#------------------------------------------------------------------------------
#$Date: 2017-02-18 01:54:34 +0200 (Sat, 18 Feb 2017) $
#$Revision: 192244 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/00/27/4002710.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4002710
loop_
_publ_author_name
'Bigun, Inna'
'Steinberg, Simon'
'Smetana, Volodymyr'
'Mudryk, Yaroslav'
'Kalychak, Yaroslav'
'Havela, Ladislav'
'Pecharsky, Vitalij'
'Mudring, Anja-Verena'
_publ_section_title
;
 Magnetocaloric Behavior in Ternary Europium Indides EuT5In: Probing the
 Design Capability of First-Principles-Based Methods on the Multifaceted
 Magnetic Materials
;
_journal_name_full               'Chemistry of Materials'
_journal_paper_doi               10.1021/acs.chemmater.6b04782
_journal_year                    2017
_chemical_formula_sum            'Cu5 Eu In'
_chemical_formula_weight         584.48
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           166
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   5.0933(7)
_cell_length_b                   5.0933(7)
_cell_length_c                   30.557(6)
_cell_measurement_reflns_used    812
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.14
_cell_measurement_theta_min      2.00
_cell_volume                     686.50(19)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0479
_diffrn_reflns_av_sigmaI/netI    0.0498
_diffrn_reflns_limit_h_max       3
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            812
_diffrn_reflns_theta_full        29.14
_diffrn_reflns_theta_max         29.14
_diffrn_reflns_theta_min         2.00
_exptl_absorpt_coefficient_mu    41.017
_exptl_absorpt_correction_T_max  0.14
_exptl_absorpt_correction_T_min  0.06
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    8.483
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'irregular fragment'
_exptl_crystal_F_000             1542
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         2.044
_refine_diff_density_min         -3.444
_refine_diff_density_rms         0.441
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.215
_refine_ls_matrix_type           full
_refine_ls_number_parameters     20
_refine_ls_number_reflns         276
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.215
_refine_ls_R_factor_all          0.0746
_refine_ls_R_factor_gt           0.0504
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0292P)²+1.8215P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0709
_refine_ls_wR_factor_ref         0.0756
_reflns_number_gt                218
_reflns_number_total             276
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cm6b04782_si_003.cif
_cod_data_source_block           EuCu5In
_cod_original_sg_symbol_H-M      R-3m
_cod_database_code               4002710
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z+1/3'
'-x+y+2/3, y+1/3, z+1/3'
'x+2/3, x-y+1/3, z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+2/3'
'-x+y+1/3, y+2/3, z+2/3'
'x+1/3, x-y+2/3, z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.0000 0.0000 0.0000 0.0119(4) Uani 1 12 d S
Eu2 Eu 0.3333 -0.3333 0.1667 0.0114(4) Uani 1 12 d S
In3 In 0.3333 -0.3333 0.05636(6) 0.0110(4) Uani 1 6 d S
Cu4 Cu 0.0000 0.0000 0.16594(13) 0.0133(7) Uani 1 6 d S
Cu5 Cu -0.3333 0.3333 0.03097(13) 0.0170(7) Uani 1 6 d S
Cu6 Cu 0.3331(5) 0.1665(2) 0.09834(7) 0.0113(4) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cu5 Eu1 Cu5 180.00(14) 19 .
Cu5 Eu1 Cu5 111.05(7) 19 19_455
Cu5 Eu1 Cu5 68.95(7) . 19_455
Cu5 Eu1 Cu5 68.95(7) 19 1_655
Cu5 Eu1 Cu5 111.05(7) . 1_655
Cu5 Eu1 Cu5 180.00(14) 19_455 1_655
Cu5 Eu1 Cu5 111.05(7) 19 19_565
Cu5 Eu1 Cu5 68.95(7) . 19_565
Cu5 Eu1 Cu5 111.05(7) 19_455 19_565
Cu5 Eu1 Cu5 68.95(7) 1_655 19_565
Cu5 Eu1 Cu5 68.95(7) 19 1_545
Cu5 Eu1 Cu5 111.05(7) . 1_545
Cu5 Eu1 Cu5 68.95(7) 19_455 1_545
Cu5 Eu1 Cu5 111.05(7) 1_655 1_545
Cu5 Eu1 Cu5 180.00(14) 19_565 1_545
Cu5 Eu1 Cu6 93.79(7) 19 .
Cu5 Eu1 Cu6 86.21(7) . .
Cu5 Eu1 Cu6 133.89(8) 19_455 .
Cu5 Eu1 Cu6 46.11(8) 1_655 .
Cu5 Eu1 Cu6 93.79(7) 19_565 .
Cu5 Eu1 Cu6 86.21(7) 1_545 .
Cu5 Eu1 Cu6 86.21(7) 19 19
Cu5 Eu1 Cu6 93.79(7) . 19
Cu5 Eu1 Cu6 46.11(8) 19_455 19
Cu5 Eu1 Cu6 133.89(8) 1_655 19
Cu5 Eu1 Cu6 86.21(7) 19_565 19
Cu5 Eu1 Cu6 93.79(7) 1_545 19
Cu6 Eu1 Cu6 180.00(8) . 19
Cu5 Eu1 Cu6 46.11(8) 19 20
Cu5 Eu1 Cu6 133.89(8) . 20
Cu5 Eu1 Cu6 86.21(7) 19_455 20
Cu5 Eu1 Cu6 93.79(7) 1_655 20
Cu5 Eu1 Cu6 86.21(7) 19_565 20
Cu5 Eu1 Cu6 93.79(7) 1_545 20
Cu6 Eu1 Cu6 135.29(6) . 20
Cu6 Eu1 Cu6 44.71(6) 19 20
Cu5 Eu1 Cu6 133.89(8) 19 2
Cu5 Eu1 Cu6 46.11(8) . 2
Cu5 Eu1 Cu6 93.79(7) 19_455 2
Cu5 Eu1 Cu6 86.21(7) 1_655 2
Cu5 Eu1 Cu6 93.79(7) 19_565 2
Cu5 Eu1 Cu6 86.21(7) 1_545 2
Cu6 Eu1 Cu6 44.71(6) . 2
Cu6 Eu1 Cu6 135.29(6) 19 2
Cu6 Eu1 Cu6 180.00(5) 20 2
Cu5 Eu1 Cu6 86.21(7) 19 21
Cu5 Eu1 Cu6 93.79(7) . 21
Cu5 Eu1 Cu6 86.21(7) 19_455 21
Cu5 Eu1 Cu6 93.79(7) 1_655 21
Cu5 Eu1 Cu6 46.11(8) 19_565 21
Cu5 Eu1 Cu6 133.89(8) 1_545 21
Cu6 Eu1 Cu6 135.29(6) . 21
Cu6 Eu1 Cu6 44.71(6) 19 21
Cu6 Eu1 Cu6 44.71(6) 20 21
Cu6 Eu1 Cu6 135.29(6) 2 21
Cu5 Eu1 Cu6 93.79(7) 19 3
Cu5 Eu1 Cu6 86.21(7) . 3
Cu5 Eu1 Cu6 93.79(7) 19_455 3
Cu5 Eu1 Cu6 86.21(7) 1_655 3
Cu5 Eu1 Cu6 133.89(8) 19_565 3
Cu5 Eu1 Cu6 46.11(8) 1_545 3
Cu6 Eu1 Cu6 44.71(6) . 3
Cu6 Eu1 Cu6 135.29(6) 19 3
Cu6 Eu1 Cu6 135.29(6) 20 3
Cu6 Eu1 Cu6 44.71(6) 2 3
Cu6 Eu1 Cu6 180.00(12) 21 3
Cu4 Eu2 Cu4 180.0 25_545 .
Cu4 Eu2 Cu4 60.006(2) 25_545 1_545
Cu4 Eu2 Cu4 119.994(2) . 1_545
Cu4 Eu2 Cu4 60.006(2) 25_545 1_655
Cu4 Eu2 Cu4 119.994(2) . 1_655
Cu4 Eu2 Cu4 119.994(2) 1_545 1_655
Cu4 Eu2 Cu4 119.995(2) 25_545 25
Cu4 Eu2 Cu4 60.005(2) . 25
Cu4 Eu2 Cu4 180.0 1_545 25
Cu4 Eu2 Cu4 60.006(2) 1_655 25
Cu4 Eu2 Cu4 119.995(2) 25_545 25_445
Cu4 Eu2 Cu4 60.005(2) . 25_445
Cu4 Eu2 Cu4 60.006(2) 1_545 25_445
Cu4 Eu2 Cu4 180.0 1_655 25_445
Cu4 Eu2 Cu4 119.994(2) 25 25_445
Cu4 Eu2 Cu6 90.25(6) 25_545 2_545
Cu4 Eu2 Cu6 89.75(6) . 2_545
Cu4 Eu2 Cu6 47.57(7) 1_545 2_545
Cu4 Eu2 Cu6 131.66(8) 1_655 2_545
Cu4 Eu2 Cu6 132.43(7) 25 2_545
Cu4 Eu2 Cu6 48.34(8) 25_445 2_545
Cu4 Eu2 Cu6 132.43(7) 25_545 3
Cu4 Eu2 Cu6 47.57(7) . 3
Cu4 Eu2 Cu6 89.75(6) 1_545 3
Cu4 Eu2 Cu6 131.66(8) 1_655 3
Cu4 Eu2 Cu6 90.25(6) 25 3
Cu4 Eu2 Cu6 48.34(8) 25_445 3
Cu6 Eu2 Cu6 45.53(7) 2_545 3
Cu4 Eu2 Cu6 132.43(7) 25_545 .
Cu4 Eu2 Cu6 47.57(7) . .
Cu4 Eu2 Cu6 131.66(8) 1_545 .
Cu4 Eu2 Cu6 89.75(6) 1_655 .
Cu4 Eu2 Cu6 48.34(8) 25 .
Cu4 Eu2 Cu6 90.25(6) 25_445 .
Cu6 Eu2 Cu6 84.09(4) 2_545 .
Cu6 Eu2 Cu6 45.45(7) 3 .
Cu4 Eu2 Cu6 90.25(6) 25_545 2_655
Cu4 Eu2 Cu6 89.75(6) . 2_655
Cu4 Eu2 Cu6 131.66(8) 1_545 2_655
Cu4 Eu2 Cu6 47.57(7) 1_655 2_655
Cu4 Eu2 Cu6 48.34(8) 25 2_655
Cu4 Eu2 Cu6 132.43(7) 25_445 2_655
Cu6 Eu2 Cu6 101.31(6) 2_545 2_655
Cu6 Eu2 Cu6 84.09(4) 3 2_655
Cu6 Eu2 Cu6 45.53(7) . 2_655
Cu4 Eu2 Cu6 48.34(8) 25_545 1_545
Cu4 Eu2 Cu6 131.66(8) . 1_545
Cu4 Eu2 Cu6 47.57(7) 1_545 1_545
Cu4 Eu2 Cu6 89.75(6) 1_655 1_545
Cu4 Eu2 Cu6 132.43(7) 25 1_545
Cu4 Eu2 Cu6 90.25(6) 25_445 1_545
Cu6 Eu2 Cu6 45.45(7) 2_545 1_545
Cu6 Eu2 Cu6 84.09(4) 3 1_545
Cu6 Eu2 Cu6 101.31(6) . 1_545
Cu6 Eu2 Cu6 84.09(4) 2_655 1_545
Cu4 Eu2 Cu6 48.34(8) 25_545 3_655
Cu4 Eu2 Cu6 131.66(8) . 3_655
Cu4 Eu2 Cu6 89.75(6) 1_545 3_655
Cu4 Eu2 Cu6 47.57(7) 1_655 3_655
Cu4 Eu2 Cu6 90.25(6) 25 3_655
Cu4 Eu2 Cu6 132.43(7) 25_445 3_655
Cu6 Eu2 Cu6 84.09(4) 2_545 3_655
Cu6 Eu2 Cu6 101.31(6) 3 3_655
Cu6 Eu2 Cu6 84.09(4) . 3_655
Cu6 Eu2 Cu6 45.45(7) 2_655 3_655
Cu6 Eu2 Cu6 45.53(7) 1_545 3_655
Cu5 In3 Cu6 116.74(5) 19 2_655
Cu5 In3 Cu6 116.74(5) 19 .
Cu6 In3 Cu6 53.09(8) 2_655 .
Cu5 In3 Cu6 116.74(5) 19 3
Cu6 In3 Cu6 101.33(6) 2_655 3
Cu6 In3 Cu6 53.00(8) . 3
Cu5 In3 Cu6 116.74(5) 19 2_545
Cu6 In3 Cu6 126.53(10) 2_655 2_545
Cu6 In3 Cu6 101.33(6) . 2_545
Cu6 In3 Cu6 53.09(8) 3 2_545
Cu5 In3 Cu6 116.74(5) 19 3_655
Cu6 In3 Cu6 53.00(8) 2_655 3_655
Cu6 In3 Cu6 101.33(6) . 3_655
Cu6 In3 Cu6 126.53(10) 3 3_655
Cu6 In3 Cu6 101.33(6) 2_545 3_655
Cu5 In3 Cu6 116.74(5) 19 1_545
Cu6 In3 Cu6 101.33(6) 2_655 1_545
Cu6 In3 Cu6 126.53(10) . 1_545
Cu6 In3 Cu6 101.33(6) 3 1_545
Cu6 In3 Cu6 53.00(8) 2_545 1_545
Cu6 In3 Cu6 53.09(8) 3_655 1_545
Cu5 In3 Cu5 75.22(8) 19 1_545
Cu6 In3 Cu5 149.63(6) 2_655 1_545
Cu6 In3 Cu5 96.57(5) . 1_545
Cu6 In3 Cu5 50.74(7) 3 1_545
Cu6 In3 Cu5 50.74(7) 2_545 1_545
Cu6 In3 Cu5 149.63(6) 3_655 1_545
Cu6 In3 Cu5 96.57(5) 1_545 1_545
Cu5 In3 Cu5 75.22(8) 19 1_655
Cu6 In3 Cu5 50.74(7) 2_655 1_655
Cu6 In3 Cu5 50.74(7) . 1_655
Cu6 In3 Cu5 96.57(5) 3 1_655
Cu6 In3 Cu5 149.63(6) 2_545 1_655
Cu6 In3 Cu5 96.57(5) 3_655 1_655
Cu6 In3 Cu5 149.63(6) 1_545 1_655
Cu5 In3 Cu5 113.73(6) 1_545 1_655
Cu5 In3 Cu5 75.22(8) 19 1_645
Cu6 In3 Cu5 96.57(5) 2_655 1_645
Cu6 In3 Cu5 149.63(6) . 1_645
Cu6 In3 Cu5 149.63(6) 3 1_645
Cu6 In3 Cu5 96.57(5) 2_545 1_645
Cu6 In3 Cu5 50.74(7) 3_655 1_645
Cu6 In3 Cu5 50.74(7) 1_545 1_645
Cu5 In3 Cu5 113.73(6) 1_545 1_645
Cu5 In3 Cu5 113.73(6) 1_655 1_645
Cu5 In3 Eu2 180.0 19 .
Cu6 In3 Eu2 63.26(5) 2_655 .
Cu6 In3 Eu2 63.26(5) . .
Cu6 In3 Eu2 63.26(5) 3 .
Cu6 In3 Eu2 63.26(5) 2_545 .
Cu6 In3 Eu2 63.26(5) 3_655 .
Cu6 In3 Eu2 63.26(5) 1_545 .
Cu5 In3 Eu2 104.78(8) 1_545 .
Cu5 In3 Eu2 104.78(8) 1_655 .
Cu5 In3 Eu2 104.78(8) 1_645 .
Cu5 In3 Eu1 59.65(3) 19 .
Cu6 In3 Eu1 103.16(4) 2_655 .
Cu6 In3 Eu1 63.88(4) . .
Cu6 In3 Eu1 63.88(4) 3 .
Cu6 In3 Eu1 103.16(4) 2_545 .
Cu6 In3 Eu1 153.45(4) 3_655 .
Cu6 In3 Eu1 153.45(4) 1_545 .
Cu5 In3 Eu1 56.90(4) 1_545 .
Cu5 In3 Eu1 56.90(4) 1_655 .
Cu5 In3 Eu1 134.87(10) 1_645 .
Eu2 In3 Eu1 120.35(3) . .
Cu6 Cu4 Cu6 60.25(11) 3 2
Cu6 Cu4 Cu6 60.25(11) 3 .
Cu6 Cu4 Cu6 60.25(11) 2 .
Cu6 Cu4 Cu6 146.53(2) 3 25
Cu6 Cu4 Cu6 146.53(2) 2 25
Cu6 Cu4 Cu6 109.69(6) . 25
Cu6 Cu4 Cu6 109.69(6) 3 27_445
Cu6 Cu4 Cu6 146.53(2) 2 27_445
Cu6 Cu4 Cu6 146.53(2) . 27_445
Cu6 Cu4 Cu6 59.39(12) 25 27_445
Cu6 Cu4 Cu6 146.53(2) 3 26_455
Cu6 Cu4 Cu6 109.69(6) 2 26_455
Cu6 Cu4 Cu6 146.53(2) . 26_455
Cu6 Cu4 Cu6 59.39(12) 25 26_455
Cu6 Cu4 Cu6 59.39(12) 27_445 26_455
Cu6 Cu4 Eu2 73.52(5) 3 .
Cu6 Cu4 Eu2 125.85(13) 2 .
Cu6 Cu4 Eu2 73.52(5) . .
Cu6 Cu4 Eu2 73.01(5) 25 .
Cu6 Cu4 Eu2 73.01(5) 27_445 .
Cu6 Cu4 Eu2 124.46(14) 26_455 .
Cu6 Cu4 Eu2 125.85(13) 3 1_565
Cu6 Cu4 Eu2 73.52(5) 2 1_565
Cu6 Cu4 Eu2 73.52(5) . 1_565
Cu6 Cu4 Eu2 73.01(5) 25 1_565
Cu6 Cu4 Eu2 124.46(14) 27_445 1_565
Cu6 Cu4 Eu2 73.01(5) 26_455 1_565
Eu2 Cu4 Eu2 119.994(2) . 1_565
Cu6 Cu4 Eu2 73.52(5) 3 1_455
Cu6 Cu4 Eu2 73.52(5) 2 1_455
Cu6 Cu4 Eu2 125.85(13) . 1_455
Cu6 Cu4 Eu2 124.46(14) 25 1_455
Cu6 Cu4 Eu2 73.01(5) 27_445 1_455
Cu6 Cu4 Eu2 73.01(5) 26_455 1_455
Eu2 Cu4 Eu2 119.994(2) . 1_455
Eu2 Cu4 Eu2 119.994(2) 1_565 1_455
Cu6 Cu4 Cu4 107.58(15) 3 25
Cu6 Cu4 Cu4 107.58(15) 2 25
Cu6 Cu4 Cu4 55.45(12) . 25
Cu6 Cu4 Cu4 54.25(11) 25 25
Cu6 Cu4 Cu4 105.88(16) 27_445 25
Cu6 Cu4 Cu4 105.88(16) 26_455 25
Eu2 Cu4 Cu4 59.998(1) . 25
Eu2 Cu4 Cu4 59.997(1) 1_565 25
Eu2 Cu4 Cu4 178.7(2) 1_455 25
Cu6 Cu4 Cu4 55.45(12) 3 25_445
Cu6 Cu4 Cu4 107.58(15) 2 25_445
Cu6 Cu4 Cu4 107.58(15) . 25_445
Cu6 Cu4 Cu4 105.88(16) 25 25_445
Cu6 Cu4 Cu4 54.25(11) 27_445 25_445
Cu6 Cu4 Cu4 105.88(16) 26_455 25_445
Eu2 Cu4 Cu4 59.998(1) . 25_445
Eu2 Cu4 Cu4 178.7(2) 1_565 25_445
Eu2 Cu4 Cu4 59.997(1) 1_455 25_445
Cu4 Cu4 Cu4 119.978(8) 25 25_445
Cu6 Cu4 Cu4 107.58(15) 3 25_455
Cu6 Cu4 Cu4 55.45(12) 2 25_455
Cu6 Cu4 Cu4 107.58(15) . 25_455
Cu6 Cu4 Cu4 105.88(16) 25 25_455
Cu6 Cu4 Cu4 105.88(16) 27_445 25_455
Cu6 Cu4 Cu4 54.25(11) 26_455 25_455
Eu2 Cu4 Cu4 178.7(2) . 25_455
Eu2 Cu4 Cu4 59.997(1) 1_565 25_455
Eu2 Cu4 Cu4 59.997(1) 1_455 25_455
Cu4 Cu4 Cu4 119.977(9) 25 25_455
Cu4 Cu4 Cu4 119.977(8) 25_445 25_455
Cu6 Cu5 Cu6 60.48(11) 2 3_565
Cu6 Cu5 Cu6 60.48(11) 2 1_455
Cu6 Cu5 Cu6 60.48(11) 3_565 1_455
Cu6 Cu5 In3 144.44(7) 2 19
Cu6 Cu5 In3 144.44(7) 3_565 19
Cu6 Cu5 In3 144.44(7) 1_455 19
Cu6 Cu5 In3 60.75(5) 2 1_565
Cu6 Cu5 In3 60.75(5) 3_565 1_565
Cu6 Cu5 In3 110.78(14) 1_455 1_565
In3 Cu5 In3 104.78(8) 19 1_565
Cu6 Cu5 In3 60.75(5) 2 1_455
Cu6 Cu5 In3 110.78(14) 3_565 1_455
Cu6 Cu5 In3 60.75(5) 1_455 1_455
In3 Cu5 In3 104.78(8) 19 1_455
In3 Cu5 In3 113.73(6) 1_565 1_455
Cu6 Cu5 In3 110.78(14) 2 1_465
Cu6 Cu5 In3 60.75(5) 3_565 1_465
Cu6 Cu5 In3 60.75(5) 1_455 1_465
In3 Cu5 In3 104.78(8) 19 1_465
In3 Cu5 In3 113.73(6) 1_565 1_465
In3 Cu5 In3 113.73(6) 1_455 1_465
Cu6 Cu5 Eu1 72.28(5) 2 .
Cu6 Cu5 Eu1 121.74(7) 3_565 .
Cu6 Cu5 Eu1 121.74(7) 1_455 .
In3 Cu5 Eu1 72.16(7) 19 .
In3 Cu5 Eu1 67.538(17) 1_565 .
In3 Cu5 Eu1 67.538(17) 1_455 .
In3 Cu5 Eu1 176.94(14) 1_465 .
Cu6 Cu5 Eu1 121.74(7) 2 1_455
Cu6 Cu5 Eu1 121.74(7) 3_565 1_455
Cu6 Cu5 Eu1 72.28(5) 1_455 1_455
In3 Cu5 Eu1 72.16(7) 19 1_455
In3 Cu5 Eu1 176.94(14) 1_565 1_455
In3 Cu5 Eu1 67.538(17) 1_455 1_455
In3 Cu5 Eu1 67.538(17) 1_465 1_455
Eu1 Cu5 Eu1 111.05(7) . 1_455
Cu6 Cu5 Eu1 121.74(7) 2 1_565
Cu6 Cu5 Eu1 72.28(5) 3_565 1_565
Cu6 Cu5 Eu1 121.74(7) 1_455 1_565
In3 Cu5 Eu1 72.16(7) 19 1_565
In3 Cu5 Eu1 67.538(17) 1_565 1_565
In3 Cu5 Eu1 176.94(14) 1_455 1_565
In3 Cu5 Eu1 67.538(17) 1_465 1_565
Eu1 Cu5 Eu1 111.05(7) . 1_565
Eu1 Cu5 Eu1 111.05(7) 1_455 1_565
Cu5 Cu6 Cu4 179.86(11) 1_655 .
Cu5 Cu6 Cu6 120.24(6) 1_655 3
Cu4 Cu6 Cu6 59.87(5) . 3
Cu5 Cu6 Cu6 120.24(6) 1_655 2
Cu4 Cu6 Cu6 59.87(5) . 2
Cu6 Cu6 Cu6 60.0 3 2
Cu5 Cu6 Cu6 59.76(6) 1_655 3_665
Cu4 Cu6 Cu6 120.13(5) . 3_665
Cu6 Cu6 Cu6 180.00(13) 3 3_665
Cu6 Cu6 Cu6 120.0 2 3_665
Cu5 Cu6 Cu6 59.76(6) 1_655 2_655
Cu4 Cu6 Cu6 120.13(5) . 2_655
Cu6 Cu6 Cu6 120.0 3 2_655
Cu6 Cu6 Cu6 180.00(13) 2 2_655
Cu6 Cu6 Cu6 60.0 3_665 2_655
Cu5 Cu6 Cu4 109.55(10) 1_655 25
Cu4 Cu6 Cu4 70.31(6) . 25
Cu6 Cu6 Cu4 119.69(6) 3 25
Cu6 Cu6 Cu4 119.69(6) 2 25
Cu6 Cu6 Cu4 60.31(6) 3_665 25
Cu6 Cu6 Cu4 60.31(6) 2_655 25
Cu5 Cu6 In3 68.52(5) 1_655 .
Cu4 Cu6 In3 111.52(5) . .
Cu6 Cu6 In3 63.50(4) 3 .
Cu6 Cu6 In3 116.55(4) 2 .
Cu6 Cu6 In3 116.50(4) 3_665 .
Cu6 Cu6 In3 63.45(4) 2_655 .
Cu4 Cu6 In3 111.64(5) 25 .
Cu5 Cu6 In3 68.52(5) 1_655 1_565
Cu4 Cu6 In3 111.52(5) . 1_565
Cu6 Cu6 In3 116.55(4) 3 1_565
Cu6 Cu6 In3 63.50(4) 2 1_565
Cu6 Cu6 In3 63.45(4) 3_665 1_565
Cu6 Cu6 In3 116.50(4) 2_655 1_565
Cu4 Cu6 In3 111.64(5) 25 1_565
In3 Cu6 In3 126.53(10) . 1_565
Cu5 Cu6 Eu2 121.04(5) 1_655 .
Cu4 Cu6 Eu2 58.90(4) . .
Cu6 Cu6 Eu2 67.27(3) 3 .
Cu6 Cu6 Eu2 112.77(3) 2 .
Cu6 Cu6 Eu2 112.73(3) 3_665 .
Cu6 Cu6 Eu2 67.23(3) 2_655 .
Cu4 Cu6 Eu2 58.65(4) 25 .
In3 Cu6 Eu2 66.08(4) . .
In3 Cu6 Eu2 167.39(7) 1_565 .
Cu5 Cu6 Eu2 121.04(5) 1_655 1_565
Cu4 Cu6 Eu2 58.90(4) . 1_565
Cu6 Cu6 Eu2 112.77(3) 3 1_565
Cu6 Cu6 Eu2 67.27(3) 2 1_565
Cu6 Cu6 Eu2 67.23(3) 3_665 1_565
Cu6 Cu6 Eu2 112.73(3) 2_655 1_565
Cu4 Cu6 Eu2 58.65(4) 25 1_565
In3 Cu6 Eu2 167.39(7) . 1_565
In3 Cu6 Eu2 66.08(4) 1_565 1_565
Eu2 Cu6 Eu2 101.31(6) . 1_565
Cu5 Cu6 Eu1 61.61(7) 1_655 .
Cu4 Cu6 Eu1 118.53(8) . .
Cu6 Cu6 Eu1 67.64(3) 3 .
Cu6 Cu6 Eu1 67.64(3) 2 .
Cu6 Cu6 Eu1 112.36(3) 3_665 .
Cu6 Cu6 Eu1 112.36(3) 2_655 .
Cu4 Cu6 Eu1 171.16(10) 25 .
In3 Cu6 Eu1 66.17(5) . .
In3 Cu6 Eu1 66.17(5) 1_565 .
Eu2 Cu6 Eu1 124.73(4) . .
Eu2 Cu6 Eu1 124.73(4) 1_565 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Cu5 3.0891(13) 19
Eu1 Cu5 3.0891(13) .
Eu1 Cu5 3.0891(13) 19_455
Eu1 Cu5 3.0891(13) 1_655
Eu1 Cu5 3.0891(13) 19_565
Eu1 Cu5 3.0891(13) 1_545
Eu1 Cu6 3.345(2) .
Eu1 Cu6 3.345(2) 19
Eu1 Cu6 3.345(2) 20
Eu1 Cu6 3.345(2) 2
Eu1 Cu6 3.345(2) 21
Eu1 Cu6 3.345(2) 3
Eu2 Cu4 2.9407(4) 25_545
Eu2 Cu4 2.9407(4) .
Eu2 Cu4 2.9407(4) 1_545
Eu2 Cu4 2.9407(4) 1_655
Eu2 Cu4 2.9407(4) 25
Eu2 Cu4 2.9407(4) 25_445
Eu2 Cu6 3.2932(14) 2_545
Eu2 Cu6 3.2932(14) 3
Eu2 Cu6 3.2932(14) .
Eu2 Cu6 3.2932(14) 2_655
Eu2 Cu6 3.2932(14) 1_545
Eu2 Cu6 3.2932(14) 3_655
In3 Cu5 2.668(4) 19
In3 Cu6 2.8515(12) 2_655
In3 Cu6 2.8515(12) .
In3 Cu6 2.8515(12) 3
In3 Cu6 2.8515(12) 2_545
In3 Cu6 2.8515(12) 3_655
In3 Cu6 2.8515(12) 1_545
In3 Cu5 3.0412(12) 1_545
In3 Cu5 3.0412(12) 1_655
In3 Cu5 3.0412(12) 1_645
Cu4 Cu6 2.535(4) 3
Cu4 Cu6 2.535(4) 2
Cu4 Cu6 2.535(4) .
Cu4 Cu6 2.573(4) 25
Cu4 Cu6 2.573(4) 27_445
Cu4 Cu6 2.573(4) 26_455
Cu4 Eu2 2.9407(4) 1_565
Cu4 Eu2 2.9407(4) 1_455
Cu4 Cu4 2.9409(4) 25
Cu4 Cu4 2.9409(4) 25_445
Cu4 Cu4 2.9410(4) 25_455
Cu5 Cu6 2.530(4) 2
Cu5 Cu6 2.530(4) 3_565
Cu5 Cu6 2.530(4) 1_455
Cu5 In3 2.668(4) 19
Cu5 In3 3.0412(12) 1_565
Cu5 In3 3.0412(12) 1_455
Cu5 In3 3.0412(12) 1_465
Cu5 Eu1 3.0891(13) 1_455
Cu5 Eu1 3.0891(13) 1_565
Cu6 Cu5 2.530(4) 1_655
Cu6 Cu6 2.545(4) 3
Cu6 Cu6 2.545(4) 2
Cu6 Cu6 2.549(4) 3_665
Cu6 Cu6 2.549(4) 2_655
Cu6 Cu4 2.573(4) 25
Cu6 In3 2.8515(12) 1_565
Cu6 Eu2 3.2932(14) 1_565
