#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/84/2228433.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2228433
loop_
_publ_author_name
'Xu, Hui-Jun'
'Li, Yu'
'Du, Qing-Yang'
_publ_section_title
;
 cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ³N,O,N'](triphenylphosphane-κP)ruthenium(II)
 methanol monosolvate
;
_journal_coeditor_code           JH2228
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1679
_journal_paper_doi               10.1107/S1600536810047033
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ru Cl2 (C16 H14 N2 O) (C18 H15 P)], C H4 O'
_chemical_formula_moiety         'C34 H29 Cl2 N2 O P Ru, C H4 O'
_chemical_formula_sum            'C35 H33 Cl2 N2 O2 P Ru'
_chemical_formula_weight         716.57
_chemical_name_systematic
;
cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-
κ³N,O,N'](triphenylphosphane-κP)ruthenium(II)
methanol monosolvate
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.868(2)
_cell_length_b                   11.480(2)
_cell_length_c                   31.6351(18)
_cell_measurement_reflns_used    592
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      13.18
_cell_measurement_theta_min      2.38
_cell_volume                     3220.6(9)
_computing_cell_refinement       'SAINT-Plus (Bruker, 2003)'
_computing_data_collection       'SMART (Bruker, 2003)'
_computing_data_reduction        'SAINT-Plus (Bruker, 2003)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_av_sigmaI/netI    0.0473
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            17669
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.89
_exptl_absorpt_coefficient_mu    0.737
_exptl_absorpt_correction_T_max  0.8547
_exptl_absorpt_correction_T_min  0.8202
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2003)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.478
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1464
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.703
_refine_diff_density_min         -0.909
_refine_ls_abs_structure_details 'Flack (1983), 2722 Friedel pairs'
_refine_ls_abs_structure_Flack   0.06(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         6304
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0597
_refine_ls_R_factor_gt           0.0485
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.06P)²+1.99P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1135
_refine_ls_wR_factor_ref         0.1167
_reflns_number_gt                5620
_reflns_number_total             6304
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            jh2228.cif
_cod_data_source_block           I
_cod_original_cell_volume        3220.7(10)
_cod_database_code               2228433
_cod_database_fobs_code          2228433
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C C1 0.1967(7) 0.4572(6) 0.6458(2) 0.0547(15) Uani d . 1 . .
H H1 0.1733 0.4993 0.6216 0.066 Uiso calc R 1 . .
C C2 0.0977(8) 0.3754(6) 0.6601(2) 0.0547(16) Uani d . 1 . .
H H2 0.0091 0.3628 0.6451 0.066 Uiso calc R 1 . .
C C3 0.1231(7) 0.3129(5) 0.69486(18) 0.0481(14) Uani d . 1 . .
H H3 0.0548 0.2561 0.7033 0.058 Uiso calc R 1 . .
C C4 0.2514(7) 0.3333(5) 0.71807(18) 0.0482(14) Uani d . 1 . .
H H4 0.2707 0.2934 0.7431 0.058 Uiso calc R 1 . .
C C5 0.3511(6) 0.4166(5) 0.70246(16) 0.0396(11) Uani d . 1 . .
C C6 0.4939(7) 0.4460(5) 0.72707(17) 0.0455(12) Uani d . 1 . .
H H6A 0.4734 0.5064 0.7477 0.055 Uiso calc R 1 . .
H H6B 0.5309 0.3776 0.7418 0.055 Uiso calc R 1 . .
C C7 0.7414(7) 0.5321(5) 0.71092(17) 0.0406(12) Uani d . 1 . .
C C8 0.8219(7) 0.4838(5) 0.74429(15) 0.0424(13) Uani d . 1 . .
H H8 0.7791 0.4250 0.7606 0.051 Uiso calc R 1 . .
C C9 0.9665(7) 0.5233(5) 0.75332(18) 0.0512(17) Uani d . 1 . .
H H9 1.0204 0.4910 0.7757 0.061 Uiso calc R 1 . .
C C10 1.0306(6) 0.6112(5) 0.72899(18) 0.0499(15) Uani d . 1 . .
H H10 1.1273 0.6376 0.7350 0.060 Uiso calc R 1 . .
C C11 0.9500(6) 0.6594(5) 0.69561(19) 0.0416(13) Uani d . 1 . .
C C12 0.8054(6) 0.6199(5) 0.68658(18) 0.0409(12) Uani d . 1 . .
C C13 0.7889(7) 0.7560(5) 0.6289(2) 0.0498(15) Uani d . 1 . .
C C14 0.9335(6) 0.7956(5) 0.63790(18) 0.0481(14) Uani d . 1 . .
H H14 0.9764 0.8543 0.6216 0.058 Uiso calc R 1 . .
C C15 1.0141(8) 0.7473(4) 0.67127(15) 0.0461(13) Uani d . 1 . .
H H15 1.1108 0.7737 0.6773 0.055 Uiso calc R 1 . .
C C16 0.6974(8) 0.8152(6) 0.59660(19) 0.0556(16) Uani d . 1 . .
H H16A 0.6168 0.7648 0.5878 0.083 Uiso calc R 1 . .
H H16B 0.7595 0.8337 0.5727 0.083 Uiso calc R 1 . .
H H16C 0.6561 0.8855 0.6082 0.083 Uiso calc R 1 . .
C C17 0.4278(6) 0.3833(5) 0.56457(16) 0.0389(12) Uani d . 1 . .
C C18 0.3214(7) 0.4467(5) 0.54310(19) 0.0492(15) Uani d . 1 . .
H H18 0.3255 0.5276 0.5434 0.059 Uiso calc R 1 . .
C C19 0.2062(7) 0.3896(6) 0.52066(19) 0.0520(16) Uani d . 1 . .
H H19 0.1352 0.4319 0.5054 0.062 Uiso calc R 1 . .
C C20 0.2012(7) 0.2744(5) 0.5218(2) 0.0510(15) Uani d . 1 . .
H H20 0.1250 0.2367 0.5069 0.061 Uiso calc R 1 . .
C C21 0.3002(7) 0.2094(6) 0.54320(19) 0.0514(15) Uani d . 1 . .
H H21 0.2917 0.1287 0.5429 0.062 Uiso calc R 1 . .
C C22 0.4163(8) 0.2625(5) 0.5660(2) 0.0526(15) Uani d . 1 . .
H H22 0.4840 0.2183 0.5818 0.063 Uiso calc R 1 . .
C C23 0.6972(6) 0.3305(5) 0.61146(17) 0.0397(12) Uani d . 1 . .
C C24 0.6582(7) 0.2702(5) 0.64730(19) 0.0469(13) Uani d . 1 . .
H H24 0.5781 0.2966 0.6637 0.056 Uiso calc R 1 . .
C C25 0.7358(8) 0.1700(5) 0.65976(17) 0.0490(15) Uani d . 1 . .
H H25 0.7136 0.1346 0.6855 0.059 Uiso calc R 1 . .
C C26 0.8444(8) 0.1244(5) 0.63414(19) 0.0529(16) Uani d . 1 . .
H H26 0.8935 0.0559 0.6416 0.063 Uiso calc R 1 . .
C C27 0.8805(6) 0.1802(4) 0.59724(17) 0.0401(12) Uani d . 1 . .
H H27 0.9554 0.1497 0.5799 0.048 Uiso calc R 1 . .
C C28 0.8063(7) 0.2826(5) 0.58537(16) 0.0407(12) Uani d . 1 . .
H H28 0.8302 0.3186 0.5599 0.049 Uiso calc R 1 . .
C C29 0.6986(7) 0.5251(5) 0.55537(18) 0.0456(14) Uani d . 1 . .
C C30 0.6518(7) 0.5601(5) 0.51666(17) 0.0462(14) Uani d . 1 . .
H H30 0.5546 0.5422 0.5077 0.055 Uiso calc R 1 . .
C C31 0.7457(7) 0.6215(5) 0.4905(2) 0.0510(16) Uani d . 1 . .
H H31 0.7118 0.6441 0.4639 0.061 Uiso calc R 1 . .
C C32 0.8927(7) 0.6507(5) 0.50324(19) 0.0485(15) Uani d . 1 . .
H H32 0.9544 0.6944 0.4855 0.058 Uiso calc R 1 . .
C C33 0.9447(7) 0.6144(5) 0.54189(19) 0.0499(15) Uani d . 1 . .
H H33 1.0441 0.6272 0.5500 0.060 Uiso calc R 1 . .
C C34 0.8443(7) 0.5582(5) 0.56832(18) 0.0446(14) Uani d . 1 . .
H H34 0.8742 0.5415 0.5958 0.054 Uiso calc R 1 . .
C C35 0.3573(7) 1.0239(6) 0.6490(2) 0.0559(16) Uani d . 1 . .
H H35A 0.3218 1.1028 0.6508 0.084 Uiso calc R 1 . .
H H35B 0.4463 1.0214 0.6317 0.084 Uiso calc R 1 . .
H H35C 0.3806 0.9956 0.6768 0.084 Uiso calc R 1 . .
Cl Cl1 0.43030(16) 0.71863(12) 0.70588(4) 0.0412(3) Uani d . 1 . .
Cl Cl2 0.35481(17) 0.69468(12) 0.60054(5) 0.0474(3) Uani d . 1 . .
N N1 0.3286(5) 0.4787(4) 0.66606(13) 0.0385(10) Uani d . 1 . .
N N2 0.7249(5) 0.6682(4) 0.65321(14) 0.0433(11) Uani d . 1 . .
O O1 0.6057(4) 0.4866(3) 0.69627(11) 0.0388(8) Uani d . 1 . .
O O2 0.2468(5) 0.9549(4) 0.63110(15) 0.0588(12) Uani d . 1 . .
H H2A 0.2852 0.8955 0.6216 0.071 Uiso calc R 1 . .
P P1 0.57943(18) 0.45692(12) 0.59589(4) 0.0401(3) Uani d . 1 . .
Ru Ru1 0.50826(5) 0.58272(3) 0.648543(12) 0.03625(11) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N1 C1 C2 . . 121.7(7) ?
N1 C1 H1 . . 119.2 ?
C2 C1 H1 . . 119.2 ?
C3 C2 C1 . . 122.4(7) ?
C3 C2 H2 . . 118.8 ?
C1 C2 H2 . . 118.8 ?
C2 C3 C4 . . 119.3(6) ?
C2 C3 H3 . . 120.4 ?
C4 C3 H3 . . 120.4 ?
C3 C4 C5 . . 117.0(5) ?
C3 C4 H4 . . 121.5 ?
C5 C4 H4 . . 121.5 ?
N1 C5 C4 . . 124.3(5) ?
N1 C5 C6 . . 115.8(5) ?
C4 C5 C6 . . 119.9(5) ?
O1 C6 C5 . . 107.0(4) ?
O1 C6 H6A . . 110.3 ?
C5 C6 H6A . . 110.3 ?
O1 C6 H6B . . 110.3 ?
C5 C6 H6B . . 110.3 ?
H6A C6 H6B . . 108.6 ?
C8 C7 C12 . . 120.0(5) ?
C8 C7 O1 . . 123.2(5) ?
C12 C7 O1 . . 116.2(5) ?
C9 C8 C7 . . 120.0(5) ?
C9 C8 H8 . . 120.0 ?
C7 C8 H8 . . 120.0 ?
C8 C9 C10 . . 120.0(5) ?
C8 C9 H9 . . 120.0 ?
C10 C9 H9 . . 120.0 ?
C11 C10 C9 . . 120.0(5) ?
C11 C10 H10 . . 120.0 ?
C9 C10 H10 . . 120.0 ?
C12 C11 C10 . . 120.0(5) ?
C12 C11 C15 . . 120.0(6) ?
C10 C11 C15 . . 120.0(5) ?
C11 C12 N2 . . 120.0(5) ?
C11 C12 C7 . . 120.0(5) ?
N2 C12 C7 . . 120.0(5) ?
N2 C13 C14 . . 120.0(6) ?
N2 C13 C16 . . 119.6(6) ?
C14 C13 C16 . . 120.1(6) ?
C13 C14 C15 . . 120.0(6) ?
C13 C14 H14 . . 120.0 ?
C15 C14 H14 . . 120.0 ?
C14 C15 C11 . . 120.0(6) ?
C14 C15 H15 . . 120.0 ?
C11 C15 H15 . . 120.0 ?
C13 C16 H16A . . 109.5 ?
C13 C16 H16B . . 109.5 ?
H16A C16 H16B . . 109.5 ?
C13 C16 H16C . . 109.5 ?
H16A C16 H16C . . 109.5 ?
H16B C16 H16C . . 109.5 ?
C18 C17 C22 . . 119.7(5) ?
C18 C17 P1 . . 121.1(4) ?
C22 C17 P1 . . 119.0(5) ?
C17 C18 C19 . . 120.2(5) ?
C17 C18 H18 . . 119.9 ?
C19 C18 H18 . . 119.9 ?
C20 C19 C18 . . 118.5(6) ?
C20 C19 H19 . . 120.8 ?
C18 C19 H19 . . 120.8 ?
C19 C20 C21 . . 123.3(6) ?
C19 C20 H20 . . 118.4 ?
C21 C20 H20 . . 118.4 ?
C20 C21 C22 . . 120.2(6) ?
C20 C21 H21 . . 119.9 ?
C22 C21 H21 . . 119.9 ?
C17 C22 C21 . . 118.1(6) ?
C17 C22 H22 . . 121.0 ?
C21 C22 H22 . . 121.0 ?
C24 C23 C28 . . 117.9(5) ?
C24 C23 P1 . . 118.2(4) ?
C28 C23 P1 . . 123.1(4) ?
C23 C24 C25 . . 121.6(6) ?
C23 C24 H24 . . 119.2 ?
C25 C24 H24 . . 119.2 ?
C26 C25 C24 . . 119.8(5) ?
C26 C25 H25 . . 120.1 ?
C24 C25 H25 . . 120.1 ?
C25 C26 C27 . . 119.5(5) ?
C25 C26 H26 . . 120.2 ?
C27 C26 H26 . . 120.2 ?
C26 C27 C28 . . 120.8(5) ?
C26 C27 H27 . . 119.6 ?
C28 C27 H27 . . 119.6 ?
C23 C28 C27 . . 120.2(5) ?
C23 C28 H28 . . 119.9 ?
C27 C28 H28 . . 119.9 ?
C30 C29 C34 . . 117.7(6) ?
C30 C29 P1 . . 125.5(5) ?
C34 C29 P1 . . 116.1(4) ?
C29 C30 C31 . . 120.8(6) ?
C29 C30 H30 . . 119.6 ?
C31 C30 H30 . . 119.6 ?
C30 C31 C32 . . 120.9(6) ?
C30 C31 H31 . . 119.5 ?
C32 C31 H31 . . 119.5 ?
C33 C32 C31 . . 119.7(6) ?
C33 C32 H32 . . 120.1 ?
C31 C32 H32 . . 120.1 ?
C32 C33 C34 . . 117.7(6) ?
C32 C33 H33 . . 121.2 ?
C34 C33 H33 . . 121.2 ?
C33 C34 C29 . . 122.8(6) ?
C33 C34 H34 . . 118.6 ?
C29 C34 H34 . . 118.6 ?
O2 C35 H35A . . 109.5 ?
O2 C35 H35B . . 109.5 ?
H35A C35 H35B . . 109.5 ?
O2 C35 H35C . . 109.5 ?
H35A C35 H35C . . 109.5 ?
H35B C35 H35C . . 109.5 ?
C1 N1 C5 . . 115.3(5) ?
C1 N1 Ru1 . . 130.1(4) ?
C5 N1 Ru1 . . 114.5(4) ?
C13 N2 C12 . . 120.0(5) ?
C13 N2 Ru1 . . 130.9(4) ?
C12 N2 Ru1 . . 109.1(4) ?
C7 O1 C6 . . 118.9(4) ?
C7 O1 Ru1 . . 113.9(3) ?
C6 O1 Ru1 . . 111.9(3) ?
C35 O2 H2A . . 109.5 ?
C29 P1 C23 . . 101.2(3) ?
C29 P1 C17 . . 103.7(3) ?
C23 P1 C17 . . 101.1(2) ?
C29 P1 Ru1 . . 113.4(2) ?
C23 P1 Ru1 . . 117.07(18) ?
C17 P1 Ru1 . . 118.10(17) ?
O1 Ru1 N1 . . 79.47(17) ?
O1 Ru1 N2 . . 79.66(16) ?
N1 Ru1 N2 . . 158.25(17) ?
O1 Ru1 P1 . . 94.55(11) ?
N1 Ru1 P1 . . 92.46(12) ?
N2 Ru1 P1 . . 95.22(13) ?
O1 Ru1 Cl2 . . 169.80(11) ?
N1 Ru1 Cl2 . . 92.40(14) ?
N2 Ru1 Cl2 . . 107.61(13) ?
P1 Ru1 Cl2 . . 91.93(6) ?
O1 Ru1 Cl1 . . 85.32(11) ?
N1 Ru1 Cl1 . . 87.29(12) ?
N2 Ru1 Cl1 . . 84.98(13) ?
P1 Ru1 Cl1 . . 179.74(6) ?
Cl2 Ru1 Cl1 . . 88.17(5) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 N1 . 1.356(8) ?
C1 C2 . 1.362(9) ?
C1 H1 . 0.9300 ?
C2 C3 . 1.332(8) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.374(8) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.393(8) ?
C4 H4 . 0.9300 ?
C5 N1 . 1.369(7) ?
C5 C6 . 1.524(8) ?
C6 O1 . 1.466(7) ?
C6 H6A . 0.9700 ?
C6 H6B . 0.9700 ?
C7 C8 . 1.390(8) ?
C7 C12 . 1.390(8) ?
C7 O1 . 1.391(7) ?
C8 C9 . 1.390(9) ?
C8 H8 . 0.9300 ?
C9 C10 . 1.390(9) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.390(8) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.390(8) ?
C11 C15 . 1.390(8) ?
C12 N2 . 1.390(7) ?
C13 N2 . 1.390(8) ?
C13 C14 . 1.390(9) ?
C13 C16 . 1.470(9) ?
C14 C15 . 1.390(9) ?
C14 H14 . 0.9300 ?
C15 H15 . 0.9300 ?
C16 H16A . 0.9600 ?
C16 H16B . 0.9600 ?
C16 H16C . 0.9600 ?
C17 C18 . 1.371(8) ?
C17 C22 . 1.392(8) ?
C17 P1 . 1.872(6) ?
C18 C19 . 1.406(8) ?
C18 H18 . 0.9300 ?
C19 C20 . 1.325(9) ?
C19 H19 . 0.9300 ?
C20 C21 . 1.337(9) ?
C20 H20 . 0.9300 ?
C21 C22 . 1.398(8) ?
C21 H21 . 0.9300 ?
C22 H22 . 0.9300 ?
C23 C24 . 1.373(8) ?
C23 C28 . 1.385(8) ?
C23 P1 . 1.855(6) ?
C24 C25 . 1.397(8) ?
C24 H24 . 0.9300 ?
C25 C26 . 1.363(9) ?
C25 H25 . 0.9300 ?
C26 C27 . 1.370(8) ?
C26 H26 . 0.9300 ?
C27 C28 . 1.398(7) ?
C27 H27 . 0.9300 ?
C28 H28 . 0.9300 ?
C29 C30 . 1.354(8) ?
C29 C34 . 1.407(9) ?
C29 P1 . 1.837(6) ?
C30 C31 . 1.369(8) ?
C30 H30 . 0.9300 ?
C31 C32 . 1.404(9) ?
C31 H31 . 0.9300 ?
C32 C33 . 1.372(8) ?
C32 H32 . 0.9300 ?
C33 C34 . 1.382(8) ?
C33 H33 . 0.9300 ?
C34 H34 . 0.9300 ?
C35 O2 . 1.381(7) ?
C35 H35A . 0.9600 ?
C35 H35B . 0.9600 ?
C35 H35C . 0.9600 ?
Cl1 Ru1 . 2.4905(14) ?
Cl2 Ru1 . 2.4104(14) ?
N1 Ru1 . 2.067(5) ?
N2 Ru1 . 2.162(5) ?
O1 Ru1 . 2.060(3) ?
O2 H2A . 0.8200 ?
P1 Ru1 . 2.2931(15) ?
