#------------------------------------------------------------------------------
#$Date: 2021-05-12 11:12:24 +0300 (Wed, 12 May 2021) $
#$Revision: 265134 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/25/1562514.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562514
loop_
_publ_author_name
'West, J. Palmer'
'Sulejmanovic, Dino'
'Becht, Gregory'
'He, Jian'
'Hitchcock, Dale'
'Yan, Yonggao'
'Hwu, Shiou-Jyh'
_publ_section_title
;
 Enhanced ferromagnetic order in Sr4Mn3O3(GeO4)3 featuring canted [MnO4]
 spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of
 the Sr4−LnMnIII2+MnIV1−O3(GeO4)3 solid-solution
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              51
_journal_page_last               59
_journal_paper_doi               10.1016/j.jssc.2013.07.033
_journal_volume                  206
_journal_year                    2013
_chemical_formula_sum            'Ge3 Mn3 O15 Sr4'
_chemical_formula_weight         973.07
_space_group_IT_number           176
_space_group_name_Hall           '-P 6c'
_space_group_name_H-M_alt        'P 63/m'
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_H-M   'P 63/m'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   11.2282(16)
_cell_length_b                   11.2282(16)
_cell_length_c                   6.0823(12)
_cell_measurement_reflns_used    431
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.93
_cell_measurement_theta_min      2.09
_cell_volume                     664.08(19)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1084
_diffrn_reflns_av_sigmaI/netI    0.0328
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            5644
_diffrn_reflns_theta_full        24.93
_diffrn_reflns_theta_max         24.93
_diffrn_reflns_theta_min         2.09
_exptl_absorpt_coefficient_mu    25.445
_exptl_absorpt_correction_T_max  0.5157
_exptl_absorpt_correction_T_min  0.1852
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB,RIGAKU/MSC,The Woodlands,TX,USA,1999.'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    4.866
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       column
_exptl_crystal_F_000             886
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.299
_refine_diff_density_min         -1.325
_refine_diff_density_rms         0.310
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.202
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     48
_refine_ls_number_reflns         431
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.202
_refine_ls_R_factor_all          0.0565
_refine_ls_R_factor_gt           0.0479
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0478P)²+13.4359P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1078
_refine_ls_wR_factor_ref         0.1153
_reflns_number_gt                377
_reflns_number_total             431
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2013-206-51.cif
_cod_data_source_block           Sr4Mn3O3(GeO4)3_(1)
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Hexagonal' was changed to
'hexagonal' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      P6(3)/m
_cod_database_code               1562514
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sr1 Sr 0.3333 0.6667 0.2500 0.0139(6) Uani 1 6 d S . .
Sr2 Sr 0.11512(15) 0.27765(15) 0.2500 0.0194(5) Uani 1 2 d S . .
Mn Mn 0.5000 0.5000 0.0000 0.0110(6) Uani 1 2 d S . .
Ge Ge 0.22256(16) 0.81497(16) -0.2500 0.0146(5) Uani 1 2 d S . .
O(1) O 0.3843(11) 0.4561(11) 0.2500 0.017(2) Uani 1 2 d S . .
O(2) O 0.3144(7) 0.8380(7) -0.0065(14) 0.0186(16) Uani 1 1 d . . .
O(4) O 0.1362(12) 0.9067(12) -0.2500 0.035(3) Uani 1 2 d S . .
O(3) O 0.0779(11) 0.6497(11) -0.2500 0.026(3) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -1.5307 3.2498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O(2) Sr1 O(2) 74.8(4) 10_556 .
O(2) Sr1 O(2) 133.21(13) 10_556 2_665
O(2) Sr1 O(2) 86.9(3) . 2_665
O(2) Sr1 O(2) 86.9(3) 10_556 11_666
O(2) Sr1 O(2) 133.21(13) . 11_666
O(2) Sr1 O(2) 74.8(4) 2_665 11_666
O(2) Sr1 O(2) 86.9(3) 10_556 12_566
O(2) Sr1 O(2) 133.21(13) . 12_566
O(2) Sr1 O(2) 133.21(12) 2_665 12_566
O(2) Sr1 O(2) 86.9(3) 11_666 12_566
O(2) Sr1 O(2) 133.21(13) 10_556 3_565
O(2) Sr1 O(2) 86.9(3) . 3_565
O(2) Sr1 O(2) 86.9(3) 2_665 3_565
O(2) Sr1 O(2) 133.21(12) 11_666 3_565
O(2) Sr1 O(2) 74.8(4) 12_566 3_565
O(2) Sr1 O(1) 70.7(2) 10_556 3_565
O(2) Sr1 O(1) 70.7(2) . 3_565
O(2) Sr1 O(1) 62.6(2) 2_665 3_565
O(2) Sr1 O(1) 62.6(2) 11_666 3_565
O(2) Sr1 O(1) 142.25(19) 12_566 3_565
O(2) Sr1 O(1) 142.25(19) 3_565 3_565
O(2) Sr1 O(1) 62.6(2) 10_556 2_665
O(2) Sr1 O(1) 62.6(2) . 2_665
O(2) Sr1 O(1) 142.25(19) 2_665 2_665
O(2) Sr1 O(1) 142.25(19) 11_666 2_665
O(2) Sr1 O(1) 70.7(2) 12_566 2_665
O(2) Sr1 O(1) 70.7(2) 3_565 2_665
O(1) Sr1 O(1) 120.000(1) 3_565 2_665
O(2) Sr1 O(1) 142.25(19) 10_556 .
O(2) Sr1 O(1) 142.25(19) . .
O(2) Sr1 O(1) 70.7(2) 2_665 .
O(2) Sr1 O(1) 70.7(2) 11_666 .
O(2) Sr1 O(1) 62.6(2) 12_566 .
O(2) Sr1 O(1) 62.6(2) 3_565 .
O(1) Sr1 O(1) 120.000(2) 3_565 .
O(1) Sr1 O(1) 120.000(2) 2_665 .
O(2) Sr1 Mn 101.13(17) 10_556 3_565
O(2) Sr1 Mn 71.15(16) . 3_565
O(2) Sr1 Mn 32.26(16) 2_665 3_565
O(2) Sr1 Mn 70.76(18) 11_666 3_565
O(2) Sr1 Mn 155.61(17) 12_566 3_565
O(2) Sr1 Mn 113.24(19) 3_565 3_565
O(1) Sr1 Mn 31.36(13) 3_565 3_565
O(1) Sr1 Mn 133.43(19) 2_665 3_565
O(1) Sr1 Mn 99.6(2) . 3_565
O(2) Sr1 Mn 32.26(16) 10_556 5_565
O(2) Sr1 Mn 70.76(18) . 5_565
O(2) Sr1 Mn 155.61(17) 2_665 5_565
O(2) Sr1 Mn 113.24(19) 11_666 5_565
O(2) Sr1 Mn 71.15(16) 12_566 5_565
O(2) Sr1 Mn 101.13(17) 3_565 5_565
O(1) Sr1 Mn 99.6(2) 3_565 5_565
O(1) Sr1 Mn 31.36(14) 2_665 5_565
O(1) Sr1 Mn 133.43(19) . 5_565
Mn Sr1 Mn 126.170(3) 3_565 5_565
O(2) Sr1 Mn 71.15(16) 10_556 6
O(2) Sr1 Mn 101.13(17) . 6
O(2) Sr1 Mn 70.76(18) 2_665 6
O(2) Sr1 Mn 32.26(16) 11_666 6
O(2) Sr1 Mn 113.24(19) 12_566 6
O(2) Sr1 Mn 155.61(17) 3_565 6
O(1) Sr1 Mn 31.36(13) 3_565 6
O(1) Sr1 Mn 133.43(19) 2_665 6
O(1) Sr1 Mn 99.6(2) . 6
Mn Sr1 Mn 50.265(11) 3_565 6
Mn Sr1 Mn 103.263(6) 5_565 6
O(4) Sr2 O(4) 101.4(5) 9_655 7_565
O(4) Sr2 O(2) 127.6(2) 9_655 11_666
O(4) Sr2 O(2) 111.9(3) 7_565 11_666
O(4) Sr2 O(2) 127.6(2) 9_655 2_665
O(4) Sr2 O(2) 111.9(3) 7_565 2_665
O(2) Sr2 O(2) 75.4(4) 11_666 2_665
O(4) Sr2 O(1) 74.1(4) 9_655 .
O(4) Sr2 O(1) 175.6(4) 7_565 .
O(2) Sr2 O(1) 71.5(2) 11_666 .
O(2) Sr2 O(1) 71.5(2) 2_665 .
O(4) Sr2 O(3) 161.9(4) 9_655 7_565
O(4) Sr2 O(3) 60.4(4) 7_565 7_565
O(2) Sr2 O(3) 65.0(2) 11_666 7_565
O(2) Sr2 O(3) 65.0(2) 2_665 7_565
O(1) Sr2 O(3) 124.0(3) . 7_565
O(4) Sr2 O(4) 84.8(2) 9_655 2_665
O(4) Sr2 O(4) 84.2(3) 7_565 2_665
O(2) Sr2 O(4) 136.2(3) 11_666 2_665
O(2) Sr2 O(4) 60.9(3) 2_665 2_665
O(1) Sr2 O(4) 95.3(2) . 2_665
O(3) Sr2 O(4) 92.8(2) 7_565 2_665
O(4) Sr2 O(4) 84.8(2) 9_655 2_666
O(4) Sr2 O(4) 84.2(3) 7_565 2_666
O(2) Sr2 O(4) 60.9(3) 11_666 2_666
O(2) Sr2 O(4) 136.2(3) 2_665 2_666
O(1) Sr2 O(4) 95.3(2) . 2_666
O(3) Sr2 O(4) 92.8(2) 7_565 2_666
O(4) Sr2 O(4) 162.5(5) 2_665 2_666
O(4) Sr2 Ge 101.40(10) 9_655 2_666
O(4) Sr2 Ge 106.47(9) 7_565 2_666
O(2) Sr2 Ge 31.69(18) 11_666 2_666
O(2) Sr2 Ge 106.14(19) 2_665 2_666
O(1) Sr2 Ge 74.77(8) . 2_666
O(3) Sr2 Ge 85.11(9) 7_565 2_666
O(4) Sr2 Ge 166.1(2) 2_665 2_666
O(4) Sr2 Ge 31.3(2) 2_666 2_666
O(4) Sr2 Ge 101.40(10) 9_655 2_665
O(4) Sr2 Ge 106.47(9) 7_565 2_665
O(2) Sr2 Ge 106.14(19) 11_666 2_665
O(2) Sr2 Ge 31.69(18) 2_665 2_665
O(1) Sr2 Ge 74.77(8) . 2_665
O(3) Sr2 Ge 85.11(9) 7_565 2_665
O(4) Sr2 Ge 31.3(2) 2_665 2_665
O(4) Sr2 Ge 166.1(2) 2_666 2_665
Ge Sr2 Ge 134.84(7) 2_666 2_665
O(4) Sr2 Ge 131.1(3) 9_655 7_565
O(4) Sr2 Ge 29.7(3) 7_565 7_565
O(2) Sr2 Ge 88.76(16) 11_666 7_565
O(2) Sr2 Ge 88.76(16) 2_665 7_565
O(1) Sr2 Ge 154.7(2) . 7_565
O(3) Sr2 Ge 30.7(2) 7_565 7_565
O(4) Sr2 Ge 88.1(2) 2_665 7_565
O(4) Sr2 Ge 88.1(2) 2_666 7_565
Ge Sr2 Ge 96.78(3) 2_666 7_565
Ge Sr2 Ge 96.78(3) 2_665 7_565
O(4) Sr2 Ge 25.0(3) 9_655 9_655
O(4) Sr2 Ge 126.4(3) 7_565 9_655
O(2) Sr2 Ge 109.88(17) 11_666 9_655
O(2) Sr2 Ge 109.88(17) 2_665 9_655
O(1) Sr2 Ge 49.1(2) . 9_655
O(3) Sr2 Ge 173.1(2) 7_565 9_655
O(4) Sr2 Ge 88.2(2) 2_665 9_655
O(4) Sr2 Ge 88.2(2) 2_666 9_655
Ge Sr2 Ge 92.29(3) 2_666 9_655
Ge Sr2 Ge 92.29(3) 2_665 9_655
Ge Sr2 Ge 156.13(6) 7_565 9_655
O(1) Mn O(1) 180.000(1) 7_665 .
O(1) Mn O(2) 90.2(4) 7_665 9_655
O(1) Mn O(2) 89.8(4) . 9_655
O(1) Mn O(2) 89.8(4) 7_665 3_565
O(1) Mn O(2) 90.2(4) . 3_565
O(2) Mn O(2) 180.000(1) 9_655 3_565
O(1) Mn O(3) 80.3(3) 7_665 2_665
O(1) Mn O(3) 99.7(3) . 2_665
O(2) Mn O(3) 87.1(4) 9_655 2_665
O(2) Mn O(3) 92.9(4) 3_565 2_665
O(1) Mn O(3) 99.7(3) 7_665 8
O(1) Mn O(3) 80.3(3) . 8
O(2) Mn O(3) 92.9(4) 9_655 8
O(2) Mn O(3) 87.1(4) 3_565 8
O(3) Mn O(3) 180.0 2_665 8
O(1) Mn Mn 36.8(3) 7_665 4_664
O(1) Mn Mn 143.2(3) . 4_664
O(2) Mn Mn 91.2(3) 9_655 4_664
O(2) Mn Mn 88.8(3) 3_565 4_664
O(3) Mn Mn 43.8(2) 2_665 4_664
O(3) Mn Mn 136.2(2) 8 4_664
O(1) Mn Mn 143.2(3) 7_665 4_665
O(1) Mn Mn 36.8(3) . 4_665
O(2) Mn Mn 88.8(3) 9_655 4_665
O(2) Mn Mn 91.2(3) 3_565 4_665
O(3) Mn Mn 136.2(2) 2_665 4_665
O(3) Mn Mn 43.8(2) 8 4_665
Mn Mn Mn 180.0 4_664 4_665
O(1) Mn Sr1 47.7(3) 7_665 7_665
O(1) Mn Sr1 132.3(3) . 7_665
O(2) Mn Sr1 44.2(2) 9_655 7_665
O(2) Mn Sr1 135.8(2) 3_565 7_665
O(3) Mn Sr1 91.1(3) 2_665 7_665
O(3) Mn Sr1 88.9(3) 8 7_665
Mn Mn Sr1 64.868(5) 4_664 7_665
Mn Mn Sr1 115.132(5) 4_665 7_665
O(1) Mn Sr1 132.3(3) 7_665 .
O(1) Mn Sr1 47.7(3) . .
O(2) Mn Sr1 135.8(2) 9_655 .
O(2) Mn Sr1 44.2(2) 3_565 .
O(3) Mn Sr1 88.9(3) 2_665 .
O(3) Mn Sr1 91.1(3) 8 .
Mn Mn Sr1 115.132(5) 4_664 .
Mn Mn Sr1 64.868(5) 4_665 .
Sr1 Mn Sr1 180.0 7_665 .
O(1) Mn Sr2 87.7(3) 7_665 8
O(1) Mn Sr2 92.3(3) . 8
O(2) Mn Sr2 41.5(2) 9_655 8
O(2) Mn Sr2 138.5(2) 3_565 8
O(3) Mn Sr2 45.9(3) 2_665 8
O(3) Mn Sr2 134.1(3) 8 8
Mn Mn Sr2 65.498(10) 4_664 8
Mn Mn Sr2 114.502(11) 4_665 8
Sr1 Mn Sr2 63.09(2) 7_665 8
Sr1 Mn Sr2 116.91(2) . 8
O(1) Mn Sr2 92.3(3) 7_665 2_665
O(1) Mn Sr2 87.7(3) . 2_665
O(2) Mn Sr2 138.5(2) 9_655 2_665
O(2) Mn Sr2 41.5(2) 3_565 2_665
O(3) Mn Sr2 134.1(3) 2_665 2_665
O(3) Mn Sr2 45.9(3) 8 2_665
Mn Mn Sr2 114.502(11) 4_664 2_665
Mn Mn Sr2 65.498(10) 4_665 2_665
Sr1 Mn Sr2 116.91(2) 7_665 2_665
Sr1 Mn Sr2 63.09(2) . 2_665
Sr2 Mn Sr2 180.00(4) 8 2_665
O(4) Ge O(2) 112.1(3) . .
O(4) Ge O(2) 112.1(3) . 10
O(2) Ge O(2) 115.8(5) . 10
O(4) Ge O(3) 97.6(5) . .
O(2) Ge O(3) 108.8(3) . .
O(2) Ge O(3) 108.8(3) 10 .
O(4) Ge Sr2 67.43(4) . 3_565
O(2) Ge Sr2 50.1(3) . 3_565
O(2) Ge Sr2 157.3(2) 10 3_565
O(3) Ge Sr2 93.48(15) . 3_565
O(4) Ge Sr2 67.43(4) . 3_564
O(2) Ge Sr2 157.3(3) . 3_564
O(2) Ge Sr2 50.1(3) 10 3_564
O(3) Ge Sr2 93.48(15) . 3_564
Sr2 Ge Sr2 134.84(7) 3_565 3_564
O(4) Ge Sr2 46.4(4) . 7_565
O(2) Ge Sr2 122.1(3) . 7_565
O(2) Ge Sr2 122.1(3) 10 7_565
O(3) Ge Sr2 51.2(4) . 7_565
Sr2 Ge Sr2 75.08(4) 3_565 7_565
Sr2 Ge Sr2 75.08(4) 3_564 7_565
O(4) Ge Sr2 37.5(4) . 8_565
O(2) Ge Sr2 94.0(2) . 8_565
O(2) Ge Sr2 94.0(2) 10 8_565
O(3) Ge Sr2 135.1(4) . 8_565
Sr2 Ge Sr2 71.89(4) 3_565 8_565
Sr2 Ge Sr2 71.89(4) 3_564 8_565
Sr2 Ge Sr2 83.87(6) 7_565 8_565
Mn O(1) Mn 106.5(5) 4_665 .
Mn O(1) Sr2 124.6(3) 4_665 .
Mn O(1) Sr2 124.6(3) . .
Mn O(1) Sr1 100.9(4) 4_665 .
Mn O(1) Sr1 100.9(4) . .
Sr2 O(1) Sr1 90.1(3) . .
Ge O(2) Mn 115.3(4) . 2_665
Ge O(2) Sr2 98.2(3) . 3_565
Mn O(2) Sr2 107.8(3) 2_665 3_565
Ge O(2) Sr1 131.9(4) . .
Mn O(2) Sr1 103.5(3) 2_665 .
Sr2 O(2) Sr1 95.6(3) 3_565 .
Ge O(4) Sr2 117.5(5) . 8_565
Ge O(4) Sr2 103.9(5) . 7_565
Sr2 O(4) Sr2 138.6(5) 8_565 7_565
Ge O(4) Sr2 81.3(2) . 3_565
Sr2 O(4) Sr2 93.5(2) 8_565 3_565
Sr2 O(4) Sr2 92.7(2) 7_565 3_565
Ge O(4) Sr2 81.3(2) . 3_564
Sr2 O(4) Sr2 93.5(2) 8_565 3_564
Sr2 O(4) Sr2 92.7(2) 7_565 3_564
Sr2 O(4) Sr2 162.5(5) 3_565 3_564
Ge O(3) Mn 129.9(3) . 6_554
Ge O(3) Mn 129.9(3) . 3_565
Mn O(3) Mn 92.5(4) 6_554 3_565
Ge O(3) Sr2 98.1(5) . 7_565
Mn O(3) Sr2 99.6(3) 6_554 7_565
Mn O(3) Sr2 99.6(3) 3_565 7_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sr1 O(2) 2.567(8) 10_556
Sr1 O(2) 2.567(8) .
Sr1 O(2) 2.567(8) 2_665
Sr1 O(2) 2.567(8) 11_666
Sr1 O(2) 2.567(8) 12_566
Sr1 O(2) 2.567(8) 3_565
Sr1 O(1) 2.697(11) 3_565
Sr1 O(1) 2.697(11) 2_665
Sr1 O(1) 2.697(11) .
Sr2 O(4) 2.493(12) 9_655
Sr2 O(4) 2.531(11) 7_565
Sr2 O(2) 2.552(8) 11_666
Sr2 O(2) 2.552(8) 2_665
Sr2 O(1) 2.663(11) .
Sr2 O(3) 2.670(11) 7_565
Sr2 O(4) 3.077(2) 2_665
Sr2 O(4) 3.077(2) 2_666
Mn O(1) 1.898(7) 7_665
Mn O(1) 1.898(7) .
Mn O(2) 1.965(7) 9_655
Mn O(2) 1.965(7) 3_565
Mn O(3) 2.105(7) 2_665
Mn O(3) 2.105(7) 8
Ge O(4) 1.732(13) .
Ge O(2) 1.748(8) .
Ge O(2) 1.748(8) 10
Ge O(3) 1.752(10) .
O(1) Mn 1.898(7) 4_665
O(2) Mn 1.965(7) 2_665
O(2) Sr2 2.552(8) 3_565
O(4) Sr2 2.493(12) 8_565
O(4) Sr2 2.531(11) 7_565
O(4) Sr2 3.077(2) 3_565
O(4) Sr2 3.077(2) 3_564
O(3) Mn 2.105(7) 6_554
O(3) Mn 2.105(7) 3_565
O(3) Sr2 2.670(11) 7_565
