#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/15/2211502.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2211502
loop_
_publ_author_name
'Clausen, Henrik F.'
'Overgaard, Jacob'
'Poulsen, Rasmus D.'
'Morgenroth, Wolfgang'
'Iversen, Bo B.'
_publ_section_title
;An Eu-based metal--organic framework:
 poly[[tris(μ₄-benzene-1,4-dicarboxylato)bis(μ₂-N,N-diethylformamide)dieuropium(III)]
 0.7-hydrate]
;
_journal_coeditor_code           LH2226
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m3333
_journal_page_last               m3335
_journal_paper_doi               10.1107/S1600536806047143
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Eu2 (C8 H4 O4)3 (C5 H11 N O)2], 0.7H2 O'
_chemical_formula_moiety         'C17 H17 Eu N O7, 0.35 H2O'
_chemical_formula_sum            'C17 H17.7 Eu N O7.35'
_chemical_formula_weight         505.08
_chemical_name_systematic
;
poly[[tris(μ₄-benzene-1,4-dicarboxylato)bis(μ₂-N,N-
diethylformamide)dieuropium(III)] 0.7-hydrate]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.91(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   18.010(7)
_cell_length_b                   11.478(7)
_cell_length_c                   18.743(12)
_cell_measurement_reflns_used    57266
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      38.83
_cell_measurement_theta_min      1.73
_cell_volume                     3665(4)
_computing_cell_refinement       XDS2004
_computing_data_collection       'program (reference)?'
_computing_data_reduction        'XDS2004 (Kabsch, 1993)'
_computing_molecular_graphics    'XSHELL (Version 4.02)'
_computing_publication_material
'enCIFer (Version 1.2; Allen et al.,  2004)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 12.65
_diffrn_measured_fraction_theta_full 0.975
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Huber four-circle'
_diffrn_measurement_method       φ
_diffrn_radiation_monochromator  'double crystal Si 111 monochr'
_diffrn_radiation_source         'D3, Hasylab, Hamburg'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.55000
_diffrn_reflns_av_R_equivalents  0.126
_diffrn_reflns_av_sigmaI/netI    0.0353
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_number            424451
_diffrn_reflns_reduction_process
;
Scaled and merged with XSCALE
W.J. Kabsch, (1993) J. Appl. Cryst. 26, 795-800
;
_diffrn_reflns_theta_full        38.81
_diffrn_reflns_theta_max         38.81
_diffrn_reflns_theta_min         1.73
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.626
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details
;
;
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.831
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rectuangular
_exptl_crystal_F_000             1982
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.075
_refine_diff_density_max         3.467
_refine_diff_density_min         -3.257
_refine_ls_extinction_coef       0.00453(17)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL97
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     288
_refine_ls_number_reflns         22159
_refine_ls_number_restraints     13
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0445
_refine_ls_R_factor_gt           0.0366
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0449P)²+7.3908P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0865
_refine_ls_wR_factor_ref         0.0899
_reflns_number_gt                19344
_reflns_number_total             22159
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            lh2226.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2211502
_cod_database_fobs_code          2211502
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu1 0.498091(3) 0.058967(4) 0.898036(3) 0.006960(10) Uani d . 1 . .
O O1 0.40982(7) 0.05628(11) 0.77564(6) 0.01829(19) Uani d . 1 . .
O O2 0.58662(5) 0.01120(9) 0.83855(5) 0.01167(11) Uani d . 1 . .
O O8 0.56978(8) 0.17803(12) 0.99946(6) 0.0222(2) Uani d . 1 . .
O O9 0.42636(12) -0.11407(17) 0.88661(7) 0.0408(5) Uani d . 1 . .
O O11 0.39304(7) 0.18172(11) 0.90617(6) 0.01712(16) Uani d . 1 . .
O O12 0.42060(7) 0.06532(11) 1.00488(8) 0.0209(2) Uani d . 1 . .
O O15 0.52735(8) 0.24314(10) 0.84810(7) 0.01913(17) Uani d . 1 . .
N N15 0.55747(17) 0.43506(14) 0.86723(17) 0.0381(5) Uani d D 1 . .
C C1 0.38204(6) 0.05873(10) 0.70580(6) 0.01068(13) Uani d . 1 . .
C C2 0.80553(7) 0.37928(11) 1.17100(6) 0.01217(14) Uani d . 1 . .
C C3 0.77018(9) 0.32070(15) 1.21686(7) 0.0185(2) Uani d . 1 . .
H H3 0.7924 0.3242 1.2690 0.022 Uiso calc R 1 . .
C C4 0.70182(12) 0.25721(18) 1.18462(7) 0.0256(4) Uani d . 1 . .
H H4 0.6785 0.2180 1.2152 0.031 Uiso calc R 1 . .
C C5 0.66815(11) 0.25224(15) 1.10620(7) 0.0222(3) Uani d . 1 . .
C C6 0.70235(9) 0.31309(13) 1.06052(7) 0.0182(2) Uani d . 1 . .
H H6 0.6791 0.3116 1.0084 0.022 Uiso calc R 1 . .
C C7 0.77102(8) 0.37592(13) 1.09267(6) 0.01507(18) Uani d . 1 . .
H H7 0.7940 0.4158 1.0620 0.018 Uiso calc R 1 . .
C C8 0.59804(13) 0.17659(17) 1.07025(8) 0.0267(4) Uani d . 1 . .
C C11 0.37941(7) 0.14514(13) 0.96395(8) 0.01517(18) Uani d . 1 . .
C C12 0.31243(8) 0.19848(13) 0.98321(8) 0.01555(19) Uani d . 1 . .
C C13 0.30288(9) 0.17871(14) 1.05310(8) 0.0187(2) Uani d . 1 . .
H H13 0.3381 0.1314 1.0885 0.022 Uiso calc R 1 . .
C C14 0.25960(9) 0.26990(15) 0.93044(8) 0.0204(3) Uani d . 1 . .
H H14 0.2662 0.2832 0.8839 0.024 Uiso calc R 1 . .
C C15 0.5187(2) 0.33910(18) 0.8711(2) 0.0492(9) Uani d . 1 A .
H H15 0.4804 0.3459 0.8942 0.059 Uiso calc R 1 . .
C C16A 0.6342(3) 0.4262(4) 0.8584(4) 0.0350(10) Uani d PD 0.475(3) A 2
H H16A 0.6457 0.3446 0.8534 0.042 Uiso calc PR 0.475(3) A 2
H H16B 0.6731 0.4555 0.9038 0.042 Uiso calc PR 0.475(3) A 2
C C18A 0.6420(7) 0.4906(12) 0.7926(7) 0.086(4) Uani d PD 0.475(3) A 2
H H18A 0.6102 0.4539 0.7469 0.129 Uiso calc PR 0.475(3) A 2
H H18B 0.6959 0.4899 0.7944 0.129 Uiso calc PR 0.475(3) A 2
H H18C 0.6250 0.5696 0.7939 0.129 Uiso calc PR 0.475(3) A 2
C C16B 0.6014(3) 0.4414(3) 0.8133(3) 0.0299(8) Uani d PD 0.525(3) A 3
H H16C 0.5774 0.5005 0.7760 0.036 Uiso calc PR 0.525(3) A 3
H H16D 0.5959 0.3674 0.7871 0.036 Uiso calc PR 0.525(3) A 3
C C18B 0.6870(4) 0.4684(8) 0.8469(6) 0.060(2) Uani d PD 0.525(3) A 3
H H18D 0.6934 0.5436 0.8706 0.089 Uiso calc PR 0.525(3) A 3
H H18E 0.7108 0.4686 0.8079 0.089 Uiso calc PR 0.525(3) A 3
H H18F 0.7118 0.4103 0.8838 0.089 Uiso calc PR 0.525(3) A 3
C C17A 0.5233(3) 0.5452(3) 0.8816(3) 0.0303(9) Uani d PD 0.475(3) A 4
H H17A 0.4677 0.5358 0.8740 0.036 Uiso calc PR 0.475(3) A 4
H H17B 0.5298 0.6057 0.8480 0.036 Uiso calc PR 0.475(3) A 4
C C19A 0.5668(4) 0.5764(6) 0.9623(4) 0.052(2) Uani d PD 0.475(3) A 4
H H19A 0.5619 0.5140 0.9946 0.078 Uiso calc PR 0.475(3) A 4
H H19B 0.5450 0.6463 0.9754 0.078 Uiso calc PR 0.475(3) A 4
H H19C 0.6212 0.5887 0.9684 0.078 Uiso calc PR 0.475(3) A 4
C C17B 0.5679(4) 0.5393(4) 0.9200(5) 0.0542(19) Uani d PD 0.525(3) A 5
H H17C 0.5557 0.5166 0.9648 0.065 Uiso calc PR 0.525(3) A 5
H H17D 0.6220 0.5653 0.9355 0.065 Uiso calc PR 0.525(3) A 5
C C19B 0.5152(6) 0.6364(6) 0.8812(8) 0.113(5) Uani d PD 0.525(3) A 5
H H19D 0.5272 0.6585 0.8368 0.169 Uiso calc PR 0.525(3) A 5
H H19E 0.5228 0.7019 0.9146 0.169 Uiso calc PR 0.525(3) A 5
H H19F 0.4615 0.6112 0.8672 0.169 Uiso calc PR 0.525(3) A 5
O O99 0.4752(5) 0.7751(5) 0.7560(4) 0.047(2) Uani d P 0.350(8) . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0015 0.0009 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0030 0.0019 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0056 0.0036 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.3977 2.4351 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O2 Eu1 O1 . . 82.99(5)
O2 Eu1 O9 . . 101.72(7)
O1 Eu1 O9 . . 73.65(5)
O2 Eu1 O8 . . 104.23(6)
O1 Eu1 O8 . . 145.32(5)
O9 Eu1 O8 . . 135.02(5)
O2 Eu1 O12 . 5_657 82.92(5)
O1 Eu1 O12 . 5_657 142.42(5)
O9 Eu1 O12 . 5_657 75.41(7)
O8 Eu1 O12 . 5_657 72.13(7)
O2 Eu1 O11 . . 149.14(4)
O1 Eu1 O11 . . 76.72(5)
O9 Eu1 O11 . . 94.63(8)
O8 Eu1 O11 . . 81.12(6)
O12 Eu1 O11 5_657 . 126.85(5)
O2 Eu1 O15 . . 75.48(5)
O1 Eu1 O15 . . 78.28(5)
O9 Eu1 O15 . . 151.91(5)
O8 Eu1 O15 . . 71.14(6)
O12 Eu1 O15 5_657 . 130.67(5)
O11 Eu1 O15 . . 77.79(5)
O2 Eu1 O12 . . 161.08(3)
O1 Eu1 O12 . . 111.53(6)
O9 Eu1 O12 . . 72.42(6)
O8 Eu1 O12 . . 71.12(6)
O12 Eu1 O12 5_657 . 78.20(5)
O11 Eu1 O12 . . 49.57(4)
O15 Eu1 O12 . . 118.29(4)
O2 Eu1 C11 . . 173.39(3)
O1 Eu1 C11 . . 93.48(6)
O9 Eu1 C11 . . 82.54(7)
O8 Eu1 C11 . . 75.57(6)
O12 Eu1 C11 5_657 . 103.15(5)
O11 Eu1 C11 . . 24.35(4)
O15 Eu1 C11 . . 98.37(5)
O12 Eu1 C11 . . 25.24(3)
O2 Eu1 Eu1 . 5_657 125.49(4)
O1 Eu1 Eu1 . 5_657 136.48(4)
O9 Eu1 Eu1 . 5_657 68.99(4)
O8 Eu1 Eu1 . 5_657 66.04(5)
O12 Eu1 Eu1 5_657 5_657 42.57(4)
O11 Eu1 Eu1 . 5_657 84.76(4)
O15 Eu1 Eu1 . 5_657 135.67(3)
O12 Eu1 Eu1 . 5_657 35.63(3)
C11 Eu1 Eu1 . 5_657 60.67(4)
C1 O1 Eu1 . . 162.10(10)
C1 O2 Eu1 2_656 . 138.06(9)
C8 O8 Eu1 . . 140.50(11)
C8 O9 Eu1 5_657 . 136.09(11)
C11 O11 Eu1 . . 103.67(8)
C11 O12 Eu1 . 5_657 168.82(13)
C11 O12 Eu1 . . 85.14(9)
Eu1 O12 Eu1 5_657 . 101.80(5)
C15 O15 Eu1 . . 125.67(15)
C15 N15 C16A . . 119.3(3)
C15 N15 C17A . . 116.6(3)
C16A N15 C17A . . 123.6(3)
C15 N15 C16B . . 119.4(2)
C17A N15 C16B . . 115.7(3)
C15 N15 C17B . . 125.2(4)
C16A N15 C17B . . 102.0(4)
C16B N15 C17B . . 115.2(4)
O1 C1 O2 . 2_656 124.61(12)
O1 C1 C2 . 8_455 117.99(11)
O2 C1 C2 2_656 8_455 117.40(10)
C3 C2 C7 . . 119.81(11)
C3 C2 C1 . 8_556 119.91(10)
C7 C2 C1 . 8_556 120.23(11)
C4 C3 C2 . . 120.09(12)
C4 C3 H3 . . 120.0
C2 C3 H3 . . 120.0
C3 C4 C5 . . 120.01(13)
C3 C4 H4 . . 120.0
C5 C4 H4 . . 120.0
C6 C5 C4 . . 119.87(13)
C6 C5 C8 . . 119.30(12)
C4 C5 C8 . . 120.74(13)
C7 C6 C5 . . 120.16(12)
C7 C6 H6 . . 119.9
C5 C6 H6 . . 119.9
C6 C7 C2 . . 120.03(12)
C6 C7 H7 . . 120.0
C2 C7 H7 . . 120.0
O8 C8 O9 . 5_657 125.27(14)
O8 C8 C5 . . 117.40(13)
O9 C8 C5 5_657 . 117.29(13)
O11 C11 O12 . . 121.52(11)
O11 C11 C12 . . 117.92(11)
O12 C11 C12 . . 120.56(12)
O11 C11 Eu1 . . 51.98(7)
O12 C11 Eu1 . . 69.62(8)
C12 C11 Eu1 . . 169.41(9)
C13 C12 C14 . . 119.90(11)
C13 C12 C11 . . 120.95(11)
C14 C12 C11 . . 119.15(11)
C14 C13 C12 7_557 . 119.64(11)
C14 C13 H13 7_557 . 120.2
C12 C13 H13 . . 120.2
C13 C14 C12 7_557 . 120.46(12)
C13 C14 H14 7_557 . 119.8
C12 C14 H14 . . 119.8
O15 C15 N15 . . 127.5(2)
O15 C15 H15 . . 116.3
N15 C15 H15 . . 116.3
N15 C16A C18A . . 114.3(6)
N15 C16A H16A . . 108.7
C18A C16A H16A . . 108.7
N15 C16A H16B . . 108.7
C18A C16A H16B . . 108.7
H16A C16A H16B . . 107.6
C16A C18A H18A . . 109.5
C16A C18A H18B . . 109.5
H18A C18A H18B . . 109.5
C16A C18A H18C . . 109.5
H18A C18A H18C . . 109.5
H18B C18A H18C . . 109.5
N15 C16B C18B . . 115.5(5)
N15 C16B H16C . . 108.4
C18B C16B H16C . . 108.4
N15 C16B H16D . . 108.4
C18B C16B H16D . . 108.4
H16C C16B H16D . . 107.5
N15 C17A C19A . . 106.1(4)
N15 C17A H17A . . 110.5
C19A C17A H17A . . 110.5
N15 C17A H17B . . 110.5
C19A C17A H17B . . 110.5
H17A C17A H17B . . 108.7
C19B C17B N15 . . 110.2(6)
C19B C17B H17C . . 109.6
N15 C17B H17C . . 109.6
C19B C17B H17D . . 109.6
N15 C17B H17D . . 109.6
H17C C17B H17D . . 108.1
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Eu1 O2 . 2.2888(12)
Eu1 O1 . 2.3295(18)
Eu1 O9 . 2.3410(17)
Eu1 O8 . 2.3574(15)
Eu1 O12 5_657 2.4007(15)
Eu1 O11 . 2.4031(12)
Eu1 O15 . 2.4376(16)
Eu1 O12 . 2.7884(18)
Eu1 Eu1 5_657 4.034(2)
O1 C1 . 1.2410(17)
O2 C1 2_656 1.2694(15)
O8 C8 . 1.2577(19)
O9 C8 5_657 1.262(2)
O11 C11 . 1.2576(17)
O12 C11 . 1.2686(16)
O15 C15 . 1.211(3)
N15 C15 . 1.318(3)
N15 C16A . 1.448(5)
N15 C17A . 1.469(4)
N15 C16B . 1.473(5)
N15 C17B . 1.524(5)
C1 C2 8_455 1.4991(17)
C2 C3 . 1.3968(18)
C2 C7 . 1.3971(18)
C3 C4 . 1.389(2)
C3 H3 . 0.9300
C4 C5 . 1.398(2)
C4 H4 . 0.9300
C5 C6 . 1.394(2)
C5 C8 . 1.500(2)
C6 C7 . 1.3891(19)
C6 H6 . 0.9300
C7 H7 . 0.9300
C11 C12 . 1.4976(16)
C12 C13 . 1.3940(19)
C12 C14 . 1.3948(18)
C13 C14 7_557 1.3907(18)
C13 H13 . 0.9300
C14 H14 . 0.9300
C15 H15 . 0.9300
C16A C18A . 1.483(7)
C16A H16A . 0.9700
C16A H16B . 0.9700
C18A H18A . 0.9600
C18A H18B . 0.9600
C18A H18C . 0.9600
C16B C18B . 1.497(6)
C16B H16C . 0.9700
C16B H16D . 0.9700
C18B H18D . 0.9600
C18B H18E . 0.9600
C18B H18F . 0.9600
C17A C19A . 1.503(7)
C17A H17A . 0.9700
C17A H17B . 0.9700
C19A H19A . 0.9600
C19A H19B . 0.9600
C19A H19C . 0.9600
C17B C19B . 1.491(7)
C17B H17C . 0.9700
C17B H17D . 0.9700
C19B H19D . 0.9600
C19B H19E . 0.9600
C19B H19F . 0.9600
O99 O99 2_656 0.987(15)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
O2 Eu1 O1 C1 . . -20.5(3)
O9 Eu1 O1 C1 . . -124.9(3)
O8 Eu1 O1 C1 . . 84.5(3)
O12 Eu1 O1 C1 5_657 . -89.2(3)
O11 Eu1 O1 C1 . . 136.1(3)
O15 Eu1 O1 C1 . . 56.1(3)
O12 Eu1 O1 C1 . . 172.1(3)
C11 Eu1 O1 C1 . . 153.9(3)
Eu1 Eu1 O1 C1 5_657 . -156.5(3)
O1 Eu1 O2 C1 . 2_656 68.61(12)
O9 Eu1 O2 C1 . 2_656 140.24(12)
O8 Eu1 O2 C1 . 2_656 -76.84(13)
O12 Eu1 O2 C1 5_657 2_656 -146.32(12)
O11 Eu1 O2 C1 . 2_656 19.70(16)
O15 Eu1 O2 C1 . 2_656 -11.05(12)
O12 Eu1 O2 C1 . 2_656 -150.00(13)
Eu1 Eu1 O2 C1 5_657 2_656 -147.33(10)
O2 Eu1 O8 C8 . . -110.2(2)
O1 Eu1 O8 C8 . . 151.4(2)
O9 Eu1 O8 C8 . . 13.1(3)
O12 Eu1 O8 C8 5_657 . -32.7(2)
O11 Eu1 O8 C8 . . 100.8(2)
O15 Eu1 O8 C8 . . -179.2(3)
O12 Eu1 O8 C8 . . 50.6(2)
C11 Eu1 O8 C8 . . 76.6(2)
Eu1 Eu1 O8 C8 5_657 . 12.6(2)
O2 Eu1 O9 C8 . 5_657 134.0(3)
O1 Eu1 O9 C8 . 5_657 -147.0(3)
O8 Eu1 O9 C8 . 5_657 9.8(3)
O12 Eu1 O9 C8 5_657 5_657 54.6(3)
O11 Eu1 O9 C8 . 5_657 -72.3(3)
O15 Eu1 O9 C8 . 5_657 -144.9(2)
O12 Eu1 O9 C8 . 5_657 -27.4(3)
C11 Eu1 O9 C8 . 5_657 -51.1(3)
Eu1 Eu1 O9 C8 5_657 5_657 10.3(3)
O2 Eu1 O11 C11 . . -177.47(9)
O1 Eu1 O11 C11 . . 132.31(12)
O9 Eu1 O11 C11 . . 60.32(11)
O8 Eu1 O11 C11 . . -74.56(12)
O12 Eu1 O11 C11 5_657 . -14.90(13)
O15 Eu1 O11 C11 . . -147.05(11)
O12 Eu1 O11 C11 . . -1.84(10)
Eu1 Eu1 O11 C11 5_657 . -8.04(10)
O2 Eu1 O12 C11 . . 174.86(11)
O1 Eu1 O12 C11 . . -46.88(12)
O9 Eu1 O12 C11 . . -110.63(13)
O8 Eu1 O12 C11 . . 96.19(12)
O12 Eu1 O12 C11 5_657 . 171.13(14)
O11 Eu1 O12 C11 . . 1.78(10)
O15 Eu1 O12 C11 . . 41.07(12)
Eu1 Eu1 O12 C11 5_657 . 171.13(14)
O2 Eu1 O12 Eu1 . 5_657 3.73(16)
O1 Eu1 O12 Eu1 . 5_657 141.99(6)
O9 Eu1 O12 Eu1 . 5_657 78.24(8)
O8 Eu1 O12 Eu1 . 5_657 -74.94(8)
O12 Eu1 O12 Eu1 5_657 5_657 0.0
O11 Eu1 O12 Eu1 . 5_657 -169.35(8)
O15 Eu1 O12 Eu1 . 5_657 -130.06(5)
C11 Eu1 O12 Eu1 . 5_657 -171.13(14)
O2 Eu1 O15 C15 . . -157.7(3)
O1 Eu1 O15 C15 . . 116.6(3)
O9 Eu1 O15 C15 . . 114.6(3)
O8 Eu1 O15 C15 . . -46.8(3)
O12 Eu1 O15 C15 5_657 . -90.7(3)
O11 Eu1 O15 C15 . . 37.9(3)
O12 Eu1 O15 C15 . . 8.3(3)
C11 Eu1 O15 C15 . . 24.7(3)
Eu1 Eu1 O15 C15 5_657 . -31.3(3)
Eu1 O1 C1 O2 . 2_656 39.1(4)
Eu1 O1 C1 C2 . 8_455 -141.8(3)
C7 C2 C3 C4 . . 1.4(3)
C1 C2 C3 C4 8_556 . -176.05(17)
C2 C3 C4 C5 . . -0.2(3)
C3 C4 C5 C6 . . -1.4(3)
C3 C4 C5 C8 . . 175.1(2)
C4 C5 C6 C7 . . 1.8(3)
C8 C5 C6 C7 . . -174.71(18)
C5 C6 C7 C2 . . -0.7(3)
C3 C2 C7 C6 . . -0.9(2)
C1 C2 C7 C6 8_556 . 176.51(14)
Eu1 O8 C8 O9 . 5_657 -24.6(4)
Eu1 O8 C8 C5 . . 153.16(16)
C6 C5 C8 O8 . . -4.9(3)
C4 C5 C8 O8 . . 178.6(2)
C6 C5 C8 O9 . 5_657 173.1(2)
C4 C5 C8 O9 . 5_657 -3.4(4)
Eu1 O11 C11 O12 . . 3.61(19)
Eu1 O11 C11 C12 . . -176.16(12)
Eu1 O12 C11 O11 5_657 . 125.9(5)
Eu1 O12 C11 O11 . . -3.03(16)
Eu1 O12 C11 C12 5_657 . -54.4(6)
Eu1 O12 C11 C12 . . 176.73(14)
Eu1 O12 C11 Eu1 5_657 . 128.9(6)
O1 Eu1 C11 O11 . . -46.15(11)
O9 Eu1 C11 O11 . . -119.14(12)
O8 Eu1 C11 O11 . . 100.47(12)
O12 Eu1 C11 O11 5_657 . 167.80(11)
O15 Eu1 C11 O11 . . 32.50(11)
O12 Eu1 C11 O11 . . 176.72(17)
Eu1 Eu1 C11 O11 5_657 . 170.81(12)
O1 Eu1 C11 O12 . . 137.13(11)
O9 Eu1 C11 O12 . . 64.14(12)
O8 Eu1 C11 O12 . . -76.25(11)
O12 Eu1 C11 O12 5_657 . -8.92(14)
O11 Eu1 C11 O12 . . -176.72(18)
O15 Eu1 C11 O12 . . -144.22(11)
Eu1 Eu1 C11 O12 5_657 . -5.91(9)
O1 Eu1 C11 C12 . . -27.4(6)
O9 Eu1 C11 C12 . . -100.4(6)
O8 Eu1 C11 C12 . . 119.2(6)
O12 Eu1 C11 C12 5_657 . -173.4(6)
O11 Eu1 C11 C12 . . 18.8(6)
O15 Eu1 C11 C12 . . 51.3(6)
O12 Eu1 C11 C12 . . -164.5(7)
Eu1 Eu1 C11 C12 5_657 . -170.4(6)
O11 C11 C12 C13 . . -167.81(16)
O12 C11 C12 C13 . . 12.4(3)
Eu1 C11 C12 C13 . . 175.5(5)
O11 C11 C12 C14 . . 11.5(2)
O12 C11 C12 C14 . . -168.30(17)
Eu1 C11 C12 C14 . . -5.2(7)
C14 C12 C13 C14 . 7_557 0.3(3)
C11 C12 C13 C14 . 7_557 179.55(17)
C13 C12 C14 C13 . 7_557 -0.3(3)
C11 C12 C14 C13 . 7_557 -179.56(17)
Eu1 O15 C15 N15 . . 153.1(3)
C16A N15 C15 O15 . . -22.3(7)
C17A N15 C15 O15 . . 165.0(4)
C16B N15 C15 O15 . . 18.0(6)
C17B N15 C15 O15 . . -155.7(5)
C15 N15 C16A C18A . . 125.0(8)
C17A N15 C16A C18A . . -62.9(10)
C16B N15 C16A C18A . . 24.7(8)
C17B N15 C16A C18A . . -92.4(9)
C15 N15 C16B C18B . . -123.1(5)
C16A N15 C16B C18B . . -23.0(6)
C17A N15 C16B C18B . . 89.5(6)
C17B N15 C16B C18B . . 51.2(6)
C15 N15 C17A C19A . . 98.8(6)
C16A N15 C17A C19A . . -73.5(6)
C16B N15 C17A C19A . . -113.0(5)
C17B N15 C17A C19A . . -15.3(7)
C15 N15 C17B C19B . . -104.2(8)
C16A N15 C17B C19B . . 116.2(8)
C17A N15 C17B C19B . . -17.4(8)
C16B N15 C17B C19B . . 81.9(9)
