#------------------------------------------------------------------------------
#$Date: 2021-05-12 10:57:27 +0300 (Wed, 12 May 2021) $
#$Revision: 265133 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/25/1562513.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562513
loop_
_publ_author_name
'Zhao, Xiaofang'
'Sun, Xiaowei'
'Han, Zhangang'
'Zhao, Chuan'
'Yu, Haitao'
'Zhai, Xueliang'
_publ_section_title
;
 Two new polyoxometalate-based hybrids consisting of Keggin-type cluster
 modified by {Ag4} group
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              178
_journal_page_last               183
_journal_paper_doi               10.1016/j.jssc.2013.09.023
_journal_volume                  207
_journal_year                    2013
_chemical_formula_sum            'C72 H72 Ag4 N12 O40 Si W12'
_chemical_formula_weight         4411.19
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.359(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   17.622(2)
_cell_length_b                   13.9629(16)
_cell_length_c                   19.330(2)
_cell_measurement_reflns_used    3552
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.07
_cell_measurement_theta_min      2.17
_cell_volume                     4748.1(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0679
_diffrn_reflns_av_sigmaI/netI    0.0787
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            23496
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.52
_exptl_absorpt_coefficient_mu    15.373
_exptl_absorpt_correction_T_max  0.136
_exptl_absorpt_correction_T_min  0.092
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    3.085
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3996
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_refine_diff_density_max         4.820
_refine_diff_density_min         -4.895
_refine_diff_density_rms         0.315
_refine_ls_extinction_coef       0.000081(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     662
_refine_ls_number_reflns         8357
_refine_ls_number_restraints     1236
_refine_ls_restrained_S_all      0.987
_refine_ls_R_factor_all          0.1302
_refine_ls_R_factor_gt           0.0780
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0603P)²+257.7142P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1712
_refine_ls_wR_factor_ref         0.2022
_reflns_number_gt                5060
_reflns_number_total             8357
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2013-207-178.cif
_cod_data_source_block           compound-2
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

data item '_exptl_crystal_density_meas' value 'none' was changed to
'?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_cell_volume        4748.0(10)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               1562513
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.43907(6) 0.56071(8) 0.16435(5) 0.0539(3) Uani 1 1 d . . .
W2 W 0.39458(6) 0.71071(9) 0.02170(5) 0.0588(3) Uani 1 1 d . . .
W3 W 0.45085(6) 0.64620(10) -0.14430(6) 0.0683(4) Uani 1 1 d . . .
W4 W 0.35940(7) 0.36002(10) 0.07482(7) 0.0839(5) Uani 1 1 d . . .
W5 W 0.41613(8) 0.30417(10) -0.09138(6) 0.0779(4) Uani 1 1 d . . .
W6 W 0.30874(7) 0.51096(13) -0.06592(6) 0.0922(6) Uani 1 1 d . . .
Ag1 Ag 0.94196(11) 0.91317(18) 0.00877(12) 0.0728(7) Uani 1 1 d . . .
Ag2 Ag 0.84954(17) 0.7292(2) 0.02590(19) 0.1238(13) Uani 1 1 d . . .
Si1 Si 0.5000 0.5000 0.0000 0.041(2) Uani 1 2 d S . .
O1 O 0.480(2) 0.470(3) 0.077(2) 0.084(4) Uani 0.50 1 d PU . .
O1' O 0.476(2) 0.575(3) 0.046(2) 0.084(4) Uani 0.50 1 d PU . .
O2 O 0.557(2) 0.418(3) 0.030(2) 0.080(5) Uani 0.50 1 d PU . .
O2' O 0.582(2) 0.567(3) 0.0193(19) 0.076(5) Uani 0.50 1 d PU . .
O3 O 0.3438(11) 0.8078(17) 0.0305(13) 0.106(6) Uani 1 1 d U . .
O4 O 0.3849(11) 0.6500(16) 0.1091(11) 0.090(4) Uani 1 1 d U . .
O5 O 0.4906(11) 0.7520(16) 0.0530(10) 0.085(4) Uani 1 1 d U . .
O6 O 0.5264(11) 0.6391(16) 0.1606(10) 0.084(4) Uani 1 1 d U . .
O7 O 0.4098(12) 0.5905(19) 0.2408(11) 0.105(6) Uani 1 1 d U . .
O8 O 0.2927(10) 0.2968(15) 0.1115(10) 0.078(5) Uani 1 1 d U . .
O9 O 0.5072(11) 0.4582(17) 0.1877(12) 0.094(4) Uani 1 1 d U . .
O10 O 0.3173(11) 0.6230(18) -0.0137(11) 0.095(4) Uani 1 1 d U . .
O11 O 0.3781(13) 0.2106(17) -0.1340(12) 0.099(6) Uani 1 1 d U . .
O12 O 0.3670(11) 0.4661(17) 0.1332(12) 0.096(4) Uani 1 1 d U . .
O13 O 0.3846(13) 0.2949(19) -0.0007(12) 0.110(4) Uani 1 1 d U . .
O14 O 0.3413(14) 0.400(2) -0.1088(12) 0.118(5) Uani 1 1 d U . .
O15 O 0.3607(12) 0.5751(19) -0.1357(11) 0.100(4) Uani 1 1 d U . .
O16 O 0.4246(11) 0.7197(18) -0.0682(11) 0.095(4) Uani 1 1 d U . .
O17 O 0.5504(11) 0.6875(17) -0.1205(12) 0.092(4) Uani 1 1 d U . .
O18 O 0.4267(13) 0.7176(16) -0.2121(10) 0.095(6) Uani 1 1 d U . .
O19 O 0.3079(13) 0.4508(19) 0.0166(12) 0.109(4) Uani 1 1 d U . .
O20 O 0.2202(10) 0.5189(15) -0.0960(10) 0.080(5) Uani 1 1 d U . .
C1 C 1.0528(14) 0.9050(19) -0.1282(13) 0.057(4) Uani 1 1 d U . .
H1 H 1.0154 0.9416 -0.1516 0.069 Uiso 1 1 calc R . .
C2 C 1.1025(14) 0.8554(19) -0.1672(13) 0.059(4) Uani 1 1 d U . .
H2 H 1.1001 0.8602 -0.2153 0.070 Uiso 1 1 calc R . .
C3 C 1.1568(13) 0.7976(19) -0.1320(13) 0.054(4) Uani 1 1 d U . .
C4 C 1.1599(13) 0.7934(18) -0.0623(12) 0.053(4) Uani 1 1 d U . .
H4 H 1.1963 0.7560 -0.0383 0.064 Uiso 1 1 calc R . .
C5 C 1.1065(13) 0.8468(19) -0.0262(13) 0.054(3) Uani 1 1 d U . .
C6 C 1.1090(14) 0.8457(18) 0.0517(13) 0.054(3) Uani 1 1 d U . .
C7 C 1.1731(14) 0.8242(18) 0.0919(13) 0.056(4) Uani 1 1 d U . .
H7 H 1.2181 0.8098 0.0714 0.067 Uiso 1 1 calc R . .
C8 C 1.1705(15) 0.8241(19) 0.1616(13) 0.059(4) Uani 1 1 d U . .
C9 C 1.1027(15) 0.8435(19) 0.1909(14) 0.062(4) Uani 1 1 d U . .
H9 H 1.1001 0.8435 0.2388 0.074 Uiso 1 1 calc R . .
C10 C 1.0394(15) 0.8627(19) 0.1488(14) 0.063(4) Uani 1 1 d U . .
H10 H 0.9933 0.8740 0.1684 0.076 Uiso 1 1 calc R . .
C11 C 1.2120(16) 0.737(2) -0.1727(14) 0.072(6) Uani 1 1 d U . .
H11A H 1.2625 0.7427 -0.1516 0.108 Uiso 1 1 calc R . .
H11B H 1.2114 0.7591 -0.2197 0.108 Uiso 1 1 calc R . .
H11C H 1.1965 0.6710 -0.1721 0.108 Uiso 1 1 calc R . .
C12 C 1.2421(16) 0.804(2) 0.2063(14) 0.075(6) Uani 1 1 d U . .
H12A H 1.2515 0.7359 0.2071 0.113 Uiso 1 1 calc R . .
H12B H 1.2359 0.8260 0.2525 0.113 Uiso 1 1 calc R . .
H12C H 1.2843 0.8359 0.1874 0.113 Uiso 1 1 calc R . .
C13 C 0.9827(16) 0.627(2) 0.1285(16) 0.071(4) Uani 1 1 d U . .
H13 H 0.9472 0.6337 0.1618 0.085 Uiso 1 1 calc R . .
C14 C 1.0562(15) 0.601(2) 0.1522(15) 0.069(4) Uani 1 1 d U . .
H14 H 1.0707 0.5975 0.1992 0.083 Uiso 1 1 calc R . .
C15 C 1.1065(15) 0.583(2) 0.1011(14) 0.063(4) Uani 1 1 d U . .
C16 C 1.0796(15) 0.5937(19) 0.0342(14) 0.061(3) Uani 1 1 d U . .
H16 H 1.1116 0.5798 -0.0010 0.074 Uiso 1 1 calc R . .
C17 C 1.0084(15) 0.624(2) 0.0169(15) 0.065(3) Uani 1 1 d U . .
C18 C 0.9802(15) 0.642(2) -0.0561(15) 0.066(4) Uani 1 1 d U . .
C19 C 1.0242(16) 0.615(2) -0.1093(15) 0.068(4) Uani 1 1 d U . .
H19 H 1.0708 0.5850 -0.1008 0.082 Uiso 1 1 calc R . .
C20 C 0.9955(16) 0.637(2) -0.1781(16) 0.073(4) Uani 1 1 d U . .
C21 C 0.9272(16) 0.679(2) -0.1868(16) 0.075(5) Uani 1 1 d U . .
H21 H 0.9081 0.6925 -0.2316 0.090 Uiso 1 1 calc R . .
C22 C 0.8857(17) 0.702(2) -0.1341(17) 0.077(4) Uani 1 1 d U . .
H22 H 0.8390 0.7326 -0.1427 0.092 Uiso 1 1 calc R . .
C23 C 1.0409(17) 0.612(2) -0.2371(16) 0.086(6) Uani 1 1 d U . .
H23A H 1.0177 0.5594 -0.2620 0.128 Uiso 1 1 calc R . .
H23B H 1.0914 0.5948 -0.2203 0.128 Uiso 1 1 calc R . .
H23C H 1.0432 0.6666 -0.2673 0.128 Uiso 1 1 calc R . .
C24 C 1.1867(16) 0.556(2) 0.1207(15) 0.076(6) Uani 1 1 d U . .
H24A H 1.2099 0.5306 0.0810 0.113 Uiso 1 1 calc R . .
H24B H 1.1879 0.5093 0.1569 0.113 Uiso 1 1 calc R . .
H24C H 1.2140 0.6124 0.1367 0.113 Uiso 1 1 calc R . .
C25 C 0.8124(19) 0.833(3) 0.1579(16) 0.091(5) Uani 1 1 d U . .
H25 H 0.8367 0.7796 0.1770 0.110 Uiso 1 1 calc R . .
C26 C 0.7826(19) 0.907(3) 0.2001(17) 0.092(6) Uani 1 1 d U . .
H26 H 0.7935 0.9033 0.2477 0.111 Uiso 1 1 calc R . .
C27 C 0.741(2) 0.979(3) 0.1762(17) 0.092(6) Uani 1 1 d U . .
C28 C 0.7300(19) 0.988(3) 0.1035(16) 0.089(5) Uani 1 1 d U . .
H28 H 0.6991 1.0369 0.0845 0.107 Uiso 1 1 calc R . .
C29 C 0.7662(19) 0.925(3) 0.0599(15) 0.083(4) Uani 1 1 d U . .
C30 C 0.7623(19) 0.929(3) -0.0154(15) 0.083(5) Uani 1 1 d U . .
C31 C 0.6956(19) 0.945(2) -0.0533(15) 0.086(5) Uani 1 1 d U . .
H31 H 0.6510 0.9499 -0.0300 0.103 Uiso 1 1 calc R . .
C32 C 0.692(2) 0.955(3) -0.1220(15) 0.089(5) Uani 1 1 d U . .
C33 C 0.759(2) 0.944(3) -0.1533(16) 0.090(5) Uani 1 1 d U . .
H33 H 0.7595 0.9472 -0.2013 0.108 Uiso 1 1 calc R . .
C34 C 0.8271(19) 0.929(2) -0.1149(14) 0.081(5) Uani 1 1 d U . .
H34 H 0.8719 0.9223 -0.1377 0.097 Uiso 1 1 calc R . .
C35 C 0.614(2) 0.967(3) -0.1584(18) 0.121(9) Uani 1 1 d U . .
H35A H 0.5781 0.9856 -0.1254 0.181 Uiso 1 1 calc R . .
H35B H 0.5980 0.9071 -0.1793 0.181 Uiso 1 1 calc R . .
H35C H 0.6161 1.0150 -0.1935 0.181 Uiso 1 1 calc R . .
C36 C 0.700(2) 1.053(3) 0.2184(18) 0.115(9) Uani 1 1 d U . .
H36A H 0.7193 1.0508 0.2657 0.173 Uiso 1 1 calc R . .
H36B H 0.6462 1.0387 0.2162 0.173 Uiso 1 1 calc R . .
H36C H 0.7074 1.1156 0.1997 0.173 Uiso 1 1 calc R . .
N1 N 1.0543(11) 0.9042(16) -0.0596(11) 0.062(6) Uani 1 1 d . . .
N2 N 1.0428(11) 0.8654(15) 0.0791(10) 0.056(5) Uani 1 1 d . . .
N3 N 0.9580(15) 0.6419(18) 0.0625(15) 0.094(9) Uani 1 1 d . . .
N4 N 0.9104(13) 0.6833(16) -0.0680(15) 0.079(7) Uani 1 1 d . . .
N5 N 0.8035(14) 0.847(2) 0.0899(14) 0.094(9) Uani 1 1 d . . .
N6 N 0.8292(12) 0.9235(15) -0.0469(9) 0.057(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 W1 O4 99.7(10) . .
O7 W1 O6 100.7(11) . .
O4 W1 O6 88.9(9) . .
O7 W1 O12 102.8(11) . .
O4 W1 O12 88.5(9) . .
O6 W1 O12 156.5(9) . .
O7 W1 O9 101.7(10) . .
O4 W1 O9 158.6(9) . .
O6 W1 O9 86.6(9) . .
O12 W1 O9 87.3(10) . .
O7 W1 O1 160.5(13) . .
O4 W1 O1 96.7(12) . .
O6 W1 O1 90.0(12) . .
O12 W1 O1 67.2(12) . .
O9 W1 O1 62.4(12) . .
O7 W1 O1' 160.5(14) . .
O4 W1 O1' 64.0(12) . .
O6 W1 O1' 69.8(12) . .
O12 W1 O1' 88.1(12) . .
O9 W1 O1' 94.8(12) . .
O1 W1 O1' 39.0(14) . .
O3 W2 O16 103.3(11) . .
O3 W2 O5 101.7(11) . .
O16 W2 O5 88.9(9) . .
O3 W2 O4 101.4(10) . .
O16 W2 O4 155.2(10) . .
O5 W2 O4 88.6(9) . .
O3 W2 O10 100.6(11) . .
O16 W2 O10 86.8(9) . .
O5 W2 O10 157.7(10) . .
O4 W2 O10 86.3(9) . .
O3 W2 O2 158.6(14) . 3_665
O16 W2 O2 60.0(12) . 3_665
O5 W2 O2 91.8(12) . 3_665
O4 W2 O2 95.5(12) . 3_665
O10 W2 O2 67.2(12) . 3_665
O3 W2 O1' 162.6(13) . .
O16 W2 O1' 92.2(11) . .
O5 W2 O1' 70.2(12) . .
O4 W2 O1' 63.8(11) . .
O10 W2 O1' 88.1(13) . .
O2 W2 O1' 38.8(13) 3_665 .
O18 W3 O9 101.7(10) . 3_665
O18 W3 O16 102.9(10) . .
O9 W3 O16 155.2(10) 3_665 .
O18 W3 O17 101.4(10) . .
O9 W3 O17 87.8(10) 3_665 .
O16 W3 O17 84.8(9) . .
O18 W3 O15 101.9(11) . .
O9 W3 O15 89.2(10) 3_665 .
O16 W3 O15 88.3(9) . .
O17 W3 O15 156.6(9) . .
O18 W3 O1 158.7(12) . 3_665
O9 W3 O1 60.4(12) 3_665 3_665
O16 W3 O1 95.0(12) . 3_665
O17 W3 O1 68.5(12) . 3_665
O15 W3 O1 90.0(12) . 3_665
O18 W3 O2 156.2(12) . 3_665
O9 W3 O2 99.7(12) 3_665 3_665
O16 W3 O2 56.7(12) . 3_665
O17 W3 O2 89.6(11) . 3_665
O15 W3 O2 68.1(12) . 3_665
O1 W3 O2 45.1(12) 3_665 3_665
O8 W4 O13 107.0(11) . .
O8 W4 O12 101.1(9) . .
O13 W4 O12 151.9(10) . .
O8 W4 O19 106.5(10) . .
O13 W4 O19 89.3(10) . .
O12 W4 O19 81.0(10) . .
O8 W4 O17 102.1(9) . 3_665
O13 W4 O17 87.8(10) . 3_665
O12 W4 O17 88.2(10) . 3_665
O19 W4 O17 150.8(10) . 3_665
O8 W4 O2' 154.9(12) . 3_665
O13 W4 O2' 57.0(13) . 3_665
O12 W4 O2' 96.0(12) . 3_665
O19 W4 O2' 58.1(11) . 3_665
O17 W4 O2' 96.7(11) 3_665 3_665
O11 W5 O13 106.0(11) . .
O11 W5 O14 102.1(12) . .
O13 W5 O14 88.4(10) . .
O11 W5 O6 101.2(10) . 3_665
O13 W5 O6 152.6(11) . 3_665
O14 W5 O6 88.6(9) . 3_665
O11 W5 O5 100.4(11) . 3_665
O13 W5 O5 84.6(9) . 3_665
O14 W5 O5 157.5(11) . 3_665
O6 W5 O5 87.9(8) 3_665 3_665
O11 W5 O2' 156.2(11) . 3_665
O13 W5 O2' 58.4(12) . 3_665
O14 W5 O2' 62.4(12) . 3_665
O6 W5 O2' 96.5(11) 3_665 3_665
O5 W5 O2' 96.0(12) 3_665 3_665
O20 W6 O19 106.8(10) . .
O20 W6 O10 100.4(10) . .
O19 W6 O10 85.2(11) . .
O20 W6 O14 102.1(11) . .
O19 W6 O14 91.3(11) . .
O10 W6 O14 157.2(11) . .
O20 W6 O15 101.9(9) . .
O19 W6 O15 151.3(10) . .
O10 W6 O15 87.8(10) . .
O14 W6 O15 84.4(11) . .
O20 W6 O2' 155.8(12) . 3_665
O19 W6 O2' 59.5(11) . 3_665
O10 W6 O2' 98.2(13) . 3_665
O14 W6 O2' 61.2(13) . 3_665
O15 W6 O2' 94.1(11) . 3_665
N6 Ag1 N2 163.8(7) . .
N6 Ag1 N1 118.3(7) . .
N2 Ag1 N1 71.3(6) . .
N6 Ag1 Ag2 68.9(6) . .
N2 Ag1 Ag2 95.2(5) . .
N1 Ag1 Ag2 117.8(6) . .
N6 Ag1 Ag1 117.5(5) . 3_775
N2 Ag1 Ag1 78.7(5) . 3_775
N1 Ag1 Ag1 55.9(6) . 3_775
Ag2 Ag1 Ag1 172.31(12) . 3_775
N5 Ag2 N4 149.3(9) . .
N5 Ag2 N3 122.1(11) . .
N4 Ag2 N3 71.2(10) . .
N5 Ag2 Ag1 70.0(7) . .
N4 Ag2 Ag1 82.6(6) . .
N3 Ag2 Ag1 92.3(7) . .
O1' Si1 O1' 179.997(7) 3_665 .
O1' Si1 O1 118(2) 3_665 .
O1' Si1 O1 62(2) . .
O1' Si1 O1 62(2) 3_665 3_665
O1' Si1 O1 118(2) . 3_665
O1 Si1 O1 179.998(4) . 3_665
O1' Si1 O2 61(2) 3_665 .
O1' Si1 O2 119(2) . .
O1 Si1 O2 69.5(19) . .
O1 Si1 O2 110.5(19) 3_665 .
O1' Si1 O2 119(2) 3_665 3_665
O1' Si1 O2 61(2) . 3_665
O1 Si1 O2 110.5(19) . 3_665
O1 Si1 O2 69.5(19) 3_665 3_665
O2 Si1 O2 179.997(6) . 3_665
O1' Si1 O2' 76(2) 3_665 3_665
O1' Si1 O2' 104(2) . 3_665
O1 Si1 O2' 80.4(19) . 3_665
O1 Si1 O2' 99.6(19) 3_665 3_665
O2 Si1 O2' 101(2) . 3_665
O2 Si1 O2' 79(2) 3_665 3_665
O1' Si1 O2' 104(2) 3_665 .
O1' Si1 O2' 76(2) . .
O1 Si1 O2' 99.6(19) . .
O1 Si1 O2' 80.4(19) 3_665 .
O2 Si1 O2' 79(2) . .
O2 Si1 O2' 101(2) 3_665 .
O2' Si1 O2' 179.999(5) 3_665 .
O1' O1 Si1 54.5(19) . .
O1' O1 W1 76(2) . .
Si1 O1 W1 130(2) . .
O1' O1 W3 148(3) . 3_665
Si1 O1 W3 123(2) . 3_665
W1 O1 W3 98.3(15) . 3_665
Si1 O1' O2 65(2) . 3_665
Si1 O1' O1 64(2) . .
O2 O1' O1 115(4) 3_665 .
Si1 O1' W2 130(2) . .
O2 O1' W2 65(2) 3_665 .
O1 O1' W2 145(3) . .
Si1 O1' W1 129(2) . .
O2 O1' W1 143(2) 3_665 .
O1 O1' W1 65.0(19) . .
W2 O1' W1 93.4(14) . .
O1' O2 Si1 55(2) 3_665 .
O1' O2 W2 76(2) 3_665 3_665
Si1 O2 W2 131(2) . 3_665
O1' O2 W3 149(3) 3_665 3_665
Si1 O2 W3 122.1(18) . 3_665
W2 O2 W3 98.9(15) 3_665 3_665
Si1 O2' W5 122.5(18) . 3_665
Si1 O2' W6 119(2) . 3_665
W5 O2' W6 98.6(15) 3_665 3_665
Si1 O2' W4 117.3(19) . 3_665
W5 O2' W4 98.0(15) 3_665 3_665
W6 O2' W4 96.3(12) 3_665 3_665
W1 O4 W2 137.2(11) . .
W2 O5 W5 137.7(13) . 3_665
W1 O6 W5 137.4(11) . 3_665
W3 O9 W1 138.1(13) 3_665 .
W6 O10 W2 139.4(11) . .
W4 O12 W1 140.0(11) . .
W4 O13 W5 145.7(16) . .
W6 O14 W5 137.5(15) . .
W3 O15 W6 138.9(13) . .
W2 O16 W3 142.9(14) . .
W3 O17 W4 138.9(13) . 3_665
W6 O19 W4 144.1(13) . .
N1 C1 C2 125(2) . .
N1 C1 H1 117.7 . .
C2 C1 H1 117.7 . .
C1 C2 C3 118(2) . .
C1 C2 H2 121.2 . .
C3 C2 H2 121.2 . .
C4 C3 C2 120(2) . .
C4 C3 C11 120(2) . .
C2 C3 C11 120(2) . .
C3 C4 C5 119(2) . .
C3 C4 H4 120.6 . .
C5 C4 H4 120.6 . .
N1 C5 C4 122(2) . .
N1 C5 C6 118(2) . .
C4 C5 C6 121(2) . .
N2 C6 C7 122(2) . .
N2 C6 C5 115(2) . .
C7 C6 C5 123(2) . .
C8 C7 C6 119(2) . .
C8 C7 H7 120.3 . .
C6 C7 H7 120.3 . .
C7 C8 C9 119(2) . .
C7 C8 C12 120(2) . .
C9 C8 C12 121(2) . .
C10 C9 C8 119(2) . .
C10 C9 H9 120.4 . .
C8 C9 H9 120.4 . .
N2 C10 C9 121(2) . .
N2 C10 H10 119.5 . .
C9 C10 H10 119.5 . .
C3 C11 H11A 109.5 . .
C3 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C3 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C8 C12 H12A 109.5 . .
C8 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C8 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
N3 C13 C14 127(3) . .
N3 C13 H13 116.7 . .
C14 C13 H13 116.7 . .
C15 C14 C13 116(3) . .
C15 C14 H14 122.2 . .
C13 C14 H14 122.2 . .
C16 C15 C14 117(3) . .
C16 C15 C24 123(2) . .
C14 C15 C24 120(3) . .
C17 C16 C15 123(3) . .
C17 C16 H16 118.7 . .
C15 C16 H16 118.7 . .
N3 C17 C16 123(3) . .
N3 C17 C18 114(3) . .
C16 C17 C18 123(2) . .
N4 C18 C19 122(3) . .
N4 C18 C17 118(3) . .
C19 C18 C17 119(2) . .
C18 C19 C20 117(3) . .
C18 C19 H19 121.4 . .
C20 C19 H19 121.4 . .
C21 C20 C19 118(3) . .
C21 C20 C23 122(3) . .
C19 C20 C23 120(3) . .
C22 C21 C20 123(3) . .
C22 C21 H21 118.6 . .
C20 C21 H21 118.6 . .
C21 C22 N4 121(3) . .
C21 C22 H22 119.5 . .
N4 C22 H22 119.5 . .
C20 C23 H23A 109.5 . .
C20 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C20 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C15 C24 H24A 109.5 . .
C15 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C15 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
N5 C25 C26 116(4) . .
N5 C25 H25 121.9 . .
C26 C25 H25 121.9 . .
C27 C26 C25 124(3) . .
C27 C26 H26 117.8 . .
C25 C26 H26 117.8 . .
C26 C27 C28 117(3) . .
C26 C27 C36 127(3) . .
C28 C27 C36 115(4) . .
C29 C28 C27 120(4) . .
C29 C28 H28 120.0 . .
C27 C28 H28 120.0 . .
N5 C29 C28 118(3) . .
N5 C29 C30 116(3) . .
C28 C29 C30 125(3) . .
N6 C30 C31 121(3) . .
N6 C30 C29 117(3) . .
C31 C30 C29 122(3) . .
C32 C31 C30 123(3) . .
C32 C31 H31 118.5 . .
C30 C31 H31 118.5 . .
C31 C32 C33 115(3) . .
C31 C32 C35 118(3) . .
C33 C32 C35 126(3) . .
C32 C33 C34 122(3) . .
C32 C33 H33 119.2 . .
C34 C33 H33 119.2 . .
N6 C34 C33 121(3) . .
N6 C34 H34 119.4 . .
C33 C34 H34 119.4 . .
C32 C35 H35A 109.5 . .
C32 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C32 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C27 C36 H36A 109.5 . .
C27 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C27 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C1 N1 C5 117(2) . .
C1 N1 Ag1 124.8(16) . .
C5 N1 Ag1 108.7(14) . .
C6 N2 C10 119(2) . .
C6 N2 Ag1 119.5(16) . .
C10 N2 Ag1 121.7(16) . .
C17 N3 C13 115(3) . .
C17 N3 Ag2 118(2) . .
C13 N3 Ag2 126(2) . .
C22 N4 C18 119(3) . .
C22 N4 Ag2 124(2) . .
C18 N4 Ag2 117(2) . .
C25 N5 C29 123(3) . .
C25 N5 Ag2 115(3) . .
C29 N5 Ag2 122(2) . .
C34 N6 C30 118(2) . .
C34 N6 Ag1 117.6(19) . .
C30 N6 Ag1 124.3(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O7 1.648(19) .
W1 O4 1.87(2) .
W1 O6 1.89(2) .
W1 O12 1.91(2) .
W1 O9 1.91(2) .
W1 O1 2.26(4) .
W1 O1' 2.42(4) .
W2 O3 1.64(2) .
W2 O16 1.85(2) .
W2 O5 1.86(2) .
W2 O4 1.91(2) .
W2 O10 1.93(2) .
W2 O2 2.25(4) 3_665
W2 O1' 2.41(4) .
W3 O18 1.682(18) .
W3 O9 1.86(2) 3_665
W3 O16 1.87(2) .
W3 O17 1.88(2) .
W3 O15 1.89(2) .
W3 O1 2.38(4) 3_665
W3 O2 2.39(4) 3_665
W4 O8 1.661(18) .
W4 O13 1.80(2) .
W4 O12 1.86(3) .
W4 O19 1.89(2) .
W4 O17 1.89(2) 3_665
W4 O2' 2.37(3) 3_665
W5 O11 1.66(2) .
W5 O13 1.87(2) .
W5 O14 1.89(2) .
W5 O6 1.899(19) 3_665
W5 O5 1.93(2) 3_665
W5 O2' 2.28(4) 3_665
W6 O20 1.636(18) .
W6 O19 1.80(2) .
W6 O10 1.86(3) .
W6 O14 1.87(3) .
W6 O15 1.90(2) .
W6 O2' 2.35(4) 3_665
Ag1 N6 2.21(2) .
Ag1 N2 2.273(19) .
Ag1 N1 2.447(18) .
Ag1 Ag2 3.070(4) .
Ag1 Ag1 3.203(5) 3_775
Ag2 N5 2.23(3) .
Ag2 N4 2.25(3) .
Ag2 N3 2.34(2) .
Si1 O1' 1.45(4) 3_665
Si1 O1' 1.45(4) .
Si1 O1 1.60(4) .
Si1 O1 1.60(4) 3_665
Si1 O2 1.61(4) .
Si1 O2 1.61(4) 3_665
Si1 O2' 1.74(4) 3_665
Si1 O2' 1.74(4) .
O1 O1' 1.57(6) .
O1 W3 2.38(4) 3_665
O1' O2 1.55(5) 3_665
O2 O1' 1.55(5) 3_665
O2 W2 2.25(4) 3_665
O2 W3 2.39(4) 3_665
O2' W5 2.27(4) 3_665
O2' W6 2.35(4) 3_665
O2' W4 2.37(3) 3_665
O5 W5 1.93(2) 3_665
O6 W5 1.899(19) 3_665
O9 W3 1.86(2) 3_665
O17 W4 1.89(2) 3_665
C1 N1 1.32(3) .
C1 C2 1.38(3) .
C1 H1 0.9300 .
C2 C3 1.40(3) .
C2 H2 0.9300 .
C3 C4 1.35(3) .
C3 C11 1.54(3) .
C4 C5 1.42(3) .
C4 H4 0.9300 .
C5 N1 1.35(3) .
C5 C6 1.50(3) .
C6 N2 1.34(3) .
C6 C7 1.37(3) .
C7 C8 1.35(3) .
C7 H7 0.9300 .
C8 C9 1.38(3) .
C8 C12 1.51(3) .
C9 C10 1.37(3) .
C9 H9 0.9300 .
C10 N2 1.35(3) .
C10 H10 0.9300 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 N3 1.34(4) .
C13 C14 1.39(4) .
C13 H13 0.9300 .
C14 C15 1.39(3) .
C14 H14 0.9300 .
C15 C16 1.36(4) .
C15 C24 1.49(4) .
C16 C17 1.35(3) .
C16 H16 0.9300 .
C17 N3 1.31(3) .
C17 C18 1.49(4) .
C18 N4 1.37(3) .
C18 C19 1.37(4) .
C19 C20 1.43(4) .
C19 H19 0.9300 .
C20 C21 1.34(4) .
C20 C23 1.47(4) .
C21 C22 1.33(4) .
C21 H21 0.9300 .
C22 N4 1.35(4) .
C22 H22 0.9300 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 N5 1.33(4) .
C25 C26 1.43(5) .
C25 H25 0.9300 .
C26 C27 1.32(5) .
C26 H26 0.9300 .
C27 C28 1.41(4) .
C27 C36 1.52(5) .
C28 C29 1.40(4) .
C28 H28 0.9300 .
C29 N5 1.38(4) .
C29 C30 1.45(4) .
C30 N6 1.36(3) .
C30 C31 1.37(4) .
C31 C32 1.33(4) .
C31 H31 0.9300 .
C32 C33 1.38(4) .
C32 C35 1.51(4) .
C33 C34 1.38(4) .
C33 H33 0.9300 .
C34 N6 1.32(3) .
C34 H34 0.9300 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
