#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/60/4086082.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4086082
loop_
_publ_author_name
'Abdel-Rahman, Obadah S.'
'Maurer, Jörg'
'Záliš, Stanislav'
'Winter, Rainer F.'
_publ_section_title
;
 Ruthenium Styryl Complexes with Ligands Derived from 2-Hydroxy- and
 2-Mercaptopyridine and 2-Hydroxy- and 2-Mercaptoquinoline
;
_journal_issue                   14
_journal_name_full               Organometallics
_journal_page_first              3611
_journal_paper_doi               10.1021/acs.organomet.5b00401
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C37 H54 F3 N O2 P2 Ru'
_chemical_formula_sum            'C37 H54 F3 N O2 P2 Ru'
_chemical_formula_weight         764.82
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.18(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   44.471(9)
_cell_length_b                   9.0287(18)
_cell_length_c                   18.372(4)
_cell_measurement_reflns_used    40820
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.23
_cell_measurement_theta_min      1.81
_cell_volume                     7282(3)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0636
_diffrn_reflns_av_sigmaI/netI    0.0384
_diffrn_reflns_limit_h_max       56
_diffrn_reflns_limit_h_min       -56
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            47906
_diffrn_reflns_theta_full        26.90
_diffrn_reflns_theta_max         26.90
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    0.567
_exptl_absorpt_correction_T_max  0.8494
_exptl_absorpt_correction_T_min  0.6703
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   empirical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.395
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3200
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.267
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.695
_refine_diff_density_min         -0.661
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         7732
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0562
_refine_ls_R_factor_gt           0.0408
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0327P)²+18.7516P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0802
_refine_ls_wR_factor_ref         0.0841
_reflns_number_gt                6228
_reflns_number_total             7732
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5b00401_si_002.cif
_cod_data_source_block           obada2
_cod_depositor_comments
'Adding full bibliography for 4086081--4086085.cif.'
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4086082
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.616971(5) 0.28177(2) 0.914088(12) 0.01369(6) Uani 1 1 d .
P1 P 0.578108(15) 0.22276(8) 0.98880(4) 0.01525(14) Uani 1 1 d .
O1 O 0.59007(4) 0.1350(2) 0.83155(11) 0.0174(4) Uani 1 1 d .
N1 N 0.58234(5) 0.3778(3) 0.82800(12) 0.0156(5) Uani 1 1 d .
C1 C 0.64469(6) 0.1279(3) 0.97039(15) 0.0166(5) Uani 1 1 d .
H1A H 0.6445 0.0367 0.9446 0.020 Uiso 1 1 calc R
F1 F 0.76732(5) -0.3021(3) 1.20673(13) 0.0492(6) Uani 1 1 d .
P2 P 0.656488(16) 0.31790(8) 0.83876(4) 0.01606(15) Uani 1 1 d .
O2 O 0.64426(5) 0.5142(2) 1.01906(12) 0.0254(5) Uani 1 1 d .
F2 F 0.76562(5) -0.3727(3) 1.09527(13) 0.0509(6) Uani 1 1 d .
C2 C 0.66328(6) 0.1250(3) 1.03602(16) 0.0193(6) Uani 1 1 d .
H2A H 0.6632 0.2100 1.0664 0.023 Uiso 1 1 calc R
F3 F 0.73473(5) -0.4642(2) 1.16081(14) 0.0432(5) Uani 1 1 d .
C3 C 0.68368(6) 0.0032(3) 1.06511(16) 0.0194(6) Uani 1 1 d .
C4 C 0.70616(7) 0.0280(3) 1.12656(16) 0.0221(6) Uani 1 1 d .
H4A H 0.7072 0.1219 1.1502 0.027 Uiso 1 1 calc R
C5 C 0.72689(7) -0.0812(4) 1.15375(17) 0.0249(6) Uani 1 1 d .
H5A H 0.7420 -0.0617 1.1954 0.030 Uiso 1 1 calc R
C6 C 0.72557(6) -0.2187(4) 1.12002(17) 0.0237(6) Uani 1 1 d .
C7 C 0.70286(8) -0.2476(3) 1.06020(19) 0.0313(8) Uani 1 1 d .
H7A H 0.7016 -0.3424 1.0375 0.038 Uiso 1 1 calc R
C8 C 0.68219(7) -0.1382(4) 1.03383(18) 0.0309(7) Uani 1 1 d .
H8A H 0.6666 -0.1597 0.9935 0.037 Uiso 1 1 calc R
C9 C 0.74807(7) -0.3369(4) 1.14545(18) 0.0291(7) Uani 1 1 d .
C10 C 0.63359(6) 0.4226(3) 0.97722(15) 0.0184(6) Uani 1 1 d .
C11 C 0.57395(6) 0.2442(3) 0.80021(15) 0.0167(6) Uani 1 1 d .
C12 C 0.54866(6) 0.2267(3) 0.74159(15) 0.0186(5) Uani 1 1 d .
H12A H 0.5425 0.1309 0.7236 0.022 Uiso 1 1 calc R
C13 C 0.53374(6) 0.3489(3) 0.71233(15) 0.0196(6) Uani 1 1 d .
H13A H 0.5169 0.3387 0.6738 0.024 Uiso 1 1 calc R
C14 C 0.54307(6) 0.4930(3) 0.73881(15) 0.0179(6) Uani 1 1 d .
C15 C 0.52885(7) 0.6242(3) 0.70886(16) 0.0224(6) Uani 1 1 d .
H15A H 0.5122 0.6181 0.6696 0.027 Uiso 1 1 calc R
C16 C 0.53878(7) 0.7602(3) 0.73564(17) 0.0227(6) Uani 1 1 d .
H16A H 0.5292 0.8478 0.7148 0.027 Uiso 1 1 calc R
C17 C 0.56343(7) 0.7698(3) 0.79454(17) 0.0240(6) Uani 1 1 d .
H17A H 0.5705 0.8642 0.8125 0.029 Uiso 1 1 calc R
C18 C 0.57724(7) 0.6441(3) 0.82618(16) 0.0198(6) Uani 1 1 d .
H18A H 0.5932 0.6520 0.8669 0.024 Uiso 1 1 calc R
C19 C 0.56767(6) 0.5031(3) 0.79816(15) 0.0164(5) Uani 1 1 d .
C20 C 0.57605(7) 0.3466(3) 1.06819(15) 0.0204(6) Uani 1 1 d .
H20A H 0.5577 0.3162 1.0895 0.024 Uiso 1 1 calc R
C21 C 0.57103(7) 0.5091(3) 1.04329(18) 0.0251(7) Uani 1 1 d .
H21A H 0.5699 0.5717 1.0863 0.038 Uiso 1 1 calc R
H21B H 0.5520 0.5171 1.0084 0.038 Uiso 1 1 calc R
H21C H 0.5881 0.5417 1.0193 0.038 Uiso 1 1 calc R
C22 C 0.60341(7) 0.3336(4) 1.13024(16) 0.0258(6) Uani 1 1 d .
H22A H 0.6007 0.4015 1.1703 0.039 Uiso 1 1 calc R
H22B H 0.6221 0.3594 1.1111 0.039 Uiso 1 1 calc R
H22C H 0.6049 0.2318 1.1489 0.039 Uiso 1 1 calc R
C23 C 0.53737(6) 0.2286(3) 0.94008(15) 0.0181(5) Uani 1 1 d .
H23A H 0.5366 0.3082 0.9020 0.022 Uiso 1 1 calc R
C24 C 0.51294(6) 0.2690(4) 0.98767(16) 0.0228(6) Uani 1 1 d .
H24A H 0.4928 0.2693 0.9568 0.034 Uiso 1 1 calc R
H24B H 0.5173 0.3675 1.0092 0.034 Uiso 1 1 calc R
H24C H 0.5132 0.1958 1.0272 0.034 Uiso 1 1 calc R
C25 C 0.52758(7) 0.0848(3) 0.89781(16) 0.0217(6) Uani 1 1 d .
H25A H 0.5064 0.0939 0.8735 0.033 Uiso 1 1 calc R
H25B H 0.5294 0.0014 0.9324 0.033 Uiso 1 1 calc R
H25C H 0.5407 0.0676 0.8606 0.033 Uiso 1 1 calc R
C26 C 0.58443(7) 0.0376(3) 1.03377(15) 0.0190(6) Uani 1 1 d .
H26A H 0.6048 0.0452 1.0658 0.023 Uiso 1 1 calc R
C27 C 0.58766(7) -0.0906(3) 0.98069(16) 0.0217(6) Uani 1 1 d .
H27A H 0.5909 -0.1834 1.0085 0.033 Uiso 1 1 calc R
H27B H 0.6051 -0.0721 0.9554 0.033 Uiso 1 1 calc R
H27C H 0.5691 -0.0983 0.9442 0.033 Uiso 1 1 calc R
C28 C 0.56235(7) -0.0039(3) 1.08628(17) 0.0240(6) Uani 1 1 d .
H28A H 0.5675 -0.1024 1.1070 0.036 Uiso 1 1 calc R
H28B H 0.5415 -0.0047 1.0592 0.036 Uiso 1 1 calc R
H28C H 0.5639 0.0689 1.1263 0.036 Uiso 1 1 calc R
C29 C 0.69566(6) 0.2749(4) 0.88751(17) 0.0234(6) Uani 1 1 d .
H29A H 0.6936 0.1784 0.9129 0.028 Uiso 1 1 calc R
C30 C 0.70739(7) 0.3835(4) 0.94949(19) 0.0315(7) Uani 1 1 d .
H30A H 0.7279 0.3542 0.9726 0.047 Uiso 1 1 calc R
H30B H 0.6938 0.3822 0.9864 0.047 Uiso 1 1 calc R
H30C H 0.7080 0.4835 0.9291 0.047 Uiso 1 1 calc R
C31 C 0.72019(7) 0.2479(4) 0.83971(19) 0.0283(7) Uani 1 1 d .
H31A H 0.7396 0.2258 0.8713 0.043 Uiso 1 1 calc R
H31B H 0.7225 0.3365 0.8103 0.043 Uiso 1 1 calc R
H31C H 0.7143 0.1639 0.8067 0.043 Uiso 1 1 calc R
C32 C 0.65551(7) 0.5056(3) 0.79668(17) 0.0205(6) Uani 1 1 d .
H32A H 0.6343 0.5169 0.7694 0.025 Uiso 1 1 calc R
C33 C 0.67633(7) 0.5311(4) 0.73840(18) 0.0277(7) Uani 1 1 d .
H33A H 0.6739 0.6330 0.7201 0.042 Uiso 1 1 calc R
H33B H 0.6708 0.4619 0.6974 0.042 Uiso 1 1 calc R
H33C H 0.6976 0.5146 0.7607 0.042 Uiso 1 1 calc R
C34 C 0.65969(8) 0.6343(3) 0.85189(19) 0.0292(7) Uani 1 1 d .
H34A H 0.6588 0.7284 0.8251 0.044 Uiso 1 1 calc R
H34B H 0.6795 0.6252 0.8837 0.044 Uiso 1 1 calc R
H34C H 0.6434 0.6314 0.8822 0.044 Uiso 1 1 calc R
C35 C 0.65450(7) 0.1933(3) 0.75653(16) 0.0223(6) Uani 1 1 d .
H35A H 0.6737 0.2099 0.7357 0.027 Uiso 1 1 calc R
C36 C 0.65450(7) 0.0314(3) 0.77868(18) 0.0271(7) Uani 1 1 d .
H36A H 0.6535 -0.0309 0.7347 0.041 Uiso 1 1 calc R
H36B H 0.6368 0.0114 0.8028 0.041 Uiso 1 1 calc R
H36C H 0.6732 0.0091 0.8129 0.041 Uiso 1 1 calc R
C37 C 0.62802(7) 0.2268(4) 0.69408(16) 0.0270(7) Uani 1 1 d .
H37A H 0.6286 0.1572 0.6534 0.041 Uiso 1 1 calc R
H37B H 0.6300 0.3283 0.6765 0.041 Uiso 1 1 calc R
H37C H 0.6086 0.2163 0.7126 0.041 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C10 Ru1 C1 90.09(12)
C10 Ru1 N1 110.68(11)
C1 Ru1 N1 159.19(10)
C10 Ru1 O1 170.34(10)
C1 Ru1 O1 99.04(10)
N1 Ru1 O1 60.30(8)
C10 Ru1 P2 90.70(9)
C1 Ru1 P2 86.93(8)
N1 Ru1 P2 91.40(6)
O1 Ru1 P2 92.93(5)
C10 Ru1 P1 92.69(9)
C1 Ru1 P1 89.48(8)
N1 Ru1 P1 90.76(6)
O1 Ru1 P1 84.29(5)
P2 Ru1 P1 175.07(3)
C20 P1 C26 102.43(13)
C20 P1 C23 101.08(13)
C26 P1 C23 107.47(13)
C20 P1 Ru1 116.19(10)
C26 P1 Ru1 112.07(9)
C23 P1 Ru1 116.15(9)
C11 O1 Ru1 92.77(16)
C11 N1 C19 120.2(2)
C11 N1 Ru1 92.27(16)
C19 N1 Ru1 147.48(19)
C2 C1 Ru1 134.8(2)
C2 C1 H1A 112.6
Ru1 C1 H1A 112.6
C32 P2 C29 110.29(14)
C32 P2 C35 102.53(14)
C29 P2 C35 100.50(14)
C32 P2 Ru1 112.86(10)
C29 P2 Ru1 113.80(10)
C35 P2 Ru1 115.70(10)
C1 C2 C3 126.4(3)
C1 C2 H2A 116.8
C3 C2 H2A 116.8
C8 C3 C4 117.3(3)
C8 C3 C2 123.2(3)
C4 C3 C2 119.5(3)
C5 C4 C3 121.6(3)
C5 C4 H4A 119.2
C3 C4 H4A 119.2
C6 C5 C4 119.9(3)
C6 C5 H5A 120.1
C4 C5 H5A 120.1
C5 C6 C7 119.6(3)
C5 C6 C9 121.7(3)
C7 C6 C9 118.7(3)
C8 C7 C6 120.0(3)
C8 C7 H7A 120.0
C6 C7 H7A 120.0
C7 C8 C3 121.5(3)
C7 C8 H8A 119.2
C3 C8 H8A 119.2
F1 C9 F2 105.7(3)
F1 C9 F3 105.6(3)
F2 C9 F3 105.3(3)
F1 C9 C6 113.8(3)
F2 C9 C6 113.2(3)
F3 C9 C6 112.5(3)
O2 C10 Ru1 179.2(3)
O1 C11 N1 114.5(2)
O1 C11 C12 124.0(3)
N1 C11 C12 121.5(3)
C13 C12 C11 118.9(3)
C13 C12 H12A 120.6
C11 C12 H12A 120.6
C12 C13 C14 120.7(3)
C12 C13 H13A 119.7
C14 C13 H13A 119.7
C15 C14 C19 119.2(3)
C15 C14 C13 123.0(3)
C19 C14 C13 117.8(3)
C16 C15 C14 120.9(3)
C16 C15 H15A 119.6
C14 C15 H15A 119.6
C15 C16 C17 119.7(3)
C15 C16 H16A 120.1
C17 C16 H16A 120.1
C18 C17 C16 120.8(3)
C18 C17 H17A 119.6
C16 C17 H17A 119.6
C17 C18 C19 120.1(3)
C17 C18 H18A 119.9
C19 C18 H18A 119.9
N1 C19 C18 120.0(3)
N1 C19 C14 120.8(3)
C18 C19 C14 119.2(3)
C22 C20 C21 110.7(2)
C22 C20 P1 114.0(2)
C21 C20 P1 111.3(2)
C22 C20 H20A 106.8
C21 C20 H20A 106.8
P1 C20 H20A 106.8
C20 C21 H21A 109.5
C20 C21 H21B 109.5
H21A C21 H21B 109.5
C20 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C20 C22 H22A 109.5
C20 C22 H22B 109.5
H22A C22 H22B 109.5
C20 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C25 C23 C24 108.5(2)
C25 C23 P1 112.84(19)
C24 C23 P1 116.53(19)
C25 C23 H23A 106.1
C24 C23 H23A 106.1
P1 C23 H23A 106.1
C23 C24 H24A 109.5
C23 C24 H24B 109.5
H24A C24 H24B 109.5
C23 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C23 C25 H25A 109.5
C23 C25 H25B 109.5
H25A C25 H25B 109.5
C23 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
C28 C26 C27 110.5(2)
C28 C26 P1 115.6(2)
C27 C26 P1 114.65(19)
C28 C26 H26A 104.9
C27 C26 H26A 104.9
P1 C26 H26A 104.9
C26 C27 H27A 109.5
C26 C27 H27B 109.5
H27A C27 H27B 109.5
C26 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
C26 C28 H28A 109.5
C26 C28 H28B 109.5
H28A C28 H28B 109.5
C26 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C31 C29 C30 109.9(3)
C31 C29 P2 117.1(2)
C30 C29 P2 113.9(2)
C31 C29 H29A 104.9
C30 C29 H29A 104.9
P2 C29 H29A 104.9
C29 C30 H30A 109.5
C29 C30 H30B 109.5
H30A C30 H30B 109.5
C29 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
C29 C31 H31A 109.5
C29 C31 H31B 109.5
H31A C31 H31B 109.5
C29 C31 H31C 109.5
H31A C31 H31C 109.5
H31B C31 H31C 109.5
C34 C32 C33 108.9(2)
C34 C32 P2 115.0(2)
C33 C32 P2 116.6(2)
C34 C32 H32A 105.0
C33 C32 H32A 105.0
P2 C32 H32A 105.0
C32 C33 H33A 109.5
C32 C33 H33B 109.5
H33A C33 H33B 109.5
C32 C33 H33C 109.5
H33A C33 H33C 109.5
H33B C33 H33C 109.5
C32 C34 H34A 109.5
C32 C34 H34B 109.5
H34A C34 H34B 109.5
C32 C34 H34C 109.5
H34A C34 H34C 109.5
H34B C34 H34C 109.5
C36 C35 C37 110.9(3)
C36 C35 P2 111.4(2)
C37 C35 P2 114.5(2)
C36 C35 H35A 106.5
C37 C35 H35A 106.5
P2 C35 H35A 106.5
C35 C36 H36A 109.5
C35 C36 H36B 109.5
H36A C36 H36B 109.5
C35 C36 H36C 109.5
H36A C36 H36C 109.5
H36B C36 H36C 109.5
C35 C37 H37A 109.5
C35 C37 H37B 109.5
H37A C37 H37B 109.5
C35 C37 H37C 109.5
H37A C37 H37C 109.5
H37B C37 H37C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ru1 C10 1.799(3)
Ru1 C1 2.028(3)
Ru1 N1 2.202(2)
Ru1 O1 2.216(2)
Ru1 P2 2.4263(10)
Ru1 P1 2.4315(9)
P1 C20 1.852(3)
P1 C26 1.866(3)
P1 C23 1.889(3)
O1 C11 1.299(3)
N1 C11 1.339(4)
N1 C19 1.375(4)
C1 C2 1.349(4)
C1 H1A 0.9500
F1 C9 1.338(4)
P2 C32 1.860(3)
P2 C29 1.868(3)
P2 C35 1.875(3)
O2 C10 1.176(4)
F2 C9 1.339(4)
C2 C3 1.471(4)
C2 H2A 0.9500
F3 C9 1.343(4)
C3 C8 1.398(4)
C3 C4 1.401(4)
C4 C5 1.387(4)
C4 H4A 0.9500
C5 C6 1.385(5)
C5 H5A 0.9500
C6 C7 1.393(4)
C6 C9 1.486(4)
C7 C8 1.383(4)
C7 H7A 0.9500
C8 H8A 0.9500
C11 C12 1.437(4)
C12 C13 1.354(4)
C12 H12A 0.9500
C13 C14 1.427(4)
C13 H13A 0.9500
C14 C15 1.413(4)
C14 C19 1.419(4)
C15 C16 1.370(4)
C15 H15A 0.9500
C16 C17 1.415(4)
C16 H16A 0.9500
C17 C18 1.374(4)
C17 H17A 0.9500
C18 C19 1.413(4)
C18 H18A 0.9500
C20 C22 1.533(4)
C20 C21 1.542(4)
C20 H20A 1.0000
C21 H21A 0.9800
C21 H21B 0.9800
C21 H21C 0.9800
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 C25 1.539(4)
C23 C24 1.543(4)
C23 H23A 1.0000
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 H25A 0.9800
C25 H25B 0.9800
C25 H25C 0.9800
C26 C28 1.529(4)
C26 C27 1.535(4)
C26 H26A 1.0000
C27 H27A 0.9800
C27 H27B 0.9800
C27 H27C 0.9800
C28 H28A 0.9800
C28 H28B 0.9800
C28 H28C 0.9800
C29 C31 1.525(4)
C29 C30 1.529(4)
C29 H29A 1.0000
C30 H30A 0.9800
C30 H30B 0.9800
C30 H30C 0.9800
C31 H31A 0.9800
C31 H31B 0.9800
C31 H31C 0.9800
C32 C34 1.534(4)
C32 C33 1.541(4)
C32 H32A 1.0000
C33 H33A 0.9800
C33 H33B 0.9800
C33 H33C 0.9800
C34 H34A 0.9800
C34 H34B 0.9800
C34 H34C 0.9800
C35 C36 1.517(4)
C35 C37 1.537(4)
C35 H35A 1.0000
C36 H36A 0.9800
C36 H36B 0.9800
C36 H36C 0.9800
C37 H37A 0.9800
C37 H37B 0.9800
C37 H37C 0.9800
