#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/74/2207495.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2207495
loop_
_publ_author_name
'You, Zhong-Lu'
_publ_section_title
;
 Bis[2-(cyclohexyliminomethyl)-4-nitrophenolato]zinc(II)
;
_journal_coeditor_code           CI6693
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2495
_journal_page_last               m2496
_journal_paper_doi               10.1107/S1600536805035531
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Zn (C13 H15 N2 O3)2]'
_chemical_formula_moiety         'C26 H30 N4 O6 Zn'
_chemical_formula_sum            'C26 H30 N4 O6 Zn'
_chemical_formula_weight         559.91
_chemical_name_systematic
;
Bis[2-(cyclohexyliminomethyl)-4-nitrophenolato]zinc(II)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.740(10)
_cell_angle_beta                 104.390(10)
_cell_angle_gamma                94.990(10)
_cell_formula_units_Z            2
_cell_length_a                   10.7590(10)
_cell_length_b                   11.1080(10)
_cell_length_c                   12.4390(10)
_cell_measurement_reflns_used    4267
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.5
_cell_measurement_theta_min      2.3
_cell_volume                     1288.5(2)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 1997b)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997a)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997a)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_sigmaI/netI    0.0440
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14907
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.88
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.001
_exptl_absorpt_correction_T_max  0.8978
_exptl_absorpt_correction_T_min  0.8173
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.291
_refine_diff_density_min         -0.353
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         5819
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0588
_refine_ls_R_factor_gt           0.0469
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0471P)²+0.1392P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1023
_refine_ls_wR_factor_ref         0.1084
_reflns_number_gt                4828
_reflns_number_total             5819
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ci6693.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2207495
_cod_database_fobs_code          2207495
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Zn1 0.03414(3) 0.20850(3) 0.40418(3) 0.04017(11) Uani d . 1 Zn
O1 0.14419(17) 0.33370(17) 0.56775(15) 0.0467(4) Uani d . 1 O
O2 -0.14807(17) 0.14646(19) 0.37687(17) 0.0488(4) Uani d . 1 O
O3 0.64779(19) 0.1822(2) 0.8072(2) 0.0723(6) Uani d . 1 O
O4 0.6737(2) 0.3863(2) 0.9419(2) 0.0759(7) Uani d . 1 O
O5 -0.68835(19) 0.1026(2) 0.0253(2) 0.0702(6) Uani d . 1 O
O6 -0.5669(2) 0.2242(3) -0.0238(2) 0.0726(6) Uani d . 1 O
N1 0.13635(19) 0.06345(19) 0.38532(17) 0.0380(5) Uani d . 1 N
N2 0.00618(18) 0.30055(19) 0.29377(17) 0.0355(4) Uani d . 1 N
N3 0.6126(2) 0.2899(3) 0.8442(2) 0.0522(6) Uani d . 1 N
N4 -0.5820(2) 0.1616(2) 0.0351(2) 0.0515(6) Uani d . 1 N
C1 0.2542(2) 0.3186(2) 0.6273(2) 0.0379(5) Uani d . 1 C
C2 0.3282(3) 0.4245(3) 0.7426(2) 0.0487(6) Uani d . 1 C
H2 0.2967 0.5030 0.7719 0.058 Uiso calc R 1 H
C3 0.4436(3) 0.4172(3) 0.8132(2) 0.0484(6) Uani d . 1 C
H3 0.4895 0.4889 0.8892 0.058 Uiso calc R 1 H
C4 0.4914(2) 0.3007(3) 0.7697(2) 0.0413(6) Uani d . 1 C
C5 0.4255(2) 0.1959(2) 0.6570(2) 0.0410(6) Uani d . 1 C
H5 0.4605 0.1196 0.6289 0.049 Uiso calc R 1 H
C6 0.3064(2) 0.2013(2) 0.5833(2) 0.0368(5) Uani d . 1 C
C7 0.2443(2) 0.0831(2) 0.4681(2) 0.0401(6) Uani d . 1 C
H7 0.2882 0.0124 0.4520 0.048 Uiso calc R 1 H
C8 0.0933(2) -0.0698(2) 0.2772(2) 0.0415(6) Uani d . 1 C
H8 0.1716 -0.1067 0.2683 0.050 Uiso calc R 1 H
C9 0.0305(3) -0.0576(3) 0.1607(2) 0.0624(8) Uani d . 1 C
H9A 0.0921 0.0014 0.1488 0.075 Uiso calc R 1 H
H9B -0.0459 -0.0183 0.1679 0.075 Uiso calc R 1 H
C10 -0.0106(3) -0.1949(3) 0.0500(3) 0.0672(9) Uani d . 1 C
H10A -0.0559 -0.1857 -0.0232 0.081 Uiso calc R 1 H
H10B 0.0672 -0.2289 0.0373 0.081 Uiso calc R 1 H
C11 -0.0986(3) -0.2942(3) 0.0664(3) 0.0651(9) Uani d . 1 C
H11A -0.1163 -0.3820 -0.0031 0.078 Uiso calc R 1 H
H11B -0.1816 -0.2668 0.0678 0.078 Uiso calc R 1 H
C12 -0.0364(3) -0.3040(3) 0.1849(3) 0.0646(8) Uani d . 1 C
H12A 0.0405 -0.3426 0.1790 0.077 Uiso calc R 1 H
H12B -0.0981 -0.3634 0.1962 0.077 Uiso calc R 1 H
C13 0.0036(3) -0.1655(3) 0.2970(3) 0.0589(8) Uani d . 1 C
H13A -0.0741 -0.1305 0.3084 0.071 Uiso calc R 1 H
H13B 0.0481 -0.1739 0.3709 0.071 Uiso calc R 1 H
C14 -0.2452(2) 0.1538(2) 0.2961(2) 0.0407(6) Uani d . 1 C
C15 -0.3735(3) 0.0951(3) 0.2816(3) 0.0548(7) Uani d . 1 C
H15 -0.3848 0.0536 0.3312 0.066 Uiso calc R 1 H
C16 -0.4815(3) 0.0968(3) 0.1979(3) 0.0531(7) Uani d . 1 C
H16 -0.5647 0.0570 0.1908 0.064 Uiso calc R 1 H
C17 -0.4664(2) 0.1580(2) 0.1238(2) 0.0414(6) Uani d . 1 C
C18 -0.3448(2) 0.2167(2) 0.1331(2) 0.0399(6) Uani d . 1 C
H18 -0.3369 0.2569 0.0817 0.048 Uiso calc R 1 H
C19 -0.2317(2) 0.2175(2) 0.2188(2) 0.0361(5) Uani d . 1 C
C20 -0.1097(2) 0.2882(2) 0.2251(2) 0.0369(5) Uani d . 1 C
H20 -0.1154 0.3301 0.1732 0.044 Uiso calc R 1 H
C21 0.1154(2) 0.3878(2) 0.2910(2) 0.0378(5) Uani d . 1 C
H21 0.0897 0.3926 0.2118 0.045 Uiso calc R 1 H
C22 0.2376(2) 0.3284(3) 0.3001(3) 0.0450(6) Uani d . 1 C
H22A 0.2600 0.3155 0.3747 0.054 Uiso calc R 1 H
H22B 0.2197 0.2411 0.2299 0.054 Uiso calc R 1 H
C23 0.3527(3) 0.4199(3) 0.3025(3) 0.0533(7) Uani d . 1 C
H23A 0.4304 0.3823 0.3130 0.064 Uiso calc R 1 H
H23B 0.3339 0.4257 0.2246 0.064 Uiso calc R 1 H
C24 0.3782(3) 0.5590(3) 0.4072(3) 0.0531(7) Uani d . 1 C
H24A 0.4030 0.5539 0.4855 0.064 Uiso calc R 1 H
H24B 0.4504 0.6168 0.4062 0.064 Uiso calc R 1 H
C25 0.2574(3) 0.6187(3) 0.3953(3) 0.0538(7) Uani d . 1 C
H25A 0.2362 0.6295 0.3197 0.065 Uiso calc R 1 H
H25B 0.2751 0.7069 0.4642 0.065 Uiso calc R 1 H
C26 0.1410(2) 0.5289(2) 0.3936(2) 0.0462(6) Uani d . 1 C
H26A 0.1587 0.5254 0.4725 0.055 Uiso calc R 1 H
H26B 0.0636 0.5666 0.3813 0.055 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O2 Zn1 O1 119.44(8) y
O2 Zn1 N1 112.74(8) y
O1 Zn1 N1 96.25(7) y
O2 Zn1 N2 96.40(7) y
O1 Zn1 N2 109.86(8) y
N1 Zn1 N2 123.95(8) y
C1 O1 Zn1 125.67(15) ?
C14 O2 Zn1 125.52(17) ?
C7 N1 C8 116.7(2) ?
C7 N1 Zn1 120.59(16) ?
C8 N1 Zn1 122.72(15) ?
C20 N2 C21 117.7(2) ?
C20 N2 Zn1 120.46(16) ?
C21 N2 Zn1 121.84(14) ?
O4 N3 O3 122.9(2) ?
O4 N3 C4 119.0(2) ?
O3 N3 C4 118.1(2) ?
O5 N4 O6 124.1(2) ?
O5 N4 C17 117.6(3) ?
O6 N4 C17 118.3(2) ?
O1 C1 C2 118.6(2) ?
O1 C1 C6 124.0(2) ?
C2 C1 C6 117.3(2) ?
C3 C2 C1 123.0(2) ?
C3 C2 H2 118.5 ?
C1 C2 H2 118.5 ?
C2 C3 C4 118.7(2) ?
C2 C3 H3 120.7 ?
C4 C3 H3 120.7 ?
C5 C4 C3 120.9(2) ?
C5 C4 N3 119.6(2) ?
C3 C4 N3 119.6(2) ?
C4 C5 C6 121.3(2) ?
C4 C5 H5 119.4 ?
C6 C5 H5 119.4 ?
C5 C6 C1 118.8(2) ?
C5 C6 C7 116.1(2) ?
C1 C6 C7 125.0(2) ?
N1 C7 C6 128.0(2) ?
N1 C7 H7 116.0 ?
C6 C7 H7 116.0 ?
N1 C8 C9 111.0(2) ?
N1 C8 C13 111.0(2) ?
C9 C8 C13 111.7(2) ?
N1 C8 H8 107.6 ?
C9 C8 H8 107.6 ?
C13 C8 H8 107.6 ?
C8 C9 C10 110.4(2) ?
C8 C9 H9A 109.6 ?
C10 C9 H9A 109.6 ?
C8 C9 H9B 109.6 ?
C10 C9 H9B 109.6 ?
H9A C9 H9B 108.1 ?
C11 C10 C9 112.3(3) ?
C11 C10 H10A 109.1 ?
C9 C10 H10A 109.1 ?
C11 C10 H10B 109.1 ?
C9 C10 H10B 109.1 ?
H10A C10 H10B 107.9 ?
C10 C11 C12 111.2(2) ?
C10 C11 H11A 109.4 ?
C12 C11 H11A 109.4 ?
C10 C11 H11B 109.4 ?
C12 C11 H11B 109.4 ?
H11A C11 H11B 108.0 ?
C11 C12 C13 111.5(3) ?
C11 C12 H12A 109.3 ?
C13 C12 H12A 109.3 ?
C11 C12 H12B 109.3 ?
C13 C12 H12B 109.3 ?
H12A C12 H12B 108.0 ?
C8 C13 C12 109.9(2) ?
C8 C13 H13A 109.7 ?
C12 C13 H13A 109.7 ?
C8 C13 H13B 109.7 ?
C12 C13 H13B 109.7 ?
H13A C13 H13B 108.2 ?
O2 C14 C15 118.6(2) ?
O2 C14 C19 124.3(2) ?
C15 C14 C19 117.1(2) ?
C16 C15 C14 122.7(3) ?
C16 C15 H15 118.7 ?
C14 C15 H15 118.7 ?
C15 C16 C17 119.3(2) ?
C15 C16 H16 120.3 ?
C17 C16 H16 120.3 ?
C18 C17 C16 121.0(2) ?
C18 C17 N4 119.5(2) ?
C16 C17 N4 119.5(2) ?
C17 C18 C19 121.1(2) ?
C17 C18 H18 119.4 ?
C19 C18 H18 119.4 ?
C18 C19 C14 118.8(2) ?
C18 C19 C20 116.3(2) ?
C14 C19 C20 124.8(2) ?
N2 C20 C19 127.8(2) ?
N2 C20 H20 116.1 ?
C19 C20 H20 116.1 ?
N2 C21 C26 110.16(19) ?
N2 C21 C22 110.44(19) ?
C26 C21 C22 111.6(2) ?
N2 C21 H21 108.2 ?
C26 C21 H21 108.2 ?
C22 C21 H21 108.2 ?
C23 C22 C21 111.2(2) ?
C23 C22 H22A 109.4 ?
C21 C22 H22A 109.4 ?
C23 C22 H22B 109.4 ?
C21 C22 H22B 109.4 ?
H22A C22 H22B 108.0 ?
C24 C23 C22 110.5(2) ?
C24 C23 H23A 109.5 ?
C22 C23 H23A 109.5 ?
C24 C23 H23B 109.5 ?
C22 C23 H23B 109.5 ?
H23A C23 H23B 108.1 ?
C25 C24 C23 110.7(2) ?
C25 C24 H24A 109.5 ?
C23 C24 H24A 109.5 ?
C25 C24 H24B 109.5 ?
C23 C24 H24B 109.5 ?
H24A C24 H24B 108.1 ?
C24 C25 C26 111.0(2) ?
C24 C25 H25A 109.4 ?
C26 C25 H25A 109.4 ?
C24 C25 H25B 109.4 ?
C26 C25 H25B 109.4 ?
H25A C25 H25B 108.0 ?
C21 C26 C25 110.7(2) ?
C21 C26 H26A 109.5 ?
C25 C26 H26A 109.5 ?
C21 C26 H26B 109.5 ?
C25 C26 H26B 109.5 ?
H26A C26 H26B 108.1 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Zn1 O2 1.918(2) y
Zn1 O1 1.927(2) y
Zn1 N1 1.998(2) y
Zn1 N2 2.000(2) y
O1 C1 1.295(3) ?
O2 C14 1.292(3) ?
O3 N3 1.228(3) ?
O4 N3 1.220(3) ?
O5 N4 1.220(3) ?
O6 N4 1.224(3) ?
N1 C7 1.280(3) ?
N1 C8 1.477(3) ?
N2 C20 1.284(3) ?
N2 C21 1.473(3) ?
N3 C4 1.446(3) ?
N4 C17 1.459(3) ?
C1 C2 1.410(3) ?
C1 C6 1.421(3) ?
C2 C3 1.361(4) ?
C2 H2 0.93 ?
C3 C4 1.386(4) ?
C3 H3 0.93 ?
C4 C5 1.367(3) ?
C5 C6 1.400(3) ?
C5 H5 0.93 ?
C6 C7 1.442(3) ?
C7 H7 0.93 ?
C8 C9 1.504(4) ?
C8 C13 1.508(4) ?
C8 H8 0.98 ?
C9 C10 1.518(4) ?
C9 H9A 0.97 ?
C9 H9B 0.97 ?
C10 C11 1.500(4) ?
C10 H10A 0.97 ?
C10 H10B 0.97 ?
C11 C12 1.511(4) ?
C11 H11A 0.97 ?
C11 H11B 0.97 ?
C12 C13 1.535(4) ?
C12 H12A 0.97 ?
C12 H12B 0.97 ?
C13 H13A 0.97 ?
C13 H13B 0.97 ?
C14 C15 1.411(4) ?
C14 C19 1.430(3) ?
C15 C16 1.360(4) ?
C15 H15 0.93 ?
C16 C17 1.379(4) ?
C16 H16 0.93 ?
C17 C18 1.366(3) ?
C18 C19 1.401(3) ?
C18 H18 0.93 ?
C19 C20 1.437(3) ?
C20 H20 0.93 ?
C21 C26 1.517(3) ?
C21 C22 1.521(3) ?
C21 H21 0.98 ?
C22 C23 1.518(4) ?
C22 H22A 0.97 ?
C22 H22B 0.97 ?
C23 C24 1.513(4) ?
C23 H23A 0.97 ?
C23 H23B 0.97 ?
C24 C25 1.511(4) ?
C24 H24A 0.97 ?
C24 H24B 0.97 ?
C25 C26 1.522(4) ?
C25 H25A 0.97 ?
C25 H25B 0.97 ?
C26 H26A 0.97 ?
C26 H26B 0.97 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C8 H8 O3 2_656 0.98 2.43 3.380(3) 163 y
C24 H24B Cg1 2_666 0.97 2.78 3.680(4) 155 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O2 Zn1 O1 C1 127.08(19)
N1 Zn1 O1 C1 6.5(2)
N2 Zn1 O1 C1 -123.0(2)
O1 Zn1 O2 C14 125.3(2)
N1 Zn1 O2 C14 -122.8(2)
N2 Zn1 O2 C14 8.2(2)
O2 Zn1 N1 C7 -130.76(19)
O1 Zn1 N1 C7 -5.2(2)
N2 Zn1 N1 C7 113.89(19)
O2 Zn1 N1 C8 49.53(19)
O1 Zn1 N1 C8 175.12(18)
N2 Zn1 N1 C8 -65.8(2)
O2 Zn1 N2 C20 -7.44(19)
O1 Zn1 N2 C20 -131.94(17)
N1 Zn1 N2 C20 115.55(18)
O2 Zn1 N2 C21 170.43(17)
O1 Zn1 N2 C21 45.93(18)
N1 Zn1 N2 C21 -66.57(19)
Zn1 O1 C1 C2 175.13(18)
Zn1 O1 C1 C6 -4.5(3)
O1 C1 C2 C3 178.6(3)
C6 C1 C2 C3 -1.7(4)
C1 C2 C3 C4 0.4(4)
C2 C3 C4 C5 1.2(4)
C2 C3 C4 N3 -178.9(2)
O4 N3 C4 C5 176.6(2)
O3 N3 C4 C5 -5.0(4)
O4 N3 C4 C3 -3.3(4)
O3 N3 C4 C3 175.0(2)
C3 C4 C5 C6 -1.5(4)
N3 C4 C5 C6 178.6(2)
C4 C5 C6 C1 0.2(4)
C4 C5 C6 C7 -178.2(2)
O1 C1 C6 C5 -179.0(2)
C2 C1 C6 C5 1.3(4)
O1 C1 C6 C7 -0.7(4)
C2 C1 C6 C7 179.6(2)
C8 N1 C7 C6 -178.1(2)
Zn1 N1 C7 C6 2.1(4)
C5 C6 C7 N1 -179.8(2)
C1 C6 C7 N1 1.9(4)
C7 N1 C8 C9 -142.6(3)
Zn1 N1 C8 C9 37.1(3)
C7 N1 C8 C13 92.4(3)
Zn1 N1 C8 C13 -87.8(2)
N1 C8 C9 C10 178.8(2)
C13 C8 C9 C10 -56.7(3)
C8 C9 C10 C11 55.1(4)
C9 C10 C11 C12 -54.4(4)
C10 C11 C12 C13 54.6(4)
N1 C8 C13 C12 -178.4(2)
C9 C8 C13 C12 57.1(3)
C11 C12 C13 C8 -55.7(4)
Zn1 O2 C14 C15 175.68(19)
Zn1 O2 C14 C19 -4.0(3)
O2 C14 C15 C16 -179.3(3)
C19 C14 C15 C16 0.4(4)
C14 C15 C16 C17 -0.1(5)
C15 C16 C17 C18 0.1(4)
C15 C16 C17 N4 -179.2(2)
O5 N4 C17 C18 176.6(2)
O6 N4 C17 C18 -4.0(4)
O5 N4 C17 C16 -4.1(4)
O6 N4 C17 C16 175.2(3)
C16 C17 C18 C19 -0.5(4)
N4 C17 C18 C19 178.8(2)
C17 C18 C19 C14 0.8(3)
C17 C18 C19 C20 -176.8(2)
O2 C14 C19 C18 178.9(2)
C15 C14 C19 C18 -0.8(3)
O2 C14 C19 C20 -3.7(4)
C15 C14 C19 C20 176.7(2)
C21 N2 C20 C19 -175.1(2)
Zn1 N2 C20 C19 2.9(3)
C18 C19 C20 N2 -178.4(2)
C14 C19 C20 N2 4.1(4)
C20 N2 C21 C26 93.5(2)
Zn1 N2 C21 C26 -84.4(2)
C20 N2 C21 C22 -142.8(2)
Zn1 N2 C21 C22 39.3(2)
N2 C21 C22 C23 -177.7(2)
C26 C21 C22 C23 -54.9(3)
C21 C22 C23 C24 56.1(3)
C22 C23 C24 C25 -57.7(3)
C23 C24 C25 C26 57.8(3)
N2 C21 C26 C25 177.6(2)
C22 C21 C26 C25 54.5(3)
C24 C25 C26 C21 -56.0(3)
