#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:08:53 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178637 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/48/4074899.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4074899
loop_
_publ_author_name
'Schuster, Oliver'
'Monkowius, Uwe'
'Schmidbaur, Hubert'
'Ray, R. Shyama'
'Krüger, Sven'
'Rösch, Notker'
_publ_section_title
;
 Unexpected Structural Preference for Aggregates with Metallophilic
 Ag- - -Au Contacts in (Trimethylphosphine)silver(I) and
 -gold(I) Phenylethynyl Complexes. An Experimental and Theoretical Study
;
_journal_issue                   4
_journal_name_full               Organometallics
_journal_page_first              1004
_journal_paper_doi               10.1021/om050985z
_journal_volume                  25
_journal_year                    2006
_chemical_formula_sum            'C54 H48 Ag3 Au3 P2'
_chemical_formula_weight         1673.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 123.9803(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   33.0696(4)
_cell_length_b                   9.9668(2)
_cell_length_c                   18.6939(3)
_cell_measurement_reflns_used    59586
_cell_measurement_temperature    143(2)
_cell_volume                     5109.28(15)
_computing_cell_refinement       DENZO
_computing_data_collection       XPRESS
_computing_data_reduction        SCALEPACK
_computing_molecular_graphics    SHELXTL-PLUS
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      143(2)
_diffrn_measured_fraction_theta_full 0.952
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measurement_device_type  'NONIUS DIP 2020'
_diffrn_measurement_method       phi-rotation
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.075
_diffrn_reflns_av_sigmaI/netI    0.0467
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            59586
_diffrn_reflns_theta_full        25.43
_diffrn_reflns_theta_max         25.43
_diffrn_reflns_theta_min         2.63
_exptl_absorpt_coefficient_mu    9.806
_exptl_absorpt_correction_T_max  0.859
_exptl_absorpt_correction_T_min  0.544
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details
;
Platon Delabs
(See: Walker, N. & Stuart, D. (1983) Acta Cryst. A39, 158-166)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.175
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3120
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.205
_refine_diff_density_min         -1.433
_refine_diff_density_rms         0.152
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.080(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     565
_refine_ls_number_reflns         8852
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0396
_refine_ls_R_factor_gt           0.0371
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0470P)²+31.3640P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0941
_refine_ls_wR_factor_ref         0.0959
_reflns_number_gt                8423
_reflns_number_total             8852
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om050985zsi20051116_045242.cif
_cod_data_source_block           40c2cos
_cod_original_cell_volume        5109.27(15)
_cod_original_sg_symbol_H-M      Cc
_cod_database_code               4074899
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.48963(3) -0.07990(6) -0.69576(5) 0.03439(17) Uani 1 1 d .
P1 P -0.53951(11) -0.0814(2) -0.85001(17) 0.0412(6) Uani 1 1 d .
Au2 Au -0.483769(16) -0.78016(4) -0.69678(3) 0.04792(12) Uani 1 1 d .
P2 P -0.44297(11) -0.0843(2) -0.54152(17) 0.0399(6) Uani 1 1 d .
Au1 Au -0.479776(15) -0.37963(4) -0.68737(2) 0.04359(11) Uani 1 1 d .
Au3 Au -0.54931(2) -0.54533(5) -0.90949(3) 0.05227(12) Uani 1 1 d .
Ag2 Ag -0.56087(3) -0.57225(7) -0.76191(6) 0.04433(19) Uani 1 1 d .
Ag3 Ag -0.44600(3) -0.59138(8) -0.75993(6) 0.0464(2) Uani 1 1 d .
C111 C -0.5426(4) -0.3540(11) -0.6983(7) 0.047(3) Uani 1 1 d .
C13 C -0.5948(5) -0.1737(15) -0.8923(9) 0.069(4) Uani 1 1 d .
H13A H -0.6156 -0.1268 -0.8784 0.103 Uiso 1 1 calc R
H13B H -0.5871 -0.2635 -0.8665 0.103 Uiso 1 1 calc R
H13C H -0.6119 -0.1815 -0.9550 0.103 Uiso 1 1 calc R
C11 C -0.5111(5) -0.1627(18) -0.9007(9) 0.075(4) Uani 1 1 d .
H11A H -0.5171 -0.1080 -0.9493 0.113 Uiso 1 1 calc R
H11B H -0.5254 -0.2520 -0.9217 0.113 Uiso 1 1 calc R
H11C H -0.4759 -0.1713 -0.8581 0.113 Uiso 1 1 calc R
C12 C -0.5595(7) 0.0781(11) -0.9042(9) 0.071(5) Uani 1 1 d .
H12A H -0.5811 0.0636 -0.9666 0.106 Uiso 1 1 calc R
H12B H -0.5311 0.1307 -0.8912 0.106 Uiso 1 1 calc R
H12C H -0.5771 0.1269 -0.8842 0.106 Uiso 1 1 calc R
C112 C -0.5795(4) -0.3349(10) -0.6998(7) 0.042(2) Uani 1 1 d .
C113 C -0.6235(4) -0.3021(10) -0.7013(7) 0.042(2) Uani 1 1 d .
C118 C -0.6675(5) -0.2897(15) -0.7771(8) 0.065(4) Uani 1 1 d .
H118 H -0.6698 -0.2971 -0.8300 0.079 Uiso 1 1 calc R
C117 C -0.7088(5) -0.2664(17) -0.7777(10) 0.076(4) Uani 1 1 d .
H117 H -0.7394 -0.2611 -0.8317 0.091 Uiso 1 1 calc R
C116 C -0.7075(5) -0.2513(14) -0.7068(12) 0.071(4) Uani 1 1 d .
H116 H -0.7362 -0.2319 -0.7089 0.085 Uiso 1 1 calc R
C115 C -0.6603(5) -0.2652(14) -0.6245(10) 0.063(3) Uani 1 1 d .
H115 H -0.6577 -0.2547 -0.5716 0.075 Uiso 1 1 calc R
C114 C -0.6211(5) -0.2928(12) -0.6251(9) 0.054(3) Uani 1 1 d .
H114 H -0.5907 -0.3065 -0.5719 0.065 Uiso 1 1 calc R
C121 C -0.4134(5) -0.4061(11) -0.6636(8) 0.053(3) Uani 1 1 d .
C23 C -0.4256(5) 0.0765(11) -0.4898(9) 0.057(3) Uani 1 1 d .
H23A H -0.4094 0.0649 -0.4274 0.085 Uiso 1 1 calc R
H23B H -0.4547 0.1325 -0.5125 0.085 Uiso 1 1 calc R
H23C H -0.4031 0.1201 -0.5011 0.085 Uiso 1 1 calc R
C21 C -0.3871(5) -0.1753(13) -0.4894(9) 0.066(4) Uani 1 1 d .
H21A H -0.3651 -0.1335 -0.5025 0.098 Uiso 1 1 calc R
H21B H -0.3936 -0.2682 -0.5101 0.098 Uiso 1 1 calc R
H21C H -0.3718 -0.1743 -0.4269 0.098 Uiso 1 1 calc R
C22 C -0.4750(6) -0.1599(15) -0.5013(9) 0.074(4) Uani 1 1 d .
H22A H -0.4931 -0.2379 -0.5368 0.110 Uiso 1 1 calc R
H22B H -0.4979 -0.0948 -0.5033 0.110 Uiso 1 1 calc R
H22C H -0.4518 -0.1886 -0.4416 0.110 Uiso 1 1 calc R
C122 C -0.3700(4) -0.4351(10) -0.6344(7) 0.043(2) Uani 1 1 d .
C123 C -0.3200(4) -0.4632(12) -0.5941(7) 0.045(2) Uani 1 1 d .
C128 C -0.3049(5) -0.5918(12) -0.5940(8) 0.050(3) Uani 1 1 d .
H128 H -0.3284 -0.6610 -0.6235 0.060 Uiso 1 1 calc R
C127 C -0.2551(5) -0.6214(15) -0.5506(9) 0.066(4) Uani 1 1 d .
H127 H -0.2447 -0.7108 -0.5494 0.079 Uiso 1 1 calc R
C126 C -0.2220(5) -0.5228(19) -0.5108(10) 0.077(4) Uani 1 1 d .
H126 H -0.1884 -0.5429 -0.4831 0.092 Uiso 1 1 calc R
C125 C -0.2358(5) -0.3945(17) -0.5092(10) 0.075(4) Uani 1 1 d .
H125 H -0.2117 -0.3267 -0.4801 0.089 Uiso 1 1 calc R
C124 C -0.2860(5) -0.3613(14) -0.5508(10) 0.065(4) Uani 1 1 d .
H124 H -0.2960 -0.2726 -0.5491 0.078 Uiso 1 1 calc R
C221 C -0.4312(4) -0.8162(11) -0.7171(7) 0.044(2) Uani 1 1 d .
C222 C -0.4030(4) -0.8751(10) -0.7275(7) 0.039(2) Uani 1 1 d .
C223 C -0.3712(4) -0.9623(10) -0.7381(6) 0.038(2) Uani 1 1 d .
C224 C -0.3780(4) -1.0996(10) -0.7390(7) 0.046(2) Uani 1 1 d .
H224 H -0.4025 -1.1346 -0.7326 0.055 Uiso 1 1 calc R
C225 C -0.3492(5) -1.1838(13) -0.7493(8) 0.054(3) Uani 1 1 d .
H225 H -0.3534 -1.2781 -0.7495 0.065 Uiso 1 1 calc R
C226 C -0.3139(5) -1.1331(13) -0.7595(7) 0.055(3) Uani 1 1 d .
H226 H -0.2948 -1.1932 -0.7683 0.066 Uiso 1 1 calc R
C227 C -0.3061(5) -1.0005(16) -0.7572(8) 0.064(3) Uani 1 1 d .
H227 H -0.2805 -0.9671 -0.7611 0.077 Uiso 1 1 calc R
C228 C -0.3365(5) -0.9117(11) -0.7489(8) 0.050(3) Uani 1 1 d .
H228 H -0.3329 -0.8175 -0.7509 0.060 Uiso 1 1 calc R
C311 C -0.6110(6) -0.5594(13) -0.9135(8) 0.059(4) Uani 1 1 d .
C312 C -0.6486(5) -0.5679(11) -0.9179(7) 0.046(3) Uani 1 1 d .
C313 C -0.6952(4) -0.5728(11) -0.9277(7) 0.045(3) Uani 1 1 d .
C314 C -0.7369(4) -0.5187(13) -0.9957(8) 0.054(3) Uani 1 1 d .
H314 H -0.7364 -0.4724 -1.0396 0.064 Uiso 1 1 calc R
C315 C -0.7794(5) -0.5308(17) -1.0009(10) 0.073(4) Uani 1 1 d .
H315 H -0.8083 -0.4940 -1.0494 0.088 Uiso 1 1 calc R
C316 C -0.7820(6) -0.5938(17) -0.9392(12) 0.081(5) Uani 1 1 d .
H316 H -0.8120 -0.5989 -0.9438 0.098 Uiso 1 1 calc R
C317 C -0.7407(5) -0.650(2) -0.8705(10) 0.079(4) Uani 1 1 d .
H317 H -0.7418 -0.6928 -0.8263 0.094 Uiso 1 1 calc R
C318 C -0.6977(5) -0.6436(17) -0.8650(8) 0.070(4) Uani 1 1 d .
H318 H -0.6696 -0.6872 -0.8189 0.084 Uiso 1 1 calc R
C211 C -0.5376(4) -0.7656(11) -0.6780(8) 0.051(3) Uani 1 1 d .
C212 C -0.5699(4) -0.7706(10) -0.6648(7) 0.040(2) Uani 1 1 d .
C213 C -0.6083(4) -0.7709(10) -0.6517(7) 0.042(2) Uani 1 1 d .
C218 C -0.6184(5) -0.6569(12) -0.6211(9) 0.051(3) Uani 1 1 d .
H218 H -0.5987 -0.5790 -0.6071 0.061 Uiso 1 1 calc R
C217 C -0.6567(5) -0.6558(16) -0.6110(9) 0.063(3) Uani 1 1 d .
H217 H -0.6638 -0.5770 -0.5913 0.076 Uiso 1 1 calc R
C216 C -0.6847(5) -0.7705(18) -0.6296(9) 0.075(5) Uani 1 1 d .
H216 H -0.7116 -0.7699 -0.6242 0.090 Uiso 1 1 calc R
C215 C -0.6736(5) -0.8826(16) -0.6553(10) 0.069(4) Uani 1 1 d .
H215 H -0.6924 -0.9613 -0.6660 0.083 Uiso 1 1 calc R
C214 C -0.6362(5) -0.8870(13) -0.6665(10) 0.068(4) Uani 1 1 d .
H214 H -0.6291 -0.9680 -0.6843 0.082 Uiso 1 1 calc R
C321 C -0.4878(5) -0.5266(10) -0.9042(7) 0.045(3) Uani 1 1 d .
C322 C -0.4499(4) -0.5108(11) -0.9007(7) 0.042(2) Uani 1 1 d .
C323 C -0.4069(4) -0.4906(10) -0.9011(7) 0.044(2) Uani 1 1 d .
C324 C -0.3613(5) -0.5289(13) -0.8288(9) 0.056(3) Uani 1 1 d .
H324 H -0.3583 -0.5671 -0.7795 0.067 Uiso 1 1 calc R
C325 C -0.3212(5) -0.5094(15) -0.8317(11) 0.071(4) Uani 1 1 d .
H325 H -0.2901 -0.5376 -0.7843 0.085 Uiso 1 1 calc R
C326 C -0.3250(7) -0.4496(16) -0.9021(15) 0.083(6) Uani 1 1 d .
H326 H -0.2965 -0.4349 -0.9018 0.100 Uiso 1 1 calc R
C327 C -0.3688(8) -0.4120(14) -0.9711(14) 0.076(5) Uani 1 1 d .
H327 H -0.3715 -0.3716 -1.0195 0.092 Uiso 1 1 calc R
C328 C -0.4098(6) -0.4328(11) -0.9704(9) 0.051(3) Uani 1 1 d .
H328 H -0.4407 -0.4065 -1.0190 0.061 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Ag1 P2 177.09(11) . .
P1 Ag1 Au2 90.12(6) . 1_565
P2 Ag1 Au2 91.46(6) . 1_565
P1 Ag1 Au1 92.20(6) . .
P2 Ag1 Au1 86.61(6) . .
Au2 Ag1 Au1 171.26(3) 1_565 .
C13 P1 C12 104.1(7) . .
C13 P1 C11 103.5(8) . .
C12 P1 C11 103.3(8) . .
C13 P1 Ag1 112.4(5) . .
C12 P1 Ag1 117.5(5) . .
C11 P1 Ag1 114.5(5) . .
C211 Au2 C221 173.8(5) . .
C211 Au2 Ag3 131.5(3) . .
C221 Au2 Ag3 54.2(3) . .
C211 Au2 Ag2 51.5(3) . .
C221 Au2 Ag2 133.1(3) . .
Ag3 Au2 Ag2 81.04(3) . .
C211 Au2 Ag1 90.2(3) . 1_545
C221 Au2 Ag1 83.6(3) . 1_545
Ag3 Au2 Ag1 134.86(3) . 1_545
Ag2 Au2 Ag1 130.95(3) . 1_545
C22 P2 C21 103.6(8) . .
C22 P2 C23 103.8(7) . .
C21 P2 C23 103.8(6) . .
C22 P2 Ag1 112.5(5) . .
C21 P2 Ag1 116.2(5) . .
C23 P2 Ag1 115.5(5) . .
C111 Au1 C121 174.3(5) . .
C111 Au1 Ag2 53.9(3) . .
C121 Au1 Ag2 128.1(3) . .
C111 Au1 Ag1 77.9(3) . .
C121 Au1 Ag1 102.5(3) . .
Ag2 Au1 Ag1 125.59(3) . .
C111 Au1 Ag3 131.9(3) . .
C121 Au1 Ag3 51.3(3) . .
Ag2 Au1 Ag3 78.49(3) . .
Ag1 Au1 Ag3 136.43(3) . .
C321 Au3 C311 178.5(5) . .
C321 Au3 Ag2 127.9(3) . .
C311 Au3 Ag2 51.5(4) . .
C321 Au3 Ag3 50.8(3) . .
C311 Au3 Ag3 128.9(4) . .
Ag2 Au3 Ag3 78.09(3) . .
C211 Ag2 C311 126.9(4) . .
C211 Ag2 C111 121.5(4) . .
C311 Ag2 C111 111.2(4) . .
C211 Ag2 Au1 110.5(3) . .
C311 Ag2 Au1 112.2(4) . .
C111 Ag2 Au1 42.3(3) . .
C211 Ag2 Au2 42.3(3) . .
C311 Ag2 Au2 113.4(4) . .
C111 Ag2 Au2 120.8(3) . .
Au1 Ag2 Au2 85.10(3) . .
C211 Ag2 Au3 121.9(3) . .
C311 Ag2 Au3 41.8(4) . .
C111 Ag2 Au3 104.5(3) . .
Au1 Ag2 Au3 79.99(2) . .
Au2 Ag2 Au3 85.29(3) . .
C321 Ag3 C221 122.5(4) . .
C321 Ag3 C121 112.7(4) . .
C221 Ag3 C121 124.5(4) . .
C321 Ag3 C322 27.2(4) . .
C221 Ag3 C322 120.6(4) . .
C121 Ag3 C322 105.2(4) . .
C321 Ag3 Au2 123.2(3) . .
C221 Ag3 Au2 44.1(3) . .
C121 Ag3 Au2 108.5(3) . .
C322 Ag3 Au2 144.1(2) . .
C321 Ag3 Au3 41.4(3) . .
C221 Ag3 Au3 112.1(3) . .
C121 Ag3 Au3 112.7(4) . .
C322 Ag3 Au3 68.6(2) . .
Au2 Ag3 Au3 87.29(3) . .
C321 Ag3 Au1 101.3(3) . .
C221 Ag3 Au1 124.8(3) . .
C121 Ag3 Au1 41.1(4) . .
C322 Ag3 Au1 113.7(2) . .
Au2 Ag3 Au1 85.31(3) . .
Au3 Ag3 Au1 78.39(3) . .
C112 C111 Au1 175.9(10) . .
C112 C111 Ag2 99.2(8) . .
Au1 C111 Ag2 83.8(4) . .
P1 C13 H13A 109.5 . .
P1 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
P1 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
P1 C11 H11A 109.5 . .
P1 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
P1 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
P1 C12 H12A 109.5 . .
P1 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
P1 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C111 C112 C113 176.2(11) . .
C118 C113 C114 118.8(11) . .
C118 C113 C112 120.7(11) . .
C114 C113 C112 120.4(11) . .
C113 C118 C117 120.2(13) . .
C113 C118 H118 119.9 . .
C117 C118 H118 119.9 . .
C116 C117 C118 122.6(13) . .
C116 C117 H117 118.7 . .
C118 C117 H117 118.7 . .
C117 C116 C115 117.8(12) . .
C117 C116 H116 121.1 . .
C115 C116 H116 121.1 . .
C114 C115 C116 118.8(13) . .
C114 C115 H115 120.6 . .
C116 C115 H115 120.6 . .
C115 C114 C113 121.8(14) . .
C115 C114 H114 119.1 . .
C113 C114 H114 119.1 . .
C122 C121 Au1 167.6(11) . .
C122 C121 Ag3 94.4(8) . .
Au1 C121 Ag3 87.5(5) . .
P2 C23 H23A 109.5 . .
P2 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
P2 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
P2 C21 H21A 109.5 . .
P2 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
P2 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
P2 C22 H22A 109.5 . .
P2 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
P2 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C121 C122 C123 174.8(12) . .
C128 C123 C124 120.4(12) . .
C128 C123 C122 120.1(10) . .
C124 C123 C122 119.4(11) . .
C123 C128 C127 120.3(12) . .
C123 C128 H128 119.8 . .
C127 C128 H128 119.8 . .
C126 C127 C128 119.7(13) . .
C126 C127 H127 120.1 . .
C128 C127 H127 120.1 . .
C127 C126 C125 121.3(13) . .
C127 C126 H126 119.3 . .
C125 C126 H126 119.3 . .
C126 C125 C124 120.5(13) . .
C126 C125 H125 119.7 . .
C124 C125 H125 119.7 . .
C123 C124 C125 117.7(13) . .
C123 C124 H124 121.2 . .
C125 C124 H124 121.2 . .
C222 C221 Au2 161.3(10) . .
C222 C221 Ag3 116.3(9) . .
Au2 C221 Ag3 81.7(4) . .
C221 C222 C223 172.5(11) . .
C228 C223 C224 120.4(10) . .
C228 C223 C222 121.8(9) . .
C224 C223 C222 117.8(10) . .
C225 C224 C223 119.3(11) . .
C225 C224 H224 120.4 . .
C223 C224 H224 120.4 . .
C224 C225 C226 120.4(12) . .
C224 C225 H225 119.8 . .
C226 C225 H225 119.8 . .
C227 C226 C225 121.3(12) . .
C227 C226 H226 119.3 . .
C225 C226 H226 119.3 . .
C226 C227 C228 119.0(13) . .
C226 C227 H227 120.5 . .
C228 C227 H227 120.5 . .
C223 C228 C227 119.5(12) . .
C223 C228 H228 120.2 . .
C227 C228 H228 120.2 . .
C312 C311 Au3 178.5(11) . .
C312 C311 Ag2 94.9(10) . .
Au3 C311 Ag2 86.6(5) . .
C311 C312 C313 176.5(13) . .
C314 C313 C318 118.3(12) . .
C314 C313 C312 123.9(11) . .
C318 C313 C312 117.7(11) . .
C315 C314 C313 120.0(13) . .
C315 C314 H314 120.0 . .
C313 C314 H314 120.0 . .
C316 C315 C314 122.4(14) . .
C316 C315 H315 118.8 . .
C314 C315 H315 118.8 . .
C315 C316 C317 118.9(15) . .
C315 C316 H316 120.6 . .
C317 C316 H316 120.6 . .
C316 C317 C318 120.2(14) . .
C316 C317 H317 119.9 . .
C318 C317 H317 119.9 . .
C317 C318 C313 120.1(12) . .
C317 C318 H318 119.9 . .
C313 C318 H318 119.9 . .
C212 C211 Au2 173.4(9) . .
C212 C211 Ag2 99.9(8) . .
Au2 C211 Ag2 86.2(4) . .
C211 C212 C213 177.4(11) . .
C218 C213 C214 117.9(12) . .
C218 C213 C212 120.8(10) . .
C214 C213 C212 121.2(11) . .
C217 C218 C213 120.8(12) . .
C217 C218 H218 119.6 . .
C213 C218 H218 119.6 . .
C218 C217 C216 119.6(13) . .
C218 C217 H217 120.2 . .
C216 C217 H217 120.2 . .
C215 C216 C217 119.7(13) . .
C215 C216 H216 120.1 . .
C217 C216 H216 120.1 . .
C216 C215 C214 122.2(13) . .
C216 C215 H215 118.9 . .
C214 C215 H215 118.9 . .
C215 C214 C213 119.6(13) . .
C215 C214 H214 120.2 . .
C213 C214 H214 120.2 . .
C322 C321 Au3 178.0(9) . .
C322 C321 Ag3 92.7(8) . .
Au3 C321 Ag3 87.8(4) . .
C321 C322 C323 177.2(12) . .
C321 C322 Ag3 60.1(7) . .
C323 C322 Ag3 122.7(8) . .
C328 C323 C324 119.5(12) . .
C328 C323 C322 121.1(11) . .
C324 C323 C322 119.4(10) . .
C325 C324 C323 117.9(13) . .
C325 C324 H324 121.1 . .
C323 C324 H324 121.1 . .
C324 C325 C326 121.4(15) . .
C324 C325 H325 119.3 . .
C326 C325 H325 119.3 . .
C327 C326 C325 120.5(15) . .
C327 C326 H326 119.7 . .
C325 C326 H326 119.7 . .
C326 C327 C328 119.1(16) . .
C326 C327 H327 120.4 . .
C328 C327 H327 120.4 . .
C323 C328 C327 121.5(15) . .
C323 C328 H328 119.2 . .
C327 C328 H328 119.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P1 2.392(3) .
Ag1 P2 2.392(3) .
Ag1 Au2 2.9945(8) 1_565
Ag1 Au1 2.9996(8) .
P1 C13 1.788(14) .
P1 C12 1.801(11) .
P1 C11 1.852(14) .
Au2 C211 2.002(13) .
Au2 C221 2.007(12) .
Au2 Ag3 2.8535(10) .
Au2 Ag2 2.9676(9) .
Au2 Ag1 2.9945(8) 1_545
P2 C22 1.774(13) .
P2 C21 1.782(13) .
P2 C23 1.793(11) .
Au1 C111 1.988(13) .
Au1 C121 2.000(16) .
Au1 Ag2 2.9397(9) .
Au1 Ag3 3.0390(9) .
Au3 C321 1.988(13) .
Au3 C311 2.005(18) .
Au3 Ag2 3.0014(11) .
Au3 Ag3 3.0038(11) .
Ag2 C211 2.327(11) .
Ag2 C311 2.354(13) .
Ag2 C111 2.389(11) .
Ag3 C321 2.330(11) .
Ag3 C221 2.338(11) .
Ag3 C121 2.375(11) .
Ag3 C322 2.685(11) .
C111 C112 1.220(16) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C112 C113 1.476(15) .
C113 C118 1.353(17) .
C113 C114 1.385(17) .
C118 C117 1.38(2) .
C118 H118 0.9500 .
C117 C116 1.31(2) .
C117 H117 0.9500 .
C116 C115 1.46(2) .
C116 H116 0.9500 .
C115 C114 1.332(18) .
C115 H115 0.9500 .
C114 H114 0.9500 .
C121 C122 1.250(19) .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C122 C123 1.410(16) .
C123 C128 1.375(17) .
C123 C124 1.390(16) .
C128 C127 1.403(18) .
C128 H128 0.9500 .
C127 C126 1.34(2) .
C127 H127 0.9500 .
C126 C125 1.36(2) .
C126 H126 0.9500 .
C125 C124 1.42(2) .
C125 H125 0.9500 .
C124 H124 0.9500 .
C221 C222 1.209(15) .
C222 C223 1.459(14) .
C223 C228 1.370(17) .
C223 C224 1.385(14) .
C224 C225 1.362(16) .
C224 H224 0.9500 .
C225 C226 1.378(19) .
C225 H225 0.9500 .
C226 C227 1.34(2) .
C226 H226 0.9500 .
C227 C228 1.411(19) .
C227 H227 0.9500 .
C228 H228 0.9500 .
C311 C312 1.20(2) .
C312 C313 1.447(18) .
C313 C314 1.360(17) .
C313 C318 1.411(18) .
C314 C315 1.36(2) .
C314 H314 0.9500 .
C315 C316 1.36(3) .
C315 H315 0.9500 .
C316 C317 1.36(2) .
C316 H316 0.9500 .
C317 C318 1.37(2) .
C317 H317 0.9500 .
C318 H318 0.9500 .
C211 C212 1.227(16) .
C212 C213 1.418(15) .
C213 C218 1.395(16) .
C213 C214 1.409(17) .
C218 C217 1.380(18) .
C218 H218 0.9500 .
C217 C216 1.39(2) .
C217 H217 0.9500 .
C216 C215 1.35(2) .
C216 H216 0.9500 .
C215 C214 1.37(2) .
C215 H215 0.9500 .
C214 H214 0.9500 .
C321 C322 1.230(16) .
C322 C323 1.438(16) .
C323 C328 1.373(17) .
C323 C324 1.403(18) .
C324 C325 1.37(2) .
C324 H324 0.9500 .
C325 C326 1.39(3) .
C325 H325 0.9500 .
C326 C327 1.35(3) .
C326 H326 0.9500 .
C327 C328 1.38(2) .
C327 H327 0.9500 .
C328 H328 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
P2 Ag1 P1 C13 -5(2) .
Au2 Ag1 P1 C13 -127.6(6) 1_565
Au1 Ag1 P1 C13 60.9(6) .
P2 Ag1 P1 C12 116(2) .
Au2 Ag1 P1 C12 -6.8(8) 1_565
Au1 Ag1 P1 C12 -178.4(8) .
P2 Ag1 P1 C11 -123(2) .
Au2 Ag1 P1 C11 114.6(6) 1_565
Au1 Ag1 P1 C11 -56.9(6) .
P1 Ag1 P2 C22 -2(2) .
Au2 Ag1 P2 C22 120.8(6) 1_565
Au1 Ag1 P2 C22 -67.7(6) .
P1 Ag1 P2 C21 117(2) .
Au2 Ag1 P2 C21 -120.0(5) 1_565
Au1 Ag1 P2 C21 51.4(5) .
P1 Ag1 P2 C23 -121(2) .
Au2 Ag1 P2 C23 1.9(6) 1_565
Au1 Ag1 P2 C23 173.3(6) .
P1 Ag1 Au1 C111 -84.6(3) .
P2 Ag1 Au1 C111 92.7(3) .
Au2 Ag1 Au1 C111 170.2(4) 1_565
P1 Ag1 Au1 C121 101.2(4) .
P2 Ag1 Au1 C121 -81.4(4) .
Au2 Ag1 Au1 C121 -4.0(4) 1_565
P1 Ag1 Au1 Ag2 -58.08(9) .
P2 Ag1 Au1 Ag2 119.26(8) .
Au2 Ag1 Au1 Ag2 -163.33(19) 1_565
P1 Ag1 Au1 Ag3 55.26(9) .
P2 Ag1 Au1 Ag3 -127.39(8) .
Au2 Ag1 Au1 Ag3 -50.0(2) 1_565
C111 Au1 Ag2 C211 -114.7(5) .
C121 Au1 Ag2 C211 58.6(6) .
Ag1 Au1 Ag2 C211 -147.4(4) .
Ag3 Au1 Ag2 C211 72.9(4) .
C111 Au1 Ag2 C311 97.6(6) .
C121 Au1 Ag2 C311 -89.2(6) .
Ag1 Au1 Ag2 C311 64.9(4) .
Ag3 Au1 Ag2 C311 -74.9(4) .
C121 Au1 Ag2 C111 173.3(6) .
Ag1 Au1 Ag2 C111 -32.7(4) .
Ag3 Au1 Ag2 C111 -172.5(4) .
C111 Au1 Ag2 Au2 -149.1(4) .
C121 Au1 Ag2 Au2 24.2(5) .
Ag1 Au1 Ag2 Au2 178.22(3) .
Ag3 Au1 Ag2 Au2 38.44(2) .
C111 Au1 Ag2 Au3 124.8(4) .
C121 Au1 Ag2 Au3 -61.9(5) .
Ag1 Au1 Ag2 Au3 92.14(3) .
Ag3 Au1 Ag2 Au3 -47.63(2) .
C221 Au2 Ag2 C211 174.5(7) .
Ag3 Au2 Ag2 C211 -169.2(5) .
Ag1 Au2 Ag2 C211 46.9(5) 1_545
C211 Au2 Ag2 C311 -119.8(6) .
C221 Au2 Ag2 C311 54.6(6) .
Ag3 Au2 Ag2 C311 71.0(4) .
Ag1 Au2 Ag2 C311 -72.9(4) 1_545
C211 Au2 Ag2 C111 104.4(6) .
C221 Au2 Ag2 C111 -81.1(6) .
Ag3 Au2 Ag2 C111 -64.8(3) .
Ag1 Au2 Ag2 C111 151.3(3) 1_545
C211 Au2 Ag2 Au1 128.1(5) .
C221 Au2 Ag2 Au1 -57.4(4) .
Ag3 Au2 Ag2 Au1 -41.06(3) .
Ag1 Au2 Ag2 Au1 174.99(3) 1_545
C211 Au2 Ag2 Au3 -151.5(5) .
C221 Au2 Ag2 Au3 22.9(4) .
Ag3 Au2 Ag2 Au3 39.27(2) .
Ag1 Au2 Ag2 Au3 -104.68(3) 1_545
C321 Au3 Ag2 C211 -70.3(5) .
C311 Au3 Ag2 C211 111.4(6) .
Ag3 Au3 Ag2 C211 -59.6(4) .
C321 Au3 Ag2 C311 178.2(6) .
Ag3 Au3 Ag2 C311 -171.0(5) .
C321 Au3 Ag2 C111 72.5(5) .
C311 Au3 Ag2 C111 -105.8(5) .
Ag3 Au3 Ag2 C111 83.2(3) .
C321 Au3 Ag2 Au1 37.7(4) .
C311 Au3 Ag2 Au1 -140.5(5) .
Ag3 Au3 Ag2 Au1 48.46(2) .
C321 Au3 Ag2 Au2 -48.1(4) .
C311 Au3 Ag2 Au2 133.6(5) .
Ag3 Au3 Ag2 Au2 -37.38(2) .
C211 Au2 Ag3 C321 -72.3(6) .
C221 Au2 Ag3 C321 104.3(5) .
Ag2 Au2 Ag3 C321 -61.0(3) .
Ag1 Au2 Ag3 C321 80.2(3) 1_545
C211 Au2 Ag3 C221 -176.6(6) .
Ag2 Au2 Ag3 C221 -165.3(4) .
Ag1 Au2 Ag3 C221 -24.1(4) 1_545
C211 Au2 Ag3 C121 62.6(6) .
C221 Au2 Ag3 C121 -120.8(5) .
Ag2 Au2 Ag3 C121 73.9(4) .
Ag1 Au2 Ag3 C121 -144.9(4) 1_545
C211 Au2 Ag3 C322 -96.9(6) .
C221 Au2 Ag3 C322 79.7(6) .
Ag2 Au2 Ag3 C322 -85.6(4) .
Ag1 Au2 Ag3 C322 55.5(4) 1_545
C211 Au2 Ag3 Au3 -50.4(5) .
C221 Au2 Ag3 Au3 126.2(4) .
Ag2 Au2 Ag3 Au3 -39.13(2) .
Ag1 Au2 Ag3 Au3 102.04(4) 1_545
C211 Au2 Ag3 Au1 28.1(5) .
C221 Au2 Ag3 Au1 -155.3(4) .
Ag2 Au2 Ag3 Au1 39.43(2) .
Ag1 Au2 Ag3 Au1 -179.39(3) 1_545
C311 Au3 Ag3 C321 -178.1(6) .
Ag2 Au3 Ag3 C321 -169.1(4) .
C321 Au3 Ag3 C221 -114.6(5) .
C311 Au3 Ag3 C221 67.3(6) .
Ag2 Au3 Ag3 C221 76.4(3) .
C321 Au3 Ag3 C121 99.2(5) .
C311 Au3 Ag3 C121 -78.9(6) .
Ag2 Au3 Ag3 C121 -69.9(3) .
C321 Au3 Ag3 C322 1.0(5) .
C311 Au3 Ag3 C322 -177.1(5) .
Ag2 Au3 Ag3 C322 -168.1(2) .
C321 Au3 Ag3 Au2 -151.9(4) .
C311 Au3 Ag3 Au2 30.0(5) .
Ag2 Au3 Ag3 Au2 39.05(2) .
C321 Au3 Ag3 Au1 122.3(4) .
C311 Au3 Ag3 Au1 -55.8(5) .
Ag2 Au3 Ag3 Au1 -46.72(2) .
C111 Au1 Ag3 C321 74.5(5) .
C121 Au1 Ag3 C321 -111.7(5) .
Ag2 Au1 Ag3 C321 82.7(3) .
Ag1 Au1 Ag3 C321 -47.7(3) .
C111 Au1 Ag3 C221 -69.2(6) .
C121 Au1 Ag3 C221 104.6(5) .
Ag2 Au1 Ag3 C221 -61.1(3) .
Ag1 Au1 Ag3 C221 168.6(3) .
C111 Au1 Ag3 C121 -173.8(7) .
Ag2 Au1 Ag3 C121 -165.6(5) .
Ag1 Au1 Ag3 C121 64.0(5) .
C111 Au1 Ag3 C322 100.0(5) .
C121 Au1 Ag3 C322 -86.2(5) .
Ag2 Au1 Ag3 C322 108.2(3) .
Ag1 Au1 Ag3 C322 -22.2(3) .
C111 Au1 Ag3 Au2 -48.4(4) .
C121 Au1 Ag3 Au2 125.3(5) .
Ag2 Au1 Ag3 Au2 -40.27(2) .
Ag1 Au1 Ag3 Au2 -170.63(3) .
C111 Au1 Ag3 Au3 39.8(4) .
C121 Au1 Ag3 Au3 -146.5(5) .
Ag2 Au1 Ag3 Au3 47.92(2) .
Ag1 Au1 Ag3 Au3 -82.44(4) .
C121 Au1 C111 C112 26(16) .
Ag2 Au1 C111 C112 138(14) .
Ag1 Au1 C111 C112 -69(13) .
Ag3 Au1 C111 C112 148(13) .
C121 Au1 C111 Ag2 -112(5) .
Ag1 Au1 C111 Ag2 153.3(3) .
Ag3 Au1 C111 Ag2 9.9(5) .
C211 Ag2 C111 C112 -90.8(9) .
C311 Ag2 C111 C112 82.7(9) .
Au1 Ag2 C111 C112 -177.2(10) .
Au2 Ag2 C111 C112 -140.6(7) .
Au3 Ag2 C111 C112 126.2(8) .
C211 Ag2 C111 Au1 86.4(6) .
C311 Ag2 C111 Au1 -100.1(6) .
Au2 Ag2 C111 Au1 36.6(4) .
Au3 Ag2 C111 Au1 -56.6(3) .
Au1 C111 C112 C113 65(26) .
Ag2 C111 C112 C113 -157(18) .
C111 C112 C113 C118 93(18) .
C111 C112 C113 C114 -91(18) .
C114 C113 C118 C117 1(2) .
C112 C113 C118 C117 176.4(13) .
C113 C118 C117 C116 2(3) .
C118 C117 C116 C115 -2(2) .
C117 C116 C115 C114 0(2) .
C116 C115 C114 C113 3(2) .
C118 C113 C114 C115 -3.5(19) .
C112 C113 C114 C115 -179.1(11) .
C111 Au1 C121 C122 27(8) .
Ag2 Au1 C121 C122 -81(4) .
Ag1 Au1 C121 C122 120(4) .
Ag3 Au1 C121 C122 -99(4) .
C111 Au1 C121 Ag3 126(4) .
Ag2 Au1 C121 Ag3 18.0(6) .
Ag1 Au1 C121 Ag3 -140.6(2) .
C321 Ag3 C121 C122 -111.3(8) .
C221 Ag3 C121 C122 62.2(10) .
C322 Ag3 C121 C122 -83.6(8) .
Au2 Ag3 C121 C122 108.7(8) .
Au3 Ag3 C121 C122 -156.4(7) .
Au1 Ag3 C121 C122 167.7(11) .
C321 Ag3 C121 Au1 81.0(5) .
C221 Ag3 C121 Au1 -105.5(5) .
C322 Ag3 C121 Au1 108.7(4) .
Au2 Ag3 C121 Au1 -59.0(4) .
Au3 Ag3 C121 Au1 35.9(4) .
Au1 C121 C122 C123 -47(15) .
Ag3 C121 C122 C123 -146(13) .
C121 C122 C123 C128 123(13) .
C121 C122 C123 C124 -54(13) .
C124 C123 C128 C127 -0.4(19) .
C122 C123 C128 C127 -177.0(12) .
C123 C128 C127 C126 -2(2) .
C128 C127 C126 C125 2(2) .
C127 C126 C125 C124 -1(3) .
C128 C123 C124 C125 2(2) .
C122 C123 C124 C125 178.5(14) .
C126 C125 C124 C123 -1(3) .
C211 Au2 C221 C222 -9(6) .
Ag3 Au2 C221 C222 -164(3) .
Ag2 Au2 C221 C222 -144(3) .
Ag1 Au2 C221 C222 -1(3) 1_545
C211 Au2 C221 Ag3 156(4) .
Ag2 Au2 C221 Ag3 20.1(5) .
Ag1 Au2 C221 Ag3 163.0(3) 1_545
C321 Ag3 C221 C222 68.5(10) .
C121 Ag3 C221 C222 -104.5(10) .
C322 Ag3 C221 C222 36.5(10) .
Au2 Ag3 C221 C222 174.5(11) .
Au3 Ag3 C221 C222 114.0(9) .
Au1 Ag3 C221 C222 -155.0(8) .
C321 Ag3 C221 Au2 -106.0(5) .
C121 Ag3 C221 Au2 81.1(6) .
C322 Ag3 C221 Au2 -138.0(3) .
Au3 Ag3 C221 Au2 -60.5(3) .
Au1 Ag3 C221 Au2 30.5(4) .
Au2 C221 C222 C223 -4(11) .
Ag3 C221 C222 C223 -166(8) .
C221 C222 C223 C228 -174(8) .
C221 C222 C223 C224 7(9) .
C228 C223 C224 C225 1.2(16) .
C222 C223 C224 C225 179.6(10) .
C223 C224 C225 C226 -0.6(17) .
C224 C225 C226 C227 1.9(18) .
C225 C226 C227 C228 -3.5(18) .
C224 C223 C228 C227 -2.9(17) .
C222 C223 C228 C227 178.8(11) .
C226 C227 C228 C223 4.0(18) .
C321 Au3 C311 C312 115(42) .
Ag2 Au3 C311 C312 -176(100) .
Ag3 Au3 C311 C312 -165(43) .
C321 Au3 C311 Ag2 -69(21) .
Ag3 Au3 C311 Ag2 11.3(6) .
C211 Ag2 C311 C312 81.1(11) .
C111 Ag2 C311 C312 -91.9(9) .
Au1 Ag2 C311 C312 -137.6(8) .
Au2 Ag2 C311 C312 128.1(8) .
Au3 Ag2 C311 C312 179.9(11) .
C211 Ag2 C311 Au3 -98.8(6) .
C111 Ag2 C311 Au3 88.2(5) .
Au1 Ag2 C311 Au3 42.5(5) .
Au2 Ag2 C311 Au3 -51.8(4) .
Au3 C311 C312 C313 -38(59) .
Ag2 C311 C312 C313 146(21) .
C311 C312 C313 C314 7(22) .
C311 C312 C313 C318 -176(21) .
C318 C313 C314 C315 2(2) .
C312 C313 C314 C315 178.3(12) .
C313 C314 C315 C316 1(2) .
C314 C315 C316 C317 -2(3) .
C315 C316 C317 C318 -1(3) .
C316 C317 C318 C313 4(3) .
C314 C313 C318 C317 -4(2) .
C312 C313 C318 C317 179.0(15) .
C221 Au2 C211 C212 19(13) .
Ag3 Au2 C211 C212 172(9) .
Ag2 Au2 C211 C212 158(10) .
Ag1 Au2 C211 C212 11(9) 1_545
C221 Au2 C211 Ag2 -139(4) .
Ag3 Au2 C211 Ag2 14.3(6) .
Ag1 Au2 C211 Ag2 -146.6(3) 1_545
C311 Ag2 C211 C212 -92.5(11) .
C111 Ag2 C211 C212 79.9(10) .
Au1 Ag2 C211 C212 125.7(8) .
Au2 Ag2 C211 C212 -177.5(11) .
Au3 Ag2 C211 C212 -143.5(7) .
C311 Ag2 C211 Au2 85.0(7) .
C111 Ag2 C211 Au2 -102.6(5) .
Au1 Ag2 C211 Au2 -56.8(4) .
Au3 Ag2 C211 Au2 34.0(5) .
Au2 C211 C212 C213 -158(21) .
Ag2 C211 C212 C213 0(28) .
C211 C212 C213 C218 -51(28) .
C211 C212 C213 C214 131(27) .
C214 C213 C218 C217 -4.0(18) .
C212 C213 C218 C217 177.9(11) .
C213 C218 C217 C216 1(2) .
C218 C217 C216 C215 2(2) .
C217 C216 C215 C214 -2(2) .
C216 C215 C214 C213 -1(2) .
C218 C213 C214 C215 4(2) .
C212 C213 C214 C215 -178.4(13) .
C311 Au3 C321 C322 -21(43) .
Ag2 Au3 C321 C322 -89(28) .
Ag3 Au3 C321 C322 -103(28) .
C311 Au3 C321 Ag3 81(21) .
Ag2 Au3 C321 Ag3 13.6(5) .
C221 Ag3 C321 C322 -94.7(8) .
C121 Ag3 C321 C322 79.0(8) .
Au2 Ag3 C321 C322 -147.7(6) .
Au3 Ag3 C321 C322 178.0(9) .
Au1 Ag3 C321 C322 120.5(7) .
C221 Ag3 C321 Au3 87.3(5) .
C121 Ag3 C321 Au3 -99.0(5) .
C322 Ag3 C321 Au3 -178.0(9) .
Au2 Ag3 C321 Au3 34.2(4) .
Au1 Ag3 C321 Au3 -57.6(3) .
Au3 C321 C322 C323 -79(40) .
Ag3 C321 C322 C323 178(100) .
Au3 C321 C322 Ag3 102(28) .
C221 Ag3 C322 C321 102.4(8) .
C121 Ag3 C322 C321 -110.2(8) .
Au2 Ag3 C322 C321 49.7(9) .
Au3 Ag3 C322 C321 -1.4(7) .
Au1 Ag3 C322 C321 -67.3(7) .
C321 Ag3 C322 C323 -179.9(13) .
C221 Ag3 C322 C323 -77.5(9) .
C121 Ag3 C322 C323 69.9(9) .
Au2 Ag3 C322 C323 -130.2(7) .
Au3 Ag3 C322 C323 178.7(9) .
Au1 Ag3 C322 C323 112.8(8) .
C321 C322 C323 C328 11(24) .
Ag3 C322 C323 C328 -171.3(8) .
C321 C322 C323 C324 -170(23) .
Ag3 C322 C323 C324 7.7(14) .
C328 C323 C324 C325 -1.6(17) .
C322 C323 C324 C325 179.4(11) .
C323 C324 C325 C326 2(2) .
C324 C325 C326 C327 -2(2) .
C325 C326 C327 C328 1(2) .
C324 C323 C328 C327 0.4(17) .
C322 C323 C328 C327 179.4(11) .
C326 C327 C328 C323 0(2) .
