#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/52/2225267.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2225267
loop_
_publ_author_name
'Wardell, James L.'
'Wardell, Solange M. S. V.'
'Tiekink, Edward R. T.'
'de Lima, Geraldo M.'
_publ_section_title
;Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium)
 tetrachloridodiphenylstannate(IV)
;
_journal_coeditor_code           HB5338
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m336
_journal_page_last               m337
_journal_paper_doi               10.1107/S1600536810006574
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '(C17 H17 F6 N2 O)2 [Sn (C6 H5)2 Cl4]'
_chemical_formula_moiety         '2(C17 H17 F6 N2 O +), C12 H10 Cl4 Sn 2-'
_chemical_formula_sum            'C46 H44 Cl4 F12 N4 O2 Sn'
_chemical_formula_weight         1173.34
_chemical_name_systematic
;Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium)
tetrachloridodiphenylstannate(IV)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.739(3)
_cell_angle_beta                 91.671(4)
_cell_angle_gamma                97.622(4)
_cell_formula_units_Z            1
_cell_length_a                   8.5578(4)
_cell_length_b                   9.1479(7)
_cell_length_c                   15.9866(11)
_cell_measurement_reflns_used    37314
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      2.9
_cell_volume                     1197.06(14)
_computing_cell_refinement
'DENZO (Otwinowski & Minor, 1997) and COLLECT (Hooft, 1998)'
_computing_data_collection       'COLLECT (Hooft, 1998)'
_computing_data_reduction
'DENZO (Otwinowski & Minor, 1997) and COLLECT (Hooft, 1998)'
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 9.091
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  '10 cm confocal mirrors'
_diffrn_radiation_source         'Enraf Nonius FR591 rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.094
_diffrn_reflns_av_sigmaI/netI    0.078
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            16610
_diffrn_reflns_theta_full        25.0
_diffrn_reflns_theta_max         25.0
_diffrn_reflns_theta_min         3.0
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.847
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.843
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2007)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.628
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       lath
_exptl_crystal_F_000             590
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.63
_refine_diff_density_min         -0.61
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.03
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     314
_refine_ls_number_reflns         4164
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.03
_refine_ls_R_factor_all          0.097
_refine_ls_R_factor_gt           0.070
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_max_lt       0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1P)²+9.2689P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.175
_refine_ls_wR_factor_ref         0.198
_reflns_number_gt                3313
_reflns_number_total             4164
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hb5338.cif
_cod_data_source_block           I
_cod_database_code               2225267
_cod_database_fobs_code          2225267
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F F1 1.4043(6) 0.6359(8) 0.5099(4) 0.0544(16) Uani d . 1 . .
F F2 1.2203(6) 0.5658(6) 0.5835(4) 0.0440(14) Uani d . 1 . .
F F3 1.3067(6) 0.8005(6) 0.6046(3) 0.0444(14) Uani d . 1 . .
F F4 0.7444(5) 0.7621(5) 0.6107(3) 0.0313(11) Uani d . 1 . .
F F5 0.8916(5) 0.9772(5) 0.6216(3) 0.0352(12) Uani d . 1 . .
F F6 0.6421(5) 0.9568(6) 0.5959(3) 0.0357(12) Uani d . 1 . .
O O1 1.2216(6) 0.5258(7) 0.2147(4) 0.0298(13) Uani d . 1 . .
H H1O 1.2615 0.5781 0.1824 0.045 Uiso calc R 1 . .
N N1 1.0279(7) 0.7459(7) 0.5071(4) 0.0192(13) Uani d . 1 . .
N N2 0.9662(8) 0.3538(7) 0.1053(4) 0.0253(15) Uani d . 1 . .
H H1N 0.9283 0.4242 0.0810 0.030 Uiso calc R 1 . .
H H2N 1.0704 0.3526 0.0929 0.030 Uiso calc R 1 . .
C C1 1.1479(8) 0.6823(9) 0.4755(5) 0.0216(16) Uani d . 1 . .
C C2 1.1698(9) 0.6207(9) 0.3865(5) 0.0229(17) Uani d . 1 . .
H H2 1.2600 0.5738 0.3684 0.027 Uiso calc R 1 . .
C C3 1.0535(8) 0.6320(8) 0.3274(5) 0.0203(16) Uani d . 1 . .
C C4 0.9256(8) 0.7103(8) 0.3568(5) 0.0175(15) Uani d . 1 . .
C C5 0.8083(8) 0.7384(8) 0.3013(5) 0.0184(15) Uani d . 1 . .
H H5 0.8148 0.7064 0.2403 0.022 Uiso calc R 1 . .
C C6 0.6856(9) 0.8109(9) 0.3343(5) 0.0243(17) Uani d . 1 . .
H H6 0.6084 0.8298 0.2960 0.029 Uiso calc R 1 . .
C C7 0.6721(9) 0.8581(9) 0.4245(5) 0.0257(17) Uani d . 1 . .
H H7 0.5838 0.9052 0.4461 0.031 Uiso calc R 1 . .
C C8 0.7842(9) 0.8372(8) 0.4816(5) 0.0221(16) Uani d . 1 . .
C C9 0.9155(8) 0.7627(8) 0.4485(5) 0.0191(15) Uani d . 1 . .
C C10 1.2703(9) 0.6709(9) 0.5419(5) 0.0259(17) Uani d . 1 . .
C C11 0.7672(9) 0.8840(9) 0.5768(5) 0.0261(18) Uani d . 1 . .
C C12 1.0672(8) 0.5601(8) 0.2328(5) 0.0222(17) Uani d . 1 . .
H H12 1.0380 0.6303 0.1981 0.027 Uiso calc R 1 . .
C C13 0.9577(9) 0.4048(9) 0.2023(5) 0.0231(17) Uani d . 1 . .
H H13 0.8468 0.4208 0.2157 0.028 Uiso calc R 1 . .
C C14 0.8746(10) 0.1981(10) 0.0636(6) 0.0317(19) Uani d . 1 . .
H H14A 0.8919 0.1690 0.0009 0.038 Uiso calc R 1 . .
H H14B 0.7603 0.2011 0.0700 0.038 Uiso calc R 1 . .
C C15 0.9281(10) 0.0804(10) 0.1060(6) 0.0308(19) Uani d . 1 . .
H H15A 0.8642 -0.0204 0.0801 0.037 Uiso calc R 1 . .
H H15B 1.0401 0.0713 0.0951 0.037 Uiso calc R 1 . .
C C16 0.9102(10) 0.1257(10) 0.2019(6) 0.0317(19) Uani d . 1 . .
H H16A 0.9485 0.0493 0.2285 0.038 Uiso calc R 1 . .
H H16B 0.7971 0.1274 0.2129 0.038 Uiso calc R 1 . .
C C17 1.0039(9) 0.2834(9) 0.2434(5) 0.0241(17) Uani d . 1 . .
H H17A 0.9859 0.3127 0.3060 0.029 Uiso calc R 1 . .
H H17B 1.1180 0.2781 0.2377 0.029 Uiso calc R 1 . .
Sn Sn 0.5000 0.5000 1.0000 0.0191(3) Uani d S 1 . .
Cl Cl1 0.2014(2) 0.3929(2) 0.94923(12) 0.0246(4) Uani d . 1 . .
Cl Cl2 0.5841(2) 0.2788(2) 0.88282(13) 0.0306(5) Uani d . 1 . .
C C18 0.5166(8) 0.6443(8) 0.9137(5) 0.0193(16) Uani d . 1 . .
C C19 0.5741(9) 0.7987(8) 0.9438(5) 0.0228(17) Uani d . 1 . .
H H19 0.6049 0.8408 1.0036 0.027 Uiso calc R 1 . .
C C20 0.5871(9) 0.8925(9) 0.8875(6) 0.0291(19) Uani d . 1 . .
H H20 0.6235 0.9987 0.9091 0.035 Uiso calc R 1 . .
C C21 0.5471(10) 0.8308(10) 0.7998(6) 0.0308(19) Uani d . 1 . .
H H21 0.5603 0.8944 0.7611 0.037 Uiso calc R 1 . .
C C22 0.4875(9) 0.6764(9) 0.7677(5) 0.0271(18) Uani d . 1 . .
H H22 0.4569 0.6345 0.7078 0.033 Uiso calc R 1 . .
C C23 0.4740(8) 0.5857(9) 0.8251(5) 0.0234(17) Uani d . 1 . .
H H23 0.4346 0.4801 0.8037 0.028 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C12 O1 H1O . . 109.5 ?
C1 N1 C9 . . 116.8(6) ?
C14 N2 C13 . . 114.1(6) ?
C14 N2 H1N . . 108.7 ?
C13 N2 H1N . . 108.7 ?
C14 N2 H2N . . 108.7 ?
C13 N2 H2N . . 108.7 ?
H1N N2 H2N . . 107.6 ?
N1 C1 C2 . . 126.4(7) ?
N1 C1 C10 . . 114.9(7) ?
C2 C1 C10 . . 118.7(6) ?
C3 C2 C1 . . 116.9(7) ?
C3 C2 H2 . . 121.5 ?
C1 C2 H2 . . 121.5 ?
C2 C3 C4 . . 119.8(7) ?
C2 C3 C12 . . 118.7(7) ?
C4 C3 C12 . . 121.6(7) ?
C5 C4 C3 . . 124.0(7) ?
C5 C4 C9 . . 118.7(6) ?
C3 C4 C9 . . 117.3(7) ?
C6 C5 C4 . . 120.8(7) ?
C6 C5 H5 . . 119.6 ?
C4 C5 H5 . . 119.6 ?
C5 C6 C7 . . 120.8(7) ?
C5 C6 H6 . . 119.6 ?
C7 C6 H6 . . 119.6 ?
C8 C7 C6 . . 121.1(7) ?
C8 C7 H7 . . 119.4 ?
C6 C7 H7 . . 119.4 ?
C7 C8 C9 . . 119.2(7) ?
C7 C8 C11 . . 120.8(7) ?
C9 C8 C11 . . 120.0(7) ?
N1 C9 C4 . . 122.6(6) ?
N1 C9 C8 . . 118.0(7) ?
C4 C9 C8 . . 119.4(6) ?
F1 C10 F2 . . 106.4(7) ?
F1 C10 F3 . . 106.4(7) ?
F2 C10 F3 . . 104.6(7) ?
F1 C10 C1 . . 114.0(7) ?
F2 C10 C1 . . 112.1(6) ?
F3 C10 C1 . . 112.6(6) ?
F5 C11 F6 . . 106.3(6) ?
F5 C11 F4 . . 106.7(6) ?
F6 C11 F4 . . 105.9(6) ?
F5 C11 C8 . . 113.8(6) ?
F6 C11 C8 . . 111.7(6) ?
F4 C11 C8 . . 111.8(6) ?
O1 C12 C3 . . 112.3(6) ?
O1 C12 C13 . . 105.2(6) ?
C3 C12 C13 . . 111.0(6) ?
O1 C12 H12 . . 109.4 ?
C3 C12 H12 . . 109.4 ?
C13 C12 H12 . . 109.4 ?
N2 C13 C17 . . 110.0(6) ?
N2 C13 C12 . . 106.0(6) ?
C17 C13 C12 . . 113.8(6) ?
N2 C13 H13 . . 109.0 ?
C17 C13 H13 . . 109.0 ?
C12 C13 H13 . . 109.0 ?
N2 C14 C15 . . 110.0(7) ?
N2 C14 H14A . . 109.7 ?
C15 C14 H14A . . 109.7 ?
N2 C14 H14B . . 109.7 ?
C15 C14 H14B . . 109.7 ?
H14A C14 H14B . . 108.2 ?
C16 C15 C14 . . 110.8(7) ?
C16 C15 H15A . . 109.5 ?
C14 C15 H15A . . 109.5 ?
C16 C15 H15B . . 109.5 ?
C14 C15 H15B . . 109.5 ?
H15A C15 H15B . . 108.1 ?
C15 C16 C17 . . 110.7(7) ?
C15 C16 H16A . . 109.5 ?
C17 C16 H16A . . 109.5 ?
C15 C16 H16B . . 109.5 ?
C17 C16 H16B . . 109.5 ?
H16A C16 H16B . . 108.1 ?
C13 C17 C16 . . 112.4(6) ?
C13 C17 H17A . . 109.1 ?
C16 C17 H17A . . 109.1 ?
C13 C17 H17B . . 109.1 ?
C16 C17 H17B . . 109.1 ?
H17A C17 H17B . . 107.9 ?
C18 Sn C18 2_667 . 180.0 ?
C18 Sn Cl2 2_667 2_667 91.2(2) ?
C18 Sn Cl2 . 2_667 88.8(2) ?
C18 Sn Cl2 2_667 . 88.8(2) ?
C18 Sn Cl2 . . 91.2(2) ?
Cl2 Sn Cl2 2_667 . 180.0 ?
C18 Sn Cl1 2_667 2_667 92.46(19) ?
C18 Sn Cl1 . 2_667 87.54(19) ?
Cl2 Sn Cl1 2_667 2_667 89.46(6) ?
Cl2 Sn Cl1 . 2_667 90.54(6) ?
C18 Sn Cl1 2_667 . 87.54(19) ?
C18 Sn Cl1 . . 92.46(19) ?
Cl2 Sn Cl1 2_667 . 90.54(6) ?
Cl2 Sn Cl1 . . 89.46(6) ?
Cl1 Sn Cl1 2_667 . 180.0 ?
C19 C18 C23 . . 118.1(7) ?
C19 C18 Sn . . 120.6(6) ?
C23 C18 Sn . . 121.2(6) ?
C18 C19 C20 . . 120.8(8) ?
C18 C19 H19 . . 119.6 ?
C20 C19 H19 . . 119.6 ?
C21 C20 C19 . . 119.9(8) ?
C21 C20 H20 . . 120.1 ?
C19 C20 H20 . . 120.1 ?
C20 C21 C22 . . 120.7(8) ?
C20 C21 H21 . . 119.6 ?
C22 C21 H21 . . 119.6 ?
C23 C22 C21 . . 118.3(8) ?
C23 C22 H22 . . 120.8 ?
C21 C22 H22 . . 120.8 ?
C22 C23 C18 . . 122.2(7) ?
C22 C23 H23 . . 118.9 ?
C18 C23 H23 . . 118.9 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
F1 C10 . 1.314(9) ?
F2 C10 . 1.334(10) ?
F3 C10 . 1.336(9) ?
F4 C11 . 1.353(9) ?
F5 C11 . 1.333(9) ?
F6 C11 . 1.337(9) ?
O1 C12 . 1.419(8) ?
O1 H1O . 0.8400 ?
N1 C1 . 1.299(9) ?
N1 C9 . 1.373(10) ?
N2 C14 . 1.509(10) ?
N2 C13 . 1.509(10) ?
N2 H1N . 0.9200 ?
N2 H2N . 0.9200 ?
C1 C2 . 1.418(11) ?
C1 C10 . 1.502(11) ?
C2 C3 . 1.385(11) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.414(10) ?
C3 C12 . 1.503(10) ?
C4 C5 . 1.411(10) ?
C4 C9 . 1.431(10) ?
C5 C6 . 1.363(11) ?
C5 H5 . 0.9500 ?
C6 C7 . 1.409(11) ?
C6 H6 . 0.9500 ?
C7 C8 . 1.369(11) ?
C7 H7 . 0.9500 ?
C8 C9 . 1.436(10) ?
C8 C11 . 1.490(11) ?
C12 C13 . 1.549(11) ?
C12 H12 . 1.0000 ?
C13 C17 . 1.515(11) ?
C13 H13 . 1.0000 ?
C14 C15 . 1.521(12) ?
C14 H14A . 0.9900 ?
C14 H14B . 0.9900 ?
C15 C16 . 1.501(12) ?
C15 H15A . 0.9900 ?
C15 H15B . 0.9900 ?
C16 C17 . 1.529(11) ?
C16 H16A . 0.9900 ?
C16 H16B . 0.9900 ?
C17 H17A . 0.9900 ?
C17 H17B . 0.9900 ?
Sn C18 2_667 2.135(7) ?
Sn C18 . 2.135(7) y
Sn Cl2 2_667 2.5804(19) ?
Sn Cl2 . 2.5804(19) y
Sn Cl1 2_667 2.6382(18) ?
Sn Cl1 . 2.6382(18) y
C18 C19 . 1.387(11) ?
C18 C23 . 1.399(11) ?
C19 C20 . 1.390(11) ?
C19 H19 . 0.9500 ?
C20 C21 . 1.385(12) ?
C20 H20 . 0.9500 ?
C21 C22 . 1.394(12) ?
C21 H21 . 0.9500 ?
C22 C23 . 1.383(11) ?
C22 H22 . 0.9500 ?
C23 H23 . 0.9500 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N2 H2n O1 1_555 0.92 2.39 2.789(9) 106
N2 H1n Cl1 2_666 0.92 2.27 3.166(7) 166
N2 H2n Cl1 1_654 0.92 2.67 3.311(7) 127
O1 H1o Cl2 2_766 0.84 2.21 3.028(6) 167
C20 H20 Cl2 1_565 0.95 2.76 3.557(9) 142
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C9 N1 C1 C2 . . . . -3.9(11) ?
C9 N1 C1 C10 . . . . 178.1(6) ?
N1 C1 C2 C3 . . . . 1.4(11) ?
C10 C1 C2 C3 . . . . 179.3(7) ?
C1 C2 C3 C4 . . . . 3.6(10) ?
C1 C2 C3 C12 . . . . -176.4(6) ?
C2 C3 C4 C5 . . . . 174.8(7) ?
C12 C3 C4 C5 . . . . -5.1(11) ?
C2 C3 C4 C9 . . . . -5.6(10) ?
C12 C3 C4 C9 . . . . 174.4(6) ?
C3 C4 C5 C6 . . . . 178.1(7) ?
C9 C4 C5 C6 . . . . -1.4(10) ?
C4 C5 C6 C7 . . . . -0.7(11) ?
C5 C6 C7 C8 . . . . 2.2(12) ?
C6 C7 C8 C9 . . . . -1.4(11) ?
C6 C7 C8 C11 . . . . -178.5(7) ?
C1 N1 C9 C4 . . . . 1.4(10) ?
C1 N1 C9 C8 . . . . -178.0(6) ?
C5 C4 C9 N1 . . . . -177.2(7) ?
C3 C4 C9 N1 . . . . 3.2(10) ?
C5 C4 C9 C8 . . . . 2.1(10) ?
C3 C4 C9 C8 . . . . -177.4(6) ?
C7 C8 C9 N1 . . . . 178.7(7) ?
C11 C8 C9 N1 . . . . -4.2(10) ?
C7 C8 C9 C4 . . . . -0.7(10) ?
C11 C8 C9 C4 . . . . 176.4(7) ?
N1 C1 C10 F1 . . . . -166.8(7) ?
C2 C1 C10 F1 . . . . 15.1(10) ?
N1 C1 C10 F2 . . . . 72.2(9) ?
C2 C1 C10 F2 . . . . -106.0(8) ?
N1 C1 C10 F3 . . . . -45.4(9) ?
C2 C1 C10 F3 . . . . 136.4(7) ?
C7 C8 C11 F5 . . . . -125.8(8) ?
C9 C8 C11 F5 . . . . 57.1(9) ?
C7 C8 C11 F6 . . . . -5.4(10) ?
C9 C8 C11 F6 . . . . 177.6(6) ?
C7 C8 C11 F4 . . . . 113.1(8) ?
C9 C8 C11 F4 . . . . -63.9(9) ?
C2 C3 C12 O1 . . . . -16.4(9) ?
C4 C3 C12 O1 . . . . 163.5(6) ?
C2 C3 C12 C13 . . . . 100.9(7) ?
C4 C3 C12 C13 . . . . -79.1(8) ?
C14 N2 C13 C17 . . . . 52.8(8) ?
C14 N2 C13 C12 . . . . 176.3(6) ?
O1 C12 C13 N2 . . . . -65.2(7) ?
C3 C12 C13 N2 . . . . 173.1(6) ?
O1 C12 C13 C17 . . . . 55.8(8) ?
C3 C12 C13 C17 . . . . -65.9(8) ?
C13 N2 C14 C15 . . . . -55.2(9) ?
N2 C14 C15 C16 . . . . 56.7(9) ?
C14 C15 C16 C17 . . . . -57.5(9) ?
N2 C13 C17 C16 . . . . -52.3(8) ?
C12 C13 C17 C16 . . . . -171.1(6) ?
C15 C16 C17 C13 . . . . 56.0(9) ?
Cl2 Sn C18 C19 2_667 . . . 37.8(5) ?
Cl2 Sn C18 C19 . . . . -142.2(5) ?
Cl1 Sn C18 C19 2_667 . . . -51.7(5) ?
Cl1 Sn C18 C19 . . . . 128.3(5) ?
Cl2 Sn C18 C23 2_667 . . . -143.9(5) ?
Cl2 Sn C18 C23 . . . . 36.1(5) ?
Cl1 Sn C18 C23 2_667 . . . 126.6(5) ?
Cl1 Sn C18 C23 . . . . -53.4(5) ?
C23 C18 C19 C20 . . . . 0.7(10) ?
Sn C18 C19 C20 . . . . 179.1(5) ?
C18 C19 C20 C21 . . . . -2.0(11) ?
C19 C20 C21 C22 . . . . 2.6(12) ?
C20 C21 C22 C23 . . . . -1.9(11) ?
C21 C22 C23 C18 . . . . 0.6(11) ?
C19 C18 C23 C22 . . . . 0.0(10) ?
Sn C18 C23 C22 . . . . -178.4(5) ?
