#------------------------------------------------------------------------------
#$Date: 2020-04-05 13:26:44 +0300 (Sun, 05 Apr 2020) $
#$Revision: 250219 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/55/68/1556870.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1556870
loop_
_publ_author_name
'Wang, Hai-Xu'
'Wan, Qingyun'
'Low, Kam-Hung'
'Zhou, Cong-Ying'
'Huang, Jie-Sheng'
'Zhang, Jun-Long'
'Che, Chi-Ming'
_publ_section_title
;
 Stable group 8 metal porphyrin mono- and bis(dialkylcarbene) complexes:
 synthesis, characterization, and catalytic activity.
;
_journal_issue                   8
_journal_name_full               'Chemical science'
_journal_page_first              2243
_journal_page_last               2259
_journal_paper_doi               10.1039/c9sc05432d
_journal_volume                  11
_journal_year                    2020
_chemical_formula_moiety         'C64 H52 F4 N4 Os'
_chemical_formula_sum            'C64 H52 F4 N4 Os'
_chemical_formula_weight         1143.29
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   diff
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-10-26 deposited with the CCDC.	2019-12-30 downloaded from the CCDC.
;
_cell_angle_alpha                97.460(3)
_cell_angle_beta                 108.927(4)
_cell_angle_gamma                107.647(3)
_cell_formula_units_Z            1
_cell_length_a                   11.0536(7)
_cell_length_b                   11.1353(7)
_cell_length_c                   11.8926(7)
_cell_measurement_reflns_used    1172
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      66.1097
_cell_measurement_theta_min      2.7504
_cell_volume                     1276.53(15)
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_data_collection       'APEX3 v2018.7-2 (Bruker-AXS, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_molecular_graphics    'shelXle (C.B. Huebschle, rev 924)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 7.3910
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type
;
'Bruker D8 VENTURE KAPPA goniometer PHOTON II CPAD'
;
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34138
_diffrn_reflns_av_R_equivalents  0.0520
_diffrn_reflns_av_unetI/netI     0.0759
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            8354
_diffrn_reflns_point_group_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        52.978
_diffrn_reflns_theta_max         52.978
_diffrn_reflns_theta_min         3.533
_diffrn_source                   'Excillum MetalJet D2'
_exptl_absorpt_coefficient_mu    3.501
_exptl_absorpt_correction_T_max  0.7512
_exptl_absorpt_correction_T_min  0.5016
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/5 - Bruker AXS area detector scaling and absorption correction
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.487
_exptl_crystal_description       ribbon
_exptl_crystal_F_000             576
_exptl_crystal_size_max          0.059
_exptl_crystal_size_mid          0.033
_exptl_crystal_size_min          0.014
_refine_diff_density_max         1.556
_refine_diff_density_min         -2.149
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     362
_refine_ls_number_reflns         4387
_refine_ls_number_restraints     141
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0567
_refine_ls_R_factor_gt           0.0517
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0432P)²+2.5115P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1270
_refine_ls_wR_factor_ref         0.1315
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4011
_reflns_number_total             4387
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9sc05432d2.cif
_cod_data_source_block           ga_CHEM0721
_cod_depositor_comments
;Adding full bibliography for 1556869--1556873.cif.

 Adding full bibliography for 1556869--1556873.cif.
;
_cod_original_cell_volume        1276.53(14)
_cod_database_code               1556870
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.820
_shelx_estimated_absorpt_t_max   0.953
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.500000 1.000000 0.500000 0.04762(17) Uani 1 2 d DS . P . .
F1 F 0.3313(5) 0.2248(4) 0.0151(4) 0.0832(14) Uani 1 1 d . . . . .
F2 F 0.0557(4) 0.5995(5) 0.9482(4) 0.0884(15) Uani 1 1 d . . . . .
N1 N 0.4004(5) 0.8078(4) 0.4941(4) 0.0394(10) Uani 1 1 d . . . . .
N2 N 0.4532(5) 1.0585(4) 0.6471(4) 0.0383(10) Uani 1 1 d . . . . .
C11 C 0.4405(6) 0.7044(5) 0.3208(5) 0.0380(12) Uani 1 1 d . . . . .
C12 C 0.3911(6) 0.7032(5) 0.4145(5) 0.0371(12) Uani 1 1 d . . . . .
C13 C 0.3210(6) 0.5857(6) 0.4446(5) 0.0453(13) Uani 1 1 d . . . . .
H13 H 0.301241 0.498384 0.404592 0.054 Uiso 1 1 calc R U . . .
C14 C 0.2897(6) 0.6245(6) 0.5398(5) 0.0473(14) Uani 1 1 d . . . . .
H14 H 0.243994 0.568978 0.579579 0.057 Uiso 1 1 calc R U . . .
C15 C 0.3374(6) 0.7647(6) 0.5714(5) 0.0433(13) Uani 1 1 d . . . . .
C16 C 0.3273(6) 0.8435(6) 0.6667(5) 0.0428(13) Uani 1 1 d . . . . .
C17 C 0.3792(6) 0.9790(6) 0.7000(5) 0.0400(12) Uani 1 1 d . . . . .
C18 C 0.3652(6) 1.0611(6) 0.7959(5) 0.0419(13) Uani 1 1 d . . . . .
H18 H 0.318282 1.032076 0.847270 0.050 Uiso 1 1 calc R U . . .
C19 C 0.4296(6) 1.1846(6) 0.7994(5) 0.0411(12) Uani 1 1 d . . . . .
H19 H 0.437284 1.259069 0.854282 0.049 Uiso 1 1 calc R U . . .
C20 C 0.4861(5) 1.1859(5) 0.7053(5) 0.0365(12) Uani 1 1 d . . . . .
C21 C 0.4110(6) 0.5747(5) 0.2397(5) 0.0395(12) Uani 1 1 d . . . . .
C22 C 0.5124(8) 0.5245(7) 0.2518(7) 0.066(2) Uani 1 1 d . . . . .
H22 H 0.601766 0.570917 0.313391 0.079 Uiso 1 1 calc R U . . .
C23 C 0.4854(9) 0.4064(8) 0.1749(8) 0.073(2) Uani 1 1 d . . . . .
H23 H 0.555643 0.371810 0.183022 0.088 Uiso 1 1 calc R U . . .
C24 C 0.3582(8) 0.3419(6) 0.0888(7) 0.0592(18) Uani 1 1 d . . . . .
C25 C 0.2555(7) 0.3881(6) 0.0729(6) 0.0576(17) Uani 1 1 d . . . . .
H25 H 0.166741 0.340853 0.010578 0.069 Uiso 1 1 calc R U . . .
C26 C 0.2831(6) 0.5068(6) 0.1505(6) 0.0484(14) Uani 1 1 d . . . . .
H26 H 0.212256 0.540700 0.141160 0.058 Uiso 1 1 calc R U . . .
C27 C 0.2543(6) 0.7764(6) 0.7414(5) 0.0419(13) Uani 1 1 d . . . . .
C28 C 0.1175(7) 0.6932(7) 0.6871(6) 0.0556(16) Uani 1 1 d . . . . .
H28 H 0.069187 0.677513 0.601202 0.067 Uiso 1 1 calc R U . . .
C29 C 0.0505(7) 0.6328(8) 0.7560(7) 0.0653(19) Uani 1 1 d . . . . .
H29 H -0.043123 0.575562 0.718513 0.078 Uiso 1 1 calc R U . . .
C30 C 0.1220(7) 0.6574(8) 0.8794(7) 0.0590(17) Uani 1 1 d . . . . .
C31 C 0.2557(7) 0.7367(7) 0.9371(6) 0.0538(16) Uani 1 1 d . . . . .
H31 H 0.302324 0.751146 1.023087 0.065 Uiso 1 1 calc R U . . .
C32 C 0.3232(6) 0.7965(6) 0.8670(5) 0.0449(13) Uani 1 1 d . . . . .
H32 H 0.417457 0.851740 0.905570 0.054 Uiso 1 1 calc R U . . .
C1 C 0.6822(8) 0.9954(9) 0.6163(8) 0.0543(15) Uani 0.614(5) 1 d D U P A 1
C2 C 0.7444(9) 0.8952(9) 0.5956(8) 0.057(2) Uani 0.614(5) 1 d D U P A 1
H2 H 0.680735 0.826417 0.518105 0.069 Uiso 0.614(5) 1 calc R U P A 1
C3 C 0.7844(9) 1.0967(9) 0.7331(8) 0.059(2) Uani 0.614(5) 1 d D U P A 1
H3 H 0.747501 1.165697 0.750202 0.070 Uiso 0.614(5) 1 calc R U P A 1
C4 C 0.7687(11) 0.8319(10) 0.7073(8) 0.059(2) Uani 0.614(5) 1 d D U P A 1
H4A H 0.680447 0.792019 0.716488 0.071 Uiso 0.614(5) 1 calc R U P A 1
H4AB H 0.803982 0.762190 0.691907 0.071 Uiso 0.614(5) 1 calc R U P A 1
C5 C 0.8855(9) 0.9645(14) 0.5854(10) 0.070(3) Uani 0.614(5) 1 d D U P A 1
H5A H 0.923368 0.898639 0.564725 0.084 Uiso 0.614(5) 1 calc R U P A 1
H5AB H 0.871029 1.009643 0.518500 0.084 Uiso 0.614(5) 1 calc R U P A 1
C6 C 0.8080(13) 1.0295(12) 0.8422(9) 0.070(3) Uani 0.614(5) 1 d D U P A 1
H6A H 0.870213 1.096222 0.920040 0.085 Uiso 0.614(5) 1 calc R U P A 1
H6AB H 0.719085 0.986954 0.849439 0.085 Uiso 0.614(5) 1 calc R U P A 1
C7 C 0.9237(10) 1.1595(11) 0.7175(13) 0.073(3) Uani 0.614(5) 1 d D U P A 1
H7A H 0.907212 1.195724 0.644616 0.088 Uiso 0.614(5) 1 calc R U P A 1
H7AB H 0.988310 1.231756 0.790644 0.088 Uiso 0.614(5) 1 calc R U P A 1
C8 C 0.8688(10) 0.9312(9) 0.8220(9) 0.071(2) Uani 0.614(5) 1 d D U P A 1
H8 H 0.884095 0.889697 0.892444 0.085 Uiso 0.614(5) 1 calc R U P A 1
C9 C 0.9848(11) 1.0602(10) 0.7025(9) 0.077(3) Uani 0.614(5) 1 d D U P A 1
H9 H 1.075124 1.101217 0.695443 0.092 Uiso 0.614(5) 1 calc R U P A 1
C10 C 1.0063(10) 1.0026(14) 0.8139(11) 0.077(3) Uani 0.614(5) 1 d D U P A 1
H10A H 1.053873 0.941231 0.807545 0.092 Uiso 0.614(5) 1 calc R U P A 1
H10B H 1.065279 1.073304 0.889697 0.092 Uiso 0.614(5) 1 calc R U P A 1
C1B C 0.3188(8) 1.0060(15) 0.3831(12) 0.0543(15) Uani 0.386(5) 1 d D . P A 2
C2B C 0.1812(11) 0.9417(12) 0.3905(12) 0.057(2) Uani 0.386(5) 1 d D . P A 2
H2B H 0.188682 0.890622 0.454016 0.069 Uiso 0.386(5) 1 calc R U P A 2
C3B C 0.3155(15) 1.0804(11) 0.2853(10) 0.059(2) Uani 0.386(5) 1 d D . P A 2
H3B H 0.408986 1.117999 0.283297 0.070 Uiso 0.386(5) 1 calc R U P A 2
C4B C 0.143(2) 1.0613(14) 0.4277(13) 0.059(2) Uani 0.386(5) 1 d D . P A 2
H4BA H 0.054492 1.030240 0.438873 0.071 Uiso 0.386(5) 1 calc R U P A 2
H4BB H 0.214547 1.119161 0.506978 0.071 Uiso 0.386(5) 1 calc R U P A 2
C5B C 0.094(2) 0.8502(14) 0.2577(11) 0.070(3) Uani 0.386(5) 1 d D . P A 2
H5BA H 0.141438 0.794168 0.236052 0.084 Uiso 0.386(5) 1 calc R U P A 2
H5BB H 0.002718 0.793559 0.252893 0.084 Uiso 0.386(5) 1 calc R U P A 2
C6B C 0.2682(14) 1.1911(14) 0.3288(19) 0.070(3) Uani 0.386(5) 1 d D . P A 2
H6BA H 0.335317 1.244671 0.411502 0.085 Uiso 0.386(5) 1 calc R U P A 2
H6BB H 0.265712 1.248450 0.271663 0.085 Uiso 0.386(5) 1 calc R U P A 2
C7B C 0.2118(12) 0.979(2) 0.1609(13) 0.073(3) Uani 0.386(5) 1 d D . P A 2
H7BA H 0.206917 1.019454 0.091177 0.088 Uiso 0.386(5) 1 calc R U P A 2
H7BB H 0.240695 0.904007 0.147298 0.088 Uiso 0.386(5) 1 calc R U P A 2
C8B C 0.1302(13) 1.1358(15) 0.3327(11) 0.071(2) Uani 0.386(5) 1 d D . P A 2
H8B H 0.098345 1.207247 0.354510 0.085 Uiso 0.386(5) 1 calc R U P A 2
C9B C 0.0770(13) 0.9355(14) 0.1728(14) 0.077(3) Uani 0.386(5) 1 d D . P A 2
H9B H 0.006896 0.878857 0.090971 0.092 Uiso 0.386(5) 1 calc R U P A 2
C10B C 0.0275(18) 1.0431(15) 0.2089(14) 0.077(3) Uani 0.386(5) 1 d D . P A 2
H10C H 0.016385 1.092406 0.145204 0.092 Uiso 0.386(5) 1 calc R U P A 2
H10D H -0.063153 1.003662 0.213990 0.092 Uiso 0.386(5) 1 calc R U P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -6.0803 4.9890 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0583 0.0400 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1B Os1 C1B 180.0 . 2_676
C1 Os1 C1 180.0(9) 2_676 .
C1B Os1 N2 89.2(5) . .
C1B Os1 N2 90.8(5) 2_676 .
C1 Os1 N2 89.0(3) 2_676 .
C1 Os1 N2 91.0(3) . .
C1 Os1 N2 91.0(3) 2_676 2_676
C1 Os1 N2 89.0(3) . 2_676
N2 Os1 N2 180.0(3) . 2_676
C1 Os1 N1 89.9(3) 2_676 2_676
C1 Os1 N1 90.1(3) . 2_676
N2 Os1 N1 90.51(18) . 2_676
N2 Os1 N1 89.49(18) 2_676 2_676
C1B Os1 N1 90.6(4) . .
C1B Os1 N1 89.4(4) 2_676 .
C1 Os1 N1 90.1(3) 2_676 .
C1 Os1 N1 89.9(3) . .
N2 Os1 N1 89.49(18) . .
N2 Os1 N1 90.51(18) 2_676 .
N1 Os1 N1 180.0 2_676 .
C12 N1 C15 108.8(5) . .
C12 N1 Os1 124.9(4) . .
C15 N1 Os1 126.2(4) . .
C17 N2 C20 108.4(4) . .
C17 N2 Os1 126.5(4) . .
C20 N2 Os1 125.0(4) . .
C20 C11 C12 125.8(5) 2_676 .
C20 C11 C21 116.8(5) 2_676 .
C12 C11 C21 117.4(5) . .
N1 C12 C11 127.1(5) . .
N1 C12 C13 108.3(5) . .
C11 C12 C13 124.6(5) . .
C14 C13 C12 106.8(5) . .
C14 C13 H13 126.6 . .
C12 C13 H13 126.6 . .
C13 C14 C15 108.4(5) . .
C13 C14 H14 125.8 . .
C15 C14 H14 125.8 . .
N1 C15 C16 125.8(5) . .
N1 C15 C14 107.6(5) . .
C16 C15 C14 126.5(5) . .
C17 C16 C15 126.1(5) . .
C17 C16 C27 116.5(5) . .
C15 C16 C27 117.4(5) . .
N2 C17 C16 125.8(5) . .
N2 C17 C18 107.8(5) . .
C16 C17 C18 126.4(5) . .
C19 C18 C17 107.9(5) . .
C19 C18 H18 126.0 . .
C17 C18 H18 126.0 . .
C18 C19 C20 108.3(5) . .
C18 C19 H19 125.9 . .
C20 C19 H19 125.9 . .
N2 C20 C11 126.6(5) . 2_676
N2 C20 C19 107.5(5) . .
C11 C20 C19 125.9(5) 2_676 .
C26 C21 C22 119.0(6) . .
C26 C21 C11 120.2(5) . .
C22 C21 C11 120.8(5) . .
C21 C22 C23 120.6(7) . .
C21 C22 H22 119.7 . .
C23 C22 H22 119.7 . .
C24 C23 C22 118.8(7) . .
C24 C23 H23 120.6 . .
C22 C23 H23 120.6 . .
C23 C24 C25 122.7(6) . .
C23 C24 F1 118.7(7) . .
C25 C24 F1 118.7(7) . .
C24 C25 C26 118.3(6) . .
C24 C25 H25 120.8 . .
C26 C25 H25 120.8 . .
C21 C26 C25 120.7(6) . .
C21 C26 H26 119.7 . .
C25 C26 H26 119.7 . .
C28 C27 C32 118.4(5) . .
C28 C27 C16 121.1(5) . .
C32 C27 C16 120.5(5) . .
C29 C28 C27 121.0(6) . .
C29 C28 H28 119.5 . .
C27 C28 H28 119.5 . .
C30 C29 C28 118.4(7) . .
C30 C29 H29 120.8 . .
C28 C29 H29 120.8 . .
C31 C30 F2 118.2(6) . .
C31 C30 C29 123.2(6) . .
F2 C30 C29 118.6(6) . .
C30 C31 C32 118.2(6) . .
C30 C31 H31 120.9 . .
C32 C31 H31 120.9 . .
C27 C32 C31 120.8(6) . .
C27 C32 H32 119.6 . .
C31 C32 H32 119.6 . .
C2 C1 C3 106.8(7) . .
C2 C1 Os1 126.3(6) . .
C3 C1 Os1 126.7(5) . .
C1 C2 C4 109.1(8) . .
C1 C2 C5 108.9(9) . .
C4 C2 C5 109.5(8) . .
C1 C2 H2 109.8 . .
C4 C2 H2 109.8 . .
C5 C2 H2 109.8 . .
C1 C3 C6 109.0(8) . .
C1 C3 C7 109.2(8) . .
C6 C3 C7 109.9(9) . .
C1 C3 H3 109.6 . .
C6 C3 H3 109.6 . .
C7 C3 H3 109.6 . .
C8 C4 C2 110.5(8) . .
C8 C4 H4A 109.5 . .
C2 C4 H4A 109.5 . .
C8 C4 H4AB 109.5 . .
C2 C4 H4AB 109.5 . .
H4A C4 H4AB 108.1 . .
C9 C5 C2 110.7(9) . .
C9 C5 H5A 109.5 . .
C2 C5 H5A 109.5 . .
C9 C5 H5AB 109.5 . .
C2 C5 H5AB 109.5 . .
H5A C5 H5AB 108.1 . .
C8 C6 C3 110.7(9) . .
C8 C6 H6A 109.5 . .
C3 C6 H6A 109.5 . .
C8 C6 H6AB 109.5 . .
C3 C6 H6AB 109.5 . .
H6A C6 H6AB 108.1 . .
C9 C7 C3 109.9(9) . .
C9 C7 H7A 109.7 . .
C3 C7 H7A 109.7 . .
C9 C7 H7AB 109.7 . .
C3 C7 H7AB 109.7 . .
H7A C7 H7AB 108.2 . .
C4 C8 C6 106.9(9) . .
C4 C8 C10 113.2(9) . .
C6 C8 C10 107.1(10) . .
C4 C8 H8 109.9 . .
C6 C8 H8 109.9 . .
C10 C8 H8 109.9 . .
C5 C9 C7 104.6(10) . .
C5 C9 C10 113.9(10) . .
C7 C9 C10 109.2(10) . .
C5 C9 H9 109.7 . .
C7 C9 H9 109.7 . .
C10 C9 H9 109.7 . .
C8 C10 C9 110.8(9) . .
C8 C10 H10A 109.5 . .
C9 C10 H10A 109.5 . .
C8 C10 H10B 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 108.1 . .
C2B C1B C3B 114.8(9) . .
C2B C1B Os1 123.4(8) . .
C3B C1B Os1 121.7(8) . .
C1B C2B C5B 102.0(12) . .
C1B C2B C4B 102.4(12) . .
C5B C2B C4B 117.4(13) . .
C1B C2B H2B 111.4 . .
C5B C2B H2B 111.4 . .
C4B C2B H2B 111.4 . .
C1B C3B C7B 105.6(12) . .
C1B C3B C6B 102.8(12) . .
C7B C3B C6B 115.4(14) . .
C1B C3B H3B 110.8 . .
C7B C3B H3B 110.8 . .
C6B C3B H3B 110.8 . .
C8B C4B C2B 111.1(13) . .
C8B C4B H4BA 109.4 . .
C2B C4B H4BA 109.4 . .
C8B C4B H4BB 109.4 . .
C2B C4B H4BB 109.4 . .
H4BA C4B H4BB 108.0 . .
C9B C5B C2B 106.9(12) . .
C9B C5B H5BA 110.3 . .
C2B C5B H5BA 110.3 . .
C9B C5B H5BB 110.3 . .
C2B C5B H5BB 110.3 . .
H5BA C5B H5BB 108.6 . .
C8B C6B C3B 111.0(13) . .
C8B C6B H6BA 109.4 . .
C3B C6B H6BA 109.4 . .
C8B C6B H6BB 109.4 . .
C3B C6B H6BB 109.4 . .
H6BA C6B H6BB 108.0 . .
C9B C7B C3B 105.8(12) . .
C9B C7B H7BA 110.6 . .
C3B C7B H7BA 110.6 . .
C9B C7B H7BB 110.6 . .
C3B C7B H7BB 110.6 . .
H7BA C7B H7BB 108.7 . .
C6B C8B C4B 107.2(14) . .
C6B C8B C10B 110.3(13) . .
C4B C8B C10B 108.9(14) . .
C6B C8B H8B 110.1 . .
C4B C8B H8B 110.1 . .
C10B C8B H8B 110.1 . .
C5B C9B C7B 102.7(16) . .
C5B C9B C10B 115.7(15) . .
C7B C9B C10B 116.2(16) . .
C5B C9B H9B 107.2 . .
C7B C9B H9B 107.2 . .
C10B C9B H9B 107.2 . .
C8B C10B C9B 110.7(14) . .
C8B C10B H10C 109.5 . .
C9B C10B H10C 109.5 . .
C8B C10B H10D 109.5 . .
C9B C10B H10D 109.5 . .
H10C C10B H10D 108.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Os1 C1B 2.061(7) .
Os1 C1B 2.061(7) 2_676
Os1 C1 2.061(7) 2_676
Os1 C1 2.061(7) .
Os1 N2 2.062(4) .
Os1 N2 2.062(4) 2_676
Os1 N1 2.068(5) 2_676
Os1 N1 2.068(5) .
F1 C24 1.362(7) .
F2 C30 1.364(7) .
N1 C12 1.356(7) .
N1 C15 1.375(7) .
N2 C17 1.374(7) .
N2 C20 1.375(7) .
C11 C20 1.381(8) 2_676
C11 C12 1.391(7) .
C11 C21 1.507(7) .
C12 C13 1.459(8) .
C13 C14 1.344(8) .
C13 H13 0.9500 .
C14 C15 1.441(8) .
C14 H14 0.9500 .
C15 C16 1.397(8) .
C16 C17 1.390(8) .
C16 C27 1.507(7) .
C17 C18 1.445(8) .
C18 C19 1.331(8) .
C18 H18 0.9500 .
C19 C20 1.447(7) .
C19 H19 0.9500 .
C21 C26 1.366(8) .
C21 C22 1.373(9) .
C22 C23 1.388(10) .
C22 H22 0.9500 .
C23 C24 1.343(10) .
C23 H23 0.9500 .
C24 C25 1.352(10) .
C25 C26 1.395(9) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 C28 1.387(9) .
C27 C32 1.391(8) .
C28 C29 1.382(9) .
C28 H28 0.9500 .
C29 C30 1.366(10) .
C29 H29 0.9500 .
C30 C31 1.352(10) .
C31 C32 1.393(8) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C1 C2 1.510(7) .
C1 C3 1.510(7) .
C2 C4 1.569(6) .
C2 C5 1.569(6) .
C2 H2 1.0000 .
C3 C6 1.569(6) .
C3 C7 1.569(6) .
C3 H3 1.0000 .
C4 C8 1.481(7) .
C4 H4A 0.9900 .
C4 H4AB 0.9900 .
C5 C9 1.481(7) .
C5 H5A 0.9900 .
C5 H5AB 0.9900 .
C6 C8 1.481(7) .
C6 H6A 0.9900 .
C6 H6AB 0.9900 .
C7 C9 1.481(7) .
C7 H7A 0.9900 .
C7 H7AB 0.9900 .
C8 C10 1.527(8) .
C8 H8 1.0000 .
C9 C10 1.527(8) .
C9 H9 1.0000 .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C1B C2B 1.510(7) .
C1B C3B 1.510(7) .
C2B C5B 1.569(6) .
C2B C4B 1.569(6) .
C2B H2B 1.0000 .
C3B C7B 1.569(6) .
C3B C6B 1.569(6) .
C3B H3B 1.0000 .
C4B C8B 1.481(7) .
C4B H4BA 0.9900 .
C4B H4BB 0.9900 .
C5B C9B 1.481(7) .
C5B H5BA 0.9900 .
C5B H5BB 0.9900 .
C6B C8B 1.481(7) .
C6B H6BA 0.9900 .
C6B H6BB 0.9900 .
C7B C9B 1.481(7) .
C7B H7BA 0.9900 .
C7B H7BB 0.9900 .
C8B C10B 1.527(8) .
C8B H8B 1.0000 .
C9B C10B 1.527(8) .
C9B H9B 1.0000 .
C10B H10C 0.9900 .
C10B H10D 0.9900 .
