#------------------------------------------------------------------------------
#$Date: 2021-11-10 12:26:54 +0200 (Wed, 10 Nov 2021) $
#$Revision: 270570 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/51/1565167.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1565167
loop_
_publ_author_name
'Bai, Chao'
'Fu, Xin-Yu'
'Hu, Huai-Ming'
'He, Shi'
'Wang, Xiaofang'
'Xue, Gang-Lin'
_publ_section_title
;
 Construction of visible luminescent lanthanide coordination compounds
 with different stacking modes based on a carboxylate substituted
 terpyridyl derivative ligand
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119550
_journal_paper_doi               10.1016/j.ica.2020.119550
_journal_volume                  506
_journal_year                    2020
_chemical_formula_moiety         'C132 H92 Eu2 N18 O19'
_chemical_formula_sum            'C132 H92 Eu2 N18 O19'
_chemical_formula_weight         2538.15
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.2768(11)
_cell_length_b                   25.121(3)
_cell_length_c                   39.622(4)
_cell_measurement_reflns_used    5354
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      22.13
_cell_measurement_theta_min      2.23
_cell_volume                     11224(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0859
_diffrn_reflns_av_unetI/netI     0.0633
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_number            53923
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.049
_diffrn_reflns_theta_max         25.049
_diffrn_reflns_theta_min         1.920
_exptl_absorpt_coefficient_mu    1.188
_exptl_absorpt_correction_T_max  0.835
_exptl_absorpt_correction_T_min  0.793
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.502
_exptl_crystal_description       strip
_exptl_crystal_F_000             5152
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.586
_refine_diff_density_min         -0.584
_refine_diff_density_rms         0.076
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.987
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     796
_refine_ls_number_reflns         9930
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      0.987
_refine_ls_R_factor_all          0.0775
_refine_ls_R_factor_gt           0.0403
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0458P)²+2.7541P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0879
_refine_ls_wR_factor_ref         0.1046
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6482
_reflns_number_total             9930
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            Compound3.cif
_cod_data_source_block           nw2478
_cod_original_cell_volume        11224.5(19)
_cod_database_code               1565167
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.57932(2) 0.38481(2) 0.07789(2) 0.03488(9) Uani 1 1 d . . . . .
N1 N 0.6747(3) 0.47744(15) 0.08205(9) 0.0417(10) Uani 1 1 d . . . . .
N2 N 0.4556(3) 0.46400(14) 0.05544(8) 0.0327(9) Uani 1 1 d . . . . .
N3 N 0.3663(3) 0.36419(15) 0.05694(9) 0.0406(9) Uani 1 1 d . . . . .
N4 N 0.5363(4) 0.60682(17) 0.12849(10) 0.0515(11) Uani 1 1 d . . . . .
N5 N 0.2380(3) 0.56946(15) 0.15031(9) 0.0434(10) Uani 1 1 d . . . . .
N6 N -0.0157(4) 0.49417(19) 0.17507(11) 0.0619(13) Uani 1 1 d . . . . .
N7 N 0.9169(4) 0.1188(2) 0.22679(12) 0.0708(15) Uani 1 1 d . . . . .
N8 N 0.9787(3) 0.24208(16) 0.18443(10) 0.0446(10) Uani 1 1 d . . . . .
N9 N 0.9626(3) 0.35127(17) 0.12725(11) 0.0500(11) Uani 1 1 d . . . . .
O1 O 0.3744(3) 0.66905(14) -0.02351(8) 0.0524(9) Uani 1 1 d . . . . .
O2 O 0.3287(3) 0.58455(13) -0.02401(8) 0.0559(9) Uani 1 1 d . . . . .
O3 O 0.4580(3) 0.41496(13) 0.12550(7) 0.0432(8) Uani 1 1 d . . . . .
O4 O 0.6437(3) 0.39472(13) 0.13655(8) 0.0474(8) Uani 1 1 d . . . . .
O5 O 0.5501(3) 0.29843(13) 0.09659(8) 0.0507(9) Uani 1 1 d . . . . .
O6 O 0.6613(3) 0.22634(15) 0.10554(9) 0.0633(10) Uani 1 1 d . . . . .
C1 C 0.7885(4) 0.4808(2) 0.09103(13) 0.0562(14) Uani 1 1 d . . . . .
H1 H 0.8210 0.4537 0.1041 0.067 Uiso 1 1 calc R U . . .
C2 C 0.8598(5) 0.5229(3) 0.08177(16) 0.0715(18) Uani 1 1 d . . . . .
H2 H 0.9386 0.5240 0.0887 0.086 Uiso 1 1 calc R U . . .
C3 C 0.8145(5) 0.5629(3) 0.06243(16) 0.0713(18) Uani 1 1 d . . . . .
H3 H 0.8621 0.5909 0.0552 0.086 Uiso 1 1 calc R U . . .
C4 C 0.6958(4) 0.5607(2) 0.05380(13) 0.0546(14) Uani 1 1 d . . . . .
H4 H 0.6615 0.5880 0.0412 0.066 Uiso 1 1 calc R U . . .
C5 C 0.6288(4) 0.51758(19) 0.06412(12) 0.0395(11) Uani 1 1 d . . . . .
C6 C 0.5004(4) 0.51343(18) 0.05626(10) 0.0349(11) Uani 1 1 d . . . . .
C7 C 0.4310(4) 0.55852(18) 0.05121(10) 0.0379(11) Uani 1 1 d . . . . .
H7 H 0.4658 0.5921 0.0511 0.045 Uiso 1 1 calc R U . . .
C8 C 0.3099(4) 0.55339(18) 0.04630(11) 0.0348(11) Uani 1 1 d . . . . .
C9 C 0.2658(4) 0.50184(18) 0.04473(11) 0.0408(11) Uani 1 1 d . . . . .
H9 H 0.1853 0.4966 0.0410 0.049 Uiso 1 1 calc R U . . .
C10 C 0.3392(4) 0.45816(18) 0.04861(11) 0.0367(11) Uani 1 1 d . . . . .
C11 C 0.2939(4) 0.40290(18) 0.04581(11) 0.0359(11) Uani 1 1 d . . . . .
C12 C 0.1828(4) 0.3917(2) 0.03264(13) 0.0510(13) Uani 1 1 d . . . . .
H12 H 0.1352 0.4190 0.0243 0.061 Uiso 1 1 calc R U . . .
C13 C 0.1437(5) 0.3398(2) 0.03202(13) 0.0577(14) Uani 1 1 d . . . . .
H13 H 0.0687 0.3316 0.0238 0.069 Uiso 1 1 calc R U . . .
C14 C 0.2167(5) 0.3006(2) 0.04373(13) 0.0559(14) Uani 1 1 d . . . . .
H14 H 0.1928 0.2652 0.0434 0.067 Uiso 1 1 calc R U . . .
C15 C 0.3254(4) 0.31443(19) 0.05596(12) 0.0501(13) Uani 1 1 d . . . . .
H15 H 0.3741 0.2875 0.0641 0.060 Uiso 1 1 calc R U . . .
C16 C 0.2297(4) 0.59938(17) 0.04375(11) 0.0357(11) Uani 1 1 d . . . . .
C17 C 0.1453(4) 0.6060(2) 0.06913(12) 0.0458(13) Uani 1 1 d . . . . .
H17 H 0.1409 0.5815 0.0867 0.055 Uiso 1 1 calc R U . . .
C18 C 0.0683(4) 0.6486(2) 0.06843(13) 0.0504(13) Uani 1 1 d . . . . .
H18 H 0.0132 0.6528 0.0857 0.060 Uiso 1 1 calc R U . . .
C19 C 0.0720(4) 0.6847(2) 0.04276(14) 0.0520(13) Uani 1 1 d . . . . .
H19 H 0.0180 0.7127 0.0420 0.062 Uiso 1 1 calc R U . . .
C20 C 0.1576(4) 0.67932(18) 0.01767(12) 0.0454(12) Uani 1 1 d . . . . .
H20 H 0.1618 0.7043 0.0004 0.055 Uiso 1 1 calc R U . . .
C21 C 0.2369(4) 0.63692(17) 0.01814(11) 0.0362(10) Uani 1 1 d . . . . .
C22 C 0.3204(4) 0.6296(2) -0.01134(12) 0.0417(12) Uani 1 1 d . . . . .
C23 C 0.5921(5) 0.6479(2) 0.11500(13) 0.0594(15) Uani 1 1 d . . . . .
H23 H 0.6737 0.6453 0.1121 0.071 Uiso 1 1 calc R U . . .
C24 C 0.5384(6) 0.6940(2) 0.10499(13) 0.0652(16) Uani 1 1 d . . . . .
H24 H 0.5822 0.7217 0.0957 0.078 Uiso 1 1 calc R U . . .
C25 C 0.4178(6) 0.6983(2) 0.10896(14) 0.0669(16) Uani 1 1 d . . . . .
H25 H 0.3781 0.7291 0.1025 0.080 Uiso 1 1 calc R U . . .
C26 C 0.3569(5) 0.6560(2) 0.12271(12) 0.0510(13) Uani 1 1 d . . . . .
H26 H 0.2751 0.6578 0.1255 0.061 Uiso 1 1 calc R U . . .
C27 C 0.4184(4) 0.61085(19) 0.13234(11) 0.0445(12) Uani 1 1 d . . . . .
C28 C 0.3563(4) 0.56550(18) 0.14834(11) 0.0379(11) Uani 1 1 d . . . . .
C29 C 0.4172(4) 0.52257(18) 0.16185(11) 0.0418(11) Uani 1 1 d . . . . .
H29 H 0.4990 0.5201 0.1591 0.050 Uiso 1 1 calc R U . . .
C30 C 0.3571(4) 0.48360(18) 0.17927(11) 0.0404(11) Uani 1 1 d . . . . .
C31 C 0.2345(4) 0.48845(18) 0.18173(11) 0.0424(12) Uani 1 1 d . . . . .
H31 H 0.1904 0.4631 0.1934 0.051 Uiso 1 1 calc R U . . .
C32 C 0.1792(4) 0.5311(2) 0.16674(12) 0.0413(12) Uani 1 1 d . . . . .
C33 C 0.0474(4) 0.5375(2) 0.16713(12) 0.0501(13) Uani 1 1 d . . . . .
C34 C -0.0048(5) 0.5857(2) 0.15974(13) 0.0624(15) Uani 1 1 d . . . . .
H34 H 0.0415 0.6152 0.1545 0.075 Uiso 1 1 calc R U . . .
C35 C -0.1266(6) 0.5896(3) 0.16028(16) 0.083(2) Uani 1 1 d . . . . .
H35 H -0.1636 0.6218 0.1554 0.100 Uiso 1 1 calc R U . . .
C36 C -0.1924(5) 0.5456(4) 0.16805(17) 0.087(2) Uani 1 1 d . . . . .
H36 H -0.2748 0.5472 0.1685 0.104 Uiso 1 1 calc R U . . .
C37 C -0.1348(6) 0.4996(3) 0.17509(15) 0.080(2) Uani 1 1 d . . . . .
H37 H -0.1803 0.4698 0.1803 0.097 Uiso 1 1 calc R U . . .
C38 C 0.4234(4) 0.44088(19) 0.19747(12) 0.0462(12) Uani 1 1 d . . . . .
C39 C 0.3986(5) 0.4343(2) 0.23157(13) 0.0639(16) Uani 1 1 d . . . . .
H39 H 0.3352 0.4528 0.2409 0.077 Uiso 1 1 calc R U . . .
C40 C 0.4653(7) 0.4010(3) 0.25217(15) 0.093(2) Uani 1 1 d . . . . .
H40 H 0.4464 0.3969 0.2749 0.111 Uiso 1 1 calc R U . . .
C41 C 0.5592(6) 0.3745(3) 0.23829(14) 0.093(2) Uani 1 1 d . . . . .
H41 H 0.6070 0.3534 0.2519 0.112 Uiso 1 1 calc R U . . .
C42 C 0.5839(5) 0.3787(2) 0.20440(13) 0.0668(17) Uani 1 1 d . . . . .
H42 H 0.6469 0.3596 0.1953 0.080 Uiso 1 1 calc R U . . .
C43 C 0.5161(4) 0.41113(19) 0.18354(11) 0.0410(11) Uani 1 1 d . . . . .
C44 C 0.5406(4) 0.40770(19) 0.14633(12) 0.0405(11) Uani 1 1 d . . . . .
C45 C 0.9773(7) 0.0799(3) 0.24247(15) 0.091(2) Uani 1 1 d . . . . .
H45 H 0.9343 0.0523 0.2522 0.109 Uiso 1 1 calc R U . . .
C46 C 1.0977(6) 0.0784(3) 0.24497(15) 0.080(2) Uani 1 1 d . . . . .
H46 H 1.1352 0.0508 0.2564 0.096 Uiso 1 1 calc R U . . .
C47 C 1.1611(6) 0.1176(3) 0.23049(17) 0.077(2) Uani 1 1 d . . . . .
H47 H 1.2435 0.1173 0.2314 0.093 Uiso 1 1 calc R U . . .
C48 C 1.1022(4) 0.1578(2) 0.21452(14) 0.0605(15) Uani 1 1 d . . . . .
H48 H 1.1446 0.1850 0.2041 0.073 Uiso 1 1 calc R U . . .
C49 C 0.9806(4) 0.1581(2) 0.21376(12) 0.0450(12) Uani 1 1 d . . . . .
C50 C 0.9144(4) 0.20222(19) 0.19696(11) 0.0403(11) Uani 1 1 d . . . . .
C51 C 0.7917(4) 0.20132(19) 0.19494(11) 0.0446(12) Uani 1 1 d . . . . .
H51 H 0.7496 0.1734 0.2046 0.053 Uiso 1 1 calc R U . . .
C52 C 0.7318(4) 0.24177(18) 0.17858(11) 0.0401(12) Uani 1 1 d . . . . .
C53 C 0.7996(4) 0.28240(19) 0.16465(11) 0.0416(12) Uani 1 1 d . . . . .
H53 H 0.7631 0.3102 0.1532 0.050 Uiso 1 1 calc R U . . .
C54 C 0.9224(4) 0.28133(19) 0.16794(11) 0.0406(11) Uani 1 1 d . . . . .
C55 C 1.0008(4) 0.3229(2) 0.15389(13) 0.0441(12) Uani 1 1 d . . . . .
C56 C 1.1142(4) 0.3303(2) 0.16706(14) 0.0555(14) Uani 1 1 d . . . . .
H56 H 1.1388 0.3110 0.1859 0.067 Uiso 1 1 calc R U . . .
C57 C 1.1891(5) 0.3661(2) 0.15208(16) 0.0649(16) Uani 1 1 d . . . . .
H57 H 1.2656 0.3709 0.1603 0.078 Uiso 1 1 calc R U . . .
C58 C 1.1500(5) 0.3946(2) 0.12482(16) 0.0652(17) Uani 1 1 d . . . . .
H58 H 1.1992 0.4192 0.1142 0.078 Uiso 1 1 calc R U . . .
C59 C 1.0378(5) 0.3862(2) 0.11357(14) 0.0589(15) Uani 1 1 d . . . . .
H59 H 1.0117 0.4060 0.0952 0.071 Uiso 1 1 calc R U . . .
C60 C 0.5996(4) 0.24205(19) 0.17759(13) 0.0470(13) Uani 1 1 d . . . . .
C61 C 0.5408(5) 0.2317(3) 0.20729(15) 0.077(2) Uani 1 1 d . . . . .
H61 H 0.5839 0.2246 0.2268 0.093 Uiso 1 1 calc R U . . .
C62 C 0.4177(5) 0.2318(3) 0.20845(18) 0.100(3) Uani 1 1 d . . . . .
H62 H 0.3788 0.2239 0.2285 0.120 Uiso 1 1 calc R U . . .
C63 C 0.3532(5) 0.2437(3) 0.17989(18) 0.102(3) Uani 1 1 d . . . . .
H63 H 0.2708 0.2438 0.1805 0.123 Uiso 1 1 calc R U . . .
C64 C 0.4122(4) 0.2553(3) 0.15051(16) 0.075(2) Uani 1 1 d . . . . .
H64 H 0.3690 0.2642 0.1313 0.090 Uiso 1 1 calc R U . . .
C65 C 0.5343(4) 0.25417(19) 0.14884(13) 0.0445(12) Uani 1 1 d . . . . .
C66 C 0.5886(4) 0.2601(2) 0.11475(13) 0.0441(12) Uani 1 1 d . . . . .
O7 O 0.7827(3) 0.34835(15) 0.08010(9) 0.0528(9) Uani 1 1 d D . . . .
H7A H 0.829(4) 0.348(2) 0.0973(9) 0.063 Uiso 1 1 d D U . . .
H7B H 0.786(5) 0.3156(9) 0.0754(13) 0.063 Uiso 1 1 d D U . . .
O8 O 0.7528(5) 0.2391(3) 0.04516(13) 0.122(2) Uani 1 1 d D . . . .
H8A H 0.718(6) 0.225(3) 0.0624(13) 0.146 Uiso 1 1 d D U . . .
H8B H 0.700(5) 0.250(3) 0.0311(16) 0.146 Uiso 1 1 d D U . . .
O9 O 0.5684(8) 0.6723(4) 0.0236(2) 0.120(3) Uani 0.6 1 d . . P . .
O9' O 0.5095(9) 0.7247(5) 0.0230(3) 0.098(4) Uani 0.4 1 d . . P . .
O10 O 0.9394(9) 0.4578(5) 0.0163(3) 0.138(4) Uani 0.5 1 d . . P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O4 80.43(11) . .
O5 Eu1 O7 76.91(12) . .
O4 Eu1 O7 74.27(11) . .
O5 Eu1 O2 128.45(11) . 5_665
O4 Eu1 O2 131.13(11) . 5_665
O7 Eu1 O2 76.05(12) . 5_665
O5 Eu1 N1 152.57(12) . .
O4 Eu1 N1 73.90(11) . .
O7 Eu1 N1 86.85(12) . .
O2 Eu1 N1 66.51(11) 5_665 .
O5 Eu1 N2 138.88(11) . .
O4 Eu1 N2 114.08(11) . .
O7 Eu1 N2 142.90(12) . .
O2 Eu1 N2 72.11(10) 5_665 .
N1 Eu1 N2 63.34(11) . .
O5 Eu1 N3 77.49(11) . .
O4 Eu1 N3 126.78(11) . .
O7 Eu1 N3 142.84(12) . .
O2 Eu1 N3 99.96(12) 5_665 .
N1 Eu1 N3 126.09(12) . .
N2 Eu1 N3 62.88(11) . .
O5 Eu1 O1 78.81(11) . 5_665
O4 Eu1 O1 141.37(10) . 5_665
O7 Eu1 O1 69.51(11) . 5_665
O2 Eu1 O1 50.77(11) 5_665 5_665
N1 Eu1 O1 116.18(11) . 5_665
N2 Eu1 O1 102.93(11) . 5_665
N3 Eu1 O1 79.43(11) . 5_665
O5 Eu1 C22 103.32(13) . 5_665
O4 Eu1 C22 139.71(12) . 5_665
O7 Eu1 C22 67.87(12) . 5_665
O2 Eu1 C22 25.29(12) 5_665 5_665
N1 Eu1 C22 90.46(13) . 5_665
N2 Eu1 C22 89.62(12) . 5_665
N3 Eu1 C22 92.60(12) . 5_665
O1 Eu1 C22 25.83(11) 5_665 5_665
C1 N1 C5 117.8(4) . .
C1 N1 Eu1 118.5(3) . .
C5 N1 Eu1 119.1(3) . .
C6 N2 C10 118.2(4) . .
C6 N2 Eu1 120.1(3) . .
C10 N2 Eu1 120.7(3) . .
C15 N3 C11 117.3(4) . .
C15 N3 Eu1 121.1(3) . .
C11 N3 Eu1 121.5(3) . .
C23 N4 C27 117.3(5) . .
C32 N5 C28 117.9(4) . .
C33 N6 C37 116.5(5) . .
C49 N7 C45 116.6(5) . .
C50 N8 C54 118.5(4) . .
C59 N9 C55 117.6(4) . .
C22 O1 Eu1 90.3(3) . 5_665
C22 O2 Eu1 95.5(3) . 5_665
C44 O4 Eu1 92.5(3) . .
C66 O5 Eu1 146.9(3) . .
N1 C1 C2 122.6(5) . .
N1 C1 H1 118.7 . .
C2 C1 H1 118.7 . .
C3 C2 C1 119.8(5) . .
C3 C2 H2 120.1 . .
C1 C2 H2 120.1 . .
C2 C3 C4 118.3(5) . .
C2 C3 H3 120.9 . .
C4 C3 H3 120.9 . .
C3 C4 C5 119.1(5) . .
C3 C4 H4 120.5 . .
C5 C4 H4 120.5 . .
N1 C5 C4 122.5(4) . .
N1 C5 C6 115.8(4) . .
C4 C5 C6 121.7(5) . .
N2 C6 C7 122.6(4) . .
N2 C6 C5 115.9(4) . .
C7 C6 C5 121.4(4) . .
C8 C7 C6 119.9(4) . .
C8 C7 H7 120.0 . .
C6 C7 H7 120.0 . .
C7 C8 C9 116.5(4) . .
C7 C8 C16 122.9(4) . .
C9 C8 C16 120.6(4) . .
C10 C9 C8 121.4(4) . .
C10 C9 H9 119.3 . .
C8 C9 H9 119.3 . .
N2 C10 C9 121.2(4) . .
N2 C10 C11 116.9(4) . .
C9 C10 C11 121.9(4) . .
N3 C11 C12 121.7(4) . .
N3 C11 C10 116.3(4) . .
C12 C11 C10 122.0(4) . .
C13 C12 C11 119.2(5) . .
C13 C12 H12 120.4 . .
C11 C12 H12 120.4 . .
C14 C13 C12 118.9(5) . .
C14 C13 H13 120.5 . .
C12 C13 H13 120.5 . .
C15 C14 C13 118.7(5) . .
C15 C14 H14 120.7 . .
C13 C14 H14 120.7 . .
N3 C15 C14 124.1(5) . .
N3 C15 H15 118.0 . .
C14 C15 H15 118.0 . .
C21 C16 C17 119.1(4) . .
C21 C16 C8 123.2(4) . .
C17 C16 C8 117.6(4) . .
C18 C17 C16 120.5(5) . .
C18 C17 H17 119.7 . .
C16 C17 H17 119.7 . .
C19 C18 C17 120.8(5) . .
C19 C18 H18 119.6 . .
C17 C18 H18 119.6 . .
C18 C19 C20 119.3(5) . .
C18 C19 H19 120.4 . .
C20 C19 H19 120.4 . .
C21 C20 C19 120.7(5) . .
C21 C20 H20 119.6 . .
C19 C20 H20 119.6 . .
C16 C21 C20 119.5(4) . .
C16 C21 C22 121.2(4) . .
C20 C21 C22 118.9(4) . .
O2 C22 O1 121.8(5) . .
O2 C22 C21 118.1(4) . .
O1 C22 C21 120.0(4) . .
O2 C22 Eu1 59.2(2) . 5_665
O1 C22 Eu1 63.9(3) . 5_665
C21 C22 Eu1 164.5(3) . 5_665
N4 C23 C24 124.7(5) . .
N4 C23 H23 117.7 . .
C24 C23 H23 117.7 . .
C23 C24 C25 118.2(5) . .
C23 C24 H24 120.9 . .
C25 C24 H24 120.9 . .
C24 C25 C26 118.6(5) . .
C24 C25 H25 120.7 . .
C26 C25 H25 120.7 . .
C25 C26 C27 119.4(5) . .
C25 C26 H26 120.3 . .
C27 C26 H26 120.3 . .
N4 C27 C26 121.8(5) . .
N4 C27 C28 117.4(4) . .
C26 C27 C28 120.8(5) . .
N5 C28 C29 121.9(4) . .
N5 C28 C27 116.1(4) . .
C29 C28 C27 121.9(4) . .
C30 C29 C28 120.2(4) . .
C30 C29 H29 119.9 . .
C28 C29 H29 119.9 . .
C29 C30 C31 117.6(4) . .
C29 C30 C38 120.4(4) . .
C31 C30 C38 121.8(4) . .
C32 C31 C30 119.2(4) . .
C32 C31 H31 120.4 . .
C30 C31 H31 120.4 . .
N5 C32 C31 123.2(4) . .
N5 C32 C33 114.8(4) . .
C31 C32 C33 122.0(5) . .
N6 C33 C34 122.5(5) . .
N6 C33 C32 116.3(5) . .
C34 C33 C32 121.2(5) . .
C35 C34 C33 119.0(6) . .
C35 C34 H34 120.5 . .
C33 C34 H34 120.5 . .
C36 C35 C34 119.2(7) . .
C36 C35 H35 120.4 . .
C34 C35 H35 120.4 . .
C37 C36 C35 118.4(6) . .
C37 C36 H36 120.8 . .
C35 C36 H36 120.8 . .
N6 C37 C36 124.3(7) . .
N6 C37 H37 117.9 . .
C36 C37 H37 117.9 . .
C39 C38 C43 118.1(4) . .
C39 C38 C30 117.0(4) . .
C43 C38 C30 124.6(4) . .
C40 C39 C38 122.3(5) . .
C40 C39 H39 118.9 . .
C38 C39 H39 118.9 . .
C41 C40 C39 118.4(5) . .
C41 C40 H40 120.8 . .
C39 C40 H40 120.8 . .
C40 C41 C42 120.9(5) . .
C40 C41 H41 119.6 . .
C42 C41 H41 119.6 . .
C41 C42 C43 120.9(5) . .
C41 C42 H42 119.5 . .
C43 C42 H42 119.5 . .
C42 C43 C38 119.3(4) . .
C42 C43 C44 116.7(4) . .
C38 C43 C44 123.7(4) . .
O3 C44 O4 121.0(4) . .
O3 C44 C43 120.0(4) . .
O4 C44 C43 118.9(4) . .
N7 C45 C46 124.0(7) . .
N7 C45 H45 118.0 . .
C46 C45 H45 118.0 . .
C47 C46 C45 118.6(6) . .
C47 C46 H46 120.7 . .
C45 C46 H46 120.7 . .
C46 C47 C48 118.8(6) . .
C46 C47 H47 120.6 . .
C48 C47 H47 120.6 . .
C47 C48 C49 120.0(6) . .
C47 C48 H48 120.0 . .
C49 C48 H48 120.0 . .
N7 C49 C48 121.9(5) . .
N7 C49 C50 117.1(4) . .
C48 C49 C50 121.0(5) . .
N8 C50 C51 122.3(4) . .
N8 C50 C49 116.9(4) . .
C51 C50 C49 120.9(5) . .
C52 C51 C50 120.2(4) . .
C52 C51 H51 119.9 . .
C50 C51 H51 119.9 . .
C51 C52 C53 117.2(4) . .
C51 C52 C60 120.3(4) . .
C53 C52 C60 122.4(4) . .
C52 C53 C54 119.8(4) . .
C52 C53 H53 120.1 . .
C54 C53 H53 120.1 . .
N8 C54 C53 122.0(4) . .
N8 C54 C55 114.8(4) . .
C53 C54 C55 123.2(4) . .
N9 C55 C56 121.1(5) . .
N9 C55 C54 118.6(4) . .
C56 C55 C54 120.2(5) . .
C57 C56 C55 119.5(5) . .
C57 C56 H56 120.3 . .
C55 C56 H56 120.3 . .
C58 C57 C56 119.1(5) . .
C58 C57 H57 120.4 . .
C56 C57 H57 120.4 . .
C59 C58 C57 118.5(5) . .
C59 C58 H58 120.7 . .
C57 C58 H58 120.7 . .
N9 C59 C58 124.1(5) . .
N9 C59 H59 117.9 . .
C58 C59 H59 117.9 . .
C61 C60 C65 119.2(4) . .
C61 C60 C52 117.3(5) . .
C65 C60 C52 123.5(4) . .
C60 C61 C62 120.6(6) . .
C60 C61 H61 119.7 . .
C62 C61 H61 119.7 . .
C63 C62 C61 120.0(6) . .
C63 C62 H62 120.0 . .
C61 C62 H62 120.0 . .
C64 C63 C62 119.1(5) . .
C64 C63 H63 120.4 . .
C62 C63 H63 120.4 . .
C63 C64 C65 121.3(5) . .
C63 C64 H64 119.3 . .
C65 C64 H64 119.3 . .
C64 C65 C60 119.6(5) . .
C64 C65 C66 116.8(5) . .
C60 C65 C66 123.2(4) . .
O6 C66 O5 125.2(5) . .
O6 C66 C65 118.2(4) . .
O5 C66 C65 116.5(4) . .
Eu1 O7 H7A 127(3) . .
Eu1 O7 H7B 113(4) . .
H7A O7 H7B 98(5) . .
H8A O8 H8B 109(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.317(3) .
Eu1 O4 2.448(3) .
Eu1 O7 2.471(3) .
Eu1 O2 2.495(3) 5_665
Eu1 N1 2.569(4) .
Eu1 N2 2.587(3) .
Eu1 N3 2.594(4) .
Eu1 O1 2.597(3) 5_665
Eu1 C22 2.892(5) 5_665
N1 C1 1.335(6) .
N1 C5 1.338(6) .
N2 C6 1.341(5) .
N2 C10 1.348(5) .
N3 C15 1.333(5) .
N3 C11 1.344(5) .
N4 C23 1.322(6) .
N4 C27 1.342(6) .
N5 C32 1.338(6) .
N5 C28 1.339(6) .
N6 C33 1.338(6) .
N6 C37 1.351(7) .
N7 C49 1.326(6) .
N7 C45 1.344(7) .
N8 C50 1.332(6) .
N8 C54 1.342(6) .
N9 C59 1.335(6) .
N9 C55 1.345(6) .
O1 C22 1.260(5) .
O1 Eu1 2.597(3) 5_665
O2 C22 1.241(5) .
O2 Eu1 2.495(3) 5_665
O3 C44 1.257(5) .
O4 C44 1.268(5) .
O5 C66 1.278(5) .
O6 C66 1.235(5) .
C1 C2 1.377(7) .
C1 H1 0.9300 .
C2 C3 1.363(8) .
C2 H2 0.9300 .
C3 C4 1.382(7) .
C3 H3 0.9300 .
C4 C5 1.383(6) .
C4 H4 0.9300 .
C5 C6 1.486(6) .
C6 C7 1.391(6) .
C7 C8 1.385(6) .
C7 H7 0.9300 .
C8 C9 1.389(6) .
C8 C16 1.471(6) .
C9 C10 1.383(6) .
C9 H9 0.9300 .
C10 C11 1.483(6) .
C11 C12 1.386(6) .
C12 C13 1.376(6) .
C12 H12 0.9300 .
C13 C14 1.365(7) .
C13 H13 0.9300 .
C14 C15 1.363(6) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C21 1.387(6) .
C16 C17 1.395(6) .
C17 C18 1.378(7) .
C17 H17 0.9300 .
C18 C19 1.363(7) .
C18 H18 0.9300 .
C19 C20 1.392(6) .
C19 H19 0.9300 .
C20 C21 1.391(6) .
C20 H20 0.9300 .
C21 C22 1.512(6) .
C22 Eu1 2.892(5) 5_665
C23 C24 1.365(7) .
C23 H23 0.9300 .
C24 C25 1.373(7) .
C24 H24 0.9300 .
C25 C26 1.377(7) .
C25 H25 0.9300 .
C26 C27 1.384(6) .
C26 H26 0.9300 .
C27 C28 1.480(6) .
C28 C29 1.387(6) .
C29 C30 1.376(6) .
C29 H29 0.9300 .
C30 C31 1.391(6) .
C30 C38 1.494(6) .
C31 C32 1.375(6) .
C31 H31 0.9300 .
C32 C33 1.496(6) .
C33 C34 1.377(7) .
C34 C35 1.376(8) .
C34 H34 0.9300 .
C35 C36 1.367(9) .
C35 H35 0.9300 .
C36 C37 1.354(9) .
C36 H36 0.9300 .
C37 H37 0.9300 .
C38 C39 1.390(7) .
C38 C43 1.399(6) .
C39 C40 1.389(7) .
C39 H39 0.9300 .
C40 C41 1.367(8) .
C40 H40 0.9300 .
C41 C42 1.376(7) .
C41 H41 0.9300 .
C42 C43 1.390(6) .
C42 H42 0.9300 .
C43 C44 1.502(6) .
C45 C46 1.361(9) .
C45 H45 0.9300 .
C46 C47 1.346(8) .
C46 H46 0.9300 .
C47 C48 1.365(7) .
C47 H47 0.9300 .
C48 C49 1.372(6) .
C48 H48 0.9300 .
C49 C50 1.493(6) .
C50 C51 1.386(6) .
C51 C52 1.382(6) .
C51 H51 0.9300 .
C52 C53 1.390(6) .
C52 C60 1.492(6) .
C53 C54 1.391(6) .
C53 H53 0.9300 .
C54 C55 1.477(6) .
C55 C56 1.393(6) .
C56 C57 1.370(7) .
C56 H56 0.9300 .
C57 C58 1.369(8) .
C57 H57 0.9300 .
C58 C59 1.358(7) .
C58 H58 0.9300 .
C59 H59 0.9300 .
C60 C61 1.376(7) .
C60 C65 1.390(6) .
C61 C62 1.389(7) .
C61 H61 0.9300 .
C62 C63 1.378(8) .
C62 H62 0.9300 .
C63 C64 1.372(8) .
C63 H63 0.9300 .
C64 C65 1.378(6) .
C64 H64 0.9300 .
C65 C66 1.491(7) .
O7 H7A 0.855(19) .
O7 H7B 0.844(19) .
O8 H8A 0.86(2) .
O8 H8B 0.86(2) .
O9 O9' 1.475(13) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C5 N1 C1 C2 -1.8(8) . . . .
Eu1 N1 C1 C2 153.9(4) . . . .
N1 C1 C2 C3 -0.6(9) . . . .
C1 C2 C3 C4 2.5(9) . . . .
C2 C3 C4 C5 -2.0(9) . . . .
C1 N1 C5 C4 2.3(7) . . . .
Eu1 N1 C5 C4 -153.3(4) . . . .
C1 N1 C5 C6 -176.9(4) . . . .
Eu1 N1 C5 C6 27.5(5) . . . .
C3 C4 C5 N1 -0.4(8) . . . .
C3 C4 C5 C6 178.8(5) . . . .
C10 N2 C6 C7 1.6(6) . . . .
Eu1 N2 C6 C7 -166.5(3) . . . .
C10 N2 C6 C5 179.6(4) . . . .
Eu1 N2 C6 C5 11.5(5) . . . .
N1 C5 C6 N2 -25.6(6) . . . .
C4 C5 C6 N2 155.2(4) . . . .
N1 C5 C6 C7 152.4(4) . . . .
C4 C5 C6 C7 -26.8(7) . . . .
N2 C6 C7 C8 2.4(7) . . . .
C5 C6 C7 C8 -175.4(4) . . . .
C6 C7 C8 C9 -3.8(6) . . . .
C6 C7 C8 C16 174.5(4) . . . .
C7 C8 C9 C10 1.4(6) . . . .
C16 C8 C9 C10 -177.0(4) . . . .
C6 N2 C10 C9 -4.2(6) . . . .
Eu1 N2 C10 C9 163.9(3) . . . .
C6 N2 C10 C11 176.4(4) . . . .
Eu1 N2 C10 C11 -15.6(5) . . . .
C8 C9 C10 N2 2.7(7) . . . .
C8 C9 C10 C11 -177.8(4) . . . .
C15 N3 C11 C12 -2.3(7) . . . .
Eu1 N3 C11 C12 175.9(3) . . . .
C15 N3 C11 C10 177.3(4) . . . .
Eu1 N3 C11 C10 -4.5(5) . . . .
N2 C10 C11 N3 13.1(6) . . . .
C9 C10 C11 N3 -166.4(4) . . . .
N2 C10 C11 C12 -167.4(4) . . . .
C9 C10 C11 C12 13.2(7) . . . .
N3 C11 C12 C13 2.3(7) . . . .
C10 C11 C12 C13 -177.3(4) . . . .
C11 C12 C13 C14 -1.4(8) . . . .
C12 C13 C14 C15 0.7(8) . . . .
C11 N3 C15 C14 1.6(7) . . . .
Eu1 N3 C15 C14 -176.7(4) . . . .
C13 C14 C15 N3 -0.8(8) . . . .
C7 C8 C16 C21 63.3(6) . . . .
C9 C8 C16 C21 -118.4(5) . . . .
C7 C8 C16 C17 -114.5(5) . . . .
C9 C8 C16 C17 63.8(6) . . . .
C21 C16 C17 C18 1.4(7) . . . .
C8 C16 C17 C18 179.3(4) . . . .
C16 C17 C18 C19 0.8(7) . . . .
C17 C18 C19 C20 -2.3(7) . . . .
C18 C19 C20 C21 1.6(7) . . . .
C17 C16 C21 C20 -2.1(6) . . . .
C8 C16 C21 C20 -179.8(4) . . . .
C17 C16 C21 C22 -175.4(4) . . . .
C8 C16 C21 C22 6.8(7) . . . .
C19 C20 C21 C16 0.6(7) . . . .
C19 C20 C21 C22 174.1(4) . . . .
Eu1 O2 C22 O1 -13.8(5) 5_665 . . .
Eu1 O2 C22 C21 162.4(3) 5_665 . . .
Eu1 O1 C22 O2 13.1(5) 5_665 . . .
Eu1 O1 C22 C21 -162.9(4) 5_665 . . .
C16 C21 C22 O2 41.7(6) . . . .
C20 C21 C22 O2 -131.6(5) . . . .
C16 C21 C22 O1 -142.1(4) . . . .
C20 C21 C22 O1 44.6(6) . . . .
C16 C21 C22 Eu1 117.4(12) . . . 5_665
C20 C21 C22 Eu1 -56.0(14) . . . 5_665
C27 N4 C23 C24 0.4(8) . . . .
N4 C23 C24 C25 -0.3(9) . . . .
C23 C24 C25 C26 -0.2(8) . . . .
C24 C25 C26 C27 0.5(8) . . . .
C23 N4 C27 C26 -0.1(7) . . . .
C23 N4 C27 C28 -178.3(4) . . . .
C25 C26 C27 N4 -0.4(7) . . . .
C25 C26 C27 C28 177.8(4) . . . .
C32 N5 C28 C29 1.9(6) . . . .
C32 N5 C28 C27 -175.3(4) . . . .
N4 C27 C28 N5 -176.8(4) . . . .
C26 C27 C28 N5 5.0(6) . . . .
N4 C27 C28 C29 6.1(7) . . . .
C26 C27 C28 C29 -172.2(4) . . . .
N5 C28 C29 C30 -3.1(7) . . . .
C27 C28 C29 C30 174.0(4) . . . .
C28 C29 C30 C31 1.8(6) . . . .
C28 C29 C30 C38 -172.5(4) . . . .
C29 C30 C31 C32 0.4(6) . . . .
C38 C30 C31 C32 174.6(4) . . . .
C28 N5 C32 C31 0.5(7) . . . .
C28 N5 C32 C33 -178.5(4) . . . .
C30 C31 C32 N5 -1.6(7) . . . .
C30 C31 C32 C33 177.3(4) . . . .
C37 N6 C33 C34 0.8(8) . . . .
C37 N6 C33 C32 -179.3(4) . . . .
N5 C32 C33 N6 162.8(4) . . . .
C31 C32 C33 N6 -16.2(7) . . . .
N5 C32 C33 C34 -17.3(7) . . . .
C31 C32 C33 C34 163.7(5) . . . .
N6 C33 C34 C35 -0.4(8) . . . .
C32 C33 C34 C35 179.7(5) . . . .
C33 C34 C35 C36 -0.2(9) . . . .
C34 C35 C36 C37 0.3(10) . . . .
C33 N6 C37 C36 -0.8(9) . . . .
C35 C36 C37 N6 0.2(10) . . . .
C29 C30 C38 C39 125.0(5) . . . .
C31 C30 C38 C39 -49.0(7) . . . .
C29 C30 C38 C43 -48.1(7) . . . .
C31 C30 C38 C43 137.8(5) . . . .
C43 C38 C39 C40 2.5(9) . . . .
C30 C38 C39 C40 -171.2(6) . . . .
C38 C39 C40 C41 0.8(10) . . . .
C39 C40 C41 C42 -3.0(11) . . . .
C40 C41 C42 C43 1.8(11) . . . .
C41 C42 C43 C38 1.6(9) . . . .
C41 C42 C43 C44 -172.6(6) . . . .
C39 C38 C43 C42 -3.6(8) . . . .
C30 C38 C43 C42 169.5(5) . . . .
C39 C38 C43 C44 170.1(5) . . . .
C30 C38 C43 C44 -16.8(8) . . . .
Eu1 O4 C44 O3 -6.2(5) . . . .
Eu1 O4 C44 C43 170.1(4) . . . .
C42 C43 C44 O3 148.3(5) . . . .
C38 C43 C44 O3 -25.6(7) . . . .
C42 C43 C44 O4 -28.1(7) . . . .
C38 C43 C44 O4 158.0(5) . . . .
C49 N7 C45 C46 -1.3(9) . . . .
N7 C45 C46 C47 -1.1(10) . . . .
C45 C46 C47 C48 1.4(9) . . . .
C46 C47 C48 C49 0.8(9) . . . .
C45 N7 C49 C48 3.5(8) . . . .
C45 N7 C49 C50 -178.7(5) . . . .
C47 C48 C49 N7 -3.4(8) . . . .
C47 C48 C49 C50 178.9(5) . . . .
C54 N8 C50 C51 -3.2(7) . . . .
C54 N8 C50 C49 177.3(4) . . . .
N7 C49 C50 N8 178.9(4) . . . .
C48 C49 C50 N8 -3.3(6) . . . .
N7 C49 C50 C51 -0.6(7) . . . .
C48 C49 C50 C51 177.2(5) . . . .
N8 C50 C51 C52 2.1(7) . . . .
C49 C50 C51 C52 -178.4(4) . . . .
C50 C51 C52 C53 -0.1(7) . . . .
C50 C51 C52 C60 -177.5(4) . . . .
C51 C52 C53 C54 -0.8(7) . . . .
C60 C52 C53 C54 176.6(4) . . . .
C50 N8 C54 C53 2.3(7) . . . .
C50 N8 C54 C55 -178.0(4) . . . .
C52 C53 C54 N8 -0.3(7) . . . .
C52 C53 C54 C55 180.0(4) . . . .
C59 N9 C55 C56 1.0(7) . . . .
C59 N9 C55 C54 -175.7(4) . . . .
N8 C54 C55 N9 155.0(4) . . . .
C53 C54 C55 N9 -25.3(7) . . . .
N8 C54 C55 C56 -21.7(6) . . . .
C53 C54 C55 C56 158.0(5) . . . .
N9 C55 C56 C57 -1.7(7) . . . .
C54 C55 C56 C57 175.0(5) . . . .
C55 C56 C57 C58 1.2(8) . . . .
C56 C57 C58 C59 -0.1(8) . . . .
C55 N9 C59 C58 0.2(8) . . . .
C57 C58 C59 N9 -0.6(9) . . . .
C51 C52 C60 C61 45.7(7) . . . .
C53 C52 C60 C61 -131.6(5) . . . .
C51 C52 C60 C65 -136.9(5) . . . .
C53 C52 C60 C65 45.8(7) . . . .
C65 C60 C61 C62 1.9(9) . . . .
C52 C60 C61 C62 179.3(6) . . . .
C60 C61 C62 C63 -1.7(12) . . . .
C61 C62 C63 C64 0.0(12) . . . .
C62 C63 C64 C65 1.5(11) . . . .
C63 C64 C65 C60 -1.4(10) . . . .
C63 C64 C65 C66 171.8(6) . . . .
C61 C60 C65 C64 -0.4(8) . . . .
C52 C60 C65 C64 -177.7(5) . . . .
C61 C60 C65 C66 -173.1(5) . . . .
C52 C60 C65 C66 9.6(8) . . . .
Eu1 O5 C66 O6 -86.3(7) . . . .
Eu1 O5 C66 C65 98.1(6) . . . .
C64 C65 C66 O6 -127.5(5) . . . .
C60 C65 C66 O6 45.4(7) . . . .
C64 C65 C66 O5 48.4(7) . . . .
C60 C65 C66 O5 -138.6(5) . . . .
