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#$Date: 2021-04-02 11:55:27 +0300 (Fri, 02 Apr 2021) $
#$Revision: 263546 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/14/1561457.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1561457
loop_
_publ_author_name
'Cheng, Yue'
'Yang, Meng-Lin'
'Hu, Huai-Ming'
'Xu, Bing'
'Wang, Xiaofang'
'Xue, Ganglin'
_publ_section_title
;
 Syntheses, structures and luminescence for zinc coordination polymers
 based on a multifunctional 4′-(3-carboxyphenyl)-
 3,2′:6′,3″-terpyridine ligand
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              121
_journal_page_last               130
_journal_paper_doi               10.1016/j.jssc.2016.04.002
_journal_volume                  239
_journal_year                    2016
_chemical_formula_sum            'C31 H19 N3 O9 Zn2'
_chemical_formula_weight         708.23
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.361(4)
_cell_angle_beta                 92.044(4)
_cell_angle_gamma                111.717(5)
_cell_formula_units_Z            2
_cell_length_a                   10.207(2)
_cell_length_b                   11.967(3)
_cell_length_c                   12.771(3)
_cell_measurement_reflns_used    797
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      20.62
_cell_measurement_theta_min      2.65
_cell_volume                     1373.3(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0420
_diffrn_reflns_av_sigmaI/netI    0.1043
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6909
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.68
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.812
_exptl_absorpt_correction_T_max  0.834
_exptl_absorpt_correction_T_min  0.756
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.713
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             716
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.625
_refine_diff_density_min         -0.672
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.972
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     414
_refine_ls_number_reflns         4796
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      0.972
_refine_ls_R_factor_all          0.1140
_refine_ls_R_factor_gt           0.0624
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+-0.3352P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1564
_refine_ls_wR_factor_ref         0.1886
_reflns_number_gt                2895
_reflns_number_total             4796
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2016-239-121.cif
_cod_data_source_block           nw1739_0m
_cod_original_cell_volume        1373.3(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1561457
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn -0.10796(9) -0.10522(8) 0.29683(7) 0.0349(3) Uani 1 1 d . . .
Zn2 Zn -0.33519(9) 0.23108(9) 0.61810(7) 0.0366(3) Uani 1 1 d . . .
N1 N 0.0642(6) 0.0339(5) 0.2703(5) 0.0319(14) Uani 1 1 d . . .
N2 N 0.0031(6) 0.2055(6) 0.0500(5) 0.0332(15) Uani 1 1 d . . .
N3 N -0.3220(6) 0.1696(6) -0.2505(5) 0.0349(15) Uani 1 1 d . . .
O1 O 0.7253(6) 0.7689(5) 0.1919(4) 0.0501(15) Uani 1 1 d . . .
O2 O 0.7319(6) 0.9236(6) 0.1279(5) 0.0648(18) Uani 1 1 d . . .
O3 O -0.2095(6) -0.0197(5) 0.4015(4) 0.0496(15) Uani 1 1 d . . .
O4 O -0.3127(6) 0.0941(6) 0.5037(4) 0.0511(16) Uani 1 1 d . . .
O5 O 0.0076(6) 0.1609(5) 0.6066(4) 0.0476(15) Uani 1 1 d . . .
O6 O 0.2150(9) 0.3063(9) 0.6088(8) 0.155(5) Uani 1 1 d . . .
O7 O 0.2589(8) 0.6060(6) 0.4043(6) 0.073(2) Uani 1 1 d . . .
O8 O 0.0779(9) 0.5750(7) 0.2860(7) 0.094(3) Uani 1 1 d . . .
C1 C 0.1903(8) 0.0765(7) 0.3363(6) 0.0381(19) Uani 1 1 d . . .
H1 H 0.2020 0.0323 0.3829 0.046 Uiso 1 1 calc R . .
C2 C 0.3026(8) 0.1856(7) 0.3352(6) 0.0385(19) Uani 1 1 d . . .
H2 H 0.3880 0.2163 0.3829 0.046 Uiso 1 1 calc R . .
C3 C 0.2874(7) 0.2483(8) 0.2633(6) 0.040(2) Uani 1 1 d . . .
H3 H 0.3629 0.3212 0.2623 0.048 Uiso 1 1 calc R . .
C4 C 0.1609(7) 0.2039(7) 0.1927(5) 0.0316(17) Uani 1 1 d . . .
C5 C 0.0517(8) 0.0931(7) 0.1988(6) 0.0339(18) Uani 1 1 d . . .
H5 H -0.0337 0.0594 0.1504 0.041 Uiso 1 1 calc R . .
C6 C 0.1335(7) 0.2661(6) 0.1126(5) 0.0271(16) Uani 1 1 d . . .
C7 C 0.2370(8) 0.3736(7) 0.1012(6) 0.0343(18) Uani 1 1 d . . .
H7 H 0.3264 0.4111 0.1448 0.041 Uiso 1 1 calc R . .
C8 C 0.2061(7) 0.4248(7) 0.0240(6) 0.0320(17) Uani 1 1 d . . .
C9 C 0.0705(7) 0.3712(7) -0.0326(6) 0.0352(18) Uani 1 1 d . . .
H9 H 0.0432 0.4096 -0.0784 0.042 Uiso 1 1 calc R . .
C10 C -0.0269(7) 0.2594(7) -0.0219(6) 0.0313(17) Uani 1 1 d . . .
C11 C -0.1971(7) 0.2220(7) -0.1840(6) 0.039(2) Uani 1 1 d . . .
H11 H -0.1222 0.2840 -0.2011 0.046 Uiso 1 1 calc R . .
C12 C -0.1705(7) 0.1907(6) -0.0911(5) 0.0289(16) Uani 1 1 d . . .
C13 C -0.2803(7) 0.0930(8) -0.0702(6) 0.044(2) Uani 1 1 d . . .
H13 H -0.2680 0.0665 -0.0101 0.052 Uiso 1 1 calc R . .
C14 C -0.4095(8) 0.0358(8) -0.1419(6) 0.046(2) Uani 1 1 d . . .
H14 H -0.4847 -0.0296 -0.1291 0.056 Uiso 1 1 calc R . .
C15 C -0.4278(8) 0.0736(7) -0.2302(6) 0.0361(19) Uani 1 1 d . . .
H15 H -0.5147 0.0327 -0.2775 0.043 Uiso 1 1 calc R . .
C16 C 0.3161(7) 0.5366(6) 0.0011(5) 0.0294(17) Uani 1 1 d . . .
C17 C 0.2960(8) 0.5594(8) -0.0977(6) 0.045(2) Uani 1 1 d . . .
H17 H 0.2144 0.5046 -0.1488 0.054 Uiso 1 1 calc R . .
C18 C 0.3930(8) 0.6609(9) -0.1229(7) 0.055(2) Uani 1 1 d . . .
H18 H 0.3772 0.6731 -0.1903 0.066 Uiso 1 1 calc R . .
C19 C 0.5133(8) 0.7437(8) -0.0473(6) 0.044(2) Uani 1 1 d . . .
H19 H 0.5767 0.8144 -0.0622 0.052 Uiso 1 1 calc R . .
C20 C 0.5403(7) 0.7226(6) 0.0503(6) 0.0302(17) Uani 1 1 d . . .
C21 C 0.4419(8) 0.6178(7) 0.0725(6) 0.0352(18) Uani 1 1 d . . .
H21 H 0.4614 0.6020 0.1374 0.042 Uiso 1 1 calc R . .
C22 C 0.6767(8) 0.8156(9) 0.1290(7) 0.043(2) Uani 1 1 d . . .
C23 C -0.2131(8) 0.0858(7) 0.4478(6) 0.037(2) Uani 1 1 d . . .
C24 C -0.1137(7) 0.2031(7) 0.4255(5) 0.0328(18) Uani 1 1 d . . .
C25 C -0.1645(8) 0.2391(8) 0.3422(7) 0.047(2) Uani 1 1 d . . .
H25 H -0.2564 0.1895 0.3037 0.057 Uiso 1 1 calc R . .
C26 C -0.0841(9) 0.3441(8) 0.3152(6) 0.047(2) Uani 1 1 d . . .
H26 H -0.1193 0.3636 0.2576 0.056 Uiso 1 1 calc R . .
C27 C 0.0506(8) 0.4210(8) 0.3754(7) 0.042(2) Uani 1 1 d . . .
C28 C 0.1025(8) 0.3867(7) 0.4586(6) 0.0360(18) Uani 1 1 d . . .
H28 H 0.1937 0.4375 0.4980 0.043 Uiso 1 1 calc R . .
C29 C 0.0216(8) 0.2788(6) 0.4840(6) 0.0310(17) Uani 1 1 d . . .
C30 C 0.1345(12) 0.5408(10) 0.3517(9) 0.062(3) Uani 1 1 d . . .
C31 C 0.0860(9) 0.2482(8) 0.5737(6) 0.050(2) Uani 1 1 d . . .
O9 O -0.5381(7) 0.2019(7) 0.5860(6) 0.0600(18) Uani 1 1 d D . .
H9A H -0.535(7) 0.273(3) 0.614(5) 0.02(2) Uiso 1 1 d D . .
H9B H -0.617(4) 0.144(4) 0.573(10) 0.13(5) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 O5 118.8(2) 1_445 2_556
O1 Zn1 O3 97.6(2) 1_445 .
O5 Zn1 O3 102.3(2) 2_556 .
O1 Zn1 N1 128.6(2) 1_445 .
O5 Zn1 N1 99.0(2) 2_556 .
O3 Zn1 N1 107.4(2) . .
O7 Zn2 O4 114.8(3) 2_566 .
O7 Zn2 O9 96.0(3) 2_566 .
O4 Zn2 O9 104.5(3) . .
O7 Zn2 N3 134.1(3) 2_566 1_556
O4 Zn2 N3 98.8(2) . 1_556
O9 Zn2 N3 105.2(3) . 1_556
C5 N1 C1 119.2(6) . .
C5 N1 Zn1 121.8(5) . .
C1 N1 Zn1 118.6(5) . .
C10 N2 C6 116.6(6) . .
C11 N3 C15 117.7(6) . .
C11 N3 Zn2 117.5(5) . 1_554
C15 N3 Zn2 124.6(5) . 1_554
C22 O1 Zn1 112.5(5) . 1_665
C23 O3 Zn1 142.8(6) . .
C23 O4 Zn2 134.4(5) . .
C31 O5 Zn1 115.3(5) . 2_556
C30 O7 Zn2 111.0(7) . 2_566
N1 C1 C2 120.5(7) . .
N1 C1 H1 119.8 . .
C2 C1 H1 119.8 . .
C3 C2 C1 119.9(7) . .
C3 C2 H2 120.1 . .
C1 C2 H2 120.1 . .
C2 C3 C4 120.5(7) . .
C2 C3 H3 119.8 . .
C4 C3 H3 119.8 . .
C3 C4 C5 116.5(7) . .
C3 C4 C6 124.5(6) . .
C5 C4 C6 119.1(6) . .
N1 C5 C4 123.4(6) . .
N1 C5 H5 118.3 . .
C4 C5 H5 118.3 . .
N2 C6 C7 123.3(6) . .
N2 C6 C4 114.7(6) . .
C7 C6 C4 121.9(6) . .
C6 C7 C8 119.2(6) . .
C6 C7 H7 120.4 . .
C8 C7 H7 120.4 . .
C9 C8 C7 118.0(7) . .
C9 C8 C16 119.6(6) . .
C7 C8 C16 122.4(6) . .
C8 C9 C10 120.0(6) . .
C8 C9 H9 120.0 . .
C10 C9 H9 120.0 . .
N2 C10 C9 122.4(6) . .
N2 C10 C12 116.0(6) . .
C9 C10 C12 121.6(6) . .
N3 C11 C12 124.6(7) . .
N3 C11 H11 117.7 . .
C12 C11 H11 117.7 . .
C13 C12 C11 117.1(6) . .
C13 C12 C10 123.6(6) . .
C11 C12 C10 119.2(6) . .
C12 C13 C14 118.0(7) . .
C12 C13 H13 121.0 . .
C14 C13 H13 121.0 . .
C15 C14 C13 121.3(7) . .
C15 C14 H14 119.4 . .
C13 C14 H14 119.4 . .
N3 C15 C14 121.1(7) . .
N3 C15 H15 119.4 . .
C14 C15 H15 119.4 . .
C21 C16 C17 116.8(7) . .
C21 C16 C8 123.4(6) . .
C17 C16 C8 119.8(6) . .
C18 C17 C16 122.3(7) . .
C18 C17 H17 118.8 . .
C16 C17 H17 118.8 . .
C19 C18 C17 119.3(7) . .
C19 C18 H18 120.3 . .
C17 C18 H18 120.3 . .
C20 C19 C18 120.4(7) . .
C20 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
C19 C20 C21 118.9(6) . .
C19 C20 C22 117.9(7) . .
C21 C20 C22 123.2(6) . .
C16 C21 C20 122.1(6) . .
C16 C21 H21 119.0 . .
C20 C21 H21 119.0 . .
O2 C22 O1 125.0(7) . .
O2 C22 C20 120.5(7) . .
O1 C22 C20 114.6(7) . .
O3 C23 O4 120.5(7) . .
O3 C23 C24 120.6(8) . .
O4 C23 C24 118.3(7) . .
C29 C24 C25 118.4(7) . .
C29 C24 C23 124.1(6) . .
C25 C24 C23 117.5(6) . .
C26 C25 C24 122.6(7) . .
C26 C25 H25 118.7 . .
C24 C25 H25 118.7 . .
C25 C26 C27 118.8(7) . .
C25 C26 H26 120.6 . .
C27 C26 H26 120.6 . .
C26 C27 C28 119.2(7) . .
C26 C27 C30 119.0(8) . .
C28 C27 C30 121.8(8) . .
C29 C28 C27 121.7(7) . .
C29 C28 H28 119.2 . .
C27 C28 H28 119.2 . .
C24 C29 C28 119.3(7) . .
C24 C29 C31 122.5(7) . .
C28 C29 C31 118.2(7) . .
O8 C30 O7 122.8(10) . .
O8 C30 C27 119.6(10) . .
O7 C30 C27 117.6(9) . .
O6 C31 O5 122.8(7) . .
O6 C31 C29 118.9(8) . .
O5 C31 C29 118.3(7) . .
Zn2 O9 H9A 101(5) . .
Zn2 O9 H9B 139(6) . .
H9A O9 H9B 116(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 1.940(5) 1_445
Zn1 O5 1.973(5) 2_556
Zn1 O3 2.006(6) .
Zn1 N1 2.042(6) .
Zn2 O7 1.922(7) 2_566
Zn2 O4 1.956(6) .
Zn2 O9 1.975(6) .
Zn2 N3 2.032(6) 1_556
N1 C5 1.333(8) .
N1 C1 1.350(8) .
N2 C10 1.346(8) .
N2 C6 1.349(8) .
N3 C11 1.331(8) .
N3 C15 1.349(9) .
N3 Zn2 2.032(6) 1_554
O1 C22 1.279(9) .
O1 Zn1 1.940(5) 1_665
O2 C22 1.207(10) .
O3 C23 1.249(9) .
O4 C23 1.281(9) .
O5 C31 1.249(10) .
O5 Zn1 1.973(5) 2_556
O6 C31 1.234(10) .
O7 C30 1.258(12) .
O7 Zn2 1.922(7) 2_566
O8 C30 1.240(12) .
C1 C2 1.387(10) .
C1 H1 0.9300 .
C2 C3 1.378(10) .
C2 H2 0.9300 .
C3 C4 1.379(9) .
C3 H3 0.9300 .
C4 C5 1.407(10) .
C4 C6 1.496(9) .
C5 H5 0.9300 .
C6 C7 1.380(10) .
C7 C8 1.380(9) .
C7 H7 0.9300 .
C8 C9 1.365(9) .
C8 C16 1.506(9) .
C9 C10 1.388(10) .
C9 H9 0.9300 .
C10 C12 1.488(9) .
C11 C12 1.387(9) .
C11 H11 0.9300 .
C12 C13 1.386(10) .
C13 C14 1.392(9) .
C13 H13 0.9300 .
C14 C15 1.360(10) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C21 1.385(9) .
C16 C17 1.388(10) .
C17 C18 1.382(11) .
C17 H17 0.9300 .
C18 C19 1.378(10) .
C18 H18 0.9300 .
C19 C20 1.378(10) .
C19 H19 0.9300 .
C20 C21 1.397(10) .
C20 C22 1.520(10) .
C21 H21 0.9300 .
C23 C24 1.507(10) .
C24 C29 1.381(9) .
C24 C25 1.404(10) .
C25 C26 1.368(11) .
C25 H25 0.9300 .
C26 C27 1.385(11) .
C26 H26 0.9300 .
C27 C28 1.394(10) .
C27 C30 1.495(12) .
C28 C29 1.386(10) .
C28 H28 0.9300 .
C29 C31 1.496(10) .
O9 H9A 0.818(10) .
O9 H9B 0.820(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O1 Zn1 N1 C5 34.5(7) 1_445 . . .
O5 Zn1 N1 C5 173.2(6) 2_556 . . .
O3 Zn1 N1 C5 -80.8(6) . . . .
O1 Zn1 N1 C1 -153.2(5) 1_445 . . .
O5 Zn1 N1 C1 -14.6(6) 2_556 . . .
O3 Zn1 N1 C1 91.4(6) . . . .
O1 Zn1 O3 C23 -125.4(9) 1_445 . . .
O5 Zn1 O3 C23 112.8(9) 2_556 . . .
N1 Zn1 O3 C23 9.1(9) . . . .
O7 Zn2 O4 C23 39.3(8) 2_566 . . .
O9 Zn2 O4 C23 143.1(7) . . . .
N3 Zn2 O4 C23 -108.7(7) 1_556 . . .
C5 N1 C1 C2 4.4(11) . . . .
Zn1 N1 C1 C2 -168.1(6) . . . .
N1 C1 C2 C3 -2.5(12) . . . .
C1 C2 C3 C4 0.4(12) . . . .
C2 C3 C4 C5 -0.1(12) . . . .
C2 C3 C4 C6 179.3(7) . . . .
C1 N1 C5 C4 -4.2(11) . . . .
Zn1 N1 C5 C4 167.9(6) . . . .
C3 C4 C5 N1 2.1(12) . . . .
C6 C4 C5 N1 -177.3(7) . . . .
C10 N2 C6 C7 -4.0(11) . . . .
C10 N2 C6 C4 178.9(6) . . . .
C3 C4 C6 N2 178.9(7) . . . .
C5 C4 C6 N2 -1.7(10) . . . .
C3 C4 C6 C7 1.8(12) . . . .
C5 C4 C6 C7 -178.8(7) . . . .
N2 C6 C7 C8 1.7(12) . . . .
C4 C6 C7 C8 178.5(7) . . . .
C6 C7 C8 C9 4.4(11) . . . .
C6 C7 C8 C16 -175.8(7) . . . .
C7 C8 C9 C10 -7.8(11) . . . .
C16 C8 C9 C10 172.3(7) . . . .
C6 N2 C10 C9 0.4(11) . . . .
C6 N2 C10 C12 179.4(6) . . . .
C8 C9 C10 N2 5.6(12) . . . .
C8 C9 C10 C12 -173.3(7) . . . .
C15 N3 C11 C12 -4.4(12) . . . .
Zn2 N3 C11 C12 -180.0(6) 1_554 . . .
N3 C11 C12 C13 3.7(12) . . . .
N3 C11 C12 C10 -178.2(7) . . . .
N2 C10 C12 C13 13.4(11) . . . .
C9 C10 C12 C13 -167.6(8) . . . .
N2 C10 C12 C11 -164.6(7) . . . .
C9 C10 C12 C11 14.4(11) . . . .
C11 C12 C13 C14 -1.5(12) . . . .
C10 C12 C13 C14 -179.5(7) . . . .
C12 C13 C14 C15 0.4(13) . . . .
C11 N3 C15 C14 3.0(11) . . . .
Zn2 N3 C15 C14 178.2(6) 1_554 . . .
C13 C14 C15 N3 -1.1(13) . . . .
C9 C8 C16 C21 161.8(7) . . . .
C7 C8 C16 C21 -18.1(12) . . . .
C9 C8 C16 C17 -20.6(11) . . . .
C7 C8 C16 C17 159.5(8) . . . .
C21 C16 C17 C18 -2.6(13) . . . .
C8 C16 C17 C18 179.7(8) . . . .
C16 C17 C18 C19 -0.8(14) . . . .
C17 C18 C19 C20 3.0(14) . . . .
C18 C19 C20 C21 -1.7(12) . . . .
C18 C19 C20 C22 178.5(8) . . . .
C17 C16 C21 C20 3.9(11) . . . .
C8 C16 C21 C20 -178.4(7) . . . .
C19 C20 C21 C16 -1.9(12) . . . .
C22 C20 C21 C16 177.9(7) . . . .
Zn1 O1 C22 O2 4.9(12) 1_665 . . .
Zn1 O1 C22 C20 -176.2(5) 1_665 . . .
C19 C20 C22 O2 25.7(12) . . . .
C21 C20 C22 O2 -154.1(8) . . . .
C19 C20 C22 O1 -153.2(8) . . . .
C21 C20 C22 O1 26.9(12) . . . .
Zn1 O3 C23 O4 172.5(6) . . . .
Zn1 O3 C23 C24 1.5(13) . . . .
Zn2 O4 C23 O3 160.4(6) . . . .
Zn2 O4 C23 C24 -28.4(10) . . . .
O3 C23 C24 C29 -88.4(9) . . . .
O4 C23 C24 C29 100.4(9) . . . .
O3 C23 C24 C25 93.6(10) . . . .
O4 C23 C24 C25 -77.6(9) . . . .
C29 C24 C25 C26 1.5(13) . . . .
C23 C24 C25 C26 179.6(8) . . . .
C24 C25 C26 C27 -2.6(13) . . . .
C25 C26 C27 C28 2.5(13) . . . .
C25 C26 C27 C30 -175.6(8) . . . .
C26 C27 C28 C29 -1.2(12) . . . .
C30 C27 C28 C29 176.8(8) . . . .
C25 C24 C29 C28 -0.2(11) . . . .
C23 C24 C29 C28 -178.2(7) . . . .
C25 C24 C29 C31 -179.4(8) . . . .
C23 C24 C29 C31 2.6(12) . . . .
C27 C28 C29 C24 0.1(12) . . . .
C27 C28 C29 C31 179.4(7) . . . .
Zn2 O7 C30 O8 6.9(12) 2_566 . . .
Zn2 O7 C30 C27 -169.7(6) 2_566 . . .
C26 C27 C30 O8 6.3(13) . . . .
C28 C27 C30 O8 -171.7(9) . . . .
C26 C27 C30 O7 -177.0(8) . . . .
C28 C27 C30 O7 5.0(13) . . . .
Zn1 O5 C31 O6 -8.2(14) 2_556 . . .
Zn1 O5 C31 C29 168.7(5) 2_556 . . .
C24 C29 C31 O6 167.2(10) . . . .
C28 C29 C31 O6 -12.1(14) . . . .
C24 C29 C31 O5 -9.8(12) . . . .
C28 C29 C31 O5 170.9(8) . . . .
