#------------------------------------------------------------------------------
#$Date: 2016-09-16 14:55:27 +0300 (Fri, 16 Sep 2016) $
#$Revision: 186592 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/53/74/1537455.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1537455
loop_
_publ_author_name
'Iusenko, K.V.'
'Gromilov, S.A.'
'Romanenko, G.V.'
'Korol'kov, I.V.'
'Baidina, I.A.'
'Korenev, S.V.'
_publ_section_title
;
 Double complex salts (Rh (N H3)5 Cl)2 (M Cl6) Cl2 (M= Re, Os): synthesis
 and crystal structure
;
_journal_name_full               'Zhurnal Neorganicheskoi Khimii'
_journal_page_first              568
_journal_page_last               573
_journal_volume                  49
_journal_year                    2004
_chemical_formula_sum            'Cl10 H30 N10 Re Rh2'
_chemical_name_systematic        '(Rh (N H3)5 Cl)2 (Re Cl6) Cl2'
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 100.046
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.2377
_cell_length_b                   7.9615
_cell_length_c                   13.3856
_cell_volume                     1179.234
_citation_journal_id_ASTM        ZNOKAQ
_cod_data_source_file            Iusenko_ZNOKAQ_2004_556.cif
_cod_data_source_block           H30Cl10N10Re1Rh2
_cod_original_formula_sum        'H30 Cl10 N10 Re1 Rh2'
_cod_database_code               1537455
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,y,-z
-x,-y,-z
x,-y,z
x+1/2,y+1/2,z
-x+1/2,y+1/2,-z
-x+1/2,-y+1/2,-z
x+1/2,-y+1/2,z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_attached_hydrogens
Cl4 Cl-1 -0.363 0.5 0.0957 1 0.0 0
Rh1 Rh+3 -0.1718 0.5 0.1981 1 0.0 0
N3 N-3 -0.0019 0.5 0.2864 1 0.0 3
Cl2 Cl-1 -0.0096 0 0.3219 1 0.0 0
Cl5 Cl-1 0.1763 0.5 0.125 1 0.0 0
Cl1 Cl-1 0.2117 0 0.5235 1 0.0 0
N1 N-3 -0.2324 -0.3191 0.2866 1 0.0 3
Cl3 Cl-1 0 -0.2936 0.5 1 0.0 0
N2 N-3 -0.1161 -0.316 0.1067 1 0.0 3
Re1 Re+4 0 0 0.5 1 0.0 0
