#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/43/2224308.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2224308
loop_
_publ_author_name
'An, Zhe'
_publ_section_title
;Bis(μ-2'-carboxylatobiphenyl-2-carboxylic
 acid-κ²O²:O^2'^)bis[(2,2'-bipyridine-κ²N,N')(2'-carboxylatobiphenyl-2-carboxylic
 acid-κO^2'^)zinc(II)]
;
_journal_coeditor_code           IM2149
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1501
_journal_paper_doi               10.1107/S1600536809045541
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Zn2 (C14 H9 O4)4 (C10 H8 N2)2]'
_chemical_formula_moiety         'C76 H52 N4 O16 Zn2'
_chemical_formula_sum            'C76 H52 N4 O16 Zn2'
_chemical_formula_weight         1407.96
_chemical_name_systematic
;
Bis(μ-2'-carboxylatobiphenyl-2-carboxylic
acid-κ²O²:O^2'^)bis[(2,2'-bipyridine-
κ²N,N')(2'-carboxylatobiphenyl-2-carboxylic
acid-κO^2'^)zinc(II)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.0940(10)
_cell_angle_beta                 112.7730(10)
_cell_angle_gamma                92.6800(10)
_cell_formula_units_Z            1
_cell_length_a                   10.8745(4)
_cell_length_b                   11.6465(4)
_cell_length_c                   14.0223(5)
_cell_measurement_reflns_used    6287
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.16
_cell_measurement_theta_min      2.53
_cell_volume                     1576.93(10)
_computing_cell_refinement       'SAINT (Bruker, 2005)'
_computing_data_collection       'SMART (Bruker, 2005)'
_computing_data_reduction        'SAINT (Bruker, 2005)'
_computing_molecular_graphics    'XP in SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.961
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0144
_diffrn_reflns_av_sigmaI/netI    0.0203
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            10807
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.53
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.839
_exptl_absorpt_correction_T_max  0.9359
_exptl_absorpt_correction_T_min  0.9061
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            translucent
_exptl_crystal_density_diffrn    1.483
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             724
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.287
_refine_diff_density_min         -0.246
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     444
_refine_ls_number_reflns         5332
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.999
_refine_ls_R_factor_all          0.0304
_refine_ls_R_factor_gt           0.0268
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.08P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0927
_refine_ls_wR_factor_ref         0.0977
_reflns_number_gt                4820
_reflns_number_total             5332
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            im2149.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1576.90(10)
_cod_database_code               2224308
_cod_database_fobs_code          2224308
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn Zn1 0.852166(18) 0.917078(17) 0.648679(15) 0.03426(10) Uani d . 1 . .
C C1 1.04604(17) 0.86670(15) 0.35850(14) 0.0326(4) Uani d . 1 . .
C C2 0.95130(17) 0.75294(15) 0.32443(13) 0.0320(4) Uani d . 1 . .
C C3 0.82737(18) 0.73778(17) 0.23642(14) 0.0370(4) Uani d . 1 . .
H H3 0.8065 0.7990 0.2029 0.044 Uiso calc R 1 . .
C C4 0.7356(2) 0.63560(18) 0.19791(15) 0.0436(5) Uani d . 1 . .
H H4 0.6547 0.6274 0.1386 0.052 Uiso calc R 1 . .
C C5 0.7648(2) 0.54537(18) 0.24809(16) 0.0464(5) Uani d . 1 . .
H H5 0.7027 0.4763 0.2237 0.056 Uiso calc R 1 . .
C C6 0.8865(2) 0.55764(17) 0.33480(16) 0.0421(4) Uani d . 1 . .
H H6 0.9054 0.4958 0.3677 0.050 Uiso calc R 1 . .
C C7 0.98164(18) 0.65955(15) 0.37432(14) 0.0333(4) Uani d . 1 . .
C C8 1.11438(18) 0.65573(16) 0.46245(16) 0.0381(4) Uani d . 1 . .
C C9 1.1866(2) 0.56587(19) 0.43731(19) 0.0512(5) Uani d . 1 . .
H H9 1.1517 0.5144 0.3686 0.061 Uiso calc R 1 . .
C C10 1.3082(2) 0.5520(2) 0.5122(2) 0.0639(7) Uani d . 1 . .
H H10 1.3538 0.4910 0.4940 0.077 Uiso calc R 1 . .
C C11 1.3621(2) 0.6283(2) 0.6136(2) 0.0630(7) Uani d . 1 . .
H H11 1.4452 0.6200 0.6636 0.076 Uiso calc R 1 . .
C C12 1.2928(2) 0.7173(2) 0.64123(18) 0.0500(5) Uani d . 1 . .
H H12 1.3292 0.7684 0.7101 0.060 Uiso calc R 1 . .
C C13 1.16833(18) 0.73104(17) 0.56643(15) 0.0388(4) Uani d . 1 . .
C C14 1.09428(18) 0.82548(17) 0.60017(14) 0.0369(4) Uani d . 1 . .
C C15 0.66830(19) 0.74974(17) 0.43258(15) 0.0418(4) Uani d . 1 . .
H H15 0.7471 0.7338 0.4242 0.050 Uiso calc R 1 . .
C C16 0.5473(2) 0.68971(19) 0.35408(16) 0.0478(5) Uani d . 1 . .
H H16 0.5443 0.6338 0.2939 0.057 Uiso calc R 1 . .
C C17 0.4306(2) 0.71328(19) 0.36542(16) 0.0475(5) Uani d . 1 . .
H H17 0.3474 0.6733 0.3131 0.057 Uiso calc R 1 . .
C C18 0.43798(18) 0.79707(18) 0.45546(15) 0.0410(4) Uani d . 1 . .
H H18 0.3598 0.8147 0.4641 0.049 Uiso calc R 1 . .
C C19 0.56275(17) 0.85434(15) 0.53254(14) 0.0319(4) Uani d . 1 . .
C C20 0.57917(18) 0.94393(15) 0.63252(14) 0.0327(4) Uani d . 1 . .
C C21 0.4710(2) 0.97965(18) 0.65380(16) 0.0421(4) Uani d . 1 . .
H H21 0.3831 0.9495 0.6042 0.050 Uiso calc R 1 . .
C C22 0.4958(2) 1.0608(2) 0.74987(18) 0.0533(5) Uani d . 1 . .
H H22 0.4245 1.0858 0.7661 0.064 Uiso calc R 1 . .
C C23 0.6265(2) 1.1043(2) 0.82138(19) 0.0578(6) Uani d . 1 . .
H H23 0.6450 1.1583 0.8870 0.069 Uiso calc R 1 . .
C C24 0.7292(2) 1.06703(19) 0.79452(16) 0.0498(5) Uani d . 1 . .
H H24 0.8178 1.0976 0.8425 0.060 Uiso calc R 1 . .
C C25 0.89081(19) 0.77209(16) 0.79160(14) 0.0363(4) Uani d . 1 . .
C C26 0.97304(19) 0.72768(16) 0.88630(14) 0.0359(4) Uani d . 1 . .
C C27 1.0903(2) 0.68258(19) 0.88947(16) 0.0470(5) Uani d . 1 . .
H H27 1.1207 0.6867 0.8366 0.056 Uiso calc R 1 . .
C C28 1.1621(2) 0.63166(19) 0.97031(17) 0.0501(5) Uani d . 1 . .
H H28 1.2391 0.5997 0.9707 0.060 Uiso calc R 1 . .
C C29 1.1194(2) 0.62845(18) 1.05020(16) 0.0480(5) Uani d . 1 . .
H H29 1.1679 0.5948 1.1050 0.058 Uiso calc R 1 . .
C C30 1.00411(19) 0.67535(17) 1.04919(14) 0.0406(4) Uani d . 1 . .
H H30 0.9764 0.6733 1.1039 0.049 Uiso calc R 1 . .
C C31 0.92915(18) 0.72541(15) 0.96747(13) 0.0332(4) Uani d . 1 . .
C C32 0.81105(19) 0.78099(16) 0.97435(13) 0.0364(4) Uani d . 1 . .
C C33 0.8325(2) 0.90124(19) 1.02957(16) 0.0503(5) Uani d . 1 . .
H H33 0.9165 0.9467 1.0534 0.060 Uiso calc R 1 . .
C C34 0.7298(3) 0.9532(2) 1.04906(19) 0.0693(8) Uani d . 1 . .
H H34 0.7447 1.0338 1.0844 0.083 Uiso calc R 1 . .
C C35 0.6045(3) 0.8859(3) 1.0162(2) 0.0732(8) Uani d . 1 . .
H H35 0.5368 0.9206 1.0316 0.088 Uiso calc R 1 . .
C C36 0.5812(3) 0.7675(2) 0.9608(2) 0.0614(6) Uani d . 1 . .
H H36 0.4974 0.7223 0.9383 0.074 Uiso calc R 1 . .
C C37 0.6829(2) 0.71558(19) 0.93839(16) 0.0447(5) Uani d . 1 . .
C C38 0.64762(19) 0.58724(19) 0.87503(17) 0.0460(5) Uani d . 1 . .
N N1 0.67766(14) 0.83087(13) 0.52131(11) 0.0339(3) Uani d . 1 . .
N N2 0.70656(15) 0.98810(13) 0.70158(12) 0.0356(3) Uani d . 1 . .
O O1 1.15618(13) 0.88852(13) 0.43496(12) 0.0513(4) Uani d . 1 . .
O O2 1.00560(12) 0.94223(11) 0.30197(10) 0.0394(3) Uani d . 1 . .
O O3 0.97207(13) 0.81690(13) 0.56208(10) 0.0435(3) Uani d . 1 . .
O O4 1.17363(13) 0.91838(13) 0.67693(12) 0.0498(4) Uani d . 1 . .
H H4A 1.1282 0.9697 0.6883 0.075 Uiso calc R 1 . .
O O5 0.95305(13) 0.84733(13) 0.76743(11) 0.0459(3) Uani d . 1 . .
O O6 0.76884(14) 0.73196(13) 0.74187(11) 0.0496(4) Uani d . 1 . .
O O7 0.68307(16) 0.55831(13) 0.79382(12) 0.0510(4) Uani d . 1 . .
H H7 0.7080 0.6191 0.7820 0.076 Uiso calc R 1 . .
O O8 0.58752(17) 0.51275(17) 0.89517(14) 0.0684(5) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O5 Zn1 O2 . 2_776 94.20(5) ?
O5 Zn1 N1 . . 123.40(6) ?
O2 Zn1 N1 2_776 . 141.68(6) ?
O5 Zn1 N2 . . 100.24(6) ?
O2 Zn1 N2 2_776 . 102.90(6) ?
N1 Zn1 N2 . . 79.34(6) ?
O5 Zn1 O3 . . 85.49(5) ?
O2 Zn1 O3 2_776 . 86.73(5) ?
N1 Zn1 O3 . . 88.97(5) ?
N2 Zn1 O3 . . 168.28(5) ?
O1 C1 O2 . . 120.88(17) ?
O1 C1 C2 . . 122.88(16) ?
O2 C1 C2 . . 116.24(15) ?
C7 C2 C3 . . 118.33(17) ?
C7 C2 C1 . . 123.57(16) ?
C3 C2 C1 . . 118.08(15) ?
C4 C3 C2 . . 122.22(18) ?
C4 C3 H3 . . 118.9 ?
C2 C3 H3 . . 118.9 ?
C3 C4 C5 . . 119.23(18) ?
C3 C4 H4 . . 120.4 ?
C5 C4 H4 . . 120.4 ?
C6 C5 C4 . . 119.80(19) ?
C6 C5 H5 . . 120.1 ?
C4 C5 H5 . . 120.1 ?
C5 C6 C7 . . 121.99(18) ?
C5 C6 H6 . . 119.0 ?
C7 C6 H6 . . 119.0 ?
C6 C7 C2 . . 118.41(17) ?
C6 C7 C8 . . 116.00(16) ?
C2 C7 C8 . . 125.39(16) ?
C13 C8 C9 . . 118.14(18) ?
C13 C8 C7 . . 125.70(16) ?
C9 C8 C7 . . 116.13(18) ?
C10 C9 C8 . . 121.4(2) ?
C10 C9 H9 . . 119.3 ?
C8 C9 H9 . . 119.3 ?
C11 C10 C9 . . 120.1(2) ?
C11 C10 H10 . . 119.9 ?
C9 C10 H10 . . 119.9 ?
C10 C11 C12 . . 119.9(2) ?
C10 C11 H11 . . 120.0 ?
C12 C11 H11 . . 120.0 ?
C13 C12 C11 . . 120.5(2) ?
C13 C12 H12 . . 119.8 ?
C11 C12 H12 . . 119.8 ?
C8 C13 C12 . . 119.93(18) ?
C8 C13 C14 . . 121.07(16) ?
C12 C13 C14 . . 118.99(18) ?
O3 C14 O4 . . 122.94(17) ?
O3 C14 C13 . . 123.24(18) ?
O4 C14 C13 . . 113.81(15) ?
N1 C15 C16 . . 122.57(17) ?
N1 C15 H15 . . 118.7 ?
C16 C15 H15 . . 118.7 ?
C15 C16 C17 . . 119.07(18) ?
C15 C16 H16 . . 120.5 ?
C17 C16 H16 . . 120.5 ?
C16 C17 C18 . . 119.23(18) ?
C16 C17 H17 . . 120.4 ?
C18 C17 H17 . . 120.4 ?
C19 C18 C17 . . 119.30(17) ?
C19 C18 H18 . . 120.4 ?
C17 C18 H18 . . 120.3 ?
N1 C19 C18 . . 121.39(16) ?
N1 C19 C20 . . 116.12(15) ?
C18 C19 C20 . . 122.49(16) ?
N2 C20 C21 . . 121.67(17) ?
N2 C20 C19 . . 115.57(15) ?
C21 C20 C19 . . 122.76(16) ?
C22 C21 C20 . . 118.79(19) ?
C22 C21 H21 . . 120.6 ?
C20 C21 H21 . . 120.6 ?
C23 C22 C21 . . 119.44(19) ?
C23 C22 H22 . . 120.3 ?
C21 C22 H22 . . 120.3 ?
C24 C23 C22 . . 118.9(2) ?
C24 C23 H23 . . 120.6 ?
C22 C23 H23 . . 120.6 ?
N2 C24 C23 . . 122.3(2) ?
N2 C24 H24 . . 118.9 ?
C23 C24 H24 . . 118.9 ?
O6 C25 O5 . . 124.57(17) ?
O6 C25 C26 . . 118.81(17) ?
O5 C25 C26 . . 116.61(17) ?
C27 C26 C31 . . 119.98(16) ?
C27 C26 C25 . . 119.06(16) ?
C31 C26 C25 . . 120.87(16) ?
C26 C27 C28 . . 120.69(19) ?
C26 C27 H27 . . 119.7 ?
C28 C27 H27 . . 119.7 ?
C29 C28 C27 . . 119.74(18) ?
C29 C28 H28 . . 120.1 ?
C27 C28 H28 . . 120.1 ?
C28 C29 C30 . . 120.14(18) ?
C28 C29 H29 . . 119.9 ?
C30 C29 H29 . . 119.9 ?
C31 C30 C29 . . 120.97(18) ?
C31 C30 H30 . . 119.5 ?
C29 C30 H30 . . 119.5 ?
C30 C31 C26 . . 118.45(17) ?
C30 C31 C32 . . 118.44(16) ?
C26 C31 C32 . . 123.00(15) ?
C37 C32 C33 . . 118.25(19) ?
C37 C32 C31 . . 122.99(16) ?
C33 C32 C31 . . 118.39(18) ?
C34 C33 C32 . . 120.6(2) ?
C34 C33 H33 . . 119.7 ?
C32 C33 H33 . . 119.7 ?
C33 C34 C35 . . 120.5(2) ?
C33 C34 H34 . . 119.8 ?
C35 C34 H34 . . 119.8 ?
C34 C35 C36 . . 119.8(2) ?
C34 C35 H35 . . 120.1 ?
C36 C35 H35 . . 120.1 ?
C37 C36 C35 . . 120.0(3) ?
C37 C36 H36 . . 120.0 ?
C35 C36 H36 . . 120.0 ?
C32 C37 C36 . . 120.9(2) ?
C32 C37 C38 . . 122.62(17) ?
C36 C37 C38 . . 116.5(2) ?
O8 C38 O7 . . 120.5(2) ?
O8 C38 C37 . . 122.5(2) ?
O7 C38 C37 . . 117.02(18) ?
C15 N1 C19 . . 118.43(16) ?
C15 N1 Zn1 . . 126.19(12) ?
C19 N1 Zn1 . . 115.26(12) ?
C20 N2 C24 . . 118.92(16) ?
C20 N2 Zn1 . . 113.63(11) ?
C24 N2 Zn1 . . 127.42(14) ?
C1 O2 Zn1 . 2_776 111.14(11) ?
C14 O3 Zn1 . . 123.99(12) ?
C14 O4 H4A . . 109.5 ?
C25 O5 Zn1 . . 119.66(12) ?
C38 O7 H7 . . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Zn1 O5 . 1.9795(12) ?
Zn1 O2 2_776 1.9941(13) ?
Zn1 N1 . 2.0456(15) ?
Zn1 N2 . 2.1203(15) ?
Zn1 O3 . 2.2940(13) ?
C1 O1 . 1.226(2) ?
C1 O2 . 1.295(2) ?
C1 C2 . 1.500(3) ?
C2 C7 . 1.407(2) ?
C2 C3 . 1.401(2) ?
C3 C4 . 1.373(3) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.376(3) ?
C4 H4 . 0.9300 ?
C5 C6 . 1.382(3) ?
C5 H5 . 0.9300 ?
C6 C7 . 1.389(3) ?
C6 H6 . 0.9300 ?
C7 C8 . 1.504(2) ?
C8 C13 . 1.396(3) ?
C8 C9 . 1.400(3) ?
C9 C10 . 1.378(3) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.374(4) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.382(3) ?
C11 H11 . 0.9300 ?
C12 C13 . 1.398(3) ?
C12 H12 . 0.9300 ?
C13 C14 . 1.491(3) ?
C14 O3 . 1.215(2) ?
C14 O4 . 1.319(2) ?
C15 N1 . 1.346(2) ?
C15 C16 . 1.370(3) ?
C15 H15 . 0.9300 ?
C16 C17 . 1.371(3) ?
C16 H16 . 0.9300 ?
C17 C18 . 1.382(3) ?
C17 H17 . 0.9300 ?
C18 C19 . 1.381(3) ?
C18 H18 . 0.9300 ?
C19 N1 . 1.351(2) ?
C19 C20 . 1.487(2) ?
C20 N2 . 1.338(2) ?
C20 C21 . 1.381(3) ?
C21 C22 . 1.378(3) ?
C21 H21 . 0.9300 ?
C22 C23 . 1.372(3) ?
C22 H22 . 0.9300 ?
C23 C24 . 1.369(3) ?
C23 H23 . 0.9300 ?
C24 N2 . 1.339(3) ?
C24 H24 . 0.9300 ?
C25 O6 . 1.242(2) ?
C25 O5 . 1.264(2) ?
C25 C26 . 1.505(2) ?
C26 C27 . 1.390(3) ?
C26 C31 . 1.399(3) ?
C27 C28 . 1.382(3) ?
C27 H27 . 0.9300 ?
C28 C29 . 1.376(3) ?
C28 H28 . 0.9300 ?
C29 C30 . 1.387(3) ?
C29 H29 . 0.9300 ?
C30 C31 . 1.393(2) ?
C30 H30 . 0.9300 ?
C31 C32 . 1.491(3) ?
C32 C37 . 1.400(3) ?
C32 C33 . 1.398(3) ?
C33 C34 . 1.383(3) ?
C33 H33 . 0.9300 ?
C34 C35 . 1.391(4) ?
C34 H34 . 0.9300 ?
C35 C36 . 1.378(4) ?
C35 H35 . 0.9300 ?
C36 C37 . 1.390(3) ?
C36 H36 . 0.9300 ?
C37 C38 . 1.500(3) ?
C38 O8 . 1.208(3) ?
C38 O7 . 1.318(3) ?
O2 Zn1 2_776 1.9941(13) ?
O4 H4A . 0.8200 ?
O7 H7 . 0.8200 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O4 H4A O2 2_776 0.82 1.85 2.6545(19) 167.3
O7 H7 O6 . 0.82 1.74 2.551(2) 170.4
