#------------------------------------------------------------------------------
#$Date: 2022-09-28 18:08:17 +0300 (Wed, 28 Sep 2022) $
#$Revision: 278247 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/00/17/2001787.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2001787
loop_
_publ_author_name
'Ashkenazi, P.'
'Kaftory, M.'
_publ_section_title
;
 Structures of Diels--Alder mono-adducts of 4-phenyl- or
 4-methyl-1,2,4-triazolidine-3,5-dione with
 11-substituted-1,6-methano[10]annulene
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              731
_journal_page_last               735
_journal_paper_doi               10.1107/S0108270192012253
_journal_volume                  49
_journal_year                    1993
_chemical_formula_sum            'C19 H16 N4 O2'
_chemical_formula_weight         332.36
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                96.99(3)
_cell_angle_beta                 93.58(3)
_cell_angle_gamma                92.64(3)
_cell_formula_units_Z            4
_cell_length_a                   26.027(13)
_cell_length_b                   10.155(5)
_cell_length_c                   6.147(3)
_cell_volume                     1607.1(14)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.71069
_exptl_absorpt_coefficient_mu    0.086
_exptl_crystal_density_diffrn    1.374
_exptl_crystal_F_000             696
_cod_data_source_file            al1020.cif
_cod_data_source_block           al1020_structure_3_of_3
_cod_original_cell_volume        1607.09
_cod_database_code               2001787
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
O(1) .3148(2) .3958(4) .2511(6) .0480(10)
O(2) .3981(2) .2769(4) .8695(7) .0520(10)
N(1) .3772(2) .5051(4) .5070(7) .0330(10)
N(2) .3551(2) .2946(4) .5289(7) .0340(10)
N(3) .4020(2) .4691(4) .7018(7) .0350(10)
N(4) .4028(2) .8158(4) .8268(7) .0390(10)
C(1) .4041(2) .7325(5) .6159(9) .0400(10)
C(2) .3559(2) .6424(5) .5423(10) .0380(10)
C(3) .3203(3) .6368(5) .7264(10) .041(2)
C(4) .3427(2) .6008(6) .9054(12) .046(2)
C(5) .3991(2) .5761(5) .8949(9) .0410(10)
C(6) .4295(2) .6928(5) .8216(9) .0380(10)
C(7) .4865(3) .6930(6) .8360(13) .060(2)
C(8) .5134(3) .7390(7) .6845(14) .068(2)
C(9) .4893(3) .7782(7) .4893(14) .070(2)
C(10) .4378(3) .7681(6) .4463(11) .057(2)
C(11) .4306(3) .9449(7) .8613(16) .056(2)
C(12) .3449(2) .3987(5) .4124(9) .0360(10)
C(13) .3863(2) .3389(5) .7232(9) .0380(10)
C(14) .3335(2) .1623(5) .4735(9) .0360(10)
C(15) .3062(2) .0993(6) .6137(12) .048(2)
C(16) .2845(2) -.0282(6) .5514(12) .056(2)
C(17) .2908(3) -.0900(6) .3416(12) .055(2)
C(18) .3175(3) -.0268(6) .1985(12) .055(2)
C(19) .3394(2) .0998(6) .2618(10) .047(2)
O(1') .1008(2) -.1935(4) .4276(6) .0510(10)
O(2') .1844(2) -.0524(4) -.1421(6) .0520(10)
N(1') .0977(2) -.0029(4) .2592(7) .0390(10)
N(2') .1433(2) -.1658(4) .1096(7) .0330(10)
N(3') .1230(2) .0415(4) .0789(7) .0340(10)
N(4') .0982(2) .3451(4) .3845(7) .0390(10)
C(1') .0713(2) .2142(5) .3669(9) .0390(10)
C(2') .1013(2) .1063(5) .4503(9) .0390(10)
C(3') .1582(2) .1455(6) .4971(10) .045(2)
C(4') .1798(3) .1869(6) .3274(11) .048(2)
C(5') .1443(2) .1826(5) .1275(9) .0360(10)
C(6') .0966(2) .2609(5) .1687(9) .0390(10)
C(7') .0623(3) .2877(6) -.0144(11) .052(2)
C(8') .0109(3) .2834(7) -.0041(13) .066(2)
C(9') -.0129(3) .2376(7) .1823(15) .071(3)
C(10') .0143(3) .1996(7) .3471(14) .056(2)
C(11') .0695(3) .4661(6) .4042(12) .046(2)
C(12') .1131(2) -.1280(5) .2856(8) .0350(10)
C(13') .1549(2) -.0586(5) .0011(9) .0390(10)
C(14') .1643(2) -.2929(5) .0660(9) .0350(10)
C(15') .1604(2) -.3566(6) -.1445(11) .044(2)
C(16') .1819(2) -.4771(6) -.1911(12) .051(2)
C(17') .2067(3) -.5333(6) -.0283(13) .056(2)
C(18') .2104(2) -.4714(6) .1877(13) .053(2)
C(19') .1886(2) -.3489(5) .2351(10) .0430(10)
H(2) .337(2) .651(4) .409(8) ?
H(3) .283(2) .652(5) .717(8) ?
H(4) .333(2) .575(6) 1.043(11) ?
H(5) .412(2) .535(5) 1.019(9) ?
H(7) .507(2) .657(5) .980(9) ?
H(8) .553(3) .750(6) .681(11) ?
H(9) .513(3) .808(7) .394(12) ?
H(10) .417(2) .792(5) .302(10) ?
H(111) .410(3) 1.016(7) .832(11) ?
H(112) .440(3) .967(6) .995(12) ?
H(113) .460(2) .961(5) .770(9) ?
H(15) .303(2) .130(4) .738(8) ?
H(16) .272(2) -.077(6) .690(10) ?
H(17) .279(2) -.186(6) .309(8) ?
H(18) .323(2) -.075(5) .060(9) ?
H(19) .354(2) .153(5) .161(10) ?
H(2') .087(2) .057(5) .577(8) ?
H(3') .178(2) .136(5) .634(10) ?
H(4') .215(2) .206(5) .336(9) ?
H(5') .162(2) .202(5) -.002(9) ?
H(7') .081(3) .312(7) -.150(12) ?
H(8') -.011(3) .312(6) -.137(11) ?
H(9') -.043(2) .233(5) .168(8) ?
H(10') .000(3) .160(7) .440(11) ?
H(111') .037(2) .467(5) .301(9) ?
H(112') .090(2) .559(6) .380(10) ?
H(113') .066(2) .482(5) .550(10) ?
H(15') .148(2) -.317(4) -.237(7) ?
H(16') .181(3) -.534(7) -.331(12) ?
H(17') .226(2) -.614(6) -.047(9) ?
H(18') .225(2) -.514(6) .300(10) ?
H(19') .199(2) -.301(6) .396(11) ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N(3) N(1) C(2) 112.3(3)
N(3) N(1) C(12) 108.0(3)
C(2) N(1) C(12) 119.0(4)
C(12) N(2) C(13) 110.7(4)
C(12) N(2) C(14) 125.0(4)
C(13) N(2) C(14) 124.1(4)
N(1) N(3) C(5) 111.6(3)
N(1) N(3) C(13) 108.7(4)
C(5) N(3) C(13) 119.3(4)
C(1) N(4) C(6) 61.8(3)
C(1) N(4) C(11) 119.5(5)
C(6) N(4) C(11) 121.7(4)
N(4) C(1) C(2) 116.0(4)
N(4) C(1) C(6) 58.8(3)
N(4) C(1) C(10) 121.7(4)
C(2) C(1) C(6) 110.3(4)
C(2) C(1) C(10) 118.0(5)
C(6) C(1) C(10) 117.2(5)
N(1) C(2) C(1) 102.9(4)
N(1) C(2) C(3) 105.1(3)
C(1) C(2) C(3) 111.5(5)
C(2) C(3) C(4) 113.6(5)
C(3) C(4) C(5) 115.2(5)
N(3) C(5) C(4) 105.2(4)
N(3) C(5) C(6) 102.1(4)
C(4) C(5) C(6) 112.1(4)
N(4) C(6) C(1) 59.3(3)
N(4) C(6) C(5) 115.4(4)
N(4) C(6) C(7) 121.5(4)
C(1) C(6) C(5) 110.3(4)
C(1) C(6) C(7) 117.0(4)
C(5) C(6) C(7) 118.6(4)
C(6) C(7) C(8) 120.9(6)
C(7) C(8) C(9) 121.9(7)
C(8) C(9) C(10) 122.3(7)
C(1) C(10) C(9) 119.9(6)
O(1) C(12) N(1) 126.9(4)
O(1) C(12) N(2) 126.5(4)
N(1) C(12) N(2) 106.6(4)
O(2) C(13) N(2) 127.7(5)
O(2) C(13) N(3) 127.5(5)
N(2) C(13) N(3) 104.8(4)
N(2) C(14) C(15) 122.5(5)
N(2) C(14) C(19) 117.5(4)
C(15) C(14) C(19) 119.9(5)
C(14) C(15) C(16) 120.8(6)
C(15) C(16) C(17) 119.0(6)
C(16) C(17) C(18) 120.6(6)
C(17) C(18) C(19) 120.2(6)
C(14) C(19) C(18) 119.5(5)
N(3') N(1') C(2') 109.8(3)
N(3') N(1') C(12') 108.3(3)
C(2') N(1') C(12') 121.0(4)
C(12') N(2') C(13') 110.4(4)
C(12') N(2') C(14') 124.7(3)
C(13') N(2') C(14') 124.6(4)
N(1') N(3') C(5') 112.7(3)
N(1') N(3') C(13') 107.3(3)
C(5') N(3') C(13') 119.9(4)
C(1') N(4') C(6') 62.7(3)
C(1') N(4') C(11') 120.7(4)
C(6') N(4') C(11') 119.1(4)
N(4') C(1') C(2') 116.1(4)
N(4') C(1') C(6') 59.4(3)
N(4') C(1') C(10') 121.1(4)
C(2') C(1') C(6') 109.5(4)
C(2') C(1') C(10') 119.2(4)
C(6') C(1') C(10') 115.7(5)
N(1') C(2') C(1') 104.1(4)
N(1') C(2') C(3') 106.1(4)
C(1') C(2') C(3') 112.8(4)
C(2') C(3') C(4') 113.1(5)
C(3') C(4') C(5') 114.1(6)
N(3') C(5') C(4') 105.7(4)
N(3') C(5') C(6') 103.4(4)
C(4') C(5') C(6') 112.7(4)
N(4') C(6') C(1') 57.9(3)
N(4') C(6') C(5') 115.1(4)
N(4') C(6') C(7') 121.1(4)
C(1') C(6') C(5') 108.7(4)
C(1') C(6') C(7') 116.9(4)
C(5') C(6') C(7') 120.2(4)
C(6') C(7') C(8') 121.8(5)
C(7') C(8') C(9') 120.8(7)
C(8') C(9') C(10') 122.2(7)
C(1') C(10') C(9') 122.0(6)
O(1') C(12') N(2') 127.5(4)
O(1') C(12') N(1') 126.1(4)
N(2') C(12') N(1') 106.3(3)
O(2') C(13') N(2') 127.7(4)
O(2') C(13') N(3') 125.8(4)
N(2') C(13') N(3') 106.4(4)
N(2') C(14') C(15') 119.3(4)
N(2') C(14') C(19') 119.7(4)
C(15') C(14') C(19') 121.0(5)
C(14') C(15') C(16') 120.1(5)
C(15') C(16') C(17') 119.9(6)
C(16') C(17') C(18') 121.0(6)
C(17') C(18') C(19') 119.1(6)
C(14') C(19') C(18') 118.8(5)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O(1) C(12) 1.222(6)
O(2) C(13) 1.191(7)
N(1) N(3) 1.420(5)
N(1) C(2) 1.521(6)
N(1) C(12) 1.384(6)
N(2) C(12) 1.373(6)
N(2) C(13) 1.416(6)
N(2) C(14) 1.425(6)
N(3) C(5) 1.517(6)
N(3) C(13) 1.390(6)
N(4) C(1) 1.462(6)
N(4) C(6) 1.455(6)
N(4) C(11) 1.453(8)
C(1) C(2) 1.528(7)
C(1) C(6) 1.498(7)
C(1) C(10) 1.472(9)
C(2) C(3) 1.511(8)
C(3) C(4) 1.312(9)
C(4) C(5) 1.505(8)
C(5) C(6) 1.524(7)
C(6) C(7) 1.479(8)
C(7) C(8) 1.320(10)
C(8) C(9) 1.430(10)
C(9) C(10) 1.350(10)
C(14) C(15) 1.351(8)
C(14) C(19) 1.397(7)
C(15) C(16) 1.388(8)
C(16) C(17) 1.387(9)
C(17) C(18) 1.360(10)
C(18) C(19) 1.383(7)
O(1') C(12') 1.210(6)
O(2') C(13') 1.210(7)
N(1') N(3') 1.432(6)
N(1') C(2') 1.509(6)
N(1') C(12') 1.374(6)
N(2') C(12') 1.403(6)
N(2') C(13') 1.375(6)
N(2') C(14') 1.426(6)
N(3') C(5') 1.501(6)
N(3') C(13') 1.399(6)
N(4') C(1') 1.463(6)
N(4') C(6') 1.485(6)
N(4') C(11') 1.464(7)
C(1') C(2') 1.497(7)
C(1') C(6') 1.535(7)
C(1') C(10') 1.478(8)
C(2') C(3') 1.516(8)
C(3') C(4') 1.320(9)
C(4') C(5') 1.486(8)
C(5') C(6') 1.523(7)
C(6') C(7') 1.451(8)
C(7') C(8') 1.340(10)
C(8') C(9') 1.450(10)
C(9') C(10') 1.310(10)
C(14') C(15') 1.370(7)
C(14') C(19') 1.379(8)
C(15') C(16') 1.374(8)
C(16') C(17') 1.350(10)
C(17') C(18') 1.390(10)
C(18') C(19') 1.397(8)
