#------------------------------------------------------------------------------
#$Date: 2025-07-05 13:10:14 +0300 (Sat, 05 Jul 2025) $
#$Revision: 300370 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/98/1569848.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_1569848
loop_
_publ_author_name
'Ezenyilimba, Frederick'
'LaDuca, Robert L.'
_publ_section_title
;
 Poly[[μ-1,3-bis(pyridin-3-yl)urea]bis(μ4-succinato)dicopper(II)], a
 ribbon-like coordination polymer
;
_journal_coeditor_code           BH4078
_journal_issue                   9
_journal_name_full               IUCrData
_journal_page_first              x230747
_journal_paper_doi               10.1107/S2414314623007472
_journal_volume                  8
_journal_year                    2023
_chemical_formula_iupac          '[Cu2 (C4 H4 O4)2 (C11 H10 N4 O)]'
_chemical_formula_moiety         'C19 H18 Cu2 N4 O9'
_chemical_formula_sum            'C19 H18 Cu2 N4 O9'
_chemical_formula_weight         573.45
_chemical_name_systematic
;
Poly[[μ-1,3-bis(pyridin-3-yl)urea]bis(μ₄-succinato)dicopper(II)]
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method
;
Olex2 1.3-ac4
(compiled 2020.11.27 svn.r5f609507 for Rigaku Oxford Diffraction, GUI svn.r6214)
;
_cell_angle_alpha                90
_cell_angle_beta                 111.614(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.587(2)
_cell_length_b                   6.7579(10)
_cell_length_c                   20.942(3)
_cell_measurement_reflns_used    2446
_cell_measurement_temperature    173.15
_cell_measurement_theta_max      25.11
_cell_measurement_theta_min      2.81
_cell_volume                     2050.8(5)
_computing_cell_refinement
;
SAINT (Bruker, 2013)
;
_computing_data_collection
;
COSMO (Bruker, 2009)
;
_computing_data_reduction
;
SAINT (Bruker, 2013)
;
_computing_molecular_graphics
;
CrystalMakerX (Palmer, 2020)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXT2018 (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean 8.36
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1097
_diffrn_reflns_av_unetI/netI     0.1034
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            15941
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.383
_diffrn_reflns_theta_min         1.405
_diffrn_source                   'sealed tube'
_diffrn_source_current           40.0
_diffrn_source_power             2.0
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.138
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5681
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2013)
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.857
_exptl_crystal_description       plate
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0.237
_exptl_crystal_size_mid          0.122
_exptl_crystal_size_min          0.054
_refine_diff_density_max         1.115
_refine_diff_density_min         -0.601
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.985
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         3758
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.985
_refine_ls_R_factor_all          0.1015
_refine_ls_R_factor_gt           0.0561
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0685P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1232
_refine_ls_wR_factor_ref         0.1509
_reflns_number_gt                2378
_reflns_number_total             3758
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            bh4078.cif
_cod_data_source_block           I
_cod_original_cell_volume        2050.9(5)
_cod_database_code               1569848
#BEGIN Tags that were not found in dictionaries:
_shelx_estimated_absorpt_t_min   0.631
_shelx_estimated_absorpt_t_max   0.893
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu Cu1 0.76095(5) 0.56430(10) 0.20555(4) 0.0199(2) Uani d 1 . .
Cu Cu2 0.77124(5) 0.49295(10) 0.33295(4) 0.0198(2) Uani d 1 . .
O O1 0.6695(3) 0.6855(6) 0.3154(2) 0.0241(10) Uani d 1 . .
O O2 0.6730(3) 0.7626(6) 0.2124(2) 0.0257(11) Uani d 1 . .
O O3 0.6784(3) 1.2834(6) 0.2892(2) 0.0250(10) Uani d 1 . .
O O4 0.6616(3) 1.3542(6) 0.1809(2) 0.0228(10) Uani d 1 . .
O O5 0.8617(3) 0.7122(6) 0.3540(2) 0.0272(11) Uani d 1 . .
O O6 0.8587(3) 0.7601(6) 0.2474(2) 0.0269(11) Uani d 1 . .
O O7 0.8683(3) 1.3085(6) 0.3309(2) 0.0284(11) Uani d 1 . .
O O8 0.8527(3) 1.3529(6) 0.2213(2) 0.0232(10) Uani d 1 . .
O O9 0.5334(3) 0.3287(7) 0.4400(2) 0.0355(12) Uani d 1 . .
N N1 0.7897(3) 0.4419(7) 0.4394(3) 0.0190(12) Uani d 1 . .
N N2 0.6521(4) 0.3177(7) 0.5442(3) 0.0226(12) Uani d 1 . .
H H2 0.665061 0.298117 0.588321 0.027 Uiso calc 1 . .
N N3 0.5065(4) 0.2208(7) 0.5341(3) 0.0225(12) Uani d 1 . .
H H3 0.533315 0.195629 0.578293 0.027 Uiso calc 1 . .
N N4 0.2765(4) 0.1280(7) 0.4043(2) 0.0207(12) Uani d 1 . .
C C1 0.6429(4) 0.7848(8) 0.2603(3) 0.0196(14) Uani d 1 . .
C C2 0.5697(4) 0.9394(8) 0.2500(3) 0.0194(14) Uani d 1 . .
H H2A 0.579259 1.002925 0.294759 0.023 Uiso calc 1 . .
H H2B 0.508546 0.874023 0.234080 0.023 Uiso calc 1 . .
C C3 0.5692(4) 1.0992(9) 0.1984(3) 0.0190(14) Uani d 1 . .
H H3A 0.576689 1.034695 0.158311 0.023 Uiso calc 1 . .
H H3B 0.508195 1.165147 0.181940 0.023 Uiso calc 1 . .
C C4 0.6433(4) 1.2555(8) 0.2259(3) 0.0181(14) Uani d 1 . .
C C5 0.8876(4) 0.7960(9) 0.3111(3) 0.0197(14) Uani d 1 . .
C C6 0.9644(4) 0.9500(8) 0.3372(3) 0.0225(15) Uani d 1 . .
H H6A 0.961873 1.010462 0.379568 0.027 Uiso calc 1 . .
H H6B 1.024551 0.881653 0.349782 0.027 Uiso calc 1 . .
C C7 0.9604(4) 1.1147(9) 0.2866(3) 0.0240(15) Uani d 1 . .
H H7A 1.021401 1.180573 0.301650 0.029 Uiso calc 1 . .
H H7B 0.948973 1.054800 0.241052 0.029 Uiso calc 1 . .
C C8 0.8870(4) 1.2704(9) 0.2789(3) 0.0213(15) Uani d 1 . .
C C9 0.8712(5) 0.4774(9) 0.4890(3) 0.0280(16) Uani d 1 . .
H H9 0.922054 0.513711 0.476843 0.034 Uiso calc 1 . .
C C10 0.8834(5) 0.4625(9) 0.5578(3) 0.0279(16) Uani d 1 . .
H H10 0.942091 0.487920 0.592295 0.034 Uiso calc 1 . .
C C11 0.8108(4) 0.4111(9) 0.5757(3) 0.0250(15) Uani d 1 . .
H H11 0.818417 0.401257 0.622687 0.030 Uiso calc 1 . .
C C12 0.7253(4) 0.3733(8) 0.5245(3) 0.0213(14) Uani d 1 . .
C C13 0.7181(5) 0.3899(9) 0.4566(3) 0.0234(15) Uani d 1 . .
H H13 0.660291 0.363379 0.421060 0.028 Uiso calc 1 . .
C C14 0.5621(5) 0.2911(9) 0.5012(3) 0.0235(15) Uani d 1 . .
C C15 0.2276(5) 0.0979(9) 0.4441(4) 0.0260(16) Uani d 1 . .
H H15 0.163956 0.066116 0.423285 0.031 Uiso calc 1 . .
C C16 0.2677(5) 0.1121(8) 0.5150(3) 0.0253(15) Uani d 1 . .
H H16 0.231447 0.093317 0.542417 0.030 Uiso calc 1 . .
C C17 0.3608(4) 0.1539(9) 0.5456(3) 0.0249(15) Uani d 1 . .
H H17 0.389672 0.160856 0.594176 0.030 Uiso calc 1 . .
C C18 0.4114(4) 0.1852(8) 0.5044(3) 0.0188(14) Uani d 1 . .
C C19 0.3656(5) 0.1700(9) 0.4340(3) 0.0251(15) Uani d 1 . .
H H19 0.399984 0.190872 0.405368 0.030 Uiso calc 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1.00 -1.00 1.00 0.0970
1.00 0.00 2.00 0.0150
-1.00 0.00 -2.00 0.0300
-1.00 -1.00 0.00 0.0950
0.00 0.00 1.00 0.0220
1.00 -2.00 0.00 0.1040
-1.00 1.00 2.00 0.1120
1.00 -1.00 -2.00 0.0860
1.00 0.00 -2.00 0.0150
-1.00 0.00 2.00 0.0420
1.00 0.00 0.00 0.0040
-1.00 0.00 0.00 0.0560
2.00 1.00 -2.00 0.0590
2.00 1.00 1.00 0.0470
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O2 Cu1 O4 . 1_545 90.48(18) y
O2 Cu1 O6 . . 87.41(18) y
O2 Cu1 O8 . 1_545 166.45(17) y
O2 Cu1 N4 . 2_655 91.11(18) y
O4 Cu1 N4 1_545 2_655 89.25(17) y
O6 Cu1 O4 . 1_545 169.11(17) y
O6 Cu1 N4 . 2_655 101.47(18) y
O8 Cu1 O4 1_545 1_545 88.52(17) y
O8 Cu1 O6 1_545 . 91.03(18) y
O8 Cu1 N4 1_545 2_655 102.38(18) y
O1 Cu2 O3 . 1_545 89.16(18) y
O1 Cu2 O5 . . 90.34(18) y
O1 Cu2 N1 . . 95.10(17) y
O3 Cu2 N1 1_545 . 99.11(18) y
O5 Cu2 O3 . 1_545 166.52(17) y
O5 Cu2 N1 . . 94.36(18) y
O7 Cu2 O1 1_545 . 168.62(18) y
O7 Cu2 O3 1_545 1_545 88.50(18) y
O7 Cu2 O5 1_545 . 89.35(19) y
O7 Cu2 N1 1_545 . 96.27(18) y
C1 O1 Cu2 . . 119.2(4) ?
C1 O2 Cu1 . . 127.8(4) ?
C4 O3 Cu2 . 1_565 123.8(4) ?
C4 O4 Cu1 . 1_565 122.6(4) ?
C5 O5 Cu2 . . 124.8(4) ?
C5 O6 Cu1 . . 121.1(4) ?
C8 O7 Cu2 . 1_565 125.0(4) ?
C8 O8 Cu1 . 1_565 120.7(4) ?
C9 N1 Cu2 . . 120.0(4) ?
C9 N1 C13 . . 119.1(5) ?
C13 N1 Cu2 . . 120.7(4) ?
C12 N2 H2 . . 116.9 ?
C14 N2 H2 . . 116.9 ?
C14 N2 C12 . . 126.1(5) ?
C14 N3 H3 . . 116.7 ?
C14 N3 C18 . . 126.5(5) ?
C18 N3 H3 . . 116.7 ?
C15 N4 Cu1 . 2_645 129.1(4) ?
C19 N4 Cu1 . 2_645 111.2(4) ?
C19 N4 C15 . . 118.6(6) ?
O1 C1 C2 . . 118.4(5) ?
O2 C1 O1 . . 124.7(6) ?
O2 C1 C2 . . 116.9(5) ?
C1 C2 H2A . . 108.9 ?
C1 C2 H2B . . 108.9 ?
C1 C2 C3 . . 113.5(5) ?
H2A C2 H2B . . 107.7 ?
C3 C2 H2A . . 108.9 ?
C3 C2 H2B . . 108.9 ?
C2 C3 H3A . . 108.6 ?
C2 C3 H3B . . 108.6 ?
H3A C3 H3B . . 107.5 ?
C4 C3 C2 . . 114.8(5) ?
C4 C3 H3A . . 108.6 ?
C4 C3 H3B . . 108.6 ?
O3 C4 O4 . . 125.4(5) ?
O3 C4 C3 . . 119.0(5) ?
O4 C4 C3 . . 115.5(5) ?
O5 C5 O6 . . 126.1(6) ?
O5 C5 C6 . . 117.9(6) ?
O6 C5 C6 . . 115.9(5) ?
C5 C6 H6A . . 108.5 ?
C5 C6 H6B . . 108.5 ?
H6A C6 H6B . . 107.5 ?
C7 C6 C5 . . 115.0(5) ?
C7 C6 H6A . . 108.5 ?
C7 C6 H6B . . 108.5 ?
C6 C7 H7A . . 108.6 ?
C6 C7 H7B . . 108.6 ?
H7A C7 H7B . . 107.6 ?
C8 C7 C6 . . 114.6(5) ?
C8 C7 H7A . . 108.6 ?
C8 C7 H7B . . 108.6 ?
O7 C8 O8 . . 126.2(6) ?
O7 C8 C7 . . 117.2(6) ?
O8 C8 C7 . . 116.6(5) ?
N1 C9 H9 . . 119.2 ?
N1 C9 C10 . . 121.6(6) ?
C10 C9 H9 . . 119.2 ?
C9 C10 H10 . . 120.2 ?
C11 C10 C9 . . 119.7(6) ?
C11 C10 H10 . . 120.2 ?
C10 C11 H11 . . 120.3 ?
C10 C11 C12 . . 119.5(6) ?
C12 C11 H11 . . 120.3 ?
C11 C12 N2 . . 118.4(6) ?
C13 C12 N2 . . 123.7(6) ?
C13 C12 C11 . . 117.9(6) ?
N1 C13 C12 . . 122.3(6) ?
N1 C13 H13 . . 118.8 ?
C12 C13 H13 . . 118.8 ?
O9 C14 N2 . . 123.6(6) ?
O9 C14 N3 . . 122.9(6) ?
N2 C14 N3 . . 113.4(6) ?
N4 C15 H15 . . 119.2 ?
N4 C15 C16 . . 121.5(6) ?
C16 C15 H15 . . 119.2 ?
C15 C16 H16 . . 120.3 ?
C17 C16 C15 . . 119.4(6) ?
C17 C16 H16 . . 120.3 ?
C16 C17 H17 . . 120.5 ?
C18 C17 C16 . . 119.0(6) ?
C18 C17 H17 . . 120.5 ?
C17 C18 N3 . . 120.1(6) ?
C17 C18 C19 . . 117.7(6) ?
C19 C18 N3 . . 122.1(6) ?
N4 C19 C18 . . 123.7(6) ?
N4 C19 H19 . . 118.2 ?
C18 C19 H19 . . 118.2 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 O2 . 1.960(4) y
Cu1 O4 1_545 2.023(4) y
Cu1 O6 . 1.963(4) y
Cu1 O8 1_545 1.961(4) y
Cu1 N4 2_655 2.197(5) y
Cu2 O1 . 1.979(4) y
Cu2 O3 1_545 1.990(4) y
Cu2 O5 . 1.980(4) y
Cu2 O7 1_545 1.973(4) y
Cu2 N1 . 2.167(5) y
O1 C1 . 1.265(7) ?
O2 C1 . 1.264(7) ?
O3 C4 . 1.248(7) ?
O4 C4 . 1.271(7) ?
O5 C5 . 1.249(7) ?
O6 C5 . 1.263(7) ?
O7 C8 . 1.254(7) ?
O8 C8 . 1.256(7) ?
O9 C14 . 1.218(7) ?
N1 C9 . 1.333(8) ?
N1 C13 . 1.340(7) ?
N2 H2 . 0.8800 ?
N2 C12 . 1.401(8) ?
N2 C14 . 1.371(8) ?
N3 H3 . 0.8800 ?
N3 C14 . 1.376(8) ?
N3 C18 . 1.400(8) ?
N4 C15 . 1.335(8) ?
N4 C19 . 1.327(8) ?
C1 C2 . 1.504(8) ?
C2 H2A . 0.9900 ?
C2 H2B . 0.9900 ?
C2 C3 . 1.526(8) ?
C3 H3A . 0.9900 ?
C3 H3B . 0.9900 ?
C3 C4 . 1.515(8) ?
C5 C6 . 1.528(8) ?
C6 H6A . 0.9900 ?
C6 H6B . 0.9900 ?
C6 C7 . 1.522(8) ?
C7 H7A . 0.9900 ?
C7 H7B . 0.9900 ?
C7 C8 . 1.519(8) ?
C9 H9 . 0.9500 ?
C9 C10 . 1.386(9) ?
C10 H10 . 0.9500 ?
C10 C11 . 1.361(9) ?
C11 H11 . 0.9500 ?
C11 C12 . 1.392(8) ?
C12 C13 . 1.389(8) ?
C13 H13 . 0.9500 ?
C15 H15 . 0.9500 ?
C15 C16 . 1.387(9) ?
C16 H16 . 0.9500 ?
C16 C17 . 1.383(9) ?
C17 H17 . 0.9500 ?
C17 C18 . 1.383(8) ?
C18 C19 . 1.385(8) ?
C19 H19 . 0.9500 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N2 H2 O4 4_576 0.88 2.21 3.042(6) 156.8 yes
N3 H3 O4 4_576 0.88 2.36 3.174(6) 154.2 yes
C2 H2A O3 . 0.99 2.48 2.815(7) 99.6 n
C3 H3A O2 . 0.99 2.38 2.744(7) 100.8 n
C6 H6A O7 . 0.99 2.47 2.825(7) 100.3 n
C7 H7B O6 . 0.99 2.47 2.824(8) 100.5 n
C9 H9 O5 . 0.95 2.74 3.196(8) 110.2 n
C13 H13 O9 . 0.95 2.17 2.800(8) 122.9 n
C19 H19 O2 2_645 0.95 2.35 2.965(8) 121.6 n
C19 H19 O4 2_635 0.95 2.84 3.126(7) 98.4 n
C19 H19 O9 . 0.95 2.15 2.786(8) 123.5 n
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
Cu1 O2 C1 O1 . . . . 4.2(9) ?
Cu1 O2 C1 C2 . . . . -175.2(4) ?
Cu1 O4 C4 O3 1_565 . . . 5.2(8) ?
Cu1 O4 C4 C3 1_565 . . . -177.9(4) ?
Cu1 O6 C5 O5 . . . . 2.4(9) ?
Cu1 O6 C5 C6 . . . . 179.4(4) ?
Cu1 O8 C8 O7 1_565 . . . 0.4(9) ?
Cu1 O8 C8 C7 1_565 . . . -177.5(4) ?
Cu1 N4 C15 C16 2_645 . . . 167.8(4) ?
Cu1 N4 C19 C18 2_645 . . . -169.4(5) ?
Cu2 O1 C1 O2 . . . . 4.5(8) ?
Cu2 O1 C1 C2 . . . . -176.2(4) ?
Cu2 O3 C4 O4 1_565 . . . 0.4(8) ?
Cu2 O3 C4 C3 1_565 . . . -176.4(4) ?
Cu2 O5 C5 O6 . . . . 2.4(9) ?
Cu2 O5 C5 C6 . . . . -174.6(4) ?
Cu2 O7 C8 O8 1_565 . . . 5.8(9) ?
Cu2 O7 C8 C7 1_565 . . . -176.4(4) ?
Cu2 N1 C9 C10 . . . . 174.5(5) ?
Cu2 N1 C13 C12 . . . . -174.1(4) ?
O1 C1 C2 C3 . . . . 157.7(5) ?
O2 C1 C2 C3 . . . . -22.9(8) ?
O5 C5 C6 C7 . . . . -150.1(6) ?
O6 C5 C6 C7 . . . . 32.6(8) ?
N1 C9 C10 C11 . . . . -0.2(10) ?
N2 C12 C13 N1 . . . . -179.5(5) ?
N3 C18 C19 N4 . . . . 177.0(5) ?
N4 C15 C16 C17 . . . . -1.5(9) ?
C1 C2 C3 C4 . . . . -78.3(7) ?
C2 C3 C4 O3 . . . . -22.2(8) ?
C2 C3 C4 O4 . . . . 160.7(5) ?
C5 C6 C7 C8 . . . . 75.8(7) ?
C6 C7 C8 O7 . . . . 32.4(8) ?
C6 C7 C8 O8 . . . . -149.6(5) ?
C9 N1 C13 C12 . . . . 0.7(9) ?
C9 C10 C11 C12 . . . . 0.3(9) ?
C10 C11 C12 N2 . . . . 179.0(6) ?
C10 C11 C12 C13 . . . . 0.0(9) ?
C11 C12 C13 N1 . . . . -0.5(9) ?
C12 N2 C14 O9 . . . . -6.2(9) ?
C12 N2 C14 N3 . . . . 175.0(5) ?
C13 N1 C9 C10 . . . . -0.3(9) ?
C14 N2 C12 C11 . . . . 174.2(5) ?
C14 N2 C12 C13 . . . . -6.8(9) ?
C14 N3 C18 C17 . . . . -166.6(6) ?
C14 N3 C18 C19 . . . . 16.7(9) ?
C15 N4 C19 C18 . . . . -0.2(9) ?
C15 C16 C17 C18 . . . . 1.6(9) ?
C16 C17 C18 N3 . . . . -177.7(5) ?
C16 C17 C18 C19 . . . . -0.9(9) ?
C17 C18 C19 N4 . . . . 0.3(9) ?
C18 N3 C14 O9 . . . . -1.0(10) ?
C18 N3 C14 N2 . . . . 177.8(5) ?
C19 N4 C15 C16 . . . . 0.8(9) ?
