#------------------------------------------------------------------------------
#$Date: 2016-03-21 14:55:58 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178730 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/41/4084133.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4084133
loop_
_publ_author_name
'Carmona, Daniel'
'Lamata, Pilar'
'Sánchez, Antonio'
'Pardo, Pilar'
'Rodríguez, Ricardo'
'Ramírez, Paola'
'Lahoz, Fernando J.'
'García-Orduña, Pilar'
'Oro, Luis A.'
_publ_section_title
;
 Chiral Brønsted Acid Catalysts. Activation of Methyl
 3,3,3-Trifluoropyruvate by Hydroxymethylpyridine-Containing Half-Sandwich
 Complexes
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              4016
_journal_paper_doi               10.1021/om5005463
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C32 H42 N2 O2 Rh2, 2(F6 Sb)'
_chemical_formula_sum            'C32 H42 F12 N2 O2 Rh2 Sb2'
_chemical_formula_weight         1164.02
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.120(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.8663(16)
_cell_length_b                   21.996(3)
_cell_length_c                   17.198(3)
_cell_measurement_reflns_used    3957
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      22.81
_cell_measurement_theta_min      2.22
_cell_volume                     3968.3(11)
_computing_cell_refinement       'SAINT+ v. 6.45 (Bruker AXS, 2003)'
_computing_data_collection       'SMART v. 5.611 (Bruker AXS, 2000)'
_computing_data_reduction        'SAINT+ v. 6.45 (Bruker AXS, 2003)'
_computing_molecular_graphics    'XP program, SHELXTL v6.12, Bruker2000'
_computing_publication_material  'XCIF program, SHELXTLv6.12, BrukerAXS'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX CCD system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0451
_diffrn_reflns_av_sigmaI/netI    0.0322
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            20453
_diffrn_reflns_theta_full        25.32
_diffrn_reflns_theta_max         25.32
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    2.252
_exptl_absorpt_correction_T_max  0.866
_exptl_absorpt_correction_T_min  0.705
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 SADABS: Area-Detector Absorption Correction. (1996)  Bruker-AXS 
 within SAINT+ package, v. 6.45.                    
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.948
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2256
_exptl_crystal_size_max          0.202
_exptl_crystal_size_mid          0.092
_exptl_crystal_size_min          0.064
_refine_diff_density_max         1.353
_refine_diff_density_min         -0.760
_refine_diff_density_rms         0.119
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     256
_refine_ls_number_reflns         3616
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0485
_refine_ls_R_factor_gt           0.0400
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0441P)²+21.6069P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0913
_refine_ls_wR_factor_ref         0.0951
_reflns_number_gt                3104
_reflns_number_total             3616
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5005463_si_002.cif
_cod_data_source_block           cmpnd_8a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4084133--4084136.cif.
;
_cod_original_cell_volume        3968.2(10)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4084133
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh Rh 0.05229(4) 0.121232(18) 0.16795(2) 0.02663(13) Uani 1 1 d .
O1 O -0.1180(3) 0.12265(15) 0.2040(2) 0.0288(8) Uani 1 1 d .
N1 N 0.0043(4) 0.21338(19) 0.1585(3) 0.0308(10) Uani 1 1 d .
C1 C 0.1362(5) 0.0344(3) 0.1526(3) 0.0364(13) Uani 1 1 d .
C2 C 0.0136(5) 0.0399(3) 0.0973(3) 0.0368(13) Uani 1 1 d .
C3 C 0.0161(5) 0.0920(3) 0.0472(3) 0.0354(12) Uani 1 1 d .
C4 C 0.1421(6) 0.1169(3) 0.0699(3) 0.0393(14) Uani 1 1 d .
C5 C 0.2151(5) 0.0830(3) 0.1362(3) 0.0369(13) Uani 1 1 d .
C6 C 0.1810(7) -0.0126(3) 0.2154(4) 0.0494(16) Uani 1 1 d .
H6A H 0.2260 0.0070 0.2660 0.045(17) Uiso 1 1 calc R
H6B H 0.2389 -0.0406 0.1982 0.055(18) Uiso 1 1 calc R
H6C H 0.1076 -0.0352 0.2235 0.045(17) Uiso 1 1 calc R
C7 C -0.1010(6) 0.0011(3) 0.0924(4) 0.0467(16) Uani 1 1 d .
H7A H -0.0770 -0.0340 0.1283 0.054(19) Uiso 1 1 calc R
H7B H -0.1350 -0.0130 0.0369 0.041(16) Uiso 1 1 calc R
H7C H -0.1662 0.0249 0.1088 0.06(2) Uiso 1 1 calc R
C8 C -0.0943(6) 0.1131(3) -0.0196(4) 0.0525(17) Uani 1 1 d .
H8A H -0.1735 0.0959 -0.0119 0.06(2) Uiso 1 1 calc R
H8B H -0.0824 0.0995 -0.0714 0.07(2) Uiso 1 1 calc R
H8C H -0.0990 0.1575 -0.0189 0.07(2) Uiso 1 1 calc R
C9 C 0.1900(7) 0.1685(3) 0.0284(4) 0.0523(17) Uani 1 1 d .
H9A H 0.1208 0.1976 0.0080 0.029(14) Uiso 1 1 calc R
H9B H 0.2200 0.1526 -0.0167 0.058(19) Uiso 1 1 calc R
H9C H 0.2606 0.1890 0.0667 0.06(2) Uiso 1 1 calc R
C10 C 0.3511(6) 0.0939(3) 0.1819(4) 0.0486(16) Uani 1 1 d .
H10A H 0.3755 0.1356 0.1722 0.038(16) Uiso 1 1 calc R
H10B H 0.4065 0.0651 0.1637 0.10(3) Uiso 1 1 calc R
H10C H 0.3600 0.0882 0.2396 0.029(14) Uiso 1 1 calc R
C11 C 0.0808(6) 0.2599(2) 0.1500(3) 0.0377(13) Uani 1 1 d .
H11 H 0.1683 0.2519 0.1543 0.022(13) Uiso 1 1 calc R
C12 C 0.0360(7) 0.3189(3) 0.1351(4) 0.0565(18) Uani 1 1 d .
H12 H 0.0917 0.3508 0.1289 0.07(2) Uiso 1 1 calc R
C13 C -0.0903(7) 0.3304(3) 0.1294(5) 0.0612(19) Uani 1 1 d .
H13 H -0.1232 0.3704 0.1189 0.07(2) Uiso 1 1 calc R
C14 C -0.1694(6) 0.2828(3) 0.1391(4) 0.0508(16) Uani 1 1 d .
H14 H -0.2567 0.2903 0.1358 0.07(2) Uiso 1 1 calc R
C15 C -0.1206(5) 0.2246(3) 0.1536(3) 0.0351(12) Uani 1 1 d .
C16 C -0.1966(5) 0.1703(3) 0.1649(3) 0.0363(13) Uani 1 1 d .
H16A H -0.2563 0.1819 0.1970 0.041(16) Uiso 1 1 calc R
H16B H -0.2476 0.1560 0.1116 0.043(16) Uiso 1 1 calc R
Sb1 Sb 0.5000 0.0000 0.0000 0.03409(15) Uani 1 2 d S
F1 F 0.5895(4) 0.04804(19) 0.0861(2) 0.0657(11) Uani 1 1 d .
F2 F 0.3931(3) -0.02838(16) 0.0623(2) 0.0551(10) Uani 1 1 d .
F3 F 0.6137(4) -0.06388(17) 0.0356(3) 0.0640(11) Uani 1 1 d .
Sb2 Sb 0.5000 0.30109(2) 0.2500 0.04560(18) Uani 1 2 d S
F4 F 0.3692(8) 0.2484(4) 0.2332(6) 0.072(3) Uiso 0.530(7) 1 d P
F5 F 0.5347(8) 0.2619(4) 0.1517(5) 0.077(3) Uiso 0.530(7) 1 d P
F6 F 0.4081(8) 0.3581(4) 0.1746(5) 0.077(3) Uiso 0.530(7) 1 d P
F4B F 0.3913(9) 0.2436(4) 0.1902(6) 0.068(3) Uiso 0.470(7) 1 d P
F5B F 0.5284(10) 0.3405(5) 0.1712(6) 0.082(3) Uiso 0.470(7) 1 d P
F6B F 0.3510(10) 0.3476(5) 0.2548(7) 0.087(3) Uiso 0.470(7) 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0170 0.0100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1180 0.9190 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5870 1.5460 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Rh O1 77.71(15) . .
N1 Rh C3 103.93(19) . .
O1 Rh C3 110.04(18) . .
N1 Rh O1 94.35(15) . 2
O1 Rh O1 77.18(14) . 2
C3 Rh O1 161.34(18) . 2
N1 Rh C2 139.3(2) . .
O1 Rh C2 97.01(17) . .
C3 Rh C2 39.5(2) . .
O1 Rh C2 124.16(18) 2 .
N1 Rh C5 124.3(2) . .
O1 Rh C5 157.86(19) . .
C3 Rh C5 65.6(2) . .
O1 Rh C5 101.04(18) 2 .
C2 Rh C5 65.4(2) . .
N1 Rh C4 97.82(19) . .
O1 Rh C4 147.55(19) . .
C3 Rh C4 39.2(2) . .
O1 Rh C4 135.22(19) 2 .
C2 Rh C4 65.3(2) . .
C5 Rh C4 38.4(2) . .
N1 Rh C1 162.25(19) . .
O1 Rh C1 118.79(18) . .
C3 Rh C1 65.6(2) . .
O1 Rh C1 95.80(17) 2 .
C2 Rh C1 38.7(2) . .
C5 Rh C1 39.1(2) . .
C4 Rh C1 64.8(2) . .
C16 O1 Rh 110.0(3) . .
C16 O1 Rh 120.2(3) . 2
Rh O1 Rh 102.79(14) . 2
C11 N1 C15 119.2(5) . .
C11 N1 Rh 126.5(4) . .
C15 N1 Rh 114.0(3) . .
C2 C1 C5 107.9(5) . .
C2 C1 C6 128.0(6) . .
C5 C1 C6 124.0(5) . .
C2 C1 Rh 69.9(3) . .
C5 C1 Rh 70.1(3) . .
C6 C1 Rh 126.5(4) . .
C1 C2 C3 107.8(5) . .
C1 C2 C7 127.6(6) . .
C3 C2 C7 124.5(5) . .
C1 C2 Rh 71.4(3) . .
C3 C2 Rh 69.0(3) . .
C7 C2 Rh 123.1(4) . .
C4 C3 C2 108.0(5) . .
C4 C3 C8 127.4(6) . .
C2 C3 C8 124.6(5) . .
C4 C3 Rh 72.2(3) . .
C2 C3 Rh 71.4(3) . .
C8 C3 Rh 124.4(4) . .
C5 C4 C3 108.2(5) . .
C5 C4 C9 126.0(6) . .
C3 C4 C9 125.8(6) . .
C5 C4 Rh 70.6(3) . .
C3 C4 Rh 68.6(3) . .
C9 C4 Rh 128.4(4) . .
C4 C5 C1 108.0(5) . .
C4 C5 C10 127.2(6) . .
C1 C5 C10 124.8(6) . .
C4 C5 Rh 71.0(3) . .
C1 C5 Rh 70.8(3) . .
C10 C5 Rh 124.6(4) . .
C1 C6 H6A 109.5 . .
C1 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C1 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C2 C7 H7A 109.5 . .
C2 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C2 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C3 C8 H8A 109.5 . .
C3 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C3 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C4 C9 H9A 109.5 . .
C4 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C4 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C5 C10 H10A 109.5 . .
C5 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C5 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N1 C11 C12 122.2(6) . .
N1 C11 H11 118.9 . .
C12 C11 H11 118.9 . .
C13 C12 C11 118.8(6) . .
C13 C12 H12 120.6 . .
C11 C12 H12 120.6 . .
C12 C13 C14 119.4(6) . .
C12 C13 H13 120.3 . .
C14 C13 H13 120.3 . .
C15 C14 C13 119.8(6) . .
C15 C14 H14 120.1 . .
C13 C14 H14 120.1 . .
N1 C15 C14 120.6(5) . .
N1 C15 C16 115.0(5) . .
C14 C15 C16 124.4(5) . .
O1 C16 C15 111.8(4) . .
O1 C16 H16A 109.3 . .
C15 C16 H16A 109.3 . .
O1 C16 H16B 109.3 . .
C15 C16 H16B 109.3 . .
H16A C16 H16B 107.9 . .
F3 Sb1 F3 180.0(4) . 5_655
F3 Sb1 F1 90.17(19) . .
F3 Sb1 F1 89.83(19) 5_655 .
F3 Sb1 F1 89.83(19) . 5_655
F3 Sb1 F1 90.17(19) 5_655 5_655
F1 Sb1 F1 180.0(4) . 5_655
F3 Sb1 F2 91.04(16) . .
F3 Sb1 F2 88.96(16) 5_655 .
F1 Sb1 F2 90.43(17) . .
F1 Sb1 F2 89.57(17) 5_655 .
F3 Sb1 F2 88.96(16) . 5_655
F3 Sb1 F2 91.04(16) 5_655 5_655
F1 Sb1 F2 89.57(17) . 5_655
F1 Sb1 F2 90.43(17) 5_655 5_655
F2 Sb1 F2 180.0(3) . 5_655
F5B Sb2 F5B 118.9(7) 2_655 .
F5B Sb2 F4 120.0(5) 2_655 2_655
F5B Sb2 F4 99.0(5) . 2_655
F5B Sb2 F4 99.0(5) 2_655 .
F5B Sb2 F4 120.0(5) . .
F4 Sb2 F4 99.7(6) 2_655 .
F5B Sb2 F4B 97.3(5) 2_655 2_655
F5B Sb2 F4B 124.7(5) . 2_655
F4 Sb2 F4B 26.6(3) 2_655 2_655
F4 Sb2 F4B 90.7(3) . 2_655
F5B Sb2 F4B 124.7(5) 2_655 .
F5B Sb2 F4B 97.3(5) . .
F4 Sb2 F4B 90.7(3) 2_655 .
F4 Sb2 F4B 26.6(3) . .
F4B Sb2 F4B 93.7(6) 2_655 .
F5B Sb2 F6 44.7(4) 2_655 2_655
F5B Sb2 F6 92.0(4) . 2_655
F4 Sb2 F6 93.7(4) 2_655 2_655
F4 Sb2 F6 142.3(4) . 2_655
F4B Sb2 F6 85.7(4) 2_655 2_655
F4B Sb2 F6 169.0(4) . 2_655
F5B Sb2 F6 92.0(4) 2_655 .
F5B Sb2 F6 44.7(4) . .
F4 Sb2 F6 142.3(4) 2_655 .
F4 Sb2 F6 93.7(4) . .
F4B Sb2 F6 169.0(4) 2_655 .
F4B Sb2 F6 85.7(4) . .
F6 Sb2 F6 96.9(5) 2_655 .
F5B Sb2 F6B 50.9(5) 2_655 .
F5B Sb2 F6B 95.3(5) . .
F4 Sb2 F6B 165.7(5) 2_655 .
F4 Sb2 F6B 73.3(4) . .
F4B Sb2 F6B 139.3(5) 2_655 .
F4B Sb2 F6B 88.0(4) . .
F6 Sb2 F6B 85.3(4) 2_655 .
F6 Sb2 F6B 51.7(4) . .
F5B Sb2 F6B 95.3(5) 2_655 2_655
F5B Sb2 F6B 50.9(5) . 2_655
F4 Sb2 F6B 73.3(4) 2_655 2_655
F4 Sb2 F6B 165.7(5) . 2_655
F4B Sb2 F6B 88.0(4) 2_655 2_655
F4B Sb2 F6B 139.3(5) . 2_655
F6 Sb2 F6B 51.7(4) 2_655 2_655
F6 Sb2 F6B 85.3(4) . 2_655
F6B Sb2 F6B 116.1(6) . 2_655
F5B Sb2 F5 55.9(4) 2_655 2_655
F5B Sb2 F5 174.7(4) . 2_655
F4 Sb2 F5 84.4(4) 2_655 2_655
F4 Sb2 F5 63.0(4) . 2_655
F4B Sb2 F5 58.2(4) 2_655 2_655
F4B Sb2 F5 86.7(4) . 2_655
F6 Sb2 F5 83.7(4) 2_655 2_655
F6 Sb2 F5 132.6(4) . 2_655
F6B Sb2 F5 81.3(4) . 2_655
F6B Sb2 F5 127.1(4) 2_655 2_655
F5B Sb2 F5 174.7(4) 2_655 .
F5B Sb2 F5 55.9(4) . .
F4 Sb2 F5 63.0(4) 2_655 .
F4 Sb2 F5 84.4(4) . .
F4B Sb2 F5 86.7(4) 2_655 .
F4B Sb2 F5 58.2(4) . .
F6 Sb2 F5 132.6(4) 2_655 .
F6 Sb2 F5 83.7(4) . .
F6B Sb2 F5 127.1(4) . .
F6B Sb2 F5 81.3(4) 2_655 .
F5 Sb2 F5 129.4(5) 2_655 .
F4B F4 Sb2 80.1(10) . .
F5B F5 Sb2 53.0(4) . .
F5B F6 F6B 123.8(8) . .
F5B F6 Sb2 60.4(5) . .
F6B F6 Sb2 65.5(5) . .
F4 F4B Sb2 73.3(10) . .
F6 F5B F6B 122.3(9) . 2_655
F6 F5B Sb2 74.9(6) . .
F6B F5B Sb2 72.2(6) 2_655 .
F6 F5B F5 111.6(8) . .
F6B F5B F5 100.7(7) 2_655 .
Sb2 F5B F5 71.1(5) . .
F5B F6B F6 105.7(8) 2_655 .
F5B F6B Sb2 56.9(5) 2_655 .
F6 F6B Sb2 62.8(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh N1 2.089(4) .
Rh O1 2.099(3) .
Rh C3 2.111(5) .
Rh O1 2.131(3) 2
Rh C2 2.143(5) .
Rh C5 2.153(5) .
Rh C4 2.159(5) .
Rh C1 2.162(5) .
O1 C16 1.407(6) .
O1 Rh 2.131(3) 2
N1 C11 1.350(7) .
N1 C15 1.360(7) .
C1 C2 1.425(8) .
C1 C5 1.443(8) .
C1 C6 1.483(8) .
C2 C3 1.439(8) .
C2 C7 1.493(8) .
C3 C4 1.431(8) .
C3 C8 1.502(8) .
C4 C5 1.419(8) .
C4 C9 1.504(8) .
C5 C10 1.501(8) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C12 1.386(8) .
C11 H11 0.9500 .
C12 C13 1.373(9) .
C12 H12 0.9500 .
C13 C14 1.392(9) .
C13 H13 0.9500 .
C14 C15 1.384(8) .
C14 H14 0.9500 .
C15 C16 1.494(8) .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
Sb1 F3 1.866(4) .
Sb1 F3 1.866(4) 5_655
Sb1 F1 1.871(4) .
Sb1 F1 1.871(4) 5_655
Sb1 F2 1.881(3) .
Sb1 F2 1.881(3) 5_655
Sb2 F5B 1.704(10) 2_655
Sb2 F5B 1.704(10) .
Sb2 F4 1.798(9) 2_655
Sb2 F4 1.798(9) .
Sb2 F4B 1.849(10) 2_655
Sb2 F4B 1.849(10) .
Sb2 F6 1.892(9) 2_655
Sb2 F6 1.892(9) .
Sb2 F6B 1.936(11) .
Sb2 F6B 1.936(11) 2_655
Sb2 F5 2.019(9) 2_655
Sb2 F5 2.019(9) .
F4 F4B 0.842(10) .
F5 F5B 1.766(14) .
F6 F5B 1.380(12) .
F6 F6B 1.671(13) .
F5B F6B 1.579(14) 2_655
F6B F5B 1.579(14) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Rh O1 C16 30.0(3) . .
C3 Rh O1 C16 -70.5(4) . .
O1 Rh O1 C16 127.4(3) 2 .
C2 Rh O1 C16 -109.0(4) . .
C5 Rh O1 C16 -144.7(5) . .
C4 Rh O1 C16 -55.2(5) . .
C1 Rh O1 C16 -142.9(3) . .
N1 Rh O1 Rh -99.14(17) . 2
C3 Rh O1 Rh 160.33(18) . 2
O1 Rh O1 Rh -1.71(18) 2 2
C2 Rh O1 Rh 121.81(19) . 2
C5 Rh O1 Rh 86.1(5) . 2
C4 Rh O1 Rh 175.6(3) . 2
C1 Rh O1 Rh 87.9(2) . 2
O1 Rh N1 C11 166.3(5) . .
C3 Rh N1 C11 -85.8(5) . .
O1 Rh N1 C11 90.4(4) 2 .
C2 Rh N1 C11 -107.2(5) . .
C5 Rh N1 C11 -16.1(5) . .
C4 Rh N1 C11 -46.4(5) . .
C1 Rh N1 C11 -34.3(9) . .
O1 Rh N1 C15 -19.8(3) . .
C3 Rh N1 C15 88.1(4) . .
O1 Rh N1 C15 -95.7(4) 2 .
C2 Rh N1 C15 66.7(5) . .
C5 Rh N1 C15 157.8(4) . .
C4 Rh N1 C15 127.5(4) . .
C1 Rh N1 C15 139.6(6) . .
N1 Rh C1 C2 -94.5(7) . .
O1 Rh C1 C2 62.4(4) . .
C3 Rh C1 C2 -38.0(3) . .
O1 Rh C1 C2 140.9(3) 2 .
C5 Rh C1 C2 -118.7(5) . .
C4 Rh C1 C2 -81.3(4) . .
N1 Rh C1 C5 24.2(8) . .
O1 Rh C1 C5 -178.9(3) . .
C3 Rh C1 C5 80.7(3) . .
O1 Rh C1 C5 -100.4(3) 2 .
C2 Rh C1 C5 118.7(5) . .
C4 Rh C1 C5 37.4(3) . .
N1 Rh C1 C6 142.4(6) . .
O1 Rh C1 C6 -60.7(6) . .
C3 Rh C1 C6 -161.1(6) . .
O1 Rh C1 C6 17.8(5) 2 .
C2 Rh C1 C6 -123.1(7) . .
C5 Rh C1 C6 118.2(7) . .
C4 Rh C1 C6 155.6(6) . .
C5 C1 C2 C3 -0.4(6) . .
C6 C1 C2 C3 -179.0(5) . .
Rh C1 C2 C3 59.7(4) . .
C5 C1 C2 C7 -178.0(5) . .
C6 C1 C2 C7 3.4(9) . .
Rh C1 C2 C7 -117.9(6) . .
C5 C1 C2 Rh -60.1(4) . .
C6 C1 C2 Rh 121.3(6) . .
N1 Rh C2 C1 152.2(3) . .
O1 Rh C2 C1 -128.5(3) . .
C3 Rh C2 C1 118.3(5) . .
O1 Rh C2 C1 -49.3(4) 2 .
C5 Rh C2 C1 37.5(3) . .
C4 Rh C2 C1 79.9(4) . .
N1 Rh C2 C3 33.9(5) . .
O1 Rh C2 C3 113.2(3) . .
O1 Rh C2 C3 -167.6(3) 2 .
C5 Rh C2 C3 -80.8(4) . .
C4 Rh C2 C3 -38.4(3) . .
C1 Rh C2 C3 -118.3(5) . .
N1 Rh C2 C7 -84.5(6) . .
O1 Rh C2 C7 -5.2(5) . .
C3 Rh C2 C7 -118.4(6) . .
O1 Rh C2 C7 74.0(5) 2 .
C5 Rh C2 C7 160.8(6) . .
C4 Rh C2 C7 -156.7(6) . .
C1 Rh C2 C7 123.3(7) . .
C1 C2 C3 C4 2.2(6) . .
C7 C2 C3 C4 179.9(5) . .
Rh C2 C3 C4 63.4(4) . .
C1 C2 C3 C8 179.4(5) . .
C7 C2 C3 C8 -2.9(8) . .
Rh C2 C3 C8 -119.4(5) . .
C1 C2 C3 Rh -61.2(4) . .
C7 C2 C3 Rh 116.5(5) . .
N1 Rh C3 C4 85.3(3) . .
O1 Rh C3 C4 167.1(3) . .
O1 Rh C3 C4 -82.9(7) 2 .
C2 Rh C3 C4 -116.7(5) . .
C5 Rh C3 C4 -36.4(3) . .
C1 Rh C3 C4 -79.5(4) . .
N1 Rh C3 C2 -158.0(3) . .
O1 Rh C3 C2 -76.2(3) . .
O1 Rh C3 C2 33.8(7) 2 .
C5 Rh C3 C2 80.3(4) . .
C4 Rh C3 C2 116.7(5) . .
C1 Rh C3 C2 37.2(3) . .
N1 Rh C3 C8 -38.3(6) . .
O1 Rh C3 C8 43.5(6) . .
O1 Rh C3 C8 153.5(5) 2 .
C2 Rh C3 C8 119.7(7) . .
C5 Rh C3 C8 -160.0(6) . .
C4 Rh C3 C8 -123.6(7) . .
C1 Rh C3 C8 156.9(6) . .
C2 C3 C4 C5 -3.2(6) . .
C8 C3 C4 C5 179.7(5) . .
Rh C3 C4 C5 59.7(4) . .
C2 C3 C4 C9 174.4(5) . .
C8 C3 C4 C9 -2.6(9) . .
Rh C3 C4 C9 -122.7(6) . .
C2 C3 C4 Rh -62.9(4) . .
C8 C3 C4 Rh 120.1(6) . .
N1 Rh C4 C5 137.9(3) . .
O1 Rh C4 C5 -142.7(3) . .
C3 Rh C4 C5 -119.6(5) . .
O1 Rh C4 C5 33.6(4) 2 .
C2 Rh C4 C5 -80.9(4) . .
C1 Rh C4 C5 -38.0(3) . .
N1 Rh C4 C3 -102.5(3) . .
O1 Rh C4 C3 -23.1(5) . .
O1 Rh C4 C3 153.2(3) 2 .
C2 Rh C4 C3 38.7(3) . .
C5 Rh C4 C3 119.6(5) . .
C1 Rh C4 C3 81.6(4) . .
N1 Rh C4 C9 16.9(6) . .
O1 Rh C4 C9 96.3(6) . .
C3 Rh C4 C9 119.4(7) . .
O1 Rh C4 C9 -87.4(6) 2 .
C2 Rh C4 C9 158.1(7) . .
C5 Rh C4 C9 -121.0(7) . .
C1 Rh C4 C9 -159.0(7) . .
C3 C4 C5 C1 3.0(6) . .
C9 C4 C5 C1 -174.7(5) . .
Rh C4 C5 C1 61.4(3) . .
C3 C4 C5 C10 -177.9(5) . .
C9 C4 C5 C10 4.4(9) . .
Rh C4 C5 C10 -119.5(5) . .
C3 C4 C5 Rh -58.5(4) . .
C9 C4 C5 Rh 123.9(6) . .
C2 C1 C5 C4 -1.6(6) . .
C6 C1 C5 C4 177.1(5) . .
Rh C1 C5 C4 -61.6(4) . .
C2 C1 C5 C10 179.3(5) . .
C6 C1 C5 C10 -2.0(8) . .
Rh C1 C5 C10 119.3(5) . .
C2 C1 C5 Rh 60.0(4) . .
C6 C1 C5 Rh -121.3(5) . .
N1 Rh C5 C4 -53.5(4) . .
O1 Rh C5 C4 120.3(5) . .
C3 Rh C5 C4 37.1(3) . .
O1 Rh C5 C4 -156.6(3) 2 .
C2 Rh C5 C4 80.7(4) . .
C1 Rh C5 C4 117.8(5) . .
N1 Rh C5 C1 -171.3(3) . .
O1 Rh C5 C1 2.5(6) . .
C3 Rh C5 C1 -80.7(3) . .
O1 Rh C5 C1 85.6(3) 2 .
C2 Rh C5 C1 -37.1(3) . .
C4 Rh C5 C1 -117.8(5) . .
N1 Rh C5 C10 69.2(6) . .
O1 Rh C5 C10 -117.0(6) . .
C3 Rh C5 C10 159.7(6) . .
O1 Rh C5 C10 -33.9(6) 2 .
C2 Rh C5 C10 -156.6(6) . .
C4 Rh C5 C10 122.6(7) . .
C1 Rh C5 C10 -119.5(7) . .
C15 N1 C11 C12 -1.1(9) . .
Rh N1 C11 C12 172.5(5) . .
N1 C11 C12 C13 0.5(10) . .
C11 C12 C13 C14 0.4(11) . .
C12 C13 C14 C15 -0.6(11) . .
C11 N1 C15 C14 0.8(8) . .
Rh N1 C15 C14 -173.6(5) . .
C11 N1 C15 C16 -179.3(5) . .
Rh N1 C15 C16 6.3(6) . .
C13 C14 C15 N1 0.0(10) . .
C13 C14 C15 C16 -179.9(6) . .
Rh O1 C16 C15 -35.3(5) . .
Rh O1 C16 C15 83.6(5) 2 .
N1 C15 C16 O1 19.7(7) . .
C14 C15 C16 O1 -160.5(6) . .
F5B Sb2 F4 F4B 165.6(10) 2_655 .
F5B Sb2 F4 F4B 34.6(11) . .
F4 Sb2 F4 F4B -71.7(9) 2_655 .
F4B Sb2 F4 F4B -96.9(11) 2_655 .
F6 Sb2 F4 F4B 179.2(8) 2_655 .
F6 Sb2 F4 F4B 72.9(10) . .
F6B Sb2 F4 F4B 121.1(10) . .
F6B Sb2 F4 F4B -12(2) 2_655 .
F5 Sb2 F4 F4B -150.3(11) 2_655 .
F5 Sb2 F4 F4B -10.3(10) . .
F4 Sb2 F5 F5B -123.8(6) 2_655 .
F4 Sb2 F5 F5B 132.3(5) . .
F4B Sb2 F5 F5B -136.7(5) 2_655 .
F4B Sb2 F5 F5B 126.9(6) . .
F6 Sb2 F5 F5B -55.6(7) 2_655 .
F6 Sb2 F5 F5B 38.0(5) . .
F6B Sb2 F5 F5B 68.1(6) . .
F6B Sb2 F5 F5B -48.2(5) 2_655 .
F5 Sb2 F5 F5B -179.8(5) 2_655 .
F5B Sb2 F6 F5B 130.6(7) 2_655 .
F4 Sb2 F6 F5B -19.3(9) 2_655 .
F4 Sb2 F6 F5B -130.3(6) . .
F4B Sb2 F6 F5B -17(2) 2_655 .
F4B Sb2 F6 F5B -104.8(7) . .
F6 Sb2 F6 F5B 85.9(6) 2_655 .
F6B Sb2 F6 F5B 164.3(8) . .
F6B Sb2 F6 F5B 35.4(6) 2_655 .
F5 Sb2 F6 F5B 173.6(6) 2_655 .
F5 Sb2 F6 F5B -46.4(6) . .
F5B Sb2 F6 F6B -33.8(6) 2_655 .
F5B Sb2 F6 F6B -164.3(8) . .
F4 Sb2 F6 F6B 176.4(6) 2_655 .
F4 Sb2 F6 F6B 65.4(6) . .
F4B Sb2 F6 F6B 178.3(19) 2_655 .
F4B Sb2 F6 F6B 90.9(6) . .
F6 Sb2 F6 F6B -78.4(5) 2_655 .
F6B Sb2 F6 F6B -128.9(6) 2_655 .
F5 Sb2 F6 F6B 9.3(7) 2_655 .
F5 Sb2 F6 F6B 149.3(5) . .
F5B Sb2 F4B F4 -17.4(12) 2_655 .
F5B Sb2 F4B F4 -150.2(10) . .
F4 Sb2 F4B F4 110.6(10) 2_655 .
F4B Sb2 F4B F4 84.1(10) 2_655 .
F6 Sb2 F4B F4 -3(3) 2_655 .
F6 Sb2 F4B F4 -106.9(10) . .
F6B Sb2 F4B F4 -55.1(10) . .
F6B Sb2 F4B F4 175.4(9) 2_655 .
F5 Sb2 F4B F4 26.3(10) 2_655 .
F5 Sb2 F4B F4 167.9(11) . .
F6B F6 F5B F6B -39.7(13) . 2_655
Sb2 F6 F5B F6B -56.9(8) . 2_655
F6B F6 F5B Sb2 17.2(9) . .
F6B F6 F5B F5 79.4(11) . .
Sb2 F6 F5B F5 62.2(6) . .
F5B Sb2 F5B F6 -60.1(5) 2_655 .
F4 Sb2 F5B F6 168.2(6) 2_655 .
F4 Sb2 F5B F6 61.5(7) . .
F4B Sb2 F5B F6 176.0(5) 2_655 .
F4B Sb2 F5B F6 76.4(6) . .
F6 Sb2 F5B F6 -97.7(7) 2_655 .
F6B Sb2 F5B F6 -12.3(6) . .
F6B Sb2 F5B F6 -131.9(8) 2_655 .
F5 Sb2 F5B F6 119.7(7) . .
F4 Sb2 F5B F6B -59.8(6) 2_655 2_655
F4 Sb2 F5B F6B -166.6(5) . 2_655
F4B Sb2 F5B F6B -52.0(7) 2_655 2_655
F4B Sb2 F5B F6B -151.7(6) . 2_655
F6 Sb2 F5B F6B 34.2(6) 2_655 2_655
F6 Sb2 F5B F6B 131.9(8) . 2_655
F6B Sb2 F5B F6B 119.6(7) . 2_655
F5 Sb2 F5B F6B -108.4(7) . 2_655
F5B Sb2 F5B F5 -179.8(5) 2_655 .
F4 Sb2 F5B F5 48.6(5) 2_655 .
F4 Sb2 F5B F5 -58.2(6) . .
F4B Sb2 F5B F5 56.4(6) 2_655 .
F4B Sb2 F5B F5 -43.3(5) . .
F6 Sb2 F5B F5 142.6(5) 2_655 .
F6 Sb2 F5B F5 -119.7(7) . .
F6B Sb2 F5B F5 -132.0(5) . .
F6B Sb2 F5B F5 108.4(7) 2_655 .
Sb2 F5 F5B F6 -64.4(7) . .
Sb2 F5 F5B F6B 66.8(6) . 2_655
F5B F6 F6B F5B 22.1(11) . 2_655
Sb2 F6 F6B F5B 38.5(6) . 2_655
F5B F6 F6B Sb2 -16.4(8) . .
F5B Sb2 F6B F5B -123.3(7) . 2_655
F4 Sb2 F6B F5B 54.5(18) 2_655 2_655
F4 Sb2 F6B F5B 117.0(6) . 2_655
F4B Sb2 F6B F5B 46.2(9) 2_655 2_655
F4B Sb2 F6B F5B 139.5(6) . 2_655
F6 Sb2 F6B F5B -31.7(6) 2_655 2_655
F6 Sb2 F6B F5B -134.3(7) . 2_655
F6B Sb2 F6B F5B -74.6(5) 2_655 2_655
F5 Sb2 F6B F5B 52.6(6) 2_655 2_655
F5 Sb2 F6B F5B -173.8(6) . 2_655
F5B Sb2 F6B F6 134.3(7) 2_655 .
F5B Sb2 F6B F6 11.0(6) . .
F4 Sb2 F6B F6 -171.1(15) 2_655 .
F4 Sb2 F6B F6 -108.7(6) . .
F4B Sb2 F6B F6 -179.5(6) 2_655 .
F4B Sb2 F6B F6 -86.1(5) . .
F6 Sb2 F6B F6 102.6(6) 2_655 .
F6B Sb2 F6B F6 59.7(4) 2_655 .
F5 Sb2 F6B F6 -173.1(5) 2_655 .
F5 Sb2 F6B F6 -39.4(7) . .
