#------------------------------------------------------------------------------
#$Date: 2015-10-24 04:05:49 +0300 (Sat, 24 Oct 2015) $
#$Revision: 169730 $
#$URL: svn://www.crystallography.net/cod/cif/2/02/02/2020274.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2020274
loop_
_publ_author_name
'Pukas, Svitlana'
'Gladyshevskii, Roman'
_publ_section_title
;
 The new structure type Gd₃Ni₇Al₁₄
;
_journal_coeditor_code           KU3165
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229615018082
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac          'Gd3 Ni7 Al14'
_chemical_formula_moiety         'Al14 Gd3 Ni7'
_chemical_formula_sum            'Al14 Gd3 Ni7'
_chemical_formula_weight         1260.44
_chemical_name_common            aluminide
_chemical_name_systematic
;
Trigadolinium heptanickel tetradecaaluminide
;
_space_group_crystal_system      hexagonal
_space_group_IT_number           189
_space_group_name_Hall           'P -6 -2'
_space_group_name_H-M_alt        'P -6 2 m'
_symmetry_space_group_name_Hall  'P -6 -2'
_symmetry_space_group_name_H-M   'P -6 2 m'
_audit_creation_method           SHELXL-2014
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   17.966(5)
_cell_length_b                   17.966(5)
_cell_length_c                   4.0448(6)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      12.92
_cell_measurement_theta_min      5.52
_cell_volume                     1130.7(5)
_computing_cell_refinement
;
CAD-4 EXPRESS (Enraf--Nonius, 1994)
;
_computing_data_collection
;
CAD-4 EXPRESS (Enraf--Nonius, 1994)
;
_computing_data_reduction
;
XCAD4 (Harms & Wocadlo, 1995)
;
_computing_molecular_graphics
;
ATOMS (Dowty, 1999)
;
_computing_publication_material
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXL97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Enraf--Nonius CAD-4T'
_diffrn_measurement_method       ω/2θ
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0663
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -3
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            8229
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         34.986
_diffrn_reflns_theta_min         2.267
_diffrn_standards_decay_%        12
_diffrn_standards_interval_time  120
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    22.314
_exptl_absorpt_correction_T_max  0.7990
_exptl_absorpt_correction_T_min  0.4070
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SORTAV; Blessing, 1995)
;
_exptl_crystal_colour            metallic-grey
_exptl_crystal_density_diffrn    5.554
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1710
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.302
_refine_diff_density_min         -1.586
_refine_ls_abs_structure_details
;
Flack x parameter determined using 647 quotients
[(I⁺) - (I⁻)]/[(I⁺) + (I⁻)] (Parsons et al.,  2013)
;
_refine_ls_abs_structure_Flack   -0.040(17)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.805
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     81
_refine_ls_number_reflns         1834
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.805
_refine_ls_R_factor_all          0.0322
_refine_ls_R_factor_gt           0.0226
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0050P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0296
_refine_ls_wR_factor_ref         0.0306
_reflns_number_gt                1575
_reflns_number_total             1834
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ku3165sup1.cif
_cod_data_source_block           I
_cod_original_cell_volume        1130.6(7)
_cod_database_code               2020274
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2.014
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, y, -z'
'y, x, z'
'y, x, -z'
'x-y, -y, -z'
'x-y, -y, z'
'-x, -x+y, z'
'-x, -x+y, -z'
'-y, x-y, z'
'-y, x-y, -z'
'-x+y, -x, -z'
'-x+y, -x, z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Gd Gd1 0.30680(3) 0.48122(3) 0.5000 0.00642(7) Uani d 1
Gd Gd2 0.20317(3) 0.0000 0.0000 0.00673(10) Uani d 1
Ni Ni1 0.14012(7) 0.22783(7) 0.5000 0.0068(2) Uani d 1
Ni Ni2 0.08542(7) 0.53536(7) 0.0000 0.0068(2) Uani d 1
Ni Ni3 0.15216(7) 0.42823(7) 0.0000 0.0068(2) Uani d 1
Ni Ni4 0.3333 0.6667 0.5000 0.0056(3) Uani d 1
Ni Ni5 0.0000 0.0000 0.0000 0.0090(5) Uani d 1
Al Al1 0.09982(17) 0.34005(19) 0.5000 0.0088(5) Uani d 1
Al Al2 0.14542(17) 0.50499(16) 0.5000 0.0085(5) Uani d 1
Al Al3 0.20022(18) 0.32339(18) 0.0000 0.0094(5) Uani d 1
Al Al4 0.24196(19) 0.58817(19) 0.0000 0.0093(5) Uani d 1
Al Al5 0.0851(2) 0.0000 0.5000 0.0080(7) Uani d 1
Al Al6 0.5127(2) 0.0000 0.5000 0.0096(8) Uani d 1
Al Al7 0.7055(2) 0.0000 0.5000 0.0094(7) Uani d 1
Al Al8 0.3766(2) 0.0000 0.0000 0.0146(9) Uani d 1
Al Al9 0.6093(3) 0.0000 0.0000 0.0169(9) Uani d 1
Al Al10 0.8590(2) 0.0000 0.0000 0.0098(7) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
Ni4 Gd1 Al2 . . 60.83(5)
Ni4 Gd1 Al2 . 9_665 60.63(5)
Al2 Gd1 Al2 . 9_665 121.45(8)
Ni4 Gd1 Ni3 . 1_556 87.92(2)
Al2 Gd1 Ni3 . 1_556 46.39(3)
Al2 Gd1 Ni3 9_665 1_556 130.77(3)
Ni4 Gd1 Ni3 . . 87.92(2)
Al2 Gd1 Ni3 . . 46.39(3)
Al2 Gd1 Ni3 9_665 . 130.77(3)
Ni3 Gd1 Ni3 1_556 . 79.18(3)
Ni4 Gd1 Ni2 . 9_666 87.38(2)
Al2 Gd1 Ni2 . 9_666 130.64(3)
Al2 Gd1 Ni2 9_665 9_666 46.00(3)
Ni3 Gd1 Ni2 1_556 9_666 100.82(3)
Ni3 Gd1 Ni2 . 9_666 175.30(3)
Ni4 Gd1 Ni2 . 9_665 87.38(2)
Al2 Gd1 Ni2 . 9_665 130.64(3)
Al2 Gd1 Ni2 9_665 9_665 46.00(3)
Ni3 Gd1 Ni2 1_556 9_665 175.30(3)
Ni3 Gd1 Ni2 . 9_665 100.82(3)
Ni2 Gd1 Ni2 9_666 9_665 78.79(3)
Ni4 Gd1 Al6 . 7_665 110.70(6)
Al2 Gd1 Al6 . 7_665 171.53(7)
Al2 Gd1 Al6 9_665 7_665 50.08(7)
Ni3 Gd1 Al6 1_556 7_665 137.13(3)
Ni3 Gd1 Al6 . 7_665 137.13(3)
Ni2 Gd1 Al6 9_666 7_665 45.13(3)
Ni2 Gd1 Al6 9_665 7_665 45.13(3)
Ni4 Gd1 Al3 . 1_556 130.26(4)
Al2 Gd1 Al3 . 1_556 86.37(6)
Al2 Gd1 Al3 9_665 1_556 134.00(5)
Ni3 Gd1 Al3 1_556 1_556 44.73(5)
Ni3 Gd1 Al3 . 1_556 95.17(5)
Ni2 Gd1 Al3 9_666 1_556 88.00(5)
Ni2 Gd1 Al3 9_665 1_556 139.68(6)
Al6 Gd1 Al3 7_665 1_556 100.19(7)
Ni4 Gd1 Al3 . . 130.26(4)
Al2 Gd1 Al3 . . 86.37(6)
Al2 Gd1 Al3 9_665 . 134.00(5)
Ni3 Gd1 Al3 1_556 . 95.17(5)
Ni3 Gd1 Al3 . . 44.73(5)
Ni2 Gd1 Al3 9_666 . 139.68(6)
Ni2 Gd1 Al3 9_665 . 88.00(5)
Al6 Gd1 Al3 7_665 . 100.19(7)
Al3 Gd1 Al3 1_556 . 77.82(7)
Ni4 Gd1 Al7 . 7_665 175.77(6)
Al2 Gd1 Al7 . 7_665 123.40(7)
Al2 Gd1 Al7 9_665 7_665 115.15(9)
Ni3 Gd1 Al7 1_556 7_665 95.33(5)
Ni3 Gd1 Al7 . 7_665 95.33(5)
Ni2 Gd1 Al7 9_666 7_665 89.35(5)
Ni2 Gd1 Al7 9_665 7_665 89.35(5)
Al6 Gd1 Al7 7_665 7_665 65.07(8)
Al3 Gd1 Al7 1_556 7_665 52.22(6)
Al3 Gd1 Al7 . 7_665 52.22(6)
Ni4 Gd1 Al1 . . 109.47(5)
Al2 Gd1 Al1 . . 48.65(7)
Al2 Gd1 Al1 9_665 . 170.10(7)
Ni3 Gd1 Al1 1_556 . 44.47(3)
Ni3 Gd1 Al1 . . 44.47(3)
Ni2 Gd1 Al1 9_666 . 137.95(2)
Ni2 Gd1 Al1 9_665 . 137.95(2)
Al6 Gd1 Al1 7_665 . 139.82(8)
Al3 Gd1 Al1 1_556 . 51.39(5)
Al3 Gd1 Al1 . . 51.39(5)
Al7 Gd1 Al1 7_665 . 74.75(8)
Al5 Gd2 Al5 1_554 . 87.27(10)
Al5 Gd2 Al1 1_554 3 147.65(5)
Al5 Gd2 Al1 . 3 84.92(6)
Al5 Gd2 Al1 1_554 11 84.92(6)
Al5 Gd2 Al1 . 11 147.65(5)
Al1 Gd2 Al1 3 11 117.00(10)
Al5 Gd2 Al1 1_554 11_556 147.65(5)
Al5 Gd2 Al1 . 11_556 84.92(6)
Al1 Gd2 Al1 3 11_556 62.58(9)
Al1 Gd2 Al1 11 11_556 85.10(8)
Al5 Gd2 Al1 1_554 3_554 84.92(6)
Al5 Gd2 Al1 . 3_554 147.65(5)
Al1 Gd2 Al1 3 3_554 85.10(8)
Al1 Gd2 Al1 11 3_554 62.58(9)
Al1 Gd2 Al1 11_556 3_554 117.00(10)
Al5 Gd2 Ni1 1_554 3 105.14(4)
Al5 Gd2 Ni1 . 3 49.91(3)
Al1 Gd2 Ni1 3 3 47.74(5)
Al1 Gd2 Ni1 11 3 161.61(5)
Al1 Gd2 Ni1 11_556 3 93.54(4)
Al1 Gd2 Ni1 3_554 3 102.39(5)
Al5 Gd2 Ni1 1_554 3_554 49.91(3)
Al5 Gd2 Ni1 . 3_554 105.14(4)
Al1 Gd2 Ni1 3 3_554 102.39(5)
Al1 Gd2 Ni1 11 3_554 93.54(4)
Al1 Gd2 Ni1 11_556 3_554 161.61(5)
Al1 Gd2 Ni1 3_554 3_554 47.74(5)
Ni1 Gd2 Ni1 3 3_554 81.97(3)
Al5 Gd2 Ni1 1_554 11 49.91(3)
Al5 Gd2 Ni1 . 11 105.14(4)
Al1 Gd2 Ni1 3 11 161.61(5)
Al1 Gd2 Ni1 11 11 47.74(5)
Al1 Gd2 Ni1 11_556 11 102.39(5)
Al1 Gd2 Ni1 3_554 11 93.55(4)
Ni1 Gd2 Ni1 3 11 149.32(5)
Ni1 Gd2 Ni1 3_554 11 89.98(3)
Al5 Gd2 Ni1 1_554 11_556 105.14(4)
Al5 Gd2 Ni1 . 11_556 49.91(3)
Al1 Gd2 Ni1 3 11_556 93.55(4)
Al1 Gd2 Ni1 11 11_556 102.39(5)
Al1 Gd2 Ni1 11_556 11_556 47.74(5)
Al1 Gd2 Ni1 3_554 11_556 161.61(5)
Ni1 Gd2 Ni1 3 11_556 89.98(3)
Ni1 Gd2 Ni1 3_554 11_556 149.32(5)
Ni1 Gd2 Ni1 11 11_556 81.97(3)
Al5 Gd2 Al8 1_554 . 136.37(5)
Al5 Gd2 Al8 . . 136.37(5)
Al1 Gd2 Al8 3 . 58.50(5)
Al1 Gd2 Al8 11 . 58.50(5)
Al1 Gd2 Al8 11_556 . 58.50(5)
Al1 Gd2 Al8 3_554 . 58.50(5)
Ni1 Gd2 Al8 3 . 105.34(2)
Ni1 Gd2 Al8 3_554 . 105.34(2)
Ni1 Gd2 Al8 11 . 105.34(2)
Ni1 Gd2 Al8 11_556 . 105.34(2)
Al5 Gd2 Al3 1_554 3 94.78(4)
Al5 Gd2 Al3 . 3 94.78(4)
Al1 Gd2 Al3 3 3 54.82(5)
Al1 Gd2 Al3 11 3 117.11(6)
Al1 Gd2 Al3 11_556 3 117.11(6)
Al1 Gd2 Al3 3_554 3 54.82(5)
Ni1 Gd2 Al3 3 3 47.79(3)
Ni1 Gd2 Al3 3_554 3 47.79(3)
Ni1 Gd2 Al3 11 3 137.12(2)
Ni1 Gd2 Al3 11_556 3 137.12(2)
Al8 Gd2 Al3 . 3 83.38(5)
Al7 Ni1 Al1 7_665 . 109.26(10)
Al7 Ni1 Al3 7_665 . 70.53(8)
Al1 Ni1 Al3 . . 69.08(7)
Al7 Ni1 Al3 7_665 1_556 70.53(8)
Al1 Ni1 Al3 . 1_556 69.08(7)
Al3 Ni1 Al3 . 1_556 106.75(12)
Al7 Ni1 Al5 7_665 3 144.59(10)
Al1 Ni1 Al5 . 3 106.15(11)
Al3 Ni1 Al5 . 3 123.94(6)
Al3 Ni1 Al5 1_556 3 123.94(6)
Al7 Ni1 Al10 7_665 7_665 86.93(8)
Al1 Ni1 Al10 . 7_665 126.43(3)
Al3 Ni1 Al10 . 7_665 69.50(8)
Al3 Ni1 Al10 1_556 7_665 156.70(10)
Al5 Ni1 Al10 3 7_665 71.94(9)
Al7 Ni1 Al10 7_665 7_666 86.93(8)
Al1 Ni1 Al10 . 7_666 126.43(3)
Al3 Ni1 Al10 . 7_666 156.70(10)
Al3 Ni1 Al10 1_556 7_666 69.50(8)
Al5 Ni1 Al10 3 7_666 71.94(9)
Al10 Ni1 Al10 7_665 7_666 104.44(8)
Al7 Ni1 Ni1 7_665 3 55.50(6)
Al1 Ni1 Ni1 . 3 164.77(7)
Al3 Ni1 Ni1 . 3 102.65(7)
Al3 Ni1 Ni1 1_556 3 102.65(7)
Al5 Ni1 Ni1 3 3 89.08(8)
Al10 Ni1 Ni1 7_665 3 57.77(3)
Al10 Ni1 Ni1 7_666 3 57.77(3)
Al7 Ni1 Gd2 7_665 3 136.52(3)
Al1 Ni1 Gd2 . 3 64.15(5)
Al3 Ni1 Gd2 . 3 67.19(6)
Al3 Ni1 Gd2 1_556 3 131.70(8)
Al5 Ni1 Gd2 3 3 61.92(6)
Al10 Ni1 Gd2 7_665 3 69.37(4)
Al10 Ni1 Gd2 7_666 3 133.19(9)
Ni1 Ni1 Gd2 3 3 125.63(2)
Al7 Ni1 Gd2 7_665 3_556 136.52(3)
Al1 Ni1 Gd2 . 3_556 64.15(5)
Al3 Ni1 Gd2 . 3_556 131.69(8)
Al3 Ni1 Gd2 1_556 3_556 67.20(6)
Al5 Ni1 Gd2 3 3_556 61.92(6)
Al10 Ni1 Gd2 7_665 3_556 133.19(9)
Al10 Ni1 Gd2 7_666 3_556 69.37(4)
Ni1 Ni1 Gd2 3 3_556 125.63(2)
Gd2 Ni1 Gd2 3 3_556 81.97(3)
Al6 Ni2 Al6 3_554 3 111.50(6)
Al6 Ni2 Al8 3_554 3 80.34(9)
Al6 Ni2 Al8 3 3 80.34(9)
Al6 Ni2 Al2 3_554 . 160.72(11)
Al6 Ni2 Al2 3 . 66.07(7)
Al8 Ni2 Al2 3 . 80.41(7)
Al6 Ni2 Al2 3_554 1_554 66.07(7)
Al6 Ni2 Al2 3 1_554 160.72(11)
Al8 Ni2 Al2 3 1_554 80.41(7)
Al2 Ni2 Al2 . 1_554 109.44(11)
Al6 Ni2 Al4 3_554 . 124.13(3)
Al6 Ni2 Al4 3 . 124.13(3)
Al8 Ni2 Al4 3 . 111.88(10)
Al2 Ni2 Al4 . . 63.18(7)
Al2 Ni2 Al4 1_554 . 63.19(7)
Al6 Ni2 Al9 3_554 3 65.46(9)
Al6 Ni2 Al9 3 3 65.46(9)
Al8 Ni2 Al9 3 3 115.11(9)
Al2 Ni2 Al9 . 3 124.85(6)
Al2 Ni2 Al9 1_554 3 124.85(6)
Al4 Ni2 Al9 . 3 133.02(10)
Al6 Ni2 Ni2 3_554 7 57.10(2)
Al6 Ni2 Ni2 3 7 57.10(2)
Al8 Ni2 Ni2 3 7 57.49(6)
Al2 Ni2 Ni2 . 7 112.14(6)
Al2 Ni2 Ni2 1_554 7 112.13(6)
Al4 Ni2 Ni2 . 7 169.36(7)
Al9 Ni2 Ni2 3 7 57.62(7)
Al6 Ni2 Ni3 3_554 . 110.05(9)
Al6 Ni2 Ni3 3 . 110.05(9)
Al8 Ni2 Ni3 3 . 54.87(6)
Al2 Ni2 Ni3 . . 56.76(6)
Al2 Ni2 Ni3 1_554 . 56.76(6)
Al4 Ni2 Ni3 . . 57.00(8)
Al9 Ni2 Ni3 3 . 169.98(8)
Ni2 Ni2 Ni3 7 . 112.36(3)
Al6 Ni2 Gd1 3_554 11_566 131.80(10)
Al6 Ni2 Gd1 3 11_566 67.50(6)
Al8 Ni2 Gd1 3 11_566 140.573(16)
Al2 Ni2 Gd1 . 11_566 66.29(6)
Al2 Ni2 Gd1 1_554 11_566 129.35(7)
Al4 Ni2 Gd1 . 11_566 71.99(5)
Al9 Ni2 Gd1 3 11_566 72.13(6)
Ni2 Ni2 Gd1 7 11_566 115.76(2)
Ni3 Ni2 Gd1 . 11_566 115.19(3)
Al6 Ni2 Gd1 3_554 11_565 67.50(6)
Al6 Ni2 Gd1 3 11_565 131.80(10)
Al8 Ni2 Gd1 3 11_565 140.573(16)
Al2 Ni2 Gd1 . 11_565 129.35(7)
Al2 Ni2 Gd1 1_554 11_565 66.29(6)
Al4 Ni2 Gd1 . 11_565 71.99(5)
Al9 Ni2 Gd1 3 11_565 72.13(6)
Ni2 Ni2 Gd1 7 11_565 115.76(2)
Ni3 Ni2 Gd1 . 11_565 115.19(3)
Gd1 Ni2 Gd1 11_566 11_565 78.79(3)
Al8 Ni3 Al3 3 . 118.40(14)
Al8 Ni3 Al1 3 1_554 75.87(9)
Al3 Ni3 Al1 . 1_554 70.68(7)
Al8 Ni3 Al1 3 . 75.87(9)
Al3 Ni3 Al1 . . 70.68(7)
Al1 Ni3 Al1 1_554 . 111.38(12)
Al8 Ni3 Al2 3 1_554 81.54(9)
Al3 Ni3 Al2 . 1_554 124.36(6)
Al1 Ni3 Al2 1_554 1_554 64.99(8)
Al1 Ni3 Al2 . 1_554 157.21(10)
Al8 Ni3 Al2 3 . 81.54(9)
Al3 Ni3 Al2 . . 124.36(6)
Al1 Ni3 Al2 1_554 . 157.21(10)
Al1 Ni3 Al2 . . 64.99(8)
Al2 Ni3 Al2 1_554 . 108.97(11)
Al8 Ni3 Al4 3 . 113.56(15)
Al3 Ni3 Al4 . . 128.04(11)
Al1 Ni3 Al4 1_554 . 124.28(6)
Al1 Ni3 Al4 . . 124.28(6)
Al2 Ni3 Al4 1_554 . 62.85(7)
Al2 Ni3 Al4 . . 62.85(7)
Al8 Ni3 Ni2 3 . 57.14(11)
Al3 Ni3 Ni2 . . 175.54(9)
Al1 Ni3 Ni2 1_554 . 107.11(7)
Al1 Ni3 Ni2 . . 107.12(7)
Al2 Ni3 Ni2 1_554 . 56.50(6)
Al2 Ni3 Ni2 . . 56.50(6)
Al4 Ni3 Ni2 . . 56.42(8)
Al8 Ni3 Gd1 3 . 140.408(16)
Al3 Ni3 Gd1 . . 68.65(5)
Al1 Ni3 Gd1 1_554 . 135.72(7)
Al1 Ni3 Gd1 . . 70.31(6)
Al2 Ni3 Gd1 1_554 . 129.09(7)
Al2 Ni3 Gd1 . . 65.99(6)
Al4 Ni3 Gd1 . . 71.91(6)
Ni2 Ni3 Gd1 . . 114.57(3)
Al8 Ni3 Gd1 3 1_554 140.408(16)
Al3 Ni3 Gd1 . 1_554 68.65(5)
Al1 Ni3 Gd1 1_554 1_554 70.31(6)
Al1 Ni3 Gd1 . 1_554 135.72(7)
Al2 Ni3 Gd1 1_554 1_554 65.99(6)
Al2 Ni3 Gd1 . 1_554 129.09(8)
Al4 Ni3 Gd1 . 1_554 71.91(6)
Ni2 Ni3 Gd1 . 1_554 114.57(3)
Gd1 Ni3 Gd1 . 1_554 79.18(3)
Al4 Ni4 Al4 11_566 11_565 105.46(11)
Al4 Ni4 Al4 11_566 . 144.75(4)
Al4 Ni4 Al4 11_565 . 63.26(9)
Al4 Ni4 Al4 11_566 1_556 63.26(9)
Al4 Ni4 Al4 11_565 1_556 144.75(4)
Al4 Ni4 Al4 . 1_556 105.46(11)
Al4 Ni4 Al4 11_566 9_666 63.26(9)
Al4 Ni4 Al4 11_565 9_666 144.75(4)
Al4 Ni4 Al4 . 9_666 144.75(4)
Al4 Ni4 Al4 1_556 9_666 63.26(9)
Al4 Ni4 Al4 11_566 9_665 144.75(4)
Al4 Ni4 Al4 11_565 9_665 63.26(9)
Al4 Ni4 Al4 . 9_665 63.26(9)
Al4 Ni4 Al4 1_556 9_665 144.75(4)
Al4 Ni4 Al4 9_666 9_665 105.46(11)
Al4 Ni4 Gd1 11_566 11_566 72.31(6)
Al4 Ni4 Gd1 11_565 11_566 72.31(6)
Al4 Ni4 Gd1 . 11_566 72.44(6)
Al4 Ni4 Gd1 1_556 11_566 72.45(6)
Al4 Ni4 Gd1 9_666 11_566 127.27(5)
Al4 Ni4 Gd1 9_665 11_566 127.27(5)
Al4 Ni4 Gd1 11_566 9_665 72.44(6)
Al4 Ni4 Gd1 11_565 9_665 72.44(6)
Al4 Ni4 Gd1 . 9_665 127.27(5)
Al4 Ni4 Gd1 1_556 9_665 127.27(5)
Al4 Ni4 Gd1 9_666 9_665 72.31(6)
Al4 Ni4 Gd1 9_665 9_665 72.31(6)
Gd1 Ni4 Gd1 11_566 9_665 120.0020(10)
Al4 Ni4 Gd1 11_566 . 127.27(5)
Al4 Ni4 Gd1 11_565 . 127.27(5)
Al4 Ni4 Gd1 . . 72.31(6)
Al4 Ni4 Gd1 1_556 . 72.30(6)
Al4 Ni4 Gd1 9_666 . 72.44(6)
Al4 Ni4 Gd1 9_665 . 72.44(6)
Gd1 Ni4 Gd1 11_566 . 120.0
Gd1 Ni4 Gd1 9_665 . 120.0
Al10 Ni5 Al10 7_665 3_545 120.0
Al10 Ni5 Al10 7_665 1_455 120.0
Al10 Ni5 Al10 3_545 1_455 120.0
Al10 Ni5 Al5 7_665 . 72.45(3)
Al10 Ni5 Al5 3_545 . 72.45(3)
Al10 Ni5 Al5 1_455 . 127.09(7)
Al10 Ni5 Al5 7_665 7_554 127.09(7)
Al10 Ni5 Al5 3_545 7_554 72.45(3)
Al10 Ni5 Al5 1_455 7_554 72.45(3)
Al5 Ni5 Al5 . 7_554 144.90(6)
Al10 Ni5 Al5 7_665 3 72.45(3)
Al10 Ni5 Al5 3_545 3 127.09(7)
Al10 Ni5 Al5 1_455 3 72.45(3)
Al5 Ni5 Al5 . 3 62.97(11)
Al5 Ni5 Al5 7_554 3 144.90(6)
Al10 Ni5 Al5 7_665 1_554 72.45(3)
Al10 Ni5 Al5 3_545 1_554 72.45(3)
Al10 Ni5 Al5 1_455 1_554 127.09(7)
Al5 Ni5 Al5 . 1_554 105.83(14)
Al5 Ni5 Al5 7_554 1_554 62.97(11)
Al5 Ni5 Al5 3 1_554 144.90(6)
Al10 Ni5 Al5 7_665 3_554 72.45(3)
Al10 Ni5 Al5 3_545 3_554 127.09(7)
Al10 Ni5 Al5 1_455 3_554 72.45(3)
Al5 Ni5 Al5 . 3_554 144.90(6)
Al5 Ni5 Al5 7_554 3_554 62.97(11)
Al5 Ni5 Al5 3 3_554 105.82(14)
Al5 Ni5 Al5 1_554 3_554 62.97(11)
Al10 Ni5 Al5 7_665 7 127.09(7)
Al10 Ni5 Al5 3_545 7 72.45(3)
Al10 Ni5 Al5 1_455 7 72.45(3)
Al5 Ni5 Al5 . 7 62.97(11)
Al5 Ni5 Al5 7_554 7 105.82(14)
Al5 Ni5 Al5 3 7 62.97(11)
Al5 Ni5 Al5 1_554 7 144.90(6)
Al5 Ni5 Al5 3_554 7 144.90(6)
Ni3 Al1 Ni3 1_556 . 111.38(12)
Ni3 Al1 Ni1 1_556 . 110.81(7)
Ni3 Al1 Ni1 . . 110.81(7)
Ni3 Al1 Al2 1_556 . 58.17(6)
Ni3 Al1 Al2 . . 58.17(7)
Ni1 Al1 Al2 . . 149.71(13)
Ni3 Al1 Al3 1_556 . 126.96(11)
Ni3 Al1 Al3 . . 54.40(6)
Ni1 Al1 Al3 . . 56.47(7)
Al2 Al1 Al3 . . 105.17(10)
Ni3 Al1 Al3 1_556 1_556 54.40(6)
Ni3 Al1 Al3 . 1_556 126.96(11)
Ni1 Al1 Al3 . 1_556 56.47(7)
Al2 Al1 Al3 . 1_556 105.17(10)
Al3 Al1 Al3 . 1_556 91.49(11)
Ni3 Al1 Al8 1_556 3 119.73(13)
Ni3 Al1 Al8 . 3 51.45(5)
Ni1 Al1 Al8 . 3 129.46(10)
Al2 Al1 Al8 . 3 68.78(10)
Al3 Al1 Al8 . 3 91.37(6)
Al3 Al1 Al8 1_556 3 173.83(13)
Ni3 Al1 Al8 1_556 3_556 51.45(5)
Ni3 Al1 Al8 . 3_556 119.73(13)
Ni1 Al1 Al8 . 3_556 129.46(10)
Al2 Al1 Al8 . 3_556 68.78(10)
Al3 Al1 Al8 . 3_556 173.83(13)
Al3 Al1 Al8 1_556 3_556 91.37(6)
Al8 Al1 Al8 3 3_556 85.28(11)
Ni3 Al1 Gd2 1_556 3 165.71(10)
Ni3 Al1 Gd2 . 3 81.48(3)
Ni1 Al1 Gd2 . 3 68.11(7)
Al2 Al1 Gd2 . 3 129.97(6)
Al3 Al1 Gd2 . 3 65.21(6)
Al3 Al1 Gd2 1_556 3 123.33(11)
Al8 Al1 Gd2 3 3 62.84(8)
Al8 Al1 Gd2 3_556 3 117.37(9)
Ni3 Al1 Gd2 1_556 3_556 81.48(3)
Ni3 Al1 Gd2 . 3_556 165.71(10)
Ni1 Al1 Gd2 . 3_556 68.11(7)
Al2 Al1 Gd2 . 3_556 129.97(6)
Al3 Al1 Gd2 . 3_556 123.33(11)
Al3 Al1 Gd2 1_556 3_556 65.21(6)
Al8 Al1 Gd2 3 3_556 117.37(9)
Al8 Al1 Gd2 3_556 3_556 62.84(8)
Gd2 Al1 Gd2 3 3_556 85.10(8)
Ni3 Al1 Gd1 1_556 . 65.22(6)
Ni3 Al1 Gd1 . . 65.22(6)
Ni1 Al1 Gd1 . . 87.10(8)
Al2 Al1 Gd1 . . 62.60(9)
Al3 Al1 Gd1 . . 63.01(7)
Al3 Al1 Gd1 1_556 . 63.01(7)
Al8 Al1 Gd1 3 . 113.71(8)
Al8 Al1 Gd1 3_556 . 113.71(8)
Gd2 Al1 Gd1 3 . 128.00(5)
Gd2 Al1 Gd1 3_556 . 128.00(5)
Ni2 Al2 Ni2 . 1_556 109.44(11)
Ni2 Al2 Ni3 . . 66.74(4)
Ni2 Al2 Ni3 1_556 . 159.06(12)
Ni2 Al2 Ni3 . 1_556 159.07(12)
Ni2 Al2 Ni3 1_556 1_556 66.74(4)
Ni3 Al2 Ni3 . 1_556 108.97(11)
Ni2 Al2 Al4 . 1_556 138.44(13)
Ni2 Al2 Al4 1_556 1_556 58.42(7)
Ni3 Al2 Al4 . 1_556 138.55(14)
Ni3 Al2 Al4 1_556 1_556 58.76(7)
Ni2 Al2 Al4 . . 58.42(7)
Ni2 Al2 Al4 1_556 . 138.44(13)
Ni3 Al2 Al4 . . 58.76(7)
Ni3 Al2 Al4 1_556 . 138.56(14)
Al4 Al2 Al4 1_556 . 102.34(14)
Ni2 Al2 Al1 . . 108.72(8)
Ni2 Al2 Al1 1_556 . 108.72(8)
Ni3 Al2 Al1 . . 56.84(6)
Ni3 Al2 Al1 1_556 . 56.84(6)
Al4 Al2 Al1 1_556 . 112.80(10)
Al4 Al2 Al1 . . 112.81(10)
Ni2 Al2 Al6 . 3 56.42(6)
Ni2 Al2 Al6 1_556 3 56.41(6)
Ni3 Al2 Al6 . 3 110.33(8)
Ni3 Al2 Al6 1_556 3 110.33(8)
Al4 Al2 Al6 1_556 3 110.96(10)
Al4 Al2 Al6 . 3 110.96(10)
Al1 Al2 Al6 . 3 107.04(13)
Ni2 Al2 Gd1 . . 124.32(6)
Ni2 Al2 Gd1 1_556 . 124.32(6)
Ni3 Al2 Gd1 . . 67.62(6)
Ni3 Al2 Gd1 1_556 . 67.62(6)
Al4 Al2 Gd1 1_556 . 71.41(9)
Al4 Al2 Gd1 . . 71.41(9)
Al1 Al2 Gd1 . . 68.75(8)
Al6 Al2 Gd1 3 . 175.79(12)
Ni2 Al2 Gd1 . 11_566 67.71(6)
Ni2 Al2 Gd1 1_556 11_566 67.71(6)
Ni3 Al2 Gd1 . 11_566 124.57(5)
Ni3 Al2 Gd1 1_556 11_566 124.57(5)
Al4 Al2 Gd1 1_556 11_566 71.23(8)
Al4 Al2 Gd1 . 11_566 71.22(8)
Al1 Al2 Gd1 . 11_566 172.70(12)
Al6 Al2 Gd1 3 11_566 65.66(8)
Gd1 Al2 Gd1 . 11_566 118.55(8)
Ni3 Al3 Ni1 . 1_554 109.30(8)
Ni3 Al3 Ni1 . . 109.30(8)
Ni1 Al3 Ni1 1_554 . 106.75(12)
Ni3 Al3 Al1 . . 54.92(7)
Ni1 Al3 Al1 1_554 . 124.63(12)
Ni1 Al3 Al1 . . 54.45(6)
Ni3 Al3 Al1 . 1_554 54.91(7)
Ni1 Al3 Al1 1_554 1_554 54.45(7)
Ni1 Al3 Al1 . 1_554 124.63(12)
Al1 Al3 Al1 . 1_554 91.49(11)
Ni3 Al3 Al7 . 7_665 127.94(7)
Ni1 Al3 Al7 1_554 7_665 122.49(12)
Ni1 Al3 Al7 . 7_665 52.92(8)
Al1 Al3 Al7 . 7_665 88.87(5)
Al1 Al3 Al7 1_554 7_665 176.18(15)
Ni3 Al3 Al7 . 7_664 127.94(7)
Ni1 Al3 Al7 1_554 7_664 52.92(8)
Ni1 Al3 Al7 . 7_664 122.49(12)
Al1 Al3 Al7 . 7_664 176.18(15)
Al1 Al3 Al7 1_554 7_664 88.87(5)
Al7 Al3 Al7 7_665 7_664 90.51(9)
Ni3 Al3 Al10 . 7_665 143.55(13)
Ni1 Al3 Al10 1_554 7_665 55.88(6)
Ni1 Al3 Al10 . 7_665 55.88(6)
Al1 Al3 Al10 . 7_665 103.14(9)
Al1 Al3 Al10 1_554 7_665 103.14(9)
Al7 Al3 Al10 7_665 7_665 73.09(10)
Al7 Al3 Al10 7_664 7_665 73.09(10)
Ni3 Al3 Gd2 . 3 78.72(8)
Ni1 Al3 Gd2 1_554 3 65.01(7)
Ni1 Al3 Gd2 . 3 65.01(7)
Al1 Al3 Gd2 . 3 59.97(7)
Al1 Al3 Gd2 1_554 3 59.97(7)
Al7 Al3 Gd2 7_665 3 117.16(10)
Al7 Al3 Gd2 7_664 3 117.16(10)
Al10 Al3 Gd2 7_665 3 64.83(8)
Ni3 Al3 Gd1 . 1_554 66.63(6)
Ni1 Al3 Gd1 1_554 1_554 87.68(4)
Ni1 Al3 Gd1 . 1_554 165.39(9)
Al1 Al3 Gd1 . 1_554 119.13(10)
Al1 Al3 Gd1 1_554 1_554 65.60(6)
Al7 Al3 Gd1 7_665 1_554 117.42(12)
Al7 Al3 Gd1 7_664 1_554 64.43(7)
Al10 Al3 Gd1 7_665 1_554 135.79(6)
Gd2 Al3 Gd1 3 1_554 125.37(6)
Ni3 Al3 Gd1 . . 66.62(6)
Ni1 Al3 Gd1 1_554 . 165.39(9)
Ni1 Al3 Gd1 . . 87.68(4)
Al1 Al3 Gd1 . . 65.60(6)
Al1 Al3 Gd1 1_554 . 119.12(10)
Al7 Al3 Gd1 7_665 . 64.43(7)
Al7 Al3 Gd1 7_664 . 117.42(12)
Al10 Al3 Gd1 7_665 . 135.79(6)
Gd2 Al3 Gd1 3 . 125.37(6)
Gd1 Al3 Gd1 1_554 . 77.82(7)
Ni2 Al4 Ni3 . . 66.57(8)
Ni2 Al4 Ni4 . . 120.46(7)
Ni3 Al4 Ni4 . . 120.36(7)
Ni2 Al4 Ni4 . 1_554 120.46(7)
Ni3 Al4 Ni4 . 1_554 120.36(7)
Ni4 Al4 Ni4 . 1_554 105.46(11)
Ni2 Al4 Al2 . . 58.39(8)
Ni3 Al4 Al2 . . 58.39(7)
Ni4 Al4 Al2 . . 76.10(5)
Ni4 Al4 Al2 1_554 . 178.44(12)
Ni2 Al4 Al2 . 1_554 58.39(8)
Ni3 Al4 Al2 . 1_554 58.39(7)
Ni4 Al4 Al2 . 1_554 178.44(12)
Ni4 Al4 Al2 1_554 1_554 76.10(5)
Al2 Al4 Al2 . 1_554 102.34(14)
Ni2 Al4 Al4 . 11_565 116.84(17)
Ni3 Al4 Al4 . 11_565 176.58(18)
Ni4 Al4 Al4 . 11_565 58.37(4)
Ni4 Al4 Al4 1_554 11_565 58.37(4)
Al2 Al4 Al4 . 11_565 122.94(10)
Al2 Al4 Al4 1_554 11_565 122.94(10)
Ni2 Al4 Al4 . 9_665 176.84(17)
Ni3 Al4 Al4 . 9_665 116.58(18)
Ni4 Al4 Al4 . 9_665 58.37(4)
Ni4 Al4 Al4 1_554 9_665 58.37(4)
Al2 Al4 Al4 . 9_665 122.84(11)
Al2 Al4 Al4 1_554 9_665 122.84(11)
Al4 Al4 Al4 11_565 9_665 60.0
Ni2 Al4 Gd1 . . 115.53(8)
Ni3 Al4 Gd1 . . 63.42(6)
Ni4 Al4 Gd1 . . 61.82(4)
Ni4 Al4 Gd1 1_554 . 118.82(10)
Al2 Al4 Gd1 . . 61.75(7)
Al2 Al4 Gd1 1_554 . 117.44(11)
Al4 Al4 Gd1 11_565 . 114.02(9)
Al4 Al4 Gd1 9_665 . 66.85(10)
Ni2 Al4 Gd1 . 1_554 115.53(8)
Ni3 Al4 Gd1 . 1_554 63.42(6)
Ni4 Al4 Gd1 . 1_554 118.82(10)
Ni4 Al4 Gd1 1_554 1_554 61.82(4)
Al2 Al4 Gd1 . 1_554 117.44(11)
Al2 Al4 Gd1 1_554 1_554 61.75(7)
Al4 Al4 Gd1 11_565 1_554 114.02(9)
Al4 Al4 Gd1 9_665 1_554 66.85(10)
Gd1 Al4 Gd1 . 1_554 73.68(6)
Ni2 Al4 Gd1 . 11_566 63.77(6)
Ni3 Al4 Gd1 . 11_566 115.93(8)
Ni4 Al4 Gd1 . 11_566 61.73(4)
Ni4 Al4 Gd1 1_554 11_566 118.63(10)
Al2 Al4 Gd1 . 11_566 62.09(7)
Al2 Al4 Gd1 1_554 11_566 117.69(12)
Al4 Al4 Gd1 11_565 11_566 66.64(10)
Al4 Al4 Gd1 9_665 11_566 113.86(9)
Gd1 Al4 Gd1 . 11_566 106.381(19)
Gd1 Al4 Gd1 1_554 11_566 179.27(10)
Ni2 Al4 Gd1 . 11_565 63.77(6)
Ni3 Al4 Gd1 . 11_565 115.93(8)
Ni4 Al4 Gd1 . 11_565 118.63(10)
Ni4 Al4 Gd1 1_554 11_565 61.73(4)
Al2 Al4 Gd1 . 11_565 117.69(12)
Al2 Al4 Gd1 1_554 11_565 62.09(7)
Al4 Al4 Gd1 11_565 11_565 66.64(10)
Al4 Al4 Gd1 9_665 11_565 113.86(9)
Gd1 Al4 Gd1 . 11_565 179.27(10)
Gd1 Al4 Gd1 1_554 11_565 106.382(19)
Gd1 Al4 Gd1 11_566 11_565 73.55(6)
Ni5 Al5 Ni5 . 1_556 105.83(14)
Ni5 Al5 Ni1 . 11_556 108.049(19)
Ni5 Al5 Ni1 1_556 11_556 108.049(19)
Ni5 Al5 Ni1 . 3 108.050(19)
Ni5 Al5 Ni1 1_556 3 108.050(19)
Ni1 Al5 Ni1 11_556 3 118.16(16)
Ni5 Al5 Al5 . 7 58.52(6)
Ni5 Al5 Al5 1_556 7 58.52(6)
Ni1 Al5 Al5 11_556 7 90.92(8)
Ni1 Al5 Al5 3 7 150.92(8)
Ni5 Al5 Al5 . 3 58.52(6)
Ni5 Al5 Al5 1_556 3 58.52(6)
Ni1 Al5 Al5 11_556 3 150.92(8)
Ni1 Al5 Al5 3 3 90.92(8)
Al5 Al5 Al5 7 3 60.0
Ni5 Al5 Gd2 . . 83.45(3)
Ni5 Al5 Gd2 1_556 . 170.72(12)
Ni1 Al5 Gd2 11_556 . 68.17(7)
Ni1 Al5 Gd2 3 . 68.17(7)
Al5 Al5 Gd2 7 . 128.81(4)
Al5 Al5 Gd2 3 . 128.81(4)
Ni5 Al5 Gd2 . 1_556 170.72(12)
Ni5 Al5 Gd2 1_556 1_556 83.45(3)
Ni1 Al5 Gd2 11_556 1_556 68.17(7)
Ni1 Al5 Gd2 3 1_556 68.17(7)
Al5 Al5 Gd2 7 1_556 128.81(4)
Al5 Al5 Gd2 3 1_556 128.81(4)
Gd2 Al5 Gd2 . 1_556 87.27(10)
Ni5 Al5 Al10 . 3_545 53.75(6)
Ni5 Al5 Al10 1_556 3_545 119.07(9)
Ni1 Al5 Al10 11_556 3_545 54.30(6)
Ni1 Al5 Al10 3 3_545 132.32(8)
Al5 Al5 Al10 7 3_545 63.77(7)
Al5 Al5 Al10 3 3_545 106.89(9)
Gd2 Al5 Al10 . 3_545 66.26(3)
Gd2 Al5 Al10 1_556 3_545 121.95(10)
Ni5 Al5 Al10 . 7_666 119.07(9)
Ni5 Al5 Al10 1_556 7_666 53.75(6)
Ni1 Al5 Al10 11_556 7_666 132.33(8)
Ni1 Al5 Al10 3 7_666 54.31(6)
Al5 Al5 Al10 7 7_666 106.89(9)
Al5 Al5 Al10 3 7_666 63.77(7)
Gd2 Al5 Al10 . 7_666 121.95(10)
Gd2 Al5 Al10 1_556 7_666 66.26(3)
Al10 Al5 Al10 3_545 7_666 169.97(16)
Ni5 Al5 Al10 . 3_546 119.07(9)
Ni5 Al5 Al10 1_556 3_546 53.75(6)
Ni1 Al5 Al10 11_556 3_546 54.30(6)
Ni1 Al5 Al10 3 3_546 132.32(8)
Al5 Al5 Al10 7 3_546 63.77(7)
Al5 Al5 Al10 3 3_546 106.89(9)
Gd2 Al5 Al10 . 3_546 121.95(10)
Gd2 Al5 Al10 1_556 3_546 66.26(3)
Al10 Al5 Al10 3_545 3_546 84.93(8)
Al10 Al5 Al10 7_666 3_546 94.19(9)
Ni5 Al5 Al10 . 7_665 53.75(6)
Ni5 Al5 Al10 1_556 7_665 119.07(9)
Ni1 Al5 Al10 11_556 7_665 132.33(8)
Ni1 Al5 Al10 3 7_665 54.31(6)
Al5 Al5 Al10 7 7_665 106.89(9)
Al5 Al5 Al10 3 7_665 63.77(7)
Gd2 Al5 Al10 . 7_665 66.26(3)
Gd2 Al5 Al10 1_556 7_665 121.95(10)
Al10 Al5 Al10 3_545 7_665 94.19(9)
Al10 Al5 Al10 7_666 7_665 84.93(8)
Al10 Al5 Al10 3_546 7_665 169.97(16)
Ni2 Al6 Ni2 11 3_556 163.05(19)
Ni2 Al6 Ni2 11 3 65.80(5)
Ni2 Al6 Ni2 3_556 3 111.50(6)
Ni2 Al6 Ni2 11 11_556 111.50(6)
Ni2 Al6 Ni2 3_556 11_556 65.80(5)
Ni2 Al6 Ni2 3 11_556 163.05(19)
Ni2 Al6 Al9 11 . 57.90(8)
Ni2 Al6 Al9 3_556 . 136.32(13)
Ni2 Al6 Al9 3 . 57.90(8)
Ni2 Al6 Al9 11_556 . 136.32(13)
Ni2 Al6 Al9 11 1_556 136.32(13)
Ni2 Al6 Al9 3_556 1_556 57.90(8)
Ni2 Al6 Al9 3 1_556 136.32(13)
Ni2 Al6 Al9 11_556 1_556 57.90(8)
Al9 Al6 Al9 . 1_556 98.7(2)
Ni2 Al6 Al2 11 11_556 57.51(5)
Ni2 Al6 Al2 3_556 11_556 112.24(9)
Ni2 Al6 Al2 3 11_556 112.24(9)
Ni2 Al6 Al2 11_556 11_556 57.51(5)
Al9 Al6 Al2 . 11_556 110.52(5)
Al9 Al6 Al2 1_556 11_556 110.52(5)
Ni2 Al6 Al2 11 3 112.24(9)
Ni2 Al6 Al2 3_556 3 57.51(5)
Ni2 Al6 Al2 3 3 57.51(5)
Ni2 Al6 Al2 11_556 3 112.24(9)
Al9 Al6 Al2 . 3 110.52(5)
Al9 Al6 Al2 1_556 3 110.52(5)
Al2 Al6 Al2 11_556 3 114.87(17)
Ni2 Al6 Gd1 11 7_655 122.66(6)
Ni2 Al6 Gd1 3_556 7_655 67.37(4)
Ni2 Al6 Gd1 3 7_655 67.37(4)
Ni2 Al6 Gd1 11_556 7_655 122.66(6)
Al9 Al6 Gd1 . 7_655 69.99(7)
Al9 Al6 Gd1 1_556 7_655 69.99(7)
Al2 Al6 Gd1 11_556 7_655 179.13(14)
Al2 Al6 Gd1 3 7_655 64.26(5)
Ni2 Al6 Gd1 11 9_655 67.37(4)
Ni2 Al6 Gd1 3_556 9_655 122.66(6)
Ni2 Al6 Gd1 3 9_655 122.66(6)
Ni2 Al6 Gd1 11_556 9_655 67.37(4)
Al9 Al6 Gd1 . 9_655 69.99(7)
Al9 Al6 Gd1 1_556 9_655 69.99(7)
Al2 Al6 Gd1 11_556 9_655 64.26(5)
Al2 Al6 Gd1 3 9_655 179.13(14)
Gd1 Al6 Gd1 7_655 9_655 116.61(12)
Ni1 Al7 Ni1 9_655 7_655 68.99(13)
Ni1 Al7 Al9 9_655 1_556 122.37(7)
Ni1 Al7 Al9 7_655 1_556 122.37(7)
Ni1 Al7 Al9 9_655 . 122.37(7)
Ni1 Al7 Al9 7_655 . 122.37(7)
Al9 Al7 Al9 1_556 . 99.0(2)
Ni1 Al7 Al3 9_655 7_656 102.19(13)
Ni1 Al7 Al3 7_655 7_656 56.55(7)
Al9 Al7 Al3 1_556 7_656 66.05(8)
Al9 Al7 Al3 . 7_656 132.38(11)
Ni1 Al7 Al3 9_655 9_655 56.55(7)
Ni1 Al7 Al3 7_655 9_655 102.19(13)
Al9 Al7 Al3 1_556 9_655 132.38(11)
Al9 Al7 Al3 . 9_655 66.05(8)
Al3 Al7 Al3 7_656 9_655 156.2(2)
Ni1 Al7 Al3 9_655 9_656 56.55(7)
Ni1 Al7 Al3 7_655 9_656 102.19(13)
Al9 Al7 Al3 1_556 9_656 66.05(8)
Al9 Al7 Al3 . 9_656 132.38(10)
Al3 Al7 Al3 7_656 9_656 84.60(9)
Al3 Al7 Al3 9_655 9_656 90.51(9)
Ni1 Al7 Al3 9_655 7_655 102.19(13)
Ni1 Al7 Al3 7_655 7_655 56.55(7)
Al9 Al7 Al3 1_556 7_655 132.38(11)
Al9 Al7 Al3 . 7_655 66.05(8)
Al3 Al7 Al3 7_656 7_655 90.51(9)
Al3 Al7 Al3 9_655 7_655 84.60(9)
Al3 Al7 Al3 9_656 7_655 156.2(2)
Ni1 Al7 Gd1 9_655 9_655 88.88(3)
Ni1 Al7 Gd1 7_655 9_655 157.87(12)
Al9 Al7 Gd1 1_556 9_655 69.06(8)
Al9 Al7 Gd1 . 9_655 69.06(8)
Al3 Al7 Gd1 7_656 9_655 132.50(7)
Al3 Al7 Gd1 9_655 9_655 63.35(6)
Al3 Al7 Gd1 9_656 9_655 63.35(6)
Al3 Al7 Gd1 7_655 9_655 132.50(7)
Ni1 Al7 Gd1 9_655 7_655 157.87(12)
Ni1 Al7 Gd1 7_655 7_655 88.88(3)
Al9 Al7 Gd1 1_556 7_655 69.06(8)
Al9 Al7 Gd1 . 7_655 69.06(8)
Al3 Al7 Gd1 7_656 7_655 63.35(6)
Al3 Al7 Gd1 9_655 7_655 132.50(7)
Al3 Al7 Gd1 9_656 7_655 132.50(7)
Al3 Al7 Gd1 7_655 7_655 63.35(6)
Gd1 Al7 Gd1 9_655 7_655 113.25(12)
Ni3 Al8 Ni3 11 3 159.0(2)
Ni3 Al8 Ni2 11 3 133.02(16)
Ni3 Al8 Ni2 3 3 67.99(6)
Ni3 Al8 Ni2 11 11 67.99(6)
Ni3 Al8 Ni2 3 11 133.02(16)
Ni2 Al8 Ni2 3 11 65.02(12)
Ni3 Al8 Al1 11 11 52.68(6)
Ni3 Al8 Al1 3 11 114.62(12)
Ni2 Al8 Al1 3 11 135.91(8)
Ni2 Al8 Al1 11 11 99.15(6)
Ni3 Al8 Al1 11 3 114.62(12)
Ni3 Al8 Al1 3 3 52.68(6)
Ni2 Al8 Al1 3 3 99.15(6)
Ni2 Al8 Al1 11 3 135.91(8)
Al1 Al8 Al1 11 3 117.31(18)
Ni3 Al8 Al1 11 3_554 114.62(12)
Ni3 Al8 Al1 3 3_554 52.68(6)
Ni2 Al8 Al1 3 3_554 99.15(6)
Ni2 Al8 Al1 11 3_554 135.91(8)
Al1 Al8 Al1 11 3_554 62.69(11)
Al1 Al8 Al1 3 3_554 85.28(11)
Ni3 Al8 Al1 11 11_556 52.68(6)
Ni3 Al8 Al1 3 11_556 114.62(12)
Ni2 Al8 Al1 3 11_556 135.91(8)
Ni2 Al8 Al1 11 11_556 99.15(6)
Al1 Al8 Al1 11 11_556 85.28(11)
Al1 Al8 Al1 3 11_556 62.69(11)
Al1 Al8 Al1 3_554 11_556 117.31(18)
Ni3 Al8 Gd2 11 . 79.50(11)
Ni3 Al8 Gd2 3 . 79.50(11)
Ni2 Al8 Gd2 3 . 147.49(6)
Ni2 Al8 Gd2 11 . 147.49(6)
Al1 Al8 Gd2 11 . 58.66(9)
Al1 Al8 Gd2 3 . 58.66(9)
Al1 Al8 Gd2 3_554 . 58.66(9)
Al1 Al8 Gd2 11_556 . 58.66(9)
Ni2 Al9 Ni2 11 3 64.76(14)
Ni2 Al9 Al7 11 1_554 123.27(7)
Ni2 Al9 Al7 3 1_554 123.27(7)
Ni2 Al9 Al7 11 . 123.27(7)
Ni2 Al9 Al7 3 . 123.27(7)
Al7 Al9 Al7 1_554 . 99.0(2)
Ni2 Al9 Al6 11 . 56.64(11)
Ni2 Al9 Al6 3 . 56.64(11)
Al7 Al9 Al6 1_554 . 179.9(2)
Al7 Al9 Al6 . . 81.15(9)
Ni2 Al9 Al6 11 1_554 56.64(11)
Ni2 Al9 Al6 3 1_554 56.64(11)
Al7 Al9 Al6 1_554 1_554 81.14(9)
Al7 Al9 Al6 . 1_554 179.9(2)
Al6 Al9 Al6 . 1_554 98.7(2)
Ni2 Al9 Gd1 11 9_654 63.63(4)
Ni2 Al9 Gd1 3 9_654 114.49(13)
Al7 Al9 Gd1 1_554 9_654 63.72(4)
Al7 Al9 Gd1 . 9_654 117.75(11)
Al6 Al9 Gd1 . 9_654 116.23(11)
Al6 Al9 Gd1 1_554 9_654 62.30(4)
Ni2 Al9 Gd1 11 7_655 114.49(13)
Ni2 Al9 Gd1 3 7_655 63.63(4)
Al7 Al9 Gd1 1_554 7_655 117.75(11)
Al7 Al9 Gd1 . 7_655 63.72(4)
Al6 Al9 Gd1 . 7_655 62.30(4)
Al6 Al9 Gd1 1_554 7_655 116.23(11)
Gd1 Al9 Gd1 9_654 7_655 177.98(18)
Ni2 Al9 Gd1 11 9_655 63.63(4)
Ni2 Al9 Gd1 3 9_655 114.49(13)
Al7 Al9 Gd1 1_554 9_655 117.75(11)
Al7 Al9 Gd1 . 9_655 63.72(4)
Al6 Al9 Gd1 . 9_655 62.30(4)
Al6 Al9 Gd1 1_554 9_655 116.23(11)
Gd1 Al9 Gd1 9_654 9_655 73.376(19)
Gd1 Al9 Gd1 7_655 9_655 106.59(2)
Ni2 Al9 Gd1 11 7_654 114.49(13)
Ni2 Al9 Gd1 3 7_654 63.63(4)
Al7 Al9 Gd1 1_554 7_654 63.72(4)
Al7 Al9 Gd1 . 7_654 117.75(11)
Al6 Al9 Gd1 . 7_654 116.23(11)
Al6 Al9 Gd1 1_554 7_654 62.30(4)
Gd1 Al9 Gd1 9_654 7_654 106.59(2)
Gd1 Al9 Gd1 7_655 7_654 73.376(19)
Gd1 Al9 Gd1 9_655 7_654 177.98(18)
Ni5 Al10 Ni1 1_655 7_655 107.55(8)
Ni5 Al10 Ni1 1_655 7_654 107.55(8)
Ni1 Al10 Ni1 7_655 7_654 104.44(8)
Ni5 Al10 Ni1 1_655 9_654 107.55(8)
Ni1 Al10 Ni1 7_655 9_654 144.91(17)
Ni1 Al10 Ni1 7_654 9_654 64.46(6)
Ni5 Al10 Ni1 1_655 9_655 107.55(8)
Ni1 Al10 Ni1 7_655 9_655 64.46(6)
Ni1 Al10 Ni1 7_654 9_655 144.91(17)
Ni1 Al10 Ni1 9_654 9_655 104.44(8)
Ni5 Al10 Al3 1_655 9_655 138.55(7)
Ni1 Al10 Al3 7_655 9_655 97.30(10)
Ni1 Al10 Al3 7_654 9_655 97.30(10)
Ni1 Al10 Al3 9_654 9_655 54.62(6)
Ni1 Al10 Al3 9_655 9_655 54.62(6)
Ni5 Al10 Al3 1_655 7_655 138.55(7)
Ni1 Al10 Al3 7_655 7_655 54.62(6)
Ni1 Al10 Al3 7_654 7_655 54.62(6)
Ni1 Al10 Al3 9_654 7_655 97.30(10)
Ni1 Al10 Al3 9_655 7_655 97.30(10)
Al3 Al10 Al3 9_655 7_655 82.90(14)
Ni5 Al10 Al5 1_655 3_655 53.80(8)
Ni1 Al10 Al5 7_655 3_655 53.75(6)
Ni1 Al10 Al5 7_654 3_655 118.42(7)
Ni1 Al10 Al5 9_654 3_655 161.33(15)
Ni1 Al10 Al5 9_655 3_655 83.12(5)
Al3 Al10 Al5 9_655 3_655 137.33(3)
Al3 Al10 Al5 7_655 3_655 98.63(8)
Ni5 Al10 Al5 1_655 7_654 53.80(8)
Ni1 Al10 Al5 7_655 7_654 161.33(15)
Ni1 Al10 Al5 7_654 7_654 83.12(5)
Ni1 Al10 Al5 9_654 7_654 53.76(6)
Ni1 Al10 Al5 9_655 7_654 118.42(7)
Al3 Al10 Al5 9_655 7_654 98.63(8)
Al3 Al10 Al5 7_655 7_654 137.33(3)
Al5 Al10 Al5 3_655 7_654 107.60(15)
Ni5 Al10 Al5 1_655 7_655 53.80(8)
Ni1 Al10 Al5 7_655 7_655 83.12(5)
Ni1 Al10 Al5 7_654 7_655 161.33(15)
Ni1 Al10 Al5 9_654 7_655 118.42(7)
Ni1 Al10 Al5 9_655 7_655 53.76(6)
Al3 Al10 Al5 9_655 7_655 98.63(8)
Al3 Al10 Al5 7_655 7_655 137.33(3)
Al5 Al10 Al5 3_655 7_655 52.46(14)
Al5 Al10 Al5 7_654 7_655 84.93(8)
Ni5 Al10 Al5 1_655 3_654 53.80(8)
Ni1 Al10 Al5 7_655 3_654 118.42(7)
Ni1 Al10 Al5 7_654 3_654 53.75(6)
Ni1 Al10 Al5 9_654 3_654 83.12(5)
Ni1 Al10 Al5 9_655 3_654 161.33(15)
Al3 Al10 Al5 9_655 3_654 137.33(3)
Al3 Al10 Al5 7_655 3_654 98.63(8)
Al5 Al10 Al5 3_655 3_654 84.93(8)
Al5 Al10 Al5 7_654 3_654 52.46(14)
Al5 Al10 Al5 7_655 3_654 107.60(15)
Ni5 Al10 Gd2 1_655 3_655 77.36(6)
Ni1 Al10 Gd2 7_655 3_655 62.97(2)
Ni1 Al10 Gd2 7_654 3_655 62.97(2)
Ni1 Al10 Gd2 9_654 3_655 125.90(3)
Ni1 Al10 Gd2 9_655 3_655 125.90(2)
Al3 Al10 Gd2 9_655 3_655 144.09(12)
Al3 Al10 Gd2 7_655 3_655 61.18(6)
Al5 Al10 Gd2 3_655 3_655 55.91(7)
Al5 Al10 Gd2 7_654 3_655 107.58(10)
Al5 Al10 Gd2 7_655 3_655 107.58(10)
Al5 Al10 Gd2 3_654 3_655 55.91(7)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Gd1 Ni4 . 3.1208(10)
Gd1 Al2 . 3.135(3)
Gd1 Al2 9_665 3.153(3)
Gd1 Ni3 1_556 3.1733(11)
Gd1 Ni3 . 3.1733(11)
Gd1 Ni2 9_666 3.1866(10)
Gd1 Ni2 9_665 3.1866(10)
Gd1 Al6 7_665 3.190(2)
Gd1 Al3 1_556 3.220(2)
Gd1 Al3 . 3.220(2)
Gd1 Al7 7_665 3.250(3)
Gd1 Al1 . 3.291(3)
Gd2 Al5 1_554 2.931(3)
Gd2 Al5 . 2.931(3)
Gd2 Al1 3 2.991(2)
Gd2 Al1 11 2.991(2)
Gd2 Al1 11_556 2.991(2)
Gd2 Al1 3_554 2.991(2)
Gd2 Ni1 3 3.0834(10)
Gd2 Ni1 3_554 3.0834(10)
Gd2 Ni1 11 3.0835(10)
Gd2 Ni1 11_556 3.0835(10)
Gd2 Al8 . 3.115(5)
Gd2 Al3 3 3.136(3)
Ni1 Al7 7_665 2.410(4)
Ni1 Al1 . 2.459(3)
Ni1 Al3 . 2.5199(19)
Ni1 Al3 1_556 2.5199(19)
Ni1 Al5 3 2.541(2)
Ni1 Al10 7_665 2.5588(14)
Ni1 Al10 7_666 2.5588(14)
Ni1 Ni1 3 2.729(2)
Ni1 Gd2 3 3.0835(10)
Ni1 Gd2 3_556 3.0835(10)
Ni2 Al6 3_554 2.4467(9)
Ni2 Al6 3 2.4467(9)
Ni2 Al8 3 2.473(4)
Ni2 Al2 . 2.4774(17)
Ni2 Al2 1_554 2.4774(17)
Ni2 Al4 . 2.478(3)
Ni2 Al9 3 2.482(5)
Ni2 Ni2 7 2.658(2)
Ni2 Ni3 . 2.7293(17)
Ni2 Gd1 11_566 3.1865(10)
Ni2 Gd1 11_565 3.1865(10)
Ni3 Al8 3 2.4078(15)
Ni3 Al3 . 2.433(3)
Ni3 Al1 1_554 2.4484(18)
Ni3 Al1 . 2.4484(18)
Ni3 Al2 1_554 2.4847(17)
Ni3 Al2 . 2.4847(17)
Ni3 Al4 . 2.495(3)
Ni3 Gd1 1_554 3.1734(11)
Ni4 Al4 11_566 2.5413(18)
Ni4 Al4 11_565 2.5413(18)
Ni4 Al4 . 2.5414(18)
Ni4 Al4 1_556 2.5414(18)
Ni4 Al4 9_666 2.5414(18)
Ni4 Al4 9_665 2.5414(18)
Ni4 Gd1 11_566 3.1207(10)
Ni4 Gd1 9_665 3.1208(10)
Ni5 Al10 7_665 2.534(4)
Ni5 Al10 3_545 2.534(4)
Ni5 Al10 1_455 2.534(4)
Ni5 Al5 . 2.535(2)
Ni5 Al5 7_554 2.535(2)
Ni5 Al5 3 2.535(2)
Ni5 Al5 1_554 2.535(2)
Ni5 Al5 3_554 2.535(2)
Ni5 Al5 7 2.535(2)
Al1 Ni3 1_556 2.4484(18)
Al1 Al2 . 2.650(4)
Al1 Al3 . 2.824(3)
Al1 Al3 1_556 2.824(3)
Al1 Al8 3 2.986(3)
Al1 Al8 3_556 2.986(3)
Al1 Gd2 3 2.991(2)
Al1 Gd2 3_556 2.991(2)
Al2 Ni2 1_556 2.4774(17)
Al2 Ni3 1_556 2.4847(17)
Al2 Al4 1_556 2.596(3)
Al2 Al4 . 2.596(3)
Al2 Al6 3 2.685(3)
Al2 Gd1 11_566 3.153(3)
Al3 Ni1 1_554 2.5199(19)
Al3 Al1 1_554 2.824(3)
Al3 Al7 7_665 2.848(2)
Al3 Al7 7_664 2.848(2)
Al3 Al10 7_665 2.895(4)
Al3 Gd2 3 3.136(3)
Al3 Gd1 1_554 3.220(2)
Al4 Ni4 1_554 2.5414(18)
Al4 Al2 1_554 2.596(3)
Al4 Al4 11_565 2.666(5)
Al4 Al4 9_665 2.666(5)
Al4 Gd1 1_554 3.373(2)
Al4 Gd1 11_566 3.378(2)
Al4 Gd1 11_565 3.378(2)
Al5 Ni5 1_556 2.535(2)
Al5 Ni1 11_556 2.541(2)
Al5 Ni1 3 2.541(2)
Al5 Al5 7 2.648(7)
Al5 Al5 3 2.648(7)
Al5 Gd2 1_556 2.931(3)
Al5 Al10 3_545 2.996(2)
Al5 Al10 7_666 2.996(2)
Al5 Al10 3_546 2.996(2)
Al5 Al10 7_665 2.996(2)
Al6 Ni2 11 2.4467(9)
Al6 Ni2 3_556 2.4467(9)
Al6 Ni2 3 2.4467(9)
Al6 Ni2 11_556 2.4467(9)
Al6 Al9 . 2.665(4)
Al6 Al9 1_556 2.665(4)
Al6 Al2 11_556 2.685(3)
Al6 Al2 3 2.685(3)
Al6 Gd1 7_655 3.190(2)
Al6 Gd1 9_655 3.190(2)
Al7 Ni1 9_655 2.409(4)
Al7 Ni1 7_655 2.410(4)
Al7 Al9 1_556 2.660(4)
Al7 Al9 . 2.660(4)
Al7 Al3 7_656 2.847(2)
Al7 Al3 9_655 2.847(2)
Al7 Al3 9_656 2.847(2)
Al7 Al3 7_655 2.847(2)
Al7 Gd1 9_655 3.250(3)
Al7 Gd1 7_655 3.250(3)
Al8 Ni3 11 2.4078(15)
Al8 Ni3 3 2.4078(15)
Al8 Ni2 3 2.473(4)
Al8 Ni2 11 2.473(4)
Al8 Al1 11 2.986(3)
Al8 Al1 3 2.986(3)
Al8 Al1 3_554 2.986(3)
Al8 Al1 11_556 2.986(3)
Al9 Ni2 11 2.482(5)
Al9 Ni2 3 2.482(5)
Al9 Al7 1_554 2.660(4)
Al9 Al6 1_554 2.665(4)
Al9 Gd1 9_654 3.3850(7)
Al9 Gd1 7_655 3.3850(7)
Al9 Gd1 9_655 3.3850(7)
Al9 Gd1 7_654 3.3850(7)
Al10 Ni5 1_655 2.534(4)
Al10 Ni1 7_655 2.5588(14)
Al10 Ni1 7_654 2.5588(14)
Al10 Ni1 9_654 2.5588(14)
Al10 Ni1 9_655 2.5588(14)
Al10 Al3 9_655 2.895(4)
Al10 Al3 7_655 2.895(4)
Al10 Al5 3_655 2.996(2)
Al10 Al5 7_654 2.996(2)
Al10 Al5 7_655 2.996(2)
Al10 Al5 3_654 2.996(2)
Al10 Gd2 3_655 3.2396(13)

_cod_database_fobs_code 2020274
