7 C33 H92 109.5 .
Si7 C33 H93 109.5 .
H92 C33 H93 109.5 .
Si7 C33 H94 109.5 .
H92 C33 H94 109.5 .
H93 C33 H94 109.5 .
C39 C34 C35 118.7(9) .
C39 C34 C40 120.7(8) .
C35 C34 C40 120.5(8) .
C36 C35 C34 120.9(11) .
C36 C35 H95 119.5 .
C34 C35 H95 119.5 .
C35 C36 C37 119.4(9) .
C35 C36 H96 120.3 .
C37 C36 H96 120.3 .
C38 C37 C36 120.1(7) .
C38 C37 H97 120.0 .
C36 C37 H97 120.0 .
C37 C38 C39 119.9(7) .
C37 C38 H98 120.1 .
C39 C38 H98 120.1 .
C34 C39 C38 121.0(8) .
C34 C39 H99 119.5 .
C38 C39 H99 119.5 .
C34 C40 H100 109.5 .
C34 C40 H101 109.5 .
H100 C40 H101 109.5 .
C34 C40 H102 109.5 .
H100 C40 H102 109.5 .
H101 C40 H102 109.5 .
C41 Si8 C11 114.2(2) .
C41 Si8 C25 110.6(3) .
C11 Si8 C25 106.34(13) .
C41 Si8 C19 107.4(3) .
C11 Si8 C19 105.67(13) .
C25 Si8 C19 112.75(13) .
Si8 C41 H103 109.5 .
Si8 C41 H104 109.5 .
H103 C41 H104 109.5 .
Si8 C41 H105 109.5 .
H103 C41 H105 109.5 .
H104 C41 H105 109.5 .
C22 Si9 C11 116.62(12) .
C22 Si9 C21 109.79(14) .
C11 Si9 C21 105.37(13) .
C22 Si9 C23 99.34(14) .
C11 Si9 C23 108.56(14) .
C21 Si9 C23 117.64(16) .
C26 Si10 C42 104.3(3) .
C26 Si10 C24 121.69(17) .
C42 Si10 C24 100.8(3) .
C26 Si10 C11 108.75(12) .
C42 Si10 C11 115.3(3) .
C24 Si10 C11 106.31(14) .
Si10 C42 H106 109.5 .
Si10 C42 H107 109.5 .
H106 C42 H107 109.5 .
Si10 C42 H108 109.5 .
H106 C42 H108 109.5 .
H107 C42 H108 109.5 .
C44 C43 C48 119.2(14) .
C44 C43 C49 119.1(11) .
C48 C43 C49 121.6(14) .
C45 C44 C43 122.6(12) .
C45 C44 H109 118.7 .
C43 C44 H109 118.7 .
C44 C45 C46 118.2(13) .
C44 C45 H110 120.9 .
C46 C45 H110 120.9 .
C47 C46 C45 118.7(9) .
C47 C46 H111 120.7 .
C45 C46 H111 120.7 .
C48 C47 C46 121.9(12) .
C48 C47 H112 119.0 .
C46 C47 H112 119.0 .
C47 C48 C43 119.3(19) .
C47 C48 H113 120.3 .
C43 C48 H113 120.3 .
C43 C49 H114 109.5 .
C43 C49 H115 109.5 .
H114 C49 H115 109.5 .
C43 C49 H116 109.5 .
H114 C49 H116 109.5 .
H115 C49 H116 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 C1 1.917(3) .
Ge1 C2 1.931(3) .
Ge1 C4 1.9469(19) .
Ge1 C3 1.949(2) .
C1 C2 1.546(4) .
C1 H1 0.9900 .
C1 H2 0.9900 .
C2 H3 0.9900 .
C2 H4 0.9900 .
C3 C3 1.505(4) 3_557
C3 H5 0.9900 .
C3 H6 0.9900 .
C4 C5 1.407(3) .
C4 C9 1.413(3) .
C5 C6 1.400(3) .
C5 C10 1.526(3) .
C6 C7 1.401(3) .
C6 H7 0.9500 .
C7 C8 1.405(3) .
C7 C11 1.546(3) .
C8 C9 1.398(3) .
C8 H8 0.9500 .
C9 C12 1.528(3) .
C10 Si1 1.893(2) .
C10 Si2 1.903(2) .
C10 H9 1.0000 .
C11 Si9 1.894(3) .
C11 Si5 1.906(2) .
C11 Si8 1.918(3) .
C11 Si4 1.922(2) .
C11 Si3 1.948(2) .
C11 Si10 1.990(3) .
C12 Si7 1.890(2) .
C12 Si6 1.906(2) .
C12 H10 1.0000 .
Si1 C13 1.870(3) .
Si1 C14 1.877(3) .
Si1 C15 1.879(3) .
C13 H11 0.9800 .
C13 H12 0.9800 .
C13 H13 0.9800 .
C14 H14 0.9800 .
C14 H15 0.9800 .
C14 H16 0.9800 .
C15 H17 0.9800 .
C15 H18 0.9800 .
C15 H19 0.9800 .
Si2 C18 1.868(3) .
Si2 C17 1.869(3) .
Si2 C16 1.871(3) .
C16 H20 0.9800 .
C16 H21 0.9800 .
C16 H22 0.9800 .
C17 H23 0.9800 .
C17 H24 0.9800 .
C17 H25 0.9800 .
C18 H26 0.9800 .
C18 H27 0.9800 .
C18 H28 0.9800 .
Si3 C19 1.825(3) .
Si3 C20 1.882(4) .
Si3 C21 1.900(3) .
C19 Si8 2.136(4) .
C19 H29 0.9800 .
C19 H30 0.9800 .
C19 H31 0.9800 .
C19 H32 0.9800 .
C19 H33 0.9800 .
C19 H34 0.9800 .
C20 H35 0.9800 .
C20 H36 0.9800 .
C20 H37 0.9800 .
C21 Si9 2.015(3) .
C21 H38 0.9800 .
C21 H39 0.9800 .
C21 H40 0.9800 .
C21 H41 0.9800 .
C21 H42 0.9800 .
C21 H43 0.9800 .
Si4 C23 1.892(3) .
Si4 C22 1.940(3) .
Si4 C24 1.994(4) .
C22 Si9 1.862(3) .
C22 H44 0.9800 .
C22 H45 0.9800 .
C22 H46 0.9800 .
C22 H47 0.9800 .
C22 H48 0.9800 .
C22 H49 0.9800 .
C23 Si9 2.017(3) .
C23 H50 0.9800 .
C23 H51 0.9800 .
C23 H52 0.9800 .
C23 H53 0.9800 .
C23 H54 0.9800 .
C23 H55 0.9800 .
C24 Si10 1.972(3) .
C24 H56 0.9800 .
C24 H57 0.9800 .
C24 H58 0.9800 .
C24 H59 0.9800 .
C24 H60 0.9800 .
C24 H61 0.9800 .
Si5 C27 1.887(4) .
Si5 C25 1.901(3) .
Si5 C26 1.929(3) .
C25 Si8 2.023(3) .
C25 H62 0.9800 .
C25 H63 0.9800 .
C25 H64 0.9800 .
C25 H65 0.9800 .
C25 H66 0.9800 .
C25 H67 0.9800 .
C26 Si10 1.849(3) .
C26 H68 0.9800 .
C26 H69 0.9800 .
C26 H70 0.9800 .
C26 H71 0.9800 .
C26 H72 0.9800 .
C26 H73 0.9800 .
C27 H74 0.9800 .
C27 H75 0.9800 .
C27 H76 0.9800 .
Si6 C29 1.861(3) .
Si6 C28 1.861(3) .
Si6 C30 1.880(3) .
C28 H77 0.9800 .
C28 H78 0.9800 .
C28 H79 0.9800 .
C29 H80 0.9800 .
C29 H81 0.9800 .
C29 H82 0.9800 .
C30 H83 0.9800 .
C30 H84 0.9800 .
C30 H85 0.9800 .
Si7 C33 1.860(3) .
Si7 C32 1.874(3) .
Si7 C31 1.879(3) .
C31 H86 0.9800 .
C31 H87 0.9800 .
C31 H88 0.9800 .
C32 H89 0.9800 .
C32 H90 0.9800 .
C32 H91 0.9800 .
C33 H92 0.9800 .
C33 H93 0.9800 .
C33 H94 0.9800 .
C34 C39 1.345(17) .
C34 C35 1.381(17) .
C34 C40 1.499(10) .
C35 C36 1.375(14) .
C35 H95 0.9500 .
C36 C37 1.379(9) .
C36 H96 0.9500 .
C37 C38 1.346(10) .
C37 H97 0.9500 .
C38 C39 1.399(19) .
C38 H98 0.9500 .
C39 H99 0.9500 .
C40 H100 0.9800 .
C40 H101 0.9800 .
C40 H102 0.9800 .
Si8 C41 1.883(7) .
C41 H103 0.9800 .
C41 H104 0.9800 .
C41 H105 0.9800 .
Si10 C42 1.888(7) .
C42 H106 0.9800 .
C42 H107 0.9800 .
C42 H108 0.9800 .
C43 C44 1.384(19) .
C43 C48 1.392(18) .
C43 C49 1.496(13) .
C44 C45 1.34(2) .
C44 H109 0.9500 .
C45 C46 1.43(2) .
C45 H110 0.9500 .
C46 C47 1.390(13) .
C46 H111 0.9500 .
C47 C48 1.35(2) .
C47 H112 0.9500 .
C48 H113 0.9500 .
C49 H114 0.9800 .
C49 H115 0.9800 .
C49 H116 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C4 Ge1 C1 C2 105.04(16) .
C3 Ge1 C1 C2 -99.32(17) .
C4 Ge1 C2 C1 -105.27(16) .
C3 Ge1 C2 C1 104.16(16) .
C1 Ge1 C3 C3 21.8(3) 3_557
C2 Ge1 C3 C3 -30.7(3) 3_557
C4 Ge1 C3 C3 178.0(2) 3_557
C1 Ge1 C4 C5 -118.32(19) .
C2 Ge1 C4 C5 -62.6(2) .
C3 Ge1 C4 C5 86.65(18) .
C1 Ge1 C4 C9 62.6(2) .
C2 Ge1 C4 C9 118.39(18) .
C3 Ge1 C4 C9 -92.40(19) .
C9 C4 C5 C6 -3.7(3) .
Ge1 C4 C5 C6 177.25(14) .
C9 C4 C5 C10 175.49(18) .
Ge1 C4 C5 C10 -3.6(3) .
C4 C5 C6 C7 1.5(3) .
C10 C5 C6 C7 -177.66(18) .
C5 C6 C7 C8 0.6(3) .
C5 C6 C7 C11 -176.67(18) .
C6 C7 C8 C9 -0.5(3) .
C11 C7 C8 C9 176.72(18) .
C7 C8 C9 C4 -1.6(3) .
C7 C8 C9 C12 175.99(18) .
C5 C4 C9 C8 3.7(3) .
Ge1 C4 C9 C8 -177.22(15) .
C5 C4 C9 C12 -173.85(18) .
Ge1 C4 C9 C12 5.2(3) .
C6 C5 C10 Si1 -68.8(2) .
C4 C5 C10 Si1 111.97(18) .
C6 C5 C10 Si2 72.4(2) .
C4 C5 C10 Si2 -106.77(19) .
C6 C7 C11 Si9 -125.94(18) .
C8 C7 C11 Si9 57.0(2) .
C6 C7 C11 Si5 68.1(2) .
C8 C7 C11 Si5 -109.00(18) .
C6 C7 C11 Si8 -0.2(2) .
C8 C7 C11 Si8 -177.26(16) .
C6 C7 C11 Si4 -170.82(15) .
C8 C7 C11 Si4 12.1(2) .
C6 C7 C11 Si3 -52.4(2) .
C8 C7 C11 Si3 130.50(17) .
C6 C7 C11 Si10 115.37(18) .
C8 C7 C11 Si10 -61.7(2) .
C8 C9 C12 Si7 55.3(2) .
C4 C9 C12 Si7 -127.12(18) .
C8 C9 C12 Si6 -84.0(2) .
C4 C9 C12 Si6 93.5(2) .
C5 C10 Si1 C13 -28.40(19) .
Si2 C10 Si1 C13 -167.50(13) .
C5 C10 Si1 C14 -147.19(17) .
Si2 C10 Si1 C14 73.70(16) .
C5 C10 Si1 C15 92.72(18) .
Si2 C10 Si1 C15 -46.39(16) .
C5 C10 Si2 C18 21.8(2) .
Si1 C10 Si2 C18 160.73(14) .
C5 C10 Si2 C17 -100.58(18) .
Si1 C10 Si2 C17 38.32(18) .
C5 C10 Si2 C16 140.2(2) .
Si1 C10 Si2 C16 -80.9(2) .
C7 C11 Si3 C19 47.8(2) .
Si9 C11 Si3 C19 153.84(16) .
Si5 C11 Si3 C19 -69.29(18) .
Si8 C11 Si3 C19 -58.60(16) .
Si4 C11 Si3 C19 170.98(15) .
Si10 C11 Si3 C19 -112.2(2) .
C7 C11 Si3 C20 161.78(18) .
Si9 C11 Si3 C20 -92.17(17) .
Si5 C11 Si3 C20 44.71(19) .
Si8 C11 Si3 C20 55.40(17) .
Si4 C11 Si3 C20 -75.02(18) .
Si10 C11 Si3 C20 1.8(3) .
C7 C11 Si3 C21 -78.04(17) .
Si9 C11 Si3 C21 28.01(13) .
Si5 C11 Si3 C21 164.89(13) .
Si8 C11 Si3 C21 175.58(14) .
Si4 C11 Si3 C21 45.16(15) .
Si10 C11 Si3 C21 122.0(2) .
C20 Si3 C19 Si8 -69.67(16) .
C21 Si3 C19 Si8 176.98(13) .
C11 Si3 C19 Si8 52.40(12) .
C19 Si3 C21 Si9 -156.67(13) .
C20 Si3 C21 Si9 96.68(18) .
C11 Si3 C21 Si9 -26.51(12) .
C7 C11 Si4 C23 158.40(17) .
Si9 C11 Si4 C23 61.93(16) .
Si5 C11 Si4 C23 -83.04(17) .
Si8 C11 Si4 C23 -10.5(2) .
Si3 C11 Si4 C23 37.46(17) .
Si10 C11 Si4 C23 -104.15(15) .
C7 C11 Si4 C22 45.25(18) .
Si9 C11 Si4 C22 -51.22(12) .
Si5 C11 Si4 C22 163.81(11) .
Si8 C11 Si4 C22 -123.66(16) .
Si3 C11 Si4 C22 -75.69(13) .
Si10 C11 Si4 C22 142.70(11) .
C7 C11 Si4 C24 -76.50(17) .
Si9 C11 Si4 C24 -172.96(14) .
Si5 C11 Si4 C24 42.07(15) .
Si8 C11 Si4 C24 114.59(17) .
Si3 C11 Si4 C24 162.56(12) .
Si10 C11 Si4 C24 20.96(12) .
C23 Si4 C22 Si9 -67.95(14) .
C11 Si4 C22 Si9 52.31(12) .
C24 Si4 C22 Si9 172.72(15) .
C11 Si4 C23 Si9 -58.08(12) .
C22 Si4 C23 Si9 61.43(12) .
C24 Si4 C23 Si9 179.25(15) .
C23 Si4 C24 Si10 103.95(14) .
C11 Si4 C24 Si10 -21.32(13) .
C22 Si4 C24 Si10 -143.89(11) .
C7 C11 Si5 C27 164.9(2) .
Si9 C11 Si5 C27 5.4(3) .
Si8 C11 Si5 C27 -84.3(2) .
Si4 C11 Si5 C27 41.6(2) .
Si3 C11 Si5 C27 -75.4(2) .
Si10 C11 Si5 C27 69.8(2) .
C7 C11 Si5 C25 -78.57(17) .
Si9 C11 Si5 C25 122.0(2) .
Si8 C11 Si5 C25 32.27(13) .
Si4 C11 Si5 C25 158.13(13) .
Si3 C11 Si5 C25 41.12(15) .
Si10 C11 Si5 C25 -173.64(14) .
C7 C11 Si5 C26 43.57(16) .
Si9 C11 Si5 C26 -115.9(2) .
Si8 C11 Si5 C26 154.41(11) .
Si4 C11 Si5 C26 -79.73(13) .
Si3 C11 Si5 C26 163.26(11) .
Si10 C11 Si5 C26 -51.50(11) .
C27 Si5 C25 Si8 91.32(17) .
C11 Si5 C25 Si8 -31.00(12) .
C26 Si5 C25 Si8 -152.41(11) .
C27 Si5 C26 Si10 -68.75(18) .
C25 Si5 C26 Si10 178.37(12) .
C11 Si5 C26 Si10 55.22(11) .
C9 C12 Si6 C29 105.08(18) .
Si7 C12 Si6 C29 -34.22(17) .
C9 C12 Si6 C28 -16.12(19) .
Si7 C12 Si6 C28 -155.42(12) .
C9 C12 Si6 C30 -135.13(19) .
Si7 C12 Si6 C30 85.57(18) .
C9 C12 Si7 C33 41.26(19) .
Si6 C12 Si7 C33 179.20(13) .
C9 C12 Si7 C32 159.11(17) .
Si6 C12 Si7 C32 -62.95(16) .
C9 C12 Si7 C31 -81.57(19) .
Si6 C12 Si7 C31 56.37(17) .
C39 C34 C35 C36 -0.9(18) .
C40 C34 C35 C36 -178.6(10) .
C34 C35 C36 C37 1.3(17) .
C35 C36 C37 C38 -0.9(12) .
C36 C37 C38 C39 0.0(11) .
C35 C34 C39 C38 0.1(17) .
C40 C34 C39 C38 177.7(9) .
C37 C38 C39 C34 0.4(16) .
C7 C11 Si8 C41 -170.8(3) .
Si9 C11 Si8 C41 -43.9(3) .
Si5 C11 Si8 C41 93.2(3) .
Si4 C11 Si8 C41 -2.1(4) .
Si3 C11 Si8 C41 -75.7(3) .
Si10 C11 Si8 C41 74.3(3) .
C7 C11 Si8 C25 66.96(18) .
Si9 C11 Si8 C25 -166.12(12) .
Si5 C11 Si8 C25 -29.03(11) .
Si4 C11 Si8 C25 -124.27(16) .
Si3 C11 Si8 C25 162.05(14) .
Si10 C11 Si8 C25 -47.94(15) .
C7 C11 Si8 C19 -53.08(18) .
Si9 C11 Si8 C19 73.83(15) .
Si5 C11 Si8 C19 -149.08(12) .
Si4 C11 Si8 C19 115.68(16) .
Si3 C11 Si8 C19 42.00(10) .
Si10 C11 Si8 C19 -167.98(12) .
Si5 C25 Si8 C41 -94.8(3) .
Si5 C25 Si8 C11 29.66(11) .
Si5 C25 Si8 C19 145.01(13) .
Si3 C19 Si8 C41 74.6(3) .
Si3 C19 Si8 C11 -47.57(11) .
Si3 C19 Si8 C25 -163.32(15) .
Si4 C22 Si9 C11 -56.50(12) .
Si4 C22 Si9 C21 -176.20(15) .
Si4 C22 Si9 C23 59.82(13) .
C7 C11 Si9 C22 -44.1(2) .
Si5 C11 Si9 C22 114.5(2) .
Si8 C11 Si9 C22 -173.05(14) .
Si4 C11 Si9 C22 57.51(14) .
Si3 C11 Si9 C22 -147.97(15) .
Si10 C11 Si9 C22 71.38(17) .
C7 C11 Si9 C21 77.91(17) .
Si5 C11 Si9 C21 -123.40(19) .
Si8 C11 Si9 C21 -51.00(15) .
Si4 C11 Si9 C21 179.56(15) .
Si3 C11 Si9 C21 -25.92(11) .
Si10 C11 Si9 C21 -166.57(12) .
C7 C11 Si9 C23 -155.22(16) .
Si5 C11 Si9 C23 3.5(3) .
Si8 C11 Si9 C23 75.86(16) .
Si4 C11 Si9 C23 -53.58(13) .
Si3 C11 Si9 C23 100.94(13) .
Si10 C11 Si9 C23 -39.71(17) .
Si3 C21 Si9 C22 153.30(12) .
Si3 C21 Si9 C11 26.94(11) .
Si3 C21 Si9 C23 -94.17(15) .
Si4 C23 Si9 C22 -65.46(12) .
Si4 C23 Si9 C11 56.84(12) .
Si4 C23 Si9 C21 176.28(17) .
Si5 C26 Si10 C42 71.7(3) .
Si5 C26 Si10 C24 -175.71(17) .
Si5 C26 Si10 C11 -51.79(10) .
Si4 C24 Si10 C26 145.38(14) .
Si4 C24 Si10 C42 -100.2(3) .
Si4 C24 Si10 C11 20.34(13) .
C7 C11 Si10 C26 -43.36(17) .
Si9 C11 Si10 C26 -163.33(13) .
Si5 C11 Si10 C26 54.63(12) .
Si8 C11 Si10 C26 78.71(15) .
Si4 C11 Si10 C26 -153.62(13) .
Si3 C11 Si10 C26 117.2(2) .
C7 C11 Si10 C42 -160.0(3) .
Si9 C11 Si10 C42 80.0(3) .
Si5 C11 Si10 C42 -62.0(3) .
Si8 C11 Si10 C42 -37.9(3) .
Si4 C11 Si10 C42 89.8(3) .
Si3 C11 Si10 C42 0.6(4) .
C7 C11 Si10 C24 89.27(18) .
Si9 C11 Si10 C24 -30.70(18) .
Si5 C11 Si10 C24 -172.73(16) .
Si8 C11 Si10 C24 -148.66(15) .
Si4 C11 Si10 C24 -20.99(14) .
Si3 C11 Si10 C24 -110.1(2) .
C48 C43 C44 C45 2(2) .
C49 C43 C44 C45 177.6(16) .
C43 C44 C45 C46 0(3) .
C44 C45 C46 C47 -1(2) .
C45 C46 C47 C48 -0.2(19) .
C46 C47 C48 C43 2(2) .
C44 C43 C48 C47 -3(2) .
C49 C43 C48 C47 -178.8(14) .
