#------------------------------------------------------------------------------
#$Date: 2016-03-21 13:51:17 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178704 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/15/4081585.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4081585
loop_
_publ_author_name
'Jourdain, Isabelle'
'Knorr, Michael'
'Strohmann, Carsten'
'Unkelbach, Christian'
'Rojo, Saúl'
'Gómez-Iglesias, Patricia'
'Villafañe, Fernando'
_publ_section_title
;
 Reactivity of Silyl-Substituted Iron--Platinum Hydride Complexes toward
 Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into
 the Platinum--Hydride Bond. Synthesis and Reactivity of Heterobimetallic
 Dimetallacylopentenone, Dimetallacyclobutene, μ-Vinylidene, and
 μ2-σ-Alkenyl Complexes
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              5343
_journal_paper_doi               10.1021/om4006438
_journal_volume                  32
_journal_year                    2013
_chemical_formula_sum            'C57 H48 F2 Fe O3 P3 Pt'
_chemical_formula_weight         1162.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.567(2)
_cell_angle_beta                 94.030(2)
_cell_angle_gamma                103.667(2)
_cell_formula_units_Z            2
_cell_length_a                   12.2032(3)
_cell_length_b                   13.0292(3)
_cell_length_c                   16.1156(4)
_cell_measurement_temperature    173(2)
_cell_volume                     2345.79(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0449
_diffrn_reflns_av_sigmaI/netI    0.0493
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            43403
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         2.31
_exptl_absorpt_coefficient_mu    3.445
_exptl_absorpt_correction_T_max  0.5458
_exptl_absorpt_correction_T_min  0.3395
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrysAlis RED; Oxford Diffraction, 2009'
_exptl_crystal_density_diffrn    1.646
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1162
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.478
_refine_diff_density_min         -0.899
_refine_diff_density_rms         0.093
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     609
_refine_ls_number_reflns         10222
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0329
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0157P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0460
_refine_ls_wR_factor_ref         0.0466
_reflns_number_gt                8574
_reflns_number_total             10222
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om4006438_si_002.cif
_cod_data_source_block           3c
_cod_original_cell_volume        2345.79(10)
_cod_database_code               4081585
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.9180(2) -0.0704(2) 0.1305(2) 0.0210(7) Uani 1 1 d .
C2 C 0.9429(3) -0.2383(3) 0.1738(2) 0.0252(7) Uani 1 1 d .
C3 C 0.9754(2) -0.1065(2) 0.3378(2) 0.0216(7) Uani 1 1 d .
C4 C 0.8220(2) -0.0547(2) 0.27077(18) 0.0187(6) Uani 1 1 d .
C5 C 0.7204(3) -0.0993(2) 0.2873(2) 0.0202(7) Uani 1 1 d .
H5 H 0.671(2) -0.051(2) 0.3100(19) 0.033(9) Uiso 1 1 d .
C6 C 0.6625(2) -0.2168(2) 0.27291(18) 0.0188(6) Uani 1 1 d .
C7 C 0.7162(3) -0.3013(2) 0.2679(2) 0.0253(7) Uani 1 1 d .
H7 H 0.7971 -0.2827 0.2742 0.030 Uiso 1 1 calc R
C8 C 0.6564(3) -0.4115(2) 0.2539(2) 0.0288(8) Uani 1 1 d .
H8 H 0.6956 -0.4673 0.2501 0.035 Uiso 1 1 calc R
C9 C 0.5413(3) -0.4374(2) 0.2459(2) 0.0294(8) Uani 1 1 d .
C10 C 0.4824(3) -0.3594(2) 0.2507(2) 0.0337(8) Uani 1 1 d .
H10 H 0.4014 -0.3788 0.2444 0.040 Uiso 1 1 calc R
C11 C 0.5453(3) -0.2513(2) 0.2651(2) 0.0277(8) Uani 1 1 d .
C12 C 0.7729(2) 0.2422(2) 0.42182(18) 0.0160(6) Uani 1 1 d .
C13 C 0.7919(2) 0.1734(2) 0.46957(19) 0.0200(7) Uani 1 1 d .
H13 H 0.8270 0.1155 0.4454 0.024 Uiso 1 1 calc R
C14 C 0.7599(3) 0.1892(2) 0.5521(2) 0.0272(8) Uani 1 1 d .
H14 H 0.7733 0.1420 0.5843 0.033 Uiso 1 1 calc R
C15 C 0.7092(3) 0.2721(2) 0.5880(2) 0.0284(8) Uani 1 1 d .
H15 H 0.6868 0.2819 0.6445 0.034 Uiso 1 1 calc R
C16 C 0.6906(3) 0.3418(2) 0.5412(2) 0.0272(7) Uani 1 1 d .
H16 H 0.6558 0.3997 0.5659 0.033 Uiso 1 1 calc R
C17 C 0.7226(2) 0.3270(2) 0.45896(19) 0.0227(7) Uani 1 1 d .
H17 H 0.7101 0.3752 0.4274 0.027 Uiso 1 1 calc R
C18 C 0.6765(2) 0.1717(2) 0.23834(18) 0.0168(6) Uani 1 1 d .
C19 C 0.6397(2) 0.0638(2) 0.17889(18) 0.0203(7) Uani 1 1 d .
H19 H 0.6846 0.0131 0.1777 0.024 Uiso 1 1 calc R
C20 C 0.5386(3) 0.0289(2) 0.1213(2) 0.0261(7) Uani 1 1 d .
H20 H 0.5134 -0.0461 0.0824 0.031 Uiso 1 1 calc R
C21 C 0.4741(3) 0.1021(2) 0.1202(2) 0.0262(7) Uani 1 1 d .
H21 H 0.4058 0.0786 0.0793 0.031 Uiso 1 1 calc R
C22 C 0.5092(3) 0.2095(2) 0.1785(2) 0.0265(7) Uani 1 1 d .
H22 H 0.4650 0.2603 0.1777 0.032 Uiso 1 1 calc R
C23 C 0.6083(2) 0.2440(2) 0.2381(2) 0.0223(7) Uani 1 1 d .
H23 H 0.6303 0.3176 0.2794 0.027 Uiso 1 1 calc R
C24 C 0.8729(2) 0.3572(2) 0.30891(18) 0.0156(6) Uani 1 1 d .
C25 C 0.8554(2) 0.3824(2) 0.23194(19) 0.0197(7) Uani 1 1 d .
H25 H 0.8088 0.3263 0.1812 0.024 Uiso 1 1 calc R
C26 C 0.9043(3) 0.4873(2) 0.2280(2) 0.0237(7) Uani 1 1 d .
H26 H 0.8902 0.5038 0.1753 0.028 Uiso 1 1 calc R
C27 C 0.9741(2) 0.5685(2) 0.3015(2) 0.0234(7) Uani 1 1 d .
H27 H 1.0070 0.6414 0.2995 0.028 Uiso 1 1 calc R
C28 C 0.9958(2) 0.5442(2) 0.3768(2) 0.0227(7) Uani 1 1 d .
H28 H 1.0459 0.5994 0.4262 0.027 Uiso 1 1 calc R
C29 C 0.9450(2) 0.4392(2) 0.38134(19) 0.0196(7) Uani 1 1 d .
H29 H 0.9594 0.4233 0.4342 0.023 Uiso 1 1 calc R
C30 C 1.0978(2) 0.2962(2) 0.19558(18) 0.0157(6) Uani 1 1 d .
C31 C 1.0326(2) 0.2527(2) 0.11262(19) 0.0212(7) Uani 1 1 d .
H31 H 0.9878 0.1771 0.0920 0.025 Uiso 1 1 calc R
C32 C 1.0323(3) 0.3188(2) 0.0595(2) 0.0264(7) Uani 1 1 d .
H32 H 0.9882 0.2882 0.0024 0.032 Uiso 1 1 calc R
C33 C 1.0960(3) 0.4290(3) 0.0896(2) 0.0291(8) Uani 1 1 d .
H33 H 1.0972 0.4741 0.0528 0.035 Uiso 1 1 calc R
C34 C 1.1575(3) 0.4730(2) 0.1722(2) 0.0292(8) Uani 1 1 d .
H34 H 1.1992 0.5496 0.1934 0.035 Uiso 1 1 calc R
C35 C 1.1599(2) 0.4076(2) 0.2259(2) 0.0223(7) Uani 1 1 d .
H35 H 1.2039 0.4390 0.2830 0.027 Uiso 1 1 calc R
C36 C 1.1948(2) 0.2827(2) 0.35993(18) 0.0168(6) Uani 1 1 d .
C37 C 1.1543(2) 0.3074(2) 0.44004(18) 0.0209(7) Uani 1 1 d .
H37 H 1.0746 0.2864 0.4417 0.025 Uiso 1 1 calc R
C38 C 1.2307(3) 0.3629(2) 0.5179(2) 0.0263(7) Uani 1 1 d .
H38 H 1.2029 0.3808 0.5726 0.032 Uiso 1 1 calc R
C39 C 1.3458(3) 0.3919(2) 0.5162(2) 0.0282(8) Uani 1 1 d .
H39 H 1.3976 0.4284 0.5697 0.034 Uiso 1 1 calc R
C40 C 1.3865(3) 0.3678(2) 0.4366(2) 0.0277(8) Uani 1 1 d .
H40 H 1.4663 0.3882 0.4353 0.033 Uiso 1 1 calc R
C41 C 1.3113(2) 0.3142(2) 0.3588(2) 0.0227(7) Uani 1 1 d .
H41 H 1.3396 0.2988 0.3042 0.027 Uiso 1 1 calc R
C42 C 1.1657(2) 0.1042(2) 0.19427(18) 0.0164(6) Uani 1 1 d .
H42A H 1.1359 0.0836 0.1310 0.020 Uiso 1 1 calc R
H42B H 1.2484 0.1413 0.2033 0.020 Uiso 1 1 calc R
C43 C 1.2502(2) 0.0234(2) 0.32410(18) 0.0172(6) Uani 1 1 d .
C44 C 1.2185(3) 0.0639(2) 0.40651(18) 0.0194(7) Uani 1 1 d .
H44 H 1.1414 0.0646 0.4107 0.023 Uiso 1 1 calc R
C45 C 1.2977(3) 0.1032(2) 0.4825(2) 0.0253(7) Uani 1 1 d .
H45 H 1.2751 0.1304 0.5384 0.030 Uiso 1 1 calc R
C46 C 1.4089(3) 0.1024(2) 0.4765(2) 0.0304(8) Uani 1 1 d .
H46 H 1.4633 0.1287 0.5286 0.036 Uiso 1 1 calc R
C47 C 1.4428(3) 0.0639(2) 0.3958(2) 0.0309(8) Uani 1 1 d .
H47 H 1.5202 0.0639 0.3924 0.037 Uiso 1 1 calc R
C48 C 1.3642(3) 0.0252(2) 0.3196(2) 0.0247(7) Uani 1 1 d .
H48 H 1.3881 -0.0002 0.2640 0.030 Uiso 1 1 calc R
C49 C 1.2052(2) -0.1129(2) 0.14202(18) 0.0164(6) Uani 1 1 d .
C50 C 1.2199(2) -0.0990(2) 0.06140(19) 0.0204(7) Uani 1 1 d .
H50 H 1.2010 -0.0381 0.0487 0.024 Uiso 1 1 calc R
C51 C 1.2616(3) -0.1725(2) -0.00096(19) 0.0261(7) Uani 1 1 d .
H51 H 1.2712 -0.1615 -0.0560 0.031 Uiso 1 1 calc R
C52 C 1.2893(3) -0.2608(2) 0.0158(2) 0.0277(8) Uani 1 1 d .
H52 H 1.3189 -0.3106 -0.0269 0.033 Uiso 1 1 calc R
C53 C 1.2739(3) -0.2767(2) 0.0947(2) 0.0313(8) Uani 1 1 d .
H53 H 1.2922 -0.3383 0.1065 0.038 Uiso 1 1 calc R
C54 C 1.2319(3) -0.2042(2) 0.1573(2) 0.0282(8) Uani 1 1 d .
H54 H 1.2211 -0.2168 0.2116 0.034 Uiso 1 1 calc R
C55 C 0.5023(5) 0.5491(4) 0.0056(4) 0.088(2) Uani 1 1 d .
H55A H 0.4777 0.5842 0.0621 0.106 Uiso 1 1 calc R
H55B H 0.4542 0.5569 -0.0431 0.106 Uiso 1 1 calc R
C56 C 0.6171(10) 0.5957(6) 0.0064(6) 0.167(4) Uani 1 1 d .
H56A H 0.6642 0.5886 0.0558 0.201 Uiso 1 1 calc R
H56B H 0.6415 0.5580 -0.0495 0.201 Uiso 1 1 calc R
C57 C 0.6270(10) 0.6970(8) 0.0155(7) 0.246(6) Uani 1 1 d .
H57A H 0.5856 0.7026 -0.0366 0.368 Uiso 1 1 calc R
H57B H 0.7079 0.7363 0.0223 0.368 Uiso 1 1 calc R
H57C H 0.5952 0.7309 0.0679 0.368 Uiso 1 1 calc R
F1 F 0.48611(15) -0.17438(14) 0.26946(15) 0.0508(6) Uani 1 1 d .
F2 F 0.48059(16) -0.54371(14) 0.23461(15) 0.0522(6) Uani 1 1 d .
Fe Fe 0.96146(3) -0.09512(3) 0.22970(3) 0.01571(9) Uani 1 1 d .
O1 O 0.8895(2) -0.05936(17) 0.06520(14) 0.0357(6) Uani 1 1 d .
O2 O 0.9321(2) -0.33046(17) 0.13433(14) 0.0427(7) Uani 1 1 d .
O3 O 0.97665(19) -0.11924(18) 0.40532(14) 0.0348(6) Uani 1 1 d .
P1 P 0.81283(6) 0.21588(6) 0.31153(5) 0.01518(16) Uani 1 1 d .
P2 P 1.09284(6) 0.20207(6) 0.26013(5) 0.01544(16) Uani 1 1 d .
P3 P 1.14403(6) -0.02257(6) 0.22529(5) 0.01546(16) Uani 1 1 d .
Pt Pt 0.921305(10) 0.095144(9) 0.276860(8) 0.01505(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
O1 C1 Fe 177.0(2) .
O2 C2 Fe 177.2(3) .
O3 C3 Fe 175.0(3) .
C5 C4 Fe 141.5(2) .
C5 C4 Pt 139.7(2) .
Fe C4 Pt 78.73(10) .
C4 C5 C6 129.6(3) .
C11 C6 C7 114.3(3) .
C11 C6 C5 120.2(3) .
C7 C6 C5 125.5(3) .
C8 C7 C6 122.8(3) .
C9 C8 C7 118.5(3) .
C8 C9 F2 120.0(3) .
C8 C9 C10 122.3(3) .
F2 C9 C10 117.7(3) .
C9 C10 C11 117.1(3) .
F1 C11 C10 116.7(3) .
F1 C11 C6 118.2(3) .
C10 C11 C6 125.0(3) .
C17 C12 C13 118.9(3) .
C17 C12 P1 122.4(2) .
C13 C12 P1 118.7(2) .
C14 C13 C12 120.1(3) .
C15 C14 C13 120.7(3) .
C14 C15 C16 119.6(3) .
C17 C16 C15 120.1(3) .
C16 C17 C12 120.5(3) .
C19 C18 C23 117.9(3) .
C19 C18 P1 119.7(2) .
C23 C18 P1 122.4(2) .
C20 C19 C18 121.0(3) .
C21 C20 C19 120.3(3) .
C22 C21 C20 119.6(3) .
C21 C22 C23 120.4(3) .
C22 C23 C18 120.7(3) .
C25 C24 C29 118.4(2) .
C25 C24 P1 120.5(2) .
C29 C24 P1 120.8(2) .
C26 C25 C24 121.1(3) .
C25 C26 C27 119.5(3) .
C28 C27 C26 120.3(3) .
C27 C28 C29 120.3(3) .
C28 C29 C24 120.3(3) .
C35 C30 C31 119.2(2) .
C35 C30 P2 123.7(2) .
C31 C30 P2 117.0(2) .
C32 C31 C30 120.4(3) .
C33 C32 C31 120.0(3) .
C34 C33 C32 119.7(3) .
C33 C34 C35 121.1(3) .
C30 C35 C34 119.6(3) .
C41 C36 C37 119.3(3) .
C41 C36 P2 122.2(2) .
C37 C36 P2 118.4(2) .
C36 C37 C38 119.8(3) .
C39 C38 C37 120.5(3) .
C38 C39 C40 119.9(3) .
C41 C40 C39 120.1(3) .
C40 C41 C36 120.4(3) .
P3 C42 P2 111.18(14) .
C44 C43 C48 118.4(3) .
C44 C43 P3 119.5(2) .
C48 C43 P3 122.0(2) .
C45 C44 C43 121.0(3) .
C46 C45 C44 119.5(3) .
C45 C46 C47 120.7(3) .
C46 C47 C48 120.0(3) .
C47 C48 C43 120.4(3) .
C50 C49 C54 117.7(3) .
C50 C49 P3 123.1(2) .
C54 C49 P3 119.1(2) .
C51 C50 C49 121.0(3) .
C52 C51 C50 120.5(3) .
C53 C52 C51 119.3(3) .
C52 C53 C54 120.7(3) .
C53 C54 C49 120.8(3) .
C55 C55 C56 102.5(7) 2_665
C57 C56 C55 105.6(12) .
C2 Fe C3 95.22(13) .
C2 Fe C1 92.32(13) .
C3 Fe C1 165.58(13) .
C2 Fe C4 115.21(13) .
C3 Fe C4 79.39(12) .
C1 Fe C4 86.28(12) .
C2 Fe P3 102.03(10) .
C3 Fe P3 98.92(9) .
C1 Fe P3 91.48(9) .
C4 Fe P3 142.75(8) .
C2 Fe Pt 159.83(10) .
C3 Fe Pt 95.82(9) .
C1 Fe Pt 73.58(9) .
C4 Fe Pt 50.89(8) .
P3 Fe Pt 92.88(2) .
C24 P1 C12 102.52(12) .
C24 P1 C18 102.11(12) .
C12 P1 C18 104.10(13) .
C24 P1 Pt 117.12(9) .
C12 P1 Pt 115.06(9) .
C18 P1 Pt 114.11(9) .
C36 P2 C30 105.09(12) .
C36 P2 C42 104.46(13) .
C30 P2 C42 99.99(12) .
C36 P2 Pt 116.90(9) .
C30 P2 Pt 121.16(9) .
C42 P2 Pt 106.74(9) .
C43 P3 C49 103.37(13) .
C43 P3 C42 101.97(12) .
C49 P3 C42 102.93(12) .
C43 P3 Fe 120.36(9) .
C49 P3 Fe 114.29(9) .
C42 P3 Fe 111.85(9) .
C4 Pt P1 106.24(8) .
C4 Pt P2 149.40(8) .
P1 Pt P2 104.30(3) .
C4 Pt Fe 50.39(8) .
P1 Pt Fe 156.07(2) .
P2 Pt Fe 99.02(2) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.145(3) .
C1 Fe 1.793(3) .
C2 O2 1.147(3) .
C2 Fe 1.761(3) .
C3 O3 1.148(3) .
C3 Fe 1.793(3) .
C4 C5 1.322(4) .
C4 Fe 1.995(3) .
C4 Pt 2.010(3) .
C5 C6 1.466(4) .
C6 C11 1.379(4) .
C6 C7 1.393(4) .
C7 C8 1.390(4) .
C8 C9 1.352(4) .
C9 F2 1.358(3) .
C9 C10 1.365(4) .
C10 C11 1.375(4) .
C11 F1 1.356(3) .
C12 C17 1.389(4) .
C12 C13 1.393(4) .
C12 P1 1.830(3) .
C13 C14 1.382(4) .
C14 C15 1.369(4) .
C15 C16 1.389(4) .
C16 C17 1.378(4) .
C18 C19 1.387(4) .
C18 C23 1.397(4) .
C18 P1 1.831(3) .
C19 C20 1.381(4) .
C20 C21 1.375(4) .
C21 C22 1.375(4) .
C22 C23 1.381(4) .
C24 C25 1.391(4) .
C24 C29 1.391(4) .
C24 P1 1.829(3) .
C25 C26 1.379(4) .
C26 C27 1.387(4) .
C27 C28 1.368(4) .
C28 C29 1.389(4) .
C30 C35 1.385(4) .
C30 C31 1.386(4) .
C30 P2 1.826(3) .
C31 C32 1.385(4) .
C32 C33 1.379(4) .
C33 C34 1.363(4) .
C34 C35 1.390(4) .
C36 C41 1.386(4) .
C36 C37 1.389(4) .
C36 P2 1.822(3) .
C37 C38 1.391(4) .
C38 C39 1.369(4) .
C39 C40 1.383(4) .
C40 C41 1.381(4) .
C42 P3 1.833(3) .
C42 P2 1.842(3) .
C43 C44 1.392(4) .
C43 C48 1.393(4) .
C43 P3 1.828(3) .
C44 C45 1.385(4) .
C45 C46 1.370(4) .
C46 C47 1.376(4) .
C47 C48 1.384(4) .
C49 C50 1.383(4) .
C49 C54 1.390(4) .
C49 P3 1.829(3) .
C50 C51 1.381(4) .
C51 C52 1.368(4) .
C52 C53 1.367(4) .
C53 C54 1.378(4) .
C55 C55 1.225(10) 2_665
C55 C56 1.387(12) .
C56 C57 1.258(10) .
Fe P3 2.2203(8) .
Fe Pt 2.5401(4) .
P1 Pt 2.2575(7) .
P2 Pt 2.3073(7) .
