#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:48:01 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178628 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/39/4073917.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4073917
loop_
_publ_author_name
'Bedford, Robin B.'
'Betham, Michael'
'Charmant, Jonathan P. H.'
'Haddow, Mairi F.'
'Orpen, A. Guy'
'Pilarski, Lukasz T.'
'Coles, Simon J.'
'Hursthouse, Michael B.'
_publ_section_title
;
 Simple Palladacyclic and Platinacyclic Catalysts for the 1,4-Conjugate
 Addition of Arylboronic Acids and Arylsiloxanes to Enones
;
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              6346
_journal_paper_doi               10.1021/om700724c
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C28 H47 F3 O4 P2 Pd'
_chemical_formula_weight         673.00
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.308(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.7332(4)
_cell_length_b                   10.3695(7)
_cell_length_c                   23.1394(14)
_cell_measurement_reflns_used    8305
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.91
_cell_volume                     3513.7(3)
_computing_cell_refinement       'DENZO, COLLECT'
_computing_data_reduction        'DENZO, COLLECT'
_computing_molecular_graphics    'PLATON (Spek, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 9.091
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker-Nonius KappaCCD Area Detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Bruker-Nonius FR591 rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0334
_diffrn_reflns_av_sigmaI/netI    0.0292
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            35909
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.30
_diffrn_standards_decay_%        negligible
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    0.662
_exptl_absorpt_correction_T_max  0.9367
_exptl_absorpt_correction_T_min  0.8013
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2.10 (Sheldrick, G.M., 2003)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.272
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       slab
_exptl_crystal_F_000             1400
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.568
_refine_diff_density_min         -1.845
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.997
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     357
_refine_ls_number_reflns         8037
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.997
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0326
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0698P)²+0.9339P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0991
_refine_ls_wR_factor_ref         0.1047
_reflns_number_gt                6494
_reflns_number_total             8037
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om700724c-file001.cif
_cod_data_source_block           11b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4073917
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.17096(16) 0.3965(2) 0.27518(9) 0.0217(4) Uani 1 1 d .
H1 H 0.1039 0.3998 0.2625 0.026 Uiso 1 1 calc R
C2 C 0.21407(19) 0.5131(2) 0.24947(10) 0.0344(6) Uani 1 1 d .
H2A H 0.1866 0.5920 0.2631 0.052 Uiso 1 1 calc R
H2B H 0.2035 0.5092 0.2069 0.052 Uiso 1 1 calc R
H2C H 0.2799 0.5135 0.2617 0.052 Uiso 1 1 calc R
C3 C 0.18354(18) 0.4004(2) 0.34167(9) 0.0309(5) Uani 1 1 d .
H3A H 0.2484 0.3900 0.3556 0.046 Uiso 1 1 calc R
H3B H 0.1485 0.3303 0.3570 0.046 Uiso 1 1 calc R
H3C H 0.1618 0.4834 0.3551 0.046 Uiso 1 1 calc R
C4 C 0.17284(15) 0.1117(2) 0.28089(9) 0.0210(4) Uani 1 1 d .
H4 H 0.1840 0.1246 0.3239 0.025 Uiso 1 1 calc R
C5 C 0.06990(15) 0.0996(2) 0.26299(10) 0.0299(5) Uani 1 1 d .
H5A H 0.0585 0.0903 0.2207 0.045 Uiso 1 1 calc R
H5B H 0.0390 0.1772 0.2751 0.045 Uiso 1 1 calc R
H5C H 0.0464 0.0238 0.2818 0.045 Uiso 1 1 calc R
C6 C 0.22432(17) -0.0076(2) 0.26424(10) 0.0299(5) Uani 1 1 d .
H6A H 0.1996 -0.0840 0.2819 0.045 Uiso 1 1 calc R
H6B H 0.2892 0.0015 0.2782 0.045 Uiso 1 1 calc R
H6C H 0.2172 -0.0170 0.2218 0.045 Uiso 1 1 calc R
C7 C 0.34601(16) 0.24443(17) 0.16752(10) 0.0160(4) Uani 1 1 d .
C8 C 0.38416(15) 0.24883(17) 0.22554(9) 0.0156(4) Uani 1 1 d .
C9 C 0.47847(16) 0.24824(17) 0.24219(9) 0.0158(4) Uani 1 1 d .
C10 C 0.53358(15) 0.24531(17) 0.19697(10) 0.0167(4) Uani 1 1 d .
H10 H 0.5979 0.2456 0.2070 0.020 Uiso 1 1 calc R
C11 C 0.50099(15) 0.24188(17) 0.13756(10) 0.0159(4) Uani 1 1 d .
C12 C 0.40673(15) 0.24118(17) 0.12505(9) 0.0163(4) Uani 1 1 d .
C13 C 0.51884(16) 0.25092(18) 0.30631(10) 0.0189(5) Uani 1 1 d .
C14 C 0.62355(17) 0.2483(2) 0.31264(11) 0.0277(5) Uani 1 1 d .
H14A H 0.6464 0.3247 0.2939 0.041 Uiso 1 1 calc R
H14B H 0.6444 0.1704 0.2941 0.041 Uiso 1 1 calc R
H14C H 0.6468 0.2480 0.3540 0.041 Uiso 1 1 calc R
C15 C 0.48734(17) 0.1320(3) 0.33827(10) 0.0323(6) Uani 1 1 d .
H15A H 0.5167 0.1316 0.3784 0.048 Uiso 1 1 calc R
H15B H 0.5043 0.0536 0.3184 0.048 Uiso 1 1 calc R
H15C H 0.4209 0.1347 0.3385 0.048 Uiso 1 1 calc R
C16 C 0.49033(17) 0.3743(3) 0.33561(10) 0.0326(6) Uani 1 1 d .
H16A H 0.5157 0.3741 0.3766 0.049 Uiso 1 1 calc R
H16B H 0.4236 0.3786 0.3330 0.049 Uiso 1 1 calc R
H16C H 0.5135 0.4493 0.3161 0.049 Uiso 1 1 calc R
C17 C 0.56542(15) 0.24105(18) 0.08958(10) 0.0184(4) Uani 1 1 d .
C18 C 0.66518(17) 0.2413(2) 0.11428(12) 0.0321(6) Uani 1 1 d .
H18A H 0.6780 0.1649 0.1388 0.048 Uiso 1 1 calc R
H18B H 0.6783 0.3192 0.1376 0.048 Uiso 1 1 calc R
H18C H 0.7037 0.2398 0.0823 0.048 Uiso 1 1 calc R
C19 C 0.54969(16) 0.1203(2) 0.05151(10) 0.0265(5) Uani 1 1 d .
H19A H 0.5907 0.1220 0.0209 0.040 Uiso 1 1 calc R
H19B H 0.4862 0.1185 0.0337 0.040 Uiso 1 1 calc R
H19C H 0.5621 0.0431 0.0756 0.040 Uiso 1 1 calc R
C20 C 0.54893(16) 0.3618(2) 0.05133(10) 0.0265(5) Uani 1 1 d .
H20A H 0.5582 0.4392 0.0756 0.040 Uiso 1 1 calc R
H20B H 0.4862 0.3608 0.0322 0.040 Uiso 1 1 calc R
H20C H 0.5919 0.3625 0.0218 0.040 Uiso 1 1 calc R
C21 C 0.23447(15) 0.0867(2) 0.01444(9) 0.0219(4) Uani 1 1 d .
H21 H 0.2682 0.0893 -0.0208 0.026 Uiso 1 1 calc R
C22 C 0.26819(17) -0.0285(2) 0.05209(10) 0.0296(5) Uani 1 1 d .
H22A H 0.2358 -0.0312 0.0869 0.044 Uiso 1 1 calc R
H22B H 0.3339 -0.0199 0.0637 0.044 Uiso 1 1 calc R
H22C H 0.2564 -0.1084 0.0298 0.044 Uiso 1 1 calc R
C23 C 0.13210(15) 0.0774(2) -0.00491(10) 0.0302(5) Uani 1 1 d .
H23A H 0.1189 -0.0044 -0.0253 0.045 Uiso 1 1 calc R
H23B H 0.1135 0.1492 -0.0311 0.045 Uiso 1 1 calc R
H23C H 0.0983 0.0815 0.0292 0.045 Uiso 1 1 calc R
C24 C 0.23180(15) 0.3702(2) 0.00713(9) 0.0222(4) Uani 1 1 d .
H24 H 0.1647 0.3694 -0.0057 0.027 Uiso 1 1 calc R
C25 C 0.28194(16) 0.3636(2) -0.04691(9) 0.0277(5) Uani 1 1 d .
H25A H 0.2667 0.4396 -0.0712 0.042 Uiso 1 1 calc R
H25B H 0.2635 0.2855 -0.0690 0.042 Uiso 1 1 calc R
H25C H 0.3479 0.3613 -0.0354 0.042 Uiso 1 1 calc R
C26 C 0.25407(18) 0.4951(2) 0.04166(10) 0.0317(5) Uani 1 1 d .
H26A H 0.3197 0.4985 0.0544 0.048 Uiso 1 1 calc R
H26B H 0.2199 0.4968 0.0757 0.048 Uiso 1 1 calc R
H26C H 0.2368 0.5697 0.0168 0.048 Uiso 1 1 calc R
C27 C 0.02487(14) 0.3292(2) 0.11910(9) 0.0221(4) Uani 1 1 d .
C28 C -0.07817(15) 0.3064(2) 0.10708(10) 0.0273(5) Uani 1 1 d .
O1 O 0.32437(11) 0.25399(12) 0.26868(6) 0.0187(3) Uani 1 1 d .
O2 O 0.36893(11) 0.23758(13) 0.06669(7) 0.0191(3) Uani 1 1 d .
O3 O 0.06899(11) 0.22659(14) 0.12388(7) 0.0213(3) Uani 1 1 d .
O4 O 0.05190(12) 0.44060(17) 0.12408(10) 0.0510(5) Uani 1 1 d .
F1 F -0.10162(13) 0.23906(18) 0.05947(10) 0.0650(7) Uani 1 1 d .
F2 F -0.12655(9) 0.41501(14) 0.10220(7) 0.0426(4) Uani 1 1 d .
F3 F -0.10979(13) 0.24320(16) 0.15114(10) 0.0584(6) Uani 1 1 d .
P1 P 0.21551(4) 0.25104(5) 0.24425(2) 0.01551(13) Uani 1 1 d .
P2 P 0.25741(4) 0.23432(5) 0.05580(2) 0.01646(12) Uani 1 1 d .
Pd1 Pd 0.211965(10) 0.241417(14) 0.146215(6) 0.01476(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 C1 C3 111.32(19)
C2 C1 P1 108.74(15)
C3 C1 P1 114.06(16)
C2 C1 H1 107.5
C3 C1 H1 107.5
P1 C1 H1 107.5
C1 C2 H2A 109.5
C1 C2 H2B 109.5
H2A C2 H2B 109.5
C1 C2 H2C 109.5
H2A C2 H2C 109.5
H2B C2 H2C 109.5
C1 C3 H3A 109.5
C1 C3 H3B 109.5
H3A C3 H3B 109.5
C1 C3 H3C 109.5
H3A C3 H3C 109.5
H3B C3 H3C 109.5
C6 C4 C5 111.79(19)
C6 C4 P1 108.64(15)
C5 C4 P1 108.70(15)
C6 C4 H4 109.2
C5 C4 H4 109.2
P1 C4 H4 109.2
C4 C5 H5A 109.5
C4 C5 H5B 109.5
H5A C5 H5B 109.5
C4 C5 H5C 109.5
H5A C5 H5C 109.5
H5B C5 H5C 109.5
C4 C6 H6A 109.5
C4 C6 H6B 109.5
H6A C6 H6B 109.5
C4 C6 H6C 109.5
H6A C6 H6C 109.5
H6B C6 H6C 109.5
C8 C7 C12 117.0(2)
C8 C7 Pd1 121.58(16)
C12 C7 Pd1 121.40(17)
C7 C8 C9 123.1(2)
C7 C8 O1 117.83(19)
C9 C8 O1 119.08(19)
C10 C9 C8 115.8(2)
C10 C9 C13 122.0(2)
C8 C9 C13 122.2(2)
C9 C10 C11 124.8(2)
C9 C10 H10 117.6
C11 C10 H10 117.6
C12 C11 C10 115.5(2)
C12 C11 C17 122.2(2)
C10 C11 C17 122.3(2)
C11 C12 O2 118.89(19)
C11 C12 C7 123.8(2)
O2 C12 C7 117.34(19)
C16 C13 C15 110.3(2)
C16 C13 C14 107.17(18)
C15 C13 C14 107.07(18)
C16 C13 C9 110.33(17)
C15 C13 C9 110.18(17)
C14 C13 C9 111.74(19)
C13 C14 H14A 109.5
C13 C14 H14B 109.5
H14A C14 H14B 109.5
C13 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C13 C15 H15A 109.5
C13 C15 H15B 109.5
H15A C15 H15B 109.5
C13 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C13 C16 H16A 109.5
C13 C16 H16B 109.5
H16A C16 H16B 109.5
C13 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C18 C17 C19 107.25(18)
C18 C17 C20 107.51(18)
C19 C17 C20 109.3(2)
C18 C17 C11 112.17(19)
C19 C17 C11 110.66(17)
C20 C17 C11 109.88(17)
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C17 C19 H19A 109.5
C17 C19 H19B 109.5
H19A C19 H19B 109.5
C17 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C17 C20 H20A 109.5
C17 C20 H20B 109.5
H20A C20 H20B 109.5
C17 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C22 C21 C23 111.46(19)
C22 C21 P2 109.16(15)
C23 C21 P2 109.14(15)
C22 C21 H21 109.0
C23 C21 H21 109.0
P2 C21 H21 109.0
C21 C22 H22A 109.5
C21 C22 H22B 109.5
H22A C22 H22B 109.5
C21 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C21 C23 H23A 109.5
C21 C23 H23B 109.5
H23A C23 H23B 109.5
C21 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C25 C24 C26 111.71(18)
C25 C24 P2 112.79(16)
C26 C24 P2 108.25(15)
C25 C24 H24 108.0
C26 C24 H24 108.0
P2 C24 H24 108.0
C24 C25 H25A 109.5
C24 C25 H25B 109.5
H25A C25 H25B 109.5
C24 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
C24 C26 H26A 109.5
C24 C26 H26B 109.5
H26A C26 H26B 109.5
C24 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
O4 C27 O3 129.6(2)
O4 C27 C28 118.0(2)
O3 C27 C28 112.43(19)
F1 C28 F2 106.8(2)
F1 C28 F3 107.2(2)
F2 C28 F3 104.53(19)
F1 C28 C27 113.41(19)
F2 C28 C27 113.30(19)
F3 C28 C27 111.0(2)
C8 O1 P1 114.86(13)
C12 O2 P2 115.76(13)
C27 O3 Pd1 117.06(14)
O1 P1 C4 103.21(9)
O1 P1 C1 103.28(9)
C4 P1 C1 108.43(11)
O1 P1 Pd1 105.06(6)
C4 P1 Pd1 117.38(7)
C1 P1 Pd1 117.39(7)
O2 P2 C21 102.95(9)
O2 P2 C24 102.48(9)
C21 P2 C24 108.23(10)
O2 P2 Pd1 104.53(6)
C21 P2 Pd1 117.18(7)
C24 P2 Pd1 118.98(7)
C7 Pd1 O3 176.73(7)
C7 Pd1 P1 80.65(7)
O3 Pd1 P1 99.23(5)
C7 Pd1 P2 80.96(7)
O3 Pd1 P2 99.15(5)
P1 Pd1 P2 161.61(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C2 1.517(3)
C1 C3 1.530(3)
C1 P1 1.823(2)
C1 H1 1.0000
C2 H2A 0.9800
C2 H2B 0.9800
C2 H2C 0.9800
C3 H3A 0.9800
C3 H3B 0.9800
C3 H3C 0.9800
C4 C6 1.522(3)
C4 C5 1.533(3)
C4 P1 1.822(2)
C4 H4 1.0000
C5 H5A 0.9800
C5 H5B 0.9800
C5 H5C 0.9800
C6 H6A 0.9800
C6 H6B 0.9800
C6 H6C 0.9800
C7 C8 1.398(3)
C7 C12 1.400(3)
C7 Pd1 1.982(2)
C8 C9 1.401(3)
C8 O1 1.403(3)
C9 C10 1.393(3)
C9 C13 1.537(3)
C10 C11 1.406(3)
C10 H10 0.9500
C11 C12 1.387(3)
C11 C17 1.538(3)
C12 O2 1.404(3)
C13 C16 1.528(3)
C13 C15 1.536(3)
C13 C14 1.534(3)
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
C16 H16A 0.9800
C16 H16B 0.9800
C16 H16C 0.9800
C17 C18 1.517(3)
C17 C19 1.534(3)
C17 C20 1.537(3)
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
C21 C22 1.529(3)
C21 C23 1.528(3)
C21 P2 1.817(2)
C21 H21 1.0000
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 H23A 0.9800
C23 H23B 0.9800
C23 H23C 0.9800
C24 C25 1.522(3)
C24 C26 1.538(3)
C24 P2 1.818(2)
C24 H24 1.0000
C25 H25A 0.9800
C25 H25B 0.9800
C25 H25C 0.9800
C26 H26A 0.9800
C26 H26B 0.9800
C26 H26C 0.9800
C27 O4 1.223(3)
C27 O3 1.245(3)
C27 C28 1.531(3)
C28 F1 1.318(3)
C28 F2 1.331(3)
C28 F3 1.338(3)
O1 P1 1.6412(17)
O2 P2 1.6350(17)
O3 Pd1 2.1187(16)
P1 Pd1 2.2656(6)
P2 Pd1 2.2669(6)
