#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:58:11 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178675 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/86/4078668.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4078668
loop_
_publ_author_name
'Mobarok, Md Hosnay'
'Ferguson, Michael J.'
'Cowie, Martin'
_publ_section_title
;
 Multiple Si--H Bond Activations in a Bis(diethylphosphino)methane-Bridged
 Complex of Rhodium and Iridium: Synthesis of an Unusual
 Bis(silyl)/μ-Silylene Complex
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              4722
_journal_paper_doi               10.1021/om300283k
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C49 H54 Ir O4 P2 Rh Si3'
_chemical_formula_sum            'C49 H54 Ir O4 P2 Rh Si3'
_chemical_formula_weight         1148.24
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.8670(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.6418(9)
_cell_length_b                   10.9486(5)
_cell_length_c                   20.9305(9)
_cell_measurement_reflns_used    9383
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      2.70
_cell_volume                     4724.3(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0115
_diffrn_reflns_av_sigmaI/netI    0.0097
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            20792
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    3.350
_exptl_absorpt_correction_T_max  0.6096
_exptl_absorpt_correction_T_min  0.3091
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.614
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2296
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.771
_refine_diff_density_min         -0.475
_refine_diff_density_rms         0.056
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         5423
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0197
_refine_ls_R_factor_gt           0.0171
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0187P)²+8.3340P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0415
_refine_ls_wR_factor_ref         0.0434
_reflns_number_gt                4895
_reflns_number_total             5423
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om300283k_si_002.cif
_cod_data_source_block           cow1126
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      I2/a
_cod_database_code               4078668
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ir Ir 0.21183(5) -0.00034(3) 0.05538(6) 0.01896(9) Uani 0.50 1 d P A -1
Rh Rh 0.29584(11) -0.00298(8) -0.05144(12) 0.01896(9) Uani 0.50 1 d P . -1
P1 P 0.2005(2) 0.21564(12) 0.04309(16) 0.0227(5) Uani 0.50 1 d PD A -1
P2 P 0.3042(2) 0.21159(12) -0.05856(16) 0.0227(5) Uani 0.50 1 d PD A -1
Si1 Si 0.16257(2) -0.05983(5) 0.15281(2) 0.02924(11) Uani 1 1 d . . .
H1 H 0.2110(11) -0.063(2) 0.2037(10) 0.037(6) Uiso 1 1 d . . .
Si2 Si 0.2500 -0.17624(6) 0.0000 0.02538(14) Uani 1 2 d S . .
O1 O 0.3414(13) 0.0201(12) 0.1363(8) 0.043(2) Uani 0.50 1 d P A -1
O2 O 0.0826(7) -0.073(3) -0.0138(6) 0.038(3) Uani 0.50 1 d P A -1
O3 O 0.1701(13) 0.0125(12) -0.1346(8) 0.043(2) Uani 0.50 1 d P B -1
O4 O 0.4208(7) -0.053(3) 0.0163(6) 0.038(3) Uani 0.50 1 d P C -1
C1 C 0.2902(6) 0.019(3) 0.1046(3) 0.026(3) Uani 0.50 1 d P A -1
C2 C 0.1307(8) -0.0405(12) 0.0120(11) 0.0288(8) Uani 0.50 1 d P A -1
C3 C 0.2136(6) -0.004(3) -0.1045(3) 0.026(3) Uani 0.50 1 d P B -1
C4 C 0.3721(9) -0.0385(12) -0.0101(11) 0.0288(8) Uani 0.50 1 d P C -1
C5 C 0.27338(16) 0.2842(3) 0.01273(16) 0.0263(7) Uani 0.50 1 d PD A -1
H5A H 0.3080 0.2822 0.0472 0.032 Uiso 0.50 1 calc PR A -1
H5B H 0.2642 0.3711 0.0027 0.032 Uiso 0.50 1 calc PR A -1
C6 C 0.13489(18) 0.2651(4) -0.01386(19) 0.0336(8) Uani 0.50 1 d P A -1
H6A H 0.1440 0.3493 -0.0281 0.040 Uiso 0.50 1 calc PR A -1
H6B H 0.1345 0.2114 -0.0520 0.040 Uiso 0.50 1 calc PR A -1
C7 C 0.0666(8) 0.2621(18) 0.0146(8) 0.039(3) Uani 0.50 1 d P A -1
H7A H 0.0339 0.2890 -0.0179 0.047 Uiso 0.50 1 calc PR A -1
H7B H 0.0662 0.3168 0.0517 0.047 Uiso 0.50 1 calc PR A -1
H7C H 0.0568 0.1787 0.0281 0.047 Uiso 0.50 1 calc PR A -1
C8 C 0.1865(2) 0.3117(3) 0.11257(19) 0.0335(8) Uani 0.50 1 d P A -1
H8A H 0.1822 0.3976 0.0983 0.040 Uiso 0.50 1 calc PR A -1
H8B H 0.1450 0.2874 0.1306 0.040 Uiso 0.50 1 calc PR A -1
C9 C 0.2402(2) 0.3039(5) 0.1652(2) 0.0449(11) Uani 0.50 1 d P A -1
H9A H 0.2335 0.3670 0.1974 0.054 Uiso 0.50 1 calc PR A -1
H9B H 0.2824 0.3165 0.1467 0.054 Uiso 0.50 1 calc PR A -1
H9C H 0.2394 0.2231 0.1854 0.054 Uiso 0.50 1 calc PR A -1
C10 C 0.38403(18) 0.2818(3) -0.06389(19) 0.0310(8) Uani 0.50 1 d P A -1
H10A H 0.4008 0.2623 -0.1062 0.037 Uiso 0.50 1 calc PR A -1
H10B H 0.3792 0.3716 -0.0613 0.037 Uiso 0.50 1 calc PR A -1
C11 C 0.4341(8) 0.2401(17) -0.0114(9) 0.043(4) Uani 0.50 1 d P A -1
H11A H 0.4771 0.2709 -0.0211 0.051 Uiso 0.50 1 calc PR A -1
H11B H 0.4350 0.1507 -0.0097 0.051 Uiso 0.50 1 calc PR A -1
H11C H 0.4219 0.2723 0.0300 0.051 Uiso 0.50 1 calc PR A -1
C12 C 0.2597(2) 0.2853(4) -0.1266(2) 0.0341(8) Uani 0.50 1 d P A -1
H12A H 0.2809 0.2623 -0.1662 0.041 Uiso 0.50 1 calc PR A -1
H12B H 0.2152 0.2514 -0.1297 0.041 Uiso 0.50 1 calc PR A -1
C13 C 0.2546(2) 0.4244(4) -0.1245(2) 0.0408(9) Uani 0.50 1 d P A -1
H13A H 0.2345 0.4541 -0.1649 0.049 Uiso 0.50 1 calc PR A -1
H13B H 0.2981 0.4596 -0.1181 0.049 Uiso 0.50 1 calc PR A -1
H13C H 0.2281 0.4486 -0.0891 0.049 Uiso 0.50 1 calc PR A -1
C21 C 0.12662(9) -0.21784(18) 0.15697(9) 0.0311(4) Uani 1 1 d . A .
C22 C 0.15380(11) -0.3045(2) 0.19977(10) 0.0391(5) Uani 1 1 d . . .
H22 H 0.1911 -0.2832 0.2258 0.047 Uiso 1 1 calc R A .
C23 C 0.12740(12) -0.4210(2) 0.20515(11) 0.0466(5) Uani 1 1 d . A .
H23 H 0.1465 -0.4778 0.2348 0.056 Uiso 1 1 calc R . .
C24 C 0.07376(13) -0.4534(2) 0.16763(12) 0.0470(5) Uani 1 1 d . . .
H24 H 0.0559 -0.5330 0.1710 0.056 Uiso 1 1 calc R A .
C25 C 0.04593(12) -0.3706(2) 0.12521(12) 0.0477(5) Uani 1 1 d . A .
H25 H 0.0087 -0.3929 0.0994 0.057 Uiso 1 1 calc R . .
C26 C 0.07204(11) -0.2548(2) 0.12000(11) 0.0419(5) Uani 1 1 d . . .
H26 H 0.0522 -0.1988 0.0904 0.050 Uiso 1 1 calc R A .
C31 C 0.10008(10) 0.05147(19) 0.18111(9) 0.0343(4) Uani 1 1 d . A .
C32 C 0.11618(12) 0.1299(2) 0.23162(10) 0.0419(5) Uani 1 1 d . . .
H32 H 0.1579 0.1239 0.2527 0.050 Uiso 1 1 calc R A .
C33 C 0.07266(14) 0.2171(2) 0.25208(12) 0.0520(6) Uani 1 1 d . A .
H33 H 0.0851 0.2702 0.2864 0.062 Uiso 1 1 calc R . .
C34 C 0.01180(13) 0.2267(2) 0.22275(13) 0.0521(6) Uani 1 1 d . . .
H34 H -0.0179 0.2862 0.2367 0.062 Uiso 1 1 calc R A .
C35 C -0.00577(12) 0.1495(2) 0.17309(13) 0.0541(6) Uani 1 1 d . A .
H35 H -0.0478 0.1553 0.1527 0.065 Uiso 1 1 calc R . .
C36 C 0.03778(11) 0.0630(2) 0.15255(12) 0.0463(5) Uani 1 1 d . . .
H36 H 0.0249 0.0103 0.1182 0.056 Uiso 1 1 calc R A .
C41 C 0.30699(9) -0.28169(16) 0.04685(9) 0.0312(4) Uani 1 1 d . A .
C42 C 0.35062(11) -0.35430(19) 0.01456(10) 0.0388(5) Uani 1 1 d . . .
H42 H 0.3499 -0.3524 -0.0308 0.047 Uiso 1 1 calc R A .
C43 C 0.39501(12) -0.4292(2) 0.04780(12) 0.0499(6) Uani 1 1 d . A .
H43 H 0.4254 -0.4752 0.0251 0.060 Uiso 1 1 calc R . .
C44 C 0.39518(16) -0.4368(3) 0.11331(13) 0.0691(9) Uani 1 1 d . . .
H44 H 0.4243 -0.4909 0.1356 0.083 Uiso 1 1 calc R A .
C45 C 0.35323(16) -0.3661(3) 0.14671(13) 0.0728(10) Uani 1 1 d . A .
H45 H 0.3537 -0.3705 0.1921 0.087 Uiso 1 1 calc R . .
C46 C 0.31029(13) -0.2884(2) 0.11371(11) 0.0516(6) Uani 1 1 d . . .
H46 H 0.2824 -0.2383 0.1372 0.062 Uiso 1 1 calc R A .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ir Ir -1.4442 7.9887 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ir C2 171.9(9) . .
C1 Ir P1 91.6(9) . .
C2 Ir P1 95.6(4) . .
C1 Ir Si2 93.4(9) . .
C2 Ir Si2 83.5(5) . .
P1 Ir Si2 140.79(9) . .
C1 Ir Si1 87.4(2) . .
C2 Ir Si1 86.8(6) . .
P1 Ir Si1 108.35(8) . .
Si2 Ir Si1 110.72(3) . .
C1 Ir Rh 83.8(3) . .
C2 Ir Rh 100.1(6) . .
P1 Ir Rh 89.20(8) . .
Si2 Ir Rh 52.84(3) . .
Si1 Ir Rh 160.58(3) . .
C4 Rh C3 166.5(9) . .
C4 Rh P2 100.4(4) . .
C3 Rh P2 91.8(8) . .
C4 Rh Si2 88.2(5) . .
C3 Rh Si2 84.4(8) . .
P2 Rh Si2 147.86(13) . .
C4 Rh Si1 91.5(7) . 2
C3 Rh Si1 80.7(2) . 2
P2 Rh Si1 99.86(11) . 2
Si2 Rh Si1 110.90(5) . 2
C4 Rh Ir 100.0(7) . .
C3 Rh Ir 84.5(3) . .
P2 Rh Ir 94.99(10) . .
Si2 Rh Ir 52.90(5) . .
Si1 Rh Ir 159.27(7) 2 .
C5 P1 C8 101.9(2) . .
C5 P1 C6 104.3(2) . .
C8 P1 C6 101.9(2) . .
C5 P1 Ir 111.52(19) . .
C8 P1 Ir 120.13(18) . .
C6 P1 Ir 115.2(2) . .
C10 P2 C5 102.6(2) . .
C10 P2 C12 100.7(2) . .
C5 P2 C12 105.0(2) . .
C10 P2 Rh 119.4(2) . .
C5 P2 Rh 110.56(17) . .
C12 P2 Rh 116.7(2) . .
C21 Si1 C31 107.49(9) . .
C21 Si1 Ir 118.03(6) . .
C31 Si1 Ir 114.44(6) . .
C41 Si2 C41 104.58(12) 2 .
C41 Si2 Rh 120.00(8) 2 .
C41 Si2 Rh 117.85(7) . .
C41 Si2 Ir 122.03(6) 2 .
C41 Si2 Ir 116.80(6) . .
Rh Si2 Ir 74.26(3) . .
O1 C1 Ir 174(2) . .
O2 C2 Ir 175.4(18) . .
O3 C3 Rh 170(3) . .
O4 C4 Rh 176(2) . .
P1 C5 P2 115.5(2) . .
C7 C6 P1 113.3(7) . .
C9 C8 P1 113.8(3) . .
C11 C10 P2 114.0(7) . .
C13 C12 P2 116.6(3) . .
C26 C21 C22 116.39(19) . .
C26 C21 Si1 123.32(15) . .
C22 C21 Si1 120.28(16) . .
C23 C22 C21 121.7(2) . .
C24 C23 C22 119.9(2) . .
C23 C24 C25 119.9(2) . .
C24 C25 C26 120.2(2) . .
C25 C26 C21 121.9(2) . .
C32 C31 C36 116.8(2) . .
C32 C31 Si1 119.70(17) . .
C36 C31 Si1 123.50(16) . .
C31 C32 C33 121.6(2) . .
C34 C33 C32 120.3(2) . .
C35 C34 C33 119.5(2) . .
C34 C35 C36 120.2(2) . .
C35 C36 C31 121.7(2) . .
C46 C41 C42 116.92(18) . .
C46 C41 Si2 123.31(15) . .
C42 C41 Si2 119.72(15) . .
C43 C42 C41 121.1(2) . .
C44 C43 C42 120.3(2) . .
C43 C44 C45 120.1(2) . .
C44 C45 C46 119.6(2) . .
C45 C46 C41 121.8(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ir C1 1.885(8) .
Ir C2 1.92(2) .
Ir P1 2.3889(14) .
Ir Si2 2.4009(10) .
Ir Si1 2.4134(13) .
Ir Rh 2.8973(14) .
Rh C4 1.80(2) .
Rh C3 1.981(11) .
Rh P2 2.3608(17) .
Rh Si2 2.3989(19) .
Rh Si1 2.410(3) 2
P1 C5 1.824(4) .
P1 C8 1.829(5) .
P1 C6 1.840(6) .
P2 C10 1.827(5) .
P2 C5 1.832(4) .
P2 C12 1.841(6) .
Si1 C21 1.886(2) .
Si1 C31 1.891(2) .
Si1 Rh 2.410(3) 2
Si2 C41 1.8876(19) 2
Si2 C41 1.8876(19) .
O1 C1 1.22(3) .
O2 C2 1.16(3) .
O3 C3 1.09(3) .
O4 C4 1.13(3) .
C6 C7 1.558(16) .
C8 C9 1.526(6) .
C10 C11 1.539(19) .
C12 C13 1.527(6) .
C21 C26 1.394(3) .
C21 C22 1.402(3) .
C22 C23 1.394(3) .
C23 C24 1.372(4) .
C24 C25 1.375(3) .
C25 C26 1.384(3) .
C31 C32 1.389(3) .
C31 C36 1.396(3) .
C32 C33 1.393(3) .
C33 C34 1.374(4) .
C34 C35 1.374(4) .
C35 C36 1.389(3) .
C41 C46 1.400(3) .
C41 C42 1.400(3) .
C42 C43 1.390(3) .
C43 C44 1.373(4) .
C44 C45 1.378(4) .
C45 C46 1.388(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ir Rh C4 19.0(10) . .
C2 Ir Rh C4 -153.86(16) . .
P1 Ir Rh C4 110.6(4) . .
Si2 Ir Rh C4 -80.0(4) . .
Si1 Ir Rh C4 -44.6(4) . .
C1 Ir Rh C3 -173.90(16) . .
C2 Ir Rh C3 13.3(9) . .
P1 Ir Rh C3 -82.2(8) . .
Si2 Ir Rh C3 87.1(8) . .
Si1 Ir Rh C3 122.6(8) . .
C1 Ir Rh P2 -82.6(9) . .
C2 Ir Rh P2 104.6(4) . .
P1 Ir Rh P2 9.10(4) . .
Si2 Ir Rh P2 178.49(15) . .
Si1 Ir Rh P2 -146.09(13) . .
C1 Ir Rh Si2 99.0(9) . .
C2 Ir Rh Si2 -73.9(4) . .
P1 Ir Rh Si2 -169.39(12) . .
Si1 Ir Rh Si2 35.42(9) . .
C1 Ir Rh Si1 141.7(10) . 2
C2 Ir Rh Si1 -31.1(4) . 2
P1 Ir Rh Si1 -126.64(19) . 2
Si2 Ir Rh Si1 42.75(11) . 2
Si1 Ir Rh Si1 78.17(16) . 2
C1 Ir P1 C5 52.6(4) . .
C2 Ir P1 C5 -131.2(6) . .
Si2 Ir P1 C5 -44.6(3) . .
Si1 Ir P1 C5 140.34(19) . .
Rh Ir P1 C5 -31.2(2) . .
C1 Ir P1 C8 -66.4(4) . .
C2 Ir P1 C8 109.8(7) . .
Si2 Ir P1 C8 -163.62(18) . .
Si1 Ir P1 C8 21.4(3) . .
Rh Ir P1 C8 -150.2(3) . .
C1 Ir P1 C6 171.2(3) . .
C2 Ir P1 C6 -12.7(6) . .
Si2 Ir P1 C6 73.9(3) . .
Si1 Ir P1 C6 -101.1(2) . .
Rh Ir P1 C6 87.4(2) . .
C4 Rh P2 C10 30.5(7) . .
C3 Rh P2 C10 -143.8(3) . .
Si2 Rh P2 C10 133.9(2) . .
Si1 Rh P2 C10 -62.9(2) 2 .
Ir Rh P2 C10 131.7(2) . .
C4 Rh P2 C5 -88.1(7) . .
C3 Rh P2 C5 97.7(3) . .
Si2 Rh P2 C5 15.3(4) . .
Si1 Rh P2 C5 178.5(2) 2 .
Ir Rh P2 C5 13.1(2) . .
C4 Rh P2 C12 151.9(7) . .
C3 Rh P2 C12 -22.3(3) . .
Si2 Rh P2 C12 -104.6(3) . .
Si1 Rh P2 C12 58.6(2) 2 .
Ir Rh P2 C12 -106.9(2) . .
C1 Ir Si1 C21 -118.9(10) . .
C2 Ir Si1 C21 55.6(4) . .
P1 Ir Si1 C21 150.37(14) . .
Si2 Ir Si1 C21 -26.27(8) . .
Rh Ir Si1 C21 -55.86(10) . .
C1 Ir Si1 C31 113.1(10) . .
C2 Ir Si1 C31 -72.5(4) . .
P1 Ir Si1 C31 22.36(14) . .
Si2 Ir Si1 C31 -154.28(8) . .
Rh Ir Si1 C31 176.13(9) . .
C4 Rh Si2 C41 -137.7(6) . 2
C3 Rh Si2 C41 31.0(4) . 2
P2 Rh Si2 C41 115.4(3) . 2
Si1 Rh Si2 C41 -46.83(11) 2 2
Ir Rh Si2 C41 118.27(7) . 2
C4 Rh Si2 C41 -8.4(6) . .
C3 Rh Si2 C41 160.3(4) . .
P2 Rh Si2 C41 -115.2(3) . .
Si1 Rh Si2 C41 82.52(11) 2 .
Ir Rh Si2 C41 -112.39(8) . .
C4 Rh Si2 Ir 104.0(6) . .
C3 Rh Si2 Ir -87.3(4) . .
P2 Rh Si2 Ir -2.8(3) . .
Si1 Rh Si2 Ir -165.09(6) 2 .
C1 Ir Si2 C41 164.5(4) . 2
C2 Ir Si2 C41 -8.0(5) . 2
P1 Ir Si2 C41 -98.95(19) . 2
Si1 Ir Si2 C41 76.01(8) . 2
Rh Ir Si2 C41 -115.88(9) . 2
C1 Ir Si2 C41 34.0(5) . .
C2 Ir Si2 C41 -138.5(5) . .
P1 Ir Si2 C41 130.60(19) . .
Si1 Ir Si2 C41 -54.44(8) . .
Rh Ir Si2 C41 113.67(8) . .
C1 Ir Si2 Rh -79.7(4) . .
C2 Ir Si2 Rh 107.8(5) . .
P1 Ir Si2 Rh 16.9(2) . .
Si1 Ir Si2 Rh -168.11(2) . .
C2 Ir C1 O1 35(13) . .
P1 Ir C1 O1 -173(10) . .
Si2 Ir C1 O1 -32(10) . .
Si1 Ir C1 O1 78(10) . .
Rh Ir C1 O1 -84(10) . .
C1 Ir C2 O2 -31(25) . .
P1 Ir C2 O2 177(100) . .
Si2 Ir C2 O2 36(21) . .
Si1 Ir C2 O2 -75(21) . .
Rh Ir C2 O2 87(21) . .
C4 Rh C3 O3 -149(7) . .
P2 Rh C3 O3 6(6) . .
Si2 Rh C3 O3 154(6) . .
Si1 Rh C3 O3 -94(6) 2 .
Ir Rh C3 O3 101(6) . .
C3 Rh C4 O4 160(20) . .
P2 Rh C4 O4 5(22) . .
Si2 Rh C4 O4 -144(22) . .
Si1 Rh C4 O4 106(22) 2 .
Ir Rh C4 O4 -92(22) . .
C8 P1 C5 P2 179.7(2) . .
C6 P1 C5 P2 -74.6(3) . .
Ir P1 C5 P2 50.3(4) . .
C10 P2 C5 P1 -168.4(2) . .
C12 P2 C5 P1 86.7(3) . .
Rh P2 C5 P1 -40.1(4) . .
C5 P1 C6 C7 -157.5(8) . .
C8 P1 C6 C7 -51.8(8) . .
Ir P1 C6 C7 80.0(8) . .
C5 P1 C8 C9 -64.1(4) . .
C6 P1 C8 C9 -171.7(3) . .
Ir P1 C8 C9 59.6(4) . .
C5 P2 C10 C11 70.8(8) . .
C12 P2 C10 C11 179.0(8) . .
Rh P2 C10 C11 -51.8(8) . .
C10 P2 C12 C13 -60.2(4) . .
C5 P2 C12 C13 46.1(4) . .
Rh P2 C12 C13 169.0(3) . .
C31 Si1 C21 C26 64.03(19) . .
Ir Si1 C21 C26 -67.20(18) . .
C31 Si1 C21 C22 -114.50(16) . .
Ir Si1 C21 C22 114.27(15) . .
C26 C21 C22 C23 -0.3(3) . .
Si1 C21 C22 C23 178.36(16) . .
C21 C22 C23 C24 0.5(3) . .
C22 C23 C24 C25 -0.5(3) . .
C23 C24 C25 C26 0.3(4) . .
C24 C25 C26 C21 -0.1(4) . .
C22 C21 C26 C25 0.1(3) . .
Si1 C21 C26 C25 -178.50(18) . .
C21 Si1 C31 C32 123.93(17) . .
Ir Si1 C31 C32 -102.89(16) . .
C21 Si1 C31 C36 -58.2(2) . .
Ir Si1 C31 C36 75.00(19) . .
C36 C31 C32 C33 -1.0(3) . .
Si1 C31 C32 C33 176.99(17) . .
C31 C32 C33 C34 0.7(4) . .
C32 C33 C34 C35 0.0(4) . .
C33 C34 C35 C36 -0.3(4) . .
C34 C35 C36 C31 0.0(4) . .
C32 C31 C36 C35 0.7(3) . .
Si1 C31 C36 C35 -177.23(19) . .
C41 Si2 C41 C46 -115.4(2) 2 .
Rh Si2 C41 C46 108.4(2) . .
Ir Si2 C41 C46 22.8(2) . .
C41 Si2 C41 C42 67.35(16) 2 .
Rh Si2 C41 C42 -68.86(19) . .
Ir Si2 C41 C42 -154.45(15) . .
C46 C41 C42 C43 -0.1(3) . .
Si2 C41 C42 C43 177.34(18) . .
C41 C42 C43 C44 2.5(4) . .
C42 C43 C44 C45 -2.9(5) . .
C43 C44 C45 C46 0.8(6) . .
C44 C45 C46 C41 1.7(5) . .
C42 C41 C46 C45 -2.0(4) . .
Si2 C41 C46 C45 -179.4(2) . .
