#------------------------------------------------------------------------------
#$Date: 2025-07-06 17:02:12 +0300 (Sun, 06 Jul 2025) $
#$Revision: 300568 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/57/47/1574714.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1574714
loop_
_publ_author_name
'Chai, Fuxiang'
'Wu, Weikang'
'Rajeshkumar, Thayalan'
'Huang, Zeming'
'Yuan, Qingbing'
'Wei, Yun'
'Maron, Laurent'
'Wang, Shaowu'
_publ_section_title
;
 Unique selectivity of rare-earth metal ambiphilic carbenes towards
 organic molecules and novel reactivity patterns with isonitriles
;
_journal_issue                   26
_journal_name_full               'Chemical Science'
_journal_page_first              11870
_journal_page_last               11887
_journal_paper_doi               10.1039/D5SC01502B
_journal_volume                  16
_journal_year                    2025
_chemical_formula_moiety         'C30 H59 Dy N4 O Si2'
_chemical_formula_sum            'C30 H59 Dy N4 O Si2'
_chemical_formula_weight         710.49
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2024-07-08
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_audit_update_record
;
2025-01-26 deposited with the CCDC.	2025-05-23 downloaded from the CCDC.
;
_cell_angle_alpha                92.672(3)
_cell_angle_beta                 111.785(2)
_cell_angle_gamma                95.539(2)
_cell_formula_units_Z            2
_cell_length_a                   10.9353(7)
_cell_length_b                   12.8290(8)
_cell_length_c                   14.6085(11)
_cell_measurement_reflns_used    8622
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      22.78
_cell_measurement_theta_min      2.42
_cell_volume                     1886.6(2)
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1225
_diffrn_reflns_av_unetI/netI     0.0688
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            61150
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.577
_diffrn_reflns_theta_min         2.099
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.069
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.3851
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1571 before and 0.0879 after correction.
The Ratio of minimum to maximum transmission is 0.5165.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.251
_exptl_crystal_description       block
_exptl_crystal_F_000             738
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.032
_refine_diff_density_min         -1.136
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     461
_refine_ls_number_reflns         8682
_refine_ls_number_restraints     312
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0430
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0428P)²+1.6169P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1004
_refine_ls_wR_factor_ref         0.1128
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6709
_reflns_number_total             8682
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5sc01502b2.cif
_cod_data_source_block           1e
_cod_depositor_comments
'Adding full bibliography for 1574708--1574717.cif.'
_cod_database_code               1574714
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.789
_shelx_estimated_absorpt_t_min   0.733
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N4A-C16A = N4-C16 = N4-C18 = N4A-C17A = N4-C17 = N4A-C18A
 1.47 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Si2 \\sim C24 \\sim C25 \\sim C26 \\sim C24A \\sim C25A \\sim C26A: within 2A
with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
O1 \\sim C27 \\sim C28 \\sim C29 \\sim C30 \\sim C27A \\sim C28A \\sim C29A
\\sim C30A: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
C15 \\sim C16 \\sim C17 \\sim C18 \\sim N4 \\sim C16A \\sim C17A \\sim C18A
\\sim N4A: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
4. Same fragment restrains
{C15, C16A, C17A, C18A, N4A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C15, C16, C17, C18, N4}
{O1, C27A, C28A, C29A, C30A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{O1, C27, C28, C29, C30}
{Si2, C24A, C25A, C26A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{Si2, C24, C25, C26}
5. Others
 Sof(H15C)=Sof(H15D)=Sof(C16A)=Sof(H16C)=Sof(H16D)=Sof(C17A)=Sof(H17D)=
 Sof(H17E)=Sof(H17F)=Sof(C18A)=Sof(H18D)=Sof(H18E)=Sof(H18F)=Sof(N4A)=1-FVAR(1)
 Sof(H15A)=Sof(H15B)=Sof(C16)=Sof(H16A)=Sof(H16B)=Sof(C17)=Sof(H17A)=Sof(H17B)=
 Sof(H17C)=Sof(C18)=Sof(H18A)=Sof(H18B)=Sof(H18C)=Sof(N4)=FVAR(1)
 Sof(C24A)=Sof(H24D)=Sof(H24E)=Sof(H24F)=Sof(C25A)=Sof(H25D)=Sof(H25E)=
 Sof(H25F)=Sof(C26A)=Sof(H26D)=Sof(H26E)=Sof(H26F)=1-FVAR(2)
 Sof(C24)=Sof(H24A)=Sof(H24B)=Sof(H24C)=Sof(C25)=Sof(H25A)=Sof(H25B)=Sof(H25C)=
 Sof(C26)=Sof(H26A)=Sof(H26B)=Sof(H26C)=FVAR(2)
 Sof(C27A)=Sof(H27C)=Sof(H27D)=Sof(C28A)=Sof(H28C)=Sof(H28D)=Sof(C29A)=
 Sof(H29C)=Sof(H29D)=Sof(C30A)=Sof(H30C)=Sof(H30D)=1-FVAR(3)
 Sof(C27)=Sof(H27A)=Sof(H27B)=Sof(C28)=Sof(H28A)=Sof(H28B)=Sof(C29)=Sof(H29A)=
 Sof(H29B)=Sof(C30)=Sof(H30A)=Sof(H30B)=FVAR(3)
6.a Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C11(H11A,H11B), C12(H12A,H12B), C15(H15A,H15B), C15(H15C,H15D),
 C16(H16A,H16B), C19(H19A,H19B), C23(H23A,H23B), C27(H27A,H27B), C28(H28A,H28B),
  C29(H29A,H29B), C30(H30A,H30B), C16A(H16C,H16D), C27A(H27C,H27D), C28A(H28C,
 H28D), C29A(H29C,H29D), C30A(H30C,H30D)
6.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7)
6.c Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C17(H17A,H17B,
 H17C), C18(H18A,H18B,H18C), C20(H20A,H20B,H20C), C21(H21A,H21B,H21C), C22(H22A,
 H22B,H22C), C24(H24A,H24B,H24C), C25(H25A,H25B,H25C), C26(H26A,H26B,H26C),
 C17A(H17D,H17E,H17F), C18A(H18D,H18E,H18F), C24A(H24D,H24E,H24F), C25A(H25D,
 H25E,H25F), C26A(H26D,H26E,H26F)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5219(5) 0.6111(4) 0.2947(4) 0.0548(11) Uani 1 1 d . . . . .
C2 C 0.5004(4) 0.5031(4) 0.2777(3) 0.0523(10) Uani 1 1 d . . . . .
C3 C 0.6251(4) 0.4609(4) 0.3029(3) 0.0499(10) Uani 1 1 d . . . . .
C4 C 0.6636(5) 0.3608(4) 0.3013(4) 0.0595(12) Uani 1 1 d . . . . .
H4 H 0.599907 0.302123 0.279074 0.071 Uiso 1 1 calc R U . . .
C5 C 0.7958(6) 0.3490(5) 0.3326(4) 0.0699(14) Uani 1 1 d . . . . .
H5 H 0.821706 0.282149 0.331177 0.084 Uiso 1 1 calc R U . . .
C6 C 0.8909(5) 0.4362(5) 0.3663(4) 0.0714(15) Uani 1 1 d . . . . .
H6 H 0.980144 0.426622 0.388901 0.086 Uiso 1 1 calc R U . . .
C7 C 0.8569(5) 0.5358(5) 0.3673(4) 0.0637(13) Uani 1 1 d . . . . .
H7 H 0.921759 0.593734 0.388566 0.076 Uiso 1 1 calc R U . . .
C8 C 0.7230(5) 0.5485(4) 0.3357(3) 0.0525(11) Uani 1 1 d . . . . .
C9 C 0.3665(5) 0.4390(4) 0.2391(4) 0.0621(12) Uani 1 1 d . . . . .
H9A H 0.336003 0.425734 0.167808 0.075 Uiso 1 1 calc R U . . .
H9B H 0.373358 0.371767 0.267249 0.075 Uiso 1 1 calc R U . . .
C10 C 0.1354(5) 0.4376(5) 0.2102(5) 0.0782(16) Uani 1 1 d . . . . .
H10A H 0.071887 0.469680 0.229579 0.117 Uiso 1 1 calc R U . . .
H10B H 0.134373 0.365509 0.225219 0.117 Uiso 1 1 calc R U . . .
H10C H 0.112959 0.440642 0.140434 0.117 Uiso 1 1 calc R U . . .
C11 C 0.2990(6) 0.4938(5) 0.3729(4) 0.0677(14) Uani 1 1 d . . . . .
H11A H 0.394397 0.504139 0.408578 0.081 Uiso 1 1 calc R U . . .
H11B H 0.265387 0.425809 0.386271 0.081 Uiso 1 1 calc R U . . .
C12 C 0.2375(6) 0.5792(5) 0.4101(4) 0.0720(15) Uani 1 1 d . . . . .
H12A H 0.142968 0.571823 0.371081 0.086 Uiso 1 1 calc R U . . .
H12B H 0.249083 0.570135 0.478279 0.086 Uiso 1 1 calc R U . . .
C13 C 0.2134(7) 0.7621(6) 0.4223(5) 0.0900(19) Uani 1 1 d . . . . .
H13A H 0.249690 0.831900 0.417453 0.135 Uiso 1 1 calc R U . . .
H13B H 0.211956 0.757114 0.487253 0.135 Uiso 1 1 calc R U . . .
H13C H 0.124704 0.747186 0.373773 0.135 Uiso 1 1 calc R U . . .
C14 C 0.4308(7) 0.7091(6) 0.4817(4) 0.0857(18) Uani 1 1 d . . . . .
H14A H 0.489020 0.664960 0.467823 0.128 Uiso 1 1 calc R U . . .
H14B H 0.427484 0.696133 0.545018 0.128 Uiso 1 1 calc R U . . .
H14C H 0.463295 0.781499 0.482659 0.128 Uiso 1 1 calc R U . . .
C15 C 0.7288(5) 0.7424(4) 0.3624(5) 0.0711(14) Uani 1 1 d D U . . .
H15A H 0.669020 0.793641 0.333480 0.085 Uiso 0.768(11) 1 calc R U P A 1
H15B H 0.802462 0.752074 0.340585 0.085 Uiso 0.768(11) 1 calc R U P A 1
H15C H 0.664882 0.792597 0.342224 0.085 Uiso 0.232(11) 1 calc R U P A 2
H15D H 0.790716 0.755841 0.329732 0.085 Uiso 0.232(11) 1 calc R U P A 2
C16 C 0.7805(13) 0.7600(8) 0.4751(6) 0.094(3) Uani 0.768(11) 1 d D U P A 1
H16A H 0.705588 0.762509 0.495206 0.113 Uiso 0.768(11) 1 calc R U P A 1
H16B H 0.824990 0.700357 0.502998 0.113 Uiso 0.768(11) 1 calc R U P A 1
C17 C 0.7864(14) 0.9379(10) 0.5170(12) 0.174(6) Uani 0.768(11) 1 d D U P A 1
H17A H 0.707069 0.926903 0.458272 0.261 Uiso 0.768(11) 1 calc R U P A 1
H17B H 0.833379 1.005728 0.519309 0.261 Uiso 0.768(11) 1 calc R U P A 1
H17C H 0.763321 0.934404 0.574241 0.261 Uiso 0.768(11) 1 calc R U P A 1
C18 C 0.9350(16) 0.8531(12) 0.6254(8) 0.168(6) Uani 0.768(11) 1 d D U P A 1
H18A H 0.869194 0.856884 0.653877 0.252 Uiso 0.768(11) 1 calc R U P A 1
H18B H 1.002784 0.911920 0.652466 0.252 Uiso 0.768(11) 1 calc R U P A 1
H18C H 0.973934 0.788910 0.640262 0.252 Uiso 0.768(11) 1 calc R U P A 1
N4 N 0.8717(10) 0.8555(7) 0.5160(7) 0.129(3) Uani 0.768(11) 1 d D U P A 1
C19 C 0.0659(5) 0.6827(4) 0.1565(4) 0.0658(13) Uani 1 1 d . . . . .
H19A H 0.041803 0.628001 0.102574 0.079 Uiso 1 1 calc R U . . .
H19B H 0.034428 0.653144 0.204866 0.079 Uiso 1 1 calc R U . . .
C20 C -0.2225(7) 0.7351(7) 0.0692(8) 0.126(3) Uani 1 1 d . . . . .
H20A H -0.249531 0.682363 0.014381 0.189 Uiso 1 1 calc R U . . .
H20B H -0.273954 0.792684 0.050305 0.189 Uiso 1 1 calc R U . . .
H20C H -0.236297 0.705492 0.124197 0.189 Uiso 1 1 calc R U . . .
C21 C -0.0222(10) 0.8269(8) -0.0091(7) 0.136(3) Uani 1 1 d . . . . .
H21A H 0.070239 0.835967 0.001108 0.204 Uiso 1 1 calc R U . . .
H21B H -0.057784 0.892406 -0.024113 0.204 Uiso 1 1 calc R U . . .
H21C H -0.068944 0.774606 -0.063242 0.204 Uiso 1 1 calc R U . . .
C22 C -0.0062(9) 0.9016(7) 0.1972(7) 0.127(3) Uani 1 1 d . . . . .
H22A H -0.040918 0.884570 0.246838 0.190 Uiso 1 1 calc R U . . .
H22B H -0.047347 0.959110 0.163555 0.190 Uiso 1 1 calc R U . . .
H22C H 0.087970 0.921296 0.227933 0.190 Uiso 1 1 calc R U . . .
C23 C 0.3908(7) 0.8812(4) 0.2715(5) 0.0792(16) Uani 1 1 d . . . . .
H23A H 0.324842 0.910246 0.291443 0.095 Uiso 1 1 calc R U . . .
H23B H 0.469081 0.884114 0.331721 0.095 Uiso 1 1 calc R U . . .
Dy1 Dy 0.31131(2) 0.69679(2) 0.23549(2) 0.04979(9) Uani 1 1 d . . . . .
N1 N 0.6591(4) 0.6368(3) 0.3291(3) 0.0534(9) Uani 1 1 d . . . . .
N2 N 0.2690(4) 0.4943(3) 0.2648(3) 0.0582(10) Uani 1 1 d . . . . .
N3 N 0.2965(5) 0.6854(4) 0.4045(3) 0.0653(11) Uani 1 1 d . . . . .
O1 O 0.3160(4) 0.6491(4) 0.0779(3) 0.0785(11) Uani 1 1 d D U . . .
C27 C 0.2148(10) 0.5955(12) -0.0114(6) 0.097(3) Uani 0.660(14) 1 d D U P B 1
H27A H 0.174989 0.531164 0.003813 0.116 Uiso 0.660(14) 1 calc R U P B 1
H27B H 0.145710 0.640030 -0.039633 0.116 Uiso 0.660(14) 1 calc R U P B 1
C28 C 0.2748(13) 0.5720(11) -0.0802(8) 0.101(3) Uani 0.660(14) 1 d D U P B 1
H28A H 0.215428 0.578220 -0.147670 0.121 Uiso 0.660(14) 1 calc R U P B 1
H28B H 0.301598 0.501914 -0.075123 0.121 Uiso 0.660(14) 1 calc R U P B 1
C29 C 0.4016(11) 0.6612(12) -0.0451(7) 0.096(3) Uani 0.660(14) 1 d D U P B 1
H29A H 0.472192 0.638896 -0.063561 0.115 Uiso 0.660(14) 1 calc R U P B 1
H29B H 0.377668 0.727031 -0.072672 0.115 Uiso 0.660(14) 1 calc R U P B 1
C30 C 0.4391(8) 0.6703(12) 0.0599(7) 0.088(3) Uani 0.660(14) 1 d D U P B 1
H30A H 0.482562 0.740423 0.087744 0.106 Uiso 0.660(14) 1 calc R U P B 1
H30B H 0.499469 0.619842 0.089771 0.106 Uiso 0.660(14) 1 calc R U P B 1
Si1 Si -0.04197(17) 0.78384(15) 0.10552(14) 0.0776(5) Uani 1 1 d . . . . .
Si2 Si 0.4362(2) 0.98310(16) 0.20264(19) 0.1019(7) Uani 1 1 d D U . . .
C24 C 0.312(2) 0.960(2) 0.0701(11) 0.125(6) Uani 0.46(3) 1 d D U P C 1
H24A H 0.320320 0.893680 0.041187 0.187 Uiso 0.46(3) 1 calc R U P C 1
H24B H 0.328925 1.015327 0.032773 0.187 Uiso 0.46(3) 1 calc R U P C 1
H24C H 0.223716 0.959360 0.069361 0.187 Uiso 0.46(3) 1 calc R U P C 1
C25 C 0.416(3) 1.1185(11) 0.235(2) 0.139(7) Uani 0.46(3) 1 d D U P C 1
H25A H 0.350331 1.117855 0.263642 0.208 Uiso 0.46(3) 1 calc R U P C 1
H25B H 0.388641 1.155351 0.176121 0.208 Uiso 0.46(3) 1 calc R U P C 1
H25C H 0.499213 1.153353 0.281407 0.208 Uiso 0.46(3) 1 calc R U P C 1
C26 C 0.6063(18) 0.978(2) 0.202(2) 0.129(6) Uani 0.46(3) 1 d D U P C 1
H26A H 0.669901 0.984431 0.268891 0.193 Uiso 0.46(3) 1 calc R U P C 1
H26B H 0.627191 1.034401 0.167455 0.193 Uiso 0.46(3) 1 calc R U P C 1
H26C H 0.609178 0.911909 0.169390 0.193 Uiso 0.46(3) 1 calc R U P C 1
C16A C 0.805(5) 0.761(2) 0.4740(9) 0.101(4) Uani 0.232(11) 1 d D U P A 2
H16C H 0.749953 0.728372 0.506715 0.121 Uiso 0.232(11) 1 calc R U P A 2
H16D H 0.884058 0.725979 0.491453 0.121 Uiso 0.232(11) 1 calc R U P A 2
C17A C 0.987(3) 0.881(3) 0.567(3) 0.139(8) Uani 0.232(11) 1 d D U P A 2
H17D H 1.005293 0.852603 0.629292 0.209 Uiso 0.232(11) 1 calc R U P A 2
H17E H 1.023013 0.953891 0.577223 0.209 Uiso 0.232(11) 1 calc R U P A 2
H17F H 1.027759 0.843127 0.529451 0.209 Uiso 0.232(11) 1 calc R U P A 2
C18A C 0.845(4) 0.939(2) 0.433(3) 0.158(8) Uani 0.232(11) 1 d D U P A 2
H18D H 0.927519 0.984835 0.456145 0.238 Uiso 0.232(11) 1 calc R U P A 2
H18E H 0.772657 0.980348 0.417082 0.238 Uiso 0.232(11) 1 calc R U P A 2
H18F H 0.837622 0.896283 0.374931 0.238 Uiso 0.232(11) 1 calc R U P A 2
N4A N 0.842(3) 0.871(2) 0.5109(19) 0.122(4) Uani 0.232(11) 1 d D U P A 2
C24A C 0.374(3) 0.956(2) 0.0642(9) 0.138(6) Uani 0.54(3) 1 d D U P C 2
H24D H 0.442138 0.929795 0.046171 0.207 Uiso 0.54(3) 1 calc R U P C 2
H24E H 0.350369 1.019096 0.033482 0.207 Uiso 0.54(3) 1 calc R U P C 2
H24F H 0.297214 0.903605 0.042365 0.207 Uiso 0.54(3) 1 calc R U P C 2
C25A C 0.355(2) 1.1005(12) 0.2131(18) 0.125(6) Uani 0.54(3) 1 d D U P C 2
H25D H 0.260308 1.081387 0.188690 0.187 Uiso 0.54(3) 1 calc R U P C 2
H25E H 0.375427 1.153237 0.174846 0.187 Uiso 0.54(3) 1 calc R U P C 2
H25F H 0.385920 1.127779 0.281237 0.187 Uiso 0.54(3) 1 calc R U P C 2
C26A C 0.6191(12) 1.029(2) 0.254(2) 0.143(7) Uani 0.54(3) 1 d D U P C 2
H26D H 0.646427 1.055997 0.321697 0.214 Uiso 0.54(3) 1 calc R U P C 2
H26E H 0.637684 1.083181 0.216099 0.214 Uiso 0.54(3) 1 calc R U P C 2
H26F H 0.666707 0.970870 0.249803 0.214 Uiso 0.54(3) 1 calc R U P C 2
C27A C 0.2035(12) 0.633(3) -0.0146(9) 0.096(4) Uani 0.340(14) 1 d D U P B 2
H27C H 0.153520 0.564750 -0.020219 0.116 Uiso 0.340(14) 1 calc R U P B 2
H27D H 0.145421 0.686622 -0.018248 0.116 Uiso 0.340(14) 1 calc R U P B 2
C28A C 0.2520(19) 0.639(2) -0.0921(10) 0.100(3) Uani 0.340(14) 1 d D U P B 2
H28C H 0.257412 0.710193 -0.111241 0.120 Uiso 0.340(14) 1 calc R U P B 2
H28D H 0.196322 0.592221 -0.149678 0.120 Uiso 0.340(14) 1 calc R U P B 2
C29A C 0.398(2) 0.602(2) -0.0425(12) 0.097(3) Uani 0.340(14) 1 d D U P B 2
H29C H 0.394613 0.527029 -0.057042 0.116 Uiso 0.340(14) 1 calc R U P B 2
H29D H 0.459680 0.639197 -0.066617 0.116 Uiso 0.340(14) 1 calc R U P B 2
C30A C 0.4349(13) 0.628(2) 0.0605(11) 0.090(3) Uani 0.340(14) 1 d D U P B 2
H30C H 0.500932 0.689244 0.082580 0.107 Uiso 0.340(14) 1 calc R U P B 2
H30D H 0.472563 0.569763 0.096988 0.107 Uiso 0.340(14) 1 calc R U P B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 Dy1 113.4(3) . . ?
C2 C1 N1 105.3(4) . . ?
N1 C1 Dy1 140.6(3) . . ?
C1 C2 C3 110.2(4) . . ?
C1 C2 C9 124.8(4) . . ?
C3 C2 C9 125.1(4) . . ?
C4 C3 C2 135.4(5) . . ?
C4 C3 C8 119.2(4) . . ?
C8 C3 C2 105.4(4) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 C3 119.7(5) . . ?
C5 C4 H4 120.1 . . ?
C4 C5 H5 119.9 . . ?
C4 C5 C6 120.2(5) . . ?
C6 C5 H5 119.9 . . ?
C5 C6 H6 119.1 . . ?
C7 C6 C5 121.7(5) . . ?
C7 C6 H6 119.1 . . ?
C6 C7 H7 120.8 . . ?
C6 C7 C8 118.4(5) . . ?
C8 C7 H7 120.8 . . ?
C7 C8 C3 120.7(5) . . ?
N1 C8 C3 107.5(4) . . ?
N1 C8 C7 131.8(5) . . ?
C2 C9 H9A 109.4 . . ?
C2 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
N2 C9 C2 111.0(4) . . ?
N2 C9 H9A 109.4 . . ?
N2 C9 H9B 109.4 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N2 C10 H10A 109.5 . . ?
N2 C10 H10B 109.5 . . ?
N2 C10 H10C 109.5 . . ?
H11A C11 H11B 107.9 . . ?
C12 C11 H11A 109.2 . . ?
C12 C11 H11B 109.2 . . ?
N2 C11 H11A 109.2 . . ?
N2 C11 H11B 109.2 . . ?
N2 C11 C12 111.9(4) . . ?
C11 C12 H12A 109.1 . . ?
C11 C12 H12B 109.1 . . ?
H12A C12 H12B 107.8 . . ?
N3 C12 C11 112.4(4) . . ?
N3 C12 H12A 109.1 . . ?
N3 C12 H12B 109.1 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N3 C13 H13A 109.5 . . ?
N3 C13 H13B 109.5 . . ?
N3 C13 H13C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N3 C14 H14A 109.5 . . ?
N3 C14 H14B 109.5 . . ?
N3 C14 H14C 109.5 . . ?
H15A C15 H15B 108.1 . . ?
H15C C15 H15D 107.7 . . ?
C16 C15 H15A 109.6 . . ?
C16 C15 H15B 109.6 . . ?
N1 C15 H15A 109.6 . . ?
N1 C15 H15B 109.6 . . ?
N1 C15 H15C 108.8 . . ?
N1 C15 H15D 108.8 . . ?
N1 C15 C16 110.3(5) . . ?
N1 C15 C16A 113.9(10) . . ?
C16A C15 H15C 108.8 . . ?
C16A C15 H15D 108.8 . . ?
C15 C16 H16A 108.8 . . ?
C15 C16 H16B 108.8 . . ?
H16A C16 H16B 107.7 . . ?
N4 C16 C15 113.9(7) . . ?
N4 C16 H16A 108.8 . . ?
N4 C16 H16B 108.8 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N4 C17 H17A 109.5 . . ?
N4 C17 H17B 109.5 . . ?
N4 C17 H17C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N4 C18 H18A 109.5 . . ?
N4 C18 H18B 109.5 . . ?
N4 C18 H18C 109.5 . . ?
C16 N4 C17 104.9(11) . . ?
C16 N4 C18 108.6(9) . . ?
C17 N4 C18 96.7(11) . . ?
H19A C19 H19B 105.8 . . ?
Dy1 C19 H19A 104.8 . . ?
Dy1 C19 H19B 104.8 . . ?
Si1 C19 H19A 104.8 . . ?
Si1 C19 H19B 104.8 . . ?
Si1 C19 Dy1 129.9(3) . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si1 C20 H20A 109.5 . . ?
Si1 C20 H20B 109.5 . . ?
Si1 C20 H20C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si1 C21 H21A 109.5 . . ?
Si1 C21 H21B 109.5 . . ?
Si1 C21 H21C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si1 C22 H22A 109.5 . . ?
Si1 C22 H22B 109.5 . . ?
Si1 C22 H22C 109.5 . . ?
H23A C23 H23B 105.3 . . ?
Dy1 C23 H23A 103.6 . . ?
Dy1 C23 H23B 103.6 . . ?
Si2 C23 H23A 103.6 . . ?
Si2 C23 H23B 103.6 . . ?
Si2 C23 Dy1 134.5(3) . . ?
C1 Dy1 N2 67.36(14) . . ?
C1 Dy1 N3 89.89(15) . . ?
C19 Dy1 C1 150.18(18) . . ?
C19 Dy1 N2 84.55(16) . . ?
C19 Dy1 N3 90.24(17) . . ?
C23 Dy1 C1 103.13(19) . . ?
C23 Dy1 C19 106.7(2) . . ?
C23 Dy1 N2 159.64(19) . . ?
C23 Dy1 N3 91.62(19) . . ?
N3 Dy1 N2 71.01(14) . . ?
O1 Dy1 C1 82.32(15) . . ?
O1 Dy1 C19 88.56(16) . . ?
O1 Dy1 C23 106.00(19) . . ?
O1 Dy1 N2 90.93(15) . . ?
O1 Dy1 N3 161.93(16) . . ?
C1 N1 C15 124.9(4) . . ?
C8 N1 C1 111.6(4) . . ?
C8 N1 C15 123.3(4) . . ?
C9 N2 C11 109.6(4) . . ?
C9 N2 Dy1 107.0(3) . . ?
C10 N2 C9 108.6(4) . . ?
C10 N2 C11 108.7(4) . . ?
C10 N2 Dy1 117.8(3) . . ?
C11 N2 Dy1 105.0(3) . . ?
C12 N3 C13 108.4(5) . . ?
C12 N3 C14 110.5(5) . . ?
C12 N3 Dy1 109.2(3) . . ?
C13 N3 Dy1 111.6(4) . . ?
C14 N3 C13 107.9(5) . . ?
C14 N3 Dy1 109.1(3) . . ?
C27 O1 Dy1 131.4(5) . . ?
C27 O1 C30 108.2(6) . . ?
C30 O1 Dy1 120.4(4) . . ?
C27A O1 Dy1 126.1(7) . . ?
C27A O1 C30A 109.1(8) . . ?
C30A O1 Dy1 124.7(6) . . ?
O1 C27 H27A 110.0 . . ?
O1 C27 H27B 110.0 . . ?
H27A C27 H27B 108.3 . . ?
C28 C27 O1 108.6(8) . . ?
C28 C27 H27A 110.0 . . ?
C28 C27 H27B 110.0 . . ?
C27 C28 H28A 111.4 . . ?
C27 C28 H28B 111.4 . . ?
C27 C28 C29 101.7(8) . . ?
H28A C28 H28B 109.3 . . ?
C29 C28 H28A 111.4 . . ?
C29 C28 H28B 111.4 . . ?
C28 C29 H29A 111.4 . . ?
C28 C29 H29B 111.4 . . ?
H29A C29 H29B 109.2 . . ?
C30 C29 C28 101.9(8) . . ?
C30 C29 H29A 111.4 . . ?
C30 C29 H29B 111.4 . . ?
O1 C30 H30A 110.5 . . ?
O1 C30 H30B 110.5 . . ?
C29 C30 O1 106.4(7) . . ?
C29 C30 H30A 110.5 . . ?
C29 C30 H30B 110.5 . . ?
H30A C30 H30B 108.6 . . ?
C19 Si1 C20 112.6(3) . . ?
C19 Si1 C21 110.4(3) . . ?
C19 Si1 C22 112.0(3) . . ?
C20 Si1 C22 106.1(4) . . ?
C21 Si1 C20 106.3(5) . . ?
C21 Si1 C22 109.2(5) . . ?
C23 Si2 C24 107.2(8) . . ?
C23 Si2 C25 117.0(10) . . ?
C23 Si2 C26 112.5(7) . . ?
C23 Si2 C24A 117.0(8) . . ?
C23 Si2 C25A 109.2(8) . . ?
C23 Si2 C26A 112.6(7) . . ?
C25 Si2 C24 101.0(8) . . ?
C25 Si2 C26 109.9(9) . . ?
C26 Si2 C24 108.4(9) . . ?
C25A Si2 C24A 100.8(8) . . ?
C25A Si2 C26A 105.8(8) . . ?
C26A Si2 C24A 110.2(9) . . ?
Si2 C24 H24A 109.5 . . ?
Si2 C24 H24B 109.5 . . ?
Si2 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si2 C25 H25A 109.5 . . ?
Si2 C25 H25B 109.5 . . ?
Si2 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si2 C26 H26A 109.5 . . ?
Si2 C26 H26B 109.5 . . ?
Si2 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C15 C16A H16C 108.7 . . ?
C15 C16A H16D 108.7 . . ?
H16C C16A H16D 107.6 . . ?
N4A C16A C15 114.1(13) . . ?
N4A C16A H16C 108.7 . . ?
N4A C16A H16D 108.7 . . ?
H17D C17A H17E 109.5 . . ?
H17D C17A H17F 109.5 . . ?
H17E C17A H17F 109.5 . . ?
N4A C17A H17D 109.5 . . ?
N4A C17A H17E 109.5 . . ?
N4A C17A H17F 109.5 . . ?
H18D C18A H18E 109.5 . . ?
H18D C18A H18F 109.5 . . ?
H18E C18A H18F 109.5 . . ?
N4A C18A H18D 109.5 . . ?
N4A C18A H18E 109.5 . . ?
N4A C18A H18F 109.5 . . ?
C16A N4A C17A 105.1(17) . . ?
C16A N4A C18A 112.4(15) . . ?
C18A N4A C17A 96.9(15) . . ?
Si2 C24A H24D 109.5 . . ?
Si2 C24A H24E 109.5 . . ?
Si2 C24A H24F 109.5 . . ?
H24D C24A H24E 109.5 . . ?
H24D C24A H24F 109.5 . . ?
H24E C24A H24F 109.5 . . ?
Si2 C25A H25D 109.5 . . ?
Si2 C25A H25E 109.5 . . ?
Si2 C25A H25F 109.5 . . ?
H25D C25A H25E 109.5 . . ?
H25D C25A H25F 109.5 . . ?
H25E C25A H25F 109.5 . . ?
Si2 C26A H26D 109.5 . . ?
Si2 C26A H26E 109.5 . . ?
Si2 C26A H26F 109.5 . . ?
H26D C26A H26E 109.5 . . ?
H26D C26A H26F 109.5 . . ?
H26E C26A H26F 109.5 . . ?
O1 C27A H27C 110.2 . . ?
O1 C27A H27D 110.2 . . ?
H27C C27A H27D 108.5 . . ?
C28A C27A O1 107.8(10) . . ?
C28A C27A H27C 110.2 . . ?
C28A C27A H27D 110.2 . . ?
C27A C28A H28C 111.2 . . ?
C27A C28A H28D 111.2 . . ?
C27A C28A C29A 102.6(11) . . ?
H28C C28A H28D 109.2 . . ?
C29A C28A H28C 111.2 . . ?
C29A C28A H28D 111.2 . . ?
C28A C29A H29C 110.9 . . ?
C28A C29A H29D 110.9 . . ?
H29C C29A H29D 108.9 . . ?
C30A C29A C28A 104.4(10) . . ?
C30A C29A H29C 110.9 . . ?
C30A C29A H29D 110.9 . . ?
O1 C30A H30C 110.1 . . ?
O1 C30A H30D 110.1 . . ?
C29A C30A O1 108.0(9) . . ?
C29A C30A H30C 110.1 . . ?
C29A C30A H30D 110.1 . . ?
H30C C30A H30D 108.4 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.377(7) . ?
C1 Dy1 2.522(5) . ?
C1 N1 1.394(6) . ?
C2 C3 1.441(6) . ?
C2 C9 1.501(7) . ?
C3 C4 1.392(7) . ?
C3 C8 1.405(7) . ?
C4 H4 0.9300 . ?
C4 C5 1.371(7) . ?
C5 H5 0.9300 . ?
C5 C6 1.386(8) . ?
C6 H6 0.9300 . ?
C6 C7 1.366(8) . ?
C7 H7 0.9300 . ?
C7 C8 1.391(7) . ?
C8 N1 1.376(6) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C9 N2 1.482(6) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C10 N2 1.474(6) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C12 1.519(8) . ?
C11 N2 1.490(7) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 N3 1.470(7) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C13 N3 1.479(8) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C14 N3 1.474(8) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C15 H15D 0.9700 . ?
C15 C16 1.527(10) . ?
C15 N1 1.455(6) . ?
C15 C16A 1.524(12) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 N4 1.452(7) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C17 N4 1.479(8) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C18 N4 1.491(8) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 Dy1 2.481(5) . ?
C19 Si1 1.834(5) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C20 Si1 1.877(7) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C21 Si1 1.868(9) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C22 Si1 1.881(8) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 Dy1 2.404(6) . ?
C23 Si2 1.826(6) . ?
Dy1 N2 2.677(4) . ?
Dy1 N3 2.543(4) . ?
Dy1 O1 2.374(4) . ?
O1 C27 1.448(9) . ?
O1 C30 1.467(8) . ?
O1 C27A 1.440(10) . ?
O1 C30A 1.462(10) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C27 C28 1.425(12) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C28 C29 1.615(13) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C29 C30 1.428(10) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
Si2 C24 1.897(13) . ?
Si2 C25 1.833(11) . ?
Si2 C26 1.871(12) . ?
Si2 C24A 1.882(12) . ?
Si2 C25A 1.851(11) . ?
Si2 C26A 1.878(12) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C16A H16C 0.9700 . ?
C16A H16D 0.9700 . ?
C16A N4A 1.453(8) . ?
C17A H17D 0.9600 . ?
C17A H17E 0.9600 . ?
C17A H17F 0.9600 . ?
C17A N4A 1.478(8) . ?
C18A H18D 0.9600 . ?
C18A H18E 0.9600 . ?
C18A H18F 0.9600 . ?
C18A N4A 1.475(8) . ?
C24A H24D 0.9600 . ?
C24A H24E 0.9600 . ?
C24A H24F 0.9600 . ?
C25A H25D 0.9600 . ?
C25A H25E 0.9600 . ?
C25A H25F 0.9600 . ?
C26A H26D 0.9600 . ?
C26A H26E 0.9600 . ?
C26A H26F 0.9600 . ?
C27A H27C 0.9700 . ?
C27A H27D 0.9700 . ?
C27A C28A 1.420(13) . ?
C28A H28C 0.9700 . ?
C28A H28D 0.9700 . ?
C28A C29A 1.615(14) . ?
C29A H29C 0.9700 . ?
C29A H29D 0.9700 . ?
C29A C30A 1.419(12) . ?
C30A H30C 0.9700 . ?
C30A H30D 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 179.9(5) . . . . ?
C1 C2 C3 C8 -0.1(5) . . . . ?
C1 C2 C9 N2 -26.5(7) . . . . ?
C2 C1 N1 C8 -1.1(5) . . . . ?
C2 C1 N1 C15 -176.1(5) . . . . ?
C2 C3 C4 C5 -179.3(5) . . . . ?
C2 C3 C8 C7 179.3(4) . . . . ?
C2 C3 C8 N1 -0.6(5) . . . . ?
C2 C9 N2 C10 169.8(4) . . . . ?
C2 C9 N2 C11 -71.6(5) . . . . ?
C2 C9 N2 Dy1 41.8(5) . . . . ?
C3 C2 C9 N2 153.1(4) . . . . ?
C3 C4 C5 C6 0.4(8) . . . . ?
C3 C8 N1 C1 1.1(5) . . . . ?
C3 C8 N1 C15 176.2(5) . . . . ?
C4 C3 C8 C7 -0.7(7) . . . . ?
C4 C3 C8 N1 179.4(4) . . . . ?
C4 C5 C6 C7 -1.7(9) . . . . ?
C5 C6 C7 C8 1.7(8) . . . . ?
C6 C7 C8 C3 -0.5(7) . . . . ?
C6 C7 C8 N1 179.4(5) . . . . ?
C7 C8 N1 C1 -178.8(5) . . . . ?
C7 C8 N1 C15 -3.7(8) . . . . ?
C8 C3 C4 C5 0.7(7) . . . . ?
C9 C2 C3 C4 0.2(9) . . . . ?
C9 C2 C3 C8 -179.8(5) . . . . ?
C11 C12 N3 C13 168.6(5) . . . . ?
C11 C12 N3 C14 -73.3(6) . . . . ?
C11 C12 N3 Dy1 46.7(5) . . . . ?
C12 C11 N2 C9 159.7(4) . . . . ?
C12 C11 N2 C10 -81.8(5) . . . . ?
C12 C11 N2 Dy1 45.1(5) . . . . ?
C15 C16 N4 C17 88.5(16) . . . . ?
C15 C16 N4 C18 -169.0(10) . . . . ?
C15 C16A N4A C17A -126(4) . . . . ?
C15 C16A N4A C18A -21(4) . . . . ?
C16 C15 N1 C1 97.9(8) . . . . ?
C16 C15 N1 C8 -76.5(9) . . . . ?
Dy1 C1 C2 C3 173.4(3) . . . . ?
Dy1 C1 C2 C9 -6.9(6) . . . . ?
Dy1 C1 N1 C8 -170.5(4) . . . . ?
Dy1 C1 N1 C15 14.5(8) . . . . ?
Dy1 C19 Si1 C20 -172.5(4) . . . . ?
Dy1 C19 Si1 C21 68.9(5) . . . . ?
Dy1 C19 Si1 C22 -53.0(5) . . . . ?
Dy1 C23 Si2 C24 39.4(11) . . . . ?
Dy1 C23 Si2 C25 151.8(11) . . . . ?
Dy1 C23 Si2 C26 -79.6(13) . . . . ?
Dy1 C23 Si2 C24A 18.1(11) . . . . ?
Dy1 C23 Si2 C25A 131.7(9) . . . . ?
Dy1 C23 Si2 C26A -111.1(13) . . . . ?
Dy1 O1 C27 C28 -171.1(7) . . . . ?
Dy1 O1 C30 C29 -163.8(7) . . . . ?
Dy1 O1 C27A C28A 161.7(14) . . . . ?
Dy1 O1 C30A C29A 180.0(14) . . . . ?
N1 C1 C2 C3 0.8(5) . . . . ?
N1 C1 C2 C9 -179.6(5) . . . . ?
N1 C15 C16 N4 169.2(10) . . . . ?
N1 C15 C16A N4A -164(3) . . . . ?
N2 C11 C12 N3 -66.5(6) . . . . ?
O1 C27 C28 C29 -25.3(14) . . . . ?
O1 C27A C28A C29A 28(3) . . . . ?
C27 O1 C30 C29 18.1(13) . . . . ?
C27 C28 C29 C30 35.7(14) . . . . ?
C28 C29 C30 O1 -32.2(13) . . . . ?
C30 O1 C27 C28 6.7(14) . . . . ?
C16A C15 N1 C1 108(2) . . . . ?
C16A C15 N1 C8 -66(2) . . . . ?
C27A O1 C30A C29A 2(3) . . . . ?
C27A C28A C29A C30A -26(3) . . . . ?
C28A C29A C30A O1 15(3) . . . . ?
C30A O1 C27A C28A -20(3) . . . . ?
