#------------------------------------------------------------------------------
#$Date: 2021-03-23 04:03:43 +0200 (Tue, 23 Mar 2021) $
#$Revision: 263223 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/11/1561177.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1561177
loop_
_publ_author_name
'Müller, Thomas'
'Dong, Zhaowen'
'Schmidtmann, Marc'
'Winkler, Jan Mathis'
_publ_section_title
;
 Three-membered cyclic digermylenes stabilized by an N-heterocyclic
 carbene
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/D1SC00956G
_journal_year                    2021
_chemical_formula_structural
'SiC4(C6H5)2(Si(C2H5)3)2Ge2(C11H20N2)2 *0.5C7H8'
_chemical_formula_sum            'C53.5 H84 Ge2 N4 Si3'
_chemical_formula_weight         1012.69
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-01-27 deposited with the CCDC.	2021-03-22 downloaded from the CCDC.
;
_cell_angle_alpha                92.7304(15)
_cell_angle_beta                 91.3450(16)
_cell_angle_gamma                111.8890(15)
_cell_formula_units_Z            2
_cell_length_a                   11.7931(5)
_cell_length_b                   14.4290(6)
_cell_length_c                   17.6548(6)
_cell_measurement_reflns_used    9831
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.48
_cell_measurement_theta_min      2.23
_cell_volume                     2781.69(19)
_computing_cell_refinement       'Bruker SAINT V8.37A'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT V8.37A'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2013/1 (Sheldrick, 2013)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0467
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            119718
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         32.031
_diffrn_reflns_theta_min         1.524
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    1.182
_exptl_absorpt_correction_T_max  0.9272
_exptl_absorpt_correction_T_min  0.7849
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS-2016/2 (Sheldrick)'
_exptl_crystal_colour            'metallic green red'
_exptl_crystal_density_diffrn    1.209
_exptl_crystal_description       plate
_exptl_crystal_F_000             1078
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.080
_refine_diff_density_max         1.543
_refine_diff_density_min         -0.769
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     602
_refine_ls_number_reflns         19379
_refine_ls_number_restraints     45
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0564
_refine_ls_R_factor_gt           0.0350
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0400P)²+1.2000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0793
_refine_ls_wR_factor_ref         0.0870
_reflns_Friedel_coverage         0.000
_reflns_number_gt                14851
_reflns_number_total             19379
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1sc00956g3.cif
_cod_data_source_block           dzw130
_cod_original_formula_sum        'C53.50 H84 Ge2 N4 Si3'
_cod_database_code               1561177
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.765
_shelx_estimated_absorpt_t_max   0.911
_exptl_absorpt_special_details
;
 numerical absorption correction followed by correction based on
 symmetry-related measurements (multi-scan)
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.09646(2) 0.14420(2) 0.21876(2) 0.01539(4) Uani 1 1 d . . . . .
Ge2 Ge 0.21793(2) 0.14757(2) 0.34267(2) 0.01461(4) Uani 1 1 d . . . . .
Si1 Si 0.28647(4) 0.28538(3) 0.25687(2) 0.01440(8) Uani 1 1 d . . . . .
Si2 Si 0.14604(4) 0.44967(3) 0.24990(3) 0.01701(8) Uani 1 1 d . . . . .
Si3 Si 0.54338(4) 0.24491(3) 0.24173(2) 0.01564(8) Uani 1 1 d . . . . .
N1 N 0.19895(12) 0.07521(10) 0.08040(7) 0.0187(3) Uani 1 1 d . . . . .
N2 N 0.14570(12) -0.04102(9) 0.16037(8) 0.0198(3) Uani 1 1 d . . . . .
N3 N -0.00831(11) 0.15053(9) 0.42624(7) 0.0167(2) Uani 1 1 d . . . . .
N4 N 0.16005(12) 0.26377(9) 0.47359(7) 0.0171(2) Uani 1 1 d . . . . .
C1 C 0.27963(13) 0.41059(11) 0.24158(8) 0.0155(3) Uani 1 1 d . . . . .
C2 C 0.39235(13) 0.46682(10) 0.21497(8) 0.0149(3) Uani 1 1 d . . . . .
C3 C 0.48411(13) 0.42016(11) 0.20967(8) 0.0150(3) Uani 1 1 d . . . . .
C4 C 0.44813(13) 0.32172(11) 0.22820(8) 0.0149(3) Uani 1 1 d . . . . .
C5 C 0.42452(14) 0.57117(11) 0.19081(9) 0.0178(3) Uani 1 1 d . . . . .
C6 C 0.37173(17) 0.58883(13) 0.12463(10) 0.0255(3) Uani 1 1 d . . . . .
H6 H 0.3168 0.5340 0.0938 0.031 Uiso 1 1 calc R U . . .
C7 C 0.3985(2) 0.68616(15) 0.10289(12) 0.0367(5) Uani 1 1 d . . . . .
H7 H 0.3618 0.6973 0.0575 0.044 Uiso 1 1 calc R U . . .
C8 C 0.4782(2) 0.76621(14) 0.14726(13) 0.0407(5) Uani 1 1 d . . . . .
H8 H 0.4957 0.8325 0.1327 0.049 Uiso 1 1 calc R U . . .
C9 C 0.5323(2) 0.75016(13) 0.21253(13) 0.0374(5) Uani 1 1 d . . . . .
H9 H 0.5876 0.8054 0.2429 0.045 Uiso 1 1 calc R U . . .
C10 C 0.50653(16) 0.65307(12) 0.23432(11) 0.0258(3) Uani 1 1 d . . . . .
H10 H 0.5451 0.6425 0.2792 0.031 Uiso 1 1 calc R U . . .
C11 C 0.60731(14) 0.47991(11) 0.18188(9) 0.0164(3) Uani 1 1 d . . . . .
C12 C 0.62242(16) 0.49572(13) 0.10498(10) 0.0261(3) Uani 1 1 d . . . . .
H12 H 0.5532 0.4714 0.0705 0.031 Uiso 1 1 calc R U . . .
C13 C 0.73764(18) 0.54674(14) 0.07797(11) 0.0335(4) Uani 1 1 d . . . . .
H13 H 0.7464 0.5569 0.0253 0.040 Uiso 1 1 calc R U . . .
C14 C 0.83921(16) 0.58269(13) 0.12694(11) 0.0299(4) Uani 1 1 d . . . . .
H14 H 0.9181 0.6154 0.1080 0.036 Uiso 1 1 calc R U . . .
C15 C 0.82570(15) 0.57086(13) 0.20376(11) 0.0267(4) Uani 1 1 d . . . . .
H15 H 0.8951 0.5973 0.2380 0.032 Uiso 1 1 calc R U . . .
C16 C 0.71025(14) 0.52009(12) 0.23105(10) 0.0216(3) Uani 1 1 d . . . . .
H16 H 0.7016 0.5128 0.2840 0.026 Uiso 1 1 calc R U . . .
C17 C 0.03686(15) 0.36326(12) 0.31488(10) 0.0221(3) Uani 1 1 d . . . . .
H17A H -0.0065 0.2983 0.2863 0.027 Uiso 1 1 calc R U . . .
H17B H 0.0853 0.3511 0.3571 0.027 Uiso 1 1 calc R U . . .
C18 C -0.05875(16) 0.39906(14) 0.34881(11) 0.0270(4) Uani 1 1 d . . . . .
H18A H -0.1030 0.4171 0.3080 0.040 Uiso 1 1 calc R U . . .
H18B H -0.0181 0.4577 0.3838 0.040 Uiso 1 1 calc R U . . .
H18C H -0.1165 0.3454 0.3765 0.040 Uiso 1 1 calc R U . . .
C19 C 0.18734(15) 0.58361(12) 0.28812(10) 0.0236(3) Uani 1 1 d . . . . .
H19A H 0.2397 0.6281 0.2512 0.028 Uiso 1 1 calc R U . . .
H19B H 0.1110 0.5971 0.2899 0.028 Uiso 1 1 calc R U . . .
C20 C 0.25281(18) 0.61352(14) 0.36619(12) 0.0329(4) Uani 1 1 d . . . . .
H20A H 0.3299 0.6025 0.3655 0.049 Uiso 1 1 calc R U . . .
H20B H 0.2008 0.5728 0.4042 0.049 Uiso 1 1 calc R U . . .
H20C H 0.2698 0.6844 0.3790 0.049 Uiso 1 1 calc R U . . .
C21 C 0.06202(16) 0.44372(13) 0.15639(10) 0.0253(3) Uani 1 1 d . . . . .
H21A H -0.0208 0.4419 0.1673 0.030 Uiso 1 1 calc R U . . .
H21B H 0.1051 0.5066 0.1314 0.030 Uiso 1 1 calc R U . . .
C22 C 0.04778(18) 0.35605(14) 0.09965(11) 0.0304(4) Uani 1 1 d . . . . .
H22A H 0.0053 0.3625 0.0530 0.046 Uiso 1 1 calc R U . . .
H22B H 0.0002 0.2930 0.1218 0.046 Uiso 1 1 calc R U . . .
H22C H 0.1288 0.3566 0.0878 0.046 Uiso 1 1 calc R U . . .
C23 C 0.45132(15) 0.11070(11) 0.20966(10) 0.0207(3) Uani 1 1 d . . . . .
H23A H 0.3766 0.0867 0.2392 0.025 Uiso 1 1 calc R U . . .
H23B H 0.4252 0.1079 0.1556 0.025 Uiso 1 1 calc R U . . .
C24 C 0.51964(18) 0.03957(13) 0.21831(13) 0.0343(4) Uani 1 1 d . . . . .
H24A H 0.5911 0.0601 0.1867 0.051 Uiso 1 1 calc R U . . .
H24B H 0.4650 -0.0288 0.2021 0.051 Uiso 1 1 calc R U . . .
H24C H 0.5464 0.0419 0.2716 0.051 Uiso 1 1 calc R U . . .
C25 C 0.57943(15) 0.24667(12) 0.34690(9) 0.0211(3) Uani 1 1 d . . . . .
H25A H 0.5074 0.1971 0.3694 0.025 Uiso 1 1 calc R U . . .
H25B H 0.6480 0.2234 0.3530 0.025 Uiso 1 1 calc R U . . .
C26 C 0.61321(16) 0.34618(13) 0.39340(10) 0.0247(3) Uani 1 1 d . . . . .
H26A H 0.5495 0.3734 0.3852 0.037 Uiso 1 1 calc R U . . .
H26B H 0.6915 0.3936 0.3774 0.037 Uiso 1 1 calc R U . . .
H26C H 0.6202 0.3353 0.4474 0.037 Uiso 1 1 calc R U . . .
C27 C 0.69016(15) 0.28104(12) 0.18979(10) 0.0226(3) Uani 1 1 d . . . . .
H27A H 0.7397 0.3523 0.2035 0.027 Uiso 1 1 calc R U . . .
H27B H 0.7368 0.2412 0.2079 0.027 Uiso 1 1 calc R U . . .
C28 C 0.67489(18) 0.26646(15) 0.10334(11) 0.0313(4) Uani 1 1 d . . . . .
H28A H 0.7556 0.2861 0.0815 0.047 Uiso 1 1 calc R U . . .
H28B H 0.6323 0.3080 0.0843 0.047 Uiso 1 1 calc R U . . .
H28C H 0.6270 0.1959 0.0887 0.047 Uiso 1 1 calc R U . . .
C29 C 0.15833(14) 0.05542(11) 0.15143(9) 0.0167(3) Uani 1 1 d . . . . .
C30 C 0.21268(15) -0.00854(13) 0.04522(10) 0.0246(3) Uani 1 1 d . . . . .
C31 C 0.17894(15) -0.08111(12) 0.09521(10) 0.0242(3) Uani 1 1 d . . . . .
C32 C 0.2550(2) -0.01395(17) -0.03379(12) 0.0430(5) Uani 1 1 d . . . . .
H32A H 0.2036 0.0050 -0.0695 0.064 Uiso 1 1 calc R U . . .
H32B H 0.2486 -0.0824 -0.0474 0.064 Uiso 1 1 calc R U . . .
H32C H 0.3402 0.0320 -0.0361 0.064 Uiso 1 1 calc R U . . .
C33 C 0.17349(19) -0.18621(14) 0.08471(13) 0.0367(5) Uani 1 1 d . . . . .
H33A H 0.2410 -0.1930 0.1143 0.055 Uiso 1 1 calc R U . . .
H33B H 0.1804 -0.2022 0.0309 0.055 Uiso 1 1 calc R U . . .
H33C H 0.0954 -0.2324 0.1021 0.055 Uiso 1 1 calc R U . . .
C34 C 0.21428(15) 0.17116(12) 0.04714(9) 0.0218(3) Uani 1 1 d . . . . .
H34 H 0.2012 0.2147 0.0891 0.026 Uiso 1 1 calc R U . . .
C35 C 0.34234(19) 0.22612(17) 0.02193(15) 0.0437(5) Uani 1 1 d . . . . .
H35A H 0.4013 0.2333 0.0640 0.066 Uiso 1 1 calc R U . . .
H35B H 0.3501 0.2925 0.0065 0.066 Uiso 1 1 calc R U . . .
H35C H 0.3587 0.1882 -0.0211 0.066 Uiso 1 1 calc R U . . .
C36 C 0.1146(2) 0.15636(18) -0.01258(15) 0.0525(7) Uani 1 1 d . . . . .
H36A H 0.1233 0.1142 -0.0555 0.079 Uiso 1 1 calc R U . . .
H36B H 0.1210 0.2215 -0.0301 0.079 Uiso 1 1 calc R U . . .
H36C H 0.0346 0.1238 0.0091 0.079 Uiso 1 1 calc R U . . .
C37 C 0.09570(19) -0.09177(12) 0.22997(10) 0.0286(4) Uani 1 1 d . . . . .
H37 H 0.1062 -0.0372 0.2698 0.034 Uiso 1 1 calc R U . . .
C38 C 0.1658(3) -0.15246(17) 0.26040(15) 0.0523(6) Uani 1 1 d . . . . .
H38A H 0.1422 -0.2161 0.2302 0.078 Uiso 1 1 calc R U . . .
H38B H 0.1466 -0.1656 0.3135 0.078 Uiso 1 1 calc R U . . .
H38C H 0.2538 -0.1149 0.2571 0.078 Uiso 1 1 calc R U . . .
C39 C -0.0409(2) -0.15014(14) 0.21970(12) 0.0363(4) Uani 1 1 d . . . . .
H39A H -0.0813 -0.1055 0.2039 0.054 Uiso 1 1 calc R U . . .
H39B H -0.0730 -0.1780 0.2678 0.054 Uiso 1 1 calc R U . . .
H39C H -0.0566 -0.2047 0.1808 0.054 Uiso 1 1 calc R U . . .
C40 C 0.11389(13) 0.19141(10) 0.41652(8) 0.0150(3) Uani 1 1 d . . . . .
C41 C -0.03940(15) 0.19926(12) 0.48773(9) 0.0206(3) Uani 1 1 d . . . . .
C42 C 0.06586(15) 0.27060(12) 0.51718(9) 0.0210(3) Uani 1 1 d . . . . .
C43 C -0.16685(17) 0.17566(16) 0.51265(11) 0.0337(4) Uani 1 1 d . . . . .
H43A H -0.2142 0.1938 0.4737 0.051 Uiso 1 1 calc R U . . .
H43B H -0.1646 0.2138 0.5605 0.051 Uiso 1 1 calc R U . . .
H43C H -0.2053 0.1039 0.5201 0.051 Uiso 1 1 calc R U . . .
C44 C 0.08255(19) 0.34455(15) 0.58302(11) 0.0348(4) Uani 1 1 d . . . . .
H44A H 0.1220 0.3263 0.6262 0.052 Uiso 1 1 calc R U . . .
H44B H 0.0026 0.3442 0.5973 0.052 Uiso 1 1 calc R U . . .
H44C H 0.1340 0.4116 0.5687 0.052 Uiso 1 1 calc R U . . .
C45 C -0.09027(14) 0.06198(11) 0.37924(9) 0.0193(3) Uani 1 1 d . . . . .
H45 H -0.0410 0.0522 0.3365 0.023 Uiso 1 1 calc R U . . .
C46 C -0.12629(17) -0.03261(13) 0.42293(11) 0.0276(4) Uani 1 1 d . . . . .
H46A H -0.0526 -0.0442 0.4385 0.041 Uiso 1 1 calc R U . . .
H46B H -0.1800 -0.0898 0.3904 0.041 Uiso 1 1 calc R U . . .
H46C H -0.1694 -0.0246 0.4681 0.041 Uiso 1 1 calc R U . . .
C47 C -0.19943(17) 0.07797(15) 0.34297(12) 0.0323(4) Uani 1 1 d . . . . .
H47A H -0.2603 0.0724 0.3811 0.048 Uiso 1 1 calc R U . . .
H47B H -0.2360 0.0271 0.3014 0.048 Uiso 1 1 calc R U . . .
H47C H -0.1723 0.1447 0.3230 0.048 Uiso 1 1 calc R U . . .
C48 C 0.29294(14) 0.32412(12) 0.48365(9) 0.0207(3) Uani 1 1 d . . . . .
H48 H 0.3349 0.2913 0.4492 0.025 Uiso 1 1 calc R U . . .
C49 C 0.34311(17) 0.32319(14) 0.56372(10) 0.0293(4) Uani 1 1 d . . . . .
H49A H 0.3180 0.3666 0.5982 0.044 Uiso 1 1 calc R U . . .
H49B H 0.4326 0.3477 0.5641 0.044 Uiso 1 1 calc R U . . .
H49C H 0.3110 0.2547 0.5804 0.044 Uiso 1 1 calc R U . . .
C50 C 0.32374(17) 0.42919(13) 0.45768(11) 0.0286(4) Uani 1 1 d . . . . .
H50A H 0.2923 0.4256 0.4053 0.043 Uiso 1 1 calc R U . . .
H50B H 0.4127 0.4648 0.4602 0.043 Uiso 1 1 calc R U . . .
H50C H 0.2861 0.4651 0.4908 0.043 Uiso 1 1 calc R U . . .
C51 C 0.4901(4) 0.0199(3) 0.4948(3) 0.102(2) Uani 0.5 1 d G U P A -1
C52 C 0.4403(3) -0.0081(3) 0.4212(2) 0.0671(16) Uani 0.5 1 d G U P A -1
H52 H 0.3996 0.0292 0.3975 0.081 Uiso 0.5 1 calc R U P A -1
C53 C 0.4501(4) -0.0908(3) 0.3825(2) 0.110(2) Uani 0.5 1 d G U P A -1
H53 H 0.4161 -0.1099 0.3322 0.132 Uiso 0.5 1 calc R U P A -1
C54 C 0.5098(4) -0.1454(3) 0.4173(3) 0.0773(19) Uani 0.5 1 d G U P A -1
H54 H 0.5165 -0.2019 0.3908 0.093 Uiso 0.5 1 calc R U P A -1
C55 C 0.5595(4) -0.1174(3) 0.4908(3) 0.0708(18) Uani 0.5 1 d G U P A -1
H55 H 0.6003 -0.1547 0.5146 0.085 Uiso 0.5 1 calc R U P A -1
C56 C 0.5497(3) -0.0348(3) 0.5296(2) 0.0507(13) Uani 0.5 1 d G U P A -1
H56 H 0.5838 -0.0156 0.5799 0.061 Uiso 0.5 1 calc R U P A -1
C57 C 0.4924(7) 0.1107(5) 0.5437(7) 0.111(3) Uani 0.5 1 d . U P A -1
H57A H 0.5455 0.1720 0.5215 0.166 Uiso 0.5 1 calc R U P A -1
H57B H 0.5239 0.1080 0.5951 0.166 Uiso 0.5 1 calc R U P A -1
H57C H 0.4093 0.1104 0.5460 0.166 Uiso 0.5 1 calc R U P A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C29 Ge1 Si1 102.10(4) . . ?
C29 Ge1 Ge2 98.83(4) . . ?
Si1 Ge1 Ge2 58.500(11) . . ?
C40 Ge2 Si1 103.06(4) . . ?
C40 Ge2 Ge1 98.30(4) . . ?
Si1 Ge2 Ge1 58.276(11) . . ?
C4 Si1 C1 94.54(6) . . ?
C4 Si1 Ge1 133.28(5) . . ?
C1 Si1 Ge1 113.83(5) . . ?
C4 Si1 Ge2 115.01(5) . . ?
C1 Si1 Ge2 141.71(5) . . ?
Ge1 Si1 Ge2 63.224(11) . . ?
C1 Si2 C17 107.52(7) . . ?
C1 Si2 C21 113.68(7) . . ?
C17 Si2 C21 108.56(8) . . ?
C1 Si2 C19 114.13(7) . . ?
C17 Si2 C19 109.12(7) . . ?
C21 Si2 C19 103.66(8) . . ?
C4 Si3 C23 109.37(7) . . ?
C4 Si3 C27 117.10(7) . . ?
C23 Si3 C27 106.01(7) . . ?
C4 Si3 C25 108.22(7) . . ?
C23 Si3 C25 106.63(7) . . ?
C27 Si3 C25 109.04(8) . . ?
C29 N1 C30 110.29(13) . . ?
C29 N1 C34 121.65(13) . . ?
C30 N1 C34 127.87(14) . . ?
C29 N2 C31 110.35(14) . . ?
C29 N2 C37 121.34(13) . . ?
C31 N2 C37 128.21(14) . . ?
C40 N3 C41 110.41(13) . . ?
C40 N3 C45 122.09(12) . . ?
C41 N3 C45 127.38(13) . . ?
C40 N4 C42 110.30(13) . . ?
C40 N4 C48 121.82(12) . . ?
C42 N4 C48 127.87(13) . . ?
C2 C1 Si2 126.21(11) . . ?
C2 C1 Si1 105.10(10) . . ?
Si2 C1 Si1 128.40(8) . . ?
C1 C2 C3 117.67(13) . . ?
C1 C2 C5 123.28(13) . . ?
C3 C2 C5 119.05(12) . . ?
C4 C3 C2 117.12(13) . . ?
C4 C3 C11 124.15(13) . . ?
C2 C3 C11 118.69(12) . . ?
C3 C4 Si3 128.99(11) . . ?
C3 C4 Si1 105.49(10) . . ?
Si3 C4 Si1 124.52(8) . . ?
C6 C5 C10 118.38(15) . . ?
C6 C5 C2 120.43(14) . . ?
C10 C5 C2 121.18(15) . . ?
C5 C6 C7 120.78(18) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
C8 C7 C6 120.00(19) . . ?
C8 C7 H7 120.0 . . ?
C6 C7 H7 120.0 . . ?
C9 C8 C7 120.06(17) . . ?
C9 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C8 C9 C10 120.21(19) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 H9 119.9 . . ?
C9 C10 C5 120.55(18) . . ?
C9 C10 H10 119.7 . . ?
C5 C10 H10 119.7 . . ?
C12 C11 C16 117.94(14) . . ?
C12 C11 C3 120.31(14) . . ?
C16 C11 C3 121.74(14) . . ?
C13 C12 C11 120.80(17) . . ?
C13 C12 H12 119.6 . . ?
C11 C12 H12 119.6 . . ?
C14 C13 C12 120.53(17) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C13 C14 C15 119.59(16) . . ?
C13 C14 H14 120.2 . . ?
C15 C14 H14 120.2 . . ?
C14 C15 C16 119.98(17) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C11 C16 C15 121.07(16) . . ?
C11 C16 H16 119.5 . . ?
C15 C16 H16 119.5 . . ?
C18 C17 Si2 116.34(12) . . ?
C18 C17 H17A 108.2 . . ?
Si2 C17 H17A 108.2 . . ?
C18 C17 H17B 108.2 . . ?
Si2 C17 H17B 108.2 . . ?
H17A C17 H17B 107.4 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 Si2 117.57(12) . . ?
C20 C19 H19A 107.9 . . ?
Si2 C19 H19A 107.9 . . ?
C20 C19 H19B 107.9 . . ?
Si2 C19 H19B 107.9 . . ?
H19A C19 H19B 107.2 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 Si2 117.25(12) . . ?
C22 C21 H21A 108.0 . . ?
Si2 C21 H21A 108.0 . . ?
C22 C21 H21B 108.0 . . ?
Si2 C21 H21B 108.0 . . ?
H21A C21 H21B 107.2 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 Si3 114.41(12) . . ?
C24 C23 H23A 108.7 . . ?
Si3 C23 H23A 108.7 . . ?
C24 C23 H23B 108.7 . . ?
Si3 C23 H23B 108.7 . . ?
H23A C23 H23B 107.6 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 Si3 117.70(12) . . ?
C26 C25 H25A 107.9 . . ?
Si3 C25 H25A 107.9 . . ?
C26 C25 H25B 107.9 . . ?
Si3 C25 H25B 107.9 . . ?
H25A C25 H25B 107.2 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C28 C27 Si3 115.40(12) . . ?
C28 C27 H27A 108.4 . . ?
Si3 C27 H27A 108.4 . . ?
C28 C27 H27B 108.4 . . ?
Si3 C27 H27B 108.4 . . ?
H27A C27 H27B 107.5 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N1 C29 N2 105.50(13) . . ?
N1 C29 Ge1 125.20(11) . . ?
N2 C29 Ge1 128.14(11) . . ?
C31 C30 N1 106.85(14) . . ?
C31 C30 C32 128.20(16) . . ?
N1 C30 C32 124.94(17) . . ?
C30 C31 N2 107.00(14) . . ?
C30 C31 C33 128.32(17) . . ?
N2 C31 C33 124.66(17) . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N1 C34 C36 110.57(15) . . ?
N1 C34 C35 113.01(15) . . ?
C36 C34 C35 114.60(18) . . ?
N1 C34 H34 106.0 . . ?
C36 C34 H34 106.0 . . ?
C35 C34 H34 106.0 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N2 C37 C39 111.05(15) . . ?
N2 C37 C38 113.64(18) . . ?
C39 C37 C38 113.56(17) . . ?
N2 C37 H37 105.9 . . ?
C39 C37 H37 105.9 . . ?
C38 C37 H37 105.9 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
N3 C40 N4 105.55(12) . . ?
N3 C40 Ge2 129.61(11) . . ?
N4 C40 Ge2 124.42(11) . . ?
C42 C41 N3 106.93(13) . . ?
C42 C41 C43 128.51(15) . . ?
N3 C41 C43 124.54(15) . . ?
C41 C42 N4 106.76(13) . . ?
C41 C42 C44 128.30(15) . . ?
N4 C42 C44 124.94(15) . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C42 C44 H44A 109.5 . . ?
C42 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C42 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N3 C45 C47 113.00(14) . . ?
N3 C45 C46 111.36(13) . . ?
C47 C45 C46 113.20(14) . . ?
N3 C45 H45 106.2 . . ?
C47 C45 H45 106.2 . . ?
C46 C45 H45 106.2 . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
N4 C48 C50 111.52(14) . . ?
N4 C48 C49 112.64(13) . . ?
C50 C48 C49 112.77(14) . . ?
N4 C48 H48 106.5 . . ?
C50 C48 H48 106.5 . . ?
C49 C48 H48 106.5 . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C48 C50 H50A 109.5 . . ?
C48 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C48 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C52 C51 C56 120.0 . . ?
C52 C51 C57 126.6(5) . . ?
C56 C51 C57 113.3(5) . . ?
C51 C52 C53 120.0 . . ?
C51 C52 H52 120.0 . . ?
C53 C52 H52 120.0 . . ?
C52 C53 C54 120.0 . . ?
C52 C53 H53 120.0 . . ?
C54 C53 H53 120.0 . . ?
C55 C54 C53 120.0 . . ?
C55 C54 H54 120.0 . . ?
C53 C54 H54 120.0 . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C55 C56 C51 120.0 . . ?
C55 C56 H56 120.0 . . ?
C51 C56 H56 120.0 . . ?
C51 C57 H57A 109.5 . . ?
C51 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C51 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C29 2.0443(15) . ?
Ge1 Si1 2.4533(4) . ?
Ge1 Ge2 2.5750(2) . ?
Ge2 C40 2.0447(14) . ?
Ge2 Si1 2.4592(4) . ?
Si1 C4 1.8684(15) . ?
Si1 C1 1.8701(15) . ?
Si2 C1 1.8674(15) . ?
Si2 C17 1.8807(16) . ?
Si2 C21 1.8870(18) . ?
Si2 C19 1.8936(16) . ?
Si3 C4 1.8675(15) . ?
Si3 C23 1.8838(16) . ?
Si3 C27 1.8858(16) . ?
Si3 C25 1.8919(17) . ?
N1 C29 1.358(2) . ?
N1 C30 1.397(2) . ?
N1 C34 1.480(2) . ?
N2 C29 1.3605(19) . ?
N2 C31 1.392(2) . ?
N2 C37 1.481(2) . ?
N3 C40 1.3570(19) . ?
N3 C41 1.3948(19) . ?
N3 C45 1.482(2) . ?
N4 C40 1.3608(18) . ?
N4 C42 1.3964(19) . ?
N4 C48 1.483(2) . ?
C1 C2 1.381(2) . ?
C2 C3 1.475(2) . ?
C2 C5 1.495(2) . ?
C3 C4 1.381(2) . ?
C3 C11 1.495(2) . ?
C5 C6 1.389(2) . ?
C5 C10 1.396(2) . ?
C6 C7 1.395(2) . ?
C6 H6 0.9500 . ?
C7 C8 1.379(3) . ?
C7 H7 0.9500 . ?
C8 C9 1.375(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.394(2) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 C12 1.392(2) . ?
C11 C16 1.393(2) . ?
C12 C13 1.391(2) . ?
C12 H12 0.9500 . ?
C13 C14 1.377(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.381(3) . ?
C14 H14 0.9500 . ?
C15 C16 1.394(2) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 C18 1.528(2) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.525(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.531(2) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C24 1.533(2) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.530(2) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.528(3) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C30 C31 1.352(3) . ?
C30 C32 1.501(3) . ?
C31 C33 1.496(2) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 C36 1.508(3) . ?
C34 C35 1.510(2) . ?
C34 H34 1.0000 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C39 1.515(3) . ?
C37 C38 1.517(3) . ?
C37 H37 1.0000 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C41 C42 1.355(2) . ?
C41 C43 1.494(2) . ?
C42 C44 1.498(2) . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C47 1.522(2) . ?
C45 C46 1.524(2) . ?
C45 H45 1.0000 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 C50 1.518(2) . ?
C48 C49 1.522(2) . ?
C48 H48 1.0000 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 C52 1.3900 . ?
C51 C56 1.3900 . ?
C51 C57 1.526(9) . ?
C52 C53 1.3900 . ?
C52 H52 0.9500 . ?
C53 C54 1.3900 . ?
C53 H53 0.9500 . ?
C54 C55 1.3900 . ?
C54 H54 0.9500 . ?
C55 C56 1.3900 . ?
C55 H55 0.9500 . ?
C56 H56 0.9500 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 Si2 C1 C2 -163.39(13) . . . . ?
C21 Si2 C1 C2 76.42(15) . . . . ?
C19 Si2 C1 C2 -42.20(16) . . . . ?
C17 Si2 C1 Si1 23.70(13) . . . . ?
C21 Si2 C1 Si1 -96.49(12) . . . . ?
C19 Si2 C1 Si1 144.89(10) . . . . ?
C4 Si1 C1 C2 1.83(11) . . . . ?
Ge1 Si1 C1 C2 -140.07(9) . . . . ?
Ge2 Si1 C1 C2 143.54(8) . . . . ?
C4 Si1 C1 Si2 175.91(10) . . . . ?
Ge1 Si1 C1 Si2 34.02(12) . . . . ?
Ge2 Si1 C1 Si2 -42.37(15) . . . . ?
Si2 C1 C2 C3 -177.25(11) . . . . ?
Si1 C1 C2 C3 -2.99(16) . . . . ?
Si2 C1 C2 C5 2.1(2) . . . . ?
Si1 C1 C2 C5 176.33(12) . . . . ?
C1 C2 C3 C4 3.2(2) . . . . ?
C5 C2 C3 C4 -176.19(14) . . . . ?
C1 C2 C3 C11 -179.30(13) . . . . ?
C5 C2 C3 C11 1.3(2) . . . . ?
C2 C3 C4 Si3 -170.20(11) . . . . ?
C11 C3 C4 Si3 12.4(2) . . . . ?
C2 C3 C4 Si1 -1.38(16) . . . . ?
C11 C3 C4 Si1 -178.77(12) . . . . ?
C23 Si3 C4 C3 -146.86(14) . . . . ?
C27 Si3 C4 C3 -26.30(17) . . . . ?
C25 Si3 C4 C3 97.36(15) . . . . ?
C23 Si3 C4 Si1 46.25(11) . . . . ?
C27 Si3 C4 Si1 166.81(9) . . . . ?
C25 Si3 C4 Si1 -69.54(11) . . . . ?
C1 Si1 C4 C3 -0.27(11) . . . . ?
Ge1 Si1 C4 C3 128.89(9) . . . . ?
Ge2 Si1 C4 C3 -155.21(9) . . . . ?
C1 Si1 C4 Si3 169.19(9) . . . . ?
Ge1 Si1 C4 Si3 -61.65(12) . . . . ?
Ge2 Si1 C4 Si3 14.25(11) . . . . ?
C1 C2 C5 C6 -70.5(2) . . . . ?
C3 C2 C5 C6 108.85(17) . . . . ?
C1 C2 C5 C10 108.65(18) . . . . ?
C3 C2 C5 C10 -72.03(19) . . . . ?
C10 C5 C6 C7 -1.1(2) . . . . ?
C2 C5 C6 C7 178.09(15) . . . . ?
C5 C6 C7 C8 0.0(3) . . . . ?
C6 C7 C8 C9 0.7(3) . . . . ?
C7 C8 C9 C10 -0.3(3) . . . . ?
C8 C9 C10 C5 -0.7(3) . . . . ?
C6 C5 C10 C9 1.4(2) . . . . ?
C2 C5 C10 C9 -177.71(15) . . . . ?
C4 C3 C11 C12 101.73(19) . . . . ?
C2 C3 C11 C12 -75.62(19) . . . . ?
C4 C3 C11 C16 -77.3(2) . . . . ?
C2 C3 C11 C16 105.32(17) . . . . ?
C16 C11 C12 C13 2.4(2) . . . . ?
C3 C11 C12 C13 -176.66(16) . . . . ?
C11 C12 C13 C14 0.0(3) . . . . ?
C12 C13 C14 C15 -2.2(3) . . . . ?
C13 C14 C15 C16 2.0(3) . . . . ?
C12 C11 C16 C15 -2.7(2) . . . . ?
C3 C11 C16 C15 176.38(14) . . . . ?
C14 C15 C16 C11 0.5(3) . . . . ?
C1 Si2 C17 C18 162.22(13) . . . . ?
C21 Si2 C17 C18 -74.39(15) . . . . ?
C19 Si2 C17 C18 37.94(16) . . . . ?
C1 Si2 C19 C20 -58.32(15) . . . . ?
C17 Si2 C19 C20 61.97(15) . . . . ?
C21 Si2 C19 C20 177.50(13) . . . . ?
C1 Si2 C21 C22 38.18(16) . . . . ?
C17 Si2 C21 C22 -81.42(15) . . . . ?
C19 Si2 C21 C22 162.66(13) . . . . ?
C4 Si3 C23 C24 -179.72(13) . . . . ?
C27 Si3 C23 C24 53.17(15) . . . . ?
C25 Si3 C23 C24 -62.93(15) . . . . ?
C4 Si3 C25 C26 -41.62(14) . . . . ?
C23 Si3 C25 C26 -159.18(12) . . . . ?
C27 Si3 C25 C26 86.77(13) . . . . ?
C4 Si3 C27 C28 -66.51(14) . . . . ?
C23 Si3 C27 C28 55.80(14) . . . . ?
C25 Si3 C27 C28 170.25(12) . . . . ?
C30 N1 C29 N2 -0.50(17) . . . . ?
C34 N1 C29 N2 174.95(13) . . . . ?
C30 N1 C29 Ge1 -168.99(11) . . . . ?
C34 N1 C29 Ge1 6.5(2) . . . . ?
C31 N2 C29 N1 0.30(17) . . . . ?
C37 N2 C29 N1 -176.36(14) . . . . ?
C31 N2 C29 Ge1 168.33(12) . . . . ?
C37 N2 C29 Ge1 -8.3(2) . . . . ?
C29 N1 C30 C31 0.53(19) . . . . ?
C34 N1 C30 C31 -174.57(15) . . . . ?
C29 N1 C30 C32 179.50(18) . . . . ?
C34 N1 C30 C32 4.4(3) . . . . ?
N1 C30 C31 N2 -0.33(19) . . . . ?
C32 C30 C31 N2 -179.25(19) . . . . ?
N1 C30 C31 C33 178.17(17) . . . . ?
C32 C30 C31 C33 -0.8(3) . . . . ?
C29 N2 C31 C30 0.03(19) . . . . ?
C37 N2 C31 C30 176.39(16) . . . . ?
C29 N2 C31 C33 -178.54(16) . . . . ?
C37 N2 C31 C33 -2.2(3) . . . . ?
C29 N1 C34 C36 -106.5(2) . . . . ?
C30 N1 C34 C36 68.1(2) . . . . ?
C29 N1 C34 C35 123.55(18) . . . . ?
C30 N1 C34 C35 -61.8(2) . . . . ?
C29 N2 C37 C39 94.04(18) . . . . ?
C31 N2 C37 C39 -82.0(2) . . . . ?
C29 N2 C37 C38 -136.47(17) . . . . ?
C31 N2 C37 C38 47.5(2) . . . . ?
C41 N3 C40 N4 1.95(17) . . . . ?
C45 N3 C40 N4 -174.18(13) . . . . ?
C41 N3 C40 Ge2 174.67(11) . . . . ?
C45 N3 C40 Ge2 -1.5(2) . . . . ?
C42 N4 C40 N3 -2.29(17) . . . . ?
C48 N4 C40 N3 178.19(13) . . . . ?
C42 N4 C40 Ge2 -175.50(11) . . . . ?
C48 N4 C40 Ge2 5.0(2) . . . . ?
C40 N3 C41 C42 -0.88(18) . . . . ?
C45 N3 C41 C42 174.98(14) . . . . ?
C40 N3 C41 C43 177.77(16) . . . . ?
C45 N3 C41 C43 -6.4(3) . . . . ?
N3 C41 C42 N4 -0.54(18) . . . . ?
C43 C41 C42 N4 -179.13(17) . . . . ?
N3 C41 C42 C44 179.00(17) . . . . ?
C43 C41 C42 C44 0.4(3) . . . . ?
C40 N4 C42 C41 1.80(18) . . . . ?
C48 N4 C42 C41 -178.72(15) . . . . ?
C40 N4 C42 C44 -177.76(17) . . . . ?
C48 N4 C42 C44 1.7(3) . . . . ?
C40 N3 C45 C47 -127.69(16) . . . . ?
C41 N3 C45 C47 56.9(2) . . . . ?
C40 N3 C45 C46 103.60(17) . . . . ?
C41 N3 C45 C46 -71.8(2) . . . . ?
C40 N4 C48 C50 104.81(17) . . . . ?
C42 N4 C48 C50 -74.6(2) . . . . ?
C40 N4 C48 C49 -127.22(16) . . . . ?
C42 N4 C48 C49 53.4(2) . . . . ?
C56 C51 C52 C53 0.0 . . . . ?
C57 C51 C52 C53 177.1(5) . . . . ?
C51 C52 C53 C54 0.0 . . . . ?
C52 C53 C54 C55 0.0 . . . . ?
C53 C54 C55 C56 0.0 . . . . ?
C54 C55 C56 C51 0.0 . . . . ?
C52 C51 C56 C55 0.0 . . . . ?
C57 C51 C56 C55 -177.4(5) . . . . ?
