#------------------------------------------------------------------------------
#$Date: 2016-02-20 02:53:41 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/55/2105503.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2105503
loop_
_publ_author_name
'Ebihara, Masahiro'
'Fuma, Yasuhiro'
_publ_section_title
;
 Two- and three-dimensional assembled structures constructed from
 amidate-bridged paddlewheel complexes with group 6 oxometallate ions
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              480
_journal_page_last               489
_journal_paper_doi               10.1107/S2052519213024068
_journal_volume                  69
_journal_year                    2013
_chemical_formula_moiety         'C24 H48 Cr N8 O12 Rh4, 1.08(H2 O)'
_chemical_formula_sum            'C24 H50.16 Cr N8 O13.08 Rh4'
_chemical_formula_weight         1123.76
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.405(5)
_cell_angle_beta                 101.362(4)
_cell_angle_gamma                106.816(5)
_cell_formula_units_Z            2
_cell_length_a                   12.978(2)
_cell_length_b                   13.576(3)
_cell_length_c                   14.498(3)
_cell_measurement_reflns_used    4246
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     2119.9(7)
_computing_cell_refinement       CrystalClear
_computing_data_collection
'CrystalClear (Molecular Structure Corporation & Rigaku Corporation, 2001)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 14.62
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0645
_diffrn_reflns_av_sigmaI/netI    0.1209
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17505
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.10
_exptl_absorpt_coefficient_mu    1.833
_exptl_absorpt_correction_T_max  0.945
_exptl_absorpt_correction_T_min  0.843
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   '(Higashi, 1999)'
_exptl_crystal_colour            Brown
_exptl_crystal_density_diffrn    1.758
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1116
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.877
_refine_diff_density_min         -0.933
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.173
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     588
_refine_ls_number_reflns         9650
_refine_ls_number_restraints     394
_refine_ls_restrained_S_all      1.152
_refine_ls_R_factor_all          0.1407
_refine_ls_R_factor_gt           0.0886
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+19.3981P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1190
_refine_ls_wR_factor_ref         0.1330
_reflns_number_gt                6828
_reflns_number_total             9650
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ry5054.cif
_cod_data_source_block           VII
_cod_original_cell_volume        2120.1(8)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_database_code               2105503
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh1 0.90911(6) 0.43100(6) 0.48748(6) 0.01574(17) Uani d . 1 1 . .
Rh Rh2 0.53889(6) 0.44323(6) 0.44196(6) 0.01450(17) Uani d . 1 1 . .
Rh Rh3 0.50903(6) 0.05012(6) 0.44729(6) 0.01919(18) Uani d . 1 1 . .
Rh Rh4 0.56458(6) 0.05915(7) 0.09075(6) 0.0230(2) Uani d . 1 1 . .
N N1 0.9308(6) 0.3172(7) 0.3670(7) 0.032(2) Uani d . 1 1 A .
H H1 0.8808 0.2464 0.3337 0.039 Uiso calc R 1 1 . .
O O1 1.1015(5) 0.4457(6) 0.3861(5) 0.0312(18) Uani d . 1 1 . .
N N2 0.8427(6) 0.4852(7) 0.3932(7) 0.029(2) Uani d . 1 1 B .
H H2 0.7691 0.4565 0.3662 0.035 Uiso calc R 1 1 . .
O O2 1.0107(5) 0.6132(7) 0.4103(6) 0.042(2) Uani d . 1 1 . .
N N3 0.6313(6) 0.4490(6) 0.5726(6) 0.0205(18) Uani d . 1 1 . .
H H3 0.6772 0.4141 0.5667 0.025 Uiso calc R 1 1 . .
O O3 0.5550(5) 0.5493(5) 0.6828(5) 0.0210(15) Uani d . 1 1 . .
N N4 0.4072(6) 0.3062(6) 0.4161(6) 0.0216(18) Uani d . 1 1 . .
H H4 0.4027 0.2386 0.3748 0.026 Uiso calc R 1 1 . .
O O4 0.3329(5) 0.4074(5) 0.5260(5) 0.0210(15) Uani d . 1 1 . .
N N5 0.4804(6) 0.1701(6) 0.5566(6) 0.0226(18) Uani d . 1 1 . .
H H5 0.4798 0.2297 0.5489 0.027 Uiso calc R 1 1 . .
O O5 0.4655(5) 0.0813(6) 0.6600(5) 0.0251(16) Uani d . 1 1 . .
N N6 0.6741(6) 0.1250(6) 0.5316(6) 0.0183(17) Uani d . 1 1 . .
H H6 0.7182 0.1721 0.5158 0.022 Uiso calc R 1 1 . .
O O6 0.6629(5) 0.0369(6) 0.6365(5) 0.0258(16) Uani d . 1 1 . .
N N7 0.4821(7) 0.1631(7) 0.1004(6) 0.032(2) Uani d . 1 1 F .
H H7 0.5047 0.2251 0.1597 0.038 Uiso calc R 1 1 . .
O O7 0.3547(6) 0.0515(6) -0.0683(5) 0.0345(19) Uani d . 1 1 . .
N N8 0.4510(7) -0.0406(7) 0.1252(7) 0.037(2) Uani d . 1 1 G .
H H8 0.4666 -0.0282 0.1901 0.045 Uiso calc R 1 1 . .
O O8 0.3234(6) -0.1515(6) -0.0456(5) 0.036(2) Uani d . 1 1 . .
Cr Cr1 0.63841(11) 0.23545(12) 0.35111(11) 0.0143(3) Uani d . 1 1 . .
O O9 0.7442(5) 0.3007(5) 0.4669(5) 0.0165(14) Uani d . 1 1 . .
O O10 0.6020(5) 0.3353(5) 0.3297(4) 0.0155(13) Uani d . 1 1 . .
O O11 0.5248(5) 0.1421(5) 0.3528(5) 0.0186(14) Uani d . 1 1 . .
O O12 0.6823(5) 0.1681(5) 0.2567(5) 0.0207(15) Uani d . 1 1 . .
O O13 0.7441(12) -0.0304(13) 0.2723(13) 0.056(7) Uani d P 0.55(2) 1 . .
O O14 0.9443(17) 0.1153(18) 0.4449(18) 0.094(11) Uani d P 0.53(3) 1 . .
C C1 1.0184(8) 0.3451(9) 0.3358(8) 0.035(3) Uani d DU 1 1 . .
C C2A 1.024(2) 0.273(2) 0.2267(17) 0.027(7) Uani d PDU 0.51(6) 1 A 1
H H9A 1.0128 0.3105 0.1830 0.032 Uiso calc PR 0.51(6) 1 A 1
H H10A 1.1004 0.2735 0.2374 0.032 Uiso calc PR 0.51(6) 1 A 1
C C3A 0.939(2) 0.150(2) 0.167(2) 0.032(6) Uani d PDU 0.51(6) 1 A 1
H H11A 0.9405 0.1142 0.2129 0.047 Uiso calc PR 0.51(6) 1 A 1
H H12A 0.9591 0.1081 0.1076 0.047 Uiso calc PR 0.51(6) 1 A 1
H H13A 0.8640 0.1469 0.1414 0.047 Uiso calc PR 0.51(6) 1 A 1
C C2B 1.031(2) 0.247(2) 0.247(2) 0.026(7) Uani d PDU 0.49(6) 1 A 2
H H9B 1.0257 0.2624 0.1872 0.031 Uiso calc PR 0.49(6) 1 A 2
H H10 1.1086 0.2517 0.2730 0.031 Uiso calc PR 0.49(6) 1 A 2
C C3B 0.951(3) 0.124(2) 0.207(3) 0.052(10) Uani d PDU 0.49(6) 1 A 2
H H11B 0.9707 0.0974 0.2579 0.079 Uiso calc PR 0.49(6) 1 A 2
H H12B 0.9559 0.0752 0.1408 0.079 Uiso calc PR 0.49(6) 1 A 2
H H13B 0.8737 0.1189 0.1953 0.079 Uiso calc PR 0.49(6) 1 A 2
C C4 0.8988(9) 0.5597(11) 0.3677(10) 0.048(3) Uani d DU 1 1 . .
C C5A 0.8450(15) 0.579(2) 0.2769(16) 0.069(7) Uani d PDU 0.820(19) 1 B 1
H H14A 0.8610 0.6608 0.3042 0.083 Uiso calc PR 0.820(19) 1 B 1
H H15A 0.8824 0.5590 0.2249 0.083 Uiso calc PR 0.820(19) 1 B 1
C C6A 0.7181(11) 0.5109(16) 0.2210(14) 0.070(6) Uani d PDU 0.820(19) 1 B 1
H H16A 0.7009 0.4292 0.1911 0.105 Uiso calc PR 0.820(19) 1 B 1
H H17A 0.6926 0.5293 0.1653 0.105 Uiso calc PR 0.820(19) 1 B 1
H H18A 0.6794 0.5309 0.2709 0.105 Uiso calc PR 0.820(19) 1 B 1
C C5B 0.838(8) 0.619(7) 0.322(5) 0.042(11) Uani d PDU 0.180(19) 1 B 2
H H14B 0.7603 0.6007 0.3238 0.051 Uiso calc PR 0.180(19) 1 B 2
H H15B 0.8802 0.7031 0.3575 0.051 Uiso calc PR 0.180(19) 1 B 2
C C6B 0.840(6) 0.562(6) 0.212(5) 0.048(13) Uani d PDU 0.180(19) 1 B 2
H H16B 0.8394 0.6119 0.1796 0.072 Uiso calc PR 0.180(19) 1 B 2
H H17B 0.7739 0.4895 0.1697 0.072 Uiso calc PR 0.180(19) 1 B 2
H H18B 0.9084 0.5470 0.2148 0.072 Uiso calc PR 0.180(19) 1 B 2
C C7 0.6260(8) 0.5024(8) 0.6660(7) 0.020(2) Uani d . 1 1 . .
C C8 0.7040(8) 0.5119(9) 0.7649(7) 0.026(2) Uani d . 1 1 . .
H H19 0.6586 0.4979 0.8079 0.032 Uiso calc R 1 1 . .
H H20 0.7618 0.5910 0.8062 0.032 Uiso calc R 1 1 . .
C C9 0.7651(9) 0.4285(10) 0.7446(8) 0.033(3) Uani d . 1 1 . .
H H21 0.7090 0.3496 0.7050 0.050 Uiso calc R 1 1 . .
H H22 0.8114 0.4401 0.8114 0.050 Uiso calc R 1 1 . .
H H23 0.8132 0.4435 0.7048 0.050 Uiso calc R 1 1 . .
C C10 0.3270(7) 0.3103(8) 0.4566(8) 0.022(2) Uani d U 1 1 C .
C C11 0.2268(8) 0.2021(9) 0.4277(9) 0.045(3) Uani d DU 1 1 . .
H H24A 0.2535 0.1408 0.4207 0.054 Uiso calc PR 0.513(18) 1 C 1
H H25A 0.1728 0.1782 0.3587 0.054 Uiso calc PR 0.513(18) 1 C 1
H H24B 0.1642 0.2231 0.4423 0.054 Uiso calc PR 0.487(18) 1 C 2
H H25B 0.2482 0.1689 0.4731 0.054 Uiso calc PR 0.487(18) 1 C 2
C C12A 0.1629(16) 0.2140(17) 0.5080(16) 0.037(6) Uani d PDU 0.513(18) 1 C 1
H H26A 0.2177 0.2574 0.5791 0.055 Uiso calc PR 0.513(18) 1 C 1
H H27A 0.1165 0.1380 0.4963 0.055 Uiso calc PR 0.513(18) 1 C 1
H H28A 0.1147 0.2539 0.4986 0.055 Uiso calc PR 0.513(18) 1 C 1
C C12B 0.1832(16) 0.1083(16) 0.3108(16) 0.037(6) Uani d PDU 0.487(18) 1 C 2
H H26B 0.1822 0.1444 0.2654 0.056 Uiso calc PR 0.487(18) 1 C 2
H H27B 0.1070 0.0538 0.2929 0.056 Uiso calc PR 0.487(18) 1 C 2
H H28B 0.2333 0.0681 0.3013 0.056 Uiso calc PR 0.487(18) 1 C 2
C C13 0.4623(8) 0.1632(8) 0.6399(8) 0.023(2) Uani d U 1 1 D .
C C14 0.4364(10) 0.2569(10) 0.7208(9) 0.040(3) Uani d DU 1 1 . .
H H29A 0.4485 0.3209 0.7038 0.048 Uiso calc PR 0.611(19) 1 D 1
H H30A 0.3559 0.2241 0.7119 0.048 Uiso calc PR 0.611(19) 1 D 1
H H29B 0.4978 0.2993 0.7894 0.048 Uiso calc PR 0.389(19) 1 D 2
H H30B 0.4260 0.3114 0.6958 0.048 Uiso calc PR 0.389(19) 1 D 2
C C15A 0.508(2) 0.306(2) 0.8378(15) 0.070(8) Uani d PDU 0.611(19) 1 D 1
H H31A 0.4934 0.3709 0.8806 0.105 Uiso calc PR 0.611(19) 1 D 1
H H32A 0.5876 0.3304 0.8466 0.105 Uiso calc PR 0.611(19) 1 D 1
H H33A 0.4862 0.2465 0.8595 0.105 Uiso calc PR 0.611(19) 1 D 1
C C15B 0.324(2) 0.186(2) 0.728(3) 0.047(8) Uani d PDU 0.389(19) 1 D 2
H H31B 0.2613 0.1615 0.6653 0.070 Uiso calc PR 0.389(19) 1 D 2
H H32B 0.3122 0.2340 0.7896 0.070 Uiso calc PR 0.389(19) 1 D 2
H H33B 0.3300 0.1194 0.7328 0.070 Uiso calc PR 0.389(19) 1 D 2
C C16 0.7218(7) 0.1087(8) 0.6096(7) 0.019(2) Uani d U 1 1 E .
C C17 0.8469(8) 0.1746(10) 0.6714(8) 0.033(3) Uani d DU 1 1 . .
H H34A 0.8654 0.1683 0.7365 0.040 Uiso calc PR 0.57(2) 1 E 1
H H35A 0.8693 0.2562 0.6898 0.040 Uiso calc PR 0.57(2) 1 E 1
H H34B 0.8555 0.2364 0.7384 0.040 Uiso calc PR 0.43(2) 1 E 2
H H35B 0.8807 0.2116 0.6328 0.040 Uiso calc PR 0.43(2) 1 E 2
C C18A 0.9106(16) 0.1202(19) 0.599(2) 0.060(8) Uani d PDU 0.57(2) 1 E 1
H H36A 0.9883 0.1434 0.6420 0.091 Uiso calc PR 0.57(2) 1 E 1
H H37A 0.9106 0.1467 0.5466 0.091 Uiso calc PR 0.57(2) 1 E 1
H H38A 0.8722 0.0369 0.5645 0.091 Uiso calc PR 0.57(2) 1 E 1
C C18B 0.9183(19) 0.111(2) 0.697(2) 0.050(10) Uani d PDU 0.43(2) 1 E 2
H H36B 0.8860 0.0723 0.7340 0.076 Uiso calc PR 0.43(2) 1 E 2
H H37B 0.9956 0.1664 0.7409 0.076 Uiso calc PR 0.43(2) 1 E 2
H H38B 0.9186 0.0552 0.6320 0.076 Uiso calc PR 0.43(2) 1 E 2
C C19 0.3968(9) 0.1434(9) 0.0235(9) 0.038(3) Uani d DU 1 1 . .
C C20A 0.350(3) 0.234(3) 0.033(5) 0.055(11) Uani d PDU 0.52(6) 1 F 1
H H39A 0.3776 0.2918 0.1067 0.066 Uiso calc PR 0.52(6) 1 F 1
H H40A 0.3784 0.2729 -0.0067 0.066 Uiso calc PR 0.52(6) 1 F 1
C C21A 0.221(3) 0.186(4) -0.008(5) 0.10(2) Uani d PDU 0.52(6) 1 F 1
H H41A 0.1907 0.1041 -0.0311 0.149 Uiso calc PR 0.52(6) 1 F 1
H H42A 0.1955 0.1998 -0.0674 0.149 Uiso calc PR 0.52(6) 1 F 1
H H43A 0.1949 0.2240 0.0471 0.149 Uiso calc PR 0.52(6) 1 F 1
C C20B 0.326(3) 0.214(3) 0.044(5) 0.042(8) Uani d PDU 0.48(6) 1 F 2
H H39B 0.3734 0.2897 0.1057 0.051 Uiso calc PR 0.48(6) 1 F 2
H H40B 0.3035 0.2276 -0.0165 0.051 Uiso calc PR 0.48(6) 1 F 2
C C21B 0.222(4) 0.157(3) 0.063(6) 0.099(19) Uani d PDU 0.48(6) 1 F 2
H H41B 0.1731 0.0845 0.0014 0.149 Uiso calc PR 0.48(6) 1 F 2
H H42B 0.1810 0.2069 0.0781 0.149 Uiso calc PR 0.48(6) 1 F 2
H H43B 0.2440 0.1435 0.1230 0.149 Uiso calc PR 0.48(6) 1 F 2
C C22 0.3524(9) -0.1252(9) 0.0542(8) 0.036(3) Uani d DU 1 1 . .
C C23A 0.257(3) -0.174(3) 0.092(3) 0.047(10) Uani d PDU 0.40(2) 1 G 1
H H44A 0.2039 -0.1359 0.0912 0.056 Uiso calc PR 0.40(2) 1 G 1
H H45A 0.2885 -0.1625 0.1632 0.056 Uiso calc PR 0.40(2) 1 G 1
C C23B 0.286(3) -0.211(5) 0.087(5) 0.046(9) Uani d PDU 0.37(3) 1 G 2
H H44B 0.3052 -0.1748 0.1636 0.056 Uiso calc PR 0.37(3) 1 G 2
H H45B 0.3055 -0.2785 0.0656 0.056 Uiso calc PR 0.37(3) 1 G 2
C C23C 0.265(6) -0.197(10) 0.085(11) 0.042(10) Uani d PDU 0.23(3) 1 G 3
H H44C 0.2983 -0.1816 0.1575 0.050 Uiso calc PR 0.23(3) 1 G 3
H H45C 0.2389 -0.2792 0.0380 0.050 Uiso calc PR 0.23(3) 1 G 3
C C24A 0.195(3) -0.308(2) 0.008(2) 0.044(7) Uani d PDU 0.40(2) 1 G 1
H H46A 0.2488 -0.3439 0.0107 0.065 Uiso calc PR 0.40(2) 1 G 1
H H47A 0.1662 -0.3172 -0.0618 0.065 Uiso calc PR 0.40(2) 1 G 1
H H48A 0.1323 -0.3452 0.0261 0.065 Uiso calc PR 0.40(2) 1 G 1
C C24B 0.153(3) -0.249(4) 0.029(3) 0.066(11) Uani d PDU 0.37(3) 1 G 2
H H46B 0.1421 -0.1847 0.0215 0.098 Uiso calc PR 0.37(3) 1 G 2
H H47B 0.1103 -0.2703 0.0696 0.098 Uiso calc PR 0.37(3) 1 G 2
H H48B 0.1277 -0.3138 -0.0408 0.098 Uiso calc PR 0.37(3) 1 G 2
C C24C 0.160(4) -0.158(6) 0.074(5) 0.058(13) Uani d PDU 0.23(3) 1 G 3
H H46C 0.1884 -0.0748 0.1160 0.087 Uiso calc PR 0.23(3) 1 G 3
H H47C 0.1055 -0.1955 0.0983 0.087 Uiso calc PR 0.23(3) 1 G 3
H H48C 0.1242 -0.1790 0.0006 0.087 Uiso calc PR 0.23(3) 1 G 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N2 Rh1 N1 . . 89.6(4) ?
N2 Rh1 O2 . 2_766 175.4(3) ?
N1 Rh1 O2 . 2_766 91.5(4) ?
N2 Rh1 O1 . 2_766 91.1(3) ?
N1 Rh1 O1 . 2_766 176.1(3) ?
O2 Rh1 O1 2_766 2_766 87.5(3) ?
N2 Rh1 O9 . . 96.6(3) ?
N1 Rh1 O9 . . 93.0(3) ?
O2 Rh1 O9 2_766 . 87.8(2) ?
O1 Rh1 O9 2_766 . 90.8(2) ?
N2 Rh1 Rh1 . 2_766 85.3(2) ?
N1 Rh1 Rh1 . 2_766 86.5(2) ?
O2 Rh1 Rh1 2_766 2_766 90.29(18) ?
O1 Rh1 Rh1 2_766 2_766 89.67(18) ?
O9 Rh1 Rh1 . 2_766 178.04(17) y
N4 Rh2 N3 . . 92.0(3) ?
N4 Rh2 O3 . 2_666 90.0(3) ?
N3 Rh2 O3 . 2_666 175.1(3) ?
N4 Rh2 O4 . 2_666 175.1(3) ?
N3 Rh2 O4 . 2_666 88.8(3) ?
O3 Rh2 O4 2_666 2_666 88.8(3) ?
N4 Rh2 O10 . . 92.6(3) ?
N3 Rh2 O10 . . 97.0(3) ?
O3 Rh2 O10 2_666 . 87.3(2) ?
O4 Rh2 O10 2_666 . 92.1(2) ?
N4 Rh2 Rh2 . 2_666 85.8(2) ?
N3 Rh2 Rh2 . 2_666 85.2(2) ?
O3 Rh2 Rh2 2_666 2_666 90.50(18) ?
O4 Rh2 Rh2 2_666 2_666 89.47(18) ?
O10 Rh2 Rh2 . 2_666 177.28(15) y
N6 Rh3 N5 . . 90.8(3) ?
N6 Rh3 O5 . 2_656 89.8(3) ?
N5 Rh3 O5 . 2_656 175.6(3) ?
N6 Rh3 O6 . 2_656 175.7(3) ?
N5 Rh3 O6 . 2_656 90.3(3) ?
O5 Rh3 O6 2_656 2_656 88.7(3) ?
N6 Rh3 O11 . . 94.3(3) ?
N5 Rh3 O11 . . 93.3(3) ?
O5 Rh3 O11 2_656 . 91.0(2) ?
O6 Rh3 O11 2_656 . 89.8(2) ?
N6 Rh3 Rh3 . 2_656 85.8(2) ?
N5 Rh3 Rh3 . 2_656 86.2(2) ?
O5 Rh3 Rh3 2_656 2_656 89.51(19) ?
O6 Rh3 Rh3 2_656 2_656 90.12(19) ?
O11 Rh3 Rh3 . 2_656 179.44(18) y
N8 Rh4 N7 . . 91.9(4) ?
N8 Rh4 O8 . 2_655 176.1(3) ?
N7 Rh4 O8 . 2_655 89.7(3) ?
N8 Rh4 O7 . 2_655 89.8(4) ?
N7 Rh4 O7 . 2_655 175.5(3) ?
O8 Rh4 O7 2_655 2_655 88.4(3) ?
N8 Rh4 O12 . . 94.1(3) ?
N7 Rh4 O12 . . 93.7(3) ?
O8 Rh4 O12 2_655 . 89.4(2) ?
O7 Rh4 O12 2_655 . 90.4(2) ?
N8 Rh4 Rh4 . 2_655 85.9(2) ?
N7 Rh4 Rh4 . 2_655 85.9(2) ?
O8 Rh4 Rh4 2_655 2_655 90.58(19) ?
O7 Rh4 Rh4 2_655 2_655 89.97(18) ?
O12 Rh4 Rh4 . 2_655 179.67(18) y
C1 N1 Rh1 . . 122.7(6) ?
C1 N1 H1 . . 118.6 ?
Rh1 N1 H1 . . 118.6 ?
C1 O1 Rh1 . 2_766 118.1(6) ?
C4 N2 Rh1 . . 126.2(7) ?
C4 N2 H2 . . 116.9 ?
Rh1 N2 H2 . . 116.9 ?
C4 O2 Rh1 . 2_766 117.2(7) ?
C7 N3 Rh2 . . 123.6(6) ?
C7 N3 H3 . . 118.2 ?
Rh2 N3 H3 . . 118.2 ?
C7 O3 Rh2 . 2_666 116.6(6) ?
C10 N4 Rh2 . . 124.9(6) ?
C10 N4 H4 . . 117.5 ?
Rh2 N4 H4 . . 117.5 ?
C10 O4 Rh2 . 2_666 118.4(6) ?
C13 N5 Rh3 . . 123.2(7) ?
C13 N5 H5 . . 118.4 ?
Rh3 N5 H5 . . 118.4 ?
C13 O5 Rh3 . 2_656 118.0(6) ?
C16 N6 Rh3 . . 125.0(6) ?
C16 N6 H6 . . 117.5 ?
Rh3 N6 H6 . . 117.5 ?
C16 O6 Rh3 . 2_656 117.3(6) ?
C19 N7 Rh4 . . 124.0(7) ?
C19 N7 H7 . . 118.0 ?
Rh4 N7 H7 . . 118.0 ?
C19 O7 Rh4 . 2_655 117.1(7) ?
C22 N8 Rh4 . . 123.7(8) ?
C22 N8 H8 . . 118.1 ?
Rh4 N8 H8 . . 118.1 ?
C22 O8 Rh4 . 2_655 117.6(6) ?
O9 Cr1 O10 . . 109.2(3) y
O11 Cr1 O9 . . 110.1(3) y
O12 Cr1 O9 . . 108.9(3) y
O11 Cr1 O10 . . 108.4(3) y
O12 Cr1 O10 . . 109.8(3) y
O12 Cr1 O11 . . 110.4(3) y
Cr1 O9 Rh1 . . 118.1(3) y
Cr1 O10 Rh2 . . 119.7(3) y
Cr1 O11 Rh3 . . 131.4(3) y
Cr1 O12 Rh4 . . 121.1(3) y
O1 C1 N1 . . 122.8(9) ?
O1 C1 C2B . . 118.5(13) ?
N1 C1 C2B . . 117.8(14) ?
O1 C1 C2A . . 111.4(13) ?
N1 C1 C2A . . 124.9(12) ?
C3A C2A C1 . . 115.9(18) ?
C3A C2A H9A . . 108.3 ?
C1 C2A H9A . . 108.3 ?
C3A C2A H10A . . 108.3 ?
C1 C2A H10A . . 108.3 ?
H9A C2A H10A . . 107.4 ?
C2A C3A H11A . . 109.5 ?
C2A C3A H12A . . 109.5 ?
H11A C3A H12A . . 109.5 ?
C2A C3A H13A . . 109.5 ?
H11A C3A H13A . . 109.5 ?
H12A C3A H13A . . 109.5 ?
C3B C2B C1 . . 119(2) ?
C3B C2B H9B . . 107.5 ?
C1 C2B H9B . . 107.5 ?
C3B C2B H10 . . 107.5 ?
C1 C2B H10 . . 107.5 ?
H9B C2B H10 . . 107.0 ?
C2B C3B H11B . . 109.5 ?
C2B C3B H12B . . 109.5 ?
H11B C3B H12B . . 109.5 ?
C2B C3B H13B . . 109.5 ?
H11B C3B H13B . . 109.5 ?
H12B C3B H13B . . 109.5 ?
N2 C4 O2 . . 121.0(10) ?
N2 C4 C5A . . 123.4(11) ?
O2 C4 C5A . . 115.0(12) ?
N2 C4 C5B . . 119(4) ?
O2 C4 C5B . . 116(4) ?
C6A C5A C4 . . 116.1(14) ?
C6A C5A H14A . . 108.3 ?
C4 C5A H14A . . 108.3 ?
C6A C5A H15A . . 108.3 ?
C4 C5A H15A . . 108.3 ?
H14A C5A H15A . . 107.4 ?
C5A C6A H16A . . 109.5 ?
C5A C6A H17A . . 109.5 ?
H16A C6A H17A . . 109.5 ?
C5A C6A H18A . . 109.5 ?
H16A C6A H18A . . 109.5 ?
H17A C6A H18A . . 109.5 ?
C6B C5B C4 . . 97(4) ?
C6B C5B H14B . . 112.4 ?
C4 C5B H14B . . 112.4 ?
C6B C5B H15B . . 112.4 ?
C4 C5B H15B . . 112.4 ?
H14B C5B H15B . . 110.0 ?
C5B C6B H16B . . 109.5 ?
C5B C6B H17B . . 109.5 ?
H16B C6B H17B . . 109.5 ?
C5B C6B H18B . . 109.5 ?
H16B C6B H18B . . 109.5 ?
H17B C6B H18B . . 109.5 ?
O3 C7 N3 . . 123.6(8) ?
O3 C7 C8 . . 114.4(8) ?
N3 C7 C8 . . 122.0(9) ?
C7 C8 C9 . . 115.5(8) ?
C7 C8 H19 . . 108.4 ?
C9 C8 H19 . . 108.4 ?
C7 C8 H20 . . 108.4 ?
C9 C8 H20 . . 108.4 ?
H19 C8 H20 . . 107.5 ?
C8 C9 H21 . . 109.5 ?
C8 C9 H22 . . 109.5 ?
H21 C9 H22 . . 109.5 ?
C8 C9 H23 . . 109.5 ?
H21 C9 H23 . . 109.5 ?
H22 C9 H23 . . 109.5 ?
O4 C10 N4 . . 121.1(8) ?
O4 C10 C11 . . 117.6(8) ?
N4 C10 C11 . . 121.2(9) ?
C10 C11 C12B . . 114.8(11) ?
C10 C11 C12A . . 114.8(10) ?
C12B C11 C12A . . 128.0(12) ?
C10 C11 H24A . . 108.6 ?
C12A C11 H24A . . 108.6 ?
C10 C11 H25A . . 108.6 ?
C12A C11 H25A . . 108.6 ?
H24A C11 H25A . . 107.5 ?
C10 C11 H24B . . 108.6 ?
C12B C11 H24B . . 108.6 ?
C10 C11 H25B . . 108.6 ?
C12B C11 H25B . . 108.6 ?
H24B C11 H25B . . 107.6 ?
C11 C12A H26A . . 109.5 ?
C11 C12A H27A . . 109.5 ?
H26A C12A H27A . . 109.5 ?
C11 C12A H28A . . 109.5 ?
H26A C12A H28A . . 109.5 ?
H27A C12A H28A . . 109.5 ?
C11 C12B H26B . . 109.5 ?
C11 C12B H27B . . 109.5 ?
H26B C12B H27B . . 109.5 ?
C11 C12B H28B . . 109.5 ?
H26B C12B H28B . . 109.5 ?
H27B C12B H28B . . 109.5 ?
O5 C13 N5 . . 123.0(9) ?
O5 C13 C14 . . 115.8(9) ?
N5 C13 C14 . . 121.2(9) ?
C15A C14 C13 . . 115.9(12) ?
C15B C14 C13 . . 103.5(13) ?
C15A C14 H29A . . 108.3 ?
C13 C14 H29A . . 108.3 ?
C15A C14 H30A . . 108.3 ?
C13 C14 H30A . . 108.3 ?
H29A C14 H30A . . 107.4 ?
C15B C14 H29B . . 111.1 ?
C13 C14 H29B . . 111.1 ?
C15B C14 H30B . . 111.1 ?
C13 C14 H30B . . 111.1 ?
H30A C14 H30B . . 92.3 ?
H29B C14 H30B . . 109.0 ?
C14 C15A H31A . . 109.5 ?
C14 C15A H32A . . 109.5 ?
H31A C15A H32A . . 109.5 ?
C14 C15A H33A . . 109.5 ?
H31A C15A H33A . . 109.5 ?
H32A C15A H33A . . 109.5 ?
C14 C15B H31B . . 109.5 ?
C14 C15B H32B . . 109.5 ?
H31B C15B H32B . . 109.5 ?
C14 C15B H33B . . 109.5 ?
H31B C15B H33B . . 109.5 ?
H32B C15B H33B . . 109.5 ?
O6 C16 N6 . . 121.7(8) ?
O6 C16 C17 . . 117.9(8) ?
N6 C16 C17 . . 120.4(8) ?
C16 C17 C18B . . 119.7(12) ?
C16 C17 C18A . . 106.9(11) ?
C16 C17 H34A . . 110.3 ?
C18A C17 H34A . . 110.3 ?
C16 C17 H35A . . 110.3 ?
C18A C17 H35A . . 110.3 ?
H34A C17 H35A . . 108.6 ?
C16 C17 H34B . . 107.4 ?
C18B C17 H34B . . 107.4 ?
C16 C17 H35B . . 107.4 ?
C18B C17 H35B . . 107.4 ?
H34B C17 H35B . . 106.9 ?
C17 C18A H36A . . 109.5 ?
C17 C18A H37A . . 109.5 ?
H36A C18A H37A . . 109.5 ?
C17 C18A H38A . . 109.5 ?
H36A C18A H38A . . 109.5 ?
H37A C18A H38A . . 109.5 ?
C17 C18B H36B . . 109.5 ?
C17 C18B H37B . . 109.5 ?
H36B C18B H37B . . 109.5 ?
C17 C18B H38B . . 109.5 ?
H36B C18B H38B . . 109.5 ?
H37B C18B H38B . . 109.5 ?
N7 C19 O7 . . 122.8(10) ?
N7 C19 C20B . . 120(2) ?
O7 C19 C20B . . 116(2) ?
N7 C19 C20A . . 121(2) ?
O7 C19 C20A . . 116(2) ?
C21A C20A C19 . . 114(2) ?
C21A C20A H39A . . 108.8 ?
C19 C20A H39A . . 108.8 ?
C21A C20A H40A . . 108.8 ?
C19 C20A H40A . . 108.8 ?
H39A C20A H40A . . 107.7 ?
C20A C21A H41A . . 109.5 ?
C20A C21A H42A . . 109.5 ?
H41A C21A H42A . . 109.5 ?
C20A C21A H43A . . 109.5 ?
H41A C21A H43A . . 109.5 ?
H42A C21A H43A . . 109.5 ?
C21B C20B C19 . . 113(3) ?
C21B C20B H39B . . 109.1 ?
C19 C20B H39B . . 109.1 ?
C21B C20B H40B . . 109.1 ?
C19 C20B H40B . . 109.1 ?
H39B C20B H40B . . 107.8 ?
C20B C21B H41B . . 109.5 ?
C20B C21B H42B . . 109.5 ?
H41B C21B H42B . . 109.5 ?
C20B C21B H43B . . 109.5 ?
H41B C21B H43B . . 109.5 ?
H42B C21B H43B . . 109.5 ?
O8 C22 N8 . . 122.1(10) ?
O8 C22 C23C . . 116(5) ?
N8 C22 C23C . . 122(5) ?
O8 C22 C23B . . 119(3) ?
N8 C22 C23B . . 117(2) ?
O8 C22 C23A . . 117(2) ?
N8 C22 C23A . . 119.4(19) ?
C22 C23A C24A . . 104(2) ?
C22 C23A H44A . . 110.9 ?
C24A C23A H44A . . 110.9 ?
C22 C23A H45A . . 110.9 ?
C24A C23A H45A . . 110.9 ?
H44A C23A H45A . . 108.9 ?
C22 C23B C24B . . 107(3) ?
C22 C23B H44B . . 110.4 ?
C24B C23B H44B . . 110.4 ?
C22 C23B H45B . . 110.4 ?
C24B C23B H45B . . 110.4 ?
H44B C23B H45B . . 108.6 ?
C22 C23C C24C . . 106(4) ?
C22 C23C H44C . . 110.5 ?
C24C C23C H44C . . 110.5 ?
C22 C23C H45C . . 110.5 ?
C24C C23C H45C . . 110.5 ?
H44C C23C H45C . . 108.7 ?
C23A C24A H46A . . 109.5 ?
C23A C24A H47A . . 109.5 ?
H46A C24A H47A . . 109.5 ?
C23A C24A H48A . . 109.5 ?
H46A C24A H48A . . 109.5 ?
H47A C24A H48A . . 109.5 ?
C23B C24B H46B . . 109.5 ?
C23B C24B H47B . . 109.5 ?
H46B C24B H47B . . 109.5 ?
C23B C24B H48B . . 109.5 ?
H46B C24B H48B . . 109.5 ?
H47B C24B H48B . . 109.5 ?
C23C C24C H46C . . 109.5 ?
C23C C24C H47C . . 109.5 ?
H46C C24C H47C . . 109.5 ?
C23C C24C H48C . . 109.5 ?
H46C C24C H48C . . 109.5 ?
H47C C24C H48C . . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Rh1 N1 . 1.976(8) y
Rh1 N2 . 1.956(8) y
Rh1 O1 2_766 2.019(7) y
Rh1 O2 2_766 2.017(7) y
Rh1 O9 . 2.226(5) y
Rh1 Rh1 2_766 2.4071(14) y
Rh2 N3 . 1.992(7) y
Rh2 N4 . 1.975(7) y
Rh2 O3 2_666 2.027(6) y
Rh2 O4 2_666 2.030(6) y
Rh2 O10 . 2.207(6) y
Rh2 Rh2 2_666 2.4122(15) y
Rh3 N5 . 1.980(8) y
Rh3 N6 . 1.969(6) y
Rh3 O5 2_656 2.034(7) y
Rh3 O6 2_656 2.040(6) y
Rh3 O11 . 2.179(6) y
Rh3 Rh3 2_656 2.4053(15) y
Rh4 N7 . 1.985(9) y
Rh4 N8 . 1.977(9) y
Rh4 O7 2_655 2.033(7) y
Rh4 O8 2_655 2.016(7) y
Rh4 O12 . 2.201(6) y
Rh4 Rh4 2_655 2.4076(15) y
N1 C1 . 1.313(12) ?
N1 H1 . 0.8600 ?
O1 C1 . 1.280(11) ?
N2 C4 . 1.286(13) ?
N2 H2 . 0.8600 ?
O2 C4 . 1.309(12) ?
N3 C7 . 1.296(11) ?
N3 H3 . 0.8600 ?
O3 C7 . 1.275(11) ?
N4 C10 . 1.297(11) ?
N4 H4 . 0.8600 ?
O4 C10 . 1.286(11) ?
N5 C13 . 1.306(12) ?
N5 H5 . 0.8600 ?
O5 C13 . 1.262(11) ?
N6 C16 . 1.306(11) ?
N6 H6 . 0.8600 ?
O6 C16 . 1.290(11) ?
N7 C19 . 1.286(13) ?
N7 H7 . 0.8600 ?
O7 C19 . 1.296(11) ?
N8 C22 . 1.322(12) ?
N8 H8 . 0.8600 ?
O8 C22 . 1.294(12) ?
Cr1 O12 . 1.639(6) ?
Cr1 O11 . 1.654(6) ?
Cr1 O9 . 1.656(6) ?
Cr1 O10 . 1.670(6) ?
C1 C2B . 1.540(18) ?
C1 C2A . 1.541(18) ?
C2A C3A . 1.485(19) ?
C2A H9A . 0.9700 ?
C2A H10A . 0.9700 ?
C3A H11A . 0.9600 ?
C3A H12A . 0.9600 ?
C3A H13A . 0.9600 ?
C2B C3B . 1.49(2) ?
C2B H9B . 0.9700 ?
C2B H10 . 0.9700 ?
C3B H11B . 0.9600 ?
C3B H12B . 0.9600 ?
C3B H13B . 0.9600 ?
C4 C5A . 1.511(16) ?
C4 C5B . 1.51(2) ?
C5A C6A . 1.50(2) ?
C5A H14A . 0.9700 ?
C5A H15A . 0.9700 ?
C6A H16A . 0.9600 ?
C6A H17A . 0.9600 ?
C6A H18A . 0.9600 ?
C5B C6B . 1.51(3) ?
C5B H14B . 0.9700 ?
C5B H15B . 0.9700 ?
C6B H16B . 0.9600 ?
C6B H17B . 0.9600 ?
C6B H18B . 0.9600 ?
C7 C8 . 1.521(12) ?
C8 C9 . 1.534(13) ?
C8 H19 . 0.9700 ?
C8 H20 . 0.9700 ?
C9 H21 . 0.9600 ?
C9 H22 . 0.9600 ?
C9 H23 . 0.9600 ?
C10 C11 . 1.495(12) ?
C11 C12B . 1.541(18) ?
C11 C12A . 1.545(18) ?
C11 H24A . 0.9700 ?
C11 H25A . 0.9700 ?
C11 H24B . 0.9700 ?
C11 H25B . 0.9700 ?
C12A H26A . 0.9600 ?
C12A H27A . 0.9600 ?
C12A H28A . 0.9600 ?
C12B H26B . 0.9600 ?
C12B H27B . 0.9600 ?
C12B H28B . 0.9600 ?
C13 C14 . 1.540(14) ?
C14 C15A . 1.530(19) ?
C14 C15B . 1.54(2) ?
C14 H29A . 0.9700 ?
C14 H30A . 0.9700 ?
C14 H29B . 0.9700 ?
C14 H30B . 0.9700 ?
C15A H31A . 0.9600 ?
C15A H32A . 0.9600 ?
C15A H33A . 0.9600 ?
C15B H31B . 0.9600 ?
C15B H32B . 0.9600 ?
C15B H33B . 0.9600 ?
C16 C17 . 1.488(12) ?
C17 C18B . 1.52(2) ?
C17 C18A . 1.56(2) ?
C17 H34A . 0.9700 ?
C17 H35A . 0.9700 ?
C17 H34B . 0.9700 ?
C17 H35B . 0.9700 ?
C18A H36A . 0.9600 ?
C18A H37A . 0.9600 ?
C18A H38A . 0.9600 ?
C18B H36B . 0.9600 ?
C18B H37B . 0.9600 ?
C18B H38B . 0.9600 ?
C19 C20B . 1.50(2) ?
C19 C20A . 1.50(2) ?
C20A C21A . 1.50(3) ?
C20A H39A . 0.9700 ?
C20A H40A . 0.9700 ?
C21A H41A . 0.9600 ?
C21A H42A . 0.9600 ?
C21A H43A . 0.9600 ?
C20B C21B . 1.49(3) ?
C20B H39B . 0.9700 ?
C20B H40B . 0.9700 ?
C21B H41B . 0.9600 ?
C21B H42B . 0.9600 ?
C21B H43B . 0.9600 ?
C22 C23C . 1.53(2) ?
C22 C23B . 1.53(2) ?
C22 C23A . 1.526(19) ?
C23A C24A . 1.59(4) ?
C23A H44A . 0.9700 ?
C23A H45A . 0.9700 ?
C23B C24B . 1.59(4) ?
C23B H44B . 0.9700 ?
C23B H45B . 0.9700 ?
C23C C24C . 1.59(4) ?
C23C H44C . 0.9700 ?
C23C H45C . 0.9700 ?
C24A H46A . 0.9600 ?
C24A H47A . 0.9600 ?
C24A H48A . 0.9600 ?
C24B H46B . 0.9600 ?
C24B H47B . 0.9600 ?
C24B H48B . 0.9600 ?
C24C H46C . 0.9600 ?
C24C H47C . 0.9600 ?
C24C H48C . 0.9600 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N1 H1 O12 . 0.86 2.32 2.963(9) 131.5
N2 H2 O10 . 0.86 2.12 2.917(9) 153.2
N3 H3 O9 . 0.86 2.19 2.965(9) 149.9
N4 H4 O11 . 0.86 2.33 3.015(10) 137.3
N5 H5 N4 . 0.86 2.66 3.404(11) 146.3
N6 H6 O9 . 0.86 2.09 2.860(9) 149.0
N7 H7 O10 . 0.86 2.19 2.978(9) 153.1
N8 H8 O11 . 0.86 2.37 3.016(10) 132.4
N8 H8 O5 2_656 0.86 2.61 3.392(11) 151.3
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
N2 Rh1 N1 C1 . 81.6(9)
O2 Rh1 N1 C1 2_766 -93.9(9)
O9 Rh1 N1 C1 . 178.2(9)
Rh1 Rh1 N1 C1 2_766 -3.7(9)
N1 Rh1 N2 C4 . -83.1(11)
O1 Rh1 N2 C4 2_766 93.0(11)
O9 Rh1 N2 C4 . -176.1(11)
Rh1 Rh1 N2 C4 2_766 3.4(11)
N4 Rh2 N3 C7 . -86.1(8)
O4 Rh2 N3 C7 2_666 89.1(8)
O10 Rh2 N3 C7 . -178.9(7)
Rh2 Rh2 N3 C7 2_666 -0.5(7)
N3 Rh2 N4 C10 . 86.8(8)
O3 Rh2 N4 C10 2_666 -88.7(8)
O10 Rh2 N4 C10 . -176.0(8)
Rh2 Rh2 N4 C10 2_666 1.8(8)
N6 Rh3 N5 C13 . -86.1(7)
O6 Rh3 N5 C13 2_656 89.8(7)
O11 Rh3 N5 C13 . 179.6(7)
Rh3 Rh3 N5 C13 2_656 -0.3(7)
N5 Rh3 N6 C16 . 83.8(8)
O5 Rh3 N6 C16 2_656 -91.9(8)
O11 Rh3 N6 C16 . 177.1(8)
Rh3 Rh3 N6 C16 2_656 -2.4(8)
N8 Rh4 N7 C19 . -84.6(10)
O8 Rh4 N7 C19 2_655 91.8(9)
O12 Rh4 N7 C19 . -178.9(9)
Rh4 Rh4 N7 C19 2_655 1.2(9)
N7 Rh4 N8 C22 . 83.4(10)
O7 Rh4 N8 C22 2_655 -92.4(10)
O12 Rh4 N8 C22 . 177.2(9)
Rh4 Rh4 N8 C22 2_655 -2.4(9)
O12 Cr1 O9 Rh1 . 58.5(4)
O11 Cr1 O9 Rh1 . 179.7(3)
O10 Cr1 O9 Rh1 . -61.3(4)
N2 Rh1 O9 Cr1 . 31.2(4)
N1 Rh1 O9 Cr1 . -58.8(4)
O2 Rh1 O9 Cr1 2_766 -150.2(4)
O1 Rh1 O9 Cr1 2_766 122.4(4)
O12 Cr1 O10 Rh2 . -179.9(3)
O11 Cr1 O10 Rh2 . 59.3(4)
O9 Cr1 O10 Rh2 . -60.6(4)
N4 Rh2 O10 Cr1 . -60.2(4)
N3 Rh2 O10 Cr1 . 32.2(4)
O3 Rh2 O10 Cr1 2_666 -150.1(3)
O4 Rh2 O10 Cr1 2_666 121.2(3)
O12 Cr1 O11 Rh3 . 95.8(5)
O9 Cr1 O11 Rh3 . -24.4(5)
O10 Cr1 O11 Rh3 . -143.8(4)
N6 Rh3 O11 Cr1 . 2.9(5)
N5 Rh3 O11 Cr1 . 94.0(5)
O5 Rh3 O11 Cr1 2_656 -87.0(5)
O6 Rh3 O11 Cr1 2_656 -175.7(5)
O11 Cr1 O12 Rh4 . 54.6(5)
O9 Cr1 O12 Rh4 . 175.6(3)
O10 Cr1 O12 Rh4 . -65.0(4)
N8 Rh4 O12 Cr1 . -55.7(5)
N7 Rh4 O12 Cr1 . 36.4(5)
O8 Rh4 O12 Cr1 2_655 126.1(4)
O7 Rh4 O12 Cr1 2_655 -145.5(4)
Rh1 O1 C1 N1 2_766 -4.5(15)
Rh1 O1 C1 C2B 2_766 -173.2(18)
Rh1 O1 C1 C2A 2_766 165.0(16)
Rh1 N1 C1 O1 . 6.0(16)
Rh1 N1 C1 C2B . 174.7(17)
Rh1 N1 C1 C2A . -162.1(19)
O1 C1 C2A C3A . 173.2(18)
N1 C1 C2A C3A . -18(3)
C2B C1 C2A C3A . 59(4)
O1 C1 C2B C3B . 165(2)
N1 C1 C2B C3B . -5(3)
C2A C1 C2B C3B . -120(6)
Rh1 N2 C4 O2 . -4.3(19)
Rh1 N2 C4 C5A . 166.1(14)
Rh1 N2 C4 C5B . -162(3)
Rh1 O2 C4 N2 2_766 2.3(17)
Rh1 O2 C4 C5A 2_766 -168.9(13)
Rh1 O2 C4 C5B 2_766 160(3)
N2 C4 C5A C6A . 4(3)
O2 C4 C5A C6A . 175.3(16)
C5B C4 C5A C6A . -86(9)
N2 C4 C5B C6B . -111(5)
O2 C4 C5B C6B . 90(5)
C5A C4 C5B C6B . -5(5)
Rh2 O3 C7 N3 2_666 -8.0(12)
Rh2 O3 C7 C8 2_666 173.1(6)
Rh2 N3 C7 O3 . 5.5(13)
Rh2 N3 C7 C8 . -175.6(7)
O3 C7 C8 C9 . 163.2(9)
N3 C7 C8 C9 . -15.7(14)
Rh2 O4 C10 N4 2_666 7.1(12)
Rh2 O4 C10 C11 2_666 -175.2(7)
Rh2 N4 C10 O4 . -6.0(14)
Rh2 N4 C10 C11 . 176.5(8)
O4 C10 C11 C12B . 145.9(12)
N4 C10 C11 C12B . -36.5(16)
O4 C10 C11 C12A . -18.1(16)
N4 C10 C11 C12A . 159.6(12)
Rh3 O5 C13 N5 2_656 -3.6(12)
Rh3 O5 C13 C14 2_656 176.9(6)
Rh3 N5 C13 O5 . 2.6(13)
Rh3 N5 C13 C14 . -177.9(7)
O5 C13 C14 C15A . 48.9(16)
N5 C13 C14 C15A . -130.7(14)
O5 C13 C14 C15B . -53.7(17)
N5 C13 C14 C15B . 126.8(16)
Rh3 O6 C16 N6 2_656 -0.4(12)
Rh3 O6 C16 C17 2_656 178.8(7)
Rh3 N6 C16 O6 . 2.2(13)
Rh3 N6 C16 C17 . -176.9(7)
O6 C16 C17 C18B . 46(2)
N6 C16 C17 C18B . -134.9(18)
O6 C16 C17 C18A . 106.3(14)
N6 C16 C17 C18A . -74.5(15)
Rh4 N7 C19 O7 . 1.2(17)
Rh4 N7 C19 C20B . 169(2)
Rh4 N7 C19 C20A . -172(3)
Rh4 O7 C19 N7 2_655 -3.4(15)
Rh4 O7 C19 C20B 2_655 -171(2)
Rh4 O7 C19 C20A 2_655 170(2)
N7 C19 C20A C21A . -137(4)
O7 C19 C20A C21A . 49(5)
C20B C19 C20A C21A . -44(11)
N7 C19 C20B C21B . -95(5)
O7 C19 C20B C21B . 73(5)
C20A C19 C20B C21B . 168(18)
Rh4 O8 C22 N8 2_655 0.5(15)
Rh4 O8 C22 C23C 2_655 180(4)
Rh4 O8 C22 C23B 2_655 -164(2)
Rh4 O8 C22 C23A 2_655 165(2)
Rh4 N8 C22 O8 . 1.7(17)
Rh4 N8 C22 C23C . -177(4)
Rh4 N8 C22 C23B . 167(2)
Rh4 N8 C22 C23A . -163(2)
O8 C22 C23A C24A . 49(4)
N8 C22 C23A C24A . -145(2)
O8 C22 C23B C24B . -48(5)
N8 C22 C23B C24B . 146(3)
O8 C22 C23C C24C . -71(9)
N8 C22 C23C C24C . 109(6)
