#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/23/2222323.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2222323
loop_
_publ_author_name
'Heston, Scott A.'
'Noll, Bruce C.'
'Helm, Monte L.'
_publ_section_title
;{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ³P,P',P''}chloridoplatinium(II)
 hexafluoridophosphate
;
_journal_coeditor_code           HB2993
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m793
_journal_paper_doi               10.1107/S1600536809022405
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Pt Cl (C34 H33 P3)] P F6'
_chemical_formula_moiety         'C34 H33 Cl P3 Pt +, F6 P -'
_chemical_formula_sum            'C34 H33 Cl F6 P4 Pt'
_chemical_formula_weight         910.02
_chemical_name_common            '[Pt(triphos)Cl](PF6)2'
_chemical_name_systematic
;
{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-
κ³P,P',P''}chloridoplatinium(II)
hexafluoridophosphate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.528(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.3870(11)
_cell_length_b                   19.6221(18)
_cell_length_c                   16.4439(16)
_cell_measurement_reflns_used    9957
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.10
_cell_measurement_theta_min      2.45
_cell_volume                     3503.6(6)
_computing_cell_refinement       'SAINT (Bruker, 2008)'
_computing_data_collection       'APEX2 (Bruker, 2008)'
_computing_data_reduction        'SAINT and XPREP (Bruker, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008b)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008b)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008b)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008b)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean 8.33
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker SMART X2S'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_av_sigmaI/netI    0.0243
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21968
_diffrn_reflns_theta_full        25.08
_diffrn_reflns_theta_max         25.08
_diffrn_reflns_theta_min         2.78
_exptl_absorpt_coefficient_mu    4.320
_exptl_absorpt_correction_T_max  0.65
_exptl_absorpt_correction_T_min  0.21
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2008a)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.725
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1784
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.580
_refine_diff_density_min         -0.414
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     452
_refine_ls_number_reflns         6155
_refine_ls_number_restraints     204
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0284
_refine_ls_R_factor_gt           0.0202
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0227P)²+1.641P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0456
_refine_ls_wR_factor_ref         0.0489
_reflns_number_gt                5269
_reflns_number_total             6155
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hb2993.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2222323
_cod_database_fobs_code          2222323
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt1 0.139852(10) 0.364806(6) 0.374003(7) 0.03173(5) Uani d . 1 . .
Cl Cl1 0.31867(8) 0.35123(5) 0.48942(5) 0.0498(2) Uani d . 1 . .
P P1 0.22200(7) 0.43573(4) 0.29227(5) 0.03695(19) Uani d . 1 . .
P P2 -0.03648(7) 0.37743(4) 0.27189(5) 0.03518(19) Uani d . 1 . .
P P3 0.03774(7) 0.28264(4) 0.42630(5) 0.03706(19) Uani d . 1 . .
C C1 0.3286(3) 0.39017(18) 0.2487(2) 0.0417(8) Uani d . 1 . .
C C2 0.3950(4) 0.3357(2) 0.2925(3) 0.0696(12) Uani d . 1 . .
H H2 0.3851 0.3227 0.3444 0.084 Uiso calc R 1 . .
C C3 0.4758(5) 0.3003(3) 0.2602(4) 0.0929(17) Uani d . 1 . .
H H3 0.5209 0.2641 0.2909 0.111 Uiso calc R 1 . .
C C4 0.4896(4) 0.3182(3) 0.1838(3) 0.0811(14) Uani d . 1 . .
H H4 0.5422 0.2933 0.1614 0.097 Uiso calc R 1 . .
C C5 0.4268(4) 0.3724(3) 0.1397(3) 0.0809(15) Uani d . 1 . .
H H5 0.4382 0.3850 0.0881 0.097 Uiso calc R 1 . .
C C6 0.3458(4) 0.4088(2) 0.1716(2) 0.0662(12) Uani d . 1 . .
H H6 0.3030 0.4457 0.1413 0.079 Uiso calc R 1 . .
C C7 0.2923(3) 0.51580(17) 0.3367(2) 0.0448(8) Uani d . 1 . .
C C8 0.3091(4) 0.5681(2) 0.2843(3) 0.0690(12) Uani d . 1 . .
H H8 0.2889 0.5616 0.2257 0.083 Uiso calc R 1 . .
C C9 0.3563(5) 0.6303(2) 0.3202(4) 0.0815(15) Uani d . 1 . .
H H9 0.3673 0.6653 0.2852 0.098 Uiso calc R 1 . .
C C10 0.3863(4) 0.6405(2) 0.4054(4) 0.0774(15) Uani d . 1 . .
H H10 0.4162 0.6827 0.4283 0.093 Uiso calc R 1 . .
C C11 0.3726(4) 0.5886(2) 0.4579(3) 0.0774(14) Uani d . 1 . .
H H11 0.3950 0.5954 0.5166 0.093 Uiso calc R 1 . .
C C12 0.3255(3) 0.5262(2) 0.4237(3) 0.0587(10) Uani d . 1 . .
H H12 0.3162 0.4913 0.4595 0.070 Uiso calc R 1 . .
C C13 0.0924(3) 0.46082(19) 0.2000(2) 0.0480(9) Uani d . 1 . .
H H13A 0.0534 0.5012 0.2141 0.058 Uiso calc R 1 . .
H H13B 0.1226 0.4718 0.1524 0.058 Uiso calc R 1 . .
C C14 -0.0024(3) 0.40301(19) 0.1745(2) 0.0459(8) Uani d . 1 . .
H H14A 0.0311 0.3649 0.1510 0.055 Uiso calc R 1 . .
H H14B -0.0766 0.4188 0.1320 0.055 Uiso calc R 1 . .
C C15 -0.1372(3) 0.44123(17) 0.2947(2) 0.0392(8) Uani d . 1 . .
C C16 -0.2526(3) 0.4525(2) 0.2376(2) 0.0612(11) Uani d . 1 . .
H H16 -0.2769 0.4292 0.1860 0.073 Uiso calc R 1 . .
C C17 -0.3320(4) 0.4987(2) 0.2575(3) 0.0777(13) Uani d . 1 . .
H H17 -0.4097 0.5061 0.2192 0.093 Uiso calc R 1 . .
C C18 -0.2964(4) 0.5334(2) 0.3334(3) 0.0718(12) Uani d . 1 . .
H H18 -0.3501 0.5642 0.3462 0.086 Uiso calc R 1 . .
C C19 -0.1830(4) 0.5230(2) 0.3901(3) 0.0655(11) Uani d . 1 . .
H H19 -0.1593 0.5468 0.4413 0.079 Uiso calc R 1 . .
C C20 -0.1031(3) 0.47681(18) 0.3711(2) 0.0512(9) Uani d . 1 . .
H H20 -0.0258 0.4696 0.4100 0.061 Uiso calc R 1 . .
C C21 -0.1212(3) 0.29792(17) 0.2618(2) 0.0446(8) Uani d . 1 . .
H H21A -0.2052 0.3041 0.2255 0.054 Uiso calc R 1 . .
H H21B -0.0824 0.2631 0.2368 0.054 Uiso calc R 1 . .
C C22 -0.1201(3) 0.27699(19) 0.3519(2) 0.0500(9) Uani d . 1 . .
H H22A -0.1502 0.2307 0.3510 0.060 Uiso calc R 1 . .
H H22B -0.1743 0.3067 0.3713 0.060 Uiso calc R 1 . .
C C23 0.0305(3) 0.29942(17) 0.5330(2) 0.0413(8) Uani d . 1 . .
C C24 -0.0603(3) 0.3399(2) 0.5480(2) 0.0529(9) Uani d . 1 . .
H H24 -0.1274 0.3533 0.5027 0.063 Uiso calc R 1 . .
C C25 -0.0518(4) 0.3605(2) 0.6305(3) 0.0605(11) Uani d . 1 . .
H H25 -0.1135 0.3874 0.6402 0.073 Uiso calc R 1 . .
C C26 0.0467(4) 0.3415(2) 0.6974(2) 0.0590(10) Uani d . 1 . .
H H26 0.0533 0.3564 0.7523 0.071 Uiso calc R 1 . .
C C27 0.1362(4) 0.3003(2) 0.6833(2) 0.0614(11) Uani d . 1 . .
H H27 0.2024 0.2865 0.7290 0.074 Uiso calc R 1 . .
C C28 0.1287(3) 0.2791(2) 0.6017(2) 0.0538(9) Uani d . 1 . .
H H28 0.1896 0.2512 0.5929 0.065 Uiso calc R 1 . .
C C29 0.1039(3) 0.19806(16) 0.42953(19) 0.0387(8) Uani d . 1 . .
C C30 0.0425(4) 0.14216(19) 0.4497(2) 0.0539(10) Uani d . 1 . .
H H30 -0.0322 0.1483 0.4609 0.065 Uiso calc R 1 . .
C C31 0.0923(5) 0.0778(2) 0.4532(3) 0.0677(12) Uani d . 1 . .
H H31 0.0515 0.0407 0.4673 0.081 Uiso calc R 1 . .
C C32 0.2015(4) 0.0680(2) 0.4359(3) 0.0675(12) Uani d . 1 . .
H H32 0.2343 0.0244 0.4381 0.081 Uiso calc R 1 . .
C C33 0.2626(4) 0.1225(2) 0.4153(3) 0.0610(11) Uani d . 1 . .
H H33 0.3362 0.1157 0.4029 0.073 Uiso calc R 1 . .
C C34 0.2149(3) 0.18766(18) 0.4131(2) 0.0456(8) Uani d . 1 . .
H H34 0.2575 0.2246 0.4005 0.055 Uiso calc R 1 . .
P P4 0.33951(10) 0.86107(6) 0.53542(7) 0.0655(3) Uani d D 1 . .
F F1 0.2344(3) 0.91309(17) 0.5407(2) 0.1331(13) Uani d D 1 A .
F F2 0.4424(3) 0.81198(16) 0.5283(2) 0.1263(12) Uani d D 1 A .
F F3 0.4311(7) 0.8949(6) 0.6137(6) 0.170(6) Uani d PDU 0.614(17) A 1
F F4 0.2458(8) 0.8302(5) 0.4551(7) 0.181(7) Uani d PDU 0.614(17) A 1
F F5 0.3788(11) 0.9131(4) 0.4771(7) 0.143(6) Uani d PDU 0.614(17) A 1
F F6 0.2992(7) 0.8122(5) 0.5916(7) 0.196(7) Uani d PDU 0.614(17) A 1
F F3' 0.3623(16) 0.8459(7) 0.6302(5) 0.170(11) Uani d PDU 0.386(17) A 2
F F4' 0.3028(14) 0.8713(10) 0.4399(5) 0.184(10) Uani d PDU 0.386(17) A 2
F F5' 0.4294(9) 0.9199(4) 0.5545(15) 0.153(11) Uani d PDU 0.386(17) A 2
F F6' 0.2434(11) 0.8018(5) 0.5150(11) 0.141(9) Uani d PDU 0.386(17) A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P2 Pt1 P3 . . 85.22(3) ?
P2 Pt1 P1 . . 85.71(3) ?
P3 Pt1 P1 . . 167.13(3) ?
P2 Pt1 Cl1 . . 175.83(3) ?
P3 Pt1 Cl1 . . 91.79(3) ?
P1 Pt1 Cl1 . . 97.69(3) ?
C7 P1 C1 . . 108.56(15) ?
C7 P1 C13 . . 104.36(16) ?
C1 P1 C13 . . 105.78(16) ?
C7 P1 Pt1 . . 119.51(12) ?
C1 P1 Pt1 . . 111.53(12) ?
C13 P1 Pt1 . . 105.99(11) ?
C15 P2 C21 . . 105.12(16) ?
C15 P2 C14 . . 107.82(16) ?
C21 P2 C14 . . 113.75(16) ?
C15 P2 Pt1 . . 114.03(11) ?
C21 P2 Pt1 . . 108.04(11) ?
C14 P2 Pt1 . . 108.22(11) ?
C23 P3 C29 . . 106.08(15) ?
C23 P3 C22 . . 109.46(16) ?
C29 P3 C22 . . 106.05(16) ?
C23 P3 Pt1 . . 114.22(11) ?
C29 P3 Pt1 . . 113.54(11) ?
C22 P3 Pt1 . . 107.16(11) ?
C2 C1 C6 . . 118.3(3) ?
C2 C1 P1 . . 120.0(3) ?
C6 C1 P1 . . 121.6(3) ?
C1 C2 C3 . . 120.9(4) ?
C1 C2 H2 . . 119.6 ?
C3 C2 H2 . . 119.6 ?
C4 C3 C2 . . 120.1(4) ?
C4 C3 H3 . . 120.0 ?
C2 C3 H3 . . 120.0 ?
C3 C4 C5 . . 120.4(4) ?
C3 C4 H4 . . 119.8 ?
C5 C4 H4 . . 119.8 ?
C4 C5 C6 . . 120.2(4) ?
C4 C5 H5 . . 119.9 ?
C6 C5 H5 . . 119.9 ?
C5 C6 C1 . . 120.1(4) ?
C5 C6 H6 . . 119.9 ?
C1 C6 H6 . . 119.9 ?
C12 C7 C8 . . 119.1(4) ?
C12 C7 P1 . . 119.7(3) ?
C8 C7 P1 . . 121.1(3) ?
C7 C8 C9 . . 119.5(4) ?
C7 C8 H8 . . 120.3 ?
C9 C8 H8 . . 120.3 ?
C10 C9 C8 . . 121.0(4) ?
C10 C9 H9 . . 119.5 ?
C8 C9 H9 . . 119.5 ?
C9 C10 C11 . . 119.9(4) ?
C9 C10 H10 . . 120.0 ?
C11 C10 H10 . . 120.0 ?
C10 C11 C12 . . 120.2(5) ?
C10 C11 H11 . . 119.9 ?
C12 C11 H11 . . 119.9 ?
C7 C12 C11 . . 120.2(4) ?
C7 C12 H12 . . 119.9 ?
C11 C12 H12 . . 119.9 ?
C14 C13 P1 . . 110.6(2) ?
C14 C13 H13A . . 109.5 ?
P1 C13 H13A . . 109.5 ?
C14 C13 H13B . . 109.5 ?
P1 C13 H13B . . 109.5 ?
H13A C13 H13B . . 108.1 ?
C13 C14 P2 . . 106.3(2) ?
C13 C14 H14A . . 110.5 ?
P2 C14 H14A . . 110.5 ?
C13 C14 H14B . . 110.5 ?
P2 C14 H14B . . 110.5 ?
H14A C14 H14B . . 108.7 ?
C16 C15 C20 . . 118.9(3) ?
C16 C15 P2 . . 120.1(3) ?
C20 C15 P2 . . 120.9(3) ?
C15 C16 C17 . . 119.9(4) ?
C15 C16 H16 . . 120.1 ?
C17 C16 H16 . . 120.1 ?
C18 C17 C16 . . 120.2(4) ?
C18 C17 H17 . . 119.9 ?
C16 C17 H17 . . 119.9 ?
C19 C18 C17 . . 120.6(4) ?
C19 C18 H18 . . 119.7 ?
C17 C18 H18 . . 119.7 ?
C18 C19 C20 . . 119.7(4) ?
C18 C19 H19 . . 120.1 ?
C20 C19 H19 . . 120.1 ?
C19 C20 C15 . . 120.7(3) ?
C19 C20 H20 . . 119.7 ?
C15 C20 H20 . . 119.7 ?
C22 C21 P2 . . 107.0(2) ?
C22 C21 H21A . . 110.3 ?
P2 C21 H21A . . 110.3 ?
C22 C21 H21B . . 110.3 ?
P2 C21 H21B . . 110.3 ?
H21A C21 H21B . . 108.6 ?
C21 C22 P3 . . 110.3(2) ?
C21 C22 H22A . . 109.6 ?
P3 C22 H22A . . 109.6 ?
C21 C22 H22B . . 109.6 ?
P3 C22 H22B . . 109.6 ?
H22A C22 H22B . . 108.1 ?
C24 C23 C28 . . 118.9(3) ?
C24 C23 P3 . . 122.1(3) ?
C28 C23 P3 . . 118.4(3) ?
C23 C24 C25 . . 120.3(4) ?
C23 C24 H24 . . 119.9 ?
C25 C24 H24 . . 119.9 ?
C26 C25 C24 . . 120.4(4) ?
C26 C25 H25 . . 119.8 ?
C24 C25 H25 . . 119.8 ?
C25 C26 C27 . . 119.7(4) ?
C25 C26 H26 . . 120.1 ?
C27 C26 H26 . . 120.1 ?
C26 C27 C28 . . 120.6(4) ?
C26 C27 H27 . . 119.7 ?
C28 C27 H27 . . 119.7 ?
C27 C28 C23 . . 120.2(3) ?
C27 C28 H28 . . 119.9 ?
C23 C28 H28 . . 119.9 ?
C34 C29 C30 . . 118.9(3) ?
C34 C29 P3 . . 121.6(3) ?
C30 C29 P3 . . 119.5(3) ?
C31 C30 C29 . . 120.1(4) ?
C31 C30 H30 . . 120.0 ?
C29 C30 H30 . . 120.0 ?
C32 C31 C30 . . 120.5(4) ?
C32 C31 H31 . . 119.8 ?
C30 C31 H31 . . 119.8 ?
C31 C32 C33 . . 120.1(4) ?
C31 C32 H32 . . 119.9 ?
C33 C32 H32 . . 119.9 ?
C32 C33 C34 . . 120.1(4) ?
C32 C33 H33 . . 119.9 ?
C34 C33 H33 . . 119.9 ?
C29 C34 C33 . . 120.3(3) ?
C29 C34 H34 . . 119.9 ?
C33 C34 H34 . . 119.9 ?
F5' P4 F4' . . 94.2(8) ?
F5' P4 F3' . . 92.3(7) ?
F4' P4 F3' . . 173.1(8) ?
F6 P4 F3 . . 90.9(5) ?
F6 P4 F2 . . 91.6(4) ?
F5' P4 F2 . . 90.6(4) ?
F4' P4 F2 . . 89.0(5) ?
F3' P4 F2 . . 93.2(4) ?
F3 P4 F2 . . 89.6(4) ?
F6 P4 F4 . . 90.9(5) ?
F3 P4 F4 . . 177.5(5) ?
F2 P4 F4 . . 92.0(3) ?
F6 P4 F5 . . 178.6(5) ?
F3 P4 F5 . . 89.1(4) ?
F2 P4 F5 . . 89.8(3) ?
F4 P4 F5 . . 89.0(5) ?
F5' P4 F6' . . 178.3(6) ?
F4' P4 F6' . . 85.3(8) ?
F3' P4 F6' . . 88.1(6) ?
F2 P4 F6' . . 91.0(4) ?
F6 P4 F1 . . 90.1(4) ?
F5' P4 F1 . . 88.4(4) ?
F4' P4 F1 . . 89.7(5) ?
F3' P4 F1 . . 88.2(4) ?
F3 P4 F1 . . 90.5(4) ?
F2 P4 F1 . . 178.3(2) ?
F4 P4 F1 . . 87.8(3) ?
F5 P4 F1 . . 88.5(3) ?
F6' P4 F1 . . 90.0(4) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pt1 P2 . 2.2095(8) y
Pt1 P3 . 2.3007(8) y
Pt1 P1 . 2.3185(8) y
Pt1 Cl1 . 2.3434(8) y
P1 C7 . 1.814(4) ?
P1 C1 . 1.819(3) ?
P1 C13 . 1.836(3) ?
P2 C15 . 1.812(3) ?
P2 C21 . 1.815(3) ?
P2 C14 . 1.828(3) ?
P3 C23 . 1.812(3) ?
P3 C29 . 1.817(3) ?
P3 C22 . 1.848(3) ?
C1 C2 . 1.380(5) ?
C1 C6 . 1.389(5) ?
C2 C3 . 1.381(6) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.359(6) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.362(6) ?
C4 H4 . 0.9300 ?
C5 C6 . 1.388(6) ?
C5 H5 . 0.9300 ?
C6 H6 . 0.9300 ?
C7 C12 . 1.381(5) ?
C7 C8 . 1.390(5) ?
C8 C9 . 1.390(6) ?
C8 H8 . 0.9300 ?
C9 C10 . 1.352(7) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.375(6) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.386(5) ?
C11 H11 . 0.9300 ?
C12 H12 . 0.9300 ?
C13 C14 . 1.535(5) ?
C13 H13A . 0.9700 ?
C13 H13B . 0.9700 ?
C14 H14A . 0.9700 ?
C14 H14B . 0.9700 ?
C15 C16 . 1.383(5) ?
C15 C20 . 1.387(5) ?
C16 C17 . 1.387(5) ?
C16 H16 . 0.9300 ?
C17 C18 . 1.371(6) ?
C17 H17 . 0.9300 ?
C18 C19 . 1.361(6) ?
C18 H18 . 0.9300 ?
C19 C20 . 1.384(5) ?
C19 H19 . 0.9300 ?
C20 H20 . 0.9300 ?
C21 C22 . 1.535(5) ?
C21 H21A . 0.9700 ?
C21 H21B . 0.9700 ?
C22 H22A . 0.9700 ?
C22 H22B . 0.9700 ?
C23 C24 . 1.383(5) ?
C23 C28 . 1.387(5) ?
C24 C25 . 1.392(5) ?
C24 H24 . 0.9300 ?
C25 C26 . 1.365(6) ?
C25 H25 . 0.9300 ?
C26 C27 . 1.375(5) ?
C26 H26 . 0.9300 ?
C27 C28 . 1.382(5) ?
C27 H27 . 0.9300 ?
C28 H28 . 0.9300 ?
C29 C34 . 1.385(4) ?
C29 C30 . 1.393(5) ?
C30 C31 . 1.379(5) ?
C30 H30 . 0.9300 ?
C31 C32 . 1.370(6) ?
C31 H31 . 0.9300 ?
C32 C33 . 1.372(6) ?
C32 H32 . 0.9300 ?
C33 C34 . 1.385(5) ?
C33 H33 . 0.9300 ?
C34 H34 . 0.9300 ?
P4 F6 . 1.496(5) ?
P4 F5' . 1.512(8) ?
P4 F4' . 1.512(8) ?
P4 F3' . 1.530(8) ?
P4 F3 . 1.542(7) ?
P4 F2 . 1.548(3) ?
P4 F4 . 1.549(6) ?
P4 F5 . 1.556(6) ?
P4 F6' . 1.563(8) ?
P4 F1 . 1.595(3) ?
