#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/67/2216782.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2216782
loop_
_publ_author_name
'Zhao, Pei-Zheng'
'Xuan, Xiao-Peng'
'Tang, Qing-Hu'
_publ_section_title
Bis(μ-4-hydroxybenzoato-κ²O:O')bis[(2,9-dimethyl-1,10-phenanthroline-κ²N,N')(4-hydroxybenzoato-κ²O,O')lead(II)]
_journal_coeditor_code           SJ2410
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m3042
_journal_page_last               m3043
_journal_paper_doi               10.1107/S1600536807057868
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Pb2 (C7 H5 O3)4 (C14 H12 N2)2]'
_chemical_formula_moiety         'C56 H44 N4 O12 Pb2'
_chemical_formula_sum            'C56 H44 N4 O12 Pb2'
_chemical_formula_weight         1379.35
_chemical_name_systematic
;
Bis(μ-4-hydroxybenzoato-κ²O:O')bis[(2,9-dimethyl-1,10-
phenanthroline-κ²N,N')(4-hydroxybenzoato-
κ²O,O')lead(II)]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.6670(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.0539(9)
_cell_length_b                   20.9060(16)
_cell_length_c                   11.2905(9)
_cell_measurement_reflns_used    8418
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.05
_cell_measurement_theta_min      2.55
_cell_volume                     2555.2(4)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1997)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1997)'
_computing_publication_material  'SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0205
_diffrn_reflns_av_sigmaI/netI    0.0193
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            17442
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.55
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.648
_exptl_absorpt_correction_T_max  0.3960
_exptl_absorpt_correction_T_min  0.2768
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1997)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.793
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1336
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.491
_refine_diff_density_min         -0.561
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     338
_refine_ls_number_reflns         4760
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0238
_refine_ls_R_factor_gt           0.0184
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0193P)²+1.4405P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0408
_refine_ls_wR_factor_ref         0.0423
_reflns_number_gt                4180
_reflns_number_total             4760
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            sj2410.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2216782
_cod_database_fobs_code          2216782
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Pb Pb1 0.348130(9) 1.006948(4) 0.350408(8) 0.03245(3) Uani d . 1
O O1 0.20574(17) 1.10887(8) 0.32230(17) 0.0458(5) Uani d . 1
O O2 0.32361(17) 1.09044(8) 0.19066(16) 0.0407(4) Uani d . 1
O O3 0.1365(2) 1.37068(9) 0.03074(19) 0.0613(6) Uani d . 1
H H3 0.1626 1.3744 -0.0320 0.092 Uiso calc R 1
O O4 0.3130(2) 0.89345(9) 0.41329(18) 0.0572(6) Uani d . 1
O O5 0.4729(3) 0.90298(13) 0.5611(3) 0.1133(11) Uani d . 1
O O6 0.17088(18) 0.68062(9) 0.75700(18) 0.0509(5) Uani d . 1
H H6 0.2228 0.6634 0.8095 0.076 Uiso calc R 1
N N1 0.16493(18) 0.96424(9) 0.20827(18) 0.0304(5) Uani d . 1
N N2 0.40432(19) 0.95256(10) 0.17560(19) 0.0370(5) Uani d . 1
C C1 0.0516(2) 0.96366(12) 0.2313(2) 0.0381(6) Uani d . 1
C C2 -0.0479(3) 0.94005(15) 0.1465(3) 0.0536(8) Uani d . 1
H H2 -0.1265 0.9398 0.1642 0.064 Uiso calc R 1
C C3 -0.0309(3) 0.91738(15) 0.0379(3) 0.0554(8) Uani d . 1
H H3A -0.0982 0.9029 -0.0191 0.066 Uiso calc R 1
C C4 0.0881(3) 0.91577(13) 0.0120(2) 0.0427(7) Uani d . 1
C C5 0.1137(3) 0.89075(15) -0.0979(3) 0.0563(9) Uani d . 1
H H5 0.0490 0.8762 -0.1578 0.068 Uiso calc R 1
C C6 0.2297(3) 0.88786(15) -0.1160(3) 0.0571(9) Uani d . 1
H H6A 0.2441 0.8722 -0.1890 0.068 Uiso calc R 1
C C7 0.3317(3) 0.90852(13) -0.0251(2) 0.0464(7) Uani d . 1
C C8 0.4554(3) 0.90407(16) -0.0384(3) 0.0640(9) Uani d . 1
H H8 0.4740 0.8895 -0.1104 0.077 Uiso calc R 1
C C9 0.5475(3) 0.92142(18) 0.0556(3) 0.0691(10) Uani d . 1
H H9 0.6294 0.9174 0.0482 0.083 Uiso calc R 1
C C10 0.5203(3) 0.94512(16) 0.1627(3) 0.0547(8) Uani d . 1
C C11 0.3103(2) 0.93440(11) 0.0837(2) 0.0349(6) Uani d . 1
C C12 0.1850(2) 0.93923(11) 0.1022(2) 0.0334(6) Uani d . 1
C C13 0.0322(3) 0.98732(14) 0.3514(3) 0.0518(8) Uani d . 1
H H13A 0.1085 0.9846 0.4096 0.078 Uiso calc R 1
H H13B -0.0292 0.9615 0.3777 0.078 Uiso calc R 1
H H13C 0.0050 1.0310 0.3439 0.078 Uiso calc R 1
C C14 0.6209(3) 0.9627(2) 0.2687(3) 0.0871(13) Uani d . 1
H H14A 0.6186 1.0079 0.2830 0.131 Uiso calc R 1
H H14B 0.6997 0.9514 0.2516 0.131 Uiso calc R 1
H H14C 0.6085 0.9401 0.3393 0.131 Uiso calc R 1
C C15 0.2559(2) 1.12721(11) 0.2362(2) 0.0337(6) Uani d . 1
C C16 0.2293(2) 1.19281(11) 0.1859(2) 0.0327(6) Uani d . 1
C C17 0.1416(2) 1.23151(12) 0.2226(2) 0.0398(7) Uani d . 1
H H17 0.1018 1.2171 0.2827 0.048 Uiso calc R 1
C C18 0.1123(3) 1.29088(13) 0.1716(3) 0.0471(7) Uani d . 1
H H18 0.0533 1.3161 0.1973 0.057 Uiso calc R 1
C C19 0.1709(3) 1.31292(12) 0.0819(2) 0.0416(7) Uani d . 1
C C20 0.2618(3) 1.27543(13) 0.0469(3) 0.0455(7) Uani d . 1
H H20 0.3039 1.2905 -0.0110 0.055 Uiso calc R 1
C C21 0.2892(2) 1.21626(12) 0.0979(2) 0.0406(7) Uani d . 1
H H21 0.3491 1.1913 0.0730 0.049 Uiso calc R 1
C C22 0.3756(3) 0.87749(13) 0.5160(3) 0.0523(8) Uani d . 1
C C23 0.3240(2) 0.82471(12) 0.5819(2) 0.0390(6) Uani d . 1
C C24 0.3987(3) 0.78902(14) 0.6709(3) 0.0503(8) Uani d . 1
H H24 0.4828 0.7979 0.6909 0.060 Uiso calc R 1
C C25 0.3509(3) 0.74027(13) 0.7308(3) 0.0495(8) Uani d . 1
H H25 0.4027 0.7164 0.7897 0.059 Uiso calc R 1
C C26 0.2253(3) 0.72726(12) 0.7024(2) 0.0393(6) Uani d . 1
C C27 0.1495(3) 0.76263(13) 0.6135(3) 0.0450(7) Uani d . 1
H H27 0.0653 0.7539 0.5937 0.054 Uiso calc R 1
C C28 0.1986(3) 0.81074(13) 0.5542(2) 0.0439(7) Uani d . 1
H H28 0.1468 0.8342 0.4946 0.053 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N2 Pb1 N1 . . 67.72(7)
N2 Pb1 O2 . . 75.58(6)
N1 Pb1 O2 . . 80.12(6)
N2 Pb1 O4 . . 82.52(7)
N1 Pb1 O4 . . 72.09(7)
O2 Pb1 O4 . . 149.58(6)
N2 Pb1 O1 . . 121.26(6)
N1 Pb1 O1 . . 79.82(6)
O2 Pb1 O1 . . 50.84(6)
O4 Pb1 O1 . . 132.21(7)
N2 Pb1 O5 . 3_676 109.00(9)
N1 Pb1 O5 . 3_676 155.30(7)
O2 Pb1 O5 . 3_676 75.47(7)
O4 Pb1 O5 . 3_676 132.55(7)
O1 Pb1 O5 . 3_676 81.89(8)
N2 Pb1 C15 . . 99.56(7)
N1 Pb1 C15 . . 81.81(6)
O2 Pb1 C15 . . 25.29(6)
O4 Pb1 C15 . . 150.90(7)
O1 Pb1 C15 . . 25.87(6)
O5 Pb1 C15 3_676 . 74.53(7)
C15 O1 Pb1 . . 89.65(14)
C15 O2 Pb1 . . 96.86(15)
C19 O3 H3 . . 109.5
C22 O4 Pb1 . . 114.65(17)
C22 O5 Pb1 . 3_676 163.1(3)
C26 O6 H6 . . 109.5
C1 N1 C12 . . 119.6(2)
C1 N1 Pb1 . . 123.69(16)
C12 N1 Pb1 . . 116.66(15)
C10 N2 C11 . . 119.1(2)
C10 N2 Pb1 . . 123.19(18)
C11 N2 Pb1 . . 117.42(16)
N1 C1 C2 . . 120.8(3)
N1 C1 C13 . . 119.1(2)
C2 C1 C13 . . 120.1(2)
C3 C2 C1 . . 120.5(3)
C3 C2 H2 . . 119.8
C1 C2 H2 . . 119.8
C2 C3 C4 . . 120.1(3)
C2 C3 H3A . . 119.9
C4 C3 H3A . . 119.9
C3 C4 C12 . . 116.6(3)
C3 C4 C5 . . 123.3(3)
C12 C4 C5 . . 120.1(3)
C6 C5 C4 . . 120.9(3)
C6 C5 H5 . . 119.5
C4 C5 H5 . . 119.5
C5 C6 C7 . . 121.1(3)
C5 C6 H6A . . 119.4
C7 C6 H6A . . 119.4
C11 C7 C8 . . 117.2(3)
C11 C7 C6 . . 119.7(3)
C8 C7 C6 . . 123.0(3)
C9 C8 C7 . . 119.2(3)
C9 C8 H8 . . 120.4
C7 C8 H8 . . 120.4
C8 C9 C10 . . 120.8(3)
C8 C9 H9 . . 119.6
C10 C9 H9 . . 119.6
N2 C10 C9 . . 121.2(3)
N2 C10 C14 . . 117.2(3)
C9 C10 C14 . . 121.5(3)
N2 C11 C7 . . 122.3(2)
N2 C11 C12 . . 118.4(2)
C7 C11 C12 . . 119.3(2)
N1 C12 C4 . . 122.2(2)
N1 C12 C11 . . 119.0(2)
C4 C12 C11 . . 118.8(2)
C1 C13 H13A . . 109.5
C1 C13 H13B . . 109.5
H13A C13 H13B . . 109.5
C1 C13 H13C . . 109.5
H13A C13 H13C . . 109.5
H13B C13 H13C . . 109.5
C10 C14 H14A . . 109.5
C10 C14 H14B . . 109.5
H14A C14 H14B . . 109.5
C10 C14 H14C . . 109.5
H14A C14 H14C . . 109.5
H14B C14 H14C . . 109.5
O2 C15 O1 . . 121.2(2)
O2 C15 C16 . . 119.7(2)
O1 C15 C16 . . 119.1(2)
O2 C15 Pb1 . . 57.86(12)
O1 C15 Pb1 . . 64.48(13)
C16 C15 Pb1 . . 170.63(17)
C17 C16 C21 . . 118.0(2)
C17 C16 C15 . . 121.2(2)
C21 C16 C15 . . 120.8(2)
C18 C17 C16 . . 121.2(3)
C18 C17 H17 . . 119.4
C16 C17 H17 . . 119.4
C17 C18 C19 . . 120.0(3)
C17 C18 H18 . . 120.0
C19 C18 H18 . . 120.0
O3 C19 C18 . . 118.3(2)
O3 C19 C20 . . 122.4(3)
C18 C19 C20 . . 119.4(2)
C21 C20 C19 . . 119.9(3)
C21 C20 H20 . . 120.0
C19 C20 H20 . . 120.0
C20 C21 C16 . . 121.4(2)
C20 C21 H21 . . 119.3
C16 C21 H21 . . 119.3
O5 C22 O4 . . 122.7(3)
O5 C22 C23 . . 120.3(3)
O4 C22 C23 . . 117.0(3)
C24 C23 C28 . . 118.2(2)
C24 C23 C22 . . 121.6(3)
C28 C23 C22 . . 120.2(2)
C23 C24 C25 . . 121.4(3)
C23 C24 H24 . . 119.3
C25 C24 H24 . . 119.3
C24 C25 C26 . . 119.6(3)
C24 C25 H25 . . 120.2
C26 C25 H25 . . 120.2
O6 C26 C27 . . 117.0(2)
O6 C26 C25 . . 123.4(2)
C27 C26 C25 . . 119.6(2)
C28 C27 C26 . . 120.1(3)
C28 C27 H27 . . 119.9
C26 C27 H27 . . 119.9
C27 C28 C23 . . 121.1(3)
C27 C28 H28 . . 119.4
C23 C28 H28 . . 119.4
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pb1 N2 . 2.464(2) y
Pb1 N1 . 2.4818(19) y
Pb1 O2 . 2.4851(17) y
Pb1 O4 . 2.5291(18) y
Pb1 O1 . 2.6298(18) y
Pb1 O5 3_676 2.767(2) y
Pb1 C15 . 2.914(2) ?
O1 C15 . 1.271(3) ?
O2 C15 . 1.254(3) ?
O3 C19 . 1.359(3) ?
O3 H3 . 0.8200 ?
O4 C22 . 1.269(3) ?
O5 C22 . 1.216(4) ?
O5 Pb1 3_676 2.767(2) ?
O6 C26 . 1.357(3) ?
O6 H6 . 0.8200 ?
N1 C1 . 1.330(3) ?
N1 C12 . 1.365(3) ?
N2 C10 . 1.329(3) ?
N2 C11 . 1.365(3) ?
C1 C2 . 1.394(4) ?
C1 C13 . 1.499(4) ?
C2 C3 . 1.363(4) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.405(4) ?
C3 H3A . 0.9300 ?
C4 C12 . 1.409(3) ?
C4 C5 . 1.427(4) ?
C5 C6 . 1.340(4) ?
C5 H5 . 0.9300 ?
C6 C7 . 1.430(4) ?
C6 H6A . 0.9300 ?
C7 C11 . 1.406(4) ?
C7 C8 . 1.408(4) ?
C8 C9 . 1.363(5) ?
C8 H8 . 0.9300 ?
C9 C10 . 1.394(4) ?
C9 H9 . 0.9300 ?
C10 C14 . 1.506(4) ?
C11 C12 . 1.445(3) ?
C13 H13A . 0.9600 ?
C13 H13B . 0.9600 ?
C13 H13C . 0.9600 ?
C14 H14A . 0.9600 ?
C14 H14B . 0.9600 ?
C14 H14C . 0.9600 ?
C15 C16 . 1.491(3) ?
C16 C17 . 1.389(3) ?
C16 C21 . 1.390(3) ?
C17 C18 . 1.379(4) ?
C17 H17 . 0.9300 ?
C18 C19 . 1.386(4) ?
C18 H18 . 0.9300 ?
C19 C20 . 1.393(4) ?
C20 C21 . 1.372(4) ?
C20 H20 . 0.9300 ?
C21 H21 . 0.9300 ?
C22 C23 . 1.506(4) ?
C23 C24 . 1.383(4) ?
C23 C28 . 1.389(4) ?
C24 C25 . 1.386(4) ?
C24 H24 . 0.9300 ?
C25 C26 . 1.387(4) ?
C25 H25 . 0.9300 ?
C26 C27 . 1.385(4) ?
C27 C28 . 1.379(4) ?
C27 H27 . 0.9300 ?
C28 H28 . 0.9300 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O3 H3 O1 4_585 0.82 1.84 2.652(3) 172.4
O6 H6 O4 4_576 0.82 1.82 2.619(3) 164.7
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
N2 Pb1 O1 C15 . -36.24(16)
N1 Pb1 O1 C15 . -92.21(15)
O2 Pb1 O1 C15 . -6.72(13)
O4 Pb1 O1 C15 . -146.43(14)
O5 Pb1 O1 C15 3_676 71.10(16)
N2 Pb1 O2 C15 . 161.08(16)
N1 Pb1 O2 C15 . 91.73(15)
O4 Pb1 O2 C15 . 115.79(18)
O1 Pb1 O2 C15 . 6.86(14)
O5 Pb1 O2 C15 3_676 -84.47(16)
N2 Pb1 O4 C22 . 122.6(2)
N1 Pb1 O4 C22 . -168.4(2)
O2 Pb1 O4 C22 . 166.60(19)
O1 Pb1 O4 C22 . -111.4(2)
O5 Pb1 O4 C22 3_676 13.7(3)
C15 Pb1 O4 C22 . -141.1(2)
N2 Pb1 N1 C1 . 172.1(2)
O2 Pb1 N1 C1 . -109.56(19)
O4 Pb1 N1 C1 . 82.97(19)
O1 Pb1 N1 C1 . -57.88(19)
O5 Pb1 N1 C1 3_676 -100.7(3)
C15 Pb1 N1 C1 . -84.01(19)
N2 Pb1 N1 C12 . -6.72(15)
O2 Pb1 N1 C12 . 71.63(16)
O4 Pb1 N1 C12 . -95.83(17)
O1 Pb1 N1 C12 . 123.32(17)
O5 Pb1 N1 C12 3_676 80.5(3)
C15 Pb1 N1 C12 . 97.19(17)
N1 Pb1 N2 C10 . -177.5(2)
O2 Pb1 N2 C10 . 97.4(2)
O4 Pb1 N2 C10 . -103.9(2)
O1 Pb1 N2 C10 . 120.7(2)
O5 Pb1 N2 C10 3_676 28.7(2)
C15 Pb1 N2 C10 . 105.5(2)
N1 Pb1 N2 C11 . 8.24(16)
O2 Pb1 N2 C11 . -76.82(17)
O4 Pb1 N2 C11 . 81.90(18)
O1 Pb1 N2 C11 . -53.58(19)
O5 Pb1 N2 C11 3_676 -145.56(17)
C15 Pb1 N2 C11 . -68.75(18)
C12 N1 C1 C2 . -2.5(4)
Pb1 N1 C1 C2 . 178.8(2)
C12 N1 C1 C13 . 176.0(2)
Pb1 N1 C1 C13 . -2.7(3)
N1 C1 C2 C3 . -0.3(4)
C13 C1 C2 C3 . -178.8(3)
C1 C2 C3 C4 . 2.0(5)
C2 C3 C4 C12 . -0.8(4)
C2 C3 C4 C5 . 177.8(3)
C3 C4 C5 C6 . -177.1(3)
C12 C4 C5 C6 . 1.4(5)
C4 C5 C6 C7 . 1.3(5)
C5 C6 C7 C11 . -2.2(5)
C5 C6 C7 C8 . 177.5(3)
C11 C7 C8 C9 . 3.5(5)
C6 C7 C8 C9 . -176.2(3)
C7 C8 C9 C10 . -1.9(5)
C11 N2 C10 C9 . 2.4(4)
Pb1 N2 C10 C9 . -171.7(2)
C11 N2 C10 C14 . -177.0(3)
Pb1 N2 C10 C14 . 8.9(4)
C8 C9 C10 N2 . -1.2(5)
C8 C9 C10 C14 . 178.2(4)
C10 N2 C11 C7 . -0.6(4)
Pb1 N2 C11 C7 . 173.90(19)
C10 N2 C11 C12 . 176.3(2)
Pb1 N2 C11 C12 . -9.2(3)
C8 C7 C11 N2 . -2.4(4)
C6 C7 C11 N2 . 177.3(3)
C8 C7 C11 C12 . -179.2(3)
C6 C7 C11 C12 . 0.5(4)
C1 N1 C12 C4 . 3.7(4)
Pb1 N1 C12 C4 . -177.46(19)
C1 N1 C12 C11 . -173.9(2)
Pb1 N1 C12 C11 . 4.9(3)
C3 C4 C12 N1 . -2.0(4)
C5 C4 C12 N1 . 179.3(2)
C3 C4 C12 C11 . 175.6(2)
C5 C4 C12 C11 . -3.1(4)
N2 C11 C12 N1 . 2.8(3)
C7 C11 C12 N1 . 179.8(2)
N2 C11 C12 C4 . -174.9(2)
C7 C11 C12 C4 . 2.1(4)
Pb1 O2 C15 O1 . -12.9(3)
Pb1 O2 C15 C16 . 169.45(19)
Pb1 O1 C15 O2 . 12.1(2)
Pb1 O1 C15 C16 . -170.2(2)
N2 Pb1 C15 O2 . -18.57(15)
N1 Pb1 C15 O2 . -84.19(15)
O4 Pb1 C15 O2 . -110.36(18)
O1 Pb1 C15 O2 . -167.7(2)
O5 Pb1 C15 O2 3_676 88.64(16)
N2 Pb1 C15 O1 . 149.17(14)
N1 Pb1 C15 O1 . 83.54(14)
O2 Pb1 C15 O1 . 167.7(2)
O4 Pb1 C15 O1 . 57.4(2)
O5 Pb1 C15 O1 3_676 -103.62(16)
O2 C15 C16 C17 . 171.0(2)
O1 C15 C16 C17 . -6.7(4)
O2 C15 C16 C21 . -7.0(4)
O1 C15 C16 C21 . 175.3(2)
C21 C16 C17 C18 . 1.5(4)
C15 C16 C17 C18 . -176.6(2)
C16 C17 C18 C19 . 0.0(4)
C17 C18 C19 O3 . 177.7(3)
C17 C18 C19 C20 . -1.9(4)
O3 C19 C20 C21 . -177.2(3)
C18 C19 C20 C21 . 2.4(4)
C19 C20 C21 C16 . -1.0(4)
C17 C16 C21 C20 . -0.9(4)
C15 C16 C21 C20 . 177.1(2)
Pb1 O5 C22 O4 3_676 52.9(11)
Pb1 O5 C22 C23 3_676 -127.0(8)
Pb1 O4 C22 O5 . -25.3(4)
Pb1 O4 C22 C23 . 154.6(2)
O5 C22 C23 C24 . -22.2(5)
O4 C22 C23 C24 . 157.9(3)
O5 C22 C23 C28 . 157.7(3)
O4 C22 C23 C28 . -22.2(4)
C28 C23 C24 C25 . 0.4(4)
C22 C23 C24 C25 . -179.6(3)
C23 C24 C25 C26 . -0.8(5)
C24 C25 C26 O6 . -179.7(3)
C24 C25 C26 C27 . 0.8(4)
O6 C26 C27 C28 . -179.9(3)
C25 C26 C27 C28 . -0.4(4)
C26 C27 C28 C23 . 0.0(4)
C24 C23 C28 C27 . 0.0(4)
C22 C23 C28 C27 . -180.0(3)
