#------------------------------------------------------------------------------
#$Date: 2021-11-10 12:23:14 +0200 (Wed, 10 Nov 2021) $
#$Revision: 270568 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/51/1565165.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1565165
loop_
_publ_author_name
'Bai, Chao'
'Fu, Xin-Yu'
'Hu, Huai-Ming'
'He, Shi'
'Wang, Xiaofang'
'Xue, Gang-Lin'
_publ_section_title
;
 Construction of visible luminescent lanthanide coordination compounds
 with different stacking modes based on a carboxylate substituted
 terpyridyl derivative ligand
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119550
_journal_paper_doi               10.1016/j.ica.2020.119550
_journal_volume                  506
_journal_year                    2020
_chemical_formula_moiety         'C176 H114 Eu2 N24 O18'
_chemical_formula_sum            'C176 H114 Eu2 N24 O18'
_chemical_formula_weight         3156.83
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 107.824(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   21.515(3)
_cell_length_b                   18.530(2)
_cell_length_c                   19.322(3)
_cell_measurement_reflns_used    2832
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      19.20
_cell_measurement_theta_min      2.21
_cell_volume                     7333.4(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1165
_diffrn_reflns_av_unetI/netI     0.1375
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            36347
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.050
_diffrn_reflns_theta_max         25.050
_diffrn_reflns_theta_min         2.132
_exptl_absorpt_coefficient_mu    0.926
_exptl_absorpt_correction_T_max  0.888
_exptl_absorpt_correction_T_min  0.830
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.430
_exptl_crystal_description       block
_exptl_crystal_F_000             3216
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_refine_diff_density_max         2.248
_refine_diff_density_min         -2.749
_refine_diff_density_rms         0.142
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.275
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     991
_refine_ls_number_reflns         12963
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.276
_refine_ls_R_factor_all          0.1722
_refine_ls_R_factor_gt           0.1397
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0790P)²+71.6996P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2753
_refine_ls_wR_factor_ref         0.2920
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9863
_reflns_number_total             12963
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            Compound1.cif
_cod_data_source_block           nw2055
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1565165
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.01806(3) 0.68787(4) 0.39872(4) 0.0271(2) Uani 1 1 d . . . . .
N1 N -0.0140(5) 0.5616(6) 0.3375(6) 0.034(3) Uani 1 1 d . . . . .
N2 N 0.0685(6) 0.5733(6) 0.4770(6) 0.039(3) Uani 1 1 d . . . . .
N3 N 0.0800(6) 0.7063(6) 0.5367(6) 0.036(3) Uani 1 1 d . . . . .
N4 N -0.0957(6) 0.7839(7) 0.1550(8) 0.051(4) Uani 1 1 d . . . . .
N5 N -0.2073(5) 0.8567(7) 0.2446(7) 0.044(3) Uani 1 1 d . . . . .
N6 N -0.2698(7) 0.9539(10) 0.3720(10) 0.086(6) Uani 1 1 d . . . . .
N7 N 0.3178(7) 0.7497(8) 0.6839(8) 0.058(4) Uani 1 1 d . . . . .
N8 N 0.2594(5) 0.8397(6) 0.5148(7) 0.039(3) Uani 1 1 d . . . . .
N9 N 0.2563(6) 0.8838(8) 0.3347(8) 0.055(4) Uani 1 1 d . . . . .
N10 N 0.4318(8) -0.1600(10) 0.4151(8) 0.069(4) Uani 1 1 d . . . . .
N11 N 0.4156(6) 0.0325(9) 0.4233(8) 0.055(4) Uani 1 1 d . . . . .
N12 N 0.4120(8) 0.2216(12) 0.3776(11) 0.089(6) Uani 1 1 d . . . . .
O1 O 0.0679(5) 0.3441(5) 0.5508(5) 0.040(2) Uani 1 1 d . . . . .
O2 O 0.1011(4) 0.3103(5) 0.6641(6) 0.042(2) Uani 1 1 d . . . . .
O3 O -0.0212(4) 0.8052(5) 0.4195(6) 0.043(3) Uani 1 1 d . . . . .
O4 O 0.0755(5) 0.8063(6) 0.4020(8) 0.070(4) Uani 1 1 d . . . . .
O5 O 0.1199(4) 0.6582(5) 0.3890(5) 0.040(2) Uani 1 1 d . . . . .
O6 O 0.1193(6) 0.6283(7) 0.2769(6) 0.059(3) Uani 1 1 d . . . . .
O7 O 0.4066(8) -0.1566(10) 0.1661(9) 0.102(5) Uani 1 1 d . . . . .
H7 H 0.3768 -0.1839 0.1668 0.153 Uiso 1 1 calc R U . . .
O8 O 0.3372(8) -0.0728(9) 0.1731(8) 0.094(5) Uani 1 1 d . . . . .
C1 C -0.0589(7) 0.5543(8) 0.2727(8) 0.040(3) Uani 1 1 d . U . . .
H1 H -0.0780 0.5961 0.2488 0.048 Uiso 1 1 calc R U . . .
C2 C -0.0785(8) 0.4912(11) 0.2396(8) 0.059(5) Uani 1 1 d . . . . .
H2 H -0.1093 0.4903 0.1938 0.071 Uiso 1 1 calc R U . . .
C3 C -0.0533(8) 0.4285(11) 0.2730(10) 0.062(5) Uani 1 1 d . . . . .
H3 H -0.0667 0.3842 0.2508 0.074 Uiso 1 1 calc R U . . .
C4 C -0.0069(7) 0.4323(8) 0.3419(9) 0.047(4) Uani 1 1 d . . . . .
H4 H 0.0100 0.3904 0.3672 0.056 Uiso 1 1 calc R U . . .
C5 C 0.0136(6) 0.4992(7) 0.3715(7) 0.029(3) Uani 1 1 d . U . . .
C6 C 0.0649(6) 0.5102(8) 0.4427(7) 0.031(3) Uani 1 1 d . . . . .
C7 C 0.1070(6) 0.4542(7) 0.4730(7) 0.029(3) Uani 1 1 d . . . . .
H7A H 0.1034 0.4104 0.4486 0.034 Uiso 1 1 calc R U . . .
C8 C 0.1543(6) 0.4630(7) 0.5393(7) 0.031(3) Uani 1 1 d . . . . .
C9 C 0.1574(7) 0.5293(8) 0.5735(8) 0.042(4) Uani 1 1 d . . . . .
H9 H 0.1886 0.5377 0.6181 0.051 Uiso 1 1 calc R U . . .
C10 C 0.1129(6) 0.5834(7) 0.5402(7) 0.031(3) Uani 1 1 d . . . . .
C11 C 0.1156(6) 0.6533(7) 0.5765(7) 0.030(3) Uani 1 1 d . . . . .
C12 C 0.1498(8) 0.6641(9) 0.6482(9) 0.052(4) Uani 1 1 d . . . . .
H12 H 0.1733 0.6261 0.6754 0.063 Uiso 1 1 calc R U . . .
C13 C 0.1500(8) 0.7302(9) 0.6804(9) 0.056(5) Uani 1 1 d . . . . .
H13 H 0.1747 0.7380 0.7284 0.068 Uiso 1 1 calc R U . . .
C14 C 0.1133(10) 0.7836(10) 0.6405(10) 0.066(5) Uani 1 1 d . . . . .
H14 H 0.1100 0.8281 0.6615 0.080 Uiso 1 1 calc R U . . .
C15 C 0.0813(8) 0.7713(8) 0.5695(9) 0.048(4) Uani 1 1 d . . . . .
H15 H 0.0590 0.8096 0.5416 0.057 Uiso 1 1 calc R U . . .
C16 C 0.2011(6) 0.4043(7) 0.5777(8) 0.033(3) Uani 1 1 d . . . . .
C17 C 0.2669(7) 0.4153(9) 0.5849(9) 0.051(4) Uani 1 1 d . . . . .
H17 H 0.2795 0.4556 0.5637 0.061 Uiso 1 1 calc R U . . .
C18 C 0.3143(7) 0.3663(9) 0.6237(10) 0.054(5) Uani 1 1 d . . . . .
H18 H 0.3578 0.3727 0.6264 0.065 Uiso 1 1 calc R U . . .
C19 C 0.2959(7) 0.3078(10) 0.6583(11) 0.066(5) Uani 1 1 d . . . . .
H19 H 0.3271 0.2753 0.6847 0.079 Uiso 1 1 calc R U . . .
C20 C 0.2320(7) 0.2987(7) 0.6532(10) 0.048(4) Uani 1 1 d . . . . .
H20 H 0.2204 0.2603 0.6779 0.058 Uiso 1 1 calc R U . . .
C21 C 0.1822(7) 0.3454(7) 0.6116(8) 0.037(3) Uani 1 1 d . . . . .
C22 C 0.1138(7) 0.3326(8) 0.6095(9) 0.043(4) Uani 1 1 d . . . . .
C23 C -0.0988(9) 0.7504(10) 0.0928(10) 0.064(5) Uani 1 1 d . . . . .
H23 H -0.0595 0.7430 0.0830 0.076 Uiso 1 1 calc R U . . .
C24 C -0.1543(11) 0.7258(11) 0.0419(11) 0.076(6) Uani 1 1 d . . . . .
H24 H -0.1531 0.7015 0.0002 0.091 Uiso 1 1 calc R U . . .
C25 C -0.2103(12) 0.7389(14) 0.0560(13) 0.099(8) Uani 1 1 d . . . . .
H25 H -0.2494 0.7225 0.0238 0.119 Uiso 1 1 calc R U . . .
C26 C -0.2111(9) 0.7766(12) 0.1179(12) 0.077(6) Uani 1 1 d . . . . .
H26 H -0.2504 0.7870 0.1266 0.093 Uiso 1 1 calc R U . . .
C27 C -0.1522(7) 0.7985(7) 0.1666(9) 0.042(4) Uani 1 1 d . . . . .
C28 C -0.1507(7) 0.8454(7) 0.2303(8) 0.040(4) Uani 1 1 d . . . . .
C29 C -0.0927(6) 0.8769(6) 0.2711(6) 0.023(3) Uani 1 1 d . U . . .
H29 H -0.0543 0.8677 0.2601 0.028 Uiso 1 1 calc R U . . .
C30 C -0.0920(7) 0.9225(8) 0.3289(9) 0.039(4) Uani 1 1 d . . . . .
C31 C -0.1510(7) 0.9338(8) 0.3407(8) 0.041(4) Uani 1 1 d . . . . .
H31 H -0.1527 0.9653 0.3776 0.049 Uiso 1 1 calc R U . . .
C32 C -0.2077(7) 0.9005(8) 0.3003(8) 0.041(4) Uani 1 1 d . . . . .
C33 C -0.2712(6) 0.9117(9) 0.3168(9) 0.043(4) Uani 1 1 d . U . . .
C34 C -0.3264(8) 0.8807(11) 0.2736(10) 0.064(5) Uani 1 1 d . . . . .
H34 H -0.3254 0.8529 0.2339 0.077 Uiso 1 1 calc R U . . .
C35 C -0.3836(9) 0.8905(14) 0.2892(13) 0.087(7) Uani 1 1 d . . . . .
H35 H -0.4217 0.8676 0.2622 0.105 Uiso 1 1 calc R U . . .
C36 C -0.3831(11) 0.9346(14) 0.3450(13) 0.090(7) Uani 1 1 d . . . . .
H36 H -0.4213 0.9446 0.3561 0.108 Uiso 1 1 calc R U . . .
C37 C -0.3257(10) 0.9637(14) 0.3842(14) 0.101(9) Uani 1 1 d . . . . .
H37 H -0.3258 0.9933 0.4231 0.121 Uiso 1 1 calc R U . . .
C38 C -0.0300(7) 0.9581(8) 0.3748(9) 0.042(4) Uani 1 1 d . . . . .
C39 C -0.0293(8) 1.0336(9) 0.3784(11) 0.064(5) Uani 1 1 d . . . . .
H39 H -0.0666 1.0603 0.3561 0.077 Uiso 1 1 calc R U . . .
C40 C 0.0284(10) 1.0672(9) 0.4161(13) 0.079(7) Uani 1 1 d . . . . .
H40 H 0.0291 1.1174 0.4170 0.095 Uiso 1 1 calc R U . . .
C41 C 0.0840(9) 1.0316(10) 0.4519(10) 0.063(5) Uani 1 1 d . . . . .
H41 H 0.1213 1.0564 0.4783 0.075 Uiso 1 1 calc R U . . .
C42 C 0.0833(7) 0.9568(9) 0.4479(8) 0.048(4) Uani 1 1 d . . . . .
H42 H 0.1210 0.9320 0.4732 0.058 Uiso 1 1 calc R U . . .
C43 C 0.0290(9) 0.9164(9) 0.4079(11) 0.065(5) Uani 1 1 d . U . . .
C44 C 0.0262(8) 0.8411(9) 0.4071(8) 0.050(4) Uani 1 1 d . . . . .
C45 C 0.3326(10) 0.7639(12) 0.7572(11) 0.076(6) Uani 1 1 d . . . . .
H45 H 0.3549 0.7293 0.7905 0.091 Uiso 1 1 calc R U . . .
C46 C 0.3150(11) 0.8285(13) 0.7823(11) 0.079(7) Uani 1 1 d . . . . .
H46 H 0.3249 0.8370 0.8319 0.094 Uiso 1 1 calc R U . . .
C47 C 0.2838(12) 0.8781(13) 0.7347(12) 0.088(7) Uani 1 1 d . . . . .
H47 H 0.2739 0.9224 0.7513 0.105 Uiso 1 1 calc R U . . .
C48 C 0.2660(9) 0.8648(10) 0.6608(11) 0.066(5) Uani 1 1 d . . . . .
H48 H 0.2421 0.8983 0.6274 0.079 Uiso 1 1 calc R U . . .
C49 C 0.2850(8) 0.7995(10) 0.6385(10) 0.053(5) Uani 1 1 d . . . . .
C50 C 0.2698(6) 0.7826(9) 0.5600(8) 0.042(4) Uani 1 1 d . . . . .
C51 C 0.2660(7) 0.7126(8) 0.5341(8) 0.038(3) Uani 1 1 d . . . . .
H51 H 0.2714 0.6737 0.5658 0.046 Uiso 1 1 calc R U . . .
C52 C 0.2540(6) 0.7014(8) 0.4604(8) 0.038(4) Uani 1 1 d . . . . .
C53 C 0.2468(7) 0.7594(8) 0.4149(8) 0.040(4) Uani 1 1 d . . . . .
H53 H 0.2399 0.7528 0.3654 0.048 Uiso 1 1 calc R U . . .
C54 C 0.2498(6) 0.8286(8) 0.4440(8) 0.036(3) Uani 1 1 d . . . . .
C55 C 0.2480(6) 0.8956(9) 0.3993(9) 0.041(4) Uani 1 1 d . . . . .
C56 C 0.2424(8) 0.9635(8) 0.4249(10) 0.050(4) Uani 1 1 d . . . . .
H56 H 0.2366 0.9697 0.4703 0.060 Uiso 1 1 calc R U . . .
C57 C 0.2452(8) 1.0213(9) 0.3834(13) 0.067(6) Uani 1 1 d . . . . .
H57 H 0.2403 1.0675 0.3999 0.080 Uiso 1 1 calc R U . . .
C58 C 0.2553(8) 1.0128(12) 0.3166(13) 0.071(6) Uani 1 1 d . . . . .
H58 H 0.2582 1.0523 0.2879 0.085 Uiso 1 1 calc R U . . .
C59 C 0.2609(8) 0.9428(13) 0.2942(10) 0.066(6) Uani 1 1 d . . . . .
H59 H 0.2681 0.9357 0.2497 0.079 Uiso 1 1 calc R U . . .
C60 C 0.2588(7) 0.6240(8) 0.4358(7) 0.036(3) Uani 1 1 d . . . . .
C61 C 0.3148(8) 0.5849(9) 0.4679(9) 0.047(4) Uani 1 1 d . . . . .
H61 H 0.3478 0.6048 0.5062 0.056 Uiso 1 1 calc R U . . .
C62 C 0.3220(7) 0.5157(9) 0.4432(9) 0.050(4) Uani 1 1 d . . . . .
H62 H 0.3600 0.4900 0.4650 0.060 Uiso 1 1 calc R U . . .
C63 C 0.2739(7) 0.4848(9) 0.3872(9) 0.047(4) Uani 1 1 d . . . . .
H63 H 0.2792 0.4388 0.3705 0.056 Uiso 1 1 calc R U . . .
C64 C 0.2178(7) 0.5234(8) 0.3563(8) 0.040(4) Uani 1 1 d . . . . .
H64 H 0.1848 0.5020 0.3192 0.048 Uiso 1 1 calc R U . . .
C65 C 0.2079(5) 0.5926(7) 0.3776(7) 0.026(3) Uani 1 1 d . . . . .
C66 C 0.1439(7) 0.6304(8) 0.3429(8) 0.037(3) Uani 1 1 d . . . . .
C67 C 0.4297(9) -0.2167(11) 0.4549(13) 0.072(6) Uani 1 1 d . . . . .
H67 H 0.4320 -0.2618 0.4347 0.086 Uiso 1 1 calc R U . . .
C68 C 0.4245(8) -0.2148(13) 0.5245(11) 0.069(6) Uani 1 1 d . . . . .
H68 H 0.4247 -0.2565 0.5514 0.083 Uiso 1 1 calc R U . . .
C69 C 0.4190(8) -0.1477(14) 0.5511(12) 0.074(6) Uani 1 1 d . . . . .
H69 H 0.4142 -0.1432 0.5971 0.089 Uiso 1 1 calc R U . . .
C70 C 0.4204(8) -0.0874(12) 0.5117(10) 0.061(5) Uani 1 1 d . . . . .
H70 H 0.4182 -0.0418 0.5309 0.074 Uiso 1 1 calc R U . . .
C71 C 0.4250(7) -0.0953(10) 0.4422(9) 0.049(4) Uani 1 1 d . . . . .
C72 C 0.4263(7) -0.0311(10) 0.3964(9) 0.046(4) Uani 1 1 d . . . . .
C73 C 0.4401(8) -0.0387(10) 0.3316(10) 0.056(4) Uani 1 1 d . . . . .
H73 H 0.4492 -0.0841 0.3167 0.067 Uiso 1 1 calc R U . . .
C74 C 0.4406(8) 0.0216(11) 0.2882(10) 0.058(5) Uani 1 1 d . . . . .
C75 C 0.4257(8) 0.0870(12) 0.3156(11) 0.069(6) Uani 1 1 d . . . . .
H75 H 0.4220 0.1285 0.2876 0.083 Uiso 1 1 calc R U . . .
C76 C 0.4164(8) 0.0915(11) 0.3816(12) 0.065(5) Uani 1 1 d . . . . .
C77 C 0.4073(8) 0.1606(13) 0.4164(14) 0.072(6) Uani 1 1 d . . . . .
C78 C 0.3959(11) 0.1650(12) 0.4808(15) 0.091(7) Uani 1 1 d . . . . .
H78 H 0.3915 0.1226 0.5047 0.109 Uiso 1 1 calc R U . . .
C79 C 0.3906(13) 0.2290(19) 0.5122(18) 0.117(10) Uani 1 1 d . . . . .
H79 H 0.3828 0.2310 0.5569 0.140 Uiso 1 1 calc R U . . .
C80 C 0.3970(12) 0.2904(15) 0.4766(17) 0.096(8) Uani 1 1 d . . . . .
H80 H 0.3959 0.3351 0.4979 0.116 Uiso 1 1 calc R U . . .
C81 C 0.4049(12) 0.2862(14) 0.4098(17) 0.103(9) Uani 1 1 d . . . . .
H81 H 0.4055 0.3287 0.3845 0.123 Uiso 1 1 calc R U . . .
C82 C 0.4599(8) 0.0171(12) 0.2193(11) 0.066(5) Uani 1 1 d . . . . .
C83 C 0.5026(11) 0.0703(13) 0.2122(11) 0.089(7) Uani 1 1 d . . . . .
H83 H 0.5135 0.1082 0.2453 0.107 Uiso 1 1 calc R U . . .
C84 C 0.5292(13) 0.0664(18) 0.1547(14) 0.126(12) Uani 1 1 d . . . . .
H84 H 0.5574 0.1022 0.1488 0.151 Uiso 1 1 calc R U . . .
C85 C 0.5136(12) 0.0101(18) 0.1076(13) 0.126(12) Uani 1 1 d . . . . .
H85 H 0.5316 0.0074 0.0696 0.152 Uiso 1 1 calc R U . . .
C86 C 0.4719(9) -0.0428(14) 0.1152(10) 0.087(7) Uani 1 1 d . . . . .
H86 H 0.4621 -0.0810 0.0825 0.105 Uiso 1 1 calc R U . . .
C87 C 0.4439(9) -0.0400(10) 0.1714(10) 0.062(5) Uani 1 1 d . . . . .
C88 C 0.3895(12) -0.0909(14) 0.1727(10) 0.072(6) Uani 1 1 d . . . . .
O9 O 0.0087(5) 0.7107(6) 0.2698(7) 0.061(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O3 127.9(3) . .
O5 Eu1 O1 146.4(3) . 3_566
O3 Eu1 O1 78.7(3) . 3_566
O5 Eu1 O9 75.4(3) . .
O3 Eu1 O9 95.1(4) . .
O1 Eu1 O9 127.7(3) 3_566 .
O5 Eu1 O2 145.5(3) . 3_566
O3 Eu1 O2 72.9(3) . 3_566
O1 Eu1 O2 52.8(3) 3_566 3_566
O9 Eu1 O2 75.6(3) . 3_566
O5 Eu1 O4 74.9(4) . .
O3 Eu1 O4 53.3(3) . .
O1 Eu1 O4 129.6(4) 3_566 .
O9 Eu1 O4 76.4(4) . .
O2 Eu1 O4 115.3(4) 3_566 .
O5 Eu1 N3 85.1(3) . .
O3 Eu1 N3 78.9(3) . .
O1 Eu1 N3 80.5(3) 3_566 .
O9 Eu1 N3 149.8(4) . .
O2 Eu1 N3 128.8(3) 3_566 .
O4 Eu1 N3 76.5(4) . .
O5 Eu1 N1 82.9(3) . .
O3 Eu1 N1 145.5(3) . .
O1 Eu1 N1 80.5(3) 3_566 .
O9 Eu1 N1 76.6(4) . .
O2 Eu1 N1 72.6(3) 3_566 .
O4 Eu1 N1 148.5(4) . .
N3 Eu1 N1 124.1(3) . .
O5 Eu1 N2 67.9(3) . .
O3 Eu1 N2 137.2(3) . .
O1 Eu1 N2 78.6(3) 3_566 .
O9 Eu1 N2 127.4(3) . .
O2 Eu1 N2 118.3(3) 3_566 .
O4 Eu1 N2 125.2(4) . .
N3 Eu1 N2 61.9(3) . .
N1 Eu1 N2 63.0(4) . .
O5 Eu1 C22 157.2(4) . 3_566
O3 Eu1 C22 74.5(4) . 3_566
O1 Eu1 C22 26.8(4) 3_566 3_566
O9 Eu1 C22 101.3(4) . 3_566
O2 Eu1 C22 26.1(4) 3_566 3_566
O4 Eu1 C22 126.8(4) . 3_566
N3 Eu1 C22 105.4(4) . 3_566
N1 Eu1 C22 74.5(4) . 3_566
N2 Eu1 C22 98.8(4) . 3_566
C1 N1 C5 116.5(12) . .
C1 N1 Eu1 122.0(10) . .
C5 N1 Eu1 121.5(9) . .
C10 N2 C6 120.0(13) . .
C10 N2 Eu1 118.2(9) . .
C6 N2 Eu1 118.0(9) . .
C11 N3 C15 117.3(13) . .
C11 N3 Eu1 120.9(9) . .
C15 N3 Eu1 121.6(9) . .
C27 N4 C23 116.8(15) . .
C28 N5 C32 119.0(13) . .
C37 N6 C33 115.9(18) . .
C49 N7 C45 117.3(16) . .
C54 N8 C50 119.0(13) . .
C55 N9 C59 117.3(16) . .
C67 N10 C71 117.6(17) . .
C72 N11 C76 116.3(16) . .
C77 N12 C81 115(2) . .
C22 O1 Eu1 94.6(9) . 3_566
C22 O2 Eu1 92.5(9) . 3_566
C44 O3 Eu1 95.5(9) . .
C44 O4 Eu1 91.7(10) . .
C66 O5 Eu1 138.6(9) . .
C88 O7 H7 109.5 . .
N1 C1 C2 124.7(16) . .
N1 C1 H1 117.7 . .
C2 C1 H1 117.7 . .
C1 C2 C3 120.0(16) . .
C1 C2 H2 120.0 . .
C3 C2 H2 120.0 . .
C2 C3 C4 118.2(16) . .
C2 C3 H3 120.9 . .
C4 C3 H3 120.9 . .
C5 C4 C3 119.0(15) . .
C5 C4 H4 120.5 . .
C3 C4 H4 120.5 . .
N1 C5 C4 121.5(13) . .
N1 C5 C6 114.6(12) . .
C4 C5 C6 123.9(12) . .
N2 C6 C7 121.1(13) . .
N2 C6 C5 119.4(12) . .
C7 C6 C5 119.5(13) . .
C8 C7 C6 120.4(12) . .
C8 C7 H7A 119.8 . .
C6 C7 H7A 119.8 . .
C7 C8 C9 117.4(12) . .
C7 C8 C16 124.1(12) . .
C9 C8 C16 118.5(13) . .
C8 C9 C10 119.4(13) . .
C8 C9 H9 120.3 . .
C10 C9 H9 120.3 . .
N2 C10 C9 121.7(13) . .
N2 C10 C11 118.8(12) . .
C9 C10 C11 119.5(12) . .
N3 C11 C12 120.6(13) . .
N3 C11 C10 116.4(12) . .
C12 C11 C10 123.0(13) . .
C11 C12 C13 121.0(14) . .
C11 C12 H12 119.5 . .
C13 C12 H12 119.5 . .
C14 C13 C12 118.4(15) . .
C14 C13 H13 120.8 . .
C12 C13 H13 120.8 . .
C13 C14 C15 118.8(16) . .
C13 C14 H14 120.6 . .
C15 C14 H14 120.6 . .
C14 C15 N3 123.7(15) . .
C14 C15 H15 118.2 . .
N3 C15 H15 118.2 . .
C17 C16 C21 120.1(12) . .
C17 C16 C8 116.5(13) . .
C21 C16 C8 123.0(11) . .
C16 C17 C18 120.5(14) . .
C16 C17 H17 119.7 . .
C18 C17 H17 119.7 . .
C19 C18 C17 119.7(13) . .
C19 C18 H18 120.2 . .
C17 C18 H18 120.2 . .
C20 C19 C18 119.5(14) . .
C20 C19 H19 120.2 . .
C18 C19 H19 120.2 . .
C19 C20 C21 122.4(14) . .
C19 C20 H20 118.8 . .
C21 C20 H20 118.8 . .
C16 C21 C20 117.6(12) . .
C16 C21 C22 123.0(12) . .
C20 C21 C22 119.3(13) . .
O2 C22 O1 120.0(14) . .
O2 C22 C21 120.5(14) . .
O1 C22 C21 119.5(14) . .
O2 C22 Eu1 61.4(8) . 3_566
O1 C22 Eu1 58.6(7) . 3_566
C21 C22 Eu1 177.8(11) . 3_566
N4 C23 C24 126.2(17) . .
N4 C23 H23 116.9 . .
C24 C23 H23 116.9 . .
C25 C24 C23 115.8(19) . .
C25 C24 H24 122.1 . .
C23 C24 H24 122.1 . .
C24 C25 C26 121(2) . .
C24 C25 H25 119.5 . .
C26 C25 H25 119.5 . .
C27 C26 C25 118.7(18) . .
C27 C26 H26 120.7 . .
C25 C26 H26 120.7 . .
N4 C27 C26 121.3(16) . .
N4 C27 C28 117.8(14) . .
C26 C27 C28 120.7(15) . .
N5 C28 C29 122.1(14) . .
N5 C28 C27 117.8(14) . .
C29 C28 C27 120.1(13) . .
C28 C29 C30 119.9(12) . .
C28 C29 H29 120.1 . .
C30 C29 H29 120.1 . .
C31 C30 C29 116.2(14) . .
C31 C30 C38 122.1(14) . .
C29 C30 C38 121.7(11) . .
C30 C31 C32 122.7(15) . .
C30 C31 H31 118.6 . .
C32 C31 H31 118.6 . .
N5 C32 C31 120.0(14) . .
N5 C32 C33 118.5(14) . .
C31 C32 C33 121.5(14) . .
N6 C33 C34 123.3(14) . .
N6 C33 C32 117.1(14) . .
C34 C33 C32 119.5(16) . .
C33 C34 C35 119.2(19) . .
C33 C34 H34 120.4 . .
C35 C34 H34 120.4 . .
C36 C35 C34 118(2) . .
C36 C35 H35 121.0 . .
C34 C35 H35 121.0 . .
C37 C36 C35 118(2) . .
C37 C36 H36 120.9 . .
C35 C36 H36 120.9 . .
N6 C37 C36 125(2) . .
N6 C37 H37 117.4 . .
C36 C37 H37 117.4 . .
C39 C38 C43 120.9(15) . .
C39 C38 C30 117.4(14) . .
C43 C38 C30 121.4(14) . .
C40 C39 C38 118.1(16) . .
C40 C39 H39 120.9 . .
C38 C39 H39 120.9 . .
C41 C40 C39 124.1(16) . .
C41 C40 H40 118.0 . .
C39 C40 H40 118.0 . .
C40 C41 C42 117.6(15) . .
C40 C41 H41 121.2 . .
C42 C41 H41 121.2 . .
C41 C42 C43 123.9(15) . .
C41 C42 H42 118.1 . .
C43 C42 H42 118.1 . .
C44 C43 C42 124.4(15) . .
C44 C43 C38 119.7(17) . .
C42 C43 C38 115.2(15) . .
O4 C44 O3 118.4(14) . .
O4 C44 C43 118.3(16) . .
O3 C44 C43 122.8(16) . .
N7 C45 C46 121(2) . .
N7 C45 H45 119.3 . .
C46 C45 H45 119.3 . .
C47 C46 C45 119(2) . .
C47 C46 H46 120.4 . .
C45 C46 H46 120.4 . .
C46 C47 C48 121(2) . .
C46 C47 H47 119.5 . .
C48 C47 H47 119.5 . .
C47 C48 C49 117(2) . .
C47 C48 H48 121.3 . .
C49 C48 H48 121.3 . .
N7 C49 C48 123.5(17) . .
N7 C49 C50 115.9(15) . .
C48 C49 C50 120.6(18) . .
N8 C50 C51 121.5(14) . .
N8 C50 C49 115.9(15) . .
C51 C50 C49 122.6(15) . .
C50 C51 C52 119.1(14) . .
C50 C51 H51 120.5 . .
C52 C51 H51 120.5 . .
C53 C52 C51 119.4(14) . .
C53 C52 C60 123.0(13) . .
C51 C52 C60 117.0(13) . .
C52 C53 C54 118.9(13) . .
C52 C53 H53 120.6 . .
C54 C53 H53 120.6 . .
N8 C54 C53 121.9(13) . .
N8 C54 C55 115.4(13) . .
C53 C54 C55 122.5(13) . .
N9 C55 C56 122.8(15) . .
N9 C55 C54 114.5(14) . .
C56 C55 C54 122.6(15) . .
C57 C56 C55 119.2(18) . .
C57 C56 H56 120.4 . .
C55 C56 H56 120.4 . .
C56 C57 C58 120.9(19) . .
C56 C57 H57 119.6 . .
C58 C57 H57 119.6 . .
C57 C58 C59 116.9(18) . .
C57 C58 H58 121.6 . .
C59 C58 H58 121.6 . .
N9 C59 C58 122.9(19) . .
N9 C59 H59 118.5 . .
C58 C59 H59 118.5 . .
C61 C60 C65 119.6(13) . .
C61 C60 C52 119.1(13) . .
C65 C60 C52 121.3(12) . .
C60 C61 C62 120.1(15) . .
C60 C61 H61 120.0 . .
C62 C61 H61 120.0 . .
C63 C62 C61 121.2(15) . .
C63 C62 H62 119.4 . .
C61 C62 H62 119.4 . .
C64 C63 C62 118.4(15) . .
C64 C63 H63 120.8 . .
C62 C63 H63 120.8 . .
C63 C64 C65 123.3(14) . .
C63 C64 H64 118.4 . .
C65 C64 H64 118.4 . .
C64 C65 C60 117.4(12) . .
C64 C65 C66 120.1(12) . .
C60 C65 C66 122.4(12) . .
O6 C66 O5 127.4(14) . .
O6 C66 C65 119.5(13) . .
O5 C66 C65 112.9(12) . .
N10 C67 C68 125(2) . .
N10 C67 H67 117.4 . .
C68 C67 H67 117.4 . .
C69 C68 C67 115.5(19) . .
C69 C68 H68 122.2 . .
C67 C68 H68 122.2 . .
C70 C69 C68 121(2) . .
C70 C69 H69 119.3 . .
C68 C69 H69 119.3 . .
C69 C70 C71 119(2) . .
C69 C70 H70 120.7 . .
C71 C70 H70 120.7 . .
N10 C71 C70 121.6(18) . .
N10 C71 C72 117.4(16) . .
C70 C71 C72 120.9(17) . .
N11 C72 C73 123.6(17) . .
N11 C72 C71 115.8(15) . .
C73 C72 C71 120.5(17) . .
C72 C73 C74 120.4(17) . .
C72 C73 H73 119.8 . .
C74 C73 H73 119.8 . .
C73 C74 C75 114.8(18) . .
C73 C74 C82 122.5(18) . .
C75 C74 C82 122.5(19) . .
C76 C75 C74 121.9(19) . .
C76 C75 H75 119.0 . .
C74 C75 H75 119.0 . .
C75 C76 N11 122.7(19) . .
C75 C76 C77 124(2) . .
N11 C76 C77 113(2) . .
C78 C77 N12 121(2) . .
C78 C77 C76 124(2) . .
N12 C77 C76 115(2) . .
C77 C78 C79 122(3) . .
C77 C78 H78 118.9 . .
C79 C78 H78 118.9 . .
C78 C79 C80 118(3) . .
C78 C79 H79 120.9 . .
C80 C79 H79 120.9 . .
C81 C80 C79 120(3) . .
C81 C80 H80 120.1 . .
C79 C80 H80 120.1 . .
C80 C81 N12 123(3) . .
C80 C81 H81 118.5 . .
N12 C81 H81 118.5 . .
C87 C82 C83 121.2(19) . .
C87 C82 C74 123.6(16) . .
C83 C82 C74 114.7(19) . .
C82 C83 C84 119(2) . .
C82 C83 H83 120.4 . .
C84 C83 H83 120.4 . .
C85 C84 C83 120(2) . .
C85 C84 H84 120.1 . .
C83 C84 H84 120.1 . .
C84 C85 C86 121(2) . .
C84 C85 H85 119.5 . .
C86 C85 H85 119.5 . .
C85 C86 C87 121(2) . .
C85 C86 H86 119.6 . .
C87 C86 H86 119.6 . .
C82 C87 C86 118.2(19) . .
C82 C87 C88 120.2(17) . .
C86 C87 C88 120.8(18) . .
O8 C88 O7 125(2) . .
O8 C88 C87 125(2) . .
O7 C88 C87 110(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.321(9) .
Eu1 O3 2.411(9) .
Eu1 O1 2.414(9) 3_566
Eu1 O9 2.473(11) .
Eu1 O2 2.478(9) 3_566
Eu1 O4 2.510(11) .
Eu1 N3 2.613(12) .
Eu1 N1 2.617(11) .
Eu1 N2 2.640(12) .
Eu1 C22 2.819(15) 3_566
N1 C1 1.334(17) .
N1 C5 1.372(16) .
N2 C10 1.313(17) .
N2 C6 1.335(17) .
N3 C11 1.336(16) .
N3 C15 1.357(17) .
N4 C27 1.328(18) .
N4 C23 1.34(2) .
N5 C28 1.345(18) .
N5 C32 1.351(19) .
N6 C37 1.31(2) .
N6 C33 1.32(2) .
N7 C49 1.32(2) .
N7 C45 1.38(2) .
N8 C54 1.337(18) .
N8 C50 1.346(19) .
N9 C55 1.33(2) .
N9 C59 1.37(2) .
N10 C67 1.31(2) .
N10 C71 1.33(2) .
N11 C72 1.34(2) .
N11 C76 1.36(2) .
N12 C77 1.38(3) .
N12 C81 1.38(3) .
O1 C22 1.273(17) .
O1 Eu1 2.414(9) 3_566
O2 C22 1.240(18) .
O2 Eu1 2.478(9) 3_566
O3 C44 1.299(18) .
O4 C44 1.271(19) .
O5 C66 1.267(16) .
O6 C66 1.224(17) .
O7 C88 1.29(2) .
O7 H7 0.8200 .
O8 C88 1.18(2) .
C1 C2 1.34(2) .
C1 H1 0.9300 .
C2 C3 1.36(2) .
C2 H2 0.9300 .
C3 C4 1.40(2) .
C3 H3 0.9300 .
C4 C5 1.378(19) .
C4 H4 0.9300 .
C5 C6 1.492(18) .
C6 C7 1.382(18) .
C7 C8 1.381(18) .
C7 H7A 0.9300 .
C8 C9 1.386(19) .
C8 C16 1.514(17) .
C9 C10 1.399(19) .
C9 H9 0.9300 .
C10 C11 1.465(18) .
C11 C12 1.37(2) .
C12 C13 1.37(2) .
C12 H12 0.9300 .
C13 C14 1.35(2) .
C13 H13 0.9300 .
C14 C15 1.35(2) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.394(18) .
C16 C21 1.397(19) .
C17 C18 1.40(2) .
C17 H17 0.9300 .
C18 C19 1.39(2) .
C18 H18 0.9300 .
C19 C20 1.36(2) .
C19 H19 0.9300 .
C20 C21 1.421(18) .
C20 H20 0.9300 .
C21 C22 1.477(19) .
C22 Eu1 2.819(15) 3_566
C23 C24 1.37(3) .
C23 H23 0.9300 .
C24 C25 1.34(3) .
C24 H24 0.9300 .
C25 C26 1.39(3) .
C25 H25 0.9300 .
C26 C27 1.39(2) .
C26 H26 0.9300 .
C27 C28 1.50(2) .
C28 C29 1.385(19) .
C29 C30 1.395(19) .
C29 H29 0.9300 .
C30 C31 1.373(18) .
C30 C38 1.51(2) .
C31 C32 1.38(2) .
C31 H31 0.9300 .
C32 C33 1.509(19) .
C33 C34 1.35(2) .
C34 C35 1.37(2) .
C34 H34 0.9300 .
C35 C36 1.35(3) .
C35 H35 0.9300 .
C36 C37 1.35(3) .
C36 H36 0.9300 .
C37 H37 0.9300 .
C38 C39 1.40(2) .
C38 C43 1.46(2) .
C39 C40 1.38(2) .
C39 H39 0.9300 .
C40 C41 1.36(3) .
C40 H40 0.9300 .
C41 C42 1.39(2) .
C41 H41 0.9300 .
C42 C43 1.40(2) .
C42 H42 0.9300 .
C43 C44 1.40(2) .
C45 C46 1.39(3) .
C45 H45 0.9300 .
C46 C47 1.33(3) .
C46 H46 0.9300 .
C47 C48 1.38(3) .
C47 H47 0.9300 .
C48 C49 1.39(2) .
C48 H48 0.9300 .
C49 C50 1.48(2) .
C50 C51 1.38(2) .
C51 C52 1.383(19) .
C51 H51 0.9300 .
C52 C53 1.37(2) .
C52 C60 1.524(19) .
C53 C54 1.392(19) .
C53 H53 0.9300 .
C54 C55 1.51(2) .
C55 C56 1.37(2) .
C56 C57 1.35(2) .
C56 H56 0.9300 .
C57 C58 1.38(3) .
C57 H57 0.9300 .
C58 C59 1.38(3) .
C58 H58 0.9300 .
C59 H59 0.9300 .
C60 C61 1.38(2) .
C60 C65 1.430(18) .
C61 C62 1.39(2) .
C61 H61 0.9300 .
C62 C63 1.37(2) .
C62 H62 0.9300 .
C63 C64 1.37(2) .
C63 H63 0.9300 .
C64 C65 1.384(18) .
C64 H64 0.9300 .
C65 C66 1.507(19) .
C67 C68 1.38(3) .
C67 H67 0.9300 .
C68 C69 1.36(3) .
C68 H68 0.9300 .
C69 C70 1.36(3) .
C69 H69 0.9300 .
C70 C71 1.38(2) .
C70 H70 0.9300 .
C71 C72 1.49(2) .
C72 C73 1.38(2) .
C73 C74 1.40(2) .
C73 H73 0.9300 .
C74 C75 1.40(3) .
C74 C82 1.51(3) .
C75 C76 1.35(3) .
C75 H75 0.9300 .
C76 C77 1.49(3) .
C77 C78 1.34(3) .
C78 C79 1.35(3) .
C78 H78 0.9300 .
C79 C80 1.36(3) .
C79 H79 0.9300 .
C80 C81 1.35(3) .
C80 H80 0.9300 .
C81 H81 0.9300 .
C82 C87 1.38(3) .
C82 C83 1.38(3) .
C83 C84 1.40(3) .
C83 H83 0.9300 .
C84 C85 1.36(4) .
C84 H84 0.9300 .
C85 C86 1.37(3) .
C85 H85 0.9300 .
C86 C87 1.39(2) .
C86 H86 0.9300 .
C87 C88 1.51(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C5 N1 C1 C2 0(2) . . . .
Eu1 N1 C1 C2 -178.2(12) . . . .
N1 C1 C2 C3 2(3) . . . .
C1 C2 C3 C4 0(3) . . . .
C2 C3 C4 C5 -3(2) . . . .
C1 N1 C5 C4 -3.3(18) . . . .
Eu1 N1 C5 C4 174.9(10) . . . .
C1 N1 C5 C6 178.3(11) . . . .
Eu1 N1 C5 C6 -3.5(14) . . . .
C3 C4 C5 N1 5(2) . . . .
C3 C4 C5 C6 -177.1(14) . . . .
C10 N2 C6 C7 0.8(19) . . . .
Eu1 N2 C6 C7 158.6(9) . . . .
C10 N2 C6 C5 179.2(11) . . . .
Eu1 N2 C6 C5 -23.1(15) . . . .
N1 C5 C6 N2 17.8(17) . . . .
C4 C5 C6 N2 -160.6(13) . . . .
N1 C5 C6 C7 -163.9(11) . . . .
C4 C5 C6 C7 17.8(19) . . . .
N2 C6 C7 C8 -0.9(19) . . . .
C5 C6 C7 C8 -179.2(11) . . . .
C6 C7 C8 C9 0.2(19) . . . .
C6 C7 C8 C16 178.1(12) . . . .
C7 C8 C9 C10 0(2) . . . .
C16 C8 C9 C10 -177.6(12) . . . .
C6 N2 C10 C9 0(2) . . . .
Eu1 N2 C10 C9 -157.9(11) . . . .
C6 N2 C10 C11 180.0(11) . . . .
Eu1 N2 C10 C11 22.3(16) . . . .
C8 C9 C10 N2 0(2) . . . .
C8 C9 C10 C11 179.4(12) . . . .
C15 N3 C11 C12 2(2) . . . .
Eu1 N3 C11 C12 177.7(11) . . . .
C15 N3 C11 C10 179.5(12) . . . .
Eu1 N3 C11 C10 -5.3(15) . . . .
N2 C10 C11 N3 -11.5(18) . . . .
C9 C10 C11 N3 168.7(13) . . . .
N2 C10 C11 C12 165.4(14) . . . .
C9 C10 C11 C12 -14(2) . . . .
N3 C11 C12 C13 -2(2) . . . .
C10 C11 C12 C13 -178.8(15) . . . .
C11 C12 C13 C14 3(3) . . . .
C12 C13 C14 C15 -4(3) . . . .
C13 C14 C15 N3 5(3) . . . .
C11 N3 C15 C14 -4(2) . . . .
Eu1 N3 C15 C14 -179.3(14) . . . .
C7 C8 C16 C17 113.7(16) . . . .
C9 C8 C16 C17 -68.5(18) . . . .
C7 C8 C16 C21 -73.2(19) . . . .
C9 C8 C16 C21 104.6(17) . . . .
C21 C16 C17 C18 2(2) . . . .
C8 C16 C17 C18 175.8(15) . . . .
C16 C17 C18 C19 -3(3) . . . .
C17 C18 C19 C20 1(3) . . . .
C18 C19 C20 C21 2(3) . . . .
C17 C16 C21 C20 0(2) . . . .
C8 C16 C21 C20 -172.5(14) . . . .
C17 C16 C21 C22 176.7(15) . . . .
C8 C16 C21 C22 4(2) . . . .
C19 C20 C21 C16 -3(3) . . . .
C19 C20 C21 C22 -179.1(17) . . . .
Eu1 O2 C22 O1 -1.7(14) 3_566 . . .
Eu1 O2 C22 C21 179.0(12) 3_566 . . .
Eu1 O1 C22 O2 1.8(15) 3_566 . . .
Eu1 O1 C22 C21 -178.9(11) 3_566 . . .
C16 C21 C22 O2 -140.4(15) . . . .
C20 C21 C22 O2 36(2) . . . .
C16 C21 C22 O1 40(2) . . . .
C20 C21 C22 O1 -143.5(15) . . . .
C27 N4 C23 C24 -4(3) . . . .
N4 C23 C24 C25 2(3) . . . .
C23 C24 C25 C26 1(4) . . . .
C24 C25 C26 C27 -2(4) . . . .
C23 N4 C27 C26 3(2) . . . .
C23 N4 C27 C28 -171.2(15) . . . .
C25 C26 C27 N4 0(3) . . . .
C25 C26 C27 C28 174.0(19) . . . .
C32 N5 C28 C29 0(2) . . . .
C32 N5 C28 C27 -178.1(13) . . . .
N4 C27 C28 N5 -176.2(13) . . . .
C26 C27 C28 N5 10(2) . . . .
N4 C27 C28 C29 5(2) . . . .
C26 C27 C28 C29 -168.9(15) . . . .
N5 C28 C29 C30 -1(2) . . . .
C27 C28 C29 C30 177.9(12) . . . .
C28 C29 C30 C31 -0.8(19) . . . .
C28 C29 C30 C38 -179.9(13) . . . .
C29 C30 C31 C32 2(2) . . . .
C38 C30 C31 C32 -178.6(14) . . . .
C28 N5 C32 C31 1(2) . . . .
C28 N5 C32 C33 -178.9(13) . . . .
C30 C31 C32 N5 -3(2) . . . .
C30 C31 C32 C33 177.4(14) . . . .
C37 N6 C33 C34 1(3) . . . .
C37 N6 C33 C32 178.7(19) . . . .
N5 C32 C33 N6 179.1(16) . . . .
C31 C32 C33 N6 -1(2) . . . .
N5 C32 C33 C34 -3(2) . . . .
C31 C32 C33 C34 176.9(16) . . . .
N6 C33 C34 C35 -3(3) . . . .
C32 C33 C34 C35 179.5(17) . . . .
C33 C34 C35 C36 4(3) . . . .
C34 C35 C36 C37 -3(4) . . . .
C33 N6 C37 C36 0(4) . . . .
C35 C36 C37 N6 1(4) . . . .
C31 C30 C38 C39 -57(2) . . . .
C29 C30 C38 C39 122.0(15) . . . .
C31 C30 C38 C43 129.1(16) . . . .
C29 C30 C38 C43 -52(2) . . . .
C43 C38 C39 C40 -2(3) . . . .
C30 C38 C39 C40 -175.7(17) . . . .
C38 C39 C40 C41 -2(3) . . . .
C39 C40 C41 C42 3(3) . . . .
C40 C41 C42 C43 1(3) . . . .
C41 C42 C43 C44 -175.8(17) . . . .
C41 C42 C43 C38 -5(3) . . . .
C39 C38 C43 C44 176.4(17) . . . .
C30 C38 C43 C44 -10(3) . . . .
C39 C38 C43 C42 5(3) . . . .
C30 C38 C43 C42 178.8(14) . . . .
Eu1 O4 C44 O3 10.5(15) . . . .
Eu1 O4 C44 C43 -177.2(14) . . . .
Eu1 O3 C44 O4 -10.9(16) . . . .
Eu1 O3 C44 C43 177.1(15) . . . .
C42 C43 C44 O4 -43(3) . . . .
C38 C43 C44 O4 146.3(17) . . . .
C42 C43 C44 O3 128.7(19) . . . .
C38 C43 C44 O3 -42(3) . . . .
C49 N7 C45 C46 -1(3) . . . .
N7 C45 C46 C47 -1(3) . . . .
C45 C46 C47 C48 3(3) . . . .
C46 C47 C48 C49 -3(3) . . . .
C45 N7 C49 C48 1(3) . . . .
C45 N7 C49 C50 180.0(14) . . . .
C47 C48 C49 N7 1(3) . . . .
C47 C48 C49 C50 -177.6(16) . . . .
C54 N8 C50 C51 -4.9(19) . . . .
C54 N8 C50 C49 175.6(12) . . . .
N7 C49 C50 N8 -156.0(13) . . . .
C48 C49 C50 N8 23(2) . . . .
N7 C49 C50 C51 25(2) . . . .
C48 C49 C50 C51 -156.5(15) . . . .
N8 C50 C51 C52 3(2) . . . .
C49 C50 C51 C52 -177.6(13) . . . .
C50 C51 C52 C53 0(2) . . . .
C50 C51 C52 C60 172.4(12) . . . .
C51 C52 C53 C54 -2(2) . . . .
C60 C52 C53 C54 -173.2(12) . . . .
C50 N8 C54 C53 3.6(19) . . . .
C50 N8 C54 C55 -171.7(11) . . . .
C52 C53 C54 N8 0(2) . . . .
C52 C53 C54 C55 174.7(13) . . . .
C59 N9 C55 C56 2(2) . . . .
C59 N9 C55 C54 -174.4(13) . . . .
N8 C54 C55 N9 162.7(12) . . . .
C53 C54 C55 N9 -12.6(19) . . . .
N8 C54 C55 C56 -13.6(19) . . . .
C53 C54 C55 C56 171.1(14) . . . .
N9 C55 C56 C57 0(2) . . . .
C54 C55 C56 C57 175.9(14) . . . .
C55 C56 C57 C58 -2(3) . . . .
C56 C57 C58 C59 1(3) . . . .
C55 N9 C59 C58 -2(2) . . . .
C57 C58 C59 N9 1(3) . . . .
C53 C52 C60 C61 118.5(16) . . . .
C51 C52 C60 C61 -53.1(18) . . . .
C53 C52 C60 C65 -58.3(19) . . . .
C51 C52 C60 C65 130.1(14) . . . .
C65 C60 C61 C62 1(2) . . . .
C52 C60 C61 C62 -176.0(13) . . . .
C60 C61 C62 C63 0(2) . . . .
C61 C62 C63 C64 -1(2) . . . .
C62 C63 C64 C65 2(2) . . . .
C63 C64 C65 C60 -1(2) . . . .
C63 C64 C65 C66 -177.7(13) . . . .
C61 C60 C65 C64 -0.1(19) . . . .
C52 C60 C65 C64 176.7(12) . . . .
C61 C60 C65 C66 176.4(13) . . . .
C52 C60 C65 C66 -6.9(19) . . . .
Eu1 O5 C66 O6 24(2) . . . .
Eu1 O5 C66 C65 -152.2(10) . . . .
C64 C65 C66 O6 -45.1(19) . . . .
C60 C65 C66 O6 138.5(14) . . . .
C64 C65 C66 O5 131.1(13) . . . .
C60 C65 C66 O5 -45.3(17) . . . .
C71 N10 C67 C68 -4(3) . . . .
N10 C67 C68 C69 2(3) . . . .
C67 C68 C69 C70 -2(3) . . . .
C68 C69 C70 C71 2(3) . . . .
C67 N10 C71 C70 4(2) . . . .
C67 N10 C71 C72 -179.1(15) . . . .
C69 C70 C71 N10 -4(2) . . . .
C69 C70 C71 C72 179.7(14) . . . .
C76 N11 C72 C73 3(2) . . . .
C76 N11 C72 C71 -179.7(13) . . . .
N10 C71 C72 N11 176.3(14) . . . .
C70 C71 C72 N11 -7(2) . . . .
N10 C71 C72 C73 -6(2) . . . .
C70 C71 C72 C73 170.8(15) . . . .
N11 C72 C73 C74 -3(2) . . . .
C71 C72 C73 C74 179.2(14) . . . .
C72 C73 C74 C75 -1(2) . . . .
C72 C73 C74 C82 175.7(15) . . . .
C73 C74 C75 C76 5(3) . . . .
C82 C74 C75 C76 -171.7(16) . . . .
C74 C75 C76 N11 -5(3) . . . .
C74 C75 C76 C77 173.4(16) . . . .
C72 N11 C76 C75 2(2) . . . .
C72 N11 C76 C77 -177.2(13) . . . .
C81 N12 C77 C78 1(3) . . . .
C81 N12 C77 C76 -178.9(17) . . . .
C75 C76 C77 C78 178(2) . . . .
N11 C76 C77 C78 -3(3) . . . .
C75 C76 C77 N12 -3(3) . . . .
N11 C76 C77 N12 176.0(15) . . . .
N12 C77 C78 C79 -2(4) . . . .
C76 C77 C78 C79 177(2) . . . .
C77 C78 C79 C80 0(4) . . . .
C78 C79 C80 C81 3(4) . . . .
C79 C80 C81 N12 -5(4) . . . .
C77 N12 C81 C80 3(3) . . . .
C73 C74 C82 C87 38(3) . . . .
C75 C74 C82 C87 -146.0(19) . . . .
C73 C74 C82 C83 -134(2) . . . .
C75 C74 C82 C83 42(3) . . . .
C87 C82 C83 C84 1(3) . . . .
C74 C82 C83 C84 173(2) . . . .
C82 C83 C84 C85 -1(4) . . . .
C83 C84 C85 C86 0(5) . . . .
C84 C85 C86 C87 0(4) . . . .
C83 C82 C87 C86 0(3) . . . .
C74 C82 C87 C86 -171.4(17) . . . .
C83 C82 C87 C88 -170(2) . . . .
C74 C82 C87 C88 18(3) . . . .
C85 C86 C87 C82 -1(3) . . . .
C85 C86 C87 C88 170(2) . . . .
C82 C87 C88 O8 49(3) . . . .
C86 C87 C88 O8 -121(2) . . . .
C82 C87 C88 O7 -137.5(19) . . . .
C86 C87 C88 O7 53(3) . . . .
