#------------------------------------------------------------------------------
#$Date: 2016-03-21 11:15:17 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178685 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/96/4079622.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4079622
loop_
_publ_author_name
'Zhu, Yuyang'
'Day, Cynthia S.'
'Jones, Amanda C.'
_publ_section_title
;
 Synthesis and Structure of Cationic Phosphine Gold(I) Enol Ether
 Complexes
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              7332
_journal_paper_doi               10.1021/om300893q
_journal_volume                  31
_journal_year                    2012
_chemical_formula_sum            'C24 H35 Au F6 O P Sb'
_chemical_formula_weight         803.21
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXTL
_cell_angle_alpha                90.00
_cell_angle_beta                 105.6180(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   37.562(5)
_cell_length_b                   12.3451(15)
_cell_length_c                   24.900(3)
_cell_measurement_reflns_used    9866
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      29.22
_cell_measurement_theta_min      3.74
_cell_volume                     11120(2)
_computing_cell_refinement       'Bruker APEX2'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker APEX2'
_computing_molecular_graphics    'Bruker APEX2'
_computing_publication_material  'Bruker APEX2'
_computing_structure_refinement  'Bruker APEX2'
_computing_structure_solution    'Bruker APEX2'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0498
_diffrn_reflns_av_sigmaI/netI    0.0372
_diffrn_reflns_limit_h_max       48
_diffrn_reflns_limit_h_min       -48
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            66267
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.74
_exptl_absorpt_coefficient_mu    6.355
_exptl_absorpt_correction_T_max  0.5160
_exptl_absorpt_correction_T_min  0.3781
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 Data were corrected for absorption effects using the 
 multi-scan technique (SADABS). The ratio of minimum
 to maximum apparent transmission was 0.710. The
 calculated minimum and maximum transmission
 coefficients (based on crystal size) are  0.3781  0.5160. 
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.919
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             6176
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_refine_diff_density_max         2.519
_refine_diff_density_min         -2.675
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     682
_refine_ls_number_reflns         12721
_refine_ls_number_restraints     104
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0485
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0353P)²+76.7858P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0897
_refine_ls_wR_factor_ref         0.0960
_reflns_number_gt                10436
_reflns_number_total             12721
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om300893q_si_001.cif
_cod_data_source_block           a26s_1a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4079622
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.368054(5) 0.020347(17) -0.490217(8) 0.03459(6) Uani 1 1 d . . .
P1 P -0.39791(4) 0.00516(10) -0.42184(6) 0.0330(3) Uani 1 1 d . . .
O1 O -0.35755(16) -0.1605(4) -0.5785(2) 0.0751(15) Uani 1 1 d . . .
C1 C -0.42944(14) 0.1238(4) -0.4255(2) 0.0390(11) Uani 1 1 d . . .
C2 C -0.40475(16) 0.2243(4) -0.4192(2) 0.0436(12) Uani 1 1 d . . .
H2B H -0.3906 0.2219 -0.4470 0.065 Uiso 1 1 calc R . .
H2C H -0.3877 0.2256 -0.3817 0.065 Uiso 1 1 calc R . .
H2A H -0.4202 0.2895 -0.4250 0.065 Uiso 1 1 calc R . .
C3 C -0.45732(15) 0.1252(5) -0.4831(3) 0.0492(14) Uani 1 1 d . . .
H3A H -0.4708 0.1941 -0.4884 0.074 Uiso 1 1 calc R . .
H3B H -0.4748 0.0653 -0.4858 0.074 Uiso 1 1 calc R . .
H3C H -0.4442 0.1172 -0.5120 0.074 Uiso 1 1 calc R . .
C4 C -0.44994(18) 0.1297(5) -0.3797(3) 0.0596(18) Uani 1 1 d . . .
H4A H -0.4643 0.1970 -0.3838 0.089 Uiso 1 1 calc R . .
H4B H -0.4319 0.1285 -0.3429 0.089 Uiso 1 1 calc R . .
H4C H -0.4666 0.0675 -0.3831 0.089 Uiso 1 1 calc R . .
C5 C -0.42186(14) -0.1297(4) -0.4331(2) 0.0409(12) Uani 1 1 d . . .
C6 C -0.43821(16) -0.1475(5) -0.4961(2) 0.0475(13) Uani 1 1 d . . .
H6A H -0.4523 -0.2153 -0.5023 0.071 Uiso 1 1 calc R . .
H6B H -0.4181 -0.1516 -0.5143 0.071 Uiso 1 1 calc R . .
H6C H -0.4546 -0.0870 -0.5118 0.071 Uiso 1 1 calc R . .
C7 C -0.39102(17) -0.2148(5) -0.4126(3) 0.0546(15) Uani 1 1 d . . .
H7A H -0.4015 -0.2876 -0.4206 0.082 Uiso 1 1 calc R . .
H7B H -0.3803 -0.2066 -0.3724 0.082 Uiso 1 1 calc R . .
H7C H -0.3718 -0.2040 -0.4320 0.082 Uiso 1 1 calc R . .
C8 C -0.45281(16) -0.1469(5) -0.4043(3) 0.0526(15) Uani 1 1 d . . .
H8A H -0.4627 -0.2204 -0.4119 0.079 Uiso 1 1 calc R . .
H8B H -0.4726 -0.0942 -0.4187 0.079 Uiso 1 1 calc R . .
H8C H -0.4429 -0.1369 -0.3640 0.079 Uiso 1 1 calc R . .
C9 C -0.36687(15) 0.0055(4) -0.3513(2) 0.0381(11) Uani 1 1 d . . .
C10 C -0.32900(16) 0.0256(4) -0.3400(2) 0.0425(12) Uani 1 1 d . . .
C11 C -0.30757(18) 0.0213(5) -0.2847(2) 0.0505(14) Uani 1 1 d . . .
H11 H -0.2818 0.0361 -0.2766 0.061 Uiso 1 1 calc R . .
C12 C -0.3225(2) -0.0034(5) -0.2418(3) 0.0571(17) Uani 1 1 d . . .
H12 H -0.3072 -0.0052 -0.2046 0.069 Uiso 1 1 calc R . .
C13 C -0.3595(2) -0.0255(5) -0.2525(3) 0.0561(16) Uani 1 1 d . . .
H13 H -0.3699 -0.0442 -0.2229 0.067 Uiso 1 1 calc R . .
C14 C -0.38162(19) -0.0203(5) -0.3067(3) 0.0493(14) Uani 1 1 d . . .
H14 H -0.4073 -0.0345 -0.3140 0.059 Uiso 1 1 calc R . .
C15 C -0.30855(15) 0.0522(6) -0.3822(2) 0.0487(14) Uani 1 1 d . . .
C16 C -0.30687(17) 0.1572(6) -0.4011(3) 0.0565(16) Uani 1 1 d . . .
H16 H -0.3206 0.2126 -0.3893 0.068 Uiso 1 1 calc R . .
C17 C -0.2854(2) 0.1833(8) -0.4370(3) 0.073(2) Uani 1 1 d . . .
H17 H -0.2847 0.2555 -0.4498 0.087 Uiso 1 1 calc R . .
C18 C -0.26513(19) 0.1027(10) -0.4536(3) 0.081(3) Uani 1 1 d . . .
H18 H -0.2506 0.1190 -0.4784 0.097 Uiso 1 1 calc R . .
C19 C -0.26605(18) 0.0010(9) -0.4345(3) 0.078(3) Uani 1 1 d . . .
H19 H -0.2514 -0.0531 -0.4454 0.094 Uiso 1 1 calc R . .
C20 C -0.28775(17) -0.0273(7) -0.3994(3) 0.0648(19) Uani 1 1 d . . .
H20 H -0.2884 -0.1001 -0.3872 0.078 Uiso 1 1 calc R . .
C21 C -0.3656(2) -0.0594(6) -0.5848(3) 0.0563(17) Uani 1 1 d . . .
C22 C -0.34358(16) 0.0292(5) -0.5598(2) 0.0471(14) Uani 1 1 d . . .
H22A H -0.3236 0.0107 -0.5425 0.056 Uiso 1 1 d . . .
H22B H -0.3496 0.0869 -0.5812 0.056 Uiso 1 1 d . . .
C23 C -0.3229(2) -0.1883(8) -0.5404(4) 0.092(3) Uani 1 1 d . . .
H23A H -0.3206 -0.2673 -0.5375 0.138 Uiso 1 1 calc R . .
H23B H -0.3217 -0.1578 -0.5036 0.138 Uiso 1 1 calc R . .
H23C H -0.3027 -0.1588 -0.5539 0.138 Uiso 1 1 calc R . .
C24 C -0.40312(19) -0.0416(6) -0.6260(3) 0.0591(17) Uani 1 1 d . . .
H24A H -0.4025 -0.0671 -0.6630 0.089 Uiso 1 1 calc R . .
H24B H -0.4091 0.0358 -0.6279 0.089 Uiso 1 1 calc R . .
H24C H -0.4220 -0.0819 -0.6137 0.089 Uiso 1 1 calc R . .
Au2 Au -0.094988(7) 0.01728(2) 0.173107(10) 0.04728(7) Uani 1 1 d . . .
P2 P -0.13335(3) 0.00836(10) 0.23001(5) 0.0309(3) Uani 1 1 d . . .
C1A C -0.16311(16) 0.1330(5) 0.2169(3) 0.0465(13) Uani 1 1 d . . .
C2A C -0.1389(2) 0.2331(5) 0.2205(4) 0.082(2) Uani 1 1 d . . .
H2AA H -0.1546 0.2964 0.2074 0.123 Uiso 1 1 calc R . .
H2AB H -0.1219 0.2229 0.1972 0.123 Uiso 1 1 calc R . .
H2AC H -0.1247 0.2445 0.2593 0.123 Uiso 1 1 calc R . .
C3A C -0.1881(3) 0.1500(8) 0.2553(5) 0.109(4) Uani 1 1 d . . .
H3AA H -0.1985 0.2233 0.2500 0.164 Uiso 1 1 calc R . .
H3AB H -0.1736 0.1410 0.2942 0.164 Uiso 1 1 calc R . .
H3AC H -0.2082 0.0968 0.2465 0.164 Uiso 1 1 calc R . .
C4A C -0.1868(2) 0.1202(7) 0.1569(4) 0.091(3) Uani 1 1 d . . .
H4AA H -0.2017 0.1856 0.1457 0.137 Uiso 1 1 calc R . .
H4AB H -0.2031 0.0574 0.1545 0.137 Uiso 1 1 calc R . .
H4AC H -0.1707 0.1094 0.1322 0.137 Uiso 1 1 calc R . .
C5A C -0.10244(16) -0.0073(4) 0.3024(2) 0.0425(12) Uani 1 1 d . . .
C6A C -0.0839(2) -0.1183(6) 0.3028(3) 0.0640(18) Uani 1 1 d . . .
H6AA H -0.0664 -0.1306 0.3393 0.096 Uiso 1 1 calc R . .
H6AB H -0.0706 -0.1200 0.2738 0.096 Uiso 1 1 calc R . .
H6AC H -0.1028 -0.1752 0.2954 0.096 Uiso 1 1 calc R . .
C7A C -0.1217(2) -0.0036(6) 0.3497(3) 0.0611(18) Uani 1 1 d . . .
H7AA H -0.1031 -0.0040 0.3858 0.092 Uiso 1 1 calc R . .
H7AB H -0.1378 -0.0670 0.3470 0.092 Uiso 1 1 calc R . .
H7AC H -0.1366 0.0625 0.3463 0.092 Uiso 1 1 calc R . .
C8A C -0.07277(18) 0.0808(6) 0.3131(3) 0.0579(17) Uani 1 1 d . . .
H8AA H -0.0557 0.0706 0.3502 0.087 Uiso 1 1 calc R . .
H8AB H -0.0845 0.1521 0.3112 0.087 Uiso 1 1 calc R . .
H8AC H -0.0591 0.0762 0.2848 0.087 Uiso 1 1 calc R . .
C9A C -0.16537(13) -0.1059(4) 0.2163(2) 0.0343(10) Uani 1 1 d . . .
C10A C -0.16839(14) -0.1775(4) 0.1712(2) 0.0366(11) Uani 1 1 d . . .
C11A C -0.19713(15) -0.2529(5) 0.1599(3) 0.0471(13) Uani 1 1 d . . .
H11A H -0.2001 -0.2993 0.1286 0.057 Uiso 1 1 calc R A .
C12A C -0.22131(16) -0.2626(5) 0.1925(3) 0.0520(15) Uani 1 1 d . . .
H12A H -0.2406 -0.3146 0.1835 0.062 Uiso 1 1 calc R . .
C13A C -0.21725(16) -0.1964(5) 0.2381(3) 0.0500(14) Uani 1 1 d . . .
H13A H -0.2332 -0.2041 0.2616 0.060 Uiso 1 1 calc R A .
C14A C -0.18979(15) -0.1186(5) 0.2496(2) 0.0435(12) Uani 1 1 d . . .
H14A H -0.1874 -0.0724 0.2808 0.052 Uiso 1 1 calc R . .
C15A C -0.14273(15) -0.1810(4) 0.1351(2) 0.0385(11) Uani 1 1 d . . .
C16A C -0.10852(15) -0.2307(4) 0.1534(2) 0.0426(12) Uani 1 1 d . . .
H16A H -0.1006 -0.2574 0.1905 0.051 Uiso 1 1 calc R . .
C17A C -0.08559(17) -0.2420(5) 0.1180(3) 0.0522(15) Uani 1 1 d . . .
H17A H -0.0621 -0.2759 0.1310 0.063 Uiso 1 1 calc R A .
C18A C -0.09722(19) -0.2039(6) 0.0643(3) 0.0611(18) Uani 1 1 d . . .
H18A H -0.0816 -0.2106 0.0402 0.073 Uiso 1 1 calc R . .
C19A C -0.13130(19) -0.1561(6) 0.0452(3) 0.0614(18) Uani 1 1 d . . .
H19A H -0.1393 -0.1306 0.0079 0.074 Uiso 1 1 calc R A .
C20A C -0.15387(16) -0.1452(5) 0.0804(2) 0.0515(14) Uani 1 1 d . . .
H20A H -0.1775 -0.1124 0.0669 0.062 Uiso 1 1 calc R . .
C22A C -0.0551(3) 0.0290(8) 0.1241(5) 0.106(4) Uani 1 1 d . A .
O2 O -0.0770(3) 0.1838(8) 0.0908(4) 0.062(2) Uani 0.50 1 d P A 1
C21A C -0.0555(4) 0.1261(12) 0.1263(7) 0.066(5) Uani 0.50 1 d P A 1
C23A C -0.1012(3) 0.1240(10) 0.0474(5) 0.050(3) Uani 0.50 1 d P A 1
H23D H -0.1176 0.1739 0.0216 0.074 Uiso 0.50 1 calc PR A 1
H23E H -0.1160 0.0744 0.0634 0.074 Uiso 0.50 1 calc PR A 1
H23F H -0.0867 0.0822 0.0273 0.074 Uiso 0.50 1 calc PR A 1
C24A C -0.0351(8) 0.2149(15) 0.1642(13) 0.093(11) Uani 0.50 1 d P A 1
H24D H -0.0264 0.2692 0.1419 0.140 Uiso 0.50 1 calc PR A 1
H24E H -0.0139 0.1838 0.1918 0.140 Uiso 0.50 1 calc PR A 1
H24F H -0.0518 0.2492 0.1833 0.140 Uiso 0.50 1 calc PR A 1
O2' O -0.0128(3) 0.0506(12) 0.1931(6) 0.099(4) Uani 0.50 1 d P A 2
C21' C -0.0389(6) 0.0930(17) 0.1544(8) 0.077(5) Uiso 0.50 1 d P A 2
C23' C -0.0112(5) -0.0687(15) 0.1883(10) 0.098(6) Uani 0.50 1 d P A 2
H23G H 0.0066 -0.0981 0.2213 0.148 Uiso 0.50 1 calc PR A 2
H23H H -0.0036 -0.0877 0.1548 0.148 Uiso 0.50 1 calc PR A 2
H23I H -0.0357 -0.0993 0.1856 0.148 Uiso 0.50 1 calc PR A 2
C24' C -0.0296(8) 0.210(3) 0.1733(10) 0.090(11) Uani 0.50 1 d P A 2
H24G H -0.0045 0.2273 0.1714 0.135 Uiso 0.50 1 calc PR A 2
H24H H -0.0312 0.2184 0.2117 0.135 Uiso 0.50 1 calc PR A 2
H24I H -0.0473 0.2590 0.1488 0.135 Uiso 0.50 1 calc PR A 2
Sb1 Sb -0.221643(12) -0.06395(4) 0.411072(18) 0.05196(11) Uani 1 1 d D . .
F1 F -0.26087(16) 0.0228(5) 0.4140(2) 0.121(2) Uani 1 1 d DU B .
F2 F -0.18248(17) -0.1499(5) 0.4074(3) 0.156(3) Uani 1 1 d DU B .
F3 F -0.2141(3) 0.0213(8) 0.3556(5) 0.112(5) Uani 0.50 1 d PDU B 1
F4 F -0.2343(4) -0.1594(12) 0.4596(7) 0.130(7) Uani 0.50 1 d PDU B 1
F5 F -0.2536(4) -0.1429(12) 0.3514(6) 0.157(6) Uiso 0.50 1 d PD B 1
F6 F -0.1928(4) 0.0067(16) 0.4691(8) 0.201(9) Uiso 0.50 1 d PD B 1
F3' F -0.2337(3) -0.0479(12) 0.3365(4) 0.123(5) Uiso 0.50 1 d PD B 2
F4' F -0.2049(4) -0.0614(12) 0.4891(3) 0.116(4) Uani 0.50 1 d PDU B 2
F5' F -0.2483(4) -0.1796(9) 0.4120(9) 0.219(12) Uani 0.50 1 d PDU B 2
F6' F -0.1914(3) 0.0610(9) 0.4151(6) 0.142(5) Uiso 0.50 1 d PD B 2
Sb2 Sb -0.5000 -0.06556(6) -0.2500 0.05631(16) Uani 1 2 d SD . .
F7 F -0.4531(3) -0.0215(12) -0.2501(6) 0.141(5) Uiso 0.50 1 d PD C 1
F8 F -0.4827(4) -0.2077(10) -0.2457(7) 0.191(7) Uiso 0.50 1 d PD . 1
F9 F -0.5129(3) -0.0859(8) -0.3267(3) 0.069(3) Uiso 0.50 1 d PD C 1
F7' F -0.4533(2) -0.1149(9) -0.2484(4) 0.085(3) Uiso 0.50 1 d PD C 2
F8' F -0.5136(3) -0.0397(8) -0.3276(4) 0.065(2) Uiso 0.50 1 d PD C 2
F9' F -0.4791(4) 0.0693(11) -0.2488(6) 0.143(5) Uiso 0.50 1 d PD . 2
Sb3 Sb 0.0000 0.0000 0.0000 0.03347(11) Uani 1 2 d SD . .
F10 F 0.00113(12) -0.1107(3) -0.05019(17) 0.0724(11) Uani 1 1 d DU D .
F11 F 0.0484(2) 0.0357(10) 0.0076(4) 0.096(4) Uani 0.50 1 d PDU D -1
F12 F 0.0140(3) -0.0891(6) 0.0612(3) 0.092(4) Uani 0.50 1 d PDU D -1
F11' F 0.0490(3) -0.0318(11) 0.0297(5) 0.115(5) Uiso 0.50 1 d PD D -2
F12' F -0.0126(3) -0.1034(9) 0.0449(5) 0.100(4) Uiso 0.50 1 d PD D -2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C22 Au1 P1 175.42(16) . .
C22 Au1 C21 33.2(2) . .
P1 Au1 C21 142.70(16) . .
C9 P1 C1 106.1(2) . .
C9 P1 C5 107.5(2) . .
C1 P1 C5 114.6(2) . .
C9 P1 Au1 113.69(18) . .
C1 P1 Au1 109.32(17) . .
C5 P1 Au1 105.86(18) . .
C21 O1 C23 117.2(7) . .
C2 C1 C3 109.2(4) . .
C2 C1 C4 107.2(5) . .
C3 C1 C4 110.0(5) . .
C2 C1 P1 105.7(3) . .
C3 C1 P1 108.6(4) . .
C4 C1 P1 115.9(4) . .
C1 C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
C1 C2 H2A 109.5 . .
H2B C2 H2A 109.5 . .
H2C C2 H2A 109.5 . .
C1 C3 H3A 109.5 . .
C1 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
C1 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C1 C4 H4A 109.5 . .
C1 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C1 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C8 C5 C6 108.2(5) . .
C8 C5 C7 110.3(5) . .
C6 C5 C7 107.3(5) . .
C8 C5 P1 116.4(4) . .
C6 C5 P1 108.8(4) . .
C7 C5 P1 105.5(4) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C5 C7 H7A 109.5 . .
C5 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C5 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C5 C8 H8A 109.5 . .
C5 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C5 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 C14 118.6(5) . .
C10 C9 P1 123.1(4) . .
C14 C9 P1 118.3(4) . .
C9 C10 C11 118.5(5) . .
C9 C10 C15 125.8(5) . .
C11 C10 C15 115.7(5) . .
C12 C11 C10 122.0(6) . .
C12 C11 H11 119.0 . .
C10 C11 H11 119.0 . .
C11 C12 C13 120.1(6) . .
C11 C12 H12 120.0 . .
C13 C12 H12 120.0 . .
C12 C13 C14 119.3(6) . .
C12 C13 H13 120.3 . .
C14 C13 H13 120.3 . .
C13 C14 C9 121.5(6) . .
C13 C14 H14 119.3 . .
C9 C14 H14 119.3 . .
C16 C15 C20 118.4(6) . .
C16 C15 C10 121.5(6) . .
C20 C15 C10 119.8(6) . .
C15 C16 C17 121.4(7) . .
C15 C16 H16 119.3 . .
C17 C16 H16 119.3 . .
C18 C17 C16 119.1(8) . .
C18 C17 H17 120.4 . .
C16 C17 H17 120.4 . .
C19 C18 C17 119.8(7) . .
C19 C18 H18 120.1 . .
C17 C18 H18 120.1 . .
C18 C19 C20 122.1(8) . .
C18 C19 H19 118.9 . .
C20 C19 H19 118.9 . .
C15 C20 C19 119.2(8) . .
C15 C20 H20 120.4 . .
C19 C20 H20 120.4 . .
O1 C21 C22 127.6(7) . .
O1 C21 C24 111.6(7) . .
C22 C21 C24 120.8(6) . .
O1 C21 Au1 108.9(4) . .
C22 C21 Au1 57.3(3) . .
C24 C21 Au1 107.8(4) . .
C21 C22 Au1 89.5(3) . .
C21 C22 H22A 111.8(7) . .
Au1 C22 H22A 95.4(4) . .
C21 C22 H22B 109.5(6) . .
Au1 C22 H22B 115.4(5) . .
H22A C22 H22B 127.8(7) . .
O1 C23 H23A 109.5 . .
O1 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
O1 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C22A Au2 P2 175.8(3) . .
C22A Au2 C21' 27.8(5) . .
P2 Au2 C21' 148.5(5) . .
C22A Au2 C21A 28.6(4) . .
P2 Au2 C21A 150.1(4) . .
C21' Au2 C21A 20.9(5) . .
C9A P2 C5A 107.8(2) . .
C9A P2 C1A 105.6(3) . .
C5A P2 C1A 116.0(3) . .
C9A P2 Au2 114.62(17) . .
C5A P2 Au2 105.76(19) . .
C1A P2 Au2 107.36(18) . .
C2A C1A C4A 108.9(6) . .
C2A C1A C3A 108.0(7) . .
C4A C1A C3A 109.5(7) . .
C2A C1A P2 109.7(4) . .
C4A C1A P2 104.4(4) . .
C3A C1A P2 116.2(5) . .
C1A C2A H2AA 109.5 . .
C1A C2A H2AB 109.5 . .
H2AA C2A H2AB 109.5 . .
C1A C2A H2AC 109.5 . .
H2AA C2A H2AC 109.5 . .
H2AB C2A H2AC 109.5 . .
C1A C3A H3AA 109.5 . .
C1A C3A H3AB 109.5 . .
H3AA C3A H3AB 109.5 . .
C1A C3A H3AC 109.5 . .
H3AA C3A H3AC 109.5 . .
H3AB C3A H3AC 109.5 . .
C1A C4A H4AA 109.5 . .
C1A C4A H4AB 109.5 . .
H4AA C4A H4AB 109.5 . .
C1A C4A H4AC 109.5 . .
H4AA C4A H4AC 109.5 . .
H4AB C4A H4AC 109.5 . .
C8A C5A C6A 109.0(5) . .
C8A C5A C7A 108.5(5) . .
C6A C5A C7A 109.2(5) . .
C8A C5A P2 109.2(4) . .
C6A C5A P2 105.1(4) . .
C7A C5A P2 115.8(4) . .
C5A C6A H6AA 109.5 . .
C5A C6A H6AB 109.5 . .
H6AA C6A H6AB 109.5 . .
C5A C6A H6AC 109.5 . .
H6AA C6A H6AC 109.5 . .
H6AB C6A H6AC 109.5 . .
C5A C7A H7AA 109.5 . .
C5A C7A H7AB 109.5 . .
H7AA C7A H7AB 109.5 . .
C5A C7A H7AC 109.5 . .
H7AA C7A H7AC 109.5 . .
H7AB C7A H7AC 109.5 . .
C5A C8A H8AA 109.5 . .
C5A C8A H8AB 109.5 . .
H8AA C8A H8AB 109.5 . .
C5A C8A H8AC 109.5 . .
H8AA C8A H8AC 109.5 . .
H8AB C8A H8AC 109.5 . .
C14A C9A C10A 118.4(5) . .
C14A C9A P2 118.7(4) . .
C10A C9A P2 122.7(4) . .
C11A C10A C9A 118.0(5) . .
C11A C10A C15A 116.9(5) . .
C9A C10A C15A 125.1(5) . .
C12A C11A C10A 122.5(5) . .
C12A C11A H11A 118.7 . .
C10A C11A H11A 118.7 . .
C13A C12A C11A 119.4(5) . .
C13A C12A H12A 120.3 . .
C11A C12A H12A 120.3 . .
C12A C13A C14A 119.7(5) . .
C12A C13A H13A 120.1 . .
C14A C13A H13A 120.1 . .
C13A C14A C9A 121.8(5) . .
C13A C14A H14A 119.1 . .
C9A C14A H14A 119.1 . .
C20A C15A C16A 118.2(5) . .
C20A C15A C10A 120.8(5) . .
C16A C15A C10A 120.6(5) . .
C15A C16A C17A 120.8(6) . .
C15A C16A H16A 119.6 . .
C17A C16A H16A 119.6 . .
C18A C17A C16A 119.5(6) . .
C18A C17A H17A 120.2 . .
C16A C17A H17A 120.2 . .
C19A C18A C17A 120.4(6) . .
C19A C18A H18A 119.8 . .
C17A C18A H18A 119.8 . .
C18A C19A C20A 119.8(6) . .
C18A C19A H19A 120.1 . .
C20A C19A H19A 120.1 . .
C19A C20A C15A 121.2(6) . .
C19A C20A H20A 119.4 . .
C15A C20A H20A 119.4 . .
C21' C22A C21A 45.1(11) . .
C21' C22A Au2 90.0(10) . .
C21A C22A Au2 91.1(6) . .
C21A O2 C23A 113.6(12) . .
C22A C21A O2 124(2) . .
C22A C21A C24A 137.8(19) . .
O2 C21A C24A 98.6(16) . .
C22A C21A Au2 60.3(6) . .
O2 C21A Au2 106.6(8) . .
C24A C21A Au2 111.2(12) . .
O2 C23A H23D 109.5 . .
O2 C23A H23E 109.5 . .
H23D C23A H23E 109.5 . .
O2 C23A H23F 109.5 . .
H23D C23A H23F 109.5 . .
H23E C23A H23F 109.5 . .
C21A C24A H24D 109.5 . .
C21A C24A H24E 109.5 . .
H24D C24A H24E 109.5 . .
C21A C24A H24F 109.5 . .
H24D C24A H24F 109.5 . .
H24E C24A H24F 109.5 . .
C21' O2' C23' 112.5(16) . .
C22A C21' O2' 112(2) . .
C22A C21' C24' 153(2) . .
O2' C21' C24' 95.2(18) . .
C22A C21' Au2 62.2(9) . .
O2' C21' Au2 102.8(12) . .
C24' C21' Au2 115.8(16) . .
O2' C23' H23G 109.5 . .
O2' C23' H23H 109.5 . .
H23G C23' H23H 109.5 . .
O2' C23' H23I 109.5 . .
H23G C23' H23I 109.5 . .
H23H C23' H23I 109.5 . .
C21' C24' H24G 109.5 . .
C21' C24' H24H 109.5 . .
H24G C24' H24H 109.5 . .
C21' C24' H24I 109.5 . .
H24G C24' H24I 109.5 . .
H24H C24' H24I 109.5 . .
F5' Sb1 F6 127.9(10) . .
F5' Sb1 F3' 96.8(7) . .
F6 Sb1 F3' 135.4(9) . .
F5' Sb1 F3 133.7(8) . .
F6 Sb1 F3 98.5(10) . .
F3' Sb1 F3 36.9(5) . .
F5' Sb1 F2 89.9(5) . .
F6 Sb1 F2 90.1(5) . .
F3' Sb1 F2 89.7(4) . .
F3 Sb1 F2 90.3(3) . .
F5' Sb1 F1 90.4(5) . .
F6 Sb1 F1 90.1(5) . .
F3' Sb1 F1 89.7(4) . .
F3 Sb1 F1 89.0(3) . .
F2 Sb1 F1 179.4(2) . .
F5' Sb1 F4 38.5(7) . .
F6 Sb1 F4 89.4(10) . .
F3' Sb1 F4 135.2(7) . .
F3 Sb1 F4 172.0(8) . .
F2 Sb1 F4 90.8(4) . .
F1 Sb1 F4 89.8(3) . .
F5' Sb1 F4' 91.9(7) . .
F6 Sb1 F4' 36.0(8) . .
F3' Sb1 F4' 171.4(7) . .
F3 Sb1 F4' 134.5(7) . .
F2 Sb1 F4' 90.7(4) . .
F1 Sb1 F4' 89.9(3) . .
F4 Sb1 F4' 53.4(6) . .
F5' Sb1 F6' 176.3(8) . .
F6 Sb1 F6' 48.4(8) . .
F3' Sb1 F6' 86.9(6) . .
F3 Sb1 F6' 50.0(6) . .
F2 Sb1 F6' 89.8(4) . .
F1 Sb1 F6' 89.9(4) . .
F4 Sb1 F6' 137.8(7) . .
F4' Sb1 F6' 84.5(6) . .
F5' Sb1 F5 49.5(7) . .
F6 Sb1 F5 177.2(10) . .
F3' Sb1 F5 47.3(5) . .
F3 Sb1 F5 84.2(6) . .
F2 Sb1 F5 90.7(5) . .
F1 Sb1 F5 89.1(4) . .
F4 Sb1 F5 87.9(8) . .
F4' Sb1 F5 141.3(7) . .
F6' Sb1 F5 134.2(6) . .
F9' Sb2 F9' 50.0(9) . 2_454
F9' Sb2 F7 47.9(6) . .
F9' Sb2 F7 97.8(7) 2_454 .
F9' Sb2 F7 97.8(7) . 2_454
F9' Sb2 F7 47.9(6) 2_454 2_454
F7 Sb2 F7 145.7(10) . 2_454
F9' Sb2 F7' 84.2(5) . .
F9' Sb2 F7' 134.2(6) 2_454 .
F7 Sb2 F7' 36.4(5) . .
F7 Sb2 F7' 177.5(7) 2_454 .
F9' Sb2 F7' 134.2(6) . 2_454
F9' Sb2 F7' 84.2(5) 2_454 2_454
F7 Sb2 F7' 177.5(7) . 2_454
F7 Sb2 F7' 36.4(5) 2_454 2_454
F7' Sb2 F7' 141.5(7) . 2_454
F9' Sb2 F9 96.5(6) . 2_454
F9' Sb2 F9 97.6(6) 2_454 2_454
F7 Sb2 F9 93.2(5) . 2_454
F7 Sb2 F9 91.4(5) 2_454 2_454
F7' Sb2 F9 87.1(4) . 2_454
F7' Sb2 F9 87.8(4) 2_454 2_454
F9' Sb2 F9 97.6(6) . .
F9' Sb2 F9 96.5(6) 2_454 .
F7 Sb2 F9 91.4(5) . .
F7 Sb2 F9 93.2(5) 2_454 .
F7' Sb2 F9 87.8(4) . .
F7' Sb2 F9 87.1(4) 2_454 .
F9 Sb2 F9 164.4(6) 2_454 .
F9' Sb2 F8 174.0(7) . 2_454
F9' Sb2 F8 135.4(6) 2_454 2_454
F7 Sb2 F8 126.6(8) . 2_454
F7 Sb2 F8 87.7(6) 2_454 2_454
F7' Sb2 F8 90.3(6) . 2_454
F7' Sb2 F8 51.3(5) 2_454 2_454
F9 Sb2 F8 85.6(6) 2_454 2_454
F9 Sb2 F8 79.8(7) . 2_454
F9' Sb2 F8 135.4(6) . .
F9' Sb2 F8 174.0(7) 2_454 .
F7 Sb2 F8 87.7(6) . .
F7 Sb2 F8 126.6(8) 2_454 .
F7' Sb2 F8 51.3(5) . .
F7' Sb2 F8 90.3(6) 2_454 .
F9 Sb2 F8 79.8(7) 2_454 .
F9 Sb2 F8 85.6(6) . .
F8 Sb2 F8 39.5(9) 2_454 .
F9' Sb2 F8' 82.0(6) . .
F9' Sb2 F8' 80.4(6) 2_454 .
F7 Sb2 F8' 86.8(6) . .
F7 Sb2 F8' 87.5(6) 2_454 .
F7' Sb2 F8' 94.1(4) . .
F7' Sb2 F8' 92.3(4) 2_454 .
F9 Sb2 F8' 178.0(5) 2_454 .
F9 Sb2 F8' 17.5(4) . .
F8 Sb2 F8' 96.1(6) 2_454 .
F8 Sb2 F8' 102.2(6) . .
F9' Sb2 F8' 80.4(6) . 2_454
F9' Sb2 F8' 82.0(6) 2_454 2_454
F7 Sb2 F8' 87.5(6) . 2_454
F7 Sb2 F8' 86.8(6) 2_454 2_454
F7' Sb2 F8' 92.3(4) . 2_454
F7' Sb2 F8' 94.1(4) 2_454 2_454
F9 Sb2 F8' 17.5(4) 2_454 2_454
F9 Sb2 F8' 178.0(5) . 2_454
F8 Sb2 F8' 102.2(6) 2_454 2_454
F8 Sb2 F8' 96.1(6) . 2_454
F8' Sb2 F8' 160.6(6) . 2_454
F8 F8 Sb2 70.3(5) 2_454 .
F9' F9' Sb2 65.0(4) 2_454 .
F11' Sb3 F11' 179.999(2) . 5
F11' Sb3 F11 31.6(5) . .
F11' Sb3 F11 148.4(5) 5 .
F11' Sb3 F11 148.4(5) . 5
F11' Sb3 F11 31.6(5) 5 5
F11 Sb3 F11 179.999(1) . 5
F11' Sb3 F12 119.7(6) . 5
F11' Sb3 F12 60.3(6) 5 5
F11 Sb3 F12 89.8(5) . 5
F11 Sb3 F12 90.2(5) 5 5
F11' Sb3 F12 60.3(6) . .
F11' Sb3 F12 119.7(6) 5 .
F11 Sb3 F12 90.2(5) . .
F11 Sb3 F12 89.8(5) 5 .
F12 Sb3 F12 180.0(3) 5 .
F11' Sb3 F12' 90.0(6) . 5
F11' Sb3 F12' 90.0(6) 5 5
F11 Sb3 F12' 59.0(5) . 5
F11 Sb3 F12' 121.0(5) 5 5
F12 Sb3 F12' 31.1(4) 5 5
F12 Sb3 F12' 148.9(4) . 5
F11' Sb3 F12' 90.0(6) . .
F11' Sb3 F12' 90.0(6) 5 .
F11 Sb3 F12' 121.0(5) . .
F11 Sb3 F12' 59.0(5) 5 .
F12 Sb3 F12' 148.9(4) 5 .
F12 Sb3 F12' 31.1(4) . .
F12' Sb3 F12' 180.0(5) 5 .
F11' Sb3 F10 85.0(4) . .
F11' Sb3 F10 95.0(4) 5 .
F11 Sb3 F10 92.5(3) . .
F11 Sb3 F10 87.5(3) 5 .
F12 Sb3 F10 86.3(3) 5 .
F12 Sb3 F10 93.7(3) . .
F12' Sb3 F10 92.6(4) 5 .
F12' Sb3 F10 87.4(4) . .
F11' Sb3 F10 95.0(4) . 5
F11' Sb3 F10 85.0(4) 5 5
F11 Sb3 F10 87.5(3) . 5
F11 Sb3 F10 92.5(3) 5 5
F12 Sb3 F10 93.7(3) 5 5
F12 Sb3 F10 86.3(3) . 5
F12' Sb3 F10 87.4(4) 5 5
F12' Sb3 F10 92.6(4) . 5
F10 Sb3 F10 180.00(18) . 5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C22 2.171(6) .
Au1 P1 2.2846(13) .
Au1 C21 2.579(6) .
P1 C9 1.828(5) .
P1 C1 1.871(5) .
P1 C5 1.878(6) .
O1 C21 1.283(8) .
O1 C23 1.430(9) .
C1 C2 1.531(7) .
C1 C3 1.531(8) .
C1 C4 1.541(7) .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C2 H2A 0.9800 .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 C8 1.536(7) .
C5 C6 1.539(8) .
C5 C7 1.544(8) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 C10 1.396(8) .
C9 C14 1.404(8) .
C10 C11 1.397(8) .
C10 C15 1.496(8) .
C11 C12 1.366(9) .
C11 H11 0.9500 .
C12 C13 1.372(10) .
C12 H12 0.9500 .
C13 C14 1.384(9) .
C13 H13 0.9500 .
C14 H14 0.9500 .
C15 C16 1.386(9) .
C15 C20 1.391(9) .
C16 C17 1.392(9) .
C16 H16 0.9500 .
C17 C18 1.382(12) .
C17 H17 0.9500 .
C18 C19 1.346(12) .
C18 H18 0.9500 .
C19 C20 1.392(11) .
C19 H19 0.9500 .
C20 H20 0.9500 .
C21 C22 1.412(10) .
C21 C24 1.520(9) .
C22 H22A 0.792(6) .
C22 H22B 0.882(6) .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
Au2 C22A 2.179(7) .
Au2 P2 2.2792(12) .
Au2 C21' 2.463(19) .
Au2 C21A 2.508(11) .
P2 C9A 1.825(5) .
P2 C5A 1.873(6) .
P2 C1A 1.878(6) .
C1A C2A 1.522(9) .
C1A C4A 1.525(10) .
C1A C3A 1.525(9) .
C2A H2AA 0.9800 .
C2A H2AB 0.9800 .
C2A H2AC 0.9800 .
C3A H3AA 0.9800 .
C3A H3AB 0.9800 .
C3A H3AC 0.9800 .
C4A H4AA 0.9800 .
C4A H4AB 0.9800 .
C4A H4AC 0.9800 .
C5A C8A 1.528(8) .
C5A C6A 1.537(9) .
C5A C7A 1.540(9) .
C6A H6AA 0.9800 .
C6A H6AB 0.9800 .
C6A H6AC 0.9800 .
C7A H7AA 0.9800 .
C7A H7AB 0.9800 .
C7A H7AC 0.9800 .
C8A H8AA 0.9800 .
C8A H8AB 0.9800 .
C8A H8AC 0.9800 .
C9A C14A 1.400(7) .
C9A C10A 1.411(7) .
C10A C11A 1.396(7) .
C10A C15A 1.485(7) .
C11A C12A 1.376(8) .
C11A H11A 0.9500 .
C12A C13A 1.373(9) .
C12A H12A 0.9500 .
C13A C14A 1.382(8) .
C13A H13A 0.9500 .
C14A H14A 0.9500 .
C15A C20A 1.385(8) .
C15A C16A 1.386(7) .
C16A C17A 1.395(8) .
C16A H16A 0.9500 .
C17A C18A 1.374(9) .
C17A H17A 0.9500 .
C18A C19A 1.373(10) .
C18A H18A 0.9500 .
C19A C20A 1.381(8) .
C19A H19A 0.9500 .
C20A H20A 0.9500 .
C22A C21' 1.15(2) .
C22A C21A 1.200(16) .
O2 C21A 1.248(16) .
O2 C23A 1.416(15) .
C21A C24A 1.51(3) .
C23A H23D 0.9800 .
C23A H23E 0.9800 .
C23A H23F 0.9800 .
C24A H24D 0.9800 .
C24A H24E 0.9800 .
C24A H24F 0.9800 .
O2' C21' 1.29(2) .
O2' C23' 1.48(2) .
C21' C24' 1.53(4) .
C23' H23G 0.9800 .
C23' H23H 0.9800 .
C23' H23I 0.9800 .
C24' H24G 0.9800 .
C24' H24H 0.9800 .
C24' H24I 0.9800 .
Sb1 F5' 1.747(10) .
Sb1 F6 1.784(13) .
Sb1 F3' 1.800(10) .
Sb1 F3 1.819(7) .
Sb1 F2 1.836(4) .
Sb1 F1 1.839(4) .
Sb1 F4 1.839(8) .
Sb1 F4' 1.874(8) .
Sb1 F6' 1.902(10) .
Sb1 F5 1.907(11) .
Sb2 F9' 1.836(12) .
Sb2 F9' 1.836(12) 2_454
Sb2 F7 1.845(12) .
Sb2 F7 1.845(12) 2_454
Sb2 F7' 1.848(9) .
Sb2 F7' 1.848(9) 2_454
Sb2 F9 1.856(8) 2_454
Sb2 F9 1.856(8) .
Sb2 F8 1.864(13) 2_454
Sb2 F8 1.864(13) .
Sb2 F8' 1.889(8) .
Sb2 F8' 1.889(8) 2_454
F8 F8 1.26(3) 2_454
F9' F9' 1.55(3) 2_454
Sb3 F11' 1.831(11) .
Sb3 F11' 1.831(11) 5
Sb3 F11 1.832(6) .
Sb3 F11 1.832(6) 5
Sb3 F12 1.838(6) 5
Sb3 F12 1.838(6) .
Sb3 F12' 1.841(10) 5
Sb3 F12' 1.841(10) .
Sb3 F10 1.860(3) .
Sb3 F10 1.860(3) 5
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C22 Au1 P1 C9 159(2) . .
C21 Au1 P1 C9 134.4(3) . .
C22 Au1 P1 C1 -83(2) . .
C21 Au1 P1 C1 -107.3(3) . .
C22 Au1 P1 C5 41(2) . .
C21 Au1 P1 C5 16.6(3) . .
C9 P1 C1 C2 65.3(4) . .
C5 P1 C1 C2 -176.3(3) . .
Au1 P1 C1 C2 -57.7(4) . .
C9 P1 C1 C3 -177.6(4) . .
C5 P1 C1 C3 -59.2(4) . .
Au1 P1 C1 C3 59.4(4) . .
C9 P1 C1 C4 -53.3(5) . .
C5 P1 C1 C4 65.1(5) . .
Au1 P1 C1 C4 -176.3(4) . .
C9 P1 C5 C8 75.4(5) . .
C1 P1 C5 C8 -42.2(5) . .
Au1 P1 C5 C8 -162.7(4) . .
C9 P1 C5 C6 -162.1(4) . .
C1 P1 C5 C6 80.3(4) . .
Au1 P1 C5 C6 -40.3(4) . .
C9 P1 C5 C7 -47.3(4) . .
C1 P1 C5 C7 -164.9(4) . .
Au1 P1 C5 C7 74.6(4) . .
C1 P1 C9 C10 -113.2(5) . .
C5 P1 C9 C10 123.8(5) . .
Au1 P1 C9 C10 7.0(5) . .
C1 P1 C9 C14 69.6(5) . .
C5 P1 C9 C14 -53.4(5) . .
Au1 P1 C9 C14 -170.2(4) . .
C14 C9 C10 C11 -1.3(8) . .
P1 C9 C10 C11 -178.5(4) . .
C14 C9 C10 C15 178.9(6) . .
P1 C9 C10 C15 1.7(8) . .
C9 C10 C11 C12 1.0(9) . .
C15 C10 C11 C12 -179.2(6) . .
C10 C11 C12 C13 0.3(10) . .
C11 C12 C13 C14 -1.3(10) . .
C12 C13 C14 C9 1.0(9) . .
C10 C9 C14 C13 0.3(9) . .
P1 C9 C14 C13 177.6(5) . .
C9 C10 C15 C16 84.1(8) . .
C11 C10 C15 C16 -95.7(7) . .
C9 C10 C15 C20 -102.1(7) . .
C11 C10 C15 C20 78.1(7) . .
C20 C15 C16 C17 0.9(9) . .
C10 C15 C16 C17 174.8(6) . .
C15 C16 C17 C18 -0.6(10) . .
C16 C17 C18 C19 -0.8(11) . .
C17 C18 C19 C20 1.9(12) . .
C16 C15 C20 C19 0.1(9) . .
C10 C15 C20 C19 -173.9(6) . .
C18 C19 C20 C15 -1.5(11) . .
C23 O1 C21 C22 2.2(9) . .
C23 O1 C21 C24 -179.5(6) . .
C23 O1 C21 Au1 -60.7(7) . .
C22 Au1 C21 O1 123.1(7) . .
P1 Au1 C21 O1 -60.4(6) . .
P1 Au1 C21 C22 176.5(3) . .
C22 Au1 C21 C24 -115.7(6) . .
P1 Au1 C21 C24 60.9(5) . .
O1 C21 C22 Au1 -89.6(6) . .
C24 C21 C22 Au1 92.3(5) . .
P1 Au1 C22 C21 -28(2) . .
C22A Au2 P2 C9A -138(4) . .
C21' Au2 P2 C9A -164.5(10) . .
C21A Au2 P2 C9A 154.1(8) . .
C22A Au2 P2 C5A -20(4) . .
C21' Au2 P2 C5A -45.8(10) . .
C21A Au2 P2 C5A -87.2(8) . .
C22A Au2 P2 C1A 105(4) . .
C21' Au2 P2 C1A 78.6(10) . .
C21A Au2 P2 C1A 37.2(8) . .
C9A P2 C1A C2A -173.4(5) . .
C5A P2 C1A C2A 67.3(6) . .
Au2 P2 C1A C2A -50.6(5) . .
C9A P2 C1A C4A -56.8(5) . .
C5A P2 C1A C4A -176.2(5) . .
Au2 P2 C1A C4A 65.9(5) . .
C9A P2 C1A C3A 63.9(7) . .
C5A P2 C1A C3A -55.5(7) . .
Au2 P2 C1A C3A -173.4(6) . .
C9A P2 C5A C8A 174.4(4) . .
C1A P2 C5A C8A -67.5(5) . .
Au2 P2 C5A C8A 51.3(5) . .
C9A P2 C5A C6A 57.6(5) . .
C1A P2 C5A C6A 175.7(4) . .
Au2 P2 C5A C6A -65.5(4) . .
C9A P2 C5A C7A -62.9(5) . .
C1A P2 C5A C7A 55.2(5) . .
Au2 P2 C5A C7A 174.0(4) . .
C5A P2 C9A C14A 62.0(5) . .
C1A P2 C9A C14A -62.6(5) . .
Au2 P2 C9A C14A 179.4(4) . .
C5A P2 C9A C10A -122.7(5) . .
C1A P2 C9A C10A 112.7(5) . .
Au2 P2 C9A C10A -5.3(5) . .
C14A C9A C10A C11A 3.9(7) . .
P2 C9A C10A C11A -171.4(4) . .
C14A C9A C10A C15A -174.5(5) . .
P2 C9A C10A C15A 10.2(7) . .
C9A C10A C11A C12A -2.8(8) . .
C15A C10A C11A C12A 175.7(5) . .
C10A C11A C12A C13A -0.3(9) . .
C11A C12A C13A C14A 2.2(9) . .
C12A C13A C14A C9A -1.0(9) . .
C10A C9A C14A C13A -2.2(8) . .
P2 C9A C14A C13A 173.3(5) . .
C11A C10A C15A C20A 72.7(7) . .
C9A C10A C15A C20A -108.9(6) . .
C11A C10A C15A C16A -100.4(6) . .
C9A C10A C15A C16A 78.0(7) . .
C20A C15A C16A C17A 1.4(8) . .
C10A C15A C16A C17A 174.7(5) . .
C15A C16A C17A C18A -0.3(9) . .
C16A C17A C18A C19A -0.8(10) . .
C17A C18A C19A C20A 0.7(11) . .
C18A C19A C20A C15A 0.4(10) . .
C16A C15A C20A C19A -1.5(9) . .
C10A C15A C20A C19A -174.8(6) . .
P2 Au2 C22A C21' -30(5) . .
C21A Au2 C22A C21' 45.1(11) . .
P2 Au2 C22A C21A -75(5) . .
C21' Au2 C22A C21A -45.1(11) . .
C21' C22A C21A O2 -180(100) . .
Au2 C22A C21A O2 -90.9(11) . .
C21' C22A C21A C24A 1(2) . .
Au2 C22A C21A C24A 89.5(19) . .
C21' C22A C21A Au2 -88.9(15) . .
C23A O2 C21A C22A 0.4(15) . .
C23A O2 C21A C24A -179.8(12) . .
C23A O2 C21A Au2 -64.6(11) . .
P2 Au2 C21A C22A 171.9(8) . .
C21' Au2 C21A C22A 67.9(16) . .
C22A Au2 C21A O2 120(2) . .
P2 Au2 C21A O2 -68.5(17) . .
C21' Au2 C21A O2 -172(3) . .
C22A Au2 C21A C24A -134(2) . .
P2 Au2 C21A C24A 38.0(17) . .
C21' Au2 C21A C24A -66(2) . .
C21A C22A C21' O2' -175(2) . .
Au2 C22A C21' O2' 93.3(14) . .
C21A C22A C21' C24' -1(4) . .
Au2 C22A C21' C24' -93(4) . .
C21A C22A C21' Au2 91.6(12) . .
C23' O2' C21' C22A -1(2) . .
C23' O2' C21' C24' -178.0(16) . .
C23' O2' C21' Au2 64.1(14) . .
P2 Au2 C21' C22A 176.0(8) . .
C21A Au2 C21' C22A -71.9(18) . .
C22A Au2 C21' O2' -108(2) . .
P2 Au2 C21' O2' 67.7(17) . .
C21A Au2 C21' O2' 180(3) . .
C22A Au2 C21' C24' 149(3) . .
P2 Au2 C21' C24' -35(2) . .
C21A Au2 C21' C24' 78(2) . .
F9' Sb2 F8 F8 -175.6(12) . 2_454
F9' Sb2 F8 F8 32(8) 2_454 2_454
F7 Sb2 F8 F8 -170.8(16) . 2_454
F7 Sb2 F8 F8 11(2) 2_454 2_454
F7' Sb2 F8 F8 -170(2) . 2_454
F7' Sb2 F8 F8 7.8(16) 2_454 2_454
F9 Sb2 F8 F8 95.5(16) 2_454 2_454
F9 Sb2 F8 F8 -79.3(16) . 2_454
F8' Sb2 F8 F8 -84.6(16) . 2_454
F8' Sb2 F8 F8 101.9(16) 2_454 2_454
F7 Sb2 F9' F9' 177.1(16) . 2_454
F7 Sb2 F9' F9' -2.2(12) 2_454 2_454
F7' Sb2 F9' F9' 179.2(11) . 2_454
F7' Sb2 F9' F9' -1.1(15) 2_454 2_454
F9 Sb2 F9' F9' -94.4(11) 2_454 2_454
F9 Sb2 F9' F9' 92.2(11) . 2_454
F8 Sb2 F9' F9' 155(6) 2_454 2_454
F8 Sb2 F9' F9' -176.5(10) . 2_454
F8' Sb2 F9' F9' 84.2(11) . 2_454
F8' Sb2 F9' F9' -87.5(11) 2_454 2_454
