#------------------------------------------------------------------------------
#$Date: 2025-04-05 07:28:00 +0300 (Sat, 05 Apr 2025) $
#$Revision: 299162 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/57/34/1573471.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1573471
loop_
_publ_author_name
'Panda, Subhra Jyoti'
'Khator, Kanha Ram'
'Deswal, Priyanka'
'Nayak, Shashwat'
'Pandey, Durgesh'
'Patel, Suraj K.'
'Agrawalla, Suraj Kumar'
'Ghosh, Dibyajyoti'
'Senanayak, Satyaprasad P.'
'Purohit, Chandra Shekhar'
_publ_section_title
;
 Silver-purine MOFs for high-performance multi-terminal neuromorphic
 memory.
;
_journal_issue                   7
_journal_name_full               'Materials horizons'
_journal_page_first              2208
_journal_page_last               2222
_journal_paper_doi               10.1039/d4mh01425a
_journal_volume                  12
_journal_year                    2025
_chemical_formula_moiety         'C6 H5 Ag Cl N4, F0.813 P0.102, F5.187 P0.898'
_chemical_formula_sum            'C6 H5 Ag Cl F6 N4 P'
_chemical_formula_weight         421.43
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2024-12-06
_audit_creation_method
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_audit_update_record
;
2024-12-08 deposited with the CCDC.	2024-12-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.484(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.9676(6)
_cell_length_b                   8.4366(4)
_cell_length_c                   12.5599(5)
_cell_measurement_reflns_used    10997
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      33.5380
_cell_measurement_theta_min      3.7120
_cell_volume                     1202.70(10)
_computing_cell_refinement       'CrysAlisPro 1.171.42.52a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.52a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.52a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/2 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 200K'
_diffrn_measured_fraction_theta_full 0.9972
_diffrn_measured_fraction_theta_max 0.8700
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     -1.00  57.00   0.50    1.00    --   11.92-116.00 -67.00  116
  2  ω     28.00  81.00   0.50    1.00    --   11.92-164.00 143.00  106
  3  ω      9.00  78.00   0.50    1.00    --   11.92  37.00-150.00  138
  4  ω      6.00  81.00   0.50    1.00    --   11.92  19.00  30.00  150
  5  ω      7.00  45.00   0.50    1.00    --   11.92 -99.00-180.00   76
  6  ω    -79.00 -18.00   0.50    1.00    --  -12.70 -37.00   0.00  122
  7  ω    -41.00   2.00   0.50    1.00    --  -12.70 -77.00 -90.00   86
  8  ω    -18.00  11.00   0.50    1.00    --  -12.70 -77.00 120.00   58
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'SuperNova, Dual, Cu at home/near, Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0374534000
_diffrn_orient_matrix_UB_12      -0.0227388000
_diffrn_orient_matrix_UB_13      -0.0538233000
_diffrn_orient_matrix_UB_21      -0.0181360000
_diffrn_orient_matrix_UB_22      -0.0675538000
_diffrn_orient_matrix_UB_23      0.0239158000
_diffrn_orient_matrix_UB_31      -0.0466574000
_diffrn_orient_matrix_UB_32      0.0446012000
_diffrn_orient_matrix_UB_33      0.0085981000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0421
_diffrn_reflns_av_unetI/netI     0.0362
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.868
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16396
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.868
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.617
_diffrn_reflns_theta_min         3.321
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.098
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.72170
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.52a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.327
_exptl_crystal_description       block
_exptl_crystal_F_000             808
_exptl_crystal_preparation       'As per the reaction scheme'
_exptl_crystal_recrystallization_method 'Slow evaporation'
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.26
_refine_diff_density_max         2.584
_refine_diff_density_min         -1.685
_refine_diff_density_rms         0.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     202
_refine_ls_number_reflns         4141
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0394
_refine_ls_R_factor_gt           0.0338
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0327P)²+1.8161P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0790
_refine_ls_wR_factor_ref         0.0817
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3631
_reflns_number_total             4141
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4mh01425a2.cif
_cod_data_source_block           sjp-pf-me_auto
_cod_depositor_comments
'Adding full bibliography for 1573469--1573472.cif.'
_cod_database_code               1573471
_shelx_shelxl_version_number     2019/2
_chemical_oxdiff_formula         'C H N Ag O Cl P F'
_chemical_oxdiff_usercomment     'COLOURLESS BLOCKS'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.612
_shelx_estimated_absorpt_t_min   0.572
_diffrn_oxdiff_ac3_digest_hkl    01e872d6633750136623abb31031a54fc43366
_diffrn_oxdiff_digest_frames
;
012f2d0bf9d521bc0acbe79ebef797943b00027c987
;
_diffrn_oxdiff_digest_hkl
;
01e872d6633750136623abb31031a54fc43366
;
_reflns_odcompleteness_completeness 99.72
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     30.44
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 P1B-F3B
 1.59 with sigma of 0.01
 P1B-F1B
 1.59 with sigma of 0.01
 P1B-F2B
 1.59 with sigma of 0.01
 P1B-F5B
 1.59 with sigma of 0.01
 P1B-F4
 1.59 with sigma of 0.01
 P1B-F6B
 1.59 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(F3B) = Uanis(F3A)
Uanis(F5B) = Uanis(F5A)
Uanis(F6B) = Uanis(F6A)
Uanis(F2B) = Uanis(F2A)
Uanis(F1B) = Uanis(F1A)
Uanis(P1B) = Uanis(P1A)
4. Others
 Sof(P1B)=Sof(F1B)=Sof(F2B)=Sof(F3B)=Sof(F5B)=Sof(F6B)=1-FVAR(1)
 Sof(F1A)=Sof(F2A)=Sof(F3A)=Sof(F5A)=Sof(F6A)=Sof(P1A)=FVAR(1)
 Sof(F4)=1-FVAR(2)
 Sof(F4A)=FVAR(2)
5.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C8(H8)
5.b Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C)
;
_olex2_exptl_crystal_mounting_method 'Mounted on the loop'
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.321
_oxdiff_exptl_absorpt_empirical_full_min 0.718
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.33696(6) 0.98338(8) 0.30930(5) 0.02375(14) Uani 1 1 d . . . . .
N1 N 0.1191(2) 0.9022(3) 0.2768(2) 0.0246(5) Uani 1 1 d . . . . .
N3 N 0.04814(19) 0.7032(3) 0.37431(18) 0.0200(4) Uani 1 1 d . . . . .
N7 N 0.35549(17) 0.6821(3) 0.48648(16) 0.0159(4) Uani 1 1 d . . . . .
N9 N 0.20065(18) 0.5587(2) 0.51336(16) 0.0141(4) Uani 1 1 d . . . . .
C2 C 0.0337(2) 0.8192(4) 0.2986(3) 0.0288(6) Uani 1 1 d . . . . .
H2 H -0.043436 0.844742 0.257076 0.035 Uiso 1 1 calc R U . . .
C4 C 0.1606(2) 0.6704(3) 0.43128(18) 0.0137(4) Uani 1 1 d . . . . .
C5 C 0.2556(2) 0.7498(3) 0.41359(18) 0.0136(4) Uani 1 1 d . . . . .
C6 C 0.2304(2) 0.8698(3) 0.3349(2) 0.0173(4) Uani 1 1 d . . . . .
C8 C 0.3179(2) 0.5712(3) 0.5432(2) 0.0182(5) Uani 1 1 d . . . . .
H8 H 0.368823 0.508337 0.598386 0.022 Uiso 1 1 calc R U . . .
C10 C 0.4788(2) 0.7247(4) 0.5022(2) 0.0230(5) Uani 1 1 d . . . . .
H10A H 0.494809 0.712429 0.432449 0.034 Uiso 1 1 calc R U . . .
H10B H 0.529984 0.656596 0.557801 0.034 Uiso 1 1 calc R U . . .
H10C H 0.492128 0.832873 0.526654 0.034 Uiso 1 1 calc R U . . .
Ag1A Ag -0.09517(2) 0.56355(2) 0.40114(2) 0.01811(6) Uani 1 1 d . . . . .
P1B P 0.2976(19) 0.447(3) 0.176(3) 0.0154(2) Uani 0.102(7) 1 d D . P A 2
F1A F 0.3537(3) 0.4799(9) 0.0751(4) 0.0276(8) Uani 0.898(7) 1 d . . P A 1
F2A F 0.2429(6) 0.6177(5) 0.1575(4) 0.0443(9) Uani 0.898(7) 1 d . . P A 1
F3A F 0.4229(2) 0.5393(5) 0.2596(2) 0.0479(9) Uani 0.898(7) 1 d . . P A 1
F4A F 0.3852(8) 0.2937(13) 0.2092(9) 0.037(2) Uani 0.70(4) 1 d . . P A 1
F5A F 0.1942(3) 0.3632(5) 0.1036(2) 0.0592(11) Uani 0.898(7) 1 d . . P A 1
F6A F 0.2660(5) 0.4223(8) 0.2874(4) 0.0355(9) Uani 0.898(7) 1 d . . P A 1
P1A P 0.30902(19) 0.4530(3) 0.1803(3) 0.0154(2) Uani 0.898(7) 1 d . . P A 1
F1B F 0.330(4) 0.482(9) 0.065(4) 0.0276(8) Uani 0.102(7) 1 d D . P A 2
F2B F 0.230(6) 0.609(5) 0.175(5) 0.0443(9) Uani 0.102(7) 1 d D . P A 2
F3B F 0.4297(18) 0.455(4) 0.255(2) 0.0479(9) Uani 0.102(7) 1 d D . P A 2
F5B F 0.1708(18) 0.463(4) 0.086(2) 0.0592(11) Uani 0.102(7) 1 d D . P A 2
F6B F 0.247(6) 0.443(8) 0.278(4) 0.0355(9) Uani 0.102(7) 1 d D . P A 2
F4 F 0.342(5) 0.2701(17) 0.177(3) 0.066(8) Uani 0.30(4) 1 d D . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 N1 Ag1A 125.28(18) . 2 ?
C6 N1 C2 118.5(2) . . ?
C6 N1 Ag1A 113.96(16) . 2 ?
C2 N3 C4 114.4(2) . . ?
C2 N3 Ag1A 124.83(18) . . ?
C4 N3 Ag1A 120.68(16) . . ?
C5 N7 C10 127.6(2) . . ?
C8 N7 C5 106.07(19) . . ?
C8 N7 C10 126.3(2) . . ?
C4 N9 Ag1A 125.72(16) . 3_566 ?
C8 N9 C4 104.0(2) . . ?
C8 N9 Ag1A 128.69(16) . 3_566 ?
N1 C2 H2 116.8 . . ?
N3 C2 N1 126.5(2) . . ?
N3 C2 H2 116.8 . . ?
N3 C4 N9 126.8(2) . . ?
N3 C4 C5 123.2(2) . . ?
N9 C4 C5 110.1(2) . . ?
N7 C5 C4 105.9(2) . . ?
N7 C5 C6 136.6(2) . . ?
C6 C5 C4 117.5(2) . . ?
N1 C6 Cl1 117.36(19) . . ?
N1 C6 C5 119.9(2) . . ?
C5 C6 Cl1 122.70(19) . . ?
N7 C8 N9 114.0(2) . . ?
N7 C8 H8 123.0 . . ?
N9 C8 H8 123.0 . . ?
N7 C10 H10A 109.5 . . ?
N7 C10 H10B 109.5 . . ?
N7 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N1 Ag1A Ag1A 112.38(6) 2_545 3_566 ?
N3 Ag1A N1 91.61(8) . 2_545 ?
N3 Ag1A Ag1A 83.87(5) . 3_566 ?
N9 Ag1A N1 105.03(8) 3_566 2_545 ?
N9 Ag1A N3 160.26(8) 3_566 . ?
N9 Ag1A Ag1A 80.05(5) 3_566 3_566 ?
F1B P1B F6B 168(3) . . ?
F2B P1B F1B 96(3) . . ?
F2B P1B F6B 73(3) . . ?
F3B P1B F1B 94(3) . . ?
F3B P1B F2B 112(3) . . ?
F3B P1B F5B 171(3) . . ?
F3B P1B F6B 93(3) . . ?
F3B P1B F4 77(2) . . ?
F5B P1B F1B 79(2) . . ?
F5B P1B F2B 63(3) . . ?
F5B P1B F6B 93(3) . . ?
F5B P1B F4 109(3) . . ?
F4 P1B F1B 90(3) . . ?
F4 P1B F2B 169(4) . . ?
F4 P1B F6B 101(3) . . ?
F1A P1A F4A 89.5(4) . . ?
F1A P1A F5A 91.1(3) . . ?
F1A P1A F6A 178.6(3) . . ?
F2A P1A F1A 90.3(3) . . ?
F2A P1A F3A 89.5(3) . . ?
F2A P1A F4A 175.4(6) . . ?
F2A P1A F5A 91.3(3) . . ?
F2A P1A F6A 91.1(3) . . ?
F3A P1A F1A 90.5(3) . . ?
F3A P1A F4A 85.9(6) . . ?
F3A P1A F5A 178.3(3) . . ?
F3A P1A F6A 89.3(3) . . ?
F4A P1A F6A 89.1(4) . . ?
F5A P1A F4A 93.3(5) . . ?
F5A P1A F6A 89.2(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 C6 1.706(2) . ?
N1 C2 1.338(4) . ?
N1 C6 1.328(3) . ?
N1 Ag1A 2.553(2) 2 ?
N3 C2 1.337(3) . ?
N3 C4 1.338(3) . ?
N3 Ag1A 2.193(2) . ?
N7 C5 1.378(3) . ?
N7 C8 1.337(3) . ?
N7 C10 1.470(3) . ?
N9 C4 1.367(3) . ?
N9 C8 1.337(3) . ?
N9 Ag1A 2.161(2) 3_566 ?
C2 H2 0.9300 . ?
C4 C5 1.397(3) . ?
C5 C6 1.379(3) . ?
C8 H8 0.9300 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
Ag1A Ag1A 2.9864(4) 3_566 ?
P1B F1B 1.588(10) . ?
P1B F2B 1.587(10) . ?
P1B F3B 1.578(10) . ?
P1B F5B 1.582(10) . ?
P1B F6B 1.589(10) . ?
P1B F4 1.585(10) . ?
F1A P1A 1.591(2) . ?
F2A P1A 1.579(3) . ?
F3A P1A 1.588(3) . ?
F4A P1A 1.601(5) . ?
F5A P1A 1.597(3) . ?
F6A P1A 1.607(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 C4 C5 N7 -179.4(2) . . . . ?
N3 C4 C5 C6 1.4(4) . . . . ?
N7 C5 C6 Cl1 -2.1(4) . . . . ?
N7 C5 C6 N1 179.0(3) . . . . ?
N9 C4 C5 N7 0.7(3) . . . . ?
N9 C4 C5 C6 -178.4(2) . . . . ?
C2 N1 C6 Cl1 -177.3(2) . . . . ?
C2 N1 C6 C5 1.8(4) . . . . ?
C2 N3 C4 N9 179.7(3) . . . . ?
C2 N3 C4 C5 -0.1(4) . . . . ?
C4 N3 C2 N1 -0.4(5) . . . . ?
C4 N9 C8 N7 0.0(3) . . . . ?
C4 C5 C6 Cl1 176.76(18) . . . . ?
C4 C5 C6 N1 -2.2(4) . . . . ?
C5 N7 C8 N9 0.4(3) . . . . ?
C6 N1 C2 N3 -0.4(5) . . . . ?
C8 N7 C5 C4 -0.7(3) . . . . ?
C8 N7 C5 C6 178.2(3) . . . . ?
C8 N9 C4 N3 179.7(2) . . . . ?
C8 N9 C4 C5 -0.5(3) . . . . ?
C10 N7 C5 C4 -179.1(2) . . . . ?
C10 N7 C5 C6 -0.1(5) . . . . ?
C10 N7 C8 N9 178.8(2) . . . . ?
Ag1A N1 C2 N3 161.4(2) 2 . . . ?
Ag1A N1 C6 Cl1 18.9(3) 2 . . . ?
Ag1A N1 C6 C5 -162.08(18) 2 . . . ?
Ag1A N3 C2 N1 -177.0(3) . . . . ?
Ag1A N3 C4 N9 -3.6(3) . . . . ?
Ag1A N3 C4 C5 176.63(17) . . . . ?
Ag1A N9 C4 N3 -13.5(3) 3_566 . . . ?
Ag1A N9 C4 C5 166.31(15) 3_566 . . . ?
Ag1A N9 C8 N7 -166.21(16) 3_566 . . . ?
