#------------------------------------------------------------------------------
#$Date: 2021-07-31 12:14:03 +0300 (Sat, 31 Jul 2021) $
#$Revision: 267867 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/43/1564301.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1564301
loop_
_publ_author_name
'Kubasov, A.S.'
'Matveev, E. Yu.'
'Klyukin, I.N.'
'Nichugovskiy, A.I.'
'Zhizhin, K. Yu'
'Kuznetsov, N.T.'
_publ_section_title
;
 Silver(I) complexes with substituted derivatives of the boron cluster
 anions as ligands
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119749
_journal_paper_doi               10.1016/j.ica.2020.119749
_journal_volume                  510
_journal_year                    2020
_chemical_formula_moiety         'C74 H72 Ag2 B10 O2 P4'
_chemical_formula_sum            'C74 H72 Ag2 B10 O2 P4'
_chemical_formula_weight         1441.03
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_cell_angle_alpha                90
_cell_angle_beta                 97.235(15)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.647(5)
_cell_length_b                   14.796(6)
_cell_length_c                   37.721(15)
_cell_measurement_reflns_used    35
_cell_measurement_temperature    293
_cell_measurement_theta_max      32.230
_cell_measurement_theta_min      27.954
_cell_volume                     7556(5)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_diffrn_ambient_temperature      293
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0419
_diffrn_reflns_av_unetI/netI     0.0871
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       1
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       1
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       48
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_number            20035
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.002
_diffrn_reflns_theta_min         2.039
_exptl_absorpt_coefficient_mu    0.645
_exptl_absorpt_correction_T_max  0.6534
_exptl_absorpt_correction_T_min  0.6014
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.267
_exptl_crystal_description       block
_exptl_crystal_F_000             2944
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.563
_refine_diff_density_min         -0.746
_refine_diff_density_rms         0.086
_refine_ls_extinction_coef       0.00098(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_goodness_of_fit_ref   0.964
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     890
_refine_ls_number_reflns         16495
_refine_ls_number_restraints     270
_refine_ls_restrained_S_all      0.957
_refine_ls_R_factor_all          0.1156
_refine_ls_R_factor_gt           0.0627
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0841P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1586
_refine_ls_wR_factor_ref         0.1911
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9334
_reflns_number_total             16495
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            4.cif
_cod_data_source_block           1
_cod_database_code               1564301
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.909
_shelx_estimated_absorpt_t_min   0.801
_olex2_refinement_description
;
1. Shared sites
{C49B, C49A, C49}
{C67, C67B, C67A}
{C68A, C68}
{H68A, H68}
{H72B, H72A}
2. Others
 Fixed Sof: C49(0.39) C50(0.39) H50(0.39) C51(0.39) H51(0.39) C52(0.39)
 H52(0.39) C53(0.39) H53(0.39) C54(0.39) H54(0.39) C49A(0.45) C50A(0.45)
 H50A(0.45) C51A(0.45) H51A(0.45) C52A(0.45) H52A(0.45) C53A(0.45) H53A(0.45)
 C54A(0.45) H54A(0.45) C49B(0.16) C50B(0.16) H50B(0.16) C51B(0.16) H51B(0.16)
 C52B(0.16) H52B(0.16) C53B(0.16) H53B(0.16) C54B(0.16) H54B(0.16) C67(0.3)
 C68(0.3) H68(0.3) C69(0.3) H69(0.3) C70(0.3) H70(0.3) C71(0.3) H71(0.3)
 C72(0.3) H72(0.3) C67A(0.51) C68A(0.51) H68A(0.51) C69A(0.51) H69A(0.51)
 C70A(0.51) H70A(0.51) C71A(0.51) H71A(0.51) C72A(0.51) H72A(0.51) C67B(0.19)
 C68B(0.19) H68B(0.19) C69B(0.19) H69B(0.19) C70B(0.19) H70B(0.19) C71B(0.19)
 H71B(0.19) C72B(0.19) H72B(0.19)
 Fixed Uiso: H2(0.093) H3(0.097) H4(0.094) H5(0.09) H6(0.077) H8(0.109)
 H9(0.143) H10(0.142) H11(0.147) H12(0.118) H14(0.103) H15(0.13) H16(0.121)
 H17(0.15) H18(0.133) H20(0.091) H21(0.106) H22(0.11) H23(0.125) H24(0.09)
 H26(0.104) H27(0.13) H28(0.145) H29(0.125) H30(0.096) H32(0.077) H33(0.088)
 H34(0.104) H35(0.12) H36(0.095) H38(0.104) H39(0.149) H40(0.152) H41(0.141)
 H42(0.1) H44(0.124) H45(0.155) H46(0.168) H47(0.164) H48(0.129) H50(0.136)
 H51(0.136) H52(0.108) H53(0.128) H54(0.11) H50A(0.136) H51A(0.136) H52A(0.108)
 H53A(0.128) H54A(0.11) H50B(0.136) H51B(0.136) H52B(0.108) H53B(0.128)
 H54B(0.11) H56(0.091) H57(0.114) H58(0.125) H59(0.124) H60(0.1) H62(0.11)
 H63(0.153) H64(0.156) H65(0.132) H66(0.104) H68(0.118) H69(0.158) H70(0.156)
 H71(0.138) H72(0.115) H68A(0.118) H69A(0.158) H70A(0.156) H71A(0.138)
 H72A(0.115) H68B(0.118) H69B(0.158) H70B(0.156) H71B(0.138) H72B(0.115)
 H74A(0.155) H74B(0.155) H74C(0.155) H1(0.077) H3A(0.08) H4A(0.074) H5A(0.062)
 H6A(0.066) H7(0.07) H8A(0.062) H9A(0.062) H10A(0.066)
 Fixed X: H2(0.214922) H3(0.31691) H4(0.469798) H5(0.526558) H6(0.425251)
 H8(0.133172) H9(-0.032809) H10(-0.156898) H11(-0.120672) H12(0.041226)
 H14(0.294751) H15(0.294862) H16(0.243338) H17(0.189188) H18(0.181753)
 H20(0.006417) H21(-0.123936) H22(-0.145978) H23(-0.038374) H24(0.090702) H26(-
 0.020778) H27(-0.088761) H28(-0.001552) H29(0.159278) H30(0.226818)
 H32(0.134998) H33(0.217431) H34(0.360611) H35(0.420213) H36(0.339109)
 H38(0.806874) H39(0.932493) H40(1.024985) H41(0.995254) H42(0.867118)
 H44(0.65518) H45(0.717618) H46(0.876503) H47(0.981913) H48(0.919697)
 H50(0.750566) H51(0.715786) H52(0.647448) H53(0.611473) H54(0.644358)
 H50A(0.770874) H51A(0.751156) H52A(0.672409) H53A(0.611467) H54A(0.627499)
 H50B(0.787679) H51B(0.767462) H52B(0.671974) H53B(0.592616) H54B(0.611309)
 H56(0.244079) H57(0.22676) H58(0.347699) H59(0.492481) H60(0.516372)
 H62(0.212178) H63(0.067064) H64(0.048647) H65(0.176254) H66(0.325332)
 H68(0.441588) H69(0.441609) H70(0.401948) H71(0.363394) H72(0.365485)
 H68A(0.444588) H69A(0.416057) H70A(0.353348) H71A(0.325094) H72A(0.355605)
 H68B(0.469915) H69B(0.530374) H70B(0.501568) H71B(0.411143) H72B(0.350802)
 H74A(0.489292) H74B(0.389781) H74C(0.448953) H1(0.646594) H3A(0.719172)
 H4A(0.717124) H5A(0.487741) H6A(0.548469) H7(0.708874) H8A(0.545582)
 H9A(0.383313) H10A(0.502097)
 Fixed Y: H2(0.977997) H3(1.074123) H4(1.112157) H5(1.05556) H6(0.958417)
 H8(1.048472) H9(1.094911) H10(0.987932) H11(0.839956) H12(0.793735)
 H14(0.696114) H15(0.555939) H16(0.541918) H17(0.666388) H18(0.806664)
 H20(0.875488) H21(0.7752) H22(0.695374) H23(0.713905) H24(0.821145)
 H26(1.02615) H27(1.164163) H28(1.264494) H29(1.229936) H30(1.090199)
 H32(1.049178) H33(1.072926) H34(0.997479) H35(0.890059) H36(0.866201)
 H38(0.6139) H39(0.651769) H40(0.539393) H41(0.38776) H42(0.349247)
 H44(0.511897) H45(0.507443) H46(0.464528) H47(0.438452) H48(0.434459)
 H50(0.264299) H51(0.119053) H52(0.097289) H53(0.218008) H54(0.366662)
 H50A(0.289128) H51A(0.135938) H52A(0.081482) H53A(0.181074) H54A(0.337572)
 H50B(0.31453) H51B(0.159298) H52B(0.082623) H53B(0.155927) H54B(0.31377)
 H56(0.328817) H57(0.237794) H58(0.236163) H59(0.313663) H60(0.396341)
 H62(0.416882) H63(0.497701) H64(0.632688) H65(0.687405) H66(0.606961)
 H68(0.462368) H69(0.373967) H70(0.223557) H71(0.158054) H72(0.246559)
 H68A(0.463133) H69A(0.385834) H70A(0.241653) H71A(0.170258) H72A(0.247694)
 H68B(0.462216) H69B(0.369903) H70B(0.217235) H71B(0.153825) H72B(0.246017)
 H74A(1.139868) H74B(1.093434) H74C(1.150713) H1(0.938902) H3A(0.895984)
 H4A(0.750406) H5A(0.805128) H6A(0.83739) H7(0.699036) H8A(0.635284)
 H9A(0.777544) H10A(0.648497)
 Fixed Z: H2(0.257527) H3(0.294592) H4(0.279825) H5(0.229217) H6(0.191601)
 H8(0.184714) H9(0.174729) H10(0.174227) H11(0.181973) H12(0.192408)
 H14(0.175886) H15(0.204079) H16(0.259249) H17(0.286316) H18(0.258709)
 H20(0.109239) H21(0.097676) H22(0.045801) H23(0.003688) H24(0.012749)
 H26(0.053218) H27(0.064009) H28(0.102667) H29(0.127989) H30(0.116991)
 H32(0.010583) H33(-0.038695) H34(-0.043989) H35(-0.002202) H36(0.047601)
 H38(0.14962) H39(0.194571) H40(0.225089) H41(0.21048) H42(0.165062)
 H44(0.044707) H45(-0.010457) H46(-0.012648) H47(0.040357) H48(0.094365)
 H50(0.081046) H51(0.098839) H52(0.150616) H53(0.185224) H54(0.167498)
 H50A(0.080486) H51A(0.088993) H52A(0.134409) H53A(0.173738) H54A(0.165382)
 H50B(0.082421) H51B(0.07592) H52B(0.111516) H53B(0.15362) H54B(0.160373)
 H56(0.073721) H57(0.02365) H58(-0.014067) H59(0.000983) H60(0.054044)
 H62(0.139649) H63(0.136831) H64(0.106112) H65(0.07988) H66(0.081137)
 H68(0.18668) H69(0.237446) H70(0.231578) H71(0.176226) H72(0.124294)
 H68A(0.186014) H69A(0.237145) H70A(0.232146) H71A(0.177566) H72A(0.125362)
 H68B(0.182116) H69B(0.229426) H70B(0.226378) H71B(0.176847) H72B(0.128072)
 H74A(0.054881) H74B(0.061297) H74C(0.091767) H1(0.175269) H3A(0.108517)
 H4A(0.173602) H5A(0.182783) H6A(0.057093) H7(0.098489) H8A(0.151382)
 H9A(0.111236) H10A(0.073676)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.27916(3) 0.87870(3) 0.12908(2) 0.05863(14) Uani 1 1 d . . . . .
Ag2 Ag 0.55947(3) 0.53494(3) 0.11614(2) 0.06409(15) Uani 1 1 d . . . . .
P1 P 0.23538(10) 0.87671(10) 0.19046(3) 0.0562(3) Uani 1 1 d . . . . .
P2 P 0.16882(10) 0.93374(9) 0.07512(3) 0.0524(3) Uani 1 1 d . . . . .
P3 P 0.72136(11) 0.45416(10) 0.11672(4) 0.0631(4) Uani 1 1 d . . . . .
P4 P 0.40386(10) 0.44197(9) 0.11106(4) 0.0583(3) Uani 1 1 d . . . . .
O1 O 0.3964(3) 1.0049(3) 0.12260(11) 0.0714(10) Uani 1 1 d . . . . .
O2 O 0.5099(3) 1.0278(3) 0.08571(12) 0.0814(13) Uani 1 1 d . . . . .
C1 C 0.3088(4) 0.9565(4) 0.22061(13) 0.0584(13) Uani 1 1 d D . . . .
C2 C 0.2772(4) 0.9928(4) 0.25169(15) 0.0772(17) Uani 1 1 d D . . . .
H2 H 0.214922 0.977997 0.257527 0.093 Uiso 1 1 calc R . . . .
C3 C 0.3381(5) 1.0509(4) 0.27396(15) 0.0809(18) Uani 1 1 d D . . . .
H3 H 0.316910 1.074123 0.294592 0.097 Uiso 1 1 calc R . . . .
C4 C 0.4298(5) 1.0733(4) 0.26501(15) 0.0783(17) Uani 1 1 d D . . . .
H4 H 0.469798 1.112157 0.279825 0.094 Uiso 1 1 calc R . . . .
C5 C 0.4642(4) 1.0397(4) 0.23468(15) 0.0747(16) Uani 1 1 d D . . . .
H5 H 0.526558 1.055560 0.229217 0.090 Uiso 1 1 calc R . . . .
C6 C 0.4032(4) 0.9811(4) 0.21218(14) 0.0645(14) Uani 1 1 d D . . . .
H6 H 0.425251 0.958417 0.191601 0.077 Uiso 1 1 calc R . . . .
C7 C 0.1059(4) 0.9149(4) 0.18954(15) 0.0676(15) Uani 1 1 d . . . . .
C8 C 0.0828(5) 1.0060(5) 0.18429(19) 0.090(2) Uani 1 1 d . . . . .
H8 H 0.133172 1.048472 0.184714 0.109 Uiso 1 1 calc R . . . .
C9 C -0.0171(7) 1.0342(7) 0.1783(2) 0.119(3) Uani 1 1 d . . . . .
H9 H -0.032809 1.094911 0.174729 0.143 Uiso 1 1 calc R . . . .
C10 C -0.0912(6) 0.9697(8) 0.1779(2) 0.118(3) Uani 1 1 d . . . . .
H10 H -0.156898 0.987932 0.174227 0.142 Uiso 1 1 calc R . . . .
C11 C -0.0701(6) 0.8823(7) 0.1827(3) 0.122(3) Uani 1 1 d . . . . .
H11 H -0.120672 0.839956 0.181973 0.147 Uiso 1 1 calc R . . . .
C12 C 0.0276(5) 0.8548(5) 0.1887(2) 0.098(2) Uani 1 1 d . . . . .
H12 H 0.041226 0.793735 0.192408 0.118 Uiso 1 1 calc R . . . .
C13 C 0.2399(4) 0.7676(4) 0.21409(14) 0.0618(13) Uani 1 1 d . . . . .
C14 C 0.2727(5) 0.6916(5) 0.19816(18) 0.0861(19) Uani 1 1 d . . . . .
H14 H 0.294751 0.696114 0.175886 0.103 Uiso 1 1 calc R . . . .
C15 C 0.2731(6) 0.6067(5) 0.2153(2) 0.108(3) Uani 1 1 d . . . . .
H15 H 0.294862 0.555939 0.204079 0.130 Uiso 1 1 calc R . . . .
C16 C 0.2422(6) 0.5979(6) 0.2480(2) 0.101(2) Uani 1 1 d . . . . .
H16 H 0.243338 0.541918 0.259249 0.121 Uiso 1 1 calc R . . . .
C17 C 0.2098(8) 0.6720(7) 0.2638(2) 0.125(3) Uani 1 1 d . . . . .
H17 H 0.189188 0.666388 0.286316 0.150 Uiso 1 1 calc R . . . .
C18 C 0.2063(7) 0.7572(5) 0.24745(17) 0.111(3) Uani 1 1 d . . . . .
H18 H 0.181753 0.806664 0.258709 0.133 Uiso 1 1 calc R . . . .
C19 C 0.0624(4) 0.8589(4) 0.06229(14) 0.0570(12) Uani 1 1 d . . . . .
C20 C -0.0025(4) 0.8443(5) 0.08767(17) 0.0758(16) Uani 1 1 d . . . . .
H20 H 0.006417 0.875488 0.109239 0.091 Uiso 1 1 calc R . . . .
C21 C -0.0805(5) 0.7833(5) 0.0808(2) 0.088(2) Uani 1 1 d . . . . .
H21 H -0.123936 0.775200 0.097676 0.106 Uiso 1 1 calc R . . . .
C22 C -0.0938(5) 0.7360(5) 0.0500(2) 0.092(2) Uani 1 1 d . . . . .
H22 H -0.145978 0.695374 0.045801 0.110 Uiso 1 1 calc R . . . .
C23 C -0.0297(6) 0.7479(5) 0.0246(2) 0.104(2) Uani 1 1 d . . . . .
H23 H -0.038374 0.713905 0.003688 0.125 Uiso 1 1 calc R . . . .
C24 C 0.0492(5) 0.8115(4) 0.03013(16) 0.0752(16) Uani 1 1 d . . . . .
H24 H 0.090702 0.821145 0.012749 0.090 Uiso 1 1 calc R . . . .
C25 C 0.1105(4) 1.0426(4) 0.08335(14) 0.0621(13) Uani 1 1 d . . . . .
C26 C 0.0158(5) 1.0669(5) 0.06828(18) 0.0863(19) Uani 1 1 d . . . . .
H26 H -0.020778 1.026150 0.053218 0.104 Uiso 1 1 calc R . . . .
C27 C -0.0258(6) 1.1495(6) 0.0749(2) 0.109(3) Uani 1 1 d . . . . .
H27 H -0.088761 1.164163 0.064009 0.130 Uiso 1 1 calc R . . . .
C28 C 0.0267(7) 1.2096(6) 0.0976(3) 0.121(3) Uani 1 1 d . . . . .
H28 H -0.001552 1.264494 0.102667 0.145 Uiso 1 1 calc R . . . .
C29 C 0.1230(6) 1.1884(5) 0.1132(2) 0.104(2) Uani 1 1 d . . . . .
H29 H 0.159278 1.229936 0.127989 0.125 Uiso 1 1 calc R . . . .
C30 C 0.1637(5) 1.1048(4) 0.10627(18) 0.0801(17) Uani 1 1 d . . . . .
H30 H 0.226818 1.090199 0.116991 0.096 Uiso 1 1 calc R . . . .
C31 C 0.2274(4) 0.9539(4) 0.03451(13) 0.0553(12) Uani 1 1 d . . . . .
C32 C 0.1923(4) 1.0168(4) 0.00829(14) 0.0643(14) Uani 1 1 d . . . . .
H32 H 0.134998 1.049178 0.010583 0.077 Uiso 1 1 calc R . . . .
C33 C 0.2422(5) 1.0316(4) -0.02123(15) 0.0737(16) Uani 1 1 d . . . . .
H33 H 0.217431 1.072926 -0.038695 0.088 Uiso 1 1 calc R . . . .
C34 C 0.3268(5) 0.9860(5) -0.02455(17) 0.0864(19) Uani 1 1 d . . . . .
H34 H 0.360611 0.997479 -0.043989 0.104 Uiso 1 1 calc R . . . .
C35 C 0.3633(5) 0.9225(6) 0.00061(18) 0.100(2) Uani 1 1 d . . . . .
H35 H 0.420213 0.890059 -0.002202 0.120 Uiso 1 1 calc R . . . .
C36 C 0.3138(5) 0.9077(5) 0.03032(15) 0.0794(18) Uani 1 1 d . . . . .
H36 H 0.339109 0.866201 0.047601 0.095 Uiso 1 1 calc R . . . .
C37 C 0.8242(4) 0.4782(4) 0.15200(16) 0.0637(14) Uani 1 1 d . . . . .
C38 C 0.8444(5) 0.5682(5) 0.1616(2) 0.0869(19) Uani 1 1 d . . . . .
H38 H 0.806874 0.613900 0.149620 0.104 Uiso 1 1 calc R . . . .
C39 C 0.9199(6) 0.5914(7) 0.1888(3) 0.124(3) Uani 1 1 d . . . . .
H39 H 0.932493 0.651769 0.194571 0.149 Uiso 1 1 calc R . . . .
C40 C 0.9752(6) 0.5242(9) 0.2069(2) 0.126(4) Uani 1 1 d . . . . .
H40 H 1.024985 0.539393 0.225089 0.152 Uiso 1 1 calc R . . . .
C41 C 0.9572(5) 0.4328(8) 0.1983(2) 0.118(3) Uani 1 1 d . . . . .
H41 H 0.995254 0.387760 0.210480 0.141 Uiso 1 1 calc R . . . .
C42 C 0.8802(5) 0.4096(5) 0.17070(18) 0.0834(18) Uani 1 1 d . . . . .
H42 H 0.867118 0.349247 0.165062 0.100 Uiso 1 1 calc R . . . .
C43 C 0.7792(5) 0.4650(4) 0.07551(18) 0.0778(17) Uani 1 1 d . . . . .
C44 C 0.7197(6) 0.4929(5) 0.0437(2) 0.104(2) Uani 1 1 d . . . . .
H44 H 0.655180 0.511897 0.044707 0.124 Uiso 1 1 calc R . . . .
C45 C 0.7578(8) 0.4919(7) 0.0104(2) 0.129(3) Uani 1 1 d . . . . .
H45 H 0.717618 0.507443 -0.010457 0.155 Uiso 1 1 calc R . . . .
C46 C 0.8522(9) 0.4684(8) 0.0093(3) 0.140(4) Uani 1 1 d . . . . .
H46 H 0.876503 0.464528 -0.012648 0.168 Uiso 1 1 calc R . . . .
C47 C 0.9152(8) 0.4496(7) 0.0412(3) 0.136(3) Uani 1 1 d . . . . .
H47 H 0.981913 0.438452 0.040357 0.164 Uiso 1 1 calc R . . . .
C48 C 0.8779(6) 0.4476(6) 0.0736(2) 0.108(3) Uani 1 1 d . . . . .
H48 H 0.919697 0.434459 0.094365 0.129 Uiso 1 1 calc R . . . .
C49 C 0.7024(4) 0.3315(4) 0.12211(16) 0.0760(17) Uani 0.39 1 d D . P A 1
C50 C 0.723(2) 0.2560(11) 0.1020(7) 0.114(4) Uani 0.39 1 d D . P A 1
H50 H 0.750566 0.264299 0.081046 0.136 Uiso 0.39 1 calc R . P A 1
C51 C 0.702(3) 0.1683(13) 0.1127(9) 0.113(6) Uani 0.39 1 d D . P A 1
H51 H 0.715786 0.119053 0.098839 0.136 Uiso 0.39 1 calc R . P A 1
C52 C 0.661(2) 0.1557(14) 0.1435(8) 0.090(8) Uani 0.39 1 d D . P A 1
H52 H 0.647448 0.097289 0.150616 0.108 Uiso 0.39 1 calc R . P A 1
C53 C 0.639(3) 0.2280(14) 0.1643(8) 0.106(7) Uani 0.39 1 d D . P A 1
H53 H 0.611473 0.218008 0.185224 0.128 Uiso 0.39 1 calc R . P A 1
C54 C 0.659(3) 0.3177(14) 0.1537(6) 0.092(4) Uani 0.39 1 d D . P A 1
H54 H 0.644358 0.366662 0.167498 0.110 Uiso 0.39 1 calc R . P A 1
C49A C 0.7024(4) 0.3315(4) 0.12211(16) 0.0760(17) Uani 0.45 1 d D . P A 2
C50A C 0.7385(16) 0.2690(9) 0.0993(6) 0.114(4) Uani 0.45 1 d D . P A 2
H50A H 0.770874 0.289128 0.080486 0.136 Uiso 0.45 1 calc R . P A 2
C51A C 0.7264(18) 0.1764(10) 0.1045(8) 0.113(6) Uani 0.45 1 d D . P A 2
H51A H 0.751156 0.135938 0.088993 0.136 Uiso 0.45 1 calc R . P A 2
C52A C 0.6796(19) 0.1435(11) 0.1316(7) 0.090(8) Uani 0.45 1 d D . P A 2
H52A H 0.672409 0.081482 0.134409 0.108 Uiso 0.45 1 calc R . P A 2
C53A C 0.643(2) 0.2028(10) 0.1550(7) 0.106(7) Uani 0.45 1 d D . P A 2
H53A H 0.611467 0.181074 0.173738 0.128 Uiso 0.45 1 calc R . P A 2
C54A C 0.6534(19) 0.2975(10) 0.1500(5) 0.092(4) Uani 0.45 1 d D . P A 2
H54A H 0.627499 0.337572 0.165382 0.110 Uiso 0.45 1 calc R . P A 2
C49B C 0.7024(4) 0.3315(4) 0.12211(16) 0.0760(17) Uani 0.16 1 d D . P A 3
C50B C 0.748(3) 0.2836(18) 0.0968(9) 0.114(4) Uani 0.16 1 d D . P A 3
H50B H 0.787679 0.314530 0.082421 0.136 Uiso 0.16 1 calc R . P A 3
C51B C 0.737(4) 0.1903(19) 0.0929(12) 0.113(6) Uani 0.16 1 d D . P A 3
H51B H 0.767462 0.159298 0.075920 0.136 Uiso 0.16 1 calc R . P A 3
C52B C 0.679(3) 0.1448(18) 0.1142(12) 0.090(8) Uani 0.16 1 d D . P A 3
H52B H 0.671974 0.082623 0.111516 0.108 Uiso 0.16 1 calc R . P A 3
C53B C 0.631(3) 0.188(2) 0.1395(11) 0.106(7) Uani 0.16 1 d D . P A 3
H53B H 0.592616 0.155927 0.153620 0.128 Uiso 0.16 1 calc R . P A 3
C54B C 0.643(3) 0.2833(19) 0.1435(8) 0.092(4) Uani 0.16 1 d D . P A 3
H54B H 0.611309 0.313770 0.160373 0.110 Uiso 0.16 1 calc R . P A 3
C55 C 0.3839(4) 0.3719(4) 0.07031(15) 0.0631(13) Uani 1 1 d . . . . .
C56 C 0.2956(5) 0.3246(4) 0.05985(15) 0.0756(16) Uani 1 1 d . . . . .
H56 H 0.244079 0.328817 0.073721 0.091 Uiso 1 1 calc R . . . .
C57 C 0.2840(6) 0.2717(5) 0.02925(19) 0.095(2) Uani 1 1 d . . . . .
H57 H 0.226760 0.237794 0.023650 0.114 Uiso 1 1 calc R . . . .
C58 C 0.3572(7) 0.2694(5) 0.0070(2) 0.104(2) Uani 1 1 d . . . . .
H58 H 0.347699 0.236163 -0.014067 0.125 Uiso 1 1 calc R . . . .
C59 C 0.4432(7) 0.3155(6) 0.0159(2) 0.103(2) Uani 1 1 d . . . . .
H59 H 0.492481 0.313663 0.000983 0.124 Uiso 1 1 calc R . . . .
C60 C 0.4569(5) 0.3661(4) 0.04785(18) 0.0831(18) Uani 1 1 d . . . . .
H60 H 0.516372 0.396341 0.054044 0.100 Uiso 1 1 calc R . . . .
C61 C 0.2851(4) 0.5025(4) 0.11047(15) 0.0606(13) Uani 1 1 d . . . . .
C62 C 0.2062(5) 0.4712(5) 0.1272(2) 0.091(2) Uani 1 1 d . . . . .
H62 H 0.212178 0.416882 0.139649 0.110 Uiso 1 1 calc R . . . .
C63 C 0.1188(6) 0.5200(7) 0.1255(3) 0.127(3) Uani 1 1 d . . . . .
H63 H 0.067064 0.497701 0.136831 0.153 Uiso 1 1 calc R . . . .
C64 C 0.1076(6) 0.6007(8) 0.1074(3) 0.130(3) Uani 1 1 d . . . . .
H64 H 0.048647 0.632688 0.106112 0.156 Uiso 1 1 calc R . . . .
C65 C 0.1831(6) 0.6322(5) 0.0917(2) 0.110(3) Uani 1 1 d . . . . .
H65 H 0.176254 0.687405 0.079880 0.132 Uiso 1 1 calc R . . . .
C66 C 0.2742(5) 0.5839(4) 0.09254(19) 0.0863(19) Uani 1 1 d . . . . .
H66 H 0.325332 0.606961 0.081137 0.104 Uiso 1 1 calc R . . . .
C67 C 0.4029(4) 0.3655(3) 0.14971(15) 0.0769(17) Uani 0.3 1 d D . P B 1
C68 C 0.426(4) 0.401(2) 0.1842(5) 0.099(3) Uani 0.3 1 d D . P B 1
H68 H 0.441588 0.462368 0.186680 0.118 Uiso 0.3 1 calc R . P B 1
C69 C 0.426(5) 0.349(4) 0.2149(5) 0.131(8) Uani 0.3 1 d D . P B 1
H69 H 0.441609 0.373967 0.237446 0.158 Uiso 0.3 1 calc R . P B 1
C70 C 0.402(4) 0.259(4) 0.2112(11) 0.130(9) Uani 0.3 1 d D . P B 1
H70 H 0.401948 0.223557 0.231578 0.156 Uiso 0.3 1 calc R . P B 1
C71 C 0.379(4) 0.219(2) 0.1781(14) 0.115(9) Uani 0.3 1 d D . P B 1
H71 H 0.363394 0.158054 0.176226 0.138 Uiso 0.3 1 calc R . P B 1
C72 C 0.380(3) 0.2728(9) 0.1467(10) 0.096(3) Uani 0.3 1 d D . P B 1
H72 H 0.365485 0.246559 0.124294 0.115 Uiso 0.3 1 calc R . P B 1
C67A C 0.4029(4) 0.3655(3) 0.14971(15) 0.0769(17) Uani 0.51 1 d D . P B 2
C68A C 0.420(2) 0.4044(15) 0.1839(3) 0.099(3) Uani 0.51 1 d D . P B 2
H68A H 0.444588 0.463133 0.186014 0.118 Uiso 0.51 1 calc R . P B 2
C69A C 0.403(3) 0.358(2) 0.2149(4) 0.131(8) Uani 0.51 1 d D . P B 2
H69A H 0.416057 0.385834 0.237145 0.158 Uiso 0.51 1 calc R . P B 2
C70A C 0.367(2) 0.272(2) 0.2117(7) 0.130(9) Uani 0.51 1 d D . P B 2
H70A H 0.353348 0.241653 0.232146 0.156 Uiso 0.51 1 calc R . P B 2
C71A C 0.349(2) 0.2292(14) 0.1790(9) 0.115(9) Uani 0.51 1 d D . P B 2
H71A H 0.325094 0.170258 0.177566 0.138 Uiso 0.51 1 calc R . P B 2
C72A C 0.367(2) 0.2762(7) 0.1475(7) 0.096(3) Uani 0.51 1 d D . P B 2
H72A H 0.355605 0.247694 0.125362 0.115 Uiso 0.51 1 calc R . P B 2
C67B C 0.4029(4) 0.3655(3) 0.14971(15) 0.0769(17) Uani 0.19 1 d D . P B 3
C68B C 0.458(2) 0.4004(18) 0.1806(5) 0.099(3) Uani 0.19 1 d D . P B 3
H68B H 0.469915 0.462216 0.182116 0.118 Uiso 0.19 1 calc R . P B 3
C69B C 0.494(3) 0.345(2) 0.2092(7) 0.131(8) Uani 0.19 1 d D . P B 3
H69B H 0.530374 0.369903 0.229426 0.158 Uiso 0.19 1 calc R . P B 3
C70B C 0.477(3) 0.254(2) 0.2073(9) 0.130(9) Uani 0.19 1 d D . P B 3
H70B H 0.501568 0.217235 0.226378 0.156 Uiso 0.19 1 calc R . P B 3
C71B C 0.423(3) 0.2157(16) 0.1776(10) 0.115(9) Uani 0.19 1 d D . P B 3
H71B H 0.411143 0.153825 0.176847 0.138 Uiso 0.19 1 calc R . P B 3
C72B C 0.386(2) 0.2716(7) 0.1483(8) 0.096(3) Uani 0.19 1 d D . P B 3
H72B H 0.350802 0.246017 0.128072 0.115 Uiso 0.19 1 calc R . P B 3
C73 C 0.4704(4) 0.9771(3) 0.11085(13) 0.0537(12) Uani 1 1 d . . . . .
C74 C 0.4546(6) 1.1103(4) 0.0722(2) 0.103(3) Uani 1 1 d . . . . .
H74A H 0.489292 1.139868 0.054881 0.155 Uiso 1 1 calc R . . . .
H74B H 0.389781 1.093434 0.061297 0.155 Uiso 1 1 calc R . . . .
H74C H 0.448953 1.150713 0.091767 0.155 Uiso 1 1 calc R . . . .
B1 B 0.6200(5) 0.8849(4) 0.15644(19) 0.0640(16) Uani 1 1 d . . . . .
H1 H 0.646594 0.938902 0.175269 0.077 Uiso 1 1 d R . . . .
B2 B 0.5294(4) 0.8874(4) 0.12129(16) 0.0539(13) Uani 1 1 d . . . . .
B3 B 0.6585(5) 0.8564(4) 0.1174(2) 0.0663(17) Uani 1 1 d . . . . .
H3A H 0.719172 0.895984 0.108517 0.080 Uiso 1 1 d R . . . .
B4 B 0.6571(4) 0.7753(4) 0.15382(18) 0.0617(16) Uani 1 1 d . . . . .
H4A H 0.717124 0.750406 0.173602 0.074 Uiso 1 1 d R . . . .
B5 B 0.5278(4) 0.8052(4) 0.15925(15) 0.0518(13) Uani 1 1 d . . . . .
H5A H 0.487741 0.805128 0.182783 0.062 Uiso 1 1 d R . . . .
B6 B 0.5573(4) 0.8133(4) 0.08489(16) 0.0549(14) Uani 1 1 d . . . . .
H6A H 0.548469 0.837390 0.057093 0.066 Uiso 1 1 d R . . . .
B7 B 0.6470(5) 0.7354(4) 0.10808(17) 0.0587(15) Uani 1 1 d . . . . .
H7 H 0.708874 0.699036 0.098489 0.070 Uiso 1 1 d R . . . .
B8 B 0.5555(4) 0.6999(4) 0.13789(15) 0.0517(13) Uani 1 1 d . . . . .
H8A H 0.545582 0.635284 0.151382 0.062 Uiso 1 1 d R . . . .
B9 B 0.4646(4) 0.7793(4) 0.11535(15) 0.0519(13) Uani 1 1 d . . . . .
H9A H 0.383313 0.777544 0.111236 0.062 Uiso 1 1 d R . . . .
B10 B 0.5290(4) 0.7024(4) 0.09254(16) 0.0548(14) Uani 1 1 d . . . . .
H10A H 0.502097 0.648497 0.073676 0.066 Uiso 1 1 d R . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Ag1 P2 125.05(5) . .
P1 Ag1 O1 109.64(10) . .
P1 Ag1 H9A 121.1 . .
P2 Ag1 H9A 108.3 . .
O1 Ag1 P2 90.24(10) . .
O1 Ag1 H9A 91.8 . .
P3 Ag2 P4 118.27(6) . .
P3 Ag2 B8 120.12(13) . .
P3 Ag2 H8A 120.0 . .
P3 Ag2 B10 123.32(13) . .
P4 Ag2 B8 119.37(13) . .
P4 Ag2 H8A 107.7 . .
P4 Ag2 B10 112.99(14) . .
B8 Ag2 H8A 23.9 . .
B8 Ag2 B10 38.03(18) . .
B10 Ag2 H8A 60.6 . .
C1 P1 Ag1 113.24(17) . .
C1 P1 C7 105.0(3) . .
C7 P1 Ag1 108.83(18) . .
C13 P1 Ag1 117.92(18) . .
C13 P1 C1 106.2(2) . .
C13 P1 C7 104.5(3) . .
C19 P2 Ag1 112.99(16) . .
C25 P2 Ag1 112.03(18) . .
C25 P2 C19 103.1(3) . .
C31 P2 Ag1 116.64(17) . .
C31 P2 C19 106.8(2) . .
C31 P2 C25 104.0(2) . .
C37 P3 Ag2 120.24(19) . .
C37 P3 C49 102.4(2) . .
C37 P3 C49A 102.4(2) . .
C37 P3 C49B 102.4(2) . .
C43 P3 Ag2 115.0(2) . .
C43 P3 C37 103.0(3) . .
C43 P3 C49 105.0(3) . .
C43 P3 C49A 105.0(3) . .
C43 P3 C49B 105.0(3) . .
C49 P3 Ag2 109.48(18) . .
C49A P3 Ag2 109.48(18) . .
C49B P3 Ag2 109.48(18) . .
C55 P4 Ag2 113.91(19) . .
C55 P4 C61 103.0(2) . .
C55 P4 C67 107.4(2) . .
C55 P4 C67A 107.4(2) . .
C55 P4 C67B 107.4(2) . .
C61 P4 Ag2 117.78(18) . .
C67 P4 Ag2 111.38(18) . .
C67 P4 C61 102.3(3) . .
C67A P4 Ag2 111.38(18) . .
C67A P4 C61 102.3(3) . .
C67B P4 Ag2 111.38(18) . .
C67B P4 C61 102.3(3) . .
C73 O1 Ag1 110.7(3) . .
C73 O2 C74 117.3(4) . .
C2 C1 P1 123.9(4) . .
C2 C1 C6 118.3(5) . .
C6 C1 P1 117.8(4) . .
C1 C2 H2 119.6 . .
C3 C2 C1 120.8(5) . .
C3 C2 H2 119.6 . .
C2 C3 H3 120.3 . .
C4 C3 C2 119.4(5) . .
C4 C3 H3 120.3 . .
C3 C4 H4 119.0 . .
C3 C4 C5 122.1(6) . .
C5 C4 H4 119.0 . .
C4 C5 H5 120.6 . .
C4 C5 C6 118.8(6) . .
C6 C5 H5 120.6 . .
C1 C6 H6 119.7 . .
C5 C6 C1 120.6(5) . .
C5 C6 H6 119.7 . .
C8 C7 P1 119.8(5) . .
C12 C7 P1 122.4(5) . .
C12 C7 C8 117.2(6) . .
C7 C8 H8 119.9 . .
C7 C8 C9 120.3(8) . .
C9 C8 H8 119.9 . .
C8 C9 H9 120.5 . .
C10 C9 C8 119.0(8) . .
C10 C9 H9 120.5 . .
C9 C10 H10 119.3 . .
C11 C10 C9 121.4(8) . .
C11 C10 H10 119.3 . .
C10 C11 H11 120.2 . .
C10 C11 C12 119.6(8) . .
C12 C11 H11 120.2 . .
C7 C12 H12 118.7 . .
C11 C12 C7 122.6(8) . .
C11 C12 H12 118.7 . .
C14 C13 P1 119.9(5) . .
C14 C13 C18 117.6(6) . .
C18 C13 P1 122.5(5) . .
C13 C14 H14 119.7 . .
C13 C14 C15 120.6(6) . .
C15 C14 H14 119.7 . .
C14 C15 H15 119.4 . .
C16 C15 C14 121.2(7) . .
C16 C15 H15 119.4 . .
C15 C16 H16 120.6 . .
C17 C16 C15 118.7(7) . .
C17 C16 H16 120.6 . .
C16 C17 H17 119.0 . .
C16 C17 C18 122.0(7) . .
C18 C17 H17 119.0 . .
C13 C18 C17 119.9(7) . .
C13 C18 H18 120.1 . .
C17 C18 H18 120.1 . .
C20 C19 P2 117.3(4) . .
C24 C19 P2 122.9(4) . .
C24 C19 C20 119.6(6) . .
C19 C20 H20 119.8 . .
C21 C20 C19 120.5(6) . .
C21 C20 H20 119.8 . .
C20 C21 H21 119.6 . .
C22 C21 C20 120.8(7) . .
C22 C21 H21 119.6 . .
C21 C22 H22 120.0 . .
C21 C22 C23 120.1(7) . .
C23 C22 H22 120.0 . .
C22 C23 H23 119.6 . .
C22 C23 C24 120.8(7) . .
C24 C23 H23 119.6 . .
C19 C24 C23 118.2(6) . .
C19 C24 H24 120.9 . .
C23 C24 H24 120.9 . .
C26 C25 P2 123.8(5) . .
C26 C25 C30 117.7(6) . .
C30 C25 P2 118.5(4) . .
C25 C26 H26 118.8 . .
C27 C26 C25 122.4(7) . .
C27 C26 H26 118.8 . .
C26 C27 H27 120.3 . .
C28 C27 C26 119.4(7) . .
C28 C27 H27 120.3 . .
C27 C28 H28 119.9 . .
C27 C28 C29 120.3(7) . .
C29 C28 H28 119.9 . .
C28 C29 H29 120.2 . .
C30 C29 C28 119.5(7) . .
C30 C29 H29 120.2 . .
C25 C30 H30 119.6 . .
C29 C30 C25 120.7(7) . .
C29 C30 H30 119.6 . .
C32 C31 P2 123.4(4) . .
C36 C31 P2 118.7(4) . .
C36 C31 C32 117.9(5) . .
C31 C32 H32 119.6 . .
C33 C32 C31 120.7(5) . .
C33 C32 H32 119.6 . .
C32 C33 H33 119.9 . .
C34 C33 C32 120.1(6) . .
C34 C33 H33 119.9 . .
C33 C34 H34 119.6 . .
C33 C34 C35 120.8(6) . .
C35 C34 H34 119.6 . .
C34 C35 H35 120.4 . .
C34 C35 C36 119.2(6) . .
C36 C35 H35 120.4 . .
C31 C36 C35 121.2(6) . .
C31 C36 H36 119.4 . .
C35 C36 H36 119.4 . .
C38 C37 P3 118.6(5) . .
C38 C37 C42 118.7(6) . .
C42 C37 P3 122.7(5) . .
C37 C38 H38 119.1 . .
C37 C38 C39 121.7(7) . .
C39 C38 H38 119.1 . .
C38 C39 H39 120.2 . .
C40 C39 C38 119.5(8) . .
C40 C39 H39 120.2 . .
C39 C40 H40 119.6 . .
C39 C40 C41 120.7(8) . .
C41 C40 H40 119.6 . .
C40 C41 H41 120.2 . .
C40 C41 C42 119.5(8) . .
C42 C41 H41 120.2 . .
C37 C42 C41 119.8(7) . .
C37 C42 H42 120.1 . .
C41 C42 H42 120.1 . .
C44 C43 P3 118.6(5) . .
C48 C43 P3 123.6(6) . .
C48 C43 C44 117.8(7) . .
C43 C44 H44 119.7 . .
C45 C44 C43 120.6(8) . .
C45 C44 H44 119.7 . .
C44 C45 H45 120.2 . .
C46 C45 C44 119.5(9) . .
C46 C45 H45 120.2 . .
C45 C46 H46 119.8 . .
C45 C46 C47 120.4(9) . .
C47 C46 H46 119.8 . .
C46 C47 H47 119.9 . .
C48 C47 C46 120.3(9) . .
C48 C47 H47 119.9 . .
C43 C48 C47 120.8(8) . .
C43 C48 H48 119.6 . .
C47 C48 H48 119.6 . .
C50 C49 P3 133.4(10) . .
C50 C49 C54 118.3(13) . .
C54 C49 P3 108.3(9) . .
C49 C50 H50 119.1 . .
C49 C50 C51 121.8(15) . .
C51 C50 H50 119.1 . .
C50 C51 H51 120.3 . .
C52 C51 C50 119.4(15) . .
C52 C51 H51 120.3 . .
C51 C52 H52 119.4 . .
C51 C52 C53 121.2(15) . .
C53 C52 H52 119.4 . .
C52 C53 H53 120.0 . .
C52 C53 C54 120.0(16) . .
C54 C53 H53 120.0 . .
C49 C54 C53 119.2(15) . .
C49 C54 H54 120.4 . .
C53 C54 H54 120.4 . .
C50A C49A P3 121.2(8) . .
C50A C49A C54A 117.5(10) . .
C54A C49A P3 121.3(7) . .
C49A C50A H50A 119.8 . .
C49A C50A C51A 120.4(13) . .
C51A C50A H50A 119.8 . .
C50A C51A H51A 118.9 . .
C52A C51A C50A 122.1(14) . .
C52A C51A H51A 118.9 . .
C51A C52A H52A 120.2 . .
C51A C52A C53A 119.6(13) . .
C53A C52A H52A 120.2 . .
C52A C53A H53A 120.3 . .
C52A C53A C54A 119.4(13) . .
C54A C53A H53A 120.3 . .
C49A C54A C53A 121.0(12) . .
C49A C54A H54A 119.5 . .
C53A C54A H54A 119.5 . .
C50B C49B P3 110.0(13) . .
C50B C49B C54B 118.3(15) . .
C54B C49B P3 131.2(14) . .
C49B C50B H50B 119.4 . .
C51B C50B C49B 121.2(18) . .
C51B C50B H50B 119.4 . .
C50B C51B H51B 120.3 . .
C52B C51B C50B 119.4(19) . .
C52B C51B H51B 120.3 . .
C51B C52B H52B 118.9 . .
C51B C52B C53B 122.2(18) . .
C53B C52B H52B 118.9 . .
C52B C53B H53B 120.7 . .
C52B C53B C54B 118.6(18) . .
C54B C53B H53B 120.7 . .
C49B C54B C53B 120.3(17) . .
C49B C54B H54B 119.9 . .
C53B C54B H54B 119.9 . .
C56 C55 P4 123.0(5) . .
C60 C55 P4 120.0(5) . .
C60 C55 C56 117.0(6) . .
C55 C56 H56 119.4 . .
C57 C56 C55 121.2(6) . .
C57 C56 H56 119.4 . .
C56 C57 H57 119.9 . .
C58 C57 C56 120.2(7) . .
C58 C57 H57 119.9 . .
C57 C58 H58 119.9 . .
C59 C58 C57 120.3(7) . .
C59 C58 H58 119.9 . .
C58 C59 H59 120.2 . .
C58 C59 C60 119.6(7) . .
C60 C59 H59 120.2 . .
C55 C60 C59 121.7(7) . .
C55 C60 H60 119.2 . .
C59 C60 H60 119.2 . .
C62 C61 P4 124.0(5) . .
C66 C61 P4 117.9(5) . .
C66 C61 C62 118.0(6) . .
C61 C62 H62 119.5 . .
C63 C62 C61 121.0(7) . .
C63 C62 H62 119.5 . .
C62 C63 H63 119.5 . .
C64 C63 C62 121.0(8) . .
C64 C63 H63 119.5 . .
C63 C64 H64 120.6 . .
C65 C64 C63 118.7(8) . .
C65 C64 H64 120.6 . .
C64 C65 H65 118.9 . .
C64 C65 C66 122.2(8) . .
C66 C65 H65 118.9 . .
C61 C66 C65 119.1(7) . .
C61 C66 H66 120.5 . .
C65 C66 H66 120.5 . .
C68 C67 P4 118.5(16) . .
C68 C67 C72 117.6(15) . .
C72 C67 P4 123.9(16) . .
C67 C68 H68 118.9 . .
C69 C68 C67 122.3(16) . .
C69 C68 H68 118.9 . .
C68 C69 H69 120.6 . .
C70 C69 C68 118.8(16) . .
C70 C69 H69 120.6 . .
C69 C70 H70 119.0 . .
C69 C70 C71 121.9(16) . .
C71 C70 H70 119.0 . .
C70 C71 H71 120.4 . .
C70 C71 C72 119.3(16) . .
C72 C71 H71 120.4 . .
C67 C72 C71 120.1(15) . .
C67 C72 H72 120.0 . .
C71 C72 H72 120.0 . .
C68A C67A P4 117.2(10) . .
C68A C67A C72A 117.2(11) . .
C72A C67A P4 124.4(11) . .
C67A C68A H68A 118.6 . .
C69A C68A C67A 122.8(12) . .
C69A C68A H68A 118.6 . .
C68A C69A H69A 120.7 . .
C70A C69A C68A 118.6(13) . .
C70A C69A H69A 120.7 . .
C69A C70A H70A 119.1 . .
C69A C70A C71A 121.8(13) . .
C71A C70A H70A 119.1 . .
C70A C71A H71A 120.3 . .
C70A C71A C72A 119.4(12) . .
C72A C71A H71A 120.3 . .
C67A C72A C71A 120.2(12) . .
C67A C72A H72A 119.9 . .
C71A C72A H72A 119.9 . .
C68B C67B P4 112.0(12) . .
C68B C67B C72B 117.6(14) . .
C72B C67B P4 126.3(13) . .
C67B C68B H68B 119.1 . .
C69B C68B C67B 121.8(16) . .
C69B C68B H68B 119.1 . .
C68B C69B H69B 120.2 . .
C70B C69B C68B 119.7(18) . .
C70B C69B H69B 120.2 . .
C69B C70B H70B 119.4 . .
C69B C70B C71B 121.1(17) . .
C71B C70B H70B 119.4 . .
C70B C71B H71B 120.2 . .
C70B C71B C72B 119.5(17) . .
C72B C71B H71B 120.2 . .
C67B C72B C71B 120.3(16) . .
C67B C72B H72B 119.9 . .
C71B C72B H72B 119.9 . .
O1 C73 O2 118.7(5) . .
O1 C73 B2 127.7(5) . .
O2 C73 B2 113.7(4) . .
O2 C74 H74A 109.5 . .
O2 C74 H74B 109.5 . .
O2 C74 H74C 109.5 . .
H74A C74 H74B 109.5 . .
H74A C74 H74C 109.5 . .
H74B C74 H74C 109.5 . .
B2 B1 H1 129.7 . .
B2 B1 B4 99.7(5) . .
B2 B1 B5 66.4(3) . .
B3 B1 H1 129.4 . .
B3 B1 B2 66.3(4) . .
B3 B1 B4 65.3(4) . .
B3 B1 B5 101.1(4) . .
B4 B1 H1 130.6 . .
B4 B1 B5 65.2(4) . .
B5 B1 H1 129.5 . .
C73 B2 B1 120.8(5) . .
C73 B2 B3 130.7(4) . .
C73 B2 B5 132.9(5) . .
C73 B2 B6 117.7(4) . .
C73 B2 B9 118.9(4) . .
B1 B2 B3 56.4(4) . .
B1 B2 B5 57.8(3) . .
B1 B2 B6 111.9(4) . .
B1 B2 B9 111.8(4) . .
B3 B2 B5 90.1(4) . .
B6 B2 B3 60.1(4) . .
B6 B2 B5 101.9(4) . .
B9 B2 B3 103.0(4) . .
B9 B2 B5 58.4(3) . .
B9 B2 B6 61.8(3) . .
B1 B3 B2 57.3(4) . .
B1 B3 H3A 117.6 . .
B1 B3 B4 58.1(4) . .
B1 B3 B6 112.3(5) . .
B1 B3 B7 112.7(5) . .
B2 B3 H3A 130.9 . .
B4 B3 B2 90.2(4) . .
B4 B3 H3A 131.2 . .
B4 B3 B6 101.3(4) . .
B4 B3 B7 59.5(3) . .
B6 B3 B2 59.7(3) . .
B6 B3 H3A 120.8 . .
B7 B3 B2 101.5(4) . .
B7 B3 H3A 120.9 . .
B7 B3 B6 59.6(3) . .
B1 B4 B3 56.6(4) . .
B1 B4 H4A 118.7 . .
B1 B4 B5 58.2(3) . .
B1 B4 B7 112.2(5) . .
B1 B4 B8 112.4(4) . .
B3 B4 H4A 130.7 . .
B3 B4 B5 91.5(4) . .
B5 B4 H4A 130.0 . .
B7 B4 B3 60.3(4) . .
B7 B4 H4A 119.9 . .
B7 B4 B5 102.9(4) . .
B7 B4 B8 61.5(3) . .
B8 B4 B3 103.5(4) . .
B8 B4 H4A 119.4 . .
B8 B4 B5 59.2(3) . .
B1 B5 B2 55.7(3) . .
B1 B5 B4 56.6(3) . .
B1 B5 H5A 119.2 . .
B1 B5 B8 111.3(4) . .
B1 B5 B9 110.7(4) . .
B2 B5 H5A 132.1 . .
B4 B5 B2 88.2(4) . .
B4 B5 H5A 131.7 . .
B8 B5 B2 101.2(4) . .
B8 B5 B4 59.4(3) . .
B8 B5 H5A 120.6 . .
B9 B5 B2 59.4(3) . .
B9 B5 B4 101.5(4) . .
B9 B5 H5A 120.7 . .
B9 B5 B8 60.9(3) . .
B2 B6 B3 60.3(3) . .
B2 B6 H6A 120.7 . .
B2 B6 B9 58.9(3) . .
B3 B6 H6A 120.4 . .
B3 B6 B9 101.1(4) . .
B7 B6 B2 102.1(4) . .
B7 B6 B3 59.8(3) . .
B7 B6 H6A 130.5 . .
B7 B6 B9 90.0(4) . .
B9 B6 H6A 131.8 . .
B10 B6 B2 111.9(4) . .
B10 B6 B3 112.6(4) . .
B10 B6 H6A 118.0 . .
B10 B6 B7 57.8(3) . .
B10 B6 B9 57.3(3) . .
B3 B7 H7 119.4 . .
B3 B7 B8 102.0(4) . .
B4 B7 B3 60.2(4) . .
B4 B7 B6 102.5(4) . .
B4 B7 H7 120.2 . .
B4 B7 B8 59.5(3) . .
B6 B7 B3 60.6(3) . .
B6 B7 H7 130.4 . .
B6 B7 B8 90.4(4) . .
B8 B7 H7 131.5 . .
B10 B7 B3 113.5(4) . .
B10 B7 B4 112.0(4) . .
B10 B7 B6 58.1(3) . .
B10 B7 H7 118.4 . .
B10 B7 B8 56.8(3) . .
Ag2 B8 H8A 48.1 . .
B4 B8 Ag2 129.7(3) . .
B4 B8 B7 59.0(3) . .
B4 B8 H8A 120.9 . .
B4 B8 B9 101.8(4) . .
B5 B8 Ag2 165.4(4) . .
B5 B8 B4 61.4(3) . .
B5 B8 B7 102.7(4) . .
B5 B8 H8A 119.8 . .
B5 B8 B9 59.4(3) . .
B7 B8 Ag2 91.8(3) . .
B7 B8 H8A 131.1 . .
B9 B8 Ag2 119.8(3) . .
B9 B8 B7 90.3(4) . .
B9 B8 H8A 130.8 . .
B10 B8 Ag2 73.2(3) . .
B10 B8 B4 112.0(4) . .
B10 B8 B5 113.4(4) . .
B10 B8 B7 57.3(3) . .
B10 B8 H8A 117.4 . .
B10 B8 B9 58.4(3) . .
B2 B9 B6 59.2(3) . .
B2 B9 B8 102.4(4) . .
B2 B9 H9A 120.0 . .
B5 B9 B2 62.2(3) . .
B5 B9 B6 102.8(4) . .
B5 B9 B8 59.7(3) . .
B5 B9 H9A 119.3 . .
B6 B9 H9A 131.6 . .
B8 B9 B6 89.2(3) . .
B8 B9 H9A 131.4 . .
B10 B9 B2 111.6(4) . .
B10 B9 B5 112.4(4) . .
B10 B9 B6 56.6(3) . .
B10 B9 B8 56.9(3) . .
B10 B9 H9A 118.7 . .
Ag2 B10 H10A 64.2 . .
B6 B10 Ag2 157.0(4) . .
B6 B10 B9 66.1(3) . .
B6 B10 H10A 130.3 . .
B7 B10 Ag2 92.9(3) . .
B7 B10 B6 64.1(4) . .
B7 B10 B9 99.0(4) . .
B7 B10 H10A 130.6 . .
B8 B10 Ag2 68.8(3) . .
B8 B10 B6 99.5(4) . .
B8 B10 B7 65.9(4) . .
B8 B10 B9 64.7(3) . .
B8 B10 H10A 130.2 . .
B9 B10 Ag2 121.0(3) . .
B9 B10 H10A 130.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P1 2.4629(16) .
Ag1 P2 2.5105(15) .
Ag1 O1 2.491(4) .
Ag1 H9A 2.2259 .
Ag2 P3 2.5096(16) .
Ag2 P4 2.5173(16) .
Ag2 B8 2.578(6) .
Ag2 H8A 2.0175 .
Ag2 B10 2.648(6) .
P1 C1 1.845(5) .
P1 C7 1.851(6) .
P1 C13 1.842(6) .
P2 C19 1.842(5) .
P2 C25 1.840(6) .
P2 C31 1.839(5) .
P3 C37 1.843(6) .
P3 C43 1.837(7) .
P3 C49 1.848(6) .
P3 C49A 1.848(6) .
P3 C49B 1.848(6) .
P4 C55 1.846(6) .
P4 C61 1.850(6) .
P4 C67 1.847(6) .
P4 C67A 1.847(6) .
P4 C67B 1.847(6) .
O1 C73 1.225(6) .
O2 C73 1.372(6) .
O2 C74 1.490(7) .
C1 C2 1.406(6) .
C1 C6 1.412(6) .
C2 H2 0.9300 .
C2 C3 1.401(7) .
C3 H3 0.9300 .
C3 C4 1.376(7) .
C4 H4 0.9300 .
C4 C5 1.382(7) .
C5 H5 0.9300 .
C5 C6 1.410(6) .
C6 H6 0.9300 .
C7 C8 1.392(9) .
C7 C12 1.388(9) .
C8 H8 0.9300 .
C8 C9 1.416(10) .
C9 H9 0.9300 .
C9 C10 1.389(12) .
C10 H10 0.9300 .
C10 C11 1.332(12) .
C11 H11 0.9300 .
C11 C12 1.385(10) .
C12 H12 0.9300 .
C13 C14 1.376(8) .
C13 C18 1.401(8) .
C14 H14 0.9300 .
C14 C15 1.413(10) .
C15 H15 0.9300 .
C15 C16 1.358(10) .
C16 H16 0.9300 .
C16 C17 1.349(11) .
C17 H17 0.9300 .
C17 C18 1.402(10) .
C18 H18 0.9300 .
C19 C20 1.401(7) .
C19 C24 1.393(8) .
C20 H20 0.9300 .
C20 C21 1.394(8) .
C21 H21 0.9300 .
C21 C22 1.349(10) .
C22 H22 0.9300 .
C22 C23 1.388(10) .
C23 H23 0.9300 .
C23 C24 1.426(9) .
C24 H24 0.9300 .
C25 C26 1.392(8) .
C25 C30 1.402(8) .
C26 H26 0.9300 .
C26 C27 1.383(9) .
C27 H27 0.9300 .
C27 C28 1.372(11) .
C28 H28 0.9300 .
C28 C29 1.406(11) .
C29 H29 0.9300 .
C29 C30 1.394(9) .
C30 H30 0.9300 .
C31 C32 1.399(7) .
C31 C36 1.388(7) .
C32 H32 0.9300 .
C32 C33 1.394(8) .
C33 H33 0.9300 .
C33 C34 1.357(9) .
C34 H34 0.9300 .
C34 C35 1.383(9) .
C35 H35 0.9300 .
C35 C36 1.397(8) .
C36 H36 0.9300 .
C37 C38 1.399(8) .
C37 C42 1.406(8) .
C38 H38 0.9300 .
C38 C39 1.401(10) .
C39 H39 0.9300 .
C39 C40 1.378(13) .
C40 H40 0.9300 .
C40 C41 1.405(13) .
C41 H41 0.9300 .
C41 C42 1.424(10) .
C42 H42 0.9300 .
C43 C44 1.424(9) .
C43 C48 1.381(9) .
C44 H44 0.9300 .
C44 C45 1.418(11) .
C45 H45 0.9300 .
C45 C46 1.340(13) .
C46 H46 0.9300 .
C46 C47 1.417(13) .
C47 H47 0.9300 .
C47 C48 1.382(11) .
C48 H48 0.9300 .
C49 C50 1.396(8) .
C49 C54 1.408(9) .
C50 H50 0.9300 .
C50 C51 1.397(9) .
C51 H51 0.9300 .
C51 C52 1.365(10) .
C52 H52 0.9300 .
C52 C53 1.380(10) .
C53 H53 0.9300 .
C53 C54 1.423(9) .
C54 H54 0.9300 .
C49A C50A 1.395(8) .
C49A C54A 1.408(8) .
C50A H50A 0.9300 .
C50A C51A 1.397(9) .
C51A H51A 0.9300 .
C51A C52A 1.363(10) .
C52A H52A 0.9300 .
C52A C53A 1.381(10) .
C53A H53A 0.9300 .
C53A C54A 1.424(9) .
C54A H54A 0.9300 .
C49B C50B 1.398(9) .
C49B C54B 1.408(9) .
C50B H50B 0.9300 .
C50B C51B 1.397(10) .
C51B H51B 0.9300 .
C51B C52B 1.368(10) .
C52B H52B 0.9300 .
C52B C53B 1.379(10) .
C53B H53B 0.9300 .
C53B C54B 1.422(10) .
C54B H54B 0.9300 .
C55 C56 1.406(8) .
C55 C60 1.390(8) .
C56 H56 0.9300 .
C56 C57 1.387(8) .
C57 H57 0.9300 .
C57 C58 1.384(11) .
C58 H58 0.9300 .
C58 C59 1.362(11) .
C59 H59 0.9300 .
C59 C60 1.412(9) .
C60 H60 0.9300 .
C61 C62 1.393(8) .
C61 C66 1.380(8) .
C62 H62 0.9300 .
C62 C63 1.388(10) .
C63 H63 0.9300 .
C63 C64 1.375(12) .
C64 H64 0.9300 .
C64 C65 1.335(12) .
C65 H65 0.9300 .
C65 C66 1.431(10) .
C66 H66 0.9300 .
C67 C68 1.403(8) .
C67 C72 1.407(9) .
C68 H68 0.9300 .
C68 C69 1.397(9) .
C69 H69 0.9300 .
C69 C70 1.370(10) .
C70 H70 0.9300 .
C70 C71 1.380(10) .
C71 H71 0.9300 .
C71 C72 1.425(9) .
C72 H72 0.9300 .
C67A C68A 1.405(8) .
C67A C72A 1.407(8) .
C68A H68A 0.9300 .
C68A C69A 1.397(9) .
C69A H69A 0.9300 .
C69A C70A 1.370(9) .
C70A H70A 0.9300 .
C70A C71A 1.381(9) .
C71A H71A 0.9300 .
C71A C72A 1.427(9) .
C72A H72A 0.9300 .
C67B C68B 1.402(9) .
C67B C72B 1.408(9) .
C68B H68B 0.9300 .
C68B C69B 1.396(10) .
C69B H69B 0.9300 .
C69B C70B 1.369(10) .
C70B H70B 0.9300 .
C70B C71B 1.380(10) .
C71B H71B 0.9300 .
C71B C72B 1.423(9) .
C72B H72B 0.9300 .
C73 B2 1.576(7) .
C74 H74A 0.9600 .
C74 H74B 0.9600 .
C74 H74C 0.9600 .
B1 H1 1.0997 .
B1 B2 1.696(8) .
B1 B3 1.679(10) .
B1 B4 1.707(9) .
B1 B5 1.737(8) .
B2 B3 1.845(9) .
B2 B5 1.881(8) .
B2 B6 1.835(9) .
B2 B9 1.829(8) .
B3 H3A 1.1001 .
B3 B4 1.826(9) .
B3 B6 1.841(9) .
B3 B7 1.827(9) .
B4 H4A 1.0995 .
B4 B5 1.856(8) .
B4 B7 1.812(9) .
B4 B8 1.821(8) .
B5 H5A 1.0996 .
B5 B8 1.816(8) .
B5 B9 1.810(8) .
B6 H6A 1.0999 .
B6 B7 1.822(8) .
B6 B9 1.882(8) .
B6 B10 1.718(8) .
B7 H7 1.1000 .
B7 B8 1.858(8) .
B7 B10 1.714(9) .
B8 H8A 1.0999 .
B8 B9 1.837(8) .
B8 B10 1.704(8) .
B9 H9A 1.1003 .
B9 B10 1.732(8) .
B10 H10A 1.1003 .
