#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/73/2207329.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2207329
loop_
_publ_author_name
'Wagner, Andreas'
'Hannu-Kuure, Milja S.'
'Oilunkaniemi, Raija'
'Laitinen, Risto S.'
_publ_section_title
Di-μ-furan-2-selenolato-bis[(furan-2-selenolato)(triphenylphosphine)palladium(II)]
_journal_coeditor_code           RZ6122
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2198
_journal_page_last               m2200
_journal_paper_doi               10.1107/S1600536805031247
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Pd2 (C4 H3 O Se)4 (C18 H15 P)2]'
_chemical_formula_moiety         'C52 H42 O4 P2 Pd2 Se4'
_chemical_formula_sum            'C52 H42 O4 P2 Pd2 Se4'
_chemical_formula_weight         1321.44
_chemical_name_systematic
Di-μ-furan-2-selenolato-bis[(furan-2-selenolato)(triphenylphosphine)palladium]
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.85(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.045(3)
_cell_length_b                   16.394(3)
_cell_length_c                   12.233(2)
_cell_measurement_reflns_used    3924
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.00
_cell_measurement_theta_min      3.10
_cell_volume                     2444.8(10)
_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Nonius, 1998)'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'DIAMOND (Brandenburg & Berndt, 1999)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.99
_diffrn_measurement_device_type  'Bruker--Nonius KappaCCD'
_diffrn_measurement_method       'φ scans, and ω scans with κ offsets'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0503
_diffrn_reflns_av_sigmaI/netI    0.0416
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            17303
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.10
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.823
_exptl_absorpt_correction_T_max  0.737
_exptl_absorpt_correction_T_min  0.638
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SHELXTL; Bruker, 2001)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.795
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1288
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.747
_refine_diff_density_min         -0.925
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     290
_refine_ls_number_reflns         4701
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0538
_refine_ls_R_factor_gt           0.0416
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0378P)²+10.5236P] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0945
_refine_ls_wR_factor_ref         0.1018
_reflns_number_gt                3924
_reflns_number_total             4701
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            rz6122.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2207329
_cod_database_fobs_code          2207329
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Pd1 0.37476(3) 0.00294(2) 0.36834(3) 0.02079(11) Uani d . 1 Pd
Se2 0.45340(4) 0.07504(3) 0.55752(4) 0.02376(13) Uani d . 1 Se
Se1 0.21198(4) 0.09146(3) 0.29532(4) 0.02807(14) Uani d . 1 Se
P1 0.29905(10) -0.07365(7) 0.20388(10) 0.0217(3) Uani d . 1 P
C11 0.1765(4) 0.1128(3) 0.4285(5) 0.0318(11) Uani d . 1 C
C12 0.1147(4) 0.0644(4) 0.4719(5) 0.0349(12) Uani d . 1 C
H12 0.0846 0.0127 0.4427 0.042 Uiso calc R 1 H
C13 0.1045(7) 0.1051(7) 0.5662(7) 0.073(3) Uani d . 1 C
H13 0.0656 0.0863 0.6139 0.087 Uiso calc R 1 H
C14 0.1582(7) 0.1746(7) 0.5785(6) 0.079(3) Uani d . 1 C
H14 0.1640 0.2139 0.6374 0.095 Uiso calc R 1 H
O1 0.2066(4) 0.1824(3) 0.4911(5) 0.0640(14) Uani d . 1 O
C111 0.2031(4) -0.1458(3) 0.2282(4) 0.0237(10) Uani d . 1 C
C112 0.1771(4) -0.1401(3) 0.3291(4) 0.0274(11) Uani d . 1 C
H112 0.2070 -0.0971 0.3832 0.033 Uiso calc R 1 H
C113 0.1081(4) -0.1967(3) 0.3507(5) 0.0354(12) Uani d . 1 C
H113 0.0915 -0.1925 0.4201 0.043 Uiso calc R 1 H
C114 0.0629(4) -0.2593(3) 0.2727(5) 0.0368(13) Uani d . 1 C
H114 0.0157 -0.2980 0.2884 0.044 Uiso calc R 1 H
C115 0.0868(5) -0.2650(4) 0.1716(5) 0.0414(14) Uani d . 1 C
H115 0.0548 -0.3073 0.1170 0.050 Uiso calc R 1 H
C116 0.1569(4) -0.2096(3) 0.1494(5) 0.0329(12) Uani d . 1 C
H116 0.1739 -0.2147 0.0804 0.040 Uiso calc R 1 H
C121 0.3893(4) -0.1391(3) 0.1582(4) 0.0269(10) Uani d . 1 C
C122 0.4389(4) -0.2060(3) 0.2272(5) 0.0338(12) Uani d . 1 C
H122 0.4217 -0.2190 0.2945 0.041 Uiso calc R 1 H
C123 0.5133(5) -0.2537(3) 0.1982(6) 0.0418(14) Uani d . 1 C
H123 0.5471 -0.2988 0.2462 0.050 Uiso calc R 1 H
C124 0.5388(5) -0.2367(4) 0.1010(6) 0.0477(16) Uani d . 1 C
H124 0.5895 -0.2700 0.0817 0.057 Uiso calc R 1 H
C125 0.4900(5) -0.1705(4) 0.0308(5) 0.0431(14) Uani d . 1 C
H125 0.5073 -0.1584 -0.0366 0.052 Uiso calc R 1 H
C126 0.4153(4) -0.1216(3) 0.0596(5) 0.0332(12) Uani d . 1 C
H126 0.3822 -0.0762 0.0118 0.040 Uiso calc R 1 H
C131 0.2271(4) -0.0136(3) 0.0740(4) 0.0269(10) Uani d . 1 C
C132 0.1266(4) -0.0355(4) -0.0086(5) 0.0345(12) Uani d . 1 C
H132 0.0921 -0.0850 -0.0006 0.041 Uiso calc R 1 H
C133 0.0769(5) 0.0159(4) -0.1033(5) 0.0483(16) Uani d . 1 C
H133 0.0077 0.0014 -0.1594 0.058 Uiso calc R 1 H
C134 0.1261(6) 0.0868(4) -0.1168(6) 0.0506(17) Uani d . 1 C
H134 0.0905 0.1216 -0.1813 0.061 Uiso calc R 1 H
C135 0.2271(6) 0.1078(4) -0.0371(6) 0.0494(16) Uani d . 1 C
H135 0.2625 0.1563 -0.0474 0.059 Uiso calc R 1 H
C136 0.2773(5) 0.0576(3) 0.0590(5) 0.0391(13) Uani d . 1 C
H136 0.3466 0.0723 0.1146 0.047 Uiso calc R 1 H
C21 0.3819(4) 0.0153(3) 0.6427(5) 0.0311(11) Uani d . 1 C
C22 0.3483(5) 0.0328(4) 0.7298(5) 0.0455(15) Uani d . 1 C
H22 0.3567 0.0837 0.7691 0.055 Uiso calc R 1 H
C23 0.2966(6) -0.0392(5) 0.7546(6) 0.0547(17) Uani d . 1 C
H23 0.2635 -0.0446 0.8120 0.066 Uiso calc R 1 H
C24 0.3044(6) -0.0958(4) 0.6819(7) 0.061(2) Uani d . 1 C
H24 0.2778 -0.1500 0.6793 0.073 Uiso calc R 1 H
O2 0.3563(4) -0.0660(2) 0.6098(4) 0.0459(10) Uani d . 1 O
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P1 Pd1 Se2 . 3_656 95.23(4) yes
P1 Pd1 Se1 . . 87.57(4) yes
Se2 Pd1 Se1 3_656 . 175.18(2) yes
P1 Pd1 Se2 . . 174.50(4) yes
Se2 Pd1 Se2 3_656 . 83.28(3) yes
Se1 Pd1 Se2 . . 94.29(3) yes
C21 Se2 Pd1 . 3_656 95.21(16) no
C21 Se2 Pd1 . . 98.37(16) no
Pd1 Se2 Pd1 3_656 . 96.72(3) yes
C11 Se1 Pd1 . . 104.01(16) no
C131 P1 C111 . . 108.8(2) no
C131 P1 C121 . . 103.9(2) no
C111 P1 C121 . . 102.9(2) no
C131 P1 Pd1 . . 113.55(17) no
C111 P1 Pd1 . . 108.73(16) no
C121 P1 Pd1 . . 118.14(16) no
O1 C11 C12 . . 111.2(5) no
O1 C11 Se1 . . 122.5(4) no
C12 C11 Se1 . . 126.2(4) no
C11 C12 C13 . . 106.9(6) no
C11 C12 H12 . . 126.5 no
C13 C12 H12 . . 126.5 no
C14 C13 C12 . . 107.9(7) no
C14 C13 H13 . . 126.1 no
C12 C13 H13 . . 126.1 no
C13 C14 O1 . . 110.6(6) no
C13 C14 H14 . . 124.7 no
O1 C14 H14 . . 124.7 no
C11 O1 C14 . . 103.4(6) no
C112 C111 C116 . . 118.5(4) no
C112 C111 P1 . . 119.9(4) no
C116 C111 P1 . . 121.6(4) no
C113 C112 C111 . . 120.3(5) no
C113 C112 H112 . . 119.9 no
C111 C112 H112 . . 119.9 no
C114 C113 C112 . . 120.8(5) no
C114 C113 H113 . . 119.6 no
C112 C113 H113 . . 119.6 no
C115 C114 C113 . . 119.5(5) no
C115 C114 H114 . . 120.3 no
C113 C114 H114 . . 120.3 no
C114 C115 C116 . . 120.4(5) no
C114 C115 H115 . . 119.8 no
C116 C115 H115 . . 119.8 no
C115 C116 C111 . . 120.5(5) no
C115 C116 H116 . . 119.8 no
C111 C116 H116 . . 119.8 no
C126 C121 C122 . . 118.9(5) no
C126 C121 P1 . . 121.8(4) no
C122 C121 P1 . . 119.2(4) no
C123 C122 C121 . . 120.3(5) no
C123 C122 H122 . . 119.9 no
C121 C122 H122 . . 119.9 no
C124 C123 C122 . . 121.0(5) no
C124 C123 H123 . . 119.5 no
C122 C123 H123 . . 119.5 no
C123 C124 C125 . . 119.7(5) no
C123 C124 H124 . . 120.2 no
C125 C124 H124 . . 120.2 no
C124 C125 C126 . . 119.9(6) no
C124 C125 H125 . . 120.0 no
C126 C125 H125 . . 120.0 no
C121 C126 C125 . . 120.3(5) no
C121 C126 H126 . . 119.8 no
C125 C126 H126 . . 119.8 no
C136 C131 C132 . . 119.4(5) no
C136 C131 P1 . . 116.8(4) no
C132 C131 P1 . . 123.8(4) no
C131 C132 C133 . . 119.3(6) no
C131 C132 H132 . . 120.4 no
C133 C132 H132 . . 120.4 no
C134 C133 C132 . . 121.1(6) no
C134 C133 H133 . . 119.5 no
C132 C133 H133 . . 119.5 no
C133 C134 C135 . . 120.0(6) no
C133 C134 H134 . . 120.0 no
C135 C134 H134 . . 120.0 no
C134 C135 C136 . . 119.6(6) no
C134 C135 H135 . . 120.2 no
C136 C135 H135 . . 120.2 no
C131 C136 C135 . . 120.6(6) no
C131 C136 H136 . . 119.7 no
C135 C136 H136 . . 119.7 no
C22 C21 O2 . . 109.1(5) no
C22 C21 Se2 . . 134.3(5) no
O2 C21 Se2 . . 116.5(4) no
C21 C22 C23 . . 107.8(6) no
C21 C22 H22 . . 126.1 no
C23 C22 H22 . . 126.1 no
C24 C23 C22 . . 106.3(6) no
C24 C23 H23 . . 126.8 no
C22 C23 H23 . . 126.8 no
C23 C24 O2 . . 110.9(6) no
C23 C24 H24 . . 124.6 no
O2 C24 H24 . . 124.6 no
C24 O2 C21 . . 106.0(5) no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pd1 P1 . 2.2771(13) yes
Pd1 Se2 3_656 2.4568(8) yes
Pd1 Se1 . 2.4623(8) yes
Pd1 Se2 . 2.4729(8) yes
Se2 C21 . 1.900(5) no
Se2 Pd1 3_656 2.4568(8) no
Se1 C11 . 1.877(5) no
P1 C131 . 1.820(5) no
P1 C111 . 1.822(5) no
P1 C121 . 1.822(5) no
C11 O1 . 1.352(7) no
C11 C12 . 1.366(7) no
C12 C13 . 1.380(10) no
C12 H12 . 0.9500 no
C13 C14 . 1.318(13) no
C13 H13 . 0.9500 no
C14 O1 . 1.428(10) no
C14 H14 . 0.9500 no
C111 C112 . 1.395(7) no
C111 C116 . 1.404(7) no
C112 C113 . 1.383(7) no
C112 H112 . 0.9500 no
C113 C114 . 1.382(8) no
C113 H113 . 0.9500 no
C114 C115 . 1.382(8) no
C114 H114 . 0.9500 no
C115 C116 . 1.383(7) no
C115 H115 . 0.9500 no
C116 H116 . 0.9500 no
C121 C126 . 1.394(7) no
C121 C122 . 1.395(7) no
C122 C123 . 1.387(8) no
C122 H122 . 0.9500 no
C123 C124 . 1.372(9) no
C123 H123 . 0.9500 no
C124 C125 . 1.389(9) no
C124 H124 . 0.9500 no
C125 C126 . 1.400(8) no
C125 H125 . 0.9500 no
C126 H126 . 0.9500 no
C131 C136 . 1.381(7) no
C131 C132 . 1.388(7) no
C132 C133 . 1.392(8) no
C132 H132 . 0.9500 no
C133 C134 . 1.366(9) no
C133 H133 . 0.9500 no
C134 C135 . 1.376(10) no
C134 H134 . 0.9500 no
C135 C136 . 1.393(8) no
C135 H135 . 0.9500 no
C136 H136 . 0.9500 no
C21 C22 . 1.319(8) no
C21 O2 . 1.397(7) no
C22 C23 . 1.445(10) no
C22 H22 . 0.9500 no
C23 C24 . 1.315(10) no
C23 H23 . 0.9500 no
C24 O2 . 1.379(8) no
C24 H24 . 0.9500 no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
Se2 Pd1 Se2 C21 3_656 . -96.30(16) no
Se1 Pd1 Se2 C21 . . 87.88(16) no
Se2 Pd1 Se2 Pd1 3_656 3_656 0.0 no
Se1 Pd1 Se2 Pd1 . 3_656 -175.82(2) no
P1 Pd1 Se1 C11 . . 137.63(17) no
Se2 Pd1 Se1 C11 . . -37.19(17) no
Se2 Pd1 P1 C131 3_656 . -138.78(17) no
Se1 Pd1 P1 C131 . . 37.28(17) no
Se2 Pd1 P1 C111 3_656 . 99.89(16) no
Se1 Pd1 P1 C111 . . -84.05(16) no
Se2 Pd1 P1 C121 3_656 . -16.8(2) no
Se1 Pd1 P1 C121 . . 159.3(2) no
Pd1 Se1 C11 O1 . . 98.6(4) no
Pd1 Se1 C11 C12 . . -84.6(5) no
O1 C11 C12 C13 . . 0.2(7) no
Se1 C11 C12 C13 . . -176.9(4) no
C11 C12 C13 C14 . . -0.2(8) no
C12 C13 C14 O1 . . 0.1(8) no
C12 C11 O1 C14 . . -0.2(6) no
Se1 C11 O1 C14 . . 177.0(4) no
C13 C14 O1 C11 . . 0.1(7) no
C131 P1 C111 C112 . . -116.2(4) no
C121 P1 C111 C112 . . 134.0(4) no
Pd1 P1 C111 C112 . . 7.9(4) no
C131 P1 C111 C116 . . 66.0(5) no
C121 P1 C111 C116 . . -43.7(5) no
Pd1 P1 C111 C116 . . -169.8(4) no
C116 C111 C112 C113 . . 0.6(7) no
P1 C111 C112 C113 . . -177.2(4) no
C111 C112 C113 C114 . . -0.6(8) no
C112 C113 C114 C115 . . -0.3(8) no
C113 C114 C115 C116 . . 1.2(9) no
C114 C115 C116 C111 . . -1.2(9) no
C112 C111 C116 C115 . . 0.3(8) no
P1 C111 C116 C115 . . 178.1(4) no
C131 P1 C121 C126 . . 18.2(5) no
C111 P1 C121 C126 . . 131.6(4) no
Pd1 P1 C121 C126 . . -108.6(4) no
C131 P1 C121 C122 . . -165.7(4) no
C111 P1 C121 C122 . . -52.2(4) no
Pd1 P1 C121 C122 . . 67.5(4) no
C126 C121 C122 C123 . . 0.3(8) no
P1 C121 C122 C123 . . -175.9(4) no
C121 C122 C123 C124 . . -0.6(8) no
C122 C123 C124 C125 . . 0.4(9) no
C123 C124 C125 C126 . . 0.0(9) no
C122 C121 C126 C125 . . 0.1(8) no
P1 C121 C126 C125 . . 176.2(4) no
C124 C125 C126 C121 . . -0.2(9) no
C111 P1 C131 C136 . . 163.5(4) no
C121 P1 C131 C136 . . -87.3(4) no
Pd1 P1 C131 C136 . . 42.3(4) no
C111 P1 C131 C132 . . -16.5(5) no
C121 P1 C131 C132 . . 92.6(5) no
Pd1 P1 C131 C132 . . -137.7(4) no
C136 C131 C132 C133 . . -1.8(8) no
P1 C131 C132 C133 . . 178.2(4) no
C131 C132 C133 C134 . . 0.8(9) no
C132 C133 C134 C135 . . 1.0(10) no
C133 C134 C135 C136 . . -1.8(10) no
C132 C131 C136 C135 . . 1.0(8) no
P1 C131 C136 C135 . . -179.0(5) no
C134 C135 C136 C131 . . 0.8(10) no
Pd1 Se2 C21 C22 3_656 . 112.6(6) no
Pd1 Se2 C21 C22 . . -149.8(6) no
Pd1 Se2 C21 O2 3_656 . -67.7(4) no
Pd1 Se2 C21 O2 . . 29.9(4) no
O2 C21 C22 C23 . . -1.0(7) no
Se2 C21 C22 C23 . . 178.7(5) no
C21 C22 C23 C24 . . 1.1(8) no
C22 C23 C24 O2 . . -0.8(8) no
C23 C24 O2 C21 . . 0.2(8) no
C22 C21 O2 C24 . . 0.6(7) no
Se2 C21 O2 C24 . . -179.2(4) no
