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#$Date: 2022-10-03 17:40:12 +0300 (Mon, 03 Oct 2022) $
#$Revision: 278324 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/00/17/2001790.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2001790
loop_
_publ_author_name
'Bertolasi, V.'
'Gilli, P.'
'Ferretti, V.'
'Gilli, G.'
_publ_section_title
;
 Structure and crystal packing of the antibacterial drug
 1-{[(5-nitro-2-furanyl)methylene]amino}-2,4-imidazolidinedione
 (nitrofurantoin)
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              741
_journal_page_last               744
_journal_paper_doi               10.1107/S010827019201062X
_journal_volume                  49
_journal_year                    1993
_chemical_formula_sum            'C8 H6 N4 O5'
_chemical_formula_weight         238.16
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.18(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.8450(10)
_cell_length_b                   6.462(3)
_cell_length_c                   18.920(4)
_cell_volume                     957.7(5)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.71069
_exptl_absorpt_coefficient_mu    0.1318
_exptl_crystal_density_diffrn    1.65
_exptl_crystal_F_000             488
_cod_data_source_file            na1016.cif
_cod_data_source_block           na1016_structure_1_of_1
_cod_database_code               2001790
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x+1/2,y+1/2,-z+1/2
3 -x,-y,-z
4 x+1/2,-y+1/2,z+1/2
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
O(1) .0795(3) .1366(3) .40920(10)
O(2) -.2126(3) .6044(4) .27000(10)
O(3) .4091(2) .5535(3) .58100(10)
O(4) .5697(3) .2949(3) .66520(10)
O(5) .6712(3) .5385(4) .73340(10)
N(1) -.0826(3) .3331(4) .32800(10)
N(2) .0842(3) .4940(3) .40760(10)
N(3) .1933(3) .5136(3) .46580(10)
N(4) .5870(3) .4761(4) .68100(10)
C(1) .0342(3) .3000(4) .38530(10)
C(2) -.1145(4) .5360(5) .31550(10)
C(3) -.0045(4) .6574(4) .3683(2)
C(4) .2357(3) .6977(4) .48460(10)
C(5) .3510(4) .7264(4) .54550(10)
C(6) .5097(3) .6262(4) .63550(10)
C(7) .5188(4) .8331(4) .63690(10)
C(8) .4161(4) .8974(4) .5782(2)
H(1) -.133(4) .236(6) .298(2)
H(31) -.075(4) .734(5) .4010(10)
H(32) .073(3) .738(4) .3450(10)
H(4) .190(3) .827(4) .4630(10)
H(7) .587(3) .904(4) .6700(10)
H(8) .388(3) 1.029(5) .5620(10)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C(5) O(3) C(6) 104.8(2)
C(1) N(1) C(2) 113.0(2)
N(3) N(2) C(1) 119.3(2)
N(3) N(2) C(3) 127.6(2)
C(1) N(2) C(3) 112.8(2)
N(2) N(3) C(4) 116.9(2)
O(4) N(4) O(5) 124.3(3)
O(4) N(4) C(6) 118.3(2)
O(5) N(4) C(6) 117.4(2)
O(1) C(1) N(1) 126.7(2)
O(1) C(1) N(2) 128.1(2)
N(1) C(1) N(2) 105.2(2)
O(2) C(2) N(1) 125.8(2)
O(2) C(2) C(3) 127.1(3)
N(1) C(2) C(3) 107.2(2)
N(2) C(3) C(2) 101.7(2)
N(3) C(4) C(5) 119.0(2)
O(3) C(5) C(4) 117.8(2)
O(3) C(5) C(8) 109.6(2)
C(4) C(5) C(8) 132.6(2)
O(3) C(6) N(4) 116.1(2)
O(3) C(6) C(7) 113.0(2)
N(4) C(6) C(7) 130.9(2)
C(6) C(7) C(8) 104.8(2)
C(5) C(8) C(7) 107.8(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O(1) C(1) 1.195(3)
O(2) C(2) 1.206(3)
O(3) C(5) 1.369(3)
O(3) C(6) 1.348(3)
O(4) N(4) 1.214(3)
O(5) N(4) 1.228(3)
N(1) C(1) 1.397(3)
N(1) C(2) 1.353(4)
N(2) N(3) 1.363(3)
N(2) C(1) 1.373(3)
N(2) C(3) 1.447(4)
N(3) C(4) 1.280(3)
N(4) C(6) 1.411(3)
C(2) C(3) 1.504(4)
C(4) C(5) 1.437(3)
C(5) C(8) 1.353(4)
C(6) C(7) 1.339(4)
C(7) C(8) 1.397(4)
