#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/92/2209224.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2209224
loop_
_publ_author_name
'Déborah González Mantero'
'Antonia Neels'
'Helen Stoeckli-Evans'
_publ_section_title
;
 catena-Poly[bis[silver(I)-μ-4,4'-bipyridine-κ²N:N']
 hexafluorosilicate dihydrate ethylene glycol disolvate]
;
_journal_coeditor_code           IS2032
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1381
_journal_page_last               m1383
_journal_paper_doi               10.1107/S1600536806018150
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac
'[Ag (C10 H8 N2)]2 (Si F6) , 2H2 O , 2C2 H6 O2'
_chemical_formula_moiety
'2C10 H8 Ag N2 + , Si F6 2- , 2C2 H6 O2 , 2H2 O'
_chemical_formula_sum            'C24 H32 Ag2 F6 N4 O6 Si'
_chemical_formula_weight         830.37
_chemical_name_systematic
;
catena-Poly[bis[silver(I)-μ-4,4'-bipyridine-κ²N:N'] hexafluorosilicate
dihydrate ethylene glycol disolvate]
;
_space_group_IT_number           7
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P -2yc'
_symmetry_space_group_name_H-M   'P 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 119.701(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.8887(8)
_cell_length_b                   11.3492(6)
_cell_length_c                   14.6304(12)
_cell_measurement_reflns_used    4500
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      25.90
_cell_measurement_theta_min      2.28
_cell_volume                     1426.2(2)
_computing_cell_refinement       'CELL (Stoe & Cie, 2000)'
_computing_data_collection       'EXPOSE (Stoe & Cie, 2000)'
_computing_data_reduction        'INTEGRATE (Stoe & Cie, 2000)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      153(2)
_diffrn_detector_area_resol_mean 0.81
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Stow IPDS'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0727
_diffrn_reflns_av_sigmaI/netI    0.0952
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            10905
_diffrn_reflns_theta_full        25.86
_diffrn_reflns_theta_max         25.86
_diffrn_reflns_theta_min         2.37
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.502
_exptl_absorpt_correction_T_max  0.928
_exptl_absorpt_correction_T_min  0.252
_exptl_absorpt_correction_type   'empirical, refined from \DF'
_exptl_absorpt_process_details   '(PLATON; Spek, 2003)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.934
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             828
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.258
_refine_diff_density_min         -0.963
_refine_ls_abs_structure_details 'Flack (1983), with 2401 Friedel pairs'
_refine_ls_abs_structure_Flack   0.36(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.836
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     285
_refine_ls_number_reflns         5161
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      0.836
_refine_ls_R_factor_all          0.0668
_refine_ls_R_factor_gt           0.0421
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0419P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0878
_refine_ls_wR_factor_ref         0.0932
_reflns_number_gt                3559
_reflns_number_total             5161
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            is2032.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P c'
_cod_database_code               2209224
_cod_database_fobs_code          2209224
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
C C1 0.2006(13) 0.4271(8) 0.0097(8) 0.0202(9) Uani d . 1
H H1 0.1089 0.4689 -0.0374 0.024 Uiso calc R 1
C C2 0.1980(14) 0.3040(8) 0.0038(9) 0.0202(9) Uani d . 1
H H2 0.1086 0.2637 -0.0481 0.024 Uiso calc R 1
C C3 0.3310(14) 0.2412(8) 0.0767(9) 0.0202(9) Uani d . 1
C C4 0.4568(14) 0.3069(8) 0.1481(9) 0.0202(9) Uani d . 1
H H4 0.5488 0.2674 0.1979 0.024 Uiso calc R 1
C C5 0.4522(12) 0.4281(8) 0.1488(7) 0.0202(9) Uani d . 1
H H5 0.5403 0.4704 0.2000 0.024 Uiso calc R 1
C C6 0.3282(15) 0.1106(8) 0.0751(10) 0.0168(9) Uani d . 1
C C7 0.1928(13) 0.0489(8) 0.0539(8) 0.0168(9) Uani d . 1
H H7 0.1003 0.0906 0.0380 0.020 Uiso calc R 1
C C8 0.1946(13) -0.0722(8) 0.0564(8) 0.0168(9) Uani d . 1
H H8 0.1021 -0.1126 0.0422 0.020 Uiso calc R 1
C C9 0.4527(13) -0.0755(8) 0.0991(8) 0.0168(9) Uani d . 1
H H9 0.5441 -0.1189 0.1152 0.020 Uiso calc R 1
C C10 0.4607(13) 0.0451(8) 0.0987(7) 0.0168(9) Uani d . 1
H H10 0.5551 0.0834 0.1143 0.020 Uiso calc R 1
C C11 0.1882(11) 0.4463(8) 0.2626(7) 0.0187(9) Uani d . 1
H H11 0.0958 0.4893 0.2190 0.022 Uiso calc R 1
C C12 0.1808(14) 0.3241(8) 0.2595(9) 0.0187(9) Uani d . 1
H H12 0.0876 0.2846 0.2117 0.022 Uiso calc R 1
C C13 0.3148(15) 0.2603(8) 0.3290(9) 0.0187(9) Uani d . 1
C C14 0.4450(14) 0.3241(7) 0.4008(9) 0.0187(9) Uani d . 1
H H14 0.5355 0.2841 0.4518 0.022 Uiso calc R 1
C C15 0.4418(12) 0.4456(8) 0.3973(8) 0.0187(9) Uani d . 1
H H15 0.5293 0.4887 0.4481 0.022 Uiso calc R 1
C C16 0.3147(17) 0.1304(9) 0.3282(10) 0.0195(8) Uani d . 1
C C17 0.1851(14) 0.0643(8) 0.3097(8) 0.0195(8) Uani d . 1
H H17 0.0932 0.1026 0.2994 0.023 Uiso calc R 1
C C18 0.1906(14) -0.0575(9) 0.3065(9) 0.0195(8) Uani d . 1
H H18 0.1022 -0.1013 0.2961 0.023 Uiso calc R 1
C C19 0.4419(14) -0.0519(9) 0.3347(8) 0.0195(8) Uani d . 1
H H19 0.5313 -0.0915 0.3419 0.023 Uiso calc R 1
C C20 0.4457(14) 0.0699(9) 0.3421(8) 0.0195(8) Uani d . 1
H H20 0.5374 0.1118 0.3567 0.023 Uiso calc R 1
C C21 0.7604(12) 0.7098(9) 0.4568(8) 0.025(2) Uani d . 1
H H21A 0.7909 0.7859 0.4391 0.030 Uiso calc R 1
H H21B 0.8496 0.6548 0.4824 0.030 Uiso calc R 1
C C22 0.7126(11) 0.7274(9) 0.5402(8) 0.026(2) Uani d . 1
H H22A 0.6100 0.7670 0.5084 0.032 Uiso calc R 1
H H22B 0.7029 0.6499 0.5674 0.032 Uiso calc R 1
C C23 0.8862(12) 0.3409(9) 0.3456(8) 0.025(2) Uani d . 1
H H23A 0.8087 0.3912 0.2883 0.031 Uiso calc R 1
H H23B 0.9911 0.3641 0.3591 0.031 Uiso calc R 1
C C24 0.8755(12) 0.3593(10) 0.4433(8) 0.031(2) Uani d . 1
H H24A 0.8691 0.4447 0.4545 0.037 Uiso calc R 1
H H24B 0.7797 0.3215 0.4348 0.037 Uiso calc R 1
Ag Ag1 0.31571(7) 0.67717(6) 0.08137(5) 0.0250(2) Uani d . 1
Ag Ag2 0.32234(7) 0.69514(6) 0.31672(5) 0.0252(2) Uani d . 1
F F1 0.8630(9) 0.1899(5) 0.7792(6) 0.0310(18) Uani d . 1
F F2 0.6398(10) 0.3172(5) 0.6862(7) 0.0286(19) Uani d . 1
F F3 0.8883(7) 0.3948(6) 0.8089(5) 0.0295(15) Uani d . 1
F F4 0.7830(7) 0.4288(5) 0.6245(5) 0.0327(15) Uani d . 1
F F5 1.0031(9) 0.3017(5) 0.7160(7) 0.0264(18) Uani d . 1
F F6 0.7554(8) 0.2208(6) 0.5960(5) 0.0280(15) Uani d . 1
N N1 0.3239(18) 0.4888(7) 0.0774(12) 0.0202(9) Uani d . 1
N N2 0.3228(15) -0.1369(6) 0.0780(10) 0.0168(9) Uani d . 1
N N3 0.3154(19) 0.5053(8) 0.3223(12) 0.0187(9) Uani d . 1
N N4 0.3174(16) -0.1168(7) 0.3176(11) 0.0195(8) Uani d . 1
O O1 0.6288(12) 0.6626(8) 0.3677(7) 0.034(2) Uani d . 1
H H1A 0.6368 0.6743 0.3139 0.051 Uiso calc R 1
O O2 0.8268(8) 0.7978(6) 0.6253(5) 0.0332(18) Uani d . 1
H H2A 0.8449 0.7683 0.6830 0.050 Uiso calc R 1
O O3 0.8582(10) 0.2200(6) 0.3141(6) 0.037(2) Uani d . 1
H H3 0.8038 0.1890 0.3371 0.055 Uiso calc R 1
O O4 1.0060(12) 0.3112(6) 0.5313(8) 0.035(2) Uani d . 1
H H4A 1.0499 0.3636 0.5772 0.052 Uiso calc R 1
O O5 0.7885(10) -0.0030(7) 0.8606(7) 0.035(2) Uani d D 1
H H1O 0.804(13) 0.054(8) 0.831(8) 0.052 Uiso d D 1
H H2O 0.873(7) -0.006(9) 0.917(5) 0.052 Uiso d D 1
O O6 0.8472(13) 0.0089(7) 0.5633(8) 0.042(3) Uani d D 1
H H3O 0.817(14) 0.062(7) 0.590(9) 0.064 Uiso d D 1
H H4O 0.810(15) -0.054(6) 0.575(11) 0.064 Uiso d D 1
Si Si1 0.8215(6) 0.3115(2) 0.7020(4) 0.0178(4) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N1 C1 C2 . . 123.7(10) ?
N1 C1 H1 . . 118.1 ?
C2 C1 H1 . . 118.1 ?
C1 C2 C3 . . 118.5(10) ?
C1 C2 H2 . . 120.8 ?
C3 C2 H2 . . 120.8 ?
C4 C3 C2 . . 116.9(8) ?
C4 C3 C6 . . 123.7(9) ?
C2 C3 C6 . . 119.4(9) ?
C5 C4 C3 . . 121.6(10) ?
C5 C4 H4 . . 119.2 ?
C3 C4 H4 . . 119.2 ?
N1 C5 C4 . . 121.4(10) ?
N1 C5 H5 . . 119.3 ?
C4 C5 H5 . . 119.3 ?
C10 C6 C7 . . 117.8(8) ?
C10 C6 C3 . . 121.5(9) ?
C7 C6 C3 . . 120.7(9) ?
C8 C7 C6 . . 119.6(9) ?
C8 C7 H7 . . 120.2 ?
C6 C7 H7 . . 120.2 ?
N2 C8 C7 . . 123.0(9) ?
N2 C8 H8 . . 118.5 ?
C7 C8 H8 . . 118.5 ?
N2 C9 C10 . . 124.1(9) ?
N2 C9 H9 . . 117.9 ?
C10 C9 H9 . . 117.9 ?
C9 C10 C6 . . 119.0(9) ?
C9 C10 H10 . . 120.5 ?
C6 C10 H10 . . 120.5 ?
N3 C11 C12 . . 123.5(10) ?
N3 C11 H11 . . 118.3 ?
C12 C11 H11 . . 118.3 ?
C11 C12 C13 . . 118.4(9) ?
C11 C12 H12 . . 120.8 ?
C13 C12 H12 . . 120.8 ?
C14 C13 C12 . . 117.7(8) ?
C14 C13 C16 . . 121.5(9) ?
C12 C13 C16 . . 120.8(9) ?
C15 C14 C13 . . 119.7(9) ?
C15 C14 H14 . . 120.1 ?
C13 C14 H14 . . 120.1 ?
N3 C15 C14 . . 121.3(9) ?
N3 C15 H15 . . 119.3 ?
C14 C15 H15 . . 119.3 ?
C20 C16 C17 . . 117.7(9) ?
C20 C16 C13 . . 119.8(10) ?
C17 C16 C13 . . 122.5(10) ?
C18 C17 C16 . . 119.8(10) ?
C18 C17 H17 . . 120.1 ?
C16 C17 H17 . . 120.1 ?
N4 C18 C17 . . 122.6(9) ?
N4 C18 H18 . . 118.7 ?
C17 C18 H18 . . 118.7 ?
N4 C19 C20 . . 123.1(10) ?
N4 C19 H19 . . 118.4 ?
C20 C19 H19 . . 118.4 ?
C19 C20 C16 . . 119.7(10) ?
C19 C20 H20 . . 120.2 ?
C16 C20 H20 . . 120.2 ?
O1 C21 C22 . . 106.2(9) ?
O1 C21 H21A . . 110.5 ?
C22 C21 H21A . . 110.5 ?
O1 C21 H21B . . 110.5 ?
C22 C21 H21B . . 110.5 ?
H21A C21 H21B . . 108.7 ?
O2 C22 C21 . . 110.1(8) ?
O2 C22 H22A . . 109.6 ?
C21 C22 H22A . . 109.6 ?
O2 C22 H22B . . 109.6 ?
C21 C22 H22B . . 109.6 ?
H22A C22 H22B . . 108.2 ?
O3 C23 C24 . . 110.3(8) ?
O3 C23 H23A . . 109.6 ?
C24 C23 H23A . . 109.6 ?
O3 C23 H23B . . 109.6 ?
C24 C23 H23B . . 109.6 ?
H23A C23 H23B . . 108.1 ?
O4 C24 C23 . . 110.6(9) ?
O4 C24 H24A . . 109.5 ?
C23 C24 H24A . . 109.5 ?
O4 C24 H24B . . 109.5 ?
C23 C24 H24B . . 109.5 ?
H24A C24 H24B . . 108.1 ?
N2 Ag1 N1 1_565 . 174.0(7) y
N4 Ag2 N3 1_565 . 175.1(7) y
C1 N1 C5 . . 117.8(7) ?
C1 N1 Ag1 . . 120.9(9) ?
C5 N1 Ag1 . . 121.1(9) ?
C9 N2 C8 . . 116.4(7) ?
C9 N2 Ag1 . 1_545 123.1(8) ?
C8 N2 Ag1 . 1_545 120.5(8) ?
C11 N3 C15 . . 118.6(8) ?
C11 N3 Ag2 . . 121.6(10) ?
C15 N3 Ag2 . . 119.4(9) ?
C19 N4 C18 . . 117.1(8) ?
C19 N4 Ag2 . 1_545 121.7(9) ?
C18 N4 Ag2 . 1_545 121.1(8) ?
C21 O1 H1A . . 109.5 ?
C22 O2 H2A . . 109.5 ?
C23 O3 H3 . . 109.5 ?
C24 O4 H4A . . 109.5 ?
H1O O5 H2O . . 101(6) ?
H3O O6 H4O . . 102(13) ?
F3 Si1 F4 . . 92.1(3) ?
F3 Si1 F2 . . 90.3(4) ?
F4 Si1 F2 . . 90.4(4) ?
F3 Si1 F6 . . 177.4(4) ?
F4 Si1 F6 . . 90.5(4) ?
F2 Si1 F6 . . 89.8(4) ?
F3 Si1 F1 . . 89.1(4) ?
F4 Si1 F1 . . 178.4(6) ?
F2 Si1 F1 . . 90.7(4) ?
F6 Si1 F1 . . 88.4(3) ?
F3 Si1 F5 . . 91.2(4) ?
F4 Si1 F5 . . 90.3(4) ?
F2 Si1 F5 . . 178.3(4) ?
F6 Si1 F5 . . 88.7(4) ?
F1 Si1 F5 . . 88.5(4) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 N1 . 1.327(17) ?
C1 C2 . 1.400(13) ?
C1 H1 . 0.9500 ?
C2 C3 . 1.408(15) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.381(16) ?
C3 C6 . 1.482(13) ?
C4 C5 . 1.377(13) ?
C4 H4 . 0.9500 ?
C5 N1 . 1.365(16) ?
C5 H5 . 0.9500 ?
C6 C10 . 1.393(15) ?
C6 C7 . 1.403(16) ?
C7 C8 . 1.375(13) ?
C7 H7 . 0.9500 ?
C8 N2 . 1.359(15) ?
C8 H8 . 0.9500 ?
C9 N2 . 1.356(15) ?
C9 C10 . 1.371(13) ?
C9 H9 . 0.9500 ?
C10 H10 . 0.9500 ?
C11 N3 . 1.306(17) ?
C11 C12 . 1.388(12) ?
C11 H11 . 0.9500 ?
C12 C13 . 1.407(16) ?
C12 H12 . 0.9500 ?
C13 C14 . 1.395(15) ?
C13 C16 . 1.474(13) ?
C14 C15 . 1.380(12) ?
C14 H14 . 0.9500 ?
C15 N3 . 1.366(17) ?
C15 H15 . 0.9500 ?
C16 C20 . 1.389(17) ?
C16 C17 . 1.391(16) ?
C17 C18 . 1.385(14) ?
C17 H17 . 0.9500 ?
C18 N4 . 1.360(16) ?
C18 H18 . 0.9500 ?
C19 N4 . 1.347(15) ?
C19 C20 . 1.385(14) ?
C19 H19 . 0.9500 ?
C20 H20 . 0.9500 ?
C21 O1 . 1.414(13) ?
C21 C22 . 1.525(14) ?
C21 H21A . 0.9900 ?
C21 H21B . 0.9900 ?
C22 O2 . 1.439(11) ?
C22 H22A . 0.9900 ?
C22 H22B . 0.9900 ?
C23 O3 . 1.430(11) ?
C23 C24 . 1.500(14) ?
C23 H23A . 0.9900 ?
C23 H23B . 0.9900 ?
C24 O4 . 1.406(14) ?
C24 H24A . 0.9900 ?
C24 H24B . 0.9900 ?
Ag1 N1 . 2.141(9) y
Ag1 N2 1_565 2.113(7) y
Ag2 N3 . 2.159(9) y
Ag2 N4 1_565 2.135(8) y
F1 Si1 . 1.699(7) ?
F2 Si1 . 1.697(10) ?
F3 Si1 . 1.659(8) ?
F4 Si1 . 1.666(7) ?
F5 Si1 . 1.707(10) ?
F6 Si1 . 1.698(8) ?
O1 H1A . 0.8400 ?
O2 H2A . 0.8400 ?
O3 H3 . 0.8400 ?
O4 H4A . 0.8400 ?
O5 H1O . 0.83(11) ?
O5 H2O . 0.84(7) ?
O6 H3O . 0.85(11) ?
O6 H4O . 0.86(10) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O1 H1A F2 2_564 0.84 1.89 2.721(14) 173 yes
O2 H2A O3 2_565 0.84 1.86 2.630(11) 151 yes
O3 H3 O5 2_554 0.84 2.16 2.733(11) 126 yes
O4 H4A F5 . 0.84 2.40 2.719(14) 103 yes
O5 H1O F1 . 0.83(11) 1.93(10) 2.761(11) 173(11) yes
O6 H3O F6 . 0.85(11) 1.92(9) 2.696(12) 152(10) yes
O6 H4O O2 1_545 0.86(10) 1.81(8) 2.605(11) 153(14) yes
C23 H23A F3 2_564 0.99 2.52 3.049(12) 113 yes
C1 H1 F3 1_454 0.95 2.38 3.052(13) 127 yes
C8 H8 O4 2_454 0.95 2.42 3.208(14) 140 yes
C9 H9 F2 2_554 0.95 2.46 3.199(12) 134 yes
C9 H9 F6 2_554 0.95 2.52 3.437(16) 161 yes
C11 H11 F5 2_464 0.95 2.54 3.280(12) 135 yes
C12 H12 O2 2_464 0.95 2.43 3.349(16) 164 yes
C14 H14 F6 . 0.95 2.27 3.204(14) 168 yes
C18 H18 F1 2_454 0.95 2.47 3.410(17) 172 yes
C18 H18 F5 2_454 0.95 2.52 3.231(13) 131 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
N1 C1 C2 C3 . 3.0(19) ?
C1 C2 C3 C4 . -1.3(18) ?
C1 C2 C3 C6 . 177.2(10) ?
C2 C3 C4 C5 . 0.6(18) ?
C6 C3 C4 C5 . -177.8(10) ?
C3 C4 C5 N1 . -1.3(18) ?
C4 C3 C6 C10 . -36.2(17) ?
C2 C3 C6 C10 . 145.5(12) ?
C4 C3 C6 C7 . 141.1(13) ?
C2 C3 C6 C7 . -37.3(17) y
C10 C6 C7 C8 . -0.5(17) ?
C3 C6 C7 C8 . -177.8(9) ?
C6 C7 C8 N2 . -0.4(15) ?
N2 C9 C10 C6 . -0.2(15) ?
C7 C6 C10 C9 . 0.7(16) ?
C3 C6 C10 C9 . 178.1(9) ?
N3 C11 C12 C13 . 4.1(17) ?
C11 C12 C13 C14 . 3.2(16) ?
C11 C12 C13 C16 . -179.0(10) ?
C12 C13 C14 C15 . -3.9(17) ?
C16 C13 C14 C15 . 178.4(11) ?
C13 C14 C15 N3 . -2.4(18) ?
C14 C13 C16 C20 . -41.0(17) ?
C12 C13 C16 C20 . 141.4(12) ?
C14 C13 C16 C17 . 141.6(13) ?
C12 C13 C16 C17 . -36.1(17) y
C20 C16 C17 C18 . 0.4(16) ?
C13 C16 C17 C18 . 177.9(10) ?
C16 C17 C18 N4 . -2.0(15) ?
N4 C19 C20 C16 . -2.2(15) ?
C17 C16 C20 C19 . 1.6(17) ?
C13 C16 C20 C19 . -175.9(9) ?
O1 C21 C22 O2 . -167.9(8) ?
O3 C23 C24 O4 . 73.0(11) ?
C2 C1 N1 C5 . -4(2) ?
C2 C1 N1 Ag1 . -179.4(9) ?
C4 C5 N1 C1 . 3(2) ?
C4 C5 N1 Ag1 . 178.5(9) ?
C10 C9 N2 C8 . -0.6(18) ?
C10 C9 N2 Ag1 1_545 -179.2(8) ?
C7 C8 N2 C9 . 0.9(17) ?
C7 C8 N2 Ag1 1_545 179.5(8) ?
C12 C11 N3 C15 . -10.5(19) ?
C12 C11 N3 Ag2 . 176.3(9) ?
C14 C15 N3 C11 . 10(2) ?
C14 C15 N3 Ag2 . -177.1(9) ?
C20 C19 N4 C18 . 0.6(18) ?
C20 C19 N4 Ag2 1_545 -175.9(8) ?
C17 C18 N4 C19 . 1.5(18) ?
C17 C18 N4 Ag2 1_545 178.1(8) ?
