#------------------------------------------------------------------------------
#$Date: 2022-08-24 01:07:24 +0300 (Wed, 24 Aug 2022) $
#$Revision: 277359 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/75/1567522.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1567522
loop_
_publ_author_name
'Som, Salina'
'Choi, Jongwook'
'Katsoulis, Dimitris'
'Lee, Kangsang L.'
_publ_section_title
;
 Direct Method to Access Various Functional Arylalkoxysilanes by
 Rh-catalysed Intermolecular C--H Silylation of Alkoxysilane
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/D2SC03727K
_journal_year                    2022
_chemical_formula_sum            'C34 H36 Cl P2 Rh'
_chemical_formula_weight         644.93
_chemical_properties_physical    Air-sensitive,Moisture-sensitive,Hygroscopic
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2022-04-13 deposited with the CCDC.	2022-08-19 downloaded from the CCDC.
;
_cell_angle_alpha                107.8640(10)
_cell_angle_beta                 101.0930(10)
_cell_angle_gamma                112.0990(10)
_cell_formula_units_Z            2
_cell_length_a                   10.3091(3)
_cell_length_b                   12.7665(4)
_cell_length_c                   13.3424(4)
_cell_measurement_reflns_used    9975
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.43
_cell_measurement_theta_min      2.28
_cell_volume                     1451.17(8)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0180
_diffrn_reflns_av_unetI/netI     0.0279
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            26262
_diffrn_reflns_point_group_measured_fraction_full 0.868
_diffrn_reflns_point_group_measured_fraction_max 0.842
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         28.431
_diffrn_reflns_theta_min         1.711
_exptl_absorpt_coefficient_mu    0.813
_exptl_absorpt_correction_T_max  1.0
_exptl_absorpt_correction_T_min  0.915
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.476
_exptl_crystal_description       rectangular
_exptl_crystal_F_000             664
_exptl_crystal_size_max          0.333
_exptl_crystal_size_mid          0.186
_exptl_crystal_size_min          0.072
_refine_diff_density_max         0.597
_refine_diff_density_min         -0.438
_refine_diff_density_rms         0.054
_refine_ls_abs_structure_details
; 
 Flack x determined using 4568 quotients [(I+)-(I-)]/[(I+)+(I-)] 
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259). 
;
_refine_ls_abs_structure_Flack   -0.006(7)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         12341
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0227
_refine_ls_R_factor_gt           0.0203
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0224P)²+0.2021P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0459
_refine_ls_wR_factor_ref         0.0469
_reflns_Friedel_coverage         0.690
_reflns_Friedel_fraction_full    0.735
_reflns_Friedel_fraction_max     0.688
_reflns_number_gt                11705
_reflns_number_total             12341
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2sc03727k2.cif
_cod_data_source_block           absp1bar_b
_cod_database_code               1567522
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.773
_shelx_estimated_absorpt_t_max   0.944
loop_
_space_group_symop_operation_xyz
'x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh01 Rh 0.44070(2) 0.49003(2) 1.02681(2) 0.01042(6) Uani 1 1 d . . . . .
Rh02 Rh 0.49935(2) 0.52114(2) 0.77918(2) 0.01046(6) Uani 1 1 d . . . . .
Cl1 Cl 0.34118(10) 0.54982(8) 0.88585(7) 0.01437(19) Uani 1 1 d . . . . .
P3 P 0.51510(10) 0.43223(8) 1.15351(7) 0.01107(18) Uani 1 1 d . . . . .
P4 P 0.29163(10) 0.51823(8) 1.11392(8) 0.01156(18) Uani 1 1 d . . . . .
P1 P 0.62972(10) 0.48794(8) 0.67601(7) 0.01206(18) Uani 1 1 d . . . . .
P2 P 0.41877(10) 0.58980(8) 0.66552(8) 0.01211(18) Uani 1 1 d . . . . .
Cl2 Cl 0.60607(10) 0.46746(8) 0.92294(7) 0.01484(19) Uani 1 1 d . . . . .
C42 C 0.3439(5) 0.0817(3) 1.3137(3) 0.0248(9) Uani 1 1 d . . . . .
H42 H 0.3156 0.0400 1.3599 0.030 Uiso 1 1 calc R U . . .
C18 C 0.4782(4) 0.5608(3) 0.5428(3) 0.0167(7) Uani 1 1 d . . . . .
H18A H 0.4043 0.4786 0.4819 0.020 Uiso 1 1 calc R U . . .
H18B H 0.4857 0.6253 0.5144 0.020 Uiso 1 1 calc R U . . .
C38 C 0.7101(4) 0.4725(3) 1.2269(3) 0.0152(7) Uani 1 1 d . . . . .
H38 H 0.7076 0.4441 1.2888 0.018 Uiso 1 1 calc R U . . .
C35 C 0.4628(4) 0.2628(3) 1.0963(3) 0.0149(7) Uani 1 1 d . . . . .
H35 H 0.3724 0.2186 1.0267 0.018 Uiso 1 1 calc R U . . .
C29 C 0.1229(4) 0.4109(3) 0.5196(3) 0.0167(7) Uani 1 1 d . . . . .
C34 C 0.1047(4) 0.3171(3) 0.5569(3) 0.0211(7) Uani 1 1 d . . . . .
H34 H 0.1538 0.3387 0.6336 0.025 Uiso 1 1 calc R U . . .
C26 C 0.6052(5) 0.9120(3) 1.0845(3) 0.0317(9) Uani 1 1 d . . . . .
H26 H 0.6347 0.9439 1.1641 0.038 Uiso 1 1 calc R U . . .
C17 C 0.6296(4) 0.5643(3) 0.5788(3) 0.0178(7) Uani 1 1 d . . . . .
H17A H 0.7098 0.6516 0.6167 0.021 Uiso 1 1 calc R U . . .
H17B H 0.6480 0.5204 0.5122 0.021 Uiso 1 1 calc R U . . .
C4 C 0.8277(3) 0.5282(3) 0.7400(3) 0.0151(6) Uani 1 1 d . . . . .
H4 H 0.8316 0.4955 0.7991 0.018 Uiso 1 1 calc R U . . .
C16 C 0.9544(3) 0.7288(3) 0.9125(3) 0.0181(6) Uani 1 1 d . . . . .
H16 H 0.9103 0.6834 0.9520 0.022 Uiso 1 1 calc R U . . .
C9 C 0.5779(4) 0.1423(3) 0.7605(3) 0.0252(7) Uani 1 1 d . . . . .
H9 H 0.6451 0.1245 0.8031 0.030 Uiso 1 1 calc R U . . .
C57 C 0.0203(3) 0.3106(3) 0.9511(3) 0.0185(6) Uani 1 1 d . . . . .
C47 C 0.9473(3) 0.8063(3) 1.2730(3) 0.0215(6) Uani 1 1 d . . . . .
H47 H 0.9638 0.8539 1.2299 0.026 Uiso 1 1 calc R U . . .
C27 C 0.4745(5) 0.8999(3) 1.0213(3) 0.0274(9) Uani 1 1 d . . . . .
H27 H 0.4135 0.9245 1.0576 0.033 Uiso 1 1 calc R U . . .
C10 C 0.6272(3) 0.2149(3) 0.7033(3) 0.0210(6) Uani 1 1 d . . . . .
H10 H 0.7284 0.2466 0.7074 0.025 Uiso 1 1 calc R U . . .
C2 C 0.7242(3) 0.3391(3) 0.5537(3) 0.0220(6) Uani 1 1 d . . . . .
H2A H 0.7156 0.3494 0.4826 0.026 Uiso 1 1 calc R U . . .
H2B H 0.7329 0.2620 0.5427 0.026 Uiso 1 1 calc R U . . .
C50 C 0.8966(4) 0.6679(3) 1.3971(3) 0.0213(7) Uani 1 1 d . . . . .
H50 H 0.8788 0.6208 1.4406 0.026 Uiso 1 1 calc R U . . .
C22 C 0.2183(4) 0.5455(3) 0.6013(3) 0.0153(7) Uani 1 1 d . . . . .
H22 H 0.1783 0.5593 0.6641 0.018 Uiso 1 1 calc R U . . .
C53 C 0.0834(3) 0.4390(3) 1.0424(3) 0.0172(7) Uani 1 1 d . . . . .
H53 H 0.0399 0.4281 1.1015 0.021 Uiso 1 1 calc R U . . .
C8 C 0.4305(5) 0.0959(3) 0.7555(3) 0.0265(9) Uani 1 1 d . . . . .
H8 H 0.3967 0.0468 0.7950 0.032 Uiso 1 1 calc R U . . .
C67 C 0.4641(4) 0.9106(3) 1.4625(3) 0.0241(7) Uani 1 1 d . . . . .
H67 H 0.4308 0.9512 1.5164 0.029 Uiso 1 1 calc R U . . .
C45 C 0.8210(4) 0.6092(3) 1.2822(3) 0.0159(7) Uani 1 1 d . . . . .
C30 C 0.0476(4) 0.3760(4) 0.4060(3) 0.0240(8) Uani 1 1 d . . . . .
H30 H 0.0579 0.4380 0.3786 0.029 Uiso 1 1 calc R U . . .
C52 C 0.3075(3) 0.4804(3) 1.2374(3) 0.0141(6) Uani 1 1 d . . . . .
H52A H 0.3026 0.5436 1.2997 0.017 Uiso 1 1 calc R U . . .
H52B H 0.2234 0.3983 1.2180 0.017 Uiso 1 1 calc R U . . .
C11 C 0.9286(3) 0.6664(3) 0.7993(3) 0.0158(6) Uani 1 1 d . . . . .
C31 C -0.0420(4) 0.2510(4) 0.3335(3) 0.0299(8) Uani 1 1 d . . . . .
H31 H -0.0927 0.2284 0.2568 0.036 Uiso 1 1 calc R U . . .
C39 C 0.4272(3) 0.2022(2) 1.1756(2) 0.0157(5) Uani 1 1 d . . . . .
C48 C 1.0241(3) 0.8633(3) 1.3888(3) 0.0244(7) Uani 1 1 d . . . . .
H48 H 1.0939 0.9493 1.4246 0.029 Uiso 1 1 calc R U . . .
C32 C -0.0578(4) 0.1599(3) 0.3715(3) 0.0271(7) Uani 1 1 d . . . . .
H32 H -0.1188 0.0747 0.3214 0.033 Uiso 1 1 calc R U . . .
C60 C -0.0862(4) 0.0701(3) 0.7883(3) 0.0353(8) Uani 1 1 d . . . . .
H60 H -0.1215 -0.0116 0.7332 0.042 Uiso 1 1 calc R U . . .
C49 C 0.9979(4) 0.7941(3) 1.4506(3) 0.0264(8) Uani 1 1 d . . . . .
H49 H 1.0487 0.8322 1.5296 0.032 Uiso 1 1 calc R U . . .
C19 C 0.4722(4) 0.7599(3) 0.7214(3) 0.0190(7) Uani 1 1 d . . . . .
H19 H 0.5615 0.8019 0.7024 0.023 Uiso 1 1 calc R U . . .
C6 C 0.3829(3) 0.1941(3) 0.6358(3) 0.0198(6) Uani 1 1 d . . . . .
H6 H 0.3155 0.2117 0.5930 0.024 Uiso 1 1 calc R U . . .
C41 C 0.4810(4) 0.1097(3) 1.3010(3) 0.0224(7) Uani 1 1 d . . . . .
H41 H 0.5470 0.0870 1.3385 0.027 Uiso 1 1 calc R U . . .
C13 C 1.0794(3) 0.8641(3) 0.7987(3) 0.0239(6) Uani 1 1 d . . . . .
H13 H 1.1203 0.9106 0.7588 0.029 Uiso 1 1 calc R U . . .
C59 C -0.0921(4) 0.0886(3) 0.8943(4) 0.0399(9) Uani 1 1 d . . . . .
H59 H -0.1320 0.0192 0.9121 0.048 Uiso 1 1 calc R U . . .
C65 C 0.6607(4) 0.8782(3) 1.4114(3) 0.0268(7) Uani 1 1 d . . . . .
H65 H 0.7624 0.8955 1.4308 0.032 Uiso 1 1 calc R U . . .
C20 C 0.3410(4) 0.7705(3) 0.6539(3) 0.0280(7) Uani 1 1 d . . . . .
H20A H 0.2926 0.8013 0.7048 0.034 Uiso 1 1 calc R U . . .
H20B H 0.3799 0.8313 0.6219 0.034 Uiso 1 1 calc R U . . .
C44 C 0.2881(3) 0.1728(3) 1.1889(3) 0.0209(6) Uani 1 1 d . . . . .
H44 H 0.2204 0.1928 1.1497 0.025 Uiso 1 1 calc R U . . .
C58 C -0.0401(3) 0.2077(3) 0.9751(3) 0.0285(7) Uani 1 1 d . . . . .
H58 H -0.0457 0.2192 1.0477 0.034 Uiso 1 1 calc R U . . .
C62 C 0.0250(3) 0.2910(3) 0.8445(3) 0.0220(6) Uani 1 1 d . . . . .
H62 H 0.0652 0.3601 0.8263 0.026 Uiso 1 1 calc R U . . .
C33 C 0.0157(4) 0.1930(3) 0.4834(3) 0.0248(7) Uani 1 1 d . . . . .
H33 H 0.0051 0.1302 0.5100 0.030 Uiso 1 1 calc R U . . .
C24 C 0.6509(3) 0.8301(3) 0.9142(3) 0.0231(6) Uani 1 1 d . . . . .
H24 H 0.7130 0.8065 0.8784 0.028 Uiso 1 1 calc R U . . .
C46 C 0.8470(4) 0.6804(3) 1.2207(3) 0.0193(7) Uani 1 1 d . . . . .
H46 H 0.7954 0.6423 1.1419 0.023 Uiso 1 1 calc R U . . .
C64 C 0.5614(3) 0.7954(3) 1.3047(3) 0.0221(6) Uani 1 1 d . . . . .
H64 H 0.5961 0.7569 1.2507 0.027 Uiso 1 1 calc R U . . .
C21 C 0.2263(3) 0.6450(3) 0.5594(3) 0.0204(6) Uani 1 1 d . . . . .
H21A H 0.1274 0.6425 0.5384 0.024 Uiso 1 1 calc R U . . .
H21B H 0.2565 0.6308 0.4923 0.024 Uiso 1 1 calc R U . . .
C1 C 0.5823(3) 0.3265(3) 0.5821(2) 0.0161(5) Uani 1 1 d . . . . .
H1 H 0.4989 0.2972 0.5113 0.019 Uiso 1 1 calc R U . . .
C12 C 0.9929(3) 0.7359(3) 0.7432(3) 0.0192(6) Uani 1 1 d . . . . .
H12 H 0.9772 0.6950 0.6660 0.023 Uiso 1 1 calc R U . . .
C36 C 0.5980(3) 0.2649(3) 1.0608(3) 0.0199(6) Uani 1 1 d . . . . .
H36A H 0.5786 0.2592 0.9832 0.024 Uiso 1 1 calc R U . . .
H36B H 0.6100 0.1916 1.0612 0.024 Uiso 1 1 calc R U . . .
C7 C 0.3324(4) 0.1216(3) 0.6923(3) 0.0261(8) Uani 1 1 d . . . . .
H7 H 0.2311 0.0895 0.6880 0.031 Uiso 1 1 calc R U . . .
C3 C 0.8667(3) 0.4516(3) 0.6483(3) 0.0206(6) Uani 1 1 d . . . . .
H3A H 0.9311 0.4214 0.6824 0.025 Uiso 1 1 calc R U . . .
H3B H 0.9234 0.5054 0.6158 0.025 Uiso 1 1 calc R U . . .
C28 C 0.4298(3) 0.8518(3) 0.9041(3) 0.0222(6) Uani 1 1 d . . . . .
H28 H 0.3379 0.8429 0.8618 0.027 Uiso 1 1 calc R U . . .
C61 C -0.0288(4) 0.1707(3) 0.7631(3) 0.0296(7) Uani 1 1 d . . . . .
H61 H -0.0258 0.1585 0.6898 0.035 Uiso 1 1 calc R U . . .
C51 C 0.4549(4) 0.4779(3) 1.2739(3) 0.0150(7) Uani 1 1 d . . . . .
H51A H 0.4436 0.4182 1.3087 0.018 Uiso 1 1 calc R U . . .
H51B H 0.5323 0.5613 1.3310 0.018 Uiso 1 1 calc R U . . .
C14 C 1.1065(4) 0.9244(3) 0.9120(3) 0.0263(7) Uani 1 1 d . . . . .
H14 H 1.1677 1.0119 0.9506 0.032 Uiso 1 1 calc R U . . .
C68 C 0.3631(3) 0.8251(3) 1.3552(2) 0.0191(6) Uani 1 1 d . . . . .
H68 H 0.2609 0.8065 1.3370 0.023 Uiso 1 1 calc R U . . .
C23 C 0.5177(3) 0.8169(2) 0.8486(2) 0.0175(6) Uani 1 1 d . . . . .
C55 C 0.1441(3) 0.6570(3) 1.1228(3) 0.0206(6) Uani 1 1 d . . . . .
H55A H 0.1043 0.6494 1.1835 0.025 Uiso 1 1 calc R U . . .
H55B H 0.1401 0.7282 1.1098 0.025 Uiso 1 1 calc R U . . .
C66 C 0.6117(5) 0.9366(4) 1.4910(3) 0.0270(9) Uani 1 1 d . . . . .
H66 H 0.6800 0.9941 1.5646 0.032 Uiso 1 1 calc R U . . .
C37 C 0.7448(3) 0.3852(3) 1.1407(3) 0.0193(6) Uani 1 1 d . . . . .
H37A H 0.8159 0.3638 1.1801 0.023 Uiso 1 1 calc R U . . .
H37B H 0.7916 0.4276 1.0965 0.023 Uiso 1 1 calc R U . . .
C5 C 0.5306(3) 0.2418(2) 0.6403(2) 0.0176(6) Uani 1 1 d . . . . .
C25 C 0.6941(4) 0.8768(3) 1.0299(3) 0.0319(8) Uani 1 1 d . . . . .
H25 H 0.7852 0.8849 1.0726 0.038 Uiso 1 1 calc R U . . .
C15 C 1.0438(3) 0.8564(3) 0.9684(3) 0.0249(7) Uani 1 1 d . . . . .
H15 H 1.0621 0.8974 1.0461 0.030 Uiso 1 1 calc R U . . .
C40 C 0.5232(3) 0.1711(3) 1.2334(2) 0.0185(6) Uani 1 1 d . . . . .
H40 H 0.6190 0.1919 1.2269 0.022 Uiso 1 1 calc R U . . .
C43 C 0.2479(4) 0.1145(3) 1.2588(3) 0.0246(7) Uani 1 1 d . . . . .
H43 H 0.1545 0.0972 1.2688 0.029 Uiso 1 1 calc R U . . .
C63 C 0.4102(3) 0.7667(3) 1.2741(2) 0.0159(5) Uani 1 1 d . . . . .
C56 C 0.3061(3) 0.6774(3) 1.1561(2) 0.0158(5) Uani 1 1 d . . . . .
H56 H 0.3503 0.7117 1.1057 0.019 Uiso 1 1 calc R U . . .
C54 C 0.0520(3) 0.5375(3) 1.0154(2) 0.0183(6) Uani 1 1 d . . . . .
H54A H 0.0833 0.5477 0.9519 0.022 Uiso 1 1 calc R U . . .
H54B H -0.0557 0.5139 0.9957 0.022 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P3 Rh01 P4 85.16(4) . . ?
P3 Rh01 Cl1 176.24(3) . . ?
P4 Rh01 Cl1 91.58(3) . . ?
P3 Rh01 Cl2 98.51(3) . . ?
P4 Rh01 Cl2 176.11(3) . . ?
Cl1 Rh01 Cl2 84.79(3) . . ?
P2 Rh02 P1 85.45(4) . . ?
P2 Rh02 Cl1 93.21(3) . . ?
P1 Rh02 Cl1 176.85(4) . . ?
P2 Rh02 Cl2 173.64(3) . . ?
P1 Rh02 Cl2 96.49(3) . . ?
Cl1 Rh02 Cl2 85.15(3) . . ?
Rh02 Cl1 Rh01 95.33(3) . . ?
C51 P3 C38 100.65(16) . . ?
C51 P3 C35 111.47(16) . . ?
C38 P3 C35 90.59(15) . . ?
C51 P3 Rh01 112.07(12) . . ?
C38 P3 Rh01 126.56(12) . . ?
C35 P3 Rh01 113.33(12) . . ?
C52 P4 C56 109.19(14) . . ?
C52 P4 C53 101.34(15) . . ?
C56 P4 C53 93.01(14) . . ?
C52 P4 Rh01 114.01(11) . . ?
C56 P4 Rh01 114.11(9) . . ?
C53 P4 Rh01 122.66(11) . . ?
C17 P1 C4 105.23(16) . . ?
C17 P1 C1 102.98(15) . . ?
C4 P1 C1 92.33(13) . . ?
C17 P1 Rh02 111.41(11) . . ?
C4 P1 Rh02 121.05(11) . . ?
C1 P1 Rh02 120.88(10) . . ?
C18 P2 C22 102.54(16) . . ?
C18 P2 C19 104.25(16) . . ?
C22 P2 C19 91.84(17) . . ?
C18 P2 Rh02 112.55(12) . . ?
C22 P2 Rh02 124.19(12) . . ?
C19 P2 Rh02 118.06(12) . . ?
Rh02 Cl2 Rh01 94.68(3) . . ?
C41 C42 C43 119.7(3) . . ?
C41 C42 H42 120.2 . . ?
C43 C42 H42 120.2 . . ?
C17 C18 P2 108.2(2) . . ?
C17 C18 H18A 110.1 . . ?
P2 C18 H18A 110.1 . . ?
C17 C18 H18B 110.1 . . ?
P2 C18 H18B 110.1 . . ?
H18A C18 H18B 108.4 . . ?
C45 C38 C37 117.4(3) . . ?
C45 C38 P3 116.2(2) . . ?
C37 C38 P3 104.0(2) . . ?
C45 C38 H38 106.1 . . ?
C37 C38 H38 106.1 . . ?
P3 C38 H38 106.1 . . ?
C39 C35 C36 117.0(3) . . ?
C39 C35 P3 114.7(2) . . ?
C36 C35 P3 100.7(2) . . ?
C39 C35 H35 108.0 . . ?
C36 C35 H35 108.0 . . ?
P3 C35 H35 108.0 . . ?
C34 C29 C30 118.2(3) . . ?
C34 C29 C22 119.9(3) . . ?
C30 C29 C22 121.8(3) . . ?
C33 C34 C29 120.8(3) . . ?
C33 C34 H34 119.6 . . ?
C29 C34 H34 119.6 . . ?
C27 C26 C25 118.7(3) . . ?
C27 C26 H26 120.6 . . ?
C25 C26 H26 120.6 . . ?
C18 C17 P1 108.5(2) . . ?
C18 C17 H17A 110.0 . . ?
P1 C17 H17A 110.0 . . ?
C18 C17 H17B 110.0 . . ?
P1 C17 H17B 110.0 . . ?
H17A C17 H17B 108.4 . . ?
C11 C4 C3 117.7(3) . . ?
C11 C4 P1 112.8(2) . . ?
C3 C4 P1 106.5(2) . . ?
C11 C4 H4 106.4 . . ?
C3 C4 H4 106.4 . . ?
P1 C4 H4 106.4 . . ?
C15 C16 C11 120.8(3) . . ?
C15 C16 H16 119.6 . . ?
C11 C16 H16 119.6 . . ?
C8 C9 C10 120.1(3) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
C62 C57 C58 118.4(3) . . ?
C62 C57 C53 122.1(3) . . ?
C58 C57 C53 119.4(3) . . ?
C46 C47 C48 120.2(3) . . ?
C46 C47 H47 119.9 . . ?
C48 C47 H47 119.9 . . ?
C26 C27 C28 120.9(4) . . ?
C26 C27 H27 119.5 . . ?
C28 C27 H27 119.5 . . ?
C5 C10 C9 120.9(3) . . ?
C5 C10 H10 119.6 . . ?
C9 C10 H10 119.6 . . ?
C1 C2 C3 111.5(2) . . ?
C1 C2 H2A 109.3 . . ?
C3 C2 H2A 109.3 . . ?
C1 C2 H2B 109.3 . . ?
C3 C2 H2B 109.3 . . ?
H2A C2 H2B 108.0 . . ?
C45 C50 C49 121.7(3) . . ?
C45 C50 H50 119.2 . . ?
C49 C50 H50 119.2 . . ?
C29 C22 C21 118.4(3) . . ?
C29 C22 P2 114.3(2) . . ?
C21 C22 P2 102.7(2) . . ?
C29 C22 H22 106.9 . . ?
C21 C22 H22 106.9 . . ?
P2 C22 H22 106.9 . . ?
C57 C53 C54 119.5(3) . . ?
C57 C53 P4 114.3(2) . . ?
C54 C53 P4 104.2(2) . . ?
C57 C53 H53 105.9 . . ?
C54 C53 H53 105.9 . . ?
P4 C53 H53 105.9 . . ?
C9 C8 C7 119.7(3) . . ?
C9 C8 H8 120.2 . . ?
C7 C8 H8 120.2 . . ?
C66 C67 C68 120.3(3) . . ?
C66 C67 H67 119.8 . . ?
C68 C67 H67 119.8 . . ?
C50 C45 C46 118.1(3) . . ?
C50 C45 C38 120.4(3) . . ?
C46 C45 C38 121.5(3) . . ?
C31 C30 C29 120.3(4) . . ?
C31 C30 H30 119.8 . . ?
C29 C30 H30 119.8 . . ?
C51 C52 P4 109.5(2) . . ?
C51 C52 H52A 109.8 . . ?
P4 C52 H52A 109.8 . . ?
C51 C52 H52B 109.8 . . ?
P4 C52 H52B 109.8 . . ?
H52A C52 H52B 108.2 . . ?
C16 C11 C12 118.2(3) . . ?
C16 C11 C4 119.6(3) . . ?
C12 C11 C4 122.1(3) . . ?
C32 C31 C30 120.7(3) . . ?
C32 C31 H31 119.6 . . ?
C30 C31 H31 119.6 . . ?
C40 C39 C44 118.2(3) . . ?
C40 C39 C35 123.5(3) . . ?
C44 C39 C35 118.3(3) . . ?
C49 C48 C47 119.5(3) . . ?
C49 C48 H48 120.3 . . ?
C47 C48 H48 120.3 . . ?
C31 C32 C33 119.6(3) . . ?
C31 C32 H32 120.2 . . ?
C33 C32 H32 120.2 . . ?
C61 C60 C59 119.4(3) . . ?
C61 C60 H60 120.3 . . ?
C59 C60 H60 120.3 . . ?
C48 C49 C50 119.8(3) . . ?
C48 C49 H49 120.1 . . ?
C50 C49 H49 120.1 . . ?
C23 C19 C20 116.8(3) . . ?
C23 C19 P2 111.1(2) . . ?
C20 C19 P2 106.2(2) . . ?
C23 C19 H19 107.4 . . ?
C20 C19 H19 107.4 . . ?
P2 C19 H19 107.4 . . ?
C7 C6 C5 121.2(3) . . ?
C7 C6 H6 119.4 . . ?
C5 C6 H6 119.4 . . ?
C42 C41 C40 120.3(3) . . ?
C42 C41 H41 119.8 . . ?
C40 C41 H41 119.8 . . ?
C14 C13 C12 120.1(3) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C60 C59 C58 120.4(3) . . ?
C60 C59 H59 119.8 . . ?
C58 C59 H59 119.8 . . ?
C64 C65 C66 119.9(3) . . ?
C64 C65 H65 120.0 . . ?
C66 C65 H65 120.0 . . ?
C21 C20 C19 110.8(3) . . ?
C21 C20 H20A 109.5 . . ?
C19 C20 H20A 109.5 . . ?
C21 C20 H20B 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 108.1 . . ?
C43 C44 C39 120.8(3) . . ?
C43 C44 H44 119.6 . . ?
C39 C44 H44 119.6 . . ?
C59 C58 C57 120.7(3) . . ?
C59 C58 H58 119.7 . . ?
C57 C58 H58 119.7 . . ?
C57 C62 C61 120.6(3) . . ?
C57 C62 H62 119.7 . . ?
C61 C62 H62 119.7 . . ?
C32 C33 C34 120.4(3) . . ?
C32 C33 H33 119.8 . . ?
C34 C33 H33 119.8 . . ?
C25 C24 C23 121.3(3) . . ?
C25 C24 H24 119.3 . . ?
C23 C24 H24 119.3 . . ?
C47 C46 C45 120.8(3) . . ?
C47 C46 H46 119.6 . . ?
C45 C46 H46 119.6 . . ?
C65 C64 C63 121.3(3) . . ?
C65 C64 H64 119.3 . . ?
C63 C64 H64 119.3 . . ?
C22 C21 C20 107.7(3) . . ?
C22 C21 H21A 110.2 . . ?
C20 C21 H21A 110.2 . . ?
C22 C21 H21B 110.2 . . ?
C20 C21 H21B 110.2 . . ?
H21A C21 H21B 108.5 . . ?
C5 C1 C2 116.4(2) . . ?
C5 C1 P1 109.07(19) . . ?
C2 C1 P1 104.72(19) . . ?
C5 C1 H1 108.8 . . ?
C2 C1 H1 108.8 . . ?
P1 C1 H1 108.8 . . ?
C13 C12 C11 120.9(3) . . ?
C13 C12 H12 119.6 . . ?
C11 C12 H12 119.6 . . ?
C35 C36 C37 111.7(2) . . ?
C35 C36 H36A 109.3 . . ?
C37 C36 H36A 109.3 . . ?
C35 C36 H36B 109.3 . . ?
C37 C36 H36B 109.3 . . ?
H36A C36 H36B 107.9 . . ?
C6 C7 C8 119.8(3) . . ?
C6 C7 H7 120.1 . . ?
C8 C7 H7 120.1 . . ?
C4 C3 C2 111.4(2) . . ?
C4 C3 H3A 109.3 . . ?
C2 C3 H3A 109.3 . . ?
C4 C3 H3B 109.3 . . ?
C2 C3 H3B 109.3 . . ?
H3A C3 H3B 108.0 . . ?
C23 C28 C27 120.9(3) . . ?
C23 C28 H28 119.5 . . ?
C27 C28 H28 119.5 . . ?
C60 C61 C62 120.4(3) . . ?
C60 C61 H61 119.8 . . ?
C62 C61 H61 119.8 . . ?
C52 C51 P3 111.0(2) . . ?
C52 C51 H51A 109.4 . . ?
P3 C51 H51A 109.4 . . ?
C52 C51 H51B 109.4 . . ?
P3 C51 H51B 109.4 . . ?
H51A C51 H51B 108.0 . . ?
C15 C14 C13 119.5(3) . . ?
C15 C14 H14 120.3 . . ?
C13 C14 H14 120.3 . . ?
C67 C68 C63 120.8(3) . . ?
C67 C68 H68 119.6 . . ?
C63 C68 H68 119.6 . . ?
C28 C23 C24 117.5(3) . . ?
C28 C23 C19 123.3(3) . . ?
C24 C23 C19 119.1(3) . . ?
C54 C55 C56 107.4(2) . . ?
C54 C55 H55A 110.2 . . ?
C56 C55 H55A 110.2 . . ?
C54 C55 H55B 110.2 . . ?
C56 C55 H55B 110.2 . . ?
H55A C55 H55B 108.5 . . ?
C67 C66 C65 119.7(3) . . ?
C67 C66 H66 120.1 . . ?
C65 C66 H66 120.1 . . ?
C38 C37 C36 109.6(2) . . ?
C38 C37 H37A 109.8 . . ?
C36 C37 H37A 109.8 . . ?
C38 C37 H37B 109.8 . . ?
C36 C37 H37B 109.8 . . ?
H37A C37 H37B 108.2 . . ?
C10 C5 C6 118.4(3) . . ?
C10 C5 C1 122.4(3) . . ?
C6 C5 C1 119.1(3) . . ?
C24 C25 C26 120.6(3) . . ?
C24 C25 H25 119.7 . . ?
C26 C25 H25 119.7 . . ?
C14 C15 C16 120.5(3) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
C39 C40 C41 120.8(3) . . ?
C39 C40 H40 119.6 . . ?
C41 C40 H40 119.6 . . ?
C42 C43 C44 120.1(3) . . ?
C42 C43 H43 120.0 . . ?
C44 C43 H43 120.0 . . ?
C68 C63 C64 117.9(3) . . ?
C68 C63 C56 122.5(3) . . ?
C64 C63 C56 119.6(2) . . ?
C63 C56 C55 118.0(2) . . ?
C63 C56 P4 113.9(2) . . ?
C55 C56 P4 105.67(19) . . ?
C63 C56 H56 106.2 . . ?
C55 C56 H56 106.2 . . ?
P4 C56 H56 106.2 . . ?
C55 C54 C53 104.9(2) . . ?
C55 C54 H54A 110.8 . . ?
C53 C54 H54A 110.8 . . ?
C55 C54 H54B 110.8 . . ?
C53 C54 H54B 110.8 . . ?
H54A C54 H54B 108.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh01 P3 2.1640(9) . ?
Rh01 P4 2.1655(9) . ?
Rh01 Cl1 2.4291(9) . ?
Rh01 Cl2 2.4380(9) . ?
Rh02 P2 2.1533(10) . ?
Rh02 P1 2.1595(9) . ?
Rh02 Cl1 2.4168(9) . ?
Rh02 Cl2 2.4334(9) . ?
P3 C51 1.840(3) . ?
P3 C38 1.850(3) . ?
P3 C35 1.872(4) . ?
P4 C52 1.849(3) . ?
P4 C56 1.872(3) . ?
P4 C53 1.878(3) . ?
P1 C17 1.847(3) . ?
P1 C4 1.852(3) . ?
P1 C1 1.865(3) . ?
P2 C18 1.838(3) . ?
P2 C22 1.862(3) . ?
P2 C19 1.877(4) . ?
C42 C41 1.379(5) . ?
C42 C43 1.383(5) . ?
C42 H42 0.9500 . ?
C18 C17 1.522(4) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C38 C45 1.510(5) . ?
C38 C37 1.537(4) . ?
C38 H38 1.0000 . ?
C35 C39 1.513(4) . ?
C35 C36 1.550(4) . ?
C35 H35 1.0000 . ?
C29 C34 1.396(5) . ?
C29 C30 1.403(5) . ?
C29 C22 1.509(5) . ?
C34 C33 1.386(5) . ?
C34 H34 0.9500 . ?
C26 C27 1.370(5) . ?
C26 C25 1.393(5) . ?
C26 H26 0.9500 . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C4 C11 1.505(4) . ?
C4 C3 1.538(4) . ?
C4 H4 1.0000 . ?
C16 C15 1.386(4) . ?
C16 C11 1.391(4) . ?
C16 H16 0.9500 . ?
C9 C8 1.387(5) . ?
C9 C10 1.388(4) . ?
C9 H9 0.9500 . ?
C57 C62 1.380(5) . ?
C57 C58 1.391(4) . ?
C57 C53 1.504(4) . ?
C47 C46 1.387(4) . ?
C47 C48 1.396(5) . ?
C47 H47 0.9500 . ?
C27 C28 1.399(5) . ?
C27 H27 0.9500 . ?
C10 C5 1.388(4) . ?
C10 H10 0.9500 . ?
C2 C1 1.544(4) . ?
C2 C3 1.550(4) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C50 C45 1.384(5) . ?
C50 C49 1.392(5) . ?
C50 H50 0.9500 . ?
C22 C21 1.519(4) . ?
C22 H22 1.0000 . ?
C53 C54 1.534(4) . ?
C53 H53 1.0000 . ?
C8 C7 1.390(5) . ?
C8 H8 0.9500 . ?
C67 C66 1.375(5) . ?
C67 C68 1.392(4) . ?
C67 H67 0.9500 . ?
C45 C46 1.389(5) . ?
C30 C31 1.391(5) . ?
C30 H30 0.9500 . ?
C52 C51 1.520(4) . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C11 C12 1.394(4) . ?
C31 C32 1.374(5) . ?
C31 H31 0.9500 . ?
C39 C40 1.387(4) . ?
C39 C44 1.400(4) . ?
C48 C49 1.374(5) . ?
C48 H48 0.9500 . ?
C32 C33 1.385(5) . ?
C32 H32 0.9500 . ?
C60 C61 1.373(5) . ?
C60 C59 1.378(6) . ?
C60 H60 0.9500 . ?
C49 H49 0.9500 . ?
C19 C23 1.520(4) . ?
C19 C20 1.551(5) . ?
C19 H19 1.0000 . ?
C6 C7 1.383(5) . ?
C6 C5 1.392(4) . ?
C6 H6 0.9500 . ?
C41 C40 1.395(4) . ?
C41 H41 0.9500 . ?
C13 C14 1.385(5) . ?
C13 C12 1.388(4) . ?
C13 H13 0.9500 . ?
C59 C58 1.386(5) . ?
C59 H59 0.9500 . ?
C65 C64 1.376(4) . ?
C65 C66 1.394(5) . ?
C65 H65 0.9500 . ?
C20 C21 1.522(4) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C44 C43 1.392(4) . ?
C44 H44 0.9500 . ?
C58 H58 0.9500 . ?
C62 C61 1.396(4) . ?
C62 H62 0.9500 . ?
C33 H33 0.9500 . ?
C24 C25 1.381(5) . ?
C24 C23 1.397(4) . ?
C24 H24 0.9500 . ?
C46 H46 0.9500 . ?
C64 C63 1.402(4) . ?
C64 H64 0.9500 . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C1 C5 1.516(4) . ?
C1 H1 1.0000 . ?
C12 H12 0.9500 . ?
C36 C37 1.553(4) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C7 H7 0.9500 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C28 C23 1.388(4) . ?
C28 H28 0.9500 . ?
C61 H61 0.9500 . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C14 C15 1.379(5) . ?
C14 H14 0.9500 . ?
C68 C63 1.393(4) . ?
C68 H68 0.9500 . ?
C55 C54 1.526(4) . ?
C55 C56 1.540(4) . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C66 H66 0.9500 . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C25 H25 0.9500 . ?
C15 H15 0.9500 . ?
C40 H40 0.9500 . ?
C43 H43 0.9500 . ?
C63 C56 1.503(4) . ?
C56 H56 1.0000 . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C22 P2 C18 C17 -167.1(2) . . . . ?
C19 P2 C18 C17 97.7(3) . . . . ?
Rh02 P2 C18 C17 -31.4(3) . . . . ?
C51 P3 C38 C45 -75.3(3) . . . . ?
C35 P3 C38 C45 172.7(3) . . . . ?
Rh01 P3 C38 C45 52.6(3) . . . . ?
C51 P3 C38 C37 154.0(2) . . . . ?
C35 P3 C38 C37 42.0(2) . . . . ?
Rh01 P3 C38 C37 -78.1(2) . . . . ?
C51 P3 C35 C39 -18.3(3) . . . . ?
C38 P3 C35 C39 83.4(3) . . . . ?
Rh01 P3 C35 C39 -145.8(2) . . . . ?
C51 P3 C35 C36 -144.8(2) . . . . ?
C38 P3 C35 C36 -43.1(2) . . . . ?
Rh01 P3 C35 C36 87.6(2) . . . . ?
C30 C29 C34 C33 0.6(5) . . . . ?
C22 C29 C34 C33 179.0(3) . . . . ?
P2 C18 C17 P1 39.3(3) . . . . ?
C4 P1 C17 C18 -167.3(2) . . . . ?
C1 P1 C17 C18 96.6(2) . . . . ?
Rh02 P1 C17 C18 -34.4(2) . . . . ?
C17 P1 C4 C11 57.7(3) . . . . ?
C1 P1 C4 C11 161.8(2) . . . . ?
Rh02 P1 C4 C11 -69.6(3) . . . . ?
C17 P1 C4 C3 -72.9(2) . . . . ?
C1 P1 C4 C3 31.2(2) . . . . ?
Rh02 P1 C4 C3 159.85(17) . . . . ?
C25 C26 C27 C28 0.7(6) . . . . ?
C8 C9 C10 C5 -0.2(4) . . . . ?
C34 C29 C22 C21 -175.6(3) . . . . ?
C30 C29 C22 C21 2.8(5) . . . . ?
C34 C29 C22 P2 63.2(4) . . . . ?
C30 C29 C22 P2 -118.5(3) . . . . ?
C18 P2 C22 C29 62.0(3) . . . . ?
C19 P2 C22 C29 167.0(3) . . . . ?
Rh02 P2 C22 C29 -66.7(3) . . . . ?
C18 P2 C22 C21 -67.5(2) . . . . ?
C19 P2 C22 C21 37.5(2) . . . . ?
Rh02 P2 C22 C21 163.72(15) . . . . ?
C62 C57 C53 C54 44.2(4) . . . . ?
C58 C57 C53 C54 -138.2(3) . . . . ?
C62 C57 C53 P4 -80.3(3) . . . . ?
C58 C57 C53 P4 97.3(3) . . . . ?
C52 P4 C53 C57 -95.1(2) . . . . ?
C56 P4 C53 C57 154.7(2) . . . . ?
Rh01 P4 C53 C57 33.4(3) . . . . ?
C52 P4 C53 C54 132.7(2) . . . . ?
C56 P4 C53 C54 22.4(2) . . . . ?
Rh01 P4 C53 C54 -98.90(19) . . . . ?
C10 C9 C8 C7 0.5(5) . . . . ?
C49 C50 C45 C46 -1.0(5) . . . . ?
C49 C50 C45 C38 -179.2(3) . . . . ?
C37 C38 C45 C50 -117.1(4) . . . . ?
P3 C38 C45 C50 118.9(3) . . . . ?
C37 C38 C45 C46 64.8(4) . . . . ?
P3 C38 C45 C46 -59.2(4) . . . . ?
C34 C29 C30 C31 -0.3(5) . . . . ?
C22 C29 C30 C31 -178.6(3) . . . . ?
C56 P4 C52 C51 -110.5(2) . . . . ?
C53 P4 C52 C51 152.2(2) . . . . ?
Rh01 P4 C52 C51 18.4(3) . . . . ?
C15 C16 C11 C12 -1.1(4) . . . . ?
C15 C16 C11 C4 -178.4(3) . . . . ?
C3 C4 C11 C16 -145.2(3) . . . . ?
P1 C4 C11 C16 90.1(3) . . . . ?
C3 C4 C11 C12 37.5(4) . . . . ?
P1 C4 C11 C12 -87.1(3) . . . . ?
C29 C30 C31 C32 -0.2(6) . . . . ?
C36 C35 C39 C40 12.7(4) . . . . ?
P3 C35 C39 C40 -105.0(3) . . . . ?
C36 C35 C39 C44 -165.4(3) . . . . ?
P3 C35 C39 C44 76.9(3) . . . . ?
C46 C47 C48 C49 -0.9(5) . . . . ?
C30 C31 C32 C33 0.3(6) . . . . ?
C47 C48 C49 C50 0.7(5) . . . . ?
C45 C50 C49 C48 0.3(6) . . . . ?
C18 P2 C19 C23 -146.7(2) . . . . ?
C22 P2 C19 C23 109.9(3) . . . . ?
Rh02 P2 C19 C23 -21.0(3) . . . . ?
C18 P2 C19 C20 85.3(3) . . . . ?
C22 P2 C19 C20 -18.2(2) . . . . ?
Rh02 P2 C19 C20 -149.02(18) . . . . ?
C43 C42 C41 C40 0.2(5) . . . . ?
C61 C60 C59 C58 -0.2(6) . . . . ?
C23 C19 C20 C21 -131.0(3) . . . . ?
P2 C19 C20 C21 -6.5(3) . . . . ?
C40 C39 C44 C43 0.4(4) . . . . ?
C35 C39 C44 C43 178.6(3) . . . . ?
C60 C59 C58 C57 -0.7(5) . . . . ?
C62 C57 C58 C59 1.0(5) . . . . ?
C53 C57 C58 C59 -176.7(3) . . . . ?
C58 C57 C62 C61 -0.4(5) . . . . ?
C53 C57 C62 C61 177.2(3) . . . . ?
C31 C32 C33 C34 0.1(5) . . . . ?
C29 C34 C33 C32 -0.6(5) . . . . ?
C48 C47 C46 C45 0.2(5) . . . . ?
C50 C45 C46 C47 0.8(5) . . . . ?
C38 C45 C46 C47 178.9(3) . . . . ?
C66 C65 C64 C63 -0.9(5) . . . . ?
C29 C22 C21 C20 -174.3(3) . . . . ?
P2 C22 C21 C20 -47.3(3) . . . . ?
C19 C20 C21 C22 35.6(3) . . . . ?
C3 C2 C1 C5 -92.9(3) . . . . ?
C3 C2 C1 P1 27.6(3) . . . . ?
C17 P1 C1 C5 -162.4(2) . . . . ?
C4 P1 C1 C5 91.4(2) . . . . ?
Rh02 P1 C1 C5 -37.3(2) . . . . ?
C17 P1 C1 C2 72.4(2) . . . . ?
C4 P1 C1 C2 -33.8(2) . . . . ?
Rh02 P1 C1 C2 -162.59(16) . . . . ?
C14 C13 C12 C11 1.8(4) . . . . ?
C16 C11 C12 C13 -0.5(4) . . . . ?
C4 C11 C12 C13 176.8(3) . . . . ?
C39 C35 C36 C37 -91.4(3) . . . . ?
P3 C35 C36 C37 33.6(3) . . . . ?
C5 C6 C7 C8 0.3(5) . . . . ?
C9 C8 C7 C6 -0.5(5) . . . . ?
C11 C4 C3 C2 -147.4(3) . . . . ?
P1 C4 C3 C2 -19.7(3) . . . . ?
C1 C2 C3 C4 -5.5(4) . . . . ?
C26 C27 C28 C23 -1.1(5) . . . . ?
C59 C60 C61 C62 0.8(5) . . . . ?
C57 C62 C61 C60 -0.5(5) . . . . ?
P4 C52 C51 P3 -29.3(3) . . . . ?
C38 P3 C51 C52 167.6(2) . . . . ?
C35 P3 C51 C52 -97.6(3) . . . . ?
Rh01 P3 C51 C52 30.7(3) . . . . ?
C12 C13 C14 C15 -1.5(5) . . . . ?
C66 C67 C68 C63 -1.5(5) . . . . ?
C27 C28 C23 C24 0.8(4) . . . . ?
C27 C28 C23 C19 177.8(3) . . . . ?
C25 C24 C23 C28 -0.4(4) . . . . ?
C25 C24 C23 C19 -177.4(3) . . . . ?
C20 C19 C23 C28 14.6(4) . . . . ?
P2 C19 C23 C28 -107.5(3) . . . . ?
C20 C19 C23 C24 -168.5(3) . . . . ?
P2 C19 C23 C24 69.4(3) . . . . ?
C68 C67 C66 C65 0.9(6) . . . . ?
C64 C65 C66 C67 0.3(6) . . . . ?
C45 C38 C37 C36 -157.6(3) . . . . ?
P3 C38 C37 C36 -27.6(3) . . . . ?
C35 C36 C37 C38 -4.5(4) . . . . ?
C9 C10 C5 C6 0.0(4) . . . . ?
C9 C10 C5 C1 176.5(3) . . . . ?
C7 C6 C5 C10 0.0(4) . . . . ?
C7 C6 C5 C1 -176.7(3) . . . . ?
C2 C1 C5 C10 24.2(4) . . . . ?
P1 C1 C5 C10 -93.9(3) . . . . ?
C2 C1 C5 C6 -159.2(3) . . . . ?
P1 C1 C5 C6 82.6(3) . . . . ?
C23 C24 C25 C26 0.0(5) . . . . ?
C27 C26 C25 C24 -0.2(5) . . . . ?
C13 C14 C15 C16 0.0(5) . . . . ?
C11 C16 C15 C14 1.3(5) . . . . ?
C44 C39 C40 C41 1.4(4) . . . . ?
C35 C39 C40 C41 -176.7(3) . . . . ?
C42 C41 C40 C39 -1.7(5) . . . . ?
C41 C42 C43 C44 1.6(5) . . . . ?
C39 C44 C43 C42 -1.8(5) . . . . ?
C67 C68 C63 C64 0.9(4) . . . . ?
C67 C68 C63 C56 -177.7(3) . . . . ?
C65 C64 C63 C68 0.3(4) . . . . ?
C65 C64 C63 C56 179.0(3) . . . . ?
C68 C63 C56 C55 3.9(4) . . . . ?
C64 C63 C56 C55 -174.7(3) . . . . ?
C68 C63 C56 P4 -120.9(3) . . . . ?
C64 C63 C56 P4 60.5(3) . . . . ?
C54 C55 C56 C63 -163.1(2) . . . . ?
C54 C55 C56 P4 -34.4(3) . . . . ?
C52 P4 C56 C63 34.4(2) . . . . ?
C53 P4 C56 C63 137.5(2) . . . . ?
Rh01 P4 C56 C63 -94.52(19) . . . . ?
C52 P4 C56 C55 -96.7(2) . . . . ?
C53 P4 C56 C55 6.4(2) . . . . ?
Rh01 P4 C56 C55 134.38(17) . . . . ?
C56 C55 C54 C53 53.0(3) . . . . ?
C57 C53 C54 C55 -174.8(2) . . . . ?
P4 C53 C54 C55 -45.6(2) . . . . ?
