#------------------------------------------------------------------------------
#$Date: 2017-04-26 01:01:59 +0300 (Wed, 26 Apr 2017) $
#$Revision: 195754 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/00/27/4002746.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4002746
loop_
_publ_author_name
'Thirumal, Krishnamoorthy'
'Chong, Wee Kiang'
'Xie, Wei'
'Ganguly, Rakesh'
'Muduli, Subas Kumar'
'Sherburne, Matthew'
'Asta, Mark'
'Mhaisalkar, Subodh'
'Sum, Tze Chien'
'Soo, Han Sen'
'Mathews, Nripan'
_publ_section_title
;
 Morphology-Independent Stable White-Light Emission from Self-Assembled
 Two-Dimensional Perovskites Driven by Strong Exciton--Phonon Coupling to
 the Organic Framework
;
_journal_name_full               'Chemistry of Materials'
_journal_paper_doi               10.1021/acs.chemmater.7b00073
_journal_year                    2017
_chemical_formula_sum            'C32 H48 Cl8 N4 Pb2'
_chemical_formula_weight         1186.72
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                99.1730(10)
_cell_angle_beta                 104.5250(10)
_cell_angle_gamma                90.0030(10)
_cell_formula_units_Z            2
_cell_length_a                   11.1152(3)
_cell_length_b                   11.2048(3)
_cell_length_c                   17.5909(5)
_cell_measurement_reflns_used    9909
_cell_measurement_temperature    273.(2)
_cell_measurement_theta_max      27.16
_cell_measurement_theta_min      2.37
_cell_volume                     2091.85(10)
_computing_cell_refinement       'SAINT V8.35A (Bruker AXS Inc., 2015)'
_computing_data_collection       'APEX3 (Bruker AXS Inc., 2015)'
_computing_data_reduction        'SAINT V8.35A (Bruker AXS Inc., 2015)'
_computing_molecular_graphics    'XP (Bruker AXS Inc., 2015)'
_computing_publication_material  'APEX3 (Bruker AXS Inc., 2015)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'XT, VERSION 2014/5'
_diffrn_ambient_temperature      273.(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.948
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1067
_diffrn_reflns_av_unetI/netI     0.1253
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.948
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            17496
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.948
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.176
_diffrn_reflns_theta_min         1.843
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_type              'Bruker KappaCCD'
_exptl_absorpt_coefficient_mu    8.576
_exptl_absorpt_correction_T_max  0.43
_exptl_absorpt_correction_T_min  0.08
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'TWINABS - Bruker AXS scaling for twinned crystals - Version 2012/1'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.884
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1136
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.120
_refine_diff_density_max         2.819
_refine_diff_density_min         -2.018
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     462
_refine_ls_number_reflns         9197
_refine_ls_number_restraints     472
_refine_ls_restrained_S_all      1.064
_refine_ls_R_factor_all          0.0684
_refine_ls_R_factor_gt           0.0625
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0684P)²+2.2260P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1628
_refine_ls_wR_factor_ref         0.1705
_reflns_number_gt                7766
_reflns_number_total             9197
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            cm7b00073_si_001.cif
_cod_data_source_block           shs183x
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-Scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_database_code               4002746
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_refinement_flags_posn
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl Cl1 0.8061(2) 0.3122(3) 0.66901(16) 0.0536(6) Uani d U . . 1.0 . .
Cl Cl2 0.6916(2) 0.2035(3) 0.32649(15) 0.0557(6) Uani d U . . 1.0 . .
Cl Cl3 0.8112(3) 0.5137(2) 0.5011(2) 0.0495(7) Uani d U P D 0.839(3) A 1
Cl Cl4 0.8099(2) 0.7888(3) 0.67302(15) 0.0559(6) Uani d U . . 1.0 . .
Cl Cl5 0.5021(3) 0.6884(3) 0.49905(19) 0.0462(7) Uani d U P D 0.839(3) A 1
Cl Cl6 0.6932(2) 0.7272(3) 0.33075(15) 0.0540(6) Uani d U . . 1.0 . .
Cl Cl7 1.0020(3) 0.8115(3) 0.4988(2) 0.0476(7) Uani d U P D 0.839(3) A 1
Cl Cl8 0.6898(3) 1.0126(2) 0.4993(2) 0.0499(7) Uani d U P D 0.839(3) A 1
Cl Cl3A 0.6866(14) 0.5153(12) 0.4977(12) 0.054(4) Uani d U P D 0.161(3) A 2
Cl Cl5A 0.4977(13) 0.8147(14) 0.5026(11) 0.051(4) Uani d U P D 0.161(3) A 2
Cl Cl7A 0.9979(11) 0.6893(12) 0.4999(9) 0.044(3) Uani d U P D 0.161(3) A 2
Cl Cl8A 0.8092(13) 1.0129(11) 0.5001(11) 0.047(3) Uani d U P D 0.161(3) A 2
N N1 0.055(3) -0.071(2) 0.6524(19) 0.121(10) Uani d U P D 0.448(16) B 1
H H1A 0.0352 -0.0856 0.5994 0.181 Uiso calc U P R 0.448(16) B 1
H H1B 0.0127 -0.1224 0.6704 0.181 Uiso calc U P R 0.448(16) B 1
H H1C 0.1365 -0.0805 0.6707 0.181 Uiso calc U P R 0.448(16) B 1
N N1A 0.1337(9) 0.0260(9) 0.6455(6) 0.028(2) Uani d U P D 0.552(16) B 2
H H1A1 0.1789 0.0942 0.6526 0.043 Uiso calc U P R 0.552(16) B 2
H H1A2 0.1071 -0.0026 0.5937 0.043 Uiso calc U P R 0.552(16) B 2
H H1A3 0.18 -0.0284 0.6698 0.043 Uiso calc U P R 0.552(16) B 2
N N2 0.5643(8) 0.1279(9) 0.6445(6) 0.070(2) Uani d U . . 1.0 . .
H H2A 0.4983 0.1638 0.6562 0.105 Uiso calc U . R 1.0 . .
H H2B 0.5523 0.1119 0.5919 0.105 Uiso calc U . R 1.0 . .
H H2C 0.6315 0.1767 0.6656 0.105 Uiso calc U . R 1.0 . .
N N3 0.3656(8) 0.4525(9) 0.3566(6) 0.070(2) Uani d U . . 1.0 . .
H H3A 0.3148 0.5103 0.341 0.104 Uiso calc U . R 1.0 . .
H H3B 0.3917 0.4652 0.4094 0.104 Uiso calc U . R 1.0 . .
H H3C 0.3251 0.3808 0.34 0.104 Uiso calc U . R 1.0 . .
N N4 0.9406(8) 0.5615(8) 0.3560(5) 0.060(2) Uani d U . . 1.0 . .
H H4A 0.9455 0.5724 0.408 0.09 Uiso calc U . R 1.0 . .
H H4B 0.8752 0.599 0.3315 0.09 Uiso calc U . R 1.0 . .
H H4C 1.0096 0.5917 0.3481 0.09 Uiso calc U . R 1.0 . .
Pb Pb1 0.74493(10) 0.25712(9) 0.48810(6) 0.03464(19) Uani d U P . 0.839(3) A 1
Pb Pb2 0.75501(11) 0.76260(10) 0.51195(6) 0.0348(2) Uani d U P . 0.839(3) A 1
Pb Pb1A 0.7449(6) 0.7575(5) 0.4857(3) 0.0338(10) Uani d U P . 0.161(3) A 2
Pb Pb2A 0.7565(5) 0.2625(5) 0.5150(3) 0.0362(11) Uani d U P . 0.161(3) A 2
C C1 0.1466(9) 0.0441(8) 0.8220(6) 0.053(2) Uani d U . . 1.0 . .
C C2 0.1004(10) -0.0515(9) 0.8476(6) 0.065(2) Uani d U . . 1.0 . .
H H2 0.0163 -0.0741 0.8292 0.078 Uiso calc U . R 1.0 . .
C C3 0.1775(12) -0.1146(10) 0.9003(6) 0.071(3) Uani d U . . 1.0 . .
H H3 0.1457 -0.1781 0.9186 0.086 Uiso calc U . R 1.0 . .
C C4 0.3065(12) -0.0811(13) 0.9262(7) 0.084(3) Uani d U . . 1.0 . .
H H4 0.3588 -0.1228 0.9621 0.101 Uiso calc U . R 1.0 . .
C C5 0.3547(11) 0.0102(12) 0.8996(7) 0.080(3) Uani d U . . 1.0 . .
H H5 0.4397 0.029 0.9151 0.096 Uiso calc U . R 1.0 . .
C C6 0.2739(10) 0.0763(10) 0.8481(7) 0.058(2) Uani d U . . 1.0 . .
H H6 0.3052 0.1417 0.8313 0.07 Uiso calc U . R 1.0 . .
C C7 0.0611(10) 0.1139(10) 0.7614(6) 0.058(2) Uani d U . . 1.0 . .
H H7A -0.0144 0.1318 0.7784 0.07 Uiso calc U . R 1.0 . .
H H7B 0.1029 0.1905 0.7626 0.07 Uiso calc U . R 1.0 . .
C C8 0.0267(11) 0.0500(12) 0.6792(7) 0.068(3) Uani d U . D 1.0 . .
H H8A -0.063 0.053 0.6616 0.082 Uiso calc U P R 0.839(3) A 1
H H8B 0.0603 0.1001 0.6486 0.082 Uiso calc U P R 0.839(3) A 1
H H8C -0.0161 -0.0262 0.6775 0.082 Uiso calc U P R 0.161(3) A 2
H H8D -0.0307 0.098 0.6465 0.082 Uiso calc U P R 0.161(3) A 2
C C9 0.6452(9) 0.1233(9) 0.8219(6) 0.053(2) Uani d U . . 1.0 . .
C C10 0.6037(10) 0.2296(10) 0.8484(6) 0.064(2) Uani d U . . 1.0 . .
H H10 0.5207 0.2455 0.8284 0.076 Uiso calc U . R 1.0 . .
C C11 0.6781(12) 0.3164(11) 0.9039(7) 0.075(3) Uani d U . . 1.0 . .
H H11 0.6462 0.389 0.9223 0.09 Uiso calc U . R 1.0 . .
C C12 0.8093(11) 0.2918(12) 0.9335(7) 0.078(3) Uani d U . . 1.0 . .
H H12 0.8641 0.3479 0.9707 0.094 Uiso calc U . R 1.0 . .
C C13 0.8465(10) 0.1844(11) 0.9043(6) 0.070(3) Uani d U . . 1.0 . .
H H13 0.9297 0.1674 0.9224 0.084 Uiso calc U . R 1.0 . .
C C14 0.7698(10) 0.0973(11) 0.8492(7) 0.065(3) Uani d U . . 1.0 . .
H H14 0.8002 0.0239 0.8308 0.079 Uiso calc U . R 1.0 . .
C C15 0.5600(10) 0.0307(11) 0.7620(7) 0.065(3) Uani d U . . 1.0 . .
H H15A 0.4747 0.0522 0.7594 0.078 Uiso calc U . R 1.0 . .
H H15B 0.5714 -0.0471 0.7798 0.078 Uiso calc U . R 1.0 . .
C C16 0.5814(12) 0.0179(11) 0.6762(7) 0.069(3) Uani d U . . 1.0 . .
H H16A 0.6652 -0.0079 0.678 0.083 Uiso calc U . R 1.0 . .
H H16B 0.524 -0.0443 0.641 0.083 Uiso calc U . R 1.0 . .
C C17 0.3545(6) 0.3838(5) 0.1794(4) 0.053(2) Uani d U . G 1.0 . .
C C18 0.4024(5) 0.2750(6) 0.1527(4) 0.061(2) Uani d U . G 1.0 . .
H H18 0.4866 0.2619 0.1708 0.074 Uiso calc U . R 1.0 . .
C C19 0.3243(7) 0.1858(5) 0.0991(4) 0.071(3) Uani d U . G 1.0 . .
H H19 0.3563 0.113 0.0812 0.085 Uiso calc U . R 1.0 . .
C C20 0.1984(6) 0.2054(7) 0.0721(4) 0.080(3) Uani d U . G 1.0 . .
H H20 0.1462 0.1457 0.0362 0.096 Uiso calc U . R 1.0 . .
C C21 0.1506(4) 0.3142(8) 0.0987(5) 0.079(3) Uani d U . G 1.0 . .
H H21 0.0663 0.3273 0.0807 0.095 Uiso calc U . R 1.0 . .
C C22 0.2286(6) 0.4034(6) 0.1524(4) 0.065(3) Uani d U . G 1.0 . .
H H22 0.1966 0.4762 0.1703 0.077 Uiso calc U . R 1.0 . .
C C23 0.4361(10) 0.4801(10) 0.2348(6) 0.060(2) Uani d U . . 1.0 . .
H H23A 0.3957 0.5566 0.2325 0.072 Uiso calc U . R 1.0 . .
H H23B 0.5127 0.4869 0.2186 0.072 Uiso calc U . R 1.0 . .
C C24 0.4679(11) 0.4542(12) 0.3239(7) 0.067(3) Uani d U . . 1.0 . .
H H24A 0.5066 0.3767 0.3253 0.081 Uiso calc U . R 1.0 . .
H H24B 0.5283 0.5157 0.357 0.081 Uiso calc U . R 1.0 . .
C C25 0.8555(6) 0.4643(6) 0.1795(4) 0.054(2) Uani d U . G 1.0 . .
C C26 0.7294(6) 0.4317(6) 0.1547(4) 0.070(3) Uani d U . G 1.0 . .
H H26 0.6979 0.3703 0.175 0.084 Uiso calc U . R 1.0 . .
C C27 0.6502(5) 0.4909(8) 0.0996(4) 0.076(3) Uani d U . G 1.0 . .
H H27 0.5658 0.4691 0.083 0.092 Uiso calc U . R 1.0 . .
C C28 0.6972(7) 0.5827(7) 0.0692(4) 0.080(3) Uani d U . G 1.0 . .
H H28 0.6442 0.6223 0.0323 0.096 Uiso calc U . R 1.0 . .
C C29 0.8234(7) 0.6153(6) 0.0939(4) 0.078(3) Uani d U . G 1.0 . .
H H29 0.8548 0.6767 0.0736 0.093 Uiso calc U . R 1.0 . .
C C30 0.9025(5) 0.5561(6) 0.1491(4) 0.064(2) Uani d U . G 1.0 . .
H H30 0.9869 0.5779 0.1656 0.077 Uiso calc U . R 1.0 . .
C C31 0.9432(10) 0.3995(12) 0.2424(7) 0.067(3) Uani d U . . 1.0 . .
H H31A 0.9295 0.3128 0.2256 0.08 Uiso calc U . R 1.0 . .
H H31B 1.0287 0.4196 0.2437 0.08 Uiso calc U . R 1.0 . .
C C32 0.9262(12) 0.4312(11) 0.3239(7) 0.067(3) Uani d U . . 1.0 . .
H H32A 0.8439 0.4026 0.3238 0.081 Uiso calc U . R 1.0 . .
H H32B 0.9862 0.3889 0.3592 0.081 Uiso calc U . R 1.0 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
Pb2 Cl3 Pb1 . . 152.92(12)
Pb1 Cl5 Pb2 2_666 . 151.00(12)
Pb2 Cl7 Pb1 . 2_766 150.60(12)
Pb1 Cl8 Pb2 1_565 . 153.37(12)
Pb1A Cl3A Pb2A . . 152.1(6)
Pb2A Cl5A Pb1A 2_666 . 149.4(6)
Pb2A Cl7A Pb1A 2_766 . 150.3(6)
Pb2A Cl8A Pb1A 1_565 . 153.8(6)
Cl2 Pb1 Cl8 . 1_545 91.35(10)
Cl2 Pb1 Cl5 . 2_666 97.42(9)
Cl8 Pb1 Cl5 1_545 2_666 87.89(9)
Cl2 Pb1 Cl7 . 2_766 91.07(9)
Cl8 Pb1 Cl7 1_545 2_766 86.86(9)
Cl5 Pb1 Cl7 2_666 2_766 170.11(9)
Cl2 Pb1 Cl3 . . 96.71(10)
Cl8 Pb1 Cl3 1_545 . 171.93(12)
Cl5 Pb1 Cl3 2_666 . 91.52(9)
Cl7 Pb1 Cl3 2_766 . 92.51(9)
Cl2 Pb1 Cl1 . . 178.93(8)
Cl8 Pb1 Cl1 1_545 . 87.72(9)
Cl5 Pb1 Cl1 2_666 . 83.09(8)
Cl7 Pb1 Cl1 2_766 . 88.34(8)
Cl3 Pb1 Cl1 . . 84.21(9)
Cl4 Pb2 Cl3 . . 90.91(10)
Cl4 Pb2 Cl7 . . 97.17(9)
Cl3 Pb2 Cl7 . . 87.82(9)
Cl4 Pb2 Cl5 . . 91.34(9)
Cl3 Pb2 Cl5 . . 87.32(9)
Cl7 Pb2 Cl5 . . 170.26(8)
Cl4 Pb2 Cl8 . . 96.93(10)
Cl3 Pb2 Cl8 . . 172.16(12)
Cl7 Pb2 Cl8 . . 91.15(9)
Cl5 Pb2 Cl8 . . 92.52(9)
Cl4 Pb2 Cl6 . . 178.75(9)
Cl3 Pb2 Cl6 . . 87.88(9)
Cl7 Pb2 Cl6 . . 83.09(9)
Cl5 Pb2 Cl6 . . 88.30(8)
Cl8 Pb2 Cl6 . . 84.28(9)
Cl6 Pb1A Cl3A . . 96.7(4)
Cl6 Pb1A Cl7A . . 93.0(4)
Cl3A Pb1A Cl7A . . 87.7(4)
Cl6 Pb1A Cl5A . . 97.5(4)
Cl3A Pb1A Cl5A . . 87.2(4)
Cl7A Pb1A Cl5A . . 168.8(4)
Cl6 Pb1A Cl8A . . 92.2(4)
Cl3A Pb1A Cl8A . . 171.1(7)
Cl7A Pb1A Cl8A . . 92.9(4)
Cl5A Pb1A Cl8A . . 90.7(4)
Cl1 Pb2A Cl8A . 1_545 98.4(4)
Cl1 Pb2A Cl7A . 2_766 97.2(4)
Cl8A Pb2A Cl7A 1_545 2_766 88.0(4)
Cl1 Pb2A Cl5A . 2_666 94.0(4)
Cl8A Pb2A Cl5A 1_545 2_666 86.3(4)
Cl7A Pb2A Cl5A 2_766 2_666 168.1(4)
Cl1 Pb2A Cl3A . . 92.2(4)
Cl8A Pb2A Cl3A 1_545 . 169.3(7)
Cl7A Pb2A Cl3A 2_766 . 91.4(4)
Cl5A Pb2A Cl3A 2_666 . 92.3(4)
C2 C1 C6 . . 119.8(10)
C2 C1 C7 . . 121.0(9)
C6 C1 C7 . . 119.2(9)
C1 C2 C3 . . 120.7(10)
C2 C3 C4 . . 118.9(12)
C5 C4 C3 . . 121.3(12)
C4 C5 C6 . . 118.9(12)
C1 C6 C5 . . 120.3(10)
C8 C7 C1 . . 114.9(9)
N1 C8 C7 . . 126.2(17)
N1A C8 C7 . . 113.1(10)
C10 C9 C14 . . 120.3(10)
C10 C9 C15 . . 120.9(9)
C14 C9 C15 . . 118.8(10)
C9 C10 C11 . . 122.8(10)
C10 C11 C12 . . 118.1(11)
C13 C12 C11 . . 116.7(11)
C12 C13 C14 . . 124.5(11)
C13 C14 C9 . . 117.6(10)
C9 C15 C16 . . 113.8(9)
N2 C16 C15 . . 112.7(11)
C18 C17 C22 . . 120.0
C18 C17 C23 . . 120.7(6)
C22 C17 C23 . . 119.3(6)
C19 C18 C17 . . 120.0
C18 C19 C20 . . 120.0
C21 C20 C19 . . 120.0
C20 C21 C22 . . 120.0
C21 C22 C17 . . 120.0
C17 C23 C24 . . 111.8(9)
N3 C24 C23 . . 114.7(10)
C26 C25 C30 . . 120.0
C26 C25 C31 . . 119.8(7)
C30 C25 C31 . . 120.2(7)
C25 C26 C27 . . 120.0
C28 C27 C26 . . 120.0
C29 C28 C27 . . 120.0
C30 C29 C28 . . 120.0
C29 C30 C25 . . 120.0
C32 C31 C25 . . 114.4(9)
N4 C32 C31 . . 114.5(11)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Cl1 Pb2A . 2.593(6)
Cl1 Pb1 . 3.043(3)
Cl2 Pb1 . 2.721(3)
Cl3 Pb2 . 2.845(3)
Cl3 Pb1 . 2.927(3)
Cl4 Pb2 . 2.712(3)
Cl5 Pb1 2_666 2.869(3)
Cl5 Pb2 . 2.875(3)
Cl6 Pb1A . 2.607(6)
Cl6 Pb2 . 3.048(3)
Cl7 Pb2 . 2.872(3)
Cl7 Pb1 2_766 2.879(3)
Cl8 Pb1 1_565 2.855(3)
Cl8 Pb2 . 2.923(3)
Cl3A Pb1A . 2.843(14)
Cl3A Pb2A . 2.980(14)
Cl5A Pb2A 2_666 2.881(15)
Cl5A Pb1A . 2.898(15)
Cl7A Pb2A 2_766 2.867(14)
Cl7A Pb1A . 2.875(14)
Cl8A Pb2A 1_565 2.842(13)
Cl8A Pb1A . 2.905(13)
N1 C8 . 1.426(19)
N1A C8 . 1.462(14)
N2 C16 . 1.425(15)
N3 C24 . 1.399(14)
N4 C32 . 1.472(14)
Pb1 Cl8 1_545 2.855(3)
Pb1 Cl5 2_666 2.869(3)
Pb1 Cl7 2_766 2.879(3)
Pb2A Cl8A 1_545 2.842(13)
Pb2A Cl7A 2_766 2.867(14)
Pb2A Cl5A 2_666 2.881(15)
C1 C2 . 1.373(14)
C1 C6 . 1.402(14)
C1 C7 . 1.553(13)
C2 C3 . 1.380(14)
C3 C4 . 1.421(17)
C4 C5 . 1.353(18)
C5 C6 . 1.407(15)
C7 C8 . 1.463(15)
C9 C10 . 1.334(14)
C9 C14 . 1.394(14)
C9 C15 . 1.495(13)
C10 C11 . 1.369(15)
C11 C12 . 1.462(16)
C12 C13 . 1.338(17)
C13 C14 . 1.379(15)
C15 C16 . 1.570(17)
C17 C18 . 1.39
C17 C22 . 1.39
C17 C23 . 1.469(11)
C18 C19 . 1.39
C19 C20 . 1.39
C20 C21 . 1.39
C21 C22 . 1.39
C23 C24 . 1.590(16)
C25 C26 . 1.39
C25 C30 . 1.39
C25 C31 . 1.554(12)
C26 C27 . 1.39
C27 C28 . 1.39
C28 C29 . 1.39
C29 C30 . 1.39
C31 C32 . 1.481(16)
