#------------------------------------------------------------------------------
#$Date: 2021-07-31 11:33:50 +0300 (Sat, 31 Jul 2021) $
#$Revision: 267858 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/42/1564293.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1564293
loop_
_publ_author_name
'Li, Xi-Li'
'Li, Junfeng'
'Wang, Ailing'
'Liu, Cai-Ming'
'Cui, Minghui'
'Zhang, Yi-Quan'
_publ_section_title
;
 Observation of field-induced single-ion magnet behavior in a mononuclear
 DyIII complex by co-crystallization of a square-planar CuII complex
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119718
_journal_paper_doi               10.1016/j.ica.2020.119718
_journal_volume                  510
_journal_year                    2020
_chemical_formula_moiety         'C15 H7 Dy F18 O8,C10 H14 Cu O4'
_chemical_formula_sum            'C25 H21 Cu Dy F18 O12'
_chemical_formula_weight         1081.46
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 111.796(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.4905(5)
_cell_length_b                   19.9973(7)
_cell_length_c                   16.5143(8)
_cell_measurement_reflns_used    7927
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.314
_cell_measurement_theta_min      3.256
_cell_volume                     3830.0(3)
_computing_cell_refinement       APEX2
_computing_data_collection       'APEX2 (Bruker, 2013)'
_computing_data_reduction        APEX2
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS (Bruker, 2000)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'PHOTON 100 CMOS detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0348
_diffrn_reflns_av_unetI/netI     0.0349
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            25684
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.096
_diffrn_reflns_theta_max         25.096
_diffrn_reflns_theta_min         3.276
_exptl_absorpt_coefficient_mu    2.632
_exptl_absorpt_correction_T_max  0.504
_exptl_absorpt_correction_T_min  0.414
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2012'
_exptl_crystal_colour            'Dark Green'
_exptl_crystal_density_diffrn    1.876
_exptl_crystal_description       block
_exptl_crystal_F_000             2096
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.26
_exptl_transmission_factor_max   0.5
_exptl_transmission_factor_min   0.4
_refine_diff_density_max         0.767
_refine_diff_density_min         -0.657
_refine_diff_density_rms         0.082
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     587
_refine_ls_number_reflns         6799
_refine_ls_number_restraints     39
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0569
_refine_ls_R_factor_gt           0.0389
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0604P)²+2.0187P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0987
_refine_ls_wR_factor_ref         0.1112
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5190
_reflns_number_total             6799
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            2.cif
_cod_data_source_block           2
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1564293
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.5
_shelx_estimated_absorpt_t_max   0.6
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F3B F 0.1899(8) 0.5065(4) 1.0269(5) 0.104(4) Uani 0.545(12) 1 d . . P A 2
C2 C 0.1784(6) 0.4248(3) 0.9200(4) 0.0707(16) Uani 1 1 d . U . . .
C3 C 0.0634(6) 0.4332(3) 0.8719(5) 0.0798(18) Uani 1 1 d . . . . .
H3 H 0.0297 0.4746 0.8725 0.096 Uiso 1 1 calc R U . . .
C4 C -0.0039(5) 0.3825(3) 0.8228(4) 0.0685(15) Uani 1 1 d . . . . .
C5 C -0.1323(7) 0.3958(4) 0.7754(7) 0.105(3) Uani 1 1 d . . . . .
C6 C 0.3949(7) 0.0736(4) 0.8297(7) 0.110(2) Uani 1 1 d D U . . .
C7 C 0.2973(5) 0.1266(3) 0.7977(5) 0.0749(17) Uani 1 1 d . . . . .
C8 C 0.2101(6) 0.1169(3) 0.7171(5) 0.0775(17) Uani 1 1 d . . . . .
H8 H 0.2094 0.0781 0.6859 0.093 Uiso 1 1 calc R U . . .
C9 C 0.1254(5) 0.1633(3) 0.6829(4) 0.0677(15) Uani 1 1 d . . . . .
C10 C 0.0344(7) 0.1507(4) 0.5922(5) 0.095(2) Uani 1 1 d . . . . .
C11 C 0.5994(6) 0.3118(5) 0.9244(5) 0.0890(19) Uani 1 1 d . U . . .
C12 C 0.4889(5) 0.2940(3) 0.9387(4) 0.0634(14) Uani 1 1 d . . . . .
C13 C 0.4990(5) 0.2734(3) 1.0210(4) 0.0797(19) Uani 1 1 d . . . . .
H13 H 0.5723 0.2724 1.0644 0.096 Uiso 1 1 calc R U . . .
C14 C 0.4069(6) 0.2540(3) 1.0430(4) 0.0699(15) Uani 1 1 d . . . . .
C15 C 0.4318(8) 0.2359(5) 1.1382(5) 0.101(2) Uani 1 1 d . U . . .
C16 C 1.0815(7) -0.1639(3) 0.9679(5) 0.096(2) Uani 1 1 d . . . . .
H16A H 1.0249 -0.1768 0.9915 0.145 Uiso 1 1 calc R U . . .
H16B H 1.1571 -0.1747 1.0089 0.145 Uiso 1 1 calc R U . . .
H16C H 1.0676 -0.1874 0.9143 0.145 Uiso 1 1 calc R U . . .
C17 C 1.0737(5) -0.0898(3) 0.9509(4) 0.0667(15) Uani 1 1 d . . . . .
C18 C 1.1614(5) -0.0480(3) 1.0006(4) 0.0724(16) Uani 1 1 d . . . . .
H18 H 1.2211 -0.0669 1.0472 0.087 Uiso 1 1 calc R U . . .
C19 C 1.1673(5) 0.0197(3) 0.9865(4) 0.0619(14) Uani 1 1 d . . . . .
C20 C 1.2717(6) 0.0599(4) 1.0411(4) 0.089(2) Uani 1 1 d . . . . .
H20A H 1.2519 0.0880 1.0806 0.133 Uiso 1 1 calc R U . . .
H20B H 1.2968 0.0872 1.0037 0.133 Uiso 1 1 calc R U . . .
H20C H 1.3327 0.0301 1.0737 0.133 Uiso 1 1 calc R U . . .
C21 C 0.5973(6) -0.0139(4) 0.6946(5) 0.091(2) Uani 1 1 d . . . . .
H21A H 0.6006 -0.0361 0.6440 0.136 Uiso 1 1 calc R U . . .
H21B H 0.5335 0.0167 0.6772 0.136 Uiso 1 1 calc R U . . .
H21C H 0.5875 -0.0465 0.7339 0.136 Uiso 1 1 calc R U . . .
C22 C 0.7077(5) 0.0240(3) 0.7394(4) 0.0674(15) Uani 1 1 d . . . . .
C23 C 0.7101(5) 0.0916(3) 0.7343(4) 0.0790(18) Uani 1 1 d . . . . .
H23 H 0.6398 0.1129 0.7063 0.095 Uiso 1 1 calc R U . . .
C24 C 0.8062(6) 0.1319(3) 0.7665(4) 0.0739(16) Uani 1 1 d . . . . .
C25 C 0.8006(7) 0.2049(4) 0.7483(6) 0.116(3) Uani 1 1 d . . . . .
H25A H 0.8499 0.2155 0.7172 0.173 Uiso 1 1 calc R U . . .
H25B H 0.8257 0.2291 0.8023 0.173 Uiso 1 1 calc R U . . .
H25C H 0.7227 0.2172 0.7136 0.173 Uiso 1 1 calc R U . . .
Cu1 Cu 0.94286(5) 0.02048(3) 0.85498(4) 0.05969(19) Uani 1 1 d . . . . .
Dy1 Dy 0.20775(2) 0.27308(2) 0.84726(2) 0.05386(11) Uani 1 1 d . . . . .
F4 F -0.1886(5) 0.3801(6) 0.8214(5) 0.246(5) Uani 1 1 d . . . . .
F5 F -0.1536(6) 0.4573(3) 0.7526(8) 0.273(6) Uani 1 1 d . . . . .
F6 F -0.1777(4) 0.3632(3) 0.7041(4) 0.1280(16) Uani 1 1 d . . . . .
F7B F 0.4907(6) 0.0994(4) 0.8332(15) 0.184(7) Uani 0.81(3) 1 d . U P B 2
F8B F 0.357(3) 0.0272(11) 0.875(2) 0.132(7) Uani 0.40(7) 1 d . U P B 2
F9 F 0.3890(6) 0.0276(3) 0.7749(5) 0.187(3) Uani 1 1 d D U . . .
F10 F 0.0323(4) 0.0888(2) 0.5650(3) 0.1182(15) Uani 1 1 d . . . . .
F11 F -0.0669(4) 0.1671(3) 0.5876(4) 0.160(3) Uani 1 1 d . . . . .
F12 F 0.0559(6) 0.1890(3) 0.5337(3) 0.157(2) Uani 1 1 d . . . . .
F13 F 0.6269(6) 0.2620(4) 0.8840(6) 0.178(3) Uani 1 1 d . U . . .
F14B F 0.5825(14) 0.348(2) 0.8587(14) 0.147(11) Uani 0.64(6) 1 d . . P C 2
F15B F 0.6926(18) 0.301(3) 0.990(2) 0.155(12) Uani 0.53(7) 1 d . . P C 2
F16 F 0.4892(10) 0.2785(5) 1.1905(4) 0.208(4) Uani 1 1 d . . . . .
F18B F 0.351(2) 0.209(2) 1.1497(11) 0.183(16) Uani 0.55(4) 1 d . . P D 2
O1 O 0.2374(3) 0.3755(2) 0.9213(3) 0.0741(11) Uani 1 1 d . . . . .
O2 O 0.0282(3) 0.32472(19) 0.8122(3) 0.0692(10) Uani 1 1 d . . . . .
O3 O 0.3095(3) 0.1735(2) 0.8493(3) 0.0779(11) Uani 1 1 d . . . . .
O4 O 0.1120(3) 0.21808(18) 0.7158(3) 0.0665(10) Uani 1 1 d . . . . .
O5 O 0.3988(3) 0.3002(2) 0.8732(3) 0.0662(10) Uani 1 1 d . . . . .
O6 O 0.3047(3) 0.2489(2) 0.9944(3) 0.0697(10) Uani 1 1 d . . . . .
O7 O 0.1988(3) 0.34815(18) 0.7337(2) 0.0665(10) Uani 1 1 d . . . . .
H7A H 0.1367 0.3517 0.6892 0.080 Uiso 1 1 d R U . . .
H7B H 0.2575 0.3713 0.7373 0.080 Uiso 1 1 d R U . . .
O8 O 0.0952(3) 0.1941(2) 0.8890(3) 0.0743(11) Uani 1 1 d . . . . .
H8A H 0.0258 0.1868 0.8556 0.089 Uiso 1 1 d R U . . .
H8B H 0.1241 0.1735 0.9373 0.089 Uiso 1 1 d R U . . .
O9 O 0.9826(3) -0.07028(18) 0.8899(3) 0.0705(10) Uani 1 1 d . . . . .
O10 O 1.0890(3) 0.05407(19) 0.9304(3) 0.0681(10) Uani 1 1 d . . . . .
O11 O 0.7951(3) -0.01192(19) 0.7815(3) 0.0693(10) Uani 1 1 d . . . . .
O12 O 0.9067(3) 0.10989(19) 0.8132(3) 0.0705(10) Uani 1 1 d . . . . .
F2 F 0.2181(10) 0.5392(4) 0.9417(7) 0.244(5) Uani 1 1 d . U . . .
F1 F 0.3423(6) 0.4911(4) 0.9829(6) 0.193(3) Uani 1 1 d . U . . .
C1 C 0.2444(10) 0.4791(5) 0.9896(9) 0.130(3) Uani 1 1 d . U . . .
F3A F 0.3010(9) 0.4552(5) 1.0642(5) 0.107(5) Uani 0.455(12) 1 d . . P A 1
F17A F 0.5288(15) 0.2008(12) 1.1708(9) 0.153(5) Uani 0.5 1 d . . P D .
F17B F 0.441(3) 0.1750(9) 1.1513(11) 0.183(11) Uani 0.5 1 d . . P D .
F18A F 0.344(3) 0.255(2) 1.1615(17) 0.191(14) Uani 0.45(4) 1 d . U P D 1
F15A F 0.678(3) 0.335(3) 0.988(2) 0.136(13) Uani 0.47(7) 1 d . . P C 1
F14A F 0.601(3) 0.3760(13) 0.907(6) 0.15(2) Uani 0.36(6) 1 d . . P C 1
F8A F 0.421(5) 0.055(3) 0.909(3) 0.19(2) Uani 0.60(7) 1 d . . P B 1
F7A F 0.476(3) 0.0920(12) 0.895(2) 0.079(12) Uani 0.19(3) 1 d . U P B 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 F3B F2 54.8(8) . .
O1 C2 C3 127.1(6) . .
O1 C2 C1 113.1(7) . .
C3 C2 C1 119.5(7) . .
C2 C3 C4 122.1(6) . .
C2 C3 H3 118.9 . .
C4 C3 H3 118.9 . .
O2 C4 C3 127.2(6) . .
O2 C4 C5 114.8(6) . .
C3 C4 C5 118.0(6) . .
F4 C5 F6 105.9(8) . .
F4 C5 F5 108.4(8) . .
F6 C5 F5 104.3(9) . .
F4 C5 C4 111.4(8) . .
F6 C5 C4 113.9(6) . .
F5 C5 C4 112.5(7) . .
F7A C6 F9 130.5(15) . .
F7A C6 F8A 51(4) . .
F9 C6 F8A 117(3) . .
F9 C6 F7B 97.4(10) . .
F9 C6 F8B 87.6(13) . .
F7B C6 F8B 138(2) . .
F7A C6 C7 112.5(13) . .
F9 C6 C7 114.9(8) . .
F8A C6 C7 114.3(9) . .
F7B C6 C7 110.0(8) . .
F8B C6 C7 105.1(15) . .
O3 C7 C8 128.2(6) . .
O3 C7 C6 113.8(7) . .
C8 C7 C6 118.0(6) . .
C9 C8 C7 121.1(6) . .
C9 C8 H8 119.4 . .
C7 C8 H8 119.4 . .
O4 C9 C8 128.3(6) . .
O4 C9 C10 113.3(6) . .
C8 C9 C10 118.4(6) . .
F11 C10 F10 109.1(7) . .
F11 C10 F12 105.6(8) . .
F10 C10 F12 106.0(7) . .
F11 C10 C9 112.1(7) . .
F10 C10 C9 113.8(7) . .
F12 C10 C9 109.8(6) . .
F14B C11 F15B 130(2) . .
F15A C11 F13 117(2) . .
F14B C11 F13 89.7(19) . .
F15B C11 F13 89(2) . .
F15A C11 F14A 75(4) . .
F13 C11 F14A 127(3) . .
F15A C11 C12 115.7(16) . .
F14B C11 C12 113.3(9) . .
F15B C11 C12 114.8(15) . .
F13 C11 C12 108.9(7) . .
F14A C11 C12 110.1(16) . .
O5 C12 C13 127.4(5) . .
O5 C12 C11 114.9(6) . .
C13 C12 C11 117.7(6) . .
C12 C13 C14 124.1(6) . .
C12 C13 H13 117.9 . .
C14 C13 H13 117.9 . .
O6 C14 C13 127.7(6) . .
O6 C14 C15 114.6(6) . .
C13 C14 C15 117.7(6) . .
F18B C15 F16 119.7(18) . .
F18B C15 F17B 64(2) . .
F16 C15 F17B 124.4(13) . .
F18B C15 F17A 113(2) . .
F16 C15 F17A 82.9(11) . .
F17B C15 F17A 52.8(13) . .
F16 C15 F18A 86(2) . .
F17B C15 F18A 105(3) . .
F17A C15 F18A 138.4(16) . .
F18B C15 C14 113.6(10) . .
F16 C15 C14 113.6(8) . .
F17B C15 C14 112.5(12) . .
F17A C15 C14 110.5(9) . .
F18A C15 C14 110.7(14) . .
C17 C16 H16A 109.5 . .
C17 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C17 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O9 C17 C18 124.4(5) . .
O9 C17 C16 115.4(6) . .
C18 C17 C16 120.2(6) . .
C17 C18 C19 125.1(6) . .
C17 C18 H18 117.5 . .
C19 C18 H18 117.5 . .
O10 C19 C18 125.3(6) . .
O10 C19 C20 114.0(6) . .
C18 C19 C20 120.6(6) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 H21A 109.5 . .
C22 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C22 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O11 C22 C23 124.2(6) . .
O11 C22 C21 115.2(6) . .
C23 C22 C21 120.6(6) . .
C22 C23 C24 126.5(6) . .
C22 C23 H23 116.7 . .
C24 C23 H23 116.7 . .
O12 C24 C23 123.3(6) . .
O12 C24 C25 114.9(6) . .
C23 C24 C25 121.8(6) . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
O11 Cu1 O12 92.58(17) . .
O11 Cu1 O10 178.53(17) . .
O12 Cu1 O10 86.96(17) . .
O11 Cu1 O9 87.20(17) . .
O12 Cu1 O9 175.84(18) . .
O10 Cu1 O9 93.37(17) . .
O5 Dy1 O6 75.86(13) . .
O5 Dy1 O4 114.73(14) . .
O6 Dy1 O4 139.72(14) . .
O5 Dy1 O2 140.04(14) . .
O6 Dy1 O2 115.46(14) . .
O4 Dy1 O2 82.19(14) . .
O5 Dy1 O1 75.37(14) . .
O6 Dy1 O1 73.53(15) . .
O4 Dy1 O1 145.71(14) . .
O2 Dy1 O1 72.22(14) . .
O5 Dy1 O3 71.55(15) . .
O6 Dy1 O3 74.99(15) . .
O4 Dy1 O3 72.63(14) . .
O2 Dy1 O3 147.09(14) . .
O1 Dy1 O3 138.72(14) . .
O5 Dy1 O7 75.07(13) . .
O6 Dy1 O7 144.11(14) . .
O4 Dy1 O7 72.83(13) . .
O2 Dy1 O7 76.41(13) . .
O1 Dy1 O7 79.13(14) . .
O3 Dy1 O7 114.39(14) . .
O5 Dy1 O8 141.00(14) . .
O6 Dy1 O8 72.20(14) . .
O4 Dy1 O8 78.60(15) . .
O2 Dy1 O8 75.49(14) . .
O1 Dy1 O8 115.13(15) . .
O3 Dy1 O8 78.97(15) . .
O7 Dy1 O8 142.11(13) . .
C15 F16 F17A 50.9(7) . .
C15 F16 F18A 49.5(11) . .
F17A F16 F18A 92.4(14) . .
C15 F18B F17B 58.5(15) . .
C2 O1 Dy1 135.7(4) . .
C4 O2 Dy1 134.3(4) . .
C7 O3 Dy1 134.7(4) . .
C9 O4 Dy1 135.0(4) . .
C12 O5 Dy1 132.2(4) . .
C14 O6 Dy1 132.3(4) . .
Dy1 O7 H7A 119.8 . .
Dy1 O7 H7B 120.2 . .
H7A O7 H7B 120.0 . .
Dy1 O8 H8A 119.8 . .
Dy1 O8 H8B 120.1 . .
H8A O8 H8B 120.0 . .
C17 O9 Cu1 126.0(4) . .
C19 O10 Cu1 125.2(4) . .
C22 O11 Cu1 125.8(4) . .
C24 O12 Cu1 125.9(4) . .
C1 F2 F3B 44.4(6) . .
C1 F2 F1 47.1(6) . .
F3B F2 F1 83.9(6) . .
C1 F1 F2 53.1(7) . .
C1 F1 F3A 45.8(7) . .
F2 F1 F3A 93.0(7) . .
F3B C1 F1 133.7(8) . .
F3A C1 F1 87.1(10) . .
F3B C1 F2 80.8(9) . .
F3A C1 F2 142.9(9) . .
F1 C1 F2 79.8(9) . .
F3B C1 C2 116.4(9) . .
F3A C1 C2 113.8(9) . .
F1 C1 C2 108.8(9) . .
F2 C1 C2 103.3(9) . .
C1 F3A F1 47.1(7) . .
F17B F17A C15 59.5(14) . .
F17B F17A F16 99(2) . .
C15 F17A F16 46.2(8) . .
F17A F17B C15 67.8(14) . .
F17A F17B F18B 120(3) . .
C15 F17B F18B 57.3(16) . .
C15 F18A F16 44.5(14) . .
C11 F15A F14A 55(2) . .
C11 F14A F15A 50.2(19) . .
F7A F8A C6 62(2) . .
F8A F7A C6 67(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
F3B C1 1.206(12) .
F3B F2 1.701(12) .
C2 O1 1.227(7) .
C2 C3 1.370(9) .
C2 C1 1.572(10) .
C3 C4 1.373(9) .
C3 H3 0.9300 .
C4 O2 1.256(7) .
C4 C5 1.525(9) .
C5 F4 1.252(11) .
C5 F6 1.280(8) .
C5 F5 1.285(11) .
C6 F7A 1.23(3) .
C6 F9 1.273(8) .
C6 F8A 1.28(2) .
C6 F7B 1.285(12) .
C6 F8B 1.38(3) .
C6 C7 1.552(10) .
C7 O3 1.238(7) .
C7 C8 1.385(9) .
C8 C9 1.362(8) .
C8 H8 0.9300 .
C9 O4 1.262(6) .
C9 C10 1.528(9) .
C10 F11 1.281(9) .
C10 F10 1.315(8) .
C10 F12 1.337(9) .
C11 F15A 1.23(2) .
C11 F14B 1.261(19) .
C11 F15B 1.28(2) .
C11 F13 1.314(10) .
C11 F14A 1.32(2) .
C11 C12 1.526(8) .
C12 O5 1.244(7) .
C12 C13 1.382(9) .
C13 C14 1.384(9) .
C13 H13 0.9300 .
C14 O6 1.234(7) .
C14 C15 1.528(10) .
C15 F18B 1.220(16) .
C15 F16 1.235(10) .
C15 F17B 1.236(19) .
C15 F17A 1.328(17) .
C15 F18A 1.34(3) .
C16 C17 1.504(8) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 O9 1.269(7) .
C17 C18 1.380(8) .
C18 C19 1.381(8) .
C18 H18 0.9300 .
C19 O10 1.270(7) .
C19 C20 1.512(8) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C22 1.505(8) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 O11 1.276(7) .
C22 C23 1.355(9) .
C23 C24 1.379(9) .
C23 H23 0.9300 .
C24 O12 1.283(7) .
C24 C25 1.487(9) .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
Cu1 O11 1.906(4) .
Cu1 O12 1.909(4) .
Cu1 O10 1.910(4) .
Cu1 O9 1.913(4) .
Dy1 O5 2.327(4) .
Dy1 O6 2.328(4) .
Dy1 O4 2.329(4) .
Dy1 O2 2.338(4) .
Dy1 O1 2.344(4) .
Dy1 O3 2.356(4) .
Dy1 O7 2.372(3) .
Dy1 O8 2.380(4) .
F16 F17A 1.70(2) .
F16 F18A 1.76(5) .
F18B F17B 1.31(5) .
O7 H7A 0.8501 .
O7 H7B 0.8501 .
O8 H8A 0.8497 .
O8 H8B 0.8500 .
F2 C1 1.408(14) .
F2 F1 1.735(12) .
F1 C1 1.291(12) .
F1 F3A 1.761(12) .
C1 F3A 1.265(14) .
F17A F17B 1.14(2) .
F15A F14A 1.55(8) .
F8A F7A 1.09(7) .
