#------------------------------------------------------------------------------
#$Date: 2016-11-05 06:37:56 +0200 (Sat, 05 Nov 2016) $
#$Revision: 187851 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/54/44/1544489.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1544489
loop_
_publ_author_name
'Liu, Qing-Xin'
'Yang, Yong-Xun'
'Zhang, Jian-Ping'
'Chen, Li-Ping'
'Shen, Yun-Heng'
'Li, Hui-Liang'
'Zhang, Wei-Dong'
_publ_section_title
;
 Isolation, Structure Elucidation, and Absolute Configuration of Highly
 Oxygenated Germacranolides from Carpesium cernuum.
;
_journal_issue                   10
_journal_name_full               'Journal of natural products'
_journal_page_first              2479
_journal_page_last               2486
_journal_paper_doi               10.1021/acs.jnatprod.6b00315
_journal_volume                  79
_journal_year                    2016
_chemical_absolute_configuration rmad
_chemical_formula_moiety         'C19 H28 O8, 2(H2 O)'
_chemical_formula_sum            'C19 H32 O10'
_chemical_formula_weight         420.44
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      tetragonal
_space_group_IT_number           76
_space_group_name_Hall           'P 4w'
_space_group_name_H-M_alt        'P 41'
_symmetry_space_group_name_Hall  'P 4w'
_symmetry_space_group_name_H-M   'P 41'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2015-04-21
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.23070(10)
_cell_length_b                   10.23070(10)
_cell_length_c                   20.5352(3)
_cell_measurement_reflns_used    6834
_cell_measurement_temperature    130
_cell_measurement_theta_max      69.215
_cell_measurement_theta_min      4.32
_cell_volume                     2149.36(4)
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      130
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0382
_diffrn_reflns_av_unetI/netI     0.0307
_diffrn_reflns_Laue_measured_fraction_full 0.976
_diffrn_reflns_Laue_measured_fraction_max 0.967
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            16308
_diffrn_reflns_point_group_measured_fraction_full 0.848
_diffrn_reflns_point_group_measured_fraction_max 0.836
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         69.753
_diffrn_reflns_theta_min         4.321
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.888
_exptl_absorpt_correction_T_max  0.7532
_exptl_absorpt_correction_T_min  0.6613
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.1350 before and 0.0527 after correction.
The Ratio of minimum to maximum transmission is 0.8780.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.299
_exptl_crystal_description       block
_exptl_crystal_F_000             904
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.536
_refine_diff_density_min         -0.331
_refine_diff_density_rms         0.054
_refine_ls_abs_structure_details
;
 Flack x determined using 1293 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.06(8)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     278
_refine_ls_number_reflns         3411
_refine_ls_number_restraints     25
_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.0404
_refine_ls_R_factor_gt           0.0393
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0713P)²+0.5336P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1042
_refine_ls_wR_factor_ref         0.1054
_reflns_Friedel_coverage         0.679
_reflns_Friedel_fraction_full    0.713
_reflns_Friedel_fraction_max     0.697
_reflns_number_gt                3311
_reflns_number_total             3411
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            np6b00315_si_003.cif
_cod_data_source_block           cu_dm15100_0m
_cod_original_cell_volume        2149.36(5)
_cod_database_code               1544489
_shelxl_version_number           2014-3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.957
_shelx_estimated_absorpt_t_min   0.809
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
C2' \\sim C3' \\sim C4': within 2A with sigma of 0.005 and sigma for terminal
atoms of 0.01
Uanis(C3') \\sim Ueq, Uanis(C4') \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
3.a Free rotating group:
 O2S(H2Sa,H2Sb), O1S(H1Sa,H1Sb)
3.b Ternary CH refined with riding coordinates:
 C2(H2a), C5(H5), C6(H6a), C7(H7), C8(H8), C10(H10), C2'(H2')
3.c Secondary CH2 refined with riding coordinates:
 C1(H1a,H1b), C3(H3a,H3b)
3.d X=CH2 refined with riding coordinates:
 C13(H13a,H13b)
3.e Idealised Me refined as rotating group:
 C14(H14a,H14b,H14c), C15(H15a,H15b,H15c), C3'(H3'a,H3'b,H3'c), C4'(H4'a,H4'b,
 H4'c)
3.f Idealised tetrahedral OH refined as rotating group:
 O2(H2), O6(H6)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x, z+1/4'
'y, -x, z+3/4'
'-x, -y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
O1 O -0.01227(17) -0.00607(18) -0.16011(11) 0.0179(4) Uani 1 1 d . .
O2 O 0.20598(18) -0.02693(18) -0.18683(11) 0.0194(4) Uani 1 1 d . .
H2 H 0.1981 -0.1082 -0.1912 0.029 Uiso 1 1 calc GR .
O3 O 0.25833(19) 0.19719(19) -0.10435(11) 0.0205(4) Uani 1 1 d . .
H3 H 0.315(4) 0.188(4) -0.132(2) 0.035(11) Uiso 1 1 d . .
O4 O -0.10328(18) 0.37605(18) -0.17438(10) 0.0206(4) Uani 1 1 d . .
O5 O -0.0070(2) 0.56954(19) -0.16451(12) 0.0302(5) Uani 1 1 d . .
O6 O -0.30397(18) 0.0405(2) -0.16371(11) 0.0240(5) Uani 1 1 d . .
H6 H -0.3756 0.0721 -0.1760 0.036 Uiso 1 1 calc GR .
O7 O -0.32570(18) 0.3061(2) -0.13035(11) 0.0231(4) Uani 1 1 d . .
O8 O -0.2783(3) 0.4726(2) -0.06289(14) 0.0404(6) Uani 1 1 d . .
C1 C 0.0222(3) -0.1552(3) -0.07546(16) 0.0211(6) Uani 1 1 d . .
H1A H 0.0522 -0.2355 -0.0979 0.025 Uiso 1 1 calc R .
H1B H -0.0089 -0.1784 -0.0313 0.025 Uiso 1 1 calc R .
C2 C -0.0839(3) -0.0865(3) -0.11425(15) 0.0197(6) Uani 1 1 d . .
H2A H -0.1360 -0.1530 -0.1387 0.024 Uiso 1 1 calc R .
C3 C -0.1746(3) -0.0096(3) -0.06951(15) 0.0204(6) Uani 1 1 d . .
H3A H -0.1193 0.0417 -0.0393 0.024 Uiso 1 1 calc R .
H3B H -0.2236 -0.0735 -0.0428 0.024 Uiso 1 1 calc R .
C4 C -0.2754(3) 0.0854(3) -0.10012(15) 0.0199(6) Uani 1 1 d . .
C5 C -0.2227(2) 0.2277(3) -0.10202(16) 0.0196(6) Uani 1 1 d . .
H5 H -0.2049 0.2583 -0.0566 0.023 Uiso 1 1 calc R .
C6 C -0.0996(2) 0.2465(2) -0.14400(15) 0.0176(6) Uani 1 1 d . .
H6A H -0.0962 0.1776 -0.1785 0.021 Uiso 1 1 calc R .
C7 C 0.0285(2) 0.2429(3) -0.10311(15) 0.0181(6) Uani 1 1 d . .
H7 H 0.0108 0.2041 -0.0593 0.022 Uiso 1 1 calc R .
C8 C 0.1390(2) 0.1678(2) -0.13707(15) 0.0167(5) Uani 1 1 d . .
H8 H 0.1458 0.1998 -0.1830 0.020 Uiso 1 1 calc R .
C9 C 0.1176(3) 0.0179(2) -0.13847(15) 0.0172(5) Uani 1 1 d . .
C10 C 0.1319(3) -0.0520(3) -0.07243(15) 0.0191(6) Uani 1 1 d . .
H10 H 0.1109 0.0117 -0.0370 0.023 Uiso 1 1 calc R .
C11 C 0.0591(3) 0.3867(3) -0.09649(16) 0.0205(6) Uani 1 1 d . .
C12 C -0.0158(3) 0.4574(3) -0.14695(16) 0.0206(6) Uani 1 1 d . .
C13 C 0.1337(3) 0.4489(3) -0.05431(18) 0.0289(7) Uani 1 1 d . .
H13A H 0.1402 0.5415 -0.0559 0.035 Uiso 1 1 calc R .
H13B H 0.1809 0.4012 -0.0223 0.035 Uiso 1 1 calc R .
C14 C 0.2659(3) -0.1114(3) -0.05871(18) 0.0273(7) Uani 1 1 d . .
H14A H 0.2829 -0.1822 -0.0897 0.041 Uiso 1 1 calc GR .
H14B H 0.2677 -0.1462 -0.0143 0.041 Uiso 1 1 calc GR .
H14C H 0.3333 -0.0439 -0.0633 0.041 Uiso 1 1 calc GR .
C15 C -0.3980(3) 0.0862(3) -0.05736(18) 0.0264(6) Uani 1 1 d . .
H15A H -0.3748 0.1145 -0.0133 0.040 Uiso 1 1 calc GR .
H15B H -0.4352 -0.0020 -0.0557 0.040 Uiso 1 1 calc GR .
H15C H -0.4625 0.1467 -0.0758 0.040 Uiso 1 1 calc GR .
C1' C -0.3372(3) 0.4289(3) -0.10868(19) 0.0324(7) Uani 1 1 d . .
C2' C -0.4346(4) 0.5066(4) -0.1490(3) 0.0546(12) Uani 1 1 d . U
H2' H -0.4432 0.4659 -0.1930 0.066 Uiso 1 1 calc R .
C3' C -0.5625(6) 0.5088(8) -0.1173(5) 0.109(3) Uani 1 1 d . U
H3'A H -0.5847 0.4206 -0.1023 0.163 Uiso 1 1 calc GR .
H3'B H -0.6287 0.5390 -0.1483 0.163 Uiso 1 1 calc GR .
H3'C H -0.5598 0.5683 -0.0799 0.163 Uiso 1 1 calc GR .
C4' C -0.3870(7) 0.6473(7) -0.1563(5) 0.105(2) Uani 1 1 d . U
H4'A H -0.3765 0.6867 -0.1131 0.157 Uiso 1 1 calc GR .
H4'B H -0.4510 0.6976 -0.1814 0.157 Uiso 1 1 calc GR .
H4'C H -0.3028 0.6479 -0.1791 0.157 Uiso 1 1 calc GR .
O2S O -0.1276(2) 0.4377(2) 0.05052(11) 0.0260(5) Uani 1 1 d . .
H2SA H -0.1748 0.4468 0.0155 0.039 Uiso 1 1 d G .
H2SB H -0.0645 0.3827 0.0430 0.039 Uiso 1 1 d G .
O1S O 0.2855(2) 0.2025(2) 0.03158(11) 0.0272(5) Uani 1 1 d . .
H1SA H 0.3366 0.1437 0.0486 0.041 Uiso 1 1 d G .
H1SB H 0.2833 0.1925 -0.0105 0.041 Uiso 1 1 d G .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C9 O1 C2 111.5(2)
C9 O2 H2 109.5
C8 O3 H3 105(3)
C12 O4 C6 111.3(2)
C4 O6 H6 109.5
C1' O7 C5 116.8(2)
H1A C1 H1B 109.1
C2 C1 H1A 111.2
C2 C1 H1B 111.2
C2 C1 C10 102.9(2)
C10 C1 H1A 111.2
C10 C1 H1B 111.2
O1 C2 C1 104.0(2)
O1 C2 H2A 109.2
O1 C2 C3 114.0(2)
C1 C2 H2A 109.2
C1 C2 C3 111.0(2)
C3 C2 H2A 109.2
C2 C3 H3A 107.6
C2 C3 H3B 107.6
C2 C3 C4 119.0(3)
H3A C3 H3B 107.0
C4 C3 H3A 107.6
C4 C3 H3B 107.6
O6 C4 C3 107.9(2)
O6 C4 C5 110.6(2)
O6 C4 C15 111.2(2)
C3 C4 C5 111.5(2)
C15 C4 C3 108.4(2)
C15 C4 C5 107.1(2)
O7 C5 C4 106.1(2)
O7 C5 H5 109.5
O7 C5 C6 107.6(2)
C4 C5 H5 109.5
C6 C5 C4 114.5(2)
C6 C5 H5 109.5
O4 C6 C5 109.3(2)
O4 C6 H6A 109.7
O4 C6 C7 105.8(2)
C5 C6 H6A 109.7
C5 C6 C7 112.6(2)
C7 C6 H6A 109.7
C6 C7 H7 110.1
C8 C7 C6 112.7(2)
C8 C7 H7 110.1
C11 C7 C6 101.6(2)
C11 C7 H7 110.1
C11 C7 C8 112.1(2)
O3 C8 C7 108.1(2)
O3 C8 H8 108.4
O3 C8 C9 109.8(2)
C7 C8 H8 108.4
C7 C8 C9 113.6(2)
C9 C8 H8 108.4
O1 C9 C8 108.0(2)
O1 C9 C10 106.5(2)
O2 C9 O1 108.7(2)
O2 C9 C8 104.1(2)
O2 C9 C10 113.9(2)
C10 C9 C8 115.5(2)
C1 C10 H10 108.6
C9 C10 C1 102.3(2)
C9 C10 H10 108.6
C14 C10 C1 112.8(2)
C14 C10 C9 115.7(2)
C14 C10 H10 108.6
C12 C11 C7 107.8(2)
C13 C11 C7 130.5(3)
C13 C11 C12 121.6(3)
O4 C12 C11 109.6(2)
O5 C12 O4 120.9(3)
O5 C12 C11 129.5(3)
C11 C13 H13A 120.0
C11 C13 H13B 120.0
H13A C13 H13B 120.0
C10 C14 H14A 109.5
C10 C14 H14B 109.5
C10 C14 H14C 109.5
H14A C14 H14B 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C4 C15 H15A 109.5
C4 C15 H15B 109.5
C4 C15 H15C 109.5
H15A C15 H15B 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
O7 C1' C2' 111.6(3)
O8 C1' O7 124.4(3)
O8 C1' C2' 124.0(3)
C1' C2' H2' 109.4
C1' C2' C4' 109.7(4)
C3' C2' C1' 110.6(5)
C3' C2' H2' 109.4
C3' C2' C4' 108.4(5)
C4' C2' H2' 109.4
C2' C3' H3'A 109.5
C2' C3' H3'B 109.5
C2' C3' H3'C 109.5
H3'A C3' H3'B 109.5
H3'A C3' H3'C 109.5
H3'B C3' H3'C 109.5
C2' C4' H4'A 109.5
C2' C4' H4'B 109.5
C2' C4' H4'C 109.5
H4'A C4' H4'B 109.5
H4'A C4' H4'C 109.5
H4'B C4' H4'C 109.5
H2SA O2S H2SB 109.4
H1SA O1S H1SB 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O1 C2 1.449(3)
O1 C9 1.423(3)
O2 H2 0.8400
O2 C9 1.419(3)
O3 H3 0.82(5)
O3 C8 1.426(3)
O4 C6 1.466(3)
O4 C12 1.346(4)
O5 C12 1.206(4)
O6 H6 0.8400
O6 C4 1.415(4)
O7 C5 1.446(3)
O7 C1' 1.338(4)
O8 C1' 1.203(5)
C1 H1A 0.9900
C1 H1B 0.9900
C1 C2 1.519(4)
C1 C10 1.543(4)
C2 H2A 1.0000
C2 C3 1.525(4)
C3 H3A 0.9900
C3 H3B 0.9900
C3 C4 1.550(4)
C4 C5 1.553(4)
C4 C15 1.531(4)
C5 H5 1.0000
C5 C6 1.539(4)
C6 H6A 1.0000
C6 C7 1.556(4)
C7 H7 1.0000
C7 C8 1.535(4)
C7 C11 1.510(4)
C8 H8 1.0000
C8 C9 1.549(3)
C9 C10 1.540(4)
C10 H10 1.0000
C10 C14 1.526(4)
C11 C12 1.478(4)
C11 C13 1.318(4)
C13 H13A 0.9500
C13 H13B 0.9500
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
C1' C2' 1.520(5)
C2' H2' 1.0000
C2' C3' 1.461(8)
C2' C4' 1.527(8)
C3' H3'A 0.9800
C3' H3'B 0.9800
C3' H3'C 0.9800
C4' H4'A 0.9800
C4' H4'B 0.9800
C4' H4'C 0.9800
O2S H2SA 0.8702
O2S H2SB 0.8702
O1S H1SA 0.8701
O1S H1SB 0.8702
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2 O1S 0.84 1.90 2.724(3) 167.0 3_554
O6 H6 O2S 0.84 2.05 2.884(3) 172.0 3_454
C6 H6A O1 1.00 2.10 2.754(3) 121.2 .
O2S H2SA O8 0.87 1.95 2.815(4) 178.2 .
O2S H2SB O2 0.87 2.08 2.861(3) 149.4 2
O1S H1SA O5 0.87 1.97 2.831(3) 171.6 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O1 C2 C3 C4 53.1(3)
O1 C9 C10 C1 21.6(3)
O1 C9 C10 C14 144.7(2)
O2 C9 C10 C1 -98.2(2)
O2 C9 C10 C14 24.9(3)
O3 C8 C9 O1 169.2(2)
O3 C8 C9 O2 -75.4(3)
O3 C8 C9 C10 50.2(3)
O4 C6 C7 C8 -101.3(2)
O4 C6 C7 C11 18.8(3)
O6 C4 C5 O7 60.7(3)
O6 C4 C5 C6 -57.8(3)
O7 C5 C6 O4 28.4(3)
O7 C5 C6 C7 145.7(2)
O7 C1' C2' C3' 97.4(6)
O7 C1' C2' C4' -143.1(5)
O8 C1' C2' C3' -82.4(7)
O8 C1' C2' C4' 37.1(7)
C1 C2 C3 C4 170.2(2)
C2 O1 C9 O2 122.7(2)
C2 O1 C9 C8 -125.0(2)
C2 O1 C9 C10 -0.5(3)
C2 C1 C10 C9 -33.7(3)
C2 C1 C10 C14 -158.6(3)
C2 C3 C4 O6 26.2(3)
C2 C3 C4 C5 -95.6(3)
C2 C3 C4 C15 146.8(2)
C3 C4 C5 O7 -179.1(2)
C3 C4 C5 C6 62.4(3)
C4 C5 C6 O4 146.1(2)
C4 C5 C6 C7 -96.6(3)
C5 O7 C1' O8 -8.7(5)
C5 O7 C1' C2' 171.5(3)
C5 C6 C7 C8 139.4(2)
C5 C6 C7 C11 -100.5(2)
C6 O4 C12 O5 -178.1(3)
C6 O4 C12 C11 2.2(3)
C6 C7 C8 O3 165.8(2)
C6 C7 C8 C9 -72.1(3)
C6 C7 C11 C12 -17.9(3)
C6 C7 C11 C13 160.0(3)
C7 C8 C9 O1 48.0(3)
C7 C8 C9 O2 163.4(2)
C7 C8 C9 C10 -71.0(3)
C7 C11 C12 O4 10.8(3)
C7 C11 C12 O5 -168.9(3)
C8 C7 C11 C12 102.7(3)
C8 C7 C11 C13 -79.4(4)
C8 C9 C10 C1 141.4(2)
C8 C9 C10 C14 -95.5(3)
C9 O1 C2 C1 -21.4(3)
C9 O1 C2 C3 99.6(3)
C10 C1 C2 O1 33.9(3)
C10 C1 C2 C3 -89.1(3)
C11 C7 C8 O3 52.0(3)
C11 C7 C8 C9 174.1(2)
C12 O4 C6 C5 107.7(3)
C12 O4 C6 C7 -13.8(3)
C13 C11 C12 O4 -167.3(3)
C13 C11 C12 O5 13.0(5)
C15 C4 C5 O7 -60.6(3)
C15 C4 C5 C6 -179.1(2)
C1' O7 C5 C4 146.6(3)
C1' O7 C5 C6 -90.3(3)
