#------------------------------------------------------------------------------
#$Date: 2021-05-17 10:03:49 +0300 (Mon, 17 May 2021) $
#$Revision: 265260 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/25/1562571.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562571
loop_
_publ_author_name
'Wang, Jian'
'Xia, Sheng-Qing'
'Tao, Xu-Tang'
'Schäfer, Marion C.'
'Bobev, Svilen'
_publ_section_title
;
 New ternary phosphides and arsenides. Syntheses, crystal structures,
 physical properties of Eu2ZnP2, Eu2Zn2P3 and Eu2Cd2As3
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              116
_journal_page_last               121
_journal_paper_doi               10.1016/j.jssc.2013.06.029
_journal_volume                  205
_journal_year                    2013
_chemical_formula_sum            'As3 Cd2 Eu2'
_chemical_formula_weight         753.48
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 126.515(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.402(13)
_cell_length_b                   4.445(4)
_cell_length_c                   12.311(10)
_cell_measurement_reflns_used    839
_cell_measurement_temperature    300(2)
_cell_measurement_theta_max      26.34
_cell_measurement_theta_min      2.06
_cell_volume                     721.4(10)
_computing_cell_refinement       'APEX2 Software Suite (Bruker,2005)'
_computing_data_collection       'APEX2 Software Suite (Bruker,2005)'
_computing_data_reduction        'APEX2 Software Suite (Bruker,2005)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type
'Bruker APEX2 CCD area-detector diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0354
_diffrn_reflns_av_sigmaI/netI    0.0268
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            4016
_diffrn_reflns_theta_full        26.34
_diffrn_reflns_theta_max         26.34
_diffrn_reflns_theta_min         2.06
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    36.499
_exptl_absorpt_correction_T_max  0.4073
_exptl_absorpt_correction_T_min  0.2626
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'APEX2 Software Suite (Bruker,2005)'
_exptl_crystal_colour            Black
_exptl_crystal_density_diffrn    6.938
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Needle
_exptl_crystal_F_000             1284
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.053
_refine_diff_density_min         -1.050
_refine_diff_density_rms         0.241
_refine_ls_extinction_coef       0.00092(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_matrix_type           full
_refine_ls_number_parameters     44
_refine_ls_number_reflns         839
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0240
_refine_ls_R_factor_gt           0.0188
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0150P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0363
_refine_ls_wR_factor_ref         0.0380
_reflns_number_gt                727
_reflns_number_total             839
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2013-205-116.cif
_cod_data_source_block           x1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_cell_volume        721.3(10)
_cod_original_sg_symbol_H-M      C2/m
_cod_database_code               1562571
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.26879(3) 0.0000 0.67064(4) 0.01307(12) Uani 1 2 d S . .
Eu2 Eu 0.39372(3) 0.0000 0.04728(4) 0.01495(13) Uani 1 2 d S . .
Cd1 Cd 0.04587(5) 0.0000 0.31527(6) 0.01515(15) Uani 1 2 d S . .
Cd2 Cd 0.40805(5) 0.0000 0.34153(6) 0.01692(16) Uani 1 2 d S . .
As1 As 0.08043(6) 0.0000 0.11844(8) 0.01358(19) Uani 1 2 d S . .
As2 As 0.15973(6) 0.0000 0.81535(8) 0.0132(2) Uani 1 2 d S . .
As3 As 0.37301(6) 0.0000 0.52897(8) 0.01251(19) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
As3 Eu1 As3 87.62(6) . 7_546
As3 Eu1 As3 87.62(6) . 7_556
As3 Eu1 As3 91.75(6) 7_546 7_556
As3 Eu1 As1 92.19(6) . 7_556
As3 Eu1 As1 178.32(2) 7_546 7_556
As3 Eu1 As1 89.91(6) 7_556 7_556
As3 Eu1 As1 92.19(6) . 7_546
As3 Eu1 As1 89.91(6) 7_546 7_546
As3 Eu1 As1 178.32(2) 7_556 7_546
As1 Eu1 As1 88.44(6) 7_556 7_546
As3 Eu1 As2 179.65(3) . .
As3 Eu1 As2 92.13(6) 7_546 .
As3 Eu1 As2 92.13(6) 7_556 .
As1 Eu1 As2 88.06(6) 7_556 .
As1 Eu1 As2 88.06(6) 7_546 .
As3 Eu1 Cd2 133.09(3) . 7_546
As3 Eu1 Cd2 46.76(4) 7_546 7_546
As3 Eu1 Cd2 101.81(6) 7_556 7_546
As1 Eu1 Cd2 133.04(5) 7_556 7_546
As1 Eu1 Cd2 79.52(6) 7_546 7_546
As2 Eu1 Cd2 46.73(3) . 7_546
As3 Eu1 Cd2 133.09(3) . 7_556
As3 Eu1 Cd2 101.81(6) 7_546 7_556
As3 Eu1 Cd2 46.76(4) 7_556 7_556
As1 Eu1 Cd2 79.52(6) 7_556 7_556
As1 Eu1 Cd2 133.04(5) 7_546 7_556
As2 Eu1 Cd2 46.73(3) . 7_556
Cd2 Eu1 Cd2 76.60(6) 7_546 7_556
As3 Eu1 Cd1 79.64(8) . .
As3 Eu1 Cd1 46.28(3) 7_546 .
As3 Eu1 Cd1 46.28(3) 7_556 .
As1 Eu1 Cd1 135.31(3) 7_556 .
As1 Eu1 Cd1 135.31(3) 7_546 .
As2 Eu1 Cd1 100.01(8) . .
Cd2 Eu1 Cd1 75.10(5) 7_546 .
Cd2 Eu1 Cd1 75.10(5) 7_556 .
As3 Eu1 Cd1 46.16(3) . 7_556
As3 Eu1 Cd1 132.79(4) 7_546 7_556
As3 Eu1 Cd1 79.26(6) 7_556 7_556
As1 Eu1 Cd1 47.36(4) 7_556 7_556
As1 Eu1 Cd1 99.42(6) 7_546 7_556
As2 Eu1 Cd1 134.03(3) . 7_556
Cd2 Eu1 Cd1 178.768(11) 7_546 7_556
Cd2 Eu1 Cd1 104.61(6) 7_556 7_556
Cd1 Eu1 Cd1 105.36(5) . 7_556
As3 Eu1 Cd1 46.16(3) . 7_546
As3 Eu1 Cd1 79.26(6) 7_546 7_546
As3 Eu1 Cd1 132.79(4) 7_556 7_546
As1 Eu1 Cd1 99.42(6) 7_556 7_546
As1 Eu1 Cd1 47.36(4) 7_546 7_546
As2 Eu1 Cd1 134.03(3) . 7_546
Cd2 Eu1 Cd1 104.61(6) 7_546 7_546
Cd2 Eu1 Cd1 178.768(11) 7_556 7_546
Cd1 Eu1 Cd1 105.36(5) . 7_546
Cd1 Eu1 Cd1 74.17(6) 7_556 7_546
As3 Eu1 Eu2 127.82(5) . 1_556
As3 Eu1 Eu2 125.06(3) 7_546 1_556
As3 Eu1 Eu2 125.06(3) 7_556 1_556
As1 Eu1 Eu2 53.93(3) 7_556 1_556
As1 Eu1 Eu2 53.93(3) 7_546 1_556
As2 Eu1 Eu2 52.53(5) . 1_556
Cd2 Eu1 Eu2 83.47(3) 7_546 1_556
Cd2 Eu1 Eu2 83.47(3) 7_556 1_556
Cd1 Eu1 Eu2 152.54(3) . 1_556
Cd1 Eu1 Eu2 96.43(3) 7_556 1_556
Cd1 Eu1 Eu2 96.43(3) 7_546 1_556
As2 Eu2 As1 88.52(5) 1_554 7_545
As2 Eu2 As1 88.52(5) 1_554 7
As1 Eu2 As1 87.59(6) 7_545 7
As2 Eu2 As2 84.83(5) 1_554 7_556
As1 Eu2 As2 173.36(3) 7_545 7_556
As1 Eu2 As2 92.08(6) 7 7_556
As2 Eu2 As2 84.83(5) 1_554 7_546
As1 Eu2 As2 92.08(6) 7_545 7_546
As1 Eu2 As2 173.36(3) 7 7_546
As2 Eu2 As2 87.48(6) 7_556 7_546
As2 Eu2 As1 130.68(4) 1_554 3
As1 Eu2 As1 100.04(5) 7_545 3
As1 Eu2 As1 44.14(4) 7 3
As2 Eu2 As1 84.25(5) 7_556 3
As2 Eu2 As1 142.27(3) 7_546 3
As2 Eu2 As1 130.68(4) 1_554 3_545
As1 Eu2 As1 44.14(4) 7_545 3_545
As1 Eu2 As1 100.04(5) 7 3_545
As2 Eu2 As1 142.27(3) 7_556 3_545
As2 Eu2 As1 84.25(5) 7_546 3_545
As1 Eu2 As1 80.25(7) 3 3_545
As2 Eu2 Cd2 103.61(6) 1_554 .
As1 Eu2 Cd2 135.00(3) 7_545 .
As1 Eu2 Cd2 135.00(3) 7 .
As2 Eu2 Cd2 47.51(3) 7_556 .
As2 Eu2 Cd2 47.51(3) 7_546 .
As1 Eu2 Cd2 103.61(3) 3 .
As1 Eu2 Cd2 103.61(3) 3_545 .
As2 Eu2 Cd1 131.14(3) 1_554 3
As1 Eu2 Cd1 138.47(5) 7_545 3
As1 Eu2 Cd1 82.52(7) 7 3
As2 Eu2 Cd1 47.92(5) 7_556 3
As2 Eu2 Cd1 101.99(7) 7_546 3
As1 Eu2 Cd1 47.48(4) 3 3
As1 Eu2 Cd1 98.19(5) 3_545 3
Cd2 Eu2 Cd1 56.73(5) . 3
As2 Eu2 Cd1 131.14(3) 1_554 3_545
As1 Eu2 Cd1 82.52(7) 7_545 3_545
As1 Eu2 Cd1 138.47(5) 7 3_545
As2 Eu2 Cd1 101.99(7) 7_556 3_545
As2 Eu2 Cd1 47.92(5) 7_546 3_545
As1 Eu2 Cd1 98.19(5) 3 3_545
As1 Eu2 Cd1 47.48(4) 3_545 3_545
Cd2 Eu2 Cd1 56.73(5) . 3_545
Cd1 Eu2 Cd1 78.82(6) 3 3_545
As2 Eu2 Eu1 53.77(3) 1_554 1_554
As1 Eu2 Eu1 53.34(4) 7_545 1_554
As1 Eu2 Eu1 53.34(4) 7 1_554
As2 Eu2 Eu1 121.67(4) 7_556 1_554
As2 Eu2 Eu1 121.67(4) 7_546 1_554
As1 Eu2 Eu1 93.59(2) 3 1_554
As1 Eu2 Eu1 93.59(2) 3_545 1_554
Cd2 Eu2 Eu1 157.38(4) . 1_554
Cd1 Eu2 Eu1 135.69(3) 3 1_554
Cd1 Eu2 Eu1 135.69(3) 3_545 1_554
As2 Eu2 Eu2 120.37(7) 1_554 5_655
As1 Eu2 Eu2 52.46(3) 7_545 5_655
As1 Eu2 Eu2 52.46(3) 7 5_655
As2 Eu2 Eu2 131.61(3) 7_556 5_655
As2 Eu2 Eu2 131.61(3) 7_546 5_655
As1 Eu2 Eu2 47.58(4) 3 5_655
As1 Eu2 Eu2 47.58(4) 3_545 5_655
Cd2 Eu2 Eu2 136.03(3) . 5_655
Cd1 Eu2 Eu2 90.97(6) 3 5_655
Cd1 Eu2 Eu2 90.97(6) 3_545 5_655
Eu1 Eu2 Eu2 66.59(5) 1_554 5_655
As3 Cd1 As3 110.12(7) 7_556 7_546
As3 Cd1 As2 109.26(3) 7_556 5_556
As3 Cd1 As2 109.26(3) 7_546 5_556
As3 Cd1 As1 110.21(5) 7_556 .
As3 Cd1 As1 110.21(5) 7_546 .
As2 Cd1 As1 107.74(6) 5_556 .
As3 Cd1 Cd2 123.77(5) 7_556 3_445
As3 Cd1 Cd2 57.21(5) 7_546 3_445
As2 Cd1 Cd2 52.08(4) 5_556 3_445
As1 Cd1 Cd2 125.80(3) . 3_445
As3 Cd1 Cd2 57.21(5) 7_556 3_455
As3 Cd1 Cd2 123.77(5) 7_546 3_455
As2 Cd1 Cd2 52.08(4) 5_556 3_455
As1 Cd1 Cd2 125.80(3) . 3_455
Cd2 Cd1 Cd2 84.04(6) 3_445 3_455
As3 Cd1 Eu2 164.09(2) 7_556 3_445
As3 Cd1 Eu2 85.46(6) 7_546 3_445
As2 Cd1 Eu2 60.56(2) 5_556 3_445
As1 Cd1 Eu2 65.29(6) . 3_445
Cd2 Cd1 Eu2 61.44(5) 3_445 3_445
Cd2 Cd1 Eu2 111.83(6) 3_455 3_445
As3 Cd1 Eu2 85.46(6) 7_556 3_455
As3 Cd1 Eu2 164.09(2) 7_546 3_455
As2 Cd1 Eu2 60.56(2) 5_556 3_455
As1 Cd1 Eu2 65.29(6) . 3_455
Cd2 Cd1 Eu2 111.83(6) 3_445 3_455
Cd2 Cd1 Eu2 61.44(5) 3_455 3_455
Eu2 Cd1 Eu2 78.82(6) 3_445 3_455
As3 Cd1 Eu1 55.62(3) 7_556 .
As3 Cd1 Eu1 55.62(3) 7_546 .
As2 Cd1 Eu1 134.82(4) 5_556 .
As1 Cd1 Eu1 117.44(7) . .
Cd2 Cd1 Eu1 97.87(5) 3_445 .
Cd2 Cd1 Eu1 97.87(5) 3_455 .
Eu2 Cd1 Eu1 140.29(3) 3_445 .
Eu2 Cd1 Eu1 140.29(3) 3_455 .
As3 Cd1 Eu1 55.14(4) 7_556 7_556
As3 Cd1 Eu1 114.65(5) 7_546 7_556
As2 Cd1 Eu1 136.09(4) 5_556 7_556
As1 Cd1 Eu1 56.92(3) . 7_556
Cd2 Cd1 Eu1 171.64(2) 3_445 7_556
Cd2 Cd1 Eu1 100.49(6) 3_455 7_556
Eu2 Cd1 Eu1 122.19(5) 3_445 7_556
Eu2 Cd1 Eu1 76.53(5) 3_455 7_556
Eu1 Cd1 Eu1 74.64(5) . 7_556
As3 Cd1 Eu1 114.65(5) 7_556 7_546
As3 Cd1 Eu1 55.14(4) 7_546 7_546
As2 Cd1 Eu1 136.09(4) 5_556 7_546
As1 Cd1 Eu1 56.92(3) . 7_546
Cd2 Cd1 Eu1 100.49(6) 3_445 7_546
Cd2 Cd1 Eu1 171.64(2) 3_455 7_546
Eu2 Cd1 Eu1 76.53(5) 3_445 7_546
Eu2 Cd1 Eu1 122.19(5) 3_455 7_546
Eu1 Cd1 Eu1 74.64(5) . 7_546
Eu1 Cd1 Eu1 74.17(6) 7_556 7_546
As3 Cd2 As2 113.88(4) . 7_546
As3 Cd2 As2 113.88(4) . 7_556
As2 Cd2 As2 110.12(7) 7_546 7_556
As3 Cd2 As3 110.54(5) . 5_656
As2 Cd2 As3 103.73(3) 7_546 5_656
As2 Cd2 As3 103.73(3) 7_556 5_656
As3 Cd2 Cd2 58.90(7) . 5_656
As2 Cd2 Cd2 123.78(4) 7_546 5_656
As2 Cd2 Cd2 123.78(4) 7_556 5_656
As3 Cd2 Cd2 51.64(3) 5_656 5_656
As3 Cd2 Cd1 126.09(3) . 3
As2 Cd2 Cd1 119.58(5) 7_546 3
As2 Cd2 Cd1 52.86(5) 7_556 3
As3 Cd2 Cd1 50.90(4) 5_656 3
Cd2 Cd2 Cd1 85.22(5) 5_656 3
As3 Cd2 Cd1 126.09(3) . 3_545
As2 Cd2 Cd1 52.86(5) 7_546 3_545
As2 Cd2 Cd1 119.58(5) 7_556 3_545
As3 Cd2 Cd1 50.90(4) 5_656 3_545
Cd2 Cd2 Cd1 85.22(5) 5_656 3_545
Cd1 Cd2 Cd1 84.04(6) 3 3_545
As3 Cd2 Eu2 167.00(3) . .
As2 Cd2 Eu2 60.95(4) 7_546 .
As2 Cd2 Eu2 60.95(4) 7_556 .
As3 Cd2 Eu2 82.46(4) 5_656 .
Cd2 Cd2 Eu2 134.10(6) 5_656 .
Cd1 Cd2 Eu2 61.83(2) 3 .
Cd1 Cd2 Eu2 61.83(2) 3_545 .
As3 Cd2 Eu1 57.00(3) . 7_546
As2 Cd2 Eu1 58.90(4) 7_546 7_546
As2 Cd2 Eu1 119.98(5) 7_556 7_546
As3 Cd2 Eu1 136.07(4) 5_656 7_546
Cd2 Cd2 Eu1 101.68(5) 5_656 7_546
Cd1 Cd2 Eu1 172.52(2) 3 7_546
Cd1 Cd2 Eu1 99.31(6) 3_545 7_546
Eu2 Cd2 Eu1 113.81(2) . 7_546
As3 Cd2 Eu1 57.00(3) . 7_556
As2 Cd2 Eu1 119.98(5) 7_546 7_556
As2 Cd2 Eu1 58.90(4) 7_556 7_556
As3 Cd2 Eu1 136.07(4) 5_656 7_556
Cd2 Cd2 Eu1 101.68(5) 5_656 7_556
Cd1 Cd2 Eu1 99.31(6) 3 7_556
Cd1 Cd2 Eu1 172.52(2) 3_545 7_556
Eu2 Cd2 Eu1 113.81(2) . 7_556
Eu1 Cd2 Eu1 76.60(6) 7_546 7_556
As1 As1 Cd1 113.04(9) 5 .
As1 As1 Eu1 135.71(3) 5 7_556
Cd1 As1 Eu1 75.72(6) . 7_556
As1 As1 Eu1 135.71(3) 5 7_546
Cd1 As1 Eu1 75.72(6) . 7_546
Eu1 As1 Eu1 88.44(6) 7_556 7_546
As1 As1 Eu2 72.96(6) 5 7_545
Cd1 As1 Eu2 136.20(3) . 7_545
Eu1 As1 Eu2 131.95(5) 7_556 7_545
Eu1 As1 Eu2 72.73(6) 7_546 7_545
As1 As1 Eu2 72.96(6) 5 7
Cd1 As1 Eu2 136.20(3) . 7
Eu1 As1 Eu2 72.73(6) 7_556 7
Eu1 As1 Eu2 131.95(5) 7_546 7
Eu2 As1 Eu2 87.59(6) 7_545 7
As1 As1 Eu2 62.90(5) 5 3_445
Cd1 As1 Eu2 67.23(3) . 3_445
Eu1 As1 Eu2 142.91(4) 7_556 3_445
Eu1 As1 Eu2 84.20(6) 7_546 3_445
Eu2 As1 Eu2 79.96(5) 7_545 3_445
Eu2 As1 Eu2 135.86(4) 7 3_445
As1 As1 Eu2 62.90(5) 5 3_455
Cd1 As1 Eu2 67.23(3) . 3_455
Eu1 As1 Eu2 84.20(6) 7_556 3_455
Eu1 As1 Eu2 142.91(4) 7_546 3_455
Eu2 As1 Eu2 135.86(4) 7_545 3_455
Eu2 As1 Eu2 79.96(5) 7 3_455
Eu2 As1 Eu2 80.25(7) 3_445 3_455
Cd2 As2 Cd2 110.12(7) 7_546 7_556
Cd2 As2 Cd1 75.05(3) 7_546 5_556
Cd2 As2 Cd1 75.05(3) 7_556 5_556
Cd2 As2 Eu2 114.17(3) 7_546 1_556
Cd2 As2 Eu2 114.17(3) 7_556 1_556
Cd1 As2 Eu2 161.13(4) 5_556 1_556
Cd2 As2 Eu1 74.37(4) 7_546 .
Cd2 As2 Eu1 74.37(4) 7_556 .
Cd1 As2 Eu1 125.17(6) 5_556 .
Eu2 As2 Eu1 73.70(8) 1_556 .
Cd2 As2 Eu2 144.78(5) 7_546 7_556
Cd2 As2 Eu2 71.54(6) 7_556 7_556
Cd1 As2 Eu2 71.52(4) 5_556 7_556
Eu2 As2 Eu2 95.17(5) 1_556 7_556
Eu1 As2 Eu2 135.50(3) . 7_556
Cd2 As2 Eu2 71.54(6) 7_546 7_546
Cd2 As2 Eu2 144.78(5) 7_556 7_546
Cd1 As2 Eu2 71.52(4) 5_556 7_546
Eu2 As2 Eu2 95.17(5) 1_556 7_546
Eu1 As2 Eu2 135.50(3) . 7_546
Eu2 As2 Eu2 87.48(6) 7_556 7_546
Cd2 As3 Cd1 109.96(5) . 7_556
Cd2 As3 Cd1 109.96(5) . 7_546
Cd1 As3 Cd1 110.12(7) 7_556 7_546
Cd2 As3 Cd2 69.46(5) . 5_656
Cd1 As3 Cd2 71.89(3) 7_556 5_656
Cd1 As3 Cd2 71.89(3) 7_546 5_656
Cd2 As3 Eu1 163.44(4) . .
Cd1 As3 Eu1 78.69(5) 7_556 .
Cd1 As3 Eu1 78.69(5) 7_546 .
Cd2 As3 Eu1 127.10(6) 5_656 .
Cd2 As3 Eu1 76.24(5) . 7_546
Cd1 As3 Eu1 166.06(3) 7_556 7_546
Cd1 As3 Eu1 78.10(6) 7_546 7_546
Cd2 As3 Eu1 121.96(3) 5_656 7_546
Eu1 As3 Eu1 92.38(6) . 7_546
Cd2 As3 Eu1 76.24(5) . 7_556
Cd1 As3 Eu1 78.10(6) 7_556 7_556
Cd1 As3 Eu1 166.06(3) 7_546 7_556
Cd2 As3 Eu1 121.96(3) 5_656 7_556
Eu1 As3 Eu1 92.38(6) . 7_556
Eu1 As3 Eu1 91.75(6) 7_546 7_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 As3 3.0842(19) .
Eu1 As3 3.0961(17) 7_546
Eu1 As3 3.0961(17) 7_556
Eu1 As1 3.1867(17) 7_556
Eu1 As1 3.1867(17) 7_546
Eu1 As2 3.188(2) .
Eu1 Cd2 3.586(2) 7_546
Eu1 Cd2 3.586(2) 7_556
Eu1 Cd1 3.671(2) .
Eu1 Cd1 3.686(2) 7_556
Eu1 Cd1 3.686(2) 7_546
Eu1 Eu2 3.794(3) 1_556
Eu2 As2 3.137(2) 1_554
Eu2 As1 3.2111(18) 7_545
Eu2 As1 3.2111(18) 7
Eu2 As2 3.2143(17) 7_556
Eu2 As2 3.2143(17) 7_546
Eu2 As1 3.449(2) 3
Eu2 As1 3.449(2) 3_545
Eu2 Cd2 3.488(3) .
Eu2 Cd1 3.5005(19) 3
Eu2 Cd1 3.5005(19) 3_545
Eu2 Eu1 3.794(3) 1_554
Eu2 Eu2 4.283(3) 5_655
Cd1 As3 2.7111(17) 7_556
Cd1 As3 2.7111(17) 7_546
Cd1 As2 2.739(3) 5_556
Cd1 As1 2.798(2) .
Cd1 Cd2 3.3202(19) 3_445
Cd1 Cd2 3.3202(19) 3_455
Cd1 Eu2 3.5005(19) 3_445
Cd1 Eu2 3.5005(19) 3_455
Cd1 Eu1 3.686(2) 7_556
Cd1 Eu1 3.686(2) 7_546
Cd2 As3 2.689(2) .
Cd2 As2 2.7110(17) 7_546
Cd2 As2 2.7110(17) 7_556
Cd2 As3 2.937(3) 5_656
Cd2 Cd2 3.212(2) 5_656
Cd2 Cd1 3.3202(19) 3
Cd2 Cd1 3.3202(19) 3_545
Cd2 Eu1 3.586(2) 7_546
Cd2 Eu1 3.586(2) 7_556
As1 As1 2.512(2) 5
As1 Eu1 3.1867(17) 7_556
As1 Eu1 3.1867(17) 7_546
As1 Eu2 3.2111(18) 7_545
As1 Eu2 3.2111(18) 7
As1 Eu2 3.449(2) 3_445
As1 Eu2 3.449(2) 3_455
As2 Cd2 2.7110(17) 7_546
As2 Cd2 2.7110(17) 7_556
As2 Cd1 2.739(3) 5_556
As2 Eu2 3.137(2) 1_556
As2 Eu2 3.2143(17) 7_556
As2 Eu2 3.2143(17) 7_546
As3 Cd1 2.7111(17) 7_556
As3 Cd1 2.7111(17) 7_546
As3 Cd2 2.937(3) 5_656
As3 Eu1 3.0961(17) 7_546
As3 Eu1 3.0961(17) 7_556
